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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine c

High purity 2,2,2-Trifluoroethanol 75-89-8 /manufacturer/low price/high quality/in stock

Cas:75-89-8

Min.Order:1 Kilogram

FOB Price: $12.0 / 13.0

Type:Lab/Research institutions

inquiry

hangzhou verychem science and technology co.ltd

Product name: Trifluoroethanol ; TFE Cas No: 75-89-8 Assay: 99%min Hangzhou Verychem Science And Technology Co. Ltd. was set up in year 2004, it’s a young but fast growing company. In the twe

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Trifluoroethanol supplier in China

Cas:75-89-8

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Product informations Product Name 2,2,2-Trifluoroethanol CAS No. 75-89-8

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:1 Gram

FOB Price: $8.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,2,2-trifluoroethanol

Cas:75-89-8

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 2,2,2-Trifluoroethanol Synonyms: 2,2,2-Trifluoroethanol (TFEA);Three fluorine ethanol;2,2,2-Trifluor;Anti-TFE3 (N-terminal) antibody produced in goat;Transcription factor for IgH enhancer;2,2,2-Trifluoroethanol ReagentPlus(R), >=9

2,2,2-Trifluoroethanol 75-89-8

Cas:75-89-8

Min.Order:1 Kilogram

FOB Price: $200.0

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Product Name 2,2,2-Trifluoroethanol Synonyms ,2,2-Trifluoroethyl alcohol;2(3H)-Benzofuranone, 5-hydroxy-;5-Hydroxy-3H-1-benzofuran-2-one;b,b,b-Trifluoroethyl alcohol;2,2,2-TRIFLUOROETHANOL, 99.8%, EXT

2,2,2-Trifluoroethanol CAS: 75-89-8

Cas:75-89-8

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:Colorless transparent liquid Storage:Store in sealed contai

Trifluoroethanol/ TFE(CAS: 75-89-8)

Cas:75-89-8

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen

2,2,2-Trifluoroethanol Fat alcohol

Cas:75-89-8

Min.Order:1 Kilogram

FOB Price: $35.0 / 50.0

Type:Trading Company

inquiry

Wuhan Kemi-Works Chemical Co., Ltd

ProductName:2,2,2-Trifluoroethanol Synonyms:TFE CASNo:75-89-8 EINECS:200-913-6 MolecularFormula:C2H3F3O MolecularWe… Superiority 1.Powerful R & D team 2.The ability of quantized production,from grams to tons;

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:1 Pound

FOB Price: $1.0

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:75-89-8

Cas:75-89-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Trifluoroethanol

Cas:75-89-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

TrifluoroethanolAppearance:Pls see the Details Storage:Keep away of light, hot, water, Store in dry, dark and ventilated place Package:according to customers' requirements Application:Steroids, Cosmetics Ingredients, APIs, Intermediates, OLED&Battery

Trifluoroethanol

Cas:75-89-8

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediat

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: 2,2,2-Trifluoroethanol CAS No.:75-89-8 Molecule Formula:C2H3F3O Molecule Weight:100.04 Purity: 99.0% Package: 250kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard

High Quality 2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity 2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home

2,2,2-Trifluoroethanol china manufacture

Cas:75-89-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:0

Negotiable

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

2,2,2-Trifluroroethanol

Cas:75-89-8

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

manufacture Application:The refence standard products, for lab use, also we could produce bigger quantity on yr requirement.

2,2,2-trifluoroethanol

Cas:75-89-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 75-89-8 with competitive price

Cas:75-89-8

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support

2,2,2-Trifluoroethanol

Cas:75-89-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

n-butyl trifluoroacetate
367-64-6

n-butyl trifluoroacetate

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; potassium tert-butylate; hydrogen In 1,4-dioxane at 40℃; under 7500.75 Torr; for 16h; Time; Concentration; Pressure; Temperature; Glovebox; Inert atmosphere;99%
With lithium aluminium tetrahydride; diethyl ether
trifluoroacetic acid-methyl ester
431-47-0

trifluoroacetic acid-methyl ester

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 60℃; under 22502.3 Torr; for 2h; Pressure; Temperature; Time; Concentration; Reagent/catalyst; Autoclave;99%
With hydrogen; phosphan
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 40℃; under 19001.3 Torr; for 24h; Autoclave; Inert atmosphere;98 %Spectr.
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 40℃; under 18751.9 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Autoclave;92 %Spectr.
With C46H43N7OPRu(1+)*BF4(1-); potassium tert-butylate; hydrogen In 1,4-dioxane at 100℃; under 37503.8 Torr; for 2h; Inert atmosphere; Autoclave;100 %Spectr.
(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-n-decyl)trifluoroacetate
117068-31-2

(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-n-decyl)trifluoroacetate

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol
678-39-7

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere;A 99%
B n/a
benzyl trifluoroacetate
351-70-2

benzyl trifluoroacetate

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

benzyl alcohol
100-51-6

benzyl alcohol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere;A 99%
B n/a
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen In toluene at 90℃; under 52505.3 Torr; for 17h; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere; Glovebox;
With C21H35BrMnN2O2P; hydrogen; potassium hydride; 1,3,5-trimethyl-benzene In toluene at 100℃; under 15001.5 Torr; for 28h; Autoclave; Inert atmosphere;A 78 %Spectr.
B 99 %Spectr.
With C21H35BrMnN2O2P; hydrogen; potassium hydride In toluene at 100℃; under 15001.5 Torr; for 28h;A 78 %Spectr.
B 99 %Spectr.
4-methylbenzyl trifluoroacetate
1524-14-7

4-methylbenzyl trifluoroacetate

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

4-Methylbenzyl alcohol
589-18-4

4-Methylbenzyl alcohol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere;A 99%
B n/a
4-(trifluoromethyl)benzyl trifluoroacetate
681035-98-3

4-(trifluoromethyl)benzyl trifluoroacetate

A

4-(trifluoromethyl)benzylic alcohol
349-95-1

4-(trifluoromethyl)benzylic alcohol

B

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere;A n/a
B 99%
4-fluorobenzyl trifluoroacetate
139058-95-0

4-fluorobenzyl trifluoroacetate

A

4-fluorobenzylic alcohol
459-56-3

4-fluorobenzylic alcohol

B

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere;A n/a
B 97%
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen; triethylamine In toluene at 90℃; under 52505.3 Torr; for 17h; Inert atmosphere; Glovebox;
1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With potassium γ-hydroxybutyrate In 4-butanolide at 200℃; under 11251.1 Torr; for 6h;96%
With 4-butanolide; potassium hydroxide at 200℃; under 11251.1 Torr; for 6h;68%
With potassium acetate; ethylene glycol; acetic acid
cyclohexylmethyl trifluoroacetate
164071-20-9

cyclohexylmethyl trifluoroacetate

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

cyclohexylmethyl alcohol
100-49-2

cyclohexylmethyl alcohol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 48h; Glovebox; Inert atmosphere;A 95%
B n/a
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen In toluene at 110℃; under 52505.3 Torr; for 17h; Catalytic behavior; Solvent; Temperature; Inert atmosphere; Glovebox;
allyl trifluoroacetate
383-67-5

allyl trifluoroacetate

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

allyl alcohol
107-18-6

allyl alcohol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere;A 95%
B n/a
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen; triethylamine In toluene at 90℃; under 52505.3 Torr; for 17h; Inert atmosphere; Glovebox;
With C21H35BrMnN2O2P; hydrogen; potassium hydride; 1,3,5-trimethyl-benzene In toluene at 100℃; under 15001.5 Torr; for 60h; Autoclave; Inert atmosphere;A 97 %Spectr.
B 96 %Spectr.
With C21H35BrMnN2O2P; hydrogen; potassium hydride In toluene at 100℃; under 15001.5 Torr; for 60h;A 97 %Spectr.
B 96 %Spectr.
1,1,1-trifluoroethyl fluorosulfite
75988-14-6

1,1,1-trifluoroethyl fluorosulfite

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With water at 100℃; autoclave;93%
trifluoroacetic acid-methyl ester
431-47-0

trifluoroacetic acid-methyl ester

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

2,2,2-trifluoro-1-methoxy-ethanol
431-46-9

2,2,2-trifluoro-1-methoxy-ethanol

Conditions
ConditionsYield
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 40℃; under 4500.45 Torr; for 19h; Pressure; Temperature; Time; Concentration; Reagent/catalyst; Autoclave;A 7%
B 93%
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 40℃; under 15201 Torr; for 6h; Autoclave; Inert atmosphere;
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); hydrogen; sodium methylate In methanol at 40℃; under 7600.51 Torr; for 6h; Autoclave; Inert atmosphere;
tris(2,2,2-trifluoroethyl)phosphite
370-69-4

tris(2,2,2-trifluoroethyl)phosphite

2,2,3,3,4,4,5,5-octafluorovaleraldehyde
2648-47-7

2,2,3,3,4,4,5,5-octafluorovaleraldehyde

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

bis(2,2,2-trifluoroethyl) (1H,5H-octafluoro-1-hydroxypentyl)phosphonate

bis(2,2,2-trifluoroethyl) (1H,5H-octafluoro-1-hydroxypentyl)phosphonate

Conditions
ConditionsYield
In benzene at 20 - 25℃; for 2h;A n/a
B 89%
trifluoroacetic acid-methyl ester
431-47-0

trifluoroacetic acid-methyl ester

A

methanol
67-56-1

methanol

B

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With hydrogen; <(Ph3P)(Ph2P)RuH2-K+*diglyme>2 In toluene at 90℃; under 4650.4 Torr; for 20h; Title compound not separated from byproducts;A n/a
B 88%
With (K(1+))2<(Ph3P)3(Ph2P)Ru2H4>(2-)*2C6H14O3; hydrogen In toluene at 90℃; under 4650.4 Torr; for 20h;
trifluoroacetic anhydride
407-25-0

trifluoroacetic anhydride

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With [Zn(BH4)2(py)] In tetrahydrofuran for 1h; Heating;85%
With lithium aluminium tetrahydride; diethyl ether
With platinum Hydrogenation.unter Druck und anschliessenden Behandeln mit Eiswasser;
methyl(2,2,2-trifluoro-ethoxo){1,2-bis(diphenylphosphino)ethane}palladium
115981-45-8

methyl(2,2,2-trifluoro-ethoxo){1,2-bis(diphenylphosphino)ethane}palladium

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
In further solvent(s) Thermolysis (120°C) of starting complex (diphenylmethane, vac.).; GLC.;A 11%
B 10%
C 84%
but-2-en-1-yl 2,2,2-trifluoroacetate
6864-58-0

but-2-en-1-yl 2,2,2-trifluoroacetate

A

(E/Z)-2-buten-1-ol
6117-91-5

(E/Z)-2-buten-1-ol

B

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere;A n/a
B 84%
2-methoxyethyl trifluoroacetate
41017-81-6

2-methoxyethyl trifluoroacetate

A

2-methoxy-ethanol
109-86-4

2-methoxy-ethanol

B

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere;A n/a
B 80%
trifluoroacetic acid 2-phenylethyl ester
55419-66-4

trifluoroacetic acid 2-phenylethyl ester

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

2-phenylethanol
60-12-8

2-phenylethanol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Glovebox; Inert atmosphere;A 78%
B n/a
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen In toluene at 90℃; under 52505.3 Torr; for 17h; Inert atmosphere; Glovebox;
isopropyl Trifluoroacetate
400-38-4

isopropyl Trifluoroacetate

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

isopropyl alcohol
67-63-0

isopropyl alcohol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 60h; Glovebox; Inert atmosphere;A 77%
B n/a
With trimethylamine-N-oxide; tricarbonyl(η4-1,3-bis(trimethylsilyl)-4,5,6,7-tetrahydro-2H-inden-2-one)iron; hydrogen; triethylamine In toluene at 90℃; under 52505.3 Torr; for 17h; Inert atmosphere; Glovebox;
n-butyl trifluoroacetate
367-64-6

n-butyl trifluoroacetate

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

butan-1-ol
71-36-3

butan-1-ol

Conditions
ConditionsYield
With trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate In 1,4-dioxane at 40℃; under 18751.9 Torr; for 16h; Reagent/catalyst; Solvent; Time; Temperature; Glovebox; Inert atmosphere;A 77%
B n/a
2,2,2-Trifluoroethyl cyanate
1118-45-2

2,2,2-Trifluoroethyl cyanate

N-benzoyl-N'-benzylhydrazine
1215-52-7

N-benzoyl-N'-benzylhydrazine

A

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

B

3-Benzyl-5-phenyl-Δ4-1,3,4-oxadiazolin-2-imin
27643-04-5

3-Benzyl-5-phenyl-Δ4-1,3,4-oxadiazolin-2-imin

Conditions
ConditionsYield
In diethyl ether; ethanol for 1h; Ambient temperature;A n/a
B 75%
1-[tris(trimethylsilyl)silyl]-2,2,2-trifluoroethanol
182255-86-3

1-[tris(trimethylsilyl)silyl]-2,2,2-trifluoroethanol

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With methanol In dichloromethane at 10℃; for 0.5h; Product distribution; Irradiation;62%
In methanol; dichloromethane desilylation; Photolysis;62%
glycolic Acid
79-14-1

glycolic Acid

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With sulfur tetrafluoride at 160℃; for 8h; autoclave;A 30%
B 48%
glycolic Acid
79-14-1

glycolic Acid

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

C

1,1,1-trifluoroethyl fluorosulfite
75988-14-6

1,1,1-trifluoroethyl fluorosulfite

Conditions
ConditionsYield
With sulfur tetrafluoride at 60℃; for 15h; autoclave;A 26%
B 5%
C 42%
trifluoracetyl chloride
354-32-5

trifluoracetyl chloride

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; diethyl ether
2-(2,2-difluoroethoxy)-1,1,1-trifluoroethane

2-(2,2-difluoroethoxy)-1,1,1-trifluoroethane

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
beim Aufbewahren;
2,2,2-trifluoroacetamide
354-38-1

2,2,2-trifluoroacetamide

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With platinum(IV) oxide; diethyl ether at 90℃; Hydrogenation.unter Druck;
benzyl trifluoroacetate
351-70-2

benzyl trifluoroacetate

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; diethyl ether
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

2,2,2-Trifluoroethyl p-toluenesulfonate
433-06-7

2,2,2-Trifluoroethyl p-toluenesulfonate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 18h; Inert atmosphere;100%
With triethylamine In dichloromethane at 20℃; for 18h;100%
With triethylamine In chloroform for 6h; Ambient temperature;98%
3-benzyl-1-methyl-2-oxo-2-phenyl-2λ5-[1,3,2]diazaphospholidin-4-one
64642-21-3

3-benzyl-1-methyl-2-oxo-2-phenyl-2λ5-[1,3,2]diazaphospholidin-4-one

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

C18H20F3N2O3P

C18H20F3N2O3P

Conditions
ConditionsYield
With triethylamine In chloroform for 72h;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

α-t-Butyldimethylsilylbenzyl p-toluenesulfonate
131123-36-9

α-t-Butyldimethylsilylbenzyl p-toluenesulfonate

tert-Butyl-dimethyl-[phenyl-(2,2,2-trifluoro-ethoxy)-methyl]-silane
134644-20-5

tert-Butyl-dimethyl-[phenyl-(2,2,2-trifluoro-ethoxy)-methyl]-silane

Conditions
ConditionsYield
With 2,6-dimethylpyridine100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

2-(4-methylphenyl)prop-2-en-1-yl 4-toluenesulfonate
89618-93-9

2-(4-methylphenyl)prop-2-en-1-yl 4-toluenesulfonate

2-(4-methylphenyl)-1-(2,2,2-trifluoroethoxy)prop-2-ene
89619-18-1

2-(4-methylphenyl)-1-(2,2,2-trifluoroethoxy)prop-2-ene

Conditions
ConditionsYield
With 2,6-dimethylpyridine at 80℃; for 24h;100%
at 65℃; Kinetics; Thermodynamic data; ΔH(excit.), ΔS(excit.), other temp.;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

1-chlorocyclopropyl methyl sulfide
78708-99-3

1-chlorocyclopropyl methyl sulfide

1-Methylsulfanyl-1-(2,2,2-trifluoro-ethoxy)-cyclopropane

1-Methylsulfanyl-1-(2,2,2-trifluoro-ethoxy)-cyclopropane

Conditions
ConditionsYield
at 0℃;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

1-bromocyclopropyl benzyl sulfide
78709-02-1

1-bromocyclopropyl benzyl sulfide

[1-(2,2,2-Trifluoro-ethoxy)-cyclopropylsulfanylmethyl]-benzene

[1-(2,2,2-Trifluoro-ethoxy)-cyclopropylsulfanylmethyl]-benzene

Conditions
ConditionsYield
at 0℃;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

1-bromocyclopropyl phenetyl sulfide
78709-15-6

1-bromocyclopropyl phenetyl sulfide

{2-[1-(2,2,2-Trifluoro-ethoxy)-cyclopropylsulfanyl]-ethyl}-benzene

{2-[1-(2,2,2-Trifluoro-ethoxy)-cyclopropylsulfanyl]-ethyl}-benzene

Conditions
ConditionsYield
at 0℃;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

4-chlorobenzonitrile
100-00-5

4-chlorobenzonitrile

1-(2,2,2-trifluoroethoxy)-4-nitrobenzene
62149-35-3

1-(2,2,2-trifluoroethoxy)-4-nitrobenzene

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran; N,N-dimethyl-formamide at 25℃; for 1h; Inert atmosphere;100%
Stage #1: 2,2,2-trifluoroethanol With sodium hydride In N,N-dimethyl-formamide Cooling with liquid nitrogen;
Stage #2: 4-chlorobenzonitrile In N,N-dimethyl-formamide at 100℃; for 3h; Cooling with liquid nitrogen;
98%
With sodium hydride In N,N-dimethyl-formamide 1.) r.t., 2.) 130 deg C, 10 h;92%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

phenyl chloroformate
1885-14-9

phenyl chloroformate

2,2,2-trifluoroethyl phenyl carbonate
152899-11-1

2,2,2-trifluoroethyl phenyl carbonate

Conditions
ConditionsYield
With pyridine100%
With pyridine In dichloromethane at 20℃; for 1h;
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

N-Cbz-Ala
1142-20-7

N-Cbz-Ala

Z-L-Ala 2,2,2-trifluoroethyl ester
203640-41-9

Z-L-Ala 2,2,2-trifluoroethyl ester

Conditions
ConditionsYield
With pyridine; di-tert-butyl dicarbonate In tetrahydrofuran at 20℃; for 22h;100%
With Candida antartica lipase B at 50℃; for 16h; Molecular sieve; Enzymatic reaction;96%
With dmap; triethylamine; dicyclohexyl-carbodiimide In butan-1-ol at 20℃; pH=8 - 9;63.9%
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

(Z)-4-benzyloxy-but-2-en-1-ol
81028-03-7

(Z)-4-benzyloxy-but-2-en-1-ol

[2-(2,2,2-trifluoro-ethoxy)-but-3-enyloxymethyl]-benzene
373393-05-6

[2-(2,2,2-trifluoro-ethoxy)-but-3-enyloxymethyl]-benzene

Conditions
ConditionsYield
With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine In benzene at 20℃; for 6h; Mitsunobu reaction;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

rac-3-bromocyclohexene
1521-51-3

rac-3-bromocyclohexene

3-(2',2',2'-trifluoroethoxy)-cyclohex-1-ene
373393-06-7

3-(2',2',2'-trifluoroethoxy)-cyclohex-1-ene

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; tetra-(n-butyl)ammonium iodide100%
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; tetra-(n-butyl)ammonium iodide at 20℃; for 12h;71%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

3-Chloro-2-methylpropene
563-47-3

3-Chloro-2-methylpropene

2-methyl-3-(2',2',2'-trifluoroethoxy)-prop-1-ene
74407-77-5

2-methyl-3-(2',2',2'-trifluoroethoxy)-prop-1-ene

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; tetra-(n-butyl)ammonium iodide100%
Stage #1: 2,2,2-trifluoroethanol With potassium hydroxide at 40℃;
Stage #2: 3-Chloro-2-methylpropene In water at 40℃;
78%
With potassium carbonate In N,N-dimethyl-formamide
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

1-adamantylmethanol

1-adamantylmethanol

octahydro-2,5-methano-indene-5-carboxylic acid 2,2,2-trifluoro-ethyl ester

octahydro-2,5-methano-indene-5-carboxylic acid 2,2,2-trifluoro-ethyl ester

Conditions
ConditionsYield
With iodine; potassium carbonate at 50℃; for 5h;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

1-adamantanemethanol
770-71-8

1-adamantanemethanol

2,2,2-trifluoroethyl adamantanecarboxylate

2,2,2-trifluoroethyl adamantanecarboxylate

Conditions
ConditionsYield
With iodine; potassium carbonate at 50℃; for 5h;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

(E)-4-(benzyloxy)-2-buten-1-ol
80885-30-9, 81028-03-7, 69152-88-1

(E)-4-(benzyloxy)-2-buten-1-ol

4-(2',2',2'-trifluoroethoxy)-1-benzyloxy-but-2Z-ene
803730-98-5

4-(2',2',2'-trifluoroethoxy)-1-benzyloxy-but-2Z-ene

Conditions
ConditionsYield
Stage #1: (E)-4-(benzyloxy)-2-buten-1-ol With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine In benzene at 20℃; for 0.166667h;
Stage #2: 2,2,2-trifluoroethanol In benzene at 20℃; for 6h;
100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

PhCO-X

PhCO-X

2,2,2-trifluoroethyl benzoate
1579-72-2

2,2,2-trifluoroethyl benzoate

Conditions
ConditionsYield
With boron trifluoride; toluene at 0℃;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

5-chloro-4-formyl-1,3-dimethylpyrazole
27006-76-4

5-chloro-4-formyl-1,3-dimethylpyrazole

1,3-dimethyl-5-(2,2,2-trifluoroethoxy)-1H-pyrazole-4-carbaldehyde
126764-32-7

1,3-dimethyl-5-(2,2,2-trifluoroethoxy)-1H-pyrazole-4-carbaldehyde

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran at 0 - 20℃; for 3h;100%
C14H11NO2
947697-83-8

C14H11NO2

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

C16H14F3NO3

C16H14F3NO3

Conditions
ConditionsYield
silver trifluoromethanesulfonate at 25℃;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

bis(2-fluoro-2,2-dinitroethyl)dichloroformal
113689-58-0

bis(2-fluoro-2,2-dinitroethyl)dichloroformal

bis(2-fluoro-2,2-dinitroethyl)bis(2,2,2-trifluoroethyl)orthocarbonate
210754-61-3

bis(2-fluoro-2,2-dinitroethyl)bis(2,2,2-trifluoroethyl)orthocarbonate

Conditions
ConditionsYield
In 1,2-dichloro-ethane100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

bromoacetic acid tert-butyl ester
5292-43-3

bromoacetic acid tert-butyl ester

tert-butyl 2-(2,2,2-trifluoroethoxy)acetate
252947-89-0

tert-butyl 2-(2,2,2-trifluoroethoxy)acetate

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluoroethanol With sodium hydride In tetrahydrofuran at 0 - 20℃; for 0.75h;
Stage #2: bromoacetic acid tert-butyl ester In tetrahydrofuran at 20℃; for 15h;
100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

1,4-bis<(1-imidazolyl)carbonyloxy>-cis-2-butene
1026530-53-9

1,4-bis<(1-imidazolyl)carbonyloxy>-cis-2-butene

(Z)-but-2-ene-1,4-bis(2',2',2'-trifluoroethylcarbonate)
1155875-17-4

(Z)-but-2-ene-1,4-bis(2',2',2'-trifluoroethylcarbonate)

Conditions
ConditionsYield
With dmap In dichloromethane at 20℃; Inert atmosphere;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

2,4-Difluoronitrobenzene
446-35-5

2,4-Difluoronitrobenzene

4-fluoro-1-nitro-2-(2,2,2-trifluoroethoxy)benzene
186386-91-4

4-fluoro-1-nitro-2-(2,2,2-trifluoroethoxy)benzene

Conditions
ConditionsYield
With sodium hydroxide In toluene at 30 - 50℃; for 16.5h;100%
With caesium carbonate In tetrahydrofuran at 20℃;99.8%
With caesium carbonate In tetrahydrofuran at 25℃; for 8h;67%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

5,11,17,23,29,35-hexa-tert-butyl-2-chloro-37,38,39,40,41,42-hexamethoxycalix[6]arene
1227410-41-4

5,11,17,23,29,35-hexa-tert-butyl-2-chloro-37,38,39,40,41,42-hexamethoxycalix[6]arene

5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41,42-hexamethoxy-2-(2,2,2-trifluoroethoxy)calix[6]arene

5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41,42-hexamethoxy-2-(2,2,2-trifluoroethoxy)calix[6]arene

Conditions
ConditionsYield
In chloroform Reflux;100%
4-butoxy-2,2-bis-trifluoromethyl-oxetane
17129-00-9

4-butoxy-2,2-bis-trifluoromethyl-oxetane

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

C11H15F9O3
1226778-13-7

C11H15F9O3

Conditions
ConditionsYield
at 25 - 35℃;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

acrylonitrile
107-13-1

acrylonitrile

3-(2,2,2-trifluoroethoxy)propionitrile
272128-06-0

3-(2,2,2-trifluoroethoxy)propionitrile

Conditions
ConditionsYield
With [μN,κP,κC,κN-{2-(i-Pr2PO),6-(CH2NBn)-(C6H3)}Ni]2 In benzene at 20℃; for 5.5h;100%
With C31H23F3NiO5P2S; triethylamine In toluene at 60℃; for 3h; Inert atmosphere;
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

diethyl chlorophosphate
814-49-3

diethyl chlorophosphate

Diethyl (2,2,2-trifluoroethyl) phosphate

Diethyl (2,2,2-trifluoroethyl) phosphate

Conditions
ConditionsYield
With triethylamine at 20℃; for 5h;100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

2-chloro-4-amino-5-methylpyrimidine
14394-70-8

2-chloro-4-amino-5-methylpyrimidine

5-methyl-2-(2,2,2-trifluoro-ethoxy)-pyrimidin-4-ylamine
1319068-21-7

5-methyl-2-(2,2,2-trifluoro-ethoxy)-pyrimidin-4-ylamine

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluoroethanol With sodium for 1h; Inert atmosphere;
Stage #2: 2-chloro-4-amino-5-methylpyrimidine at 90℃;
100%
Stage #1: 2,2,2-trifluoroethanol With sodium at 20℃; for 1h; Inert atmosphere;
Stage #2: 2-chloro-4-amino-5-methylpyrimidine at 90℃;
100%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

2-Fluoro-5-nitrobenzotrifluoride
400-74-8

2-Fluoro-5-nitrobenzotrifluoride

4-nitro-1-(2,2,2-trifluoroethoxy)-2-(trifluoromethyl)benzene
1324003-80-6

4-nitro-1-(2,2,2-trifluoroethoxy)-2-(trifluoromethyl)benzene

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluoroethanol With sodium hydride In acetonitrile; mineral oil at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: 2-Fluoro-5-nitrobenzotrifluoride In acetonitrile; mineral oil for 1h;
100%
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 24h; Sealed tube;87%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

5,6-dichloronicotinic acid
41667-95-2

5,6-dichloronicotinic acid

5-chloro-6-(2,2,2-trifluoroethoxy)nicotinic acid
953729-63-0

5-chloro-6-(2,2,2-trifluoroethoxy)nicotinic acid

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluoroethanol With sodium hydride In N,N-dimethyl acetamide; mineral oil at 0℃; for 0.333333h;
Stage #2: 5,6-dichloronicotinic acid In N,N-dimethyl acetamide; mineral oil at 90℃; for 2h;
100%
With potassium hydroxide In dimethyl sulfoxide at 120℃; for 24h;
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