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Cas:106-45-6
Min.Order:1 Kilogram
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inquiryDayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. As a leading manufacturer and supplier of chemicals in China, Day
Cas:106-45-6
Min.Order:1 Kilogram
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Type:Lab/Research institutions
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p-Toluenethiol Basic information Product Name: p-Toluenethiol Synonyms: 1-Mercapto-4-methylbenzene;4-mercapto-toluen;4-methyl-benzenethio;4-Methylphenyl mercaptan;4-methylphenylmercaptan
Cas:106-45-6
Min.Order:1 Kilogram
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inquiry1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:white or off-white powder Storage:Store in sealed containers
Product Detail Minimum Order Qty. 10 Gram
Cas:106-45-6
Min.Order:10 Gram
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:106-45-6
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:106-45-6
Min.Order:10 Gram
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Type:Lab/Research institutions
inquirysuperior quality Appearance:White or colorless solid melt Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates Tra
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Cas:106-45-6
Min.Order:1 Gram
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inquiryAppearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
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high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
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Cas:106-45-6
Min.Order:1 Kilogram
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Type:Trading Company
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high purity P-Toluenethiol /best price 106-45-6 manufacturer Storage:Keep away of light,cool place Package:1kg/package;25kg/drum Application:APIs & Intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By ai
Cas:106-45-6
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inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China
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Cas:106-45-6
Min.Order:10 Milligram
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Type:Lab/Research institutions
inquiryProduct Name: p-Toluenethiol CAS: 106-45-6 MF: C7H8S MW: 124.2 EINECS: 203-399-1 Transportation:any Port:shanghai,ningbo,tianjin,qingdao
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Conditions | Yield |
---|---|
With copper(ll) sulfate pentahydrate; ethane-1,2-dithiol; potassium hydroxide In water; dimethyl sulfoxide at 90℃; for 20h; Temperature; Solvent; Reagent/catalyst; Inert atmosphere; | 99% |
With copper(ll) sulfate pentahydrate; ethane-1,2-dithiol; potassium hydroxide In water; dimethyl sulfoxide at 90℃; for 20h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere; | 97% |
With sodiumsulfide nonahydrate; copper; ethane-1,2-dithiol In dimethyl sulfoxide at 100℃; for 20h; Inert atmosphere; Sealed tube; | 97% |
Conditions | Yield |
---|---|
With potassium sulfide; acetic acid; triphenylphosphine; zinc In chloroform; water at 60℃; for 0.5h; Solvent; Reagent/catalyst; | 97.5% |
With ISOPROPYLAMIDE; dimethylsilicon dichloride; zinc In 1,2-dichloro-ethane at 75℃; for 1.5h; | 96% |
With formic acid; 6% Pd/C; triphenylphosphine at 60℃; for 8h; | 92% |
Conditions | Yield |
---|---|
With indium; ammonium chloride In ethanol for 1h; Reduction; Heating; | 96% |
With sodium tetrahydroborate; zirconium(IV) chloride In tetrahydrofuran at 35℃; for 0.25h; Reduction; | 95% |
With ammonia; aluminium; sodium chloride at 25℃; for 1h; | 94% |
Conditions | Yield |
---|---|
With iodine; triphenylphosphine In benzene for 0.166667h; Heating; | A 90% B 95% |
(4-methylpyridyl)(4-methylphenyl)sulfide
para-thiocresol
Conditions | Yield |
---|---|
With magnesium In methanol at 20℃; for 4h; | 92% |
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride; diethylamine In xylene for 6h; Heating; | 90% |
With sodium methylselenide In N,N-dimethyl-formamide for 8h; Heating; | 55% |
di(p-tolyl) disulfide
toluene-4-sulfonic acid
triphenylphosphine
A
para-thiocresol
B
Triphenylphosphine oxide
Conditions | Yield |
---|---|
In benzene for 23.5h; Product distribution; Mechanism; Heating; further reaction partners - various diaryl disulfides, diphenyl diselenide, tetrabutylammonium iodide, tributylphosphine; | A 90% B 90% |
Conditions | Yield |
---|---|
With iodine; triphenylphosphine In 1,4-dioxane; benzene for 2h; Heating; | 88% |
With hydrogenchloride; tin In water for 24h; Heating; | 81% |
Multi-step reaction with 2 steps 1: iodine; triphenylphosphine / ethanol / 2 h / Reflux; Green chemistry 2: indole; iodine; triphenylphosphine / ethanol / 2 h / Reflux; Green chemistry View Scheme | |
Multi-step reaction with 2 steps 1: sulfur dioxide / water / 9.5 h / 110 °C / Inert atmosphere 2: sodium tetrahydroborate; sodium hydroxide / water; tetrahydrofuran / 3 h / 65 - 67 °C / Inert atmosphere View Scheme |
Conditions | Yield |
---|---|
With 6% Pd/C; iodine; triphenylphosphine; isopropyl alcohol for 6h; Reflux; | 88% |
With triphenylphosphine; iodine In benzene for 2.5h; Heating; | 89 % Chromat. |
With diphosphorus pentasulfide; lithium aluminium tetrahydride 1.) sulfolane, 90 deg C for 24 h 2.) ether, room temperature for 30 min; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With potassium hydroxide In 1,4-dioxane Schlenk technique; Inert atmosphere; | A 83% B 75% |
Conditions | Yield |
---|---|
Stage #1: para-chlorotoluene With water; palladium diacetate; caesium carbonate; sodium thiosulfate; XPhos In toluene; tert-butyl alcohol at 80℃; for 24h; Inert atmosphere; Stage #2: With hydrogenchloride; zinc In water for 1h; Cooling with ice; | 82% |
With sodium hydroxide; 1-thiopropane 1) N-methyl-2-pyrrolidone, removal of water by toluene reflux, 2) reflux (ca. 186 deg C), 20 h; other reagent: n-butyl mercaptan; Yield given. Multistep reaction; | |
With pumice stone; hydrogen sulfide; thorium dioxide at 700℃; | |
With hydrogen sulfide at 700℃; |
Conditions | Yield |
---|---|
Stage #1: para-bromotoluene With water; caesium carbonate; sodium thiosulfate; bis(dibenzylideneacetone)-palladium(0); XPhos In toluene; tert-butyl alcohol at 80℃; for 24h; Inert atmosphere; Stage #2: With hydrogenchloride; zinc In water for 1h; Cooling with ice; | 81% |
With sodium thiomethoxide In N,N-dimethyl acetamide at 150℃; | |
With sodiumsulfide nonahydrate; copper; ethane-1,2-dithiol In dimethyl sulfoxide at 100℃; for 20h; Inert atmosphere; Green chemistry; | 14 %Chromat. |
Conditions | Yield |
---|---|
Stage #1: 4-methylphenylboronic acid With copper (II)-fluoride; sulfur In dimethyl sulfoxide at 100℃; for 12h; Chan-Lam Coupling; Inert atmosphere; Stage #2: With sodium tetrahydroborate In dimethyl sulfoxide at 40℃; for 5h; Inert atmosphere; | 79% |
p-toluenesulfonic acid monohydrate
trifluoroacetic anhydride
A
S-(trifluoroacetyl)-p-methylthiophenol
B
para-thiocresol
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide In dichloromethane for 20h; Product distribution; Ambient temperature; | A 78% B 11% |
With sodium hydroxide; tetra-(n-butyl)ammonium iodide 1.) CH2Cl2, 20h, room temp.; 2.) MeOH, 30 min, room temp.; Yield given. Multistep reaction. Further byproducts given; | |
With sodium hydroxide; (2S)-N-methyl-1-phenylpropan-2-amine hydrate; tetra-(n-butyl)ammonium iodide 1.) CH2Cl2, 20h, room temp.; 2.) 0 deg C; Yield given. Multistep reaction. Further byproducts given; |
1-<α-(p-tolylsulfonyl)ethyl>-4-methoxybenzene
methylmagnesium bromide
A
(4,4'-dimethyl-1,1'-biphenyl)
B
4-Methylbiphenyl
C
4-methylphenyl methylsulfide
D
1-isopropenyl-4-methoxybenzene
E
1-methoxy-4-(1-methylethyl)benzene
F
para-thiocresol
Conditions | Yield |
---|---|
With bis(triphenylphosphine)nickel(II) diiodide; tricyclohexylphosphine; phenylboronic acid In tetrahydrofuran at 70℃; Kumada Cross-Coupling; Inert atmosphere; | A 11% B 31% C 12% D 78% E 10% F 7% |
Conditions | Yield |
---|---|
With ammonium formate at 100 - 200℃; for 7h; neat (no solvent); | 77% |
With phosphorus; phosphoric acid; potassium iodide | |
With phosphonium iodide; hydrogen iodide at 75 - 100℃; | |
With diphosphorus pentasulfide; lithium aluminium tetrahydride 1.) sulfolane, 90 deg C for 60 h 2.) ether, room temperature for 30 min; Yield given. Multistep reaction; |
1-phenyl-2-(p-tolylthio)ethanone
A
di(p-tolyl) disulfide
B
para-thiocresol
C
acetophenone
Conditions | Yield |
---|---|
With electrolysis on Pt electrode In acetonitrile Product distribution; other electrode (Hg), other solvent (aq. ethanol), influence of phenol; | A n/a B n/a C 72% |
3-[(4-methylphenyl)sulfanyl]-1-propanol
A
di(p-tolyl) disulfide
B
4-methylphenyl propyl sulfide
C
para-thiocresol
Conditions | Yield |
---|---|
PPA In carbon disulfide for 40h; Ambient temperature; | A 72% B 21% C 4% |
Conditions | Yield |
---|---|
With sulfuric acid; triphenylphosphine In water at 20℃; for 10h; | A 30% B 68% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate In tetrahydrofuran for 4h; Heating; | A 60.2% B 27% |
With sodium tetrahydroborate In tetrahydrofuran for 2h; Heating; | A 30.9% B 27% |
With sodium tetrahydroborate In tetrahydrofuran Product distribution; Heating; effect of reaction time; | |
With water; triphenylphosphine In tetrahydrofuran at 20℃; |
γ-chloropropyl 4-methylphenyl sulphide
A
6-Methyl-3,4-dihydro-2H-1-benzothiopyran
B
4-methylphenyl propyl sulfide
C
para-thiocresol
Conditions | Yield |
---|---|
aluminium trichloride In carbon disulfide for 3h; Heating; | A 60% B 15% C 9% |
p-Tolyl-thionitrit
methyllithium
A
4-methylphenyl methylsulfide
B
di(p-tolyl) disulfide
C
para-thiocresol
Conditions | Yield |
---|---|
In diethyl ether at -70℃; for 0.05h; | A 57% B n/a C n/a |
p-Tolyl-thionitrit
A
di(p-tolyl) disulfide
B
4-tolyl phenyl sulfide
C
para-thiocresol
Conditions | Yield |
---|---|
In diethyl ether at -70℃; for 0.05h; | A n/a B 57% C n/a |
2-(p-tolylthio)-ethanol
A
di(p-tolyl) disulfide
B
p-methyl-2-phenylethyl chloride
C
1,2-bis(p-tolylthio)ethane
D
para-thiocresol
Conditions | Yield |
---|---|
aluminium trichloride; nitromethane In carbon disulfide for 40h; Ambient temperature; | A 2.1% B 54% C 43% D 0.3% |
Conditions | Yield |
---|---|
With triphenylphosphine In 1,4-dioxane; water | 53% |
Conditions | Yield |
---|---|
With 18-crown-6 ether; iodine; triphenylphosphine In benzene for 5h; Heating; | 50% |
With triphenylphosphine; 18-crown-6 ether; iodine In benzene for 30.5h; Heating; | 85 % Chromat. |
With diphosphorus pentasulfide; lithium aluminium tetrahydride 1.) sulfolane, 90 deg C for 24 h 2.) ether, room temperature for 30 min; Yield given. Multistep reaction; |
N-(4-methylphenylthiomethyl)benzamide
A
benzonitrile
B
2-phenyl-6-methyl-4H-1,3-benzothiazine
C
para-thiocresol
Conditions | Yield |
---|---|
With trichlorophosphate for 1h; Heating; | A 49% B 9.8% C 16% D 11% |
4-(phenyldisulfanyl)toluene
diphenyldisulfane
A
phenyl toluene-4-thiosulfonate
B
para-thiocresol
Conditions | Yield |
---|---|
With PPE | A 4% B 46% |
3-[(4-methylphenyl)sulfanyl]-1-propanol
A
ethyl p-tolyl sulfide
B
di(p-tolyl) disulfide
C
para-thiocresol
Conditions | Yield |
---|---|
sulfuric acid In carbon disulfide for 40h; Ambient temperature; | A 4% B 45% C 3% D 42% |
sulfuric acid In carbon disulfide for 40h; Product distribution; Ambient temperature; further catalysts; | A 4% B 45% C 3% D 42% |
sulfuric acid In carbon disulfide for 40h; Ambient temperature; | A 4% B 45% C 3% D 42% |
sodium tosylate
trifluoroacetic anhydride
A
S-(trifluoroacetyl)-p-methylthiophenol
B
para-thiocresol
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide In dichloromethane for 19h; Product distribution; Ambient temperature; | A 44% B 26% |
With sodium hydroxide; (2S)-N-methyl-1-phenylpropan-2-amine hydrate; tetra-(n-butyl)ammonium iodide 1.) CH2Cl2, 22h, room temp.; 2.) 0 deg C; Yield given. Multistep reaction. Further byproducts given; |
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 20℃; | 100% |
Stage #1: para-thiocresol With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.333333h; Stage #2: allyl bromide In tetrahydrofuran; mineral oil for 0.4h; | 95% |
With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 4.33333h; | 95% |
Conditions | Yield |
---|---|
With bis dichromate In dichloromethane at 0 - 5℃; for 1h; | 100% |
With bromine; potassium hydrogencarbonate In dichloromethane | 100% |
With N-phenyltriazolinedione In toluene at 20℃; for 0.166667h; | 100% |
1,3-chlorobromopropane
para-thiocresol
γ-chloropropyl 4-methylphenyl sulphide
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran at 20℃; | 100% |
With sodium hydroxide In ethanol at 100℃; | 65% |
With potassium hydroxide |
Conditions | Yield |
---|---|
With zirconium In acetonitrile Michael Addition; Electrolysis; diastereoselective reaction; | 100% |
With triethylammonium acetate at 25℃; for 0.0166667h; Thia-Michael reaction; chemoselective reaction; | 99% |
Mg-La mixed oxides In N,N-dimethyl-formamide at 24.85℃; for 0.45h; Michael addition; | 97% |
(methoxycarbonyl)disulfanyl chloride
para-thiocresol
Methoxycarbonyl 4-methylphenyl trisulfane
Conditions | Yield |
---|---|
In dichloromethane at -78℃; for 1h; | 100% |
4-tosylacetonitrile
para-thiocresol
3-p-tolylsulphonyl-2-p-tolylthiopropene
Conditions | Yield |
---|---|
With triethylamine In methanol for 1.75h; Ambient temperature; | 100% |
With triethylamine In benzene for 2h; Ambient temperature; | 65% |
With triethylamine In benzene for 18h; Ambient temperature; | 55% |
With triethylamine In benzene |
p-toluene(N-phenylsulfonyl)iminosulfinyl chloride
para-thiocresol
A
benzenesulfonamide
B
di(p-tolyl) disulfide
Conditions | Yield |
---|---|
In benzene at 20℃; for 2.5h; Mechanism; | A 100% B 95% |
2,3-dicyanobenzaldehyde
para-thiocresol
3-Oxo-1-p-tolylsulfanyl-2,3-dihydro-1H-isoindole-4-carbonitrile
Conditions | Yield |
---|---|
With triethylamine In chloroform at 20℃; for 4h; | 100% |
(methoxy)diphenyl-λ6-sulfanenitrile
para-thiocresol
A
4-methylphenyl methylsulfide
B
S,S-diphenylsulphoximine
Conditions | Yield |
---|---|
In benzene at 30℃; for 6h; Rate constant; Product distribution; | A 77% B 100% |
In benzene at 30℃; for 6h; Yields of byproduct given; | A 77% B n/a |
vinylidene-1,1-diphosphonic acid
para-thiocresol
(1-Phosphono-2-p-tolylsulfanyl-ethyl)-phosphonic acid
Conditions | Yield |
---|---|
With acetic acid; triethylamine at 110℃; for 15h; | 100% |
p-toluene(N-benzoyl)iminosulfinyl chloride
para-thiocresol
A
di(p-tolyl) disulfide
B
benzamidene hydrochloride
Conditions | Yield |
---|---|
In benzene at 20℃; for 2.5h; Mechanism; | A 90% B 100% |
para-thiocresol
4-(4-fluorophenyl)-4-oxo-n-butyl chloride
1-(4-fluorophenyl)-4-(p-tolylthio)butan-1-one
Conditions | Yield |
---|---|
100% | |
With triethylamine In tetrahydrofuran for 16h; Ambient temperature; | 99% |
Conditions | Yield |
---|---|
With dinitrogen tetraoxide In tetrachloromethane; diethyl ether for 2.5h; Ambient temperature; | 100% |
With dihydrogen peroxide; trichlorophosphate In water at 80℃; for 1.16667h; Micellar solution; | 95% |
With HOF* CH3CN In dichloromethane at 0℃; | 90% |
With dihydrogen peroxide; methyltrioxorhenium(VII) In acetonitrile at 20℃; | 87% |
Multi-step reaction with 2 steps 1: pyridine / acetonitrile / Heating 2: hydrogenchloride; water / 40 °C View Scheme |
1-Bromo-3-phenylpropane
para-thiocresol
(3-phenylpropyl)(p-tolyl)sulfane
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 20℃; for 12h; | 100% |
With potassium hydroxide | |
With potassium carbonate In acetone at 45℃; |
D-Mannose pentaacetate
para-thiocresol
4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-D-mannopyranoside
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In dichloromethane at 0 - 20℃; | 100% |
With trifluorormethanesulfonic acid In dichloromethane at 0℃; for 2.5h; Molecular sieve; Inert atmosphere; stereoselective reaction; | 88% |
With boron trifluoride diethyl etherate In dichloromethane | 87% |
1-iodo-2,4-dimethylbenzene
para-thiocresol
(2,4‑dimethylphenyl)(4‑methylphenyl) sulfide
Conditions | Yield |
---|---|
With 1-ethyl-2,2,4,4,4-pentakis(dimethylamino)-2λ5,4λ5-catenadi(phosphazene); copper(I) bromide In toluene Substitution; Heating; | 100% |
Stage #1: para-thiocresol With potassium hydroxide In methanol at 70℃; for 0.25h; Inert atmosphere; Schlenk technique; Green chemistry; Stage #2: 1-iodo-2,4-dimethylbenzene With copper(l) iodide In methanol at 110℃; for 12h; Inert atmosphere; Schlenk technique; Green chemistry; |
3,5-dimethylphenyl iodide
para-thiocresol
Conditions | Yield |
---|---|
Stage #1: para-thiocresol With potassium hydroxide In methanol at 70℃; for 0.25h; Inert atmosphere; Schlenk technique; Green chemistry; Stage #2: 3,5-dimethylphenyl iodide With copper(l) iodide In methanol at 110℃; for 12h; Inert atmosphere; Schlenk technique; Green chemistry; | 100% |
With 1-ethyl-2,2,4,4,4-pentakis(dimethylamino)-2λ5,4λ5-catenadi(phosphazene); copper(I) bromide In toluene Substitution; Heating; | 92% |
With copper(l) iodide; 1,10-Phenanthroline In 1-methyl-pyrrolidin-2-one; methanol at 25℃; for 36h; Inert atmosphere; | 50% |
With C15H16N3Ni(1+)*BF4(1-); sodium t-butanolate In acetonitrile at 100℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; | 0.20 g |
sodium ethanolate
ethylene dibromide
para-thiocresol
(2-ethoxyethyl)-para-thiocresol
Conditions | Yield |
---|---|
Stage #1: para-thiocresol With sodium ethanolate In ethanol at 20℃; Metallation; Stage #2: ethylene dibromide In ethanol at 20℃; Alkylation; Stage #3: sodium ethanolate In ethanol Substitution; Heating; | 100% |
Conditions | Yield |
---|---|
Stage #1: para-thiocresol With sodium ethanolate In ethanol at 20℃; for 0.5h; Metallation; Stage #2: 2-chloro-ethanol In ethanol for 3.5h; Alkylation; Heating; Stage #3: With hydrogenchloride In ethanol; water Chlorination; 15 h, r.t., 4.5 h, reflux; | 100% |
N-(2-bromo-ethyl)-ethylenediamine; dihydrobromide
para-thiocresol
S-2-(2-aminoethylamino)ethyl 4-tolyl sulfide
Conditions | Yield |
---|---|
With triethylamine In chloroform at 0 - 5℃; for 3h; | 100% |
N-(2-bromo-ethyl)-butanediyldiamine; dihydrobromide
para-thiocresol
Conditions | Yield |
---|---|
With triethylamine In chloroform at 0 - 5℃; for 3h; | 100% |
dibromohydrate du N-(bromoethyl-2)diamino-1,3 propane
para-thiocresol
Conditions | Yield |
---|---|
With triethylamine In chloroform at 0 - 5℃; for 3h; | 100% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 1h; | 100% |
Conditions | Yield |
---|---|
Stage #1: 4-iodobenzoic acid With SPPSLRAM SynPhase Lanterns(R); N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In dichloromethane; N,N-dimethyl-formamide at 45℃; for 15h; Stage #2: para-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h; Stage #3: With trifluoroacetic acid In dichloromethane | 100% |
4-iodobenzoic acid
para-thiocresol
4-[(4-methylphenyl)thio]benzoic acid
Conditions | Yield |
---|---|
Stage #1: 4-iodobenzoic acid With dmap; SPPSLHMP SynPhase Lanterns(R); dacarbazine In dichloromethane; N,N-dimethyl-formamide at 50℃; for 15h; Stage #2: para-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h; Stage #3: With trifluoroacetic acid In dichloromethane | 100% |
3-iodo-4-toluic acid
para-thiocresol
Conditions | Yield |
---|---|
Stage #1: 3-iodo-4-toluic acid With dmap; SPPSLHMP SynPhase Lanterns(R); dacarbazine In dichloromethane; N,N-dimethyl-formamide at 50℃; for 15h; Stage #2: para-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h; Stage #3: With trifluoroacetic acid In dichloromethane | 100% |
4-iodo-3-methylbenzoic acid
para-thiocresol
Conditions | Yield |
---|---|
Stage #1: 4-iodo-3-methylbenzoic acid With dmap; SPPSLHMP SynPhase Lanterns(R); dacarbazine In dichloromethane; N,N-dimethyl-formamide at 50℃; for 15h; Stage #2: para-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h; Stage #3: With trifluoroacetic acid In dichloromethane | 100% |
Conditions | Yield |
---|---|
With magnesium oxide In toluene at 20℃; for 0.5h; Michael addition; | 100% |
acrylic acid methyl ester
para-thiocresol
Conditions | Yield |
---|---|
With sodium acetate In tetrahydrofuran; water at 25℃; for 18h; | 100% |
With phosphotungstic acid In water at 20℃; for 2.5h; Michael addition; | 98% |
In water at 30 - 35℃; for 0.25h; thia-Michael addition; | 95% |
2-(4-bromophenyl)benzo[d][1,2]selenazol-3(2H)-one
para-thiocresol
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 1h; | 100% |
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