As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine c
Cas:75-89-8
Min.Order:1 Kilogram
FOB Price: $12.0 / 13.0
Type:Lab/Research institutions
inquiryProduct name: Trifluoroethanol ; TFE Cas No: 75-89-8 Assay: 99%min Hangzhou Verychem Science And Technology Co. Ltd. was set up in year 2004, it’s a young but fast growing company. In the twe
Cas:75-89-8
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:75-89-8
Min.Order:0 Metric Ton
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Type:Manufacturers
inquiryProduct informations Product Name 2,2,2-Trifluoroethanol CAS No. 75-89-8
Cas:75-89-8
Min.Order:1 Gram
FOB Price: $8.0
Type:Lab/Research institutions
inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:75-89-8
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryProduct Name: 2,2,2-Trifluoroethanol Synonyms: 2,2,2-Trifluoroethanol (TFEA);Three fluorine ethanol;2,2,2-Trifluor;Anti-TFE3 (N-terminal) antibody produced in goat;Transcription factor for IgH enhancer;2,2,2-Trifluoroethanol ReagentPlus(R), >=9
Cas:75-89-8
Min.Order:1 Kilogram
FOB Price: $200.0
Type:Lab/Research institutions
inquiryProduct Name 2,2,2-Trifluoroethanol Synonyms ,2,2-Trifluoroethyl alcohol;2(3H)-Benzofuranone, 5-hydroxy-;5-Hydroxy-3H-1-benzofuran-2-one;b,b,b-Trifluoroethyl alcohol;2,2,2-TRIFLUOROETHANOL, 99.8%, EXT
Cas:75-89-8
Min.Order:5 Metric Ton
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Type:Other
inquiry1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:Colorless transparent liquid Storage:Store in sealed contai
Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen
Cas:75-89-8
Min.Order:1 Kilogram
FOB Price: $35.0 / 50.0
Type:Trading Company
inquiryProductName:2,2,2-Trifluoroethanol Synonyms:TFE CASNo:75-89-8 EINECS:200-913-6 MolecularFormula:C2H3F3O MolecularWe… Superiority 1.Powerful R & D team 2.The ability of quantized production,from grams to tons;
Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:75-89-8
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Cas:75-89-8
Min.Order:1 Gram
FOB Price: $1.0
Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:75-89-8
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryTrifluoroethanolAppearance:Pls see the Details Storage:Keep away of light, hot, water, Store in dry, dark and ventilated place Package:according to customers' requirements Application:Steroids, Cosmetics Ingredients, APIs, Intermediates, OLED&Battery
Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediat
Product name: 2,2,2-Trifluoroethanol CAS No.:75-89-8 Molecule Formula:C2H3F3O Molecule Weight:100.04 Purity: 99.0% Package: 250kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard
Cas:75-89-8
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:75-89-8
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryHangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home
Cas:75-89-8
Min.Order:0 Metric Ton
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Type:Lab/Research institutions
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
Cas:75-89-8
Min.Order:100 Gram
Negotiable
Type:Lab/Research institutions
inquirymanufacture Application:The refence standard products, for lab use, also we could produce bigger quantity on yr requirement.
Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as
Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:75-89-8
Min.Order:1 Kilogram
FOB Price: $112.0
Type:Trading Company
inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; potassium tert-butylate; hydrogen In 1,4-dioxane at 40℃; under 7500.75 Torr; for 16h; Time; Concentration; Pressure; Temperature; Glovebox; Inert atmosphere; | 99% |
With lithium aluminium tetrahydride; diethyl ether |
Conditions | Yield |
---|---|
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 60℃; under 22502.3 Torr; for 2h; Pressure; Temperature; Time; Concentration; Reagent/catalyst; Autoclave; | 99% |
With hydrogen; phosphan | |
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 40℃; under 19001.3 Torr; for 24h; Autoclave; Inert atmosphere; | 98 %Spectr. |
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 40℃; under 18751.9 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Autoclave; | 92 %Spectr. |
With C46H43N7OPRu(1+)*BF4(1-); potassium tert-butylate; hydrogen In 1,4-dioxane at 100℃; under 37503.8 Torr; for 2h; Inert atmosphere; Autoclave; | 100 %Spectr. |
(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-n-decyl)trifluoroacetate
A
2,2,2-trifluoroethanol
B
3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere; | A 99% B n/a |
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere; | A 99% B n/a |
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen In toluene at 90℃; under 52505.3 Torr; for 17h; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere; Glovebox; | |
With C21H35BrMnN2O2P; hydrogen; potassium hydride; 1,3,5-trimethyl-benzene In toluene at 100℃; under 15001.5 Torr; for 28h; Autoclave; Inert atmosphere; | A 78 %Spectr. B 99 %Spectr. |
With C21H35BrMnN2O2P; hydrogen; potassium hydride In toluene at 100℃; under 15001.5 Torr; for 28h; | A 78 %Spectr. B 99 %Spectr. |
4-methylbenzyl trifluoroacetate
A
2,2,2-trifluoroethanol
B
4-Methylbenzyl alcohol
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere; | A 99% B n/a |
4-(trifluoromethyl)benzyl trifluoroacetate
A
4-(trifluoromethyl)benzylic alcohol
B
2,2,2-trifluoroethanol
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere; | A n/a B 99% |
4-fluorobenzyl trifluoroacetate
A
4-fluorobenzylic alcohol
B
2,2,2-trifluoroethanol
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere; | A n/a B 97% |
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen; triethylamine In toluene at 90℃; under 52505.3 Torr; for 17h; Inert atmosphere; Glovebox; |
Conditions | Yield |
---|---|
With potassium γ-hydroxybutyrate In 4-butanolide at 200℃; under 11251.1 Torr; for 6h; | 96% |
With 4-butanolide; potassium hydroxide at 200℃; under 11251.1 Torr; for 6h; | 68% |
With potassium acetate; ethylene glycol; acetic acid |
cyclohexylmethyl trifluoroacetate
A
2,2,2-trifluoroethanol
B
cyclohexylmethyl alcohol
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 48h; Glovebox; Inert atmosphere; | A 95% B n/a |
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen In toluene at 110℃; under 52505.3 Torr; for 17h; Catalytic behavior; Solvent; Temperature; Inert atmosphere; Glovebox; |
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere; | A 95% B n/a |
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen; triethylamine In toluene at 90℃; under 52505.3 Torr; for 17h; Inert atmosphere; Glovebox; | |
With C21H35BrMnN2O2P; hydrogen; potassium hydride; 1,3,5-trimethyl-benzene In toluene at 100℃; under 15001.5 Torr; for 60h; Autoclave; Inert atmosphere; | A 97 %Spectr. B 96 %Spectr. |
With C21H35BrMnN2O2P; hydrogen; potassium hydride In toluene at 100℃; under 15001.5 Torr; for 60h; | A 97 %Spectr. B 96 %Spectr. |
1,1,1-trifluoroethyl fluorosulfite
2,2,2-trifluoroethanol
Conditions | Yield |
---|---|
With water at 100℃; autoclave; | 93% |
trifluoroacetic acid-methyl ester
A
2,2,2-trifluoroethanol
B
2,2,2-trifluoro-1-methoxy-ethanol
Conditions | Yield |
---|---|
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 40℃; under 4500.45 Torr; for 19h; Pressure; Temperature; Time; Concentration; Reagent/catalyst; Autoclave; | A 7% B 93% |
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 40℃; under 15201 Torr; for 6h; Autoclave; Inert atmosphere; | |
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 40℃; under 7600.51 Torr; for 6h; Autoclave; Inert atmosphere; |
tris(2,2,2-trifluoroethyl)phosphite
2,2,3,3,4,4,5,5-octafluorovaleraldehyde
A
2,2,2-trifluoroethanol
Conditions | Yield |
---|---|
In benzene at 20 - 25℃; for 2h; | A n/a B 89% |
Conditions | Yield |
---|---|
With hydrogen; <(Ph3P)(Ph2P)RuH2-K+*diglyme>2 In toluene at 90℃; under 4650.4 Torr; for 20h; Title compound not separated from byproducts; | A n/a B 88% |
With (K(1+))2<(Ph3P)3(Ph2P)Ru2H4>(2-)*2C6H14O3; hydrogen In toluene at 90℃; under 4650.4 Torr; for 20h; |
Conditions | Yield |
---|---|
With [Zn(BH4)2(py)] In tetrahydrofuran for 1h; Heating; | 85% |
With lithium aluminium tetrahydride; diethyl ether | |
With platinum Hydrogenation.unter Druck und anschliessenden Behandeln mit Eiswasser; |
methyl(2,2,2-trifluoro-ethoxo){1,2-bis(diphenylphosphino)ethane}palladium
A
methane
B
ethane
C
2,2,2-trifluoroethanol
Conditions | Yield |
---|---|
In further solvent(s) Thermolysis (120°C) of starting complex (diphenylmethane, vac.).; GLC.; | A 11% B 10% C 84% |
but-2-en-1-yl 2,2,2-trifluoroacetate
A
(E/Z)-2-buten-1-ol
B
2,2,2-trifluoroethanol
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere; | A n/a B 84% |
2-methoxyethyl trifluoroacetate
A
2-methoxy-ethanol
B
2,2,2-trifluoroethanol
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere; | A n/a B 80% |
trifluoroacetic acid 2-phenylethyl ester
A
2,2,2-trifluoroethanol
B
2-phenylethanol
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere; | A 78% B n/a |
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen In toluene at 90℃; under 52505.3 Torr; for 17h; Inert atmosphere; Glovebox; |
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 60h; Glovebox; Inert atmosphere; | A 77% B n/a |
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen; triethylamine In toluene at 90℃; under 52505.3 Torr; for 17h; Inert atmosphere; Glovebox; |
Conditions | Yield |
---|---|
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Reagent/catalyst; Solvent; Time; Temperature; Glovebox; Inert atmosphere; | A 77% B n/a |
2,2,2-Trifluoroethyl cyanate
N-benzoyl-N'-benzylhydrazine
A
2,2,2-trifluoroethanol
B
3-Benzyl-5-phenyl-Δ4-1,3,4-oxadiazolin-2-imin
Conditions | Yield |
---|---|
In diethyl ether; ethanol for 1h; Ambient temperature; | A n/a B 75% |
1-[tris(trimethylsilyl)silyl]-2,2,2-trifluoroethanol
2,2,2-trifluoroethanol
Conditions | Yield |
---|---|
With methanol In dichloromethane at 10℃; for 0.5h; Product distribution; Irradiation; | 62% |
In methanol; dichloromethane desilylation; Photolysis; | 62% |
Conditions | Yield |
---|---|
With sulfur tetrafluoride at 160℃; for 8h; autoclave; | A 30% B 48% |
glycolic Acid
A
1,1,1,2-tetrafluoroethane
B
2,2,2-trifluoroethanol
C
1,1,1-trifluoroethyl fluorosulfite
Conditions | Yield |
---|---|
With sulfur tetrafluoride at 60℃; for 15h; autoclave; | A 26% B 5% C 42% |
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride; diethyl ether |
2,2,2-trifluoroethanol
Conditions | Yield |
---|---|
beim Aufbewahren; |
Conditions | Yield |
---|---|
With platinum(IV) oxide; diethyl ether at 90℃; Hydrogenation.unter Druck; |
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride; diethyl ether |
2,2,2-trifluoroethanol
p-toluenesulfonyl chloride
2,2,2-Trifluoroethyl p-toluenesulfonate
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 20℃; for 18h; Inert atmosphere; | 100% |
With triethylamine In dichloromethane at 20℃; for 18h; | 100% |
With triethylamine In chloroform for 6h; Ambient temperature; | 98% |
3-benzyl-1-methyl-2-oxo-2-phenyl-2λ5-[1,3,2]diazaphospholidin-4-one
2,2,2-trifluoroethanol
Conditions | Yield |
---|---|
With triethylamine In chloroform for 72h; | 100% |
2,2,2-trifluoroethanol
α-t-Butyldimethylsilylbenzyl p-toluenesulfonate
tert-Butyl-dimethyl-[phenyl-(2,2,2-trifluoro-ethoxy)-methyl]-silane
Conditions | Yield |
---|---|
With 2,6-dimethylpyridine | 100% |
2,2,2-trifluoroethanol
2-(4-methylphenyl)prop-2-en-1-yl 4-toluenesulfonate
2-(4-methylphenyl)-1-(2,2,2-trifluoroethoxy)prop-2-ene
Conditions | Yield |
---|---|
With 2,6-dimethylpyridine at 80℃; for 24h; | 100% |
at 65℃; Kinetics; Thermodynamic data; ΔH(excit.), ΔS(excit.), other temp.; | 100% |
2,2,2-trifluoroethanol
1-chlorocyclopropyl methyl sulfide
Conditions | Yield |
---|---|
at 0℃; | 100% |
2,2,2-trifluoroethanol
1-bromocyclopropyl benzyl sulfide
Conditions | Yield |
---|---|
at 0℃; | 100% |
2,2,2-trifluoroethanol
1-bromocyclopropyl phenetyl sulfide
Conditions | Yield |
---|---|
at 0℃; | 100% |
2,2,2-trifluoroethanol
4-chlorobenzonitrile
1-(2,2,2-trifluoroethoxy)-4-nitrobenzene
Conditions | Yield |
---|---|
With potassium tert-butylate In tetrahydrofuran; N,N-dimethyl-formamide at 25℃; for 1h; Inert atmosphere; | 100% |
Stage #1: 2,2,2-trifluoroethanol With sodium hydride In N,N-dimethyl-formamide Cooling with liquid nitrogen; Stage #2: 4-chlorobenzonitrile In N,N-dimethyl-formamide at 100℃; for 3h; Cooling with liquid nitrogen; | 98% |
With sodium hydride In N,N-dimethyl-formamide 1.) r.t., 2.) 130 deg C, 10 h; | 92% |
2,2,2-trifluoroethanol
phenyl chloroformate
2,2,2-trifluoroethyl phenyl carbonate
Conditions | Yield |
---|---|
With pyridine | 100% |
With pyridine In dichloromethane at 20℃; for 1h; |
Conditions | Yield |
---|---|
With pyridine; di-tert-butyl dicarbonate In tetrahydrofuran at 20℃; for 22h; | 100% |
With Candida antartica lipase B at 50℃; for 16h; Molecular sieve; Enzymatic reaction; | 96% |
With dmap; triethylamine; dicyclohexyl-carbodiimide In butan-1-ol at 20℃; pH=8 - 9; | 63.9% |
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane |
2,2,2-trifluoroethanol
(Z)-4-benzyloxy-but-2-en-1-ol
[2-(2,2,2-trifluoro-ethoxy)-but-3-enyloxymethyl]-benzene
Conditions | Yield |
---|---|
With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine In benzene at 20℃; for 6h; Mitsunobu reaction; | 100% |
2,2,2-trifluoroethanol
rac-3-bromocyclohexene
3-(2',2',2'-trifluoroethoxy)-cyclohex-1-ene
Conditions | Yield |
---|---|
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; tetra-(n-butyl)ammonium iodide | 100% |
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; tetra-(n-butyl)ammonium iodide at 20℃; for 12h; | 71% |
2,2,2-trifluoroethanol
3-Chloro-2-methylpropene
2-methyl-3-(2',2',2'-trifluoroethoxy)-prop-1-ene
Conditions | Yield |
---|---|
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; tetra-(n-butyl)ammonium iodide | 100% |
Stage #1: 2,2,2-trifluoroethanol With potassium hydroxide at 40℃; Stage #2: 3-Chloro-2-methylpropene In water at 40℃; | 78% |
With potassium carbonate In N,N-dimethyl-formamide |
2,2,2-trifluoroethanol
Conditions | Yield |
---|---|
With iodine; potassium carbonate at 50℃; for 5h; | 100% |
Conditions | Yield |
---|---|
With iodine; potassium carbonate at 50℃; for 5h; | 100% |
2,2,2-trifluoroethanol
(E)-4-(benzyloxy)-2-buten-1-ol
4-(2',2',2'-trifluoroethoxy)-1-benzyloxy-but-2Z-ene
Conditions | Yield |
---|---|
Stage #1: (E)-4-(benzyloxy)-2-buten-1-ol With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine In benzene at 20℃; for 0.166667h; Stage #2: 2,2,2-trifluoroethanol In benzene at 20℃; for 6h; | 100% |
Conditions | Yield |
---|---|
With boron trifluoride; toluene at 0℃; | 100% |
2,2,2-trifluoroethanol
5-chloro-4-formyl-1,3-dimethylpyrazole
1,3-dimethyl-5-(2,2,2-trifluoroethoxy)-1H-pyrazole-4-carbaldehyde
Conditions | Yield |
---|---|
With potassium tert-butylate In tetrahydrofuran at 0 - 20℃; for 3h; | 100% |
Conditions | Yield |
---|---|
silver trifluoromethanesulfonate at 25℃; | 100% |
2,2,2-trifluoroethanol
bis(2-fluoro-2,2-dinitroethyl)dichloroformal
bis(2-fluoro-2,2-dinitroethyl)bis(2,2,2-trifluoroethyl)orthocarbonate
Conditions | Yield |
---|---|
In 1,2-dichloro-ethane | 100% |
2,2,2-trifluoroethanol
bromoacetic acid tert-butyl ester
tert-butyl 2-(2,2,2-trifluoroethoxy)acetate
Conditions | Yield |
---|---|
Stage #1: 2,2,2-trifluoroethanol With sodium hydride In tetrahydrofuran at 0 - 20℃; for 0.75h; Stage #2: bromoacetic acid tert-butyl ester In tetrahydrofuran at 20℃; for 15h; | 100% |
2,2,2-trifluoroethanol
1,4-bis<(1-imidazolyl)carbonyloxy>-cis-2-butene
(Z)-but-2-ene-1,4-bis(2',2',2'-trifluoroethylcarbonate)
Conditions | Yield |
---|---|
With dmap In dichloromethane at 20℃; Inert atmosphere; | 100% |
2,2,2-trifluoroethanol
2,4-Difluoronitrobenzene
4-fluoro-1-nitro-2-(2,2,2-trifluoroethoxy)benzene
Conditions | Yield |
---|---|
With sodium hydroxide In toluene at 30 - 50℃; for 16.5h; | 100% |
With caesium carbonate In tetrahydrofuran at 20℃; | 99.8% |
With caesium carbonate In tetrahydrofuran at 25℃; for 8h; | 67% |
2,2,2-trifluoroethanol
5,11,17,23,29,35-hexa-tert-butyl-2-chloro-37,38,39,40,41,42-hexamethoxycalix[6]arene
Conditions | Yield |
---|---|
In chloroform Reflux; | 100% |
4-butoxy-2,2-bis-trifluoromethyl-oxetane
2,2,2-trifluoroethanol
C11H15F9O3
Conditions | Yield |
---|---|
at 25 - 35℃; | 100% |
2,2,2-trifluoroethanol
acrylonitrile
3-(2,2,2-trifluoroethoxy)propionitrile
Conditions | Yield |
---|---|
With [μN,κP,κC,κN-{2-(i-Pr2PO),6-(CH2NBn)-(C6H3)}Ni]2 In benzene at 20℃; for 5.5h; | 100% |
With C31H23F3NiO5P2S; triethylamine In toluene at 60℃; for 3h; Inert atmosphere; |
Conditions | Yield |
---|---|
With triethylamine at 20℃; for 5h; | 100% |
2,2,2-trifluoroethanol
2-chloro-4-amino-5-methylpyrimidine
5-methyl-2-(2,2,2-trifluoro-ethoxy)-pyrimidin-4-ylamine
Conditions | Yield |
---|---|
Stage #1: 2,2,2-trifluoroethanol With sodium for 1h; Inert atmosphere; Stage #2: 2-chloro-4-amino-5-methylpyrimidine at 90℃; | 100% |
Stage #1: 2,2,2-trifluoroethanol With sodium at 20℃; for 1h; Inert atmosphere; Stage #2: 2-chloro-4-amino-5-methylpyrimidine at 90℃; | 100% |
2,2,2-trifluoroethanol
2-Fluoro-5-nitrobenzotrifluoride
4-nitro-1-(2,2,2-trifluoroethoxy)-2-(trifluoromethyl)benzene
Conditions | Yield |
---|---|
Stage #1: 2,2,2-trifluoroethanol With sodium hydride In acetonitrile; mineral oil at 20℃; for 0.166667h; Inert atmosphere; Stage #2: 2-Fluoro-5-nitrobenzotrifluoride In acetonitrile; mineral oil for 1h; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 24h; Sealed tube; | 87% |
2,2,2-trifluoroethanol
5,6-dichloronicotinic acid
5-chloro-6-(2,2,2-trifluoroethoxy)nicotinic acid
Conditions | Yield |
---|---|
Stage #1: 2,2,2-trifluoroethanol With sodium hydride In N,N-dimethyl acetamide; mineral oil at 0℃; for 0.333333h; Stage #2: 5,6-dichloronicotinic acid In N,N-dimethyl acetamide; mineral oil at 90℃; for 2h; | 100% |
With potassium hydroxide In dimethyl sulfoxide at 120℃; for 24h; |
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