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Changchun Artel lmport and Export trade company

minimum order qty. 10 gram

High quality 1,1,1,2-Tetrafluoroethane supplier in China CAS NO.811-97-2

Cas:811-97-2

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1,1,1,2-Tetrafluoroethane supplier in China

Cas:811-97-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production Cyromazine、lead diacetate trihydrate /Lead acetate trihydrateC、 2-phenylacetamide 、 4-Aminophenyl-1-phenethylpiperidine 、Citric acid monohydrate 、 Citric acid/c

811-97-2 1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Norflurane

Cas:811-97-2

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 1,1,1,2-Tetrafluoroethane 811-97-2 ISO Manufacturer

Cas:811-97-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Disposable Cylinder Refrigerant Gas R134A 811-97-2

Cas:811-97-2

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 811-97-2 with best quality

Cas:811-97-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,1,1,2-Tetrafluoroethane 811-97-2

Cas:811-97-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:811-97-2

Cas:811-97-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

811-97-2 1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

1,1,1,2-TETRAFLUOROETHANE

Cas:811-97-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Yui Sifluo Co.. Ltd.

In fluorine chemical, Yuji Tech has been dedicated to R&D of production of ODS alternatives, fluoropolymers and fluorinated fine chemicals for years, and has become an international leading innovation enterprise in fluorine chemical research an

1,1,1,2-Tetrafluoroethane; R134a

Cas:811-97-2

Min.Order:5 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

811-97-2 1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1,1,1,2-tetrafluoroethane Properties Melting point -101°C Boiling point −26.5 °C (lit.) Density 1.21 Merck 13,4734 Stability Stable. May cause damage to the atmosphere. Incompatible with active metals, strong oxidizing agent

TIANFU-CHEM CAS:811-97-2 1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Top Purity 1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:0

Negotiable

Type:Trading Company

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

811-97-2 1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

811-97-2 1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

High quality 1,1,1,2-Tetrafluoroethane supplier in China CAS NO.811-97-2 CAS NO.811-97-2

Cas:811-97-2

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediat

1,1,1,2-Tetrafluoroethane

Cas:811-97-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

1,1,1,2-Tetrafluoroethane Cas no.811-97-2 98%

Cas:811-97-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With hydrogen
With lithium aluminium tetrahydride In tetrahydrofuran Ambient temperature;
Irradiation; electroreduction, solid polymer electrolyte, Ag/AgCl reference electrode;
With hydrogen at 350 - 750℃; under 300.03 Torr; for 0.000277778h; Autoclave;
1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With hydrogen fluoride; chromium; magnesium
With hydrogen fluoride Heating;
With hydrogen fluoride; aluminum oxide; chromium(III) oxide; magnesium oxide; zinc(II) oxide at 350℃; Fluorination;
1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1,1,2-trifluoroethylene
359-11-5

1,1,2-trifluoroethylene

Conditions
ConditionsYield
With methylene chloride; oxygen; nickel at 650 - 725℃; under 1277.21 Torr; Product distribution / selectivity;A 28%
B n/a
With methane; oxygen; nickel at 675℃; under 1277.21 Torr; Product distribution / selectivity;
With methane; oxygen; palladium on activated charcoal at 675℃; under 1277.21 Torr; Product distribution / selectivity;
(aqua)(perfluoroethane)iridium complex

(aqua)(perfluoroethane)iridium complex

A

2,2,2-trifluoroethanol
420-46-2

2,2,2-trifluoroethanol

B

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With hydrogen In dichloromethane at 20℃; under 760 Torr;
1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

A

methane
34557-54-5

methane

B

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With hydrogen at 350 - 750℃; under 300.03 Torr; for 0.000277778h; Autoclave;
acetylene
74-86-2

acetylene

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With cobalt (III) fluoride at 10℃; for 0.166667h; Inert atmosphere;34%
1,1-dichlorotetrafluoroethane
374-07-2

1,1-dichlorotetrafluoroethane

A

chlorotrifluoromethane
75-72-9

chlorotrifluoromethane

B

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With methane; oxygen; Ba(NO3)2, γ-alumina, dried at 180-450C, heated to 550C, calcined at 600C, oxidized at 450C at 600℃; under 873.827 - 904.856 Torr; Product distribution / selectivity;
With methane; oxygen; Ba(NO3)2, CsNO3, γ-alumina, dried at 180-450C, heated to 550C, calcined at 600C, oxidized at 450C at 550 - 678℃; under 873.827 - 904.856 Torr; Product distribution / selectivity;
With methane; oxygen; Ba(NO3)2, CsNO3, Co(NO3)2, γ-alumina, dried at 180-400C, heated to 550C, calcined at 575C, oxidized at 400-475C at 600℃; under 873.827 - 904.856 Torr; Product distribution / selectivity;
1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

Vinylidene fluoride
75-38-7

Vinylidene fluoride

C

1,1,2-trifluoroethylene
359-11-5

1,1,2-trifluoroethylene

Conditions
ConditionsYield
In water at 350 - 820℃; under 300.03 Torr; for 8.33333E-05h; Autoclave;
2,2,2-Trifluoroethyl p-toluenesulfonate
433-06-7

2,2,2-Trifluoroethyl p-toluenesulfonate

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With potassium fluoride; diethylene glycol at 210 - 240℃; under 500 Torr;
With potassium fluoride; potassium carbonate; [2.2.2]cryptande In acetonitrile at 115℃; under 1050.08 Torr; for 0.416667h; Yield given;
1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

Vinylidene fluoride
75-38-7

Vinylidene fluoride

C

1-Chloro-2,2-difluoroethene
359-10-4

1-Chloro-2,2-difluoroethene

D

1,1,2-trifluoroethylene
359-11-5

1,1,2-trifluoroethylene

Conditions
ConditionsYield
In water at 350 - 950℃; under 300.03 Torr; for 8.33333E-05h; Autoclave;
Vinylidene fluoride
75-38-7

Vinylidene fluoride

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With xenon difluoride; silicon tetrafluoride at 20℃; for 6h; Fluorination;94%
With sulfur tetrafluoride; lead dioxide at 100℃; for 2h;
With cobalt (III) fluoride at 125℃;
1,1-dibromo-1,2,2,2-tetrafluoroethane
27336-23-8

1,1-dibromo-1,2,2,2-tetrafluoroethane

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With ammonium persulfate; ammonium formate In N,N-dimethyl-formamide at 30 - 40℃;87%
1,1-dichlorotetrafluoroethane
374-07-2

1,1-dichlorotetrafluoroethane

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

Conditions
ConditionsYield
With triethylsilane; Perbenzoic acid 1) 25 deg C, 1 h, 2) 80 deg C, 10 h; Yield given; Yields of byproduct given;
With methylene chloride; oxygen; Ba(NO3)2, CsNO3, γ-alumina, dried at 180-450C, heated to 550C, calcined at 600C, oxidized at 450C at 600℃; under 873.827 - 904.856 Torr; Product distribution / selectivity;
1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1,2-dichloro-1,1-difluoroethane
1649-08-7

1,2-dichloro-1,1-difluoroethane

C

1,1,1-trifluoro-2,2-dichloroethane
306-83-2

1,1,1-trifluoro-2,2-dichloroethane

D

1,2-dichloro-2-fluoroethene
430-58-0

1,2-dichloro-2-fluoroethene

E

Trichloroethylene
79-01-6

Trichloroethylene

F

1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

Conditions
ConditionsYield
Stage #1: 1,1,1-trifluoro-2-chloroethane With hydrogen fluoride; oxygen at 380℃; under 760.051 Torr; Inert atmosphere;
Stage #2: With hydrogenchloride at 380℃; under 760.051 Torr;
1,1-dichlorotetrafluoroethane
374-07-2

1,1-dichlorotetrafluoroethane

A

2,2,2-trifluoroethanol
420-46-2

2,2,2-trifluoroethanol

B

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

C

1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

Conditions
ConditionsYield
With hydrogen; palladium/alumina at 140℃; Product distribution; Mechanism; var. temp.; other catalysts;A 5.5%
B 84.3%
C 10.2%
With hydrogen; palladium at 149.85℃; under 770 Torr; Rate constant; Product distribution; Thermodynamic data; E(a); other Pd catalysts; effect of HCl and sulfur;
With hydrogen; palladium/alumina at 199.85℃; for 15h; Product distribution; also fluorinated aluminas catalysts; other substrate;
With hydrogenchloride; hydrogen; 5percent Pd/C-H Kinetics; Activation energy; Further Variations:; Catalysts; Dehydrochlorination;
Difluoromethane
75-10-5

Difluoromethane

A

trifluoromethan
75-46-7

trifluoromethan

B

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With ammonia at 900℃; for 10h;
Difluoromethane
75-10-5

Difluoromethane

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1,1,2-trifluoroethylene
359-11-5

1,1,2-trifluoroethylene

Conditions
ConditionsYield
With ammonia at 1000℃; for 10h;
Trichloroethylene
79-01-6

Trichloroethylene

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With hydrogen fluoride at 300 - 514℃; under 760.051 Torr; Catalytic behavior; Reagent/catalyst; Temperature;10%
With hydrogen fluoride Heating;
Difluoromethane
75-10-5

Difluoromethane

A

trifluoromethan
75-46-7

trifluoromethan

B

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

C

1,1,2-trifluoroethylene
359-11-5

1,1,2-trifluoroethylene

Conditions
ConditionsYield
With ammonia at 950℃; for 10h;
p-cresol
106-44-5

p-cresol

1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1-Chloro-2,2-difluoroethene
359-10-4

1-Chloro-2,2-difluoroethene

C

(2-chloro-1,1-difluoro-ethyl)-p-tolyl ether
369-65-3

(2-chloro-1,1-difluoro-ethyl)-p-tolyl ether

Conditions
ConditionsYield
With potassium hydroxide at 250℃; under 28880 Torr; for 11h;A n/a
B n/a
C 73%
ethanol
64-17-5

ethanol

1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1,1,1-trifluoroethyl ethyl ether
461-24-5

1,1,1-trifluoroethyl ethyl ether

C

1-Chloro-2,2-difluoroethene
359-10-4

1-Chloro-2,2-difluoroethene

Conditions
ConditionsYield
With potassium hydroxide at 280℃; under 45600 Torr; for 11h;A n/a
B 67%
C n/a
1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1-Chloro-2,2-difluoroethene
359-10-4

1-Chloro-2,2-difluoroethene

C

1,1,1-trifluoro-2-(2,2,2-trifluoroethoxy)ethane
333-36-8

1,1,1-trifluoro-2-(2,2,2-trifluoroethoxy)ethane

Conditions
ConditionsYield
With potassium hydroxide at 250℃; under 77520 Torr; for 13h;A n/a
B n/a
C 70%
1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

para-tert-butylphenol
98-54-4

para-tert-butylphenol

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1-Chloro-2,2-difluoroethene
359-10-4

1-Chloro-2,2-difluoroethene

C

1-tert-butyl-4-(2-chloro-1,1-difluoro-ethoxy)-benzene

1-tert-butyl-4-(2-chloro-1,1-difluoro-ethoxy)-benzene

Conditions
ConditionsYield
With potassium hydroxide at 250℃; under 36480 Torr; for 11h;A n/a
B n/a
C 67%
1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

ortho-cresol
95-48-7

ortho-cresol

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1-Chloro-2,2-difluoroethene
359-10-4

1-Chloro-2,2-difluoroethene

C

(2-chloro-1,1-difluoro-ethyl)-o-tolyl ether
366-41-6

(2-chloro-1,1-difluoro-ethyl)-o-tolyl ether

Conditions
ConditionsYield
With potassium hydroxide at 250℃; under 34960 Torr; for 11h;A n/a
B n/a
C 71%
1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

phenol
108-95-2

phenol

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1-Chloro-2,2-difluoroethene
359-10-4

1-Chloro-2,2-difluoroethene

C

1-chloro-2,2-difluoroethyl phenyl ether
500-31-2

1-chloro-2,2-difluoroethyl phenyl ether

D

C14H12F2O2

C14H12F2O2

Conditions
ConditionsYield
With potassium hydroxide at 250℃; under 35720 Torr; for 11h;A n/a
B n/a
C 76%
D n/a
1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

phenol
108-95-2

phenol

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1-Chloro-2,2-difluoroethene
359-10-4

1-Chloro-2,2-difluoroethene

C

C14H12F2O2

C14H12F2O2

Conditions
ConditionsYield
With potassium hydroxide at 250℃; under 34200 Torr; for 11h;A n/a
B n/a
C 72%
glycolic Acid
79-14-1

glycolic Acid

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
With sulfur tetrafluoride at 160℃; for 5h;
methanol
67-56-1

methanol

1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

2,2,2-trifluoroethyl methyl ether
460-43-5

2,2,2-trifluoroethyl methyl ether

C

1-Chloro-2,2-difluoroethene
359-10-4

1-Chloro-2,2-difluoroethene

Conditions
ConditionsYield
With potassium hydroxide at 260℃; under 57760 Torr; for 10h;A n/a
B 55%
C n/a
1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

A

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

B

1-Chloro-2,2-difluoroethene
359-10-4

1-Chloro-2,2-difluoroethene

C

2-(2,2,2-Trifluoro-ethoxy)-butane

2-(2,2,2-Trifluoro-ethoxy)-butane

Conditions
ConditionsYield
With potassium hydroxide at 280℃; under 87400 Torr; for 11h;A n/a
B n/a
C 64%
Difluoromethane
75-10-5

Difluoromethane

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Conditions
ConditionsYield
at 900℃; for 10h; Temperature;
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

A

1,1,1,2,2-pentafluoroethane
354-33-6

1,1,1,2,2-pentafluoroethane

B

Difluoromethane
75-10-5

Difluoromethane

C

trifluoromethan
75-46-7

trifluoromethan

D

Hexafluoroethane
76-16-4

Hexafluoroethane

Conditions
ConditionsYield
With fluorine at 200 - 250℃; Product distribution; Further Variations:; Reagents;A 1.1%
B 0.9%
C 0.4%
D 97.6%
1-(chloromercuri)ferrocene

1-(chloromercuri)ferrocene

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

(C5H5)Fe(C5H4)Hg(CFCF2)

(C5H5)Fe(C5H4)Hg(CFCF2)

Conditions
ConditionsYield
With n-BuLi In diethyl ether; hexane under N2, shielded from light; ethereal soln. of CF3CH2F treated under stirring with n-BuLi in hexane at -78°C for 2 h; Fe-Hg complex in ether added at -78°C; stirred at -60°C overnight; warmed to room temp.; hexane added; filtered through Celite; filtrate concd. in vac.; elem. anal.;93%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

mercury dichloride

mercury dichloride

bis(perfluorovinyl)mercury
687-61-6

bis(perfluorovinyl)mercury

Conditions
ConditionsYield
With n-butyllithium In diethyl ether byproducts: LiCl; generation of Li salt witn BuLi at -78°C, addn. of 0.5 equiv. HgCl2; extn., drying, evapn.;90%
With n-butyllithium In tetrahydrofuran; diethyl ether byproducts: LiCl; generation of Li salt witn BuLi at -78°C in Et2O, addn. of 0.5 equiv. HgCl2 in thf; extn., drying, evapn.;90%
With BuLi In tetrahydrofuran; diethyl ether N2-atmosphere; slow addn. of BuLi to fluorocarbon (in Et2O, -78°C), stirring for 2 h, addn. of 0.5 equiv. HgCl2 (in THF), stirring overnight; warming to room temp., addn. of satd. aq. NH4Cl, drying of org. layer (MgSO4), solvent removal (reduced pressure), distn. (60-61°C/20 Torr); elem. anal.;85%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Tris(trifluorvinyl)arsan
2708-94-3

Tris(trifluorvinyl)arsan

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With n-butyllithium In diethyl ether; hexane at -78 - -70℃; for 6h; Inert atmosphere;
Stage #2: With arsenic trichloride In diethyl ether; hexane at -85 - 20℃; Inert atmosphere;
90%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

dimethylaminobis(trifluoromethyl)borane
105224-90-6

dimethylaminobis(trifluoromethyl)borane

dimethylamine-trifluoroethenylbis(trifluoromethyl)borane

dimethylamine-trifluoroethenylbis(trifluoromethyl)borane

Conditions
ConditionsYield
With tert.-butyl lithium In diethyl ether; pentane at -78℃; for 0.333333h; deprotonation, trifluorovinylation;89%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

dimethylaminobis(trifluoromethyl)borane
105224-90-6

dimethylaminobis(trifluoromethyl)borane

dimethylamine-trifluoroethenylbis(trifluoromethyl)borane
300655-75-8

dimethylamine-trifluoroethenylbis(trifluoromethyl)borane

Conditions
ConditionsYield
With t-butyl lithium In diethyl ether stirred at -78 °C for 20 min; aq. HCl added, pH 4, ther phase dried over Na2SO4, evapn., sublimation in vac., elem. anal.;89%
titanocene difluoride
309-89-7

titanocene difluoride

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

fluoro(perfluorovinyl)(η(5)-cyclopentadienyl)titanium(IV)
235747-18-9

fluoro(perfluorovinyl)(η(5)-cyclopentadienyl)titanium(IV)

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; diethyl ether; hexane N2-atmosphere; slow addn. of 2 equiv. BuLi (in hexane) to CF3CH2F (in Et2O) at -80°C, standing at -80 to -55°C for 2 h, cooling to -110°C, addn. of 1 equiv. Ti-complex (in THF, cooled to -80°C), slow warming to room temp.; vol. reduction (vac.), hexane addn., filtration, evapn. of filtrate (vac.), washing (hexane), drying (vac.); elem. anal.;88%
bis(cyclopentadienyl)titanium dichloride
1271-19-8

bis(cyclopentadienyl)titanium dichloride

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

bis(perfluorovinyl)(η(5)-cyclopentadienyl)titanium(IV)
235747-22-5

bis(perfluorovinyl)(η(5)-cyclopentadienyl)titanium(IV)

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; diethyl ether; hexane N2-atmosphere; slow addn. of 2 equiv. BuLi (in hexane) to CF3CH2F (in Et2O) at -80°C, standing at -80 to -55°C for 2 h, cooling to -110°C, addn. of 0.5 equiv. Ti-complex (in THF, cooled to -80°C), slow warming to room temp.; vol. reduction (vac.), hexane addn., filtration, evapn. of filtrate (vac.), washing (hexane), drying (vac., 30 min); elem. anal.;88%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

Chlorodiisopropylphosphane
40244-90-4

Chlorodiisopropylphosphane

i-Pr2P(CF=CF2)
750648-23-8

i-Pr2P(CF=CF2)

Conditions
ConditionsYield
With n-butyllithium In diethyl ether at -80 - 20℃;87%
bis(cyclopentadienyl)titanium dichloride
1271-19-8

bis(cyclopentadienyl)titanium dichloride

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

chloro(perfluorovinyl)(η(5)-cyclopentadienyl)titanium(IV)
235747-20-3

chloro(perfluorovinyl)(η(5)-cyclopentadienyl)titanium(IV)

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; diethyl ether; hexane N2-atmosphere; slow addn. of 2 equiv. BuLi (in hexane) to CF3CH2F (in Et2O) at -80°C, standing at -80 to -55°C for 2 h, cooling to -110°C, addn. of 1 equiv. Ti-complex (in THF, cooled to -80°C), slow warming to room temp.; vol. reduction (vac.), hexane addn., filtration, evapn. of filtrate (vac.), washing (hexane), drying (vac.);87%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

2-isopropyliodobenzene
19099-54-8

2-isopropyliodobenzene

1-isopropyl-2-(1,2,2-trifluorovinyl)benzene
105436-18-8

1-isopropyl-2-(1,2,2-trifluorovinyl)benzene

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With zinc(II) chloride; lithium diisopropyl amide In tetrahydrofuran at 15 - 20℃;
Stage #2: 2-isopropyliodobenzene With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 65℃; for 2h;
86%
Stage #1: 1,1,1,2-tetrafluoroethane With zinc(II) chloride; lithium diisopropyl amide In tetrahydrofuran at 15 - 20℃;
Stage #2: 2-isopropyliodobenzene; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 65℃; for 2h;
86%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

2-phenacylisoquinolinium bromide
25131-60-6

2-phenacylisoquinolinium bromide

(2-fluoro-pyrrolo[2,1-a]isoquinolin-3-yl)phenyl-methanone

(2-fluoro-pyrrolo[2,1-a]isoquinolin-3-yl)phenyl-methanone

Conditions
ConditionsYield
With potassium carbonate; triethylamine In N,N-dimethyl-formamide at 80℃; for 24h;85%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

3-methoxy-1-iodobenzene
766-85-8

3-methoxy-1-iodobenzene

1-methoxy-3-(1,2,2-trifluorovinyl)benzene

1-methoxy-3-(1,2,2-trifluorovinyl)benzene

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With zinc(II) chloride; lithium diisopropyl amide In tetrahydrofuran at 15 - 20℃;
Stage #2: 3-methoxy-1-iodobenzene; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 65℃; for 1h;
85%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

4,4'-diformylbiphenyl
66-98-8

4,4'-diformylbiphenyl

4,4'-bis(2-trifluoromethyl-2-fluorovinyl)biphenyl

4,4'-bis(2-trifluoromethyl-2-fluorovinyl)biphenyl

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane; 4,4'-diformylbiphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; Inert atmosphere;
Stage #2: With pyridine hydrofluoride In chloroform at 0 - 20℃; for 3h;
84%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

1-Iodonaphthalene
90-14-2

1-Iodonaphthalene

1-(1,2,2-trifluoroethenyl)naphthalene
33240-13-0

1-(1,2,2-trifluoroethenyl)naphthalene

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With zinc(II) chloride; lithium diisopropyl amide In tetrahydrofuran at 15 - 20℃;
Stage #2: 1-Iodonaphthalene; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 60℃; for 2h;
83%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

para-iodoanisole
696-62-8

para-iodoanisole

para-methoxy phenyl-2 trifluoro-1,1,2 ethylene
82907-00-4

para-methoxy phenyl-2 trifluoro-1,1,2 ethylene

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With zinc(II) chloride; lithium diisopropyl amide In tetrahydrofuran at 15 - 20℃; for 1h;
Stage #2: para-iodoanisole With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 60℃; for 1h;
82%
Stage #1: 1,1,1,2-tetrafluoroethane With zinc(II) chloride; lithium diisopropyl amide In tetrahydrofuran at 15 - 20℃;
Stage #2: para-iodoanisole; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 60℃; for 1h;
82%
1-Chloro-4-iodobenzene
637-87-6

1-Chloro-4-iodobenzene

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

1-chloro-4-(1,2,2-trifluoroethenyl)benzene
82907-01-5

1-chloro-4-(1,2,2-trifluoroethenyl)benzene

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With zinc(II) chloride; lithium diisopropyl amide In tetrahydrofuran at 15 - 20℃;
Stage #2: 1-Chloro-4-iodobenzene; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 60℃; for 2h;
82%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

(Z)-1,2-difluoro-1-(trimethylsilyl)-1-hexene
89263-94-5

(Z)-1,2-difluoro-1-(trimethylsilyl)-1-hexene

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Dehydrofluorination; metallation;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78℃; for 1h; Substitution;
Stage #3: n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Substitution;
81%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

para-thiocresol
106-45-6

para-thiocresol

tris-p-tolylsulfanyl-ethene
5324-62-9

tris-p-tolylsulfanyl-ethene

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 60℃; for 24h;81%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

phenylmercury(II) chloride
100-56-1

phenylmercury(II) chloride

(C6H5)Hg(CFCF2)

(C6H5)Hg(CFCF2)

Conditions
ConditionsYield
With n-BuLi In diethyl ether; hexane under N2, shielded from light; ethereal soln. of CF3CH2F treated under stirring with n-BuLi in hexane at -78°C for 2 h; PhHgCl in ether added at -78°C; stirred at -60°C overnight; warmed to room temp.; hexane added; filtered through Celite; filtrate concd. in vac.; elem. anal.;79%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

3-iodochlorobenzene
625-99-0

3-iodochlorobenzene

3'-chloro-1,2,2-trifluorostyrene
58174-56-4

3'-chloro-1,2,2-trifluorostyrene

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With zinc(II) chloride; lithium diisopropyl amide In tetrahydrofuran at 15 - 20℃;
Stage #2: 3-iodochlorobenzene; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 65℃; for 2h;
78%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

1,4-dibromo-2,5-dimethoxybenzene
2674-34-2

1,4-dibromo-2,5-dimethoxybenzene

1,4-bis(trifluorovinyl)-2,5-dimethoxybenzene

1,4-bis(trifluorovinyl)-2,5-dimethoxybenzene

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With zinc(II) chloride; lithium diisopropyl amide In tetrahydrofuran; hexane at -20 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 1,4-dibromo-2,5-dimethoxybenzene With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; hexane at 50 - 55℃; for 17h; Inert atmosphere;
77%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

cyclohexane-1,2-epoxide
286-20-4

cyclohexane-1,2-epoxide

trans-2-(1',2',2'-trifluoroethenyl)-cyclohexan-1-ol

trans-2-(1',2',2'-trifluoroethenyl)-cyclohexan-1-ol

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.75h;
Stage #2: cyclohexane-1,2-epoxide In tetrahydrofuran; hexane Further stages.;
76%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

1-bromo-4-(1,2,2-trifluorovinyl)benzene
134959-20-9

1-bromo-4-(1,2,2-trifluorovinyl)benzene

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With zinc(II) chloride; lithium diisopropyl amide In tetrahydrofuran at 15 - 20℃;
Stage #2: 1,4-bromoiodobenzene With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 12h;
75%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

4,6-diiodo-1,3-xylene
4102-50-5

4,6-diiodo-1,3-xylene

1,3-bis(trifluorovinyl)-4,6-dimethylbenzene

1,3-bis(trifluorovinyl)-4,6-dimethylbenzene

Conditions
ConditionsYield
Stage #1: 1,1,1,2-tetrafluoroethane With zinc(II) chloride; lithium diisopropyl amide In tetrahydrofuran; hexane at -20 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 4,6-diiodo-1,3-xylene With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; hexane at 50℃; for 16h; Inert atmosphere;
75%
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

benzaldehyde
100-52-7

benzaldehyde

1-phenyl 1-hydroxy 2.3.3-trifluoro propene (2)
2338-85-4

1-phenyl 1-hydroxy 2.3.3-trifluoro propene (2)

Conditions
ConditionsYield
With methanol; n-butyllithium In diethyl ether; hexane 1.) -78 deg C;74%
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