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Synthetic route

glycerol
56-81-5

glycerol

A

allyl alcohol
107-18-6

allyl alcohol

B

hydroxy-2-propanone
116-09-6

hydroxy-2-propanone

C

acrolein
107-02-8

acrolein

Conditions
ConditionsYield
With H3PO4-activated and WOx-loaded montmorillonite nanocatalyst In water at 320℃; for 3h; Reagent/catalyst; Flow reactor;A n/a
B n/a
C 67.3%
With phosphorus containing Fe2O3 nanoparticles In water at 320℃; for 24h; Inert atmosphere;
With 10 w% WO3/ZrO2 at 250℃; Temperature; Time; Inert atmosphere;
With HZSM5/Fe/Rb In water at 340℃; under 760.051 Torr; Inert atmosphere;
With oxygen In water at 285℃; under 760.051 Torr; for 1h; Flow reactor;A 10.65 %Chromat.
B 19.63 %Chromat.
C 57.96 %Chromat.
propargyl alcohol
107-19-7

propargyl alcohol

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With piperazine; hydrogen In ethanol at 80℃; under 4500.45 Torr; for 24h;99%
With hydrogen In methanol at 20℃; under 760.051 Torr; for 4.5h; Green chemistry;98%
With hydrogen In methanol under 760.051 Torr; for 5h;97%
acrolein
107-02-8

acrolein

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With hydrogen In water at 110℃; under 22502.3 Torr; for 2.33333h; Reagent/catalyst; Pressure; Temperature;96%
With sulfuric acid; zinc diacetate; iron(II) sulfate at 25℃; bei der elektrolytischen Reduktion an einer amalgamierten Bleikathode; Reagens 4: Hydrochinon;
With aluminum isopropoxide; isopropyl alcohol
allyl trifluoroacetate
383-67-5

allyl trifluoroacetate

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere;A 95%
B n/a
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen; triethylamine In toluene at 90℃; under 52505.3 Torr; for 17h; Inert atmosphere; Glovebox;
With C21H35BrMnN2O2P; hydrogen; potassium hydride; 1,3,5-trimethyl-benzene In toluene at 100℃; under 15001.5 Torr; for 60h; Autoclave; Inert atmosphere;A 97 %Spectr.
B 96 %Spectr.
With C21H35BrMnN2O2P; hydrogen; potassium hydride In toluene at 100℃; under 15001.5 Torr; for 60h;A 97 %Spectr.
B 96 %Spectr.
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
72824-04-5

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene; water; triethylamine In acetonitrile at 20℃; for 1h;67%
With sodium periodate; iodobenzene In water; acetonitrile at 80℃; for 8h;64%
glycerol
56-81-5

glycerol

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With formic acid at 235℃;98%
With rhenium trioxide; hydrogen at 140℃; Temperature; Reagent/catalyst; Solvent; Time;91%
In water at 148℃; for 2.5h; Catalytic behavior; Reagent/catalyst; Temperature; Solvent; Sealed tube;91%
2-(prop-2-en-1-yloxy)oxane
69161-61-1, 4203-49-0

2-(prop-2-en-1-yloxy)oxane

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With methanol at 20℃; for 0.5h;98%
With methanol; zirconium(IV) chloride at 20℃; for 4h;96%
ruthenium trichloride In water; acetonitrile at 20℃; for 0.333333h;96%
3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With tetrabutylammomium bromide; water; sodium hydroxide In hexane at 25℃; pH=5;90%
With water; sodium hydrogencarbonate at 150℃;
With copper; potassium carbonate
With fluoride In gas Rate constant; reaction efficiency;
propargyl alcohol
107-19-7

propargyl alcohol

A

propan-1-ol
71-23-8

propan-1-ol

B

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
palladium anchored polystyrene In neat (no solvent) at 25℃; under 41371.8 Torr; for 15h;A 5%
B 90%
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics;A n/a
B 85%
With hydrogen; palladium dichloride In N,N-dimethyl-formamide under 18751.5 Torr; for 0.316667h; Product distribution; Ambient temperature; various time;A 2.6%
B 76.3%
propylene glycol
57-55-6

propylene glycol

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With KOH/ZrO2 In water at 225℃; Reagent/catalyst; Temperature; Solvent;47%
(E)-4-(acetoxy)-1-phenyl-2-buten-1-one
127391-77-9

(E)-4-(acetoxy)-1-phenyl-2-buten-1-one

A

3-hydroxy-1-phenyl-but-2-en-1-one
33951-43-8

3-hydroxy-1-phenyl-but-2-en-1-one

B

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
Stage #1: (E)-4-(acetoxy)-1-phenyl-2-buten-1-one With bis(iodozinc)methane In tetrahydrofuran at 25℃; Inert atmosphere;
Stage #2: With ammonium chloride In tetrahydrofuran; water Inert atmosphere;
A 91%
B n/a
glycerol
56-81-5

glycerol

A

acetaldehyde
75-07-0

acetaldehyde

B

allyl alcohol
107-18-6

allyl alcohol

C

acrolein
107-02-8

acrolein

Conditions
ConditionsYield
With H3PO4-activated and WOx-loaded montmorillonite nanocatalyst In water at 320℃; for 3h; Flow reactor;A n/a
B n/a
C 50.7%
trimethyleneglycol
504-63-2

trimethyleneglycol

allyl alcohol
107-18-6

allyl alcohol

tris(allyl)borate
1693-71-6

tris(allyl)borate

n-perfluorohexyl iodide
355-43-1

n-perfluorohexyl iodide

A

2-iodo-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononan-1-ol
38550-44-6

2-iodo-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononan-1-ol

B

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
Stage #1: tris(allyl)borate; n-perfluorohexyl iodide With 2,2'-azobis(isobutyronitrile) at 60 - 70℃; for 3h;
Stage #2: With water at 60℃;
A 99%
B n/a
glycerol
56-81-5

glycerol

A

acetaldehyde
75-07-0

acetaldehyde

B

allyl alcohol
107-18-6

allyl alcohol

C

hydroxy-2-propanone
116-09-6

hydroxy-2-propanone

D

acrolein
107-02-8

acrolein

Conditions
ConditionsYield
With H3PO4-activated and WOx-loaded montmorillonite nanocatalyst In water at 320℃; for 3h; Reagent/catalyst; Flow reactor;A n/a
B n/a
C n/a
D 46.7%
glycerol
56-81-5

glycerol

A

propan-1-ol
71-23-8

propan-1-ol

B

propylene glycol
57-55-6

propylene glycol

C

allyl alcohol
107-18-6

allyl alcohol

D

isopropyl alcohol
67-63-0

isopropyl alcohol

Conditions
ConditionsYield
With hydrogen In 1,4-dioxane at 20 - 140℃; under 7500.75 - 60006 Torr; for 32h; Autoclave;
glycerol
56-81-5

glycerol

A

propan-1-ol
71-23-8

propan-1-ol

B

propylene glycol
57-55-6

propylene glycol

C

propene
187737-37-7

propene

D

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With hydrogen In 1,4-dioxane at 20 - 140℃; under 7500.75 - 60006 Torr; for 4h; Time; Autoclave;
methyloxirane
75-56-9, 16033-71-9

methyloxirane

A

propionaldehyde
123-38-6

propionaldehyde

B

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With lithium phosphate at 245 - 250℃;
With aluminum oxide at 275℃;
With chromium(III) oxide at 350℃;
With gold nanoparticles supported on hollow mesoporous silica (Au/SiO2) at 370℃;
oxalic acid
144-62-7

oxalic acid

glycerol
56-81-5

glycerol

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With alumina-supported iron In water at 340℃; Inert atmosphere;17.5%
Allyl acetate
591-87-7

Allyl acetate

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With water; ion exchange resin Diaion SK104H at 80℃; under 3750.38 Torr;
With water; ion exchange resin Diaion SK104H at 80℃; under 3750.38 Torr;
With water Product distribution / selectivity;
propylene glycol
57-55-6

propylene glycol

diallyl isophthalate
1087-21-4

diallyl isophthalate

A

Reaxys ID: 11381386

Reaxys ID: 11381386

B

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With di(n-butyl)tin oxide at 180℃; under 0.975098 - 9.976 Torr; for 2h;
propylene glycol
57-55-6

propylene glycol

diallyl isophthalate
1087-21-4

diallyl isophthalate

A

poly(diallyl isophthalate-co-propylene glycol)

poly(diallyl isophthalate-co-propylene glycol)

B

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With dibutyltin oxide at 180℃; under 0.975098 - 9.976 Torr; for 1h;
1,4-cyclohexanedicarboxylic acid, diallyl ester

1,4-cyclohexanedicarboxylic acid, diallyl ester

1,1,1-tri(hydroxymethyl)propane
77-99-6

1,1,1-tri(hydroxymethyl)propane

A

poly(diallyl 1,4-cyclohexane dicarboxylate-co-trimethylolpropane)

poly(diallyl 1,4-cyclohexane dicarboxylate-co-trimethylolpropane)

B

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With dibutyltin oxide at 180℃; under 0.975098 - 9.976 Torr; for 1h;
4,4'-isopropylidenebis[2-(2,6-dibromophenoxy)ethanol]
4162-45-2

4,4'-isopropylidenebis[2-(2,6-dibromophenoxy)ethanol]

diallyl isophthalate
1087-21-4

diallyl isophthalate

A

poly(2,2-bis[4-(2-hydroxyethoxy)-3,5-dibromophenyl]propane-co-diallyl isophthalate)

poly(2,2-bis[4-(2-hydroxyethoxy)-3,5-dibromophenyl]propane-co-diallyl isophthalate)

B

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With dibutyltin oxide at 180℃; under 0.975098 - 9.976 Torr; for 1h;
4,4'-isopropylidenebis[2-(2,6-dibromophenoxy)ethanol]
4162-45-2

4,4'-isopropylidenebis[2-(2,6-dibromophenoxy)ethanol]

diallyl terephthalate
1026-92-2

diallyl terephthalate

A

poly(2,2-bis[4-(2-hydroxyethoxy)-3,5-dibromophenyl]propane-co-diallyl terephthalate)

poly(2,2-bis[4-(2-hydroxyethoxy)-3,5-dibromophenyl]propane-co-diallyl terephthalate)

B

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With dibutyltin oxide at 180℃; under 0.975098 - 9.976 Torr; for 1h;
methyloxirane
75-56-9, 16033-71-9

methyloxirane

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With lithium phosphate at 280℃;
lithium phosphate containing about 0.1-0.3 wt percent of sodium and 0.3-0.5 wt percent of boron at 253 - 273℃; Conversion of starting material;
lithium phosphate containing 0.3 wt percent of boron at 273℃; Conversion of starting material;
allyloxytrimethylsilane
18146-00-4

allyloxytrimethylsilane

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With oxygen; manganese(II) p-aminobenzoate; cobalt(II) p-aminobenzoate; silica gel In hexane for 10.5h; Heating;88%
With oxygen; silica gel-supported Co/Mn p-aminobenzoate (1:1 mixture) In hexane for 12h; Heating;88%
trimethyleneglycol
504-63-2

trimethyleneglycol

A

allyl alcohol
107-18-6

allyl alcohol

B

acrolein
107-02-8

acrolein

Conditions
ConditionsYield
at 315℃; Gas phase;
propene
187737-37-7

propene

A

allyl alcohol
107-18-6

allyl alcohol

B

acrolein
107-02-8

acrolein

C

methyloxirane
75-56-9, 16033-71-9

methyloxirane

Conditions
ConditionsYield
With oxygen at 349.84℃; under 1125.11 Torr; Reagent/catalyst; Temperature;
propylene glycol
57-55-6

propylene glycol

A

2-ethyl-4-methyl-1,3-dioxolane
4359-46-0

2-ethyl-4-methyl-1,3-dioxolane

B

propionaldehyde
123-38-6

propionaldehyde

C

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With hydrogen In water at 320℃; for 5h; Temperature;

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