Conditions | Yield |
---|---|
With copper(ll) sulfate pentahydrate; ethane-1,2-dithiol; potassium hydroxide In water; dimethyl sulfoxide at 90℃; for 20h; Temperature; Solvent; Reagent/catalyst; Inert atmosphere; | 99% |
With copper(ll) sulfate pentahydrate; ethane-1,2-dithiol; potassium hydroxide In water; dimethyl sulfoxide at 90℃; for 20h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere; | 97% |
With sodiumsulfide nonahydrate; copper; ethane-1,2-dithiol In dimethyl sulfoxide at 100℃; for 20h; Inert atmosphere; Sealed tube; | 97% |
Conditions | Yield |
---|---|
With potassium sulfide; acetic acid; triphenylphosphine; zinc In chloroform; water at 60℃; for 0.5h; Solvent; Reagent/catalyst; | 97.5% |
With ISOPROPYLAMIDE; dimethylsilicon dichloride; zinc In 1,2-dichloro-ethane at 75℃; for 1.5h; | 96% |
With formic acid; 6% Pd/C; triphenylphosphine at 60℃; for 8h; | 92% |
Conditions | Yield |
---|---|
With indium; ammonium chloride In ethanol for 1h; Reduction; Heating; | 96% |
With sodium tetrahydroborate; zirconium(IV) chloride In tetrahydrofuran at 35℃; for 0.25h; Reduction; | 95% |
With ammonia; aluminium; sodium chloride at 25℃; for 1h; | 94% |
Conditions | Yield |
---|---|
With iodine; triphenylphosphine In benzene for 0.166667h; Heating; | A 90% B 95% |
(4-methylpyridyl)(4-methylphenyl)sulfide
para-thiocresol
Conditions | Yield |
---|---|
With magnesium In methanol at 20℃; for 4h; | 92% |
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride; diethylamine In xylene for 6h; Heating; | 90% |
With sodium methylselenide In N,N-dimethyl-formamide for 8h; Heating; | 55% |
di(p-tolyl) disulfide
toluene-4-sulfonic acid
triphenylphosphine
A
para-thiocresol
B
Triphenylphosphine oxide
Conditions | Yield |
---|---|
In benzene for 23.5h; Product distribution; Mechanism; Heating; further reaction partners - various diaryl disulfides, diphenyl diselenide, tetrabutylammonium iodide, tributylphosphine; | A 90% B 90% |
Conditions | Yield |
---|---|
With iodine; triphenylphosphine In 1,4-dioxane; benzene for 2h; Heating; | 88% |
With hydrogenchloride; tin In water for 24h; Heating; | 81% |
Multi-step reaction with 2 steps 1: iodine; triphenylphosphine / ethanol / 2 h / Reflux; Green chemistry 2: indole; iodine; triphenylphosphine / ethanol / 2 h / Reflux; Green chemistry View Scheme | |
Multi-step reaction with 2 steps 1: sulfur dioxide / water / 9.5 h / 110 °C / Inert atmosphere 2: sodium tetrahydroborate; sodium hydroxide / water; tetrahydrofuran / 3 h / 65 - 67 °C / Inert atmosphere View Scheme |
Conditions | Yield |
---|---|
With 6% Pd/C; iodine; triphenylphosphine; isopropyl alcohol for 6h; Reflux; | 88% |
With triphenylphosphine; iodine In benzene for 2.5h; Heating; | 89 % Chromat. |
With diphosphorus pentasulfide; lithium aluminium tetrahydride 1.) sulfolane, 90 deg C for 24 h 2.) ether, room temperature for 30 min; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With potassium hydroxide In 1,4-dioxane Schlenk technique; Inert atmosphere; | A 83% B 75% |
Conditions | Yield |
---|---|
Stage #1: para-chlorotoluene With water; palladium diacetate; caesium carbonate; sodium thiosulfate; XPhos In toluene; tert-butyl alcohol at 80℃; for 24h; Inert atmosphere; Stage #2: With hydrogenchloride; zinc In water for 1h; Cooling with ice; | 82% |
With sodium hydroxide; 1-thiopropane 1) N-methyl-2-pyrrolidone, removal of water by toluene reflux, 2) reflux (ca. 186 deg C), 20 h; other reagent: n-butyl mercaptan; Yield given. Multistep reaction; | |
With pumice stone; hydrogen sulfide; thorium dioxide at 700℃; | |
With hydrogen sulfide at 700℃; |
Conditions | Yield |
---|---|
Stage #1: para-bromotoluene With water; caesium carbonate; sodium thiosulfate; bis(dibenzylideneacetone)-palladium(0); XPhos In toluene; tert-butyl alcohol at 80℃; for 24h; Inert atmosphere; Stage #2: With hydrogenchloride; zinc In water for 1h; Cooling with ice; | 81% |
With sodium thiomethoxide In N,N-dimethyl acetamide at 150℃; | |
With sodiumsulfide nonahydrate; copper; ethane-1,2-dithiol In dimethyl sulfoxide at 100℃; for 20h; Inert atmosphere; Green chemistry; | 14 %Chromat. |
Conditions | Yield |
---|---|
Stage #1: 4-methylphenylboronic acid With copper (II)-fluoride; sulfur In dimethyl sulfoxide at 100℃; for 12h; Chan-Lam Coupling; Inert atmosphere; Stage #2: With sodium tetrahydroborate In dimethyl sulfoxide at 40℃; for 5h; Inert atmosphere; | 79% |
p-toluenesulfonic acid monohydrate
trifluoroacetic anhydride
A
S-(trifluoroacetyl)-p-methylthiophenol
B
para-thiocresol
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide In dichloromethane for 20h; Product distribution; Ambient temperature; | A 78% B 11% |
With sodium hydroxide; tetra-(n-butyl)ammonium iodide 1.) CH2Cl2, 20h, room temp.; 2.) MeOH, 30 min, room temp.; Yield given. Multistep reaction. Further byproducts given; | |
With sodium hydroxide; (2S)-N-methyl-1-phenylpropan-2-amine hydrate; tetra-(n-butyl)ammonium iodide 1.) CH2Cl2, 20h, room temp.; 2.) 0 deg C; Yield given. Multistep reaction. Further byproducts given; |
1-<α-(p-tolylsulfonyl)ethyl>-4-methoxybenzene
methylmagnesium bromide
A
(4,4'-dimethyl-1,1'-biphenyl)
B
4-Methylbiphenyl
C
4-methylphenyl methylsulfide
D
1-isopropenyl-4-methoxybenzene
E
1-methoxy-4-(1-methylethyl)benzene
F
para-thiocresol
Conditions | Yield |
---|---|
With bis(triphenylphosphine)nickel(II) diiodide; tricyclohexylphosphine; phenylboronic acid In tetrahydrofuran at 70℃; Kumada Cross-Coupling; Inert atmosphere; | A 11% B 31% C 12% D 78% E 10% F 7% |
Conditions | Yield |
---|---|
With ammonium formate at 100 - 200℃; for 7h; neat (no solvent); | 77% |
With phosphorus; phosphoric acid; potassium iodide | |
With phosphonium iodide; hydrogen iodide at 75 - 100℃; | |
With diphosphorus pentasulfide; lithium aluminium tetrahydride 1.) sulfolane, 90 deg C for 60 h 2.) ether, room temperature for 30 min; Yield given. Multistep reaction; |
1-phenyl-2-(p-tolylthio)ethanone
A
di(p-tolyl) disulfide
B
para-thiocresol
C
acetophenone
Conditions | Yield |
---|---|
With electrolysis on Pt electrode In acetonitrile Product distribution; other electrode (Hg), other solvent (aq. ethanol), influence of phenol; | A n/a B n/a C 72% |
3-[(4-methylphenyl)sulfanyl]-1-propanol
A
di(p-tolyl) disulfide
B
4-methylphenyl propyl sulfide
C
para-thiocresol
Conditions | Yield |
---|---|
PPA In carbon disulfide for 40h; Ambient temperature; | A 72% B 21% C 4% |
Conditions | Yield |
---|---|
With sulfuric acid; triphenylphosphine In water at 20℃; for 10h; | A 30% B 68% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate In tetrahydrofuran for 4h; Heating; | A 60.2% B 27% |
With sodium tetrahydroborate In tetrahydrofuran for 2h; Heating; | A 30.9% B 27% |
With sodium tetrahydroborate In tetrahydrofuran Product distribution; Heating; effect of reaction time; | |
With water; triphenylphosphine In tetrahydrofuran at 20℃; |
γ-chloropropyl 4-methylphenyl sulphide
A
6-Methyl-3,4-dihydro-2H-1-benzothiopyran
B
4-methylphenyl propyl sulfide
C
para-thiocresol
Conditions | Yield |
---|---|
aluminium trichloride In carbon disulfide for 3h; Heating; | A 60% B 15% C 9% |
p-Tolyl-thionitrit
methyllithium
A
4-methylphenyl methylsulfide
B
di(p-tolyl) disulfide
C
para-thiocresol
Conditions | Yield |
---|---|
In diethyl ether at -70℃; for 0.05h; | A 57% B n/a C n/a |
p-Tolyl-thionitrit
A
di(p-tolyl) disulfide
B
4-tolyl phenyl sulfide
C
para-thiocresol
Conditions | Yield |
---|---|
In diethyl ether at -70℃; for 0.05h; | A n/a B 57% C n/a |
2-(p-tolylthio)-ethanol
A
di(p-tolyl) disulfide
B
p-methyl-2-phenylethyl chloride
C
1,2-bis(p-tolylthio)ethane
D
para-thiocresol
Conditions | Yield |
---|---|
aluminium trichloride; nitromethane In carbon disulfide for 40h; Ambient temperature; | A 2.1% B 54% C 43% D 0.3% |
Conditions | Yield |
---|---|
With triphenylphosphine In 1,4-dioxane; water | 53% |
Conditions | Yield |
---|---|
With 18-crown-6 ether; iodine; triphenylphosphine In benzene for 5h; Heating; | 50% |
With triphenylphosphine; 18-crown-6 ether; iodine In benzene for 30.5h; Heating; | 85 % Chromat. |
With diphosphorus pentasulfide; lithium aluminium tetrahydride 1.) sulfolane, 90 deg C for 24 h 2.) ether, room temperature for 30 min; Yield given. Multistep reaction; |
N-(4-methylphenylthiomethyl)benzamide
A
benzonitrile
B
2-phenyl-6-methyl-4H-1,3-benzothiazine
C
para-thiocresol
Conditions | Yield |
---|---|
With trichlorophosphate for 1h; Heating; | A 49% B 9.8% C 16% D 11% |
4-(phenyldisulfanyl)toluene
diphenyldisulfane
A
phenyl toluene-4-thiosulfonate
B
para-thiocresol
Conditions | Yield |
---|---|
With PPE | A 4% B 46% |
3-[(4-methylphenyl)sulfanyl]-1-propanol
A
ethyl p-tolyl sulfide
B
di(p-tolyl) disulfide
C
para-thiocresol
Conditions | Yield |
---|---|
sulfuric acid In carbon disulfide for 40h; Ambient temperature; | A 4% B 45% C 3% D 42% |
sulfuric acid In carbon disulfide for 40h; Product distribution; Ambient temperature; further catalysts; | A 4% B 45% C 3% D 42% |
sulfuric acid In carbon disulfide for 40h; Ambient temperature; | A 4% B 45% C 3% D 42% |
sodium tosylate
trifluoroacetic anhydride
A
S-(trifluoroacetyl)-p-methylthiophenol
B
para-thiocresol
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide In dichloromethane for 19h; Product distribution; Ambient temperature; | A 44% B 26% |
With sodium hydroxide; (2S)-N-methyl-1-phenylpropan-2-amine hydrate; tetra-(n-butyl)ammonium iodide 1.) CH2Cl2, 22h, room temp.; 2.) 0 deg C; Yield given. Multistep reaction. Further byproducts given; |
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 20℃; | 100% |
Stage #1: para-thiocresol With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.333333h; Stage #2: allyl bromide In tetrahydrofuran; mineral oil for 0.4h; | 95% |
With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 4.33333h; | 95% |
Conditions | Yield |
---|---|
With bis dichromate In dichloromethane at 0 - 5℃; for 1h; | 100% |
With bromine; potassium hydrogencarbonate In dichloromethane | 100% |
With N-phenyltriazolinedione In toluene at 20℃; for 0.166667h; | 100% |
1,3-chlorobromopropane
para-thiocresol
γ-chloropropyl 4-methylphenyl sulphide
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran at 20℃; | 100% |
With sodium hydroxide In ethanol at 100℃; | 65% |
With potassium hydroxide |
Conditions | Yield |
---|---|
With zirconium In acetonitrile Michael Addition; Electrolysis; diastereoselective reaction; | 100% |
With triethylammonium acetate at 25℃; for 0.0166667h; Thia-Michael reaction; chemoselective reaction; | 99% |
Mg-La mixed oxides In N,N-dimethyl-formamide at 24.85℃; for 0.45h; Michael addition; | 97% |
(methoxycarbonyl)disulfanyl chloride
para-thiocresol
Methoxycarbonyl 4-methylphenyl trisulfane
Conditions | Yield |
---|---|
In dichloromethane at -78℃; for 1h; | 100% |
4-tosylacetonitrile
para-thiocresol
3-p-tolylsulphonyl-2-p-tolylthiopropene
Conditions | Yield |
---|---|
With triethylamine In methanol for 1.75h; Ambient temperature; | 100% |
With triethylamine In benzene for 2h; Ambient temperature; | 65% |
With triethylamine In benzene for 18h; Ambient temperature; | 55% |
With triethylamine In benzene |
p-toluene(N-phenylsulfonyl)iminosulfinyl chloride
para-thiocresol
A
benzenesulfonamide
B
di(p-tolyl) disulfide
Conditions | Yield |
---|---|
In benzene at 20℃; for 2.5h; Mechanism; | A 100% B 95% |
2,3-dicyanobenzaldehyde
para-thiocresol
3-Oxo-1-p-tolylsulfanyl-2,3-dihydro-1H-isoindole-4-carbonitrile
Conditions | Yield |
---|---|
With triethylamine In chloroform at 20℃; for 4h; | 100% |
(methoxy)diphenyl-λ6-sulfanenitrile
para-thiocresol
A
4-methylphenyl methylsulfide
B
S,S-diphenylsulphoximine
Conditions | Yield |
---|---|
In benzene at 30℃; for 6h; Rate constant; Product distribution; | A 77% B 100% |
In benzene at 30℃; for 6h; Yields of byproduct given; | A 77% B n/a |
vinylidene-1,1-diphosphonic acid
para-thiocresol
(1-Phosphono-2-p-tolylsulfanyl-ethyl)-phosphonic acid
Conditions | Yield |
---|---|
With acetic acid; triethylamine at 110℃; for 15h; | 100% |
p-toluene(N-benzoyl)iminosulfinyl chloride
para-thiocresol
A
di(p-tolyl) disulfide
B
benzamidene hydrochloride
Conditions | Yield |
---|---|
In benzene at 20℃; for 2.5h; Mechanism; | A 90% B 100% |
para-thiocresol
4-(4-fluorophenyl)-4-oxo-n-butyl chloride
1-(4-fluorophenyl)-4-(p-tolylthio)butan-1-one
Conditions | Yield |
---|---|
100% | |
With triethylamine In tetrahydrofuran for 16h; Ambient temperature; | 99% |
Conditions | Yield |
---|---|
With dinitrogen tetraoxide In tetrachloromethane; diethyl ether for 2.5h; Ambient temperature; | 100% |
With dihydrogen peroxide; trichlorophosphate In water at 80℃; for 1.16667h; Micellar solution; | 95% |
With HOF* CH3CN In dichloromethane at 0℃; | 90% |
With dihydrogen peroxide; methyltrioxorhenium(VII) In acetonitrile at 20℃; | 87% |
Multi-step reaction with 2 steps 1: pyridine / acetonitrile / Heating 2: hydrogenchloride; water / 40 °C View Scheme |
1-Bromo-3-phenylpropane
para-thiocresol
(3-phenylpropyl)(p-tolyl)sulfane
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 20℃; for 12h; | 100% |
With potassium hydroxide | |
With potassium carbonate In acetone at 45℃; |
D-Mannose pentaacetate
para-thiocresol
4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-D-mannopyranoside
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In dichloromethane at 0 - 20℃; | 100% |
With trifluorormethanesulfonic acid In dichloromethane at 0℃; for 2.5h; Molecular sieve; Inert atmosphere; stereoselective reaction; | 88% |
With boron trifluoride diethyl etherate In dichloromethane | 87% |
1-iodo-2,4-dimethylbenzene
para-thiocresol
(2,4‑dimethylphenyl)(4‑methylphenyl) sulfide
Conditions | Yield |
---|---|
With 1-ethyl-2,2,4,4,4-pentakis(dimethylamino)-2λ5,4λ5-catenadi(phosphazene); copper(I) bromide In toluene Substitution; Heating; | 100% |
Stage #1: para-thiocresol With potassium hydroxide In methanol at 70℃; for 0.25h; Inert atmosphere; Schlenk technique; Green chemistry; Stage #2: 1-iodo-2,4-dimethylbenzene With copper(l) iodide In methanol at 110℃; for 12h; Inert atmosphere; Schlenk technique; Green chemistry; |
3,5-dimethylphenyl iodide
para-thiocresol
Conditions | Yield |
---|---|
Stage #1: para-thiocresol With potassium hydroxide In methanol at 70℃; for 0.25h; Inert atmosphere; Schlenk technique; Green chemistry; Stage #2: 3,5-dimethylphenyl iodide With copper(l) iodide In methanol at 110℃; for 12h; Inert atmosphere; Schlenk technique; Green chemistry; | 100% |
With 1-ethyl-2,2,4,4,4-pentakis(dimethylamino)-2λ5,4λ5-catenadi(phosphazene); copper(I) bromide In toluene Substitution; Heating; | 92% |
With copper(l) iodide; 1,10-Phenanthroline In 1-methyl-pyrrolidin-2-one; methanol at 25℃; for 36h; Inert atmosphere; | 50% |
With C15H16N3Ni(1+)*BF4(1-); sodium t-butanolate In acetonitrile at 100℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; | 0.20 g |
sodium ethanolate
ethylene dibromide
para-thiocresol
(2-ethoxyethyl)-para-thiocresol
Conditions | Yield |
---|---|
Stage #1: para-thiocresol With sodium ethanolate In ethanol at 20℃; Metallation; Stage #2: ethylene dibromide In ethanol at 20℃; Alkylation; Stage #3: sodium ethanolate In ethanol Substitution; Heating; | 100% |
Conditions | Yield |
---|---|
Stage #1: para-thiocresol With sodium ethanolate In ethanol at 20℃; for 0.5h; Metallation; Stage #2: 2-chloro-ethanol In ethanol for 3.5h; Alkylation; Heating; Stage #3: With hydrogenchloride In ethanol; water Chlorination; 15 h, r.t., 4.5 h, reflux; | 100% |
N-(2-bromo-ethyl)-ethylenediamine; dihydrobromide
para-thiocresol
S-2-(2-aminoethylamino)ethyl 4-tolyl sulfide
Conditions | Yield |
---|---|
With triethylamine In chloroform at 0 - 5℃; for 3h; | 100% |
N-(2-bromo-ethyl)-butanediyldiamine; dihydrobromide
para-thiocresol
Conditions | Yield |
---|---|
With triethylamine In chloroform at 0 - 5℃; for 3h; | 100% |
dibromohydrate du N-(bromoethyl-2)diamino-1,3 propane
para-thiocresol
Conditions | Yield |
---|---|
With triethylamine In chloroform at 0 - 5℃; for 3h; | 100% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 1h; | 100% |
Conditions | Yield |
---|---|
Stage #1: 4-iodobenzoic acid With SPPSLRAM SynPhase Lanterns(R); N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In dichloromethane; N,N-dimethyl-formamide at 45℃; for 15h; Stage #2: para-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h; Stage #3: With trifluoroacetic acid In dichloromethane | 100% |
4-iodobenzoic acid
para-thiocresol
4-[(4-methylphenyl)thio]benzoic acid
Conditions | Yield |
---|---|
Stage #1: 4-iodobenzoic acid With dmap; SPPSLHMP SynPhase Lanterns(R); dacarbazine In dichloromethane; N,N-dimethyl-formamide at 50℃; for 15h; Stage #2: para-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h; Stage #3: With trifluoroacetic acid In dichloromethane | 100% |
3-iodo-4-toluic acid
para-thiocresol
Conditions | Yield |
---|---|
Stage #1: 3-iodo-4-toluic acid With dmap; SPPSLHMP SynPhase Lanterns(R); dacarbazine In dichloromethane; N,N-dimethyl-formamide at 50℃; for 15h; Stage #2: para-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h; Stage #3: With trifluoroacetic acid In dichloromethane | 100% |
4-iodo-3-methylbenzoic acid
para-thiocresol
Conditions | Yield |
---|---|
Stage #1: 4-iodo-3-methylbenzoic acid With dmap; SPPSLHMP SynPhase Lanterns(R); dacarbazine In dichloromethane; N,N-dimethyl-formamide at 50℃; for 15h; Stage #2: para-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h; Stage #3: With trifluoroacetic acid In dichloromethane | 100% |
Conditions | Yield |
---|---|
With magnesium oxide In toluene at 20℃; for 0.5h; Michael addition; | 100% |
acrylic acid methyl ester
para-thiocresol
Conditions | Yield |
---|---|
With sodium acetate In tetrahydrofuran; water at 25℃; for 18h; | 100% |
With phosphotungstic acid In water at 20℃; for 2.5h; Michael addition; | 98% |
In water at 30 - 35℃; for 0.25h; thia-Michael addition; | 95% |
2-(4-bromophenyl)benzo[d][1,2]selenazol-3(2H)-one
para-thiocresol
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 1h; | 100% |
IUPAC Name: 4-Methylbenzenethiol
Canonical SMILES: CC1=CC=C(C=C1)S
InChI: InChI=1S/C7H8S/c1-6-2-4-7(8)5-3-6/h2-5,8H,1H3
InChIKey: WLHCBQAPPJAULW-UHFFFAOYSA-N
Molecular Weight: 124.20342 [g/mol]
Molecular Formula: C7H8S
XLogP3: 2.9
EINECS: 203-399-1
Appearance: White or colorless solid melt
Melting Point: 84-86 °C
Index of Refraction: 1.577
Molar Refractivity: 39.25 cm3
Molar Volume: 118.3 cm3
Surface Tension: 37.8 dyne/cm
Density: 1.049 g/cm3
Flash Point: 69.5 °C
Enthalpy of Vaporization: 41.36 kJ/mol
Boiling Point: 195 °C at 760 mmHg
Vapour Pressure: 0.601 mmHg at 25 °C
storage temp.: Store at RT.
Water Solubility: slightly soluble
Sensitive: Stench
Product Categories of p-Toluenethiol (CAS NO.106-45-6): Intermediates; Phenol & Thiophenol & Mercaptan
p-Toluenethiol (CAS NO.106-45-6) is used in organic synthesis, and the synthesis of dyes, medicine, etc.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intraperitoneal | 200mg/kg (200mg/kg) | National Technical Information Service. Vol. AD277-689, |
Reported in EPA TSCA Inventory.
Poison by intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic fumes of SOx.
Hazard Codes: Xi,Xn
Risk Statements:
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
Safety Statements:
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
RIDADR: 2811
WGK Germany: 3
RTECS: XT8925000
F: 13
Hazard Note: Harmful/Stench
HazardClass: 6.1
PackingGroup of p-Toluenethiol (CAS NO.106-45-6): III
DOT Classification: 3; Label: Flammable Liquid, Poison (UN 1228); DOT Class: 6.1; Label: Poison, Flammable Liquid (UN 3071)
p-Toluenethiol (CAS NO.106-45-6), its Synonyms are 4-Methylbenzenethiol ; 4-Methylphenyl mercaptan ; 4-Methylphenylmercaptan ; 4-Methylthiophenol ; 4-Thiocresol ; 4-Toluenethiol ; 1-Mercapto-4-methylbenzene ; Toluene, 4-mercapto- ; Benzenethiol, 4-methyl- ; p-Methylphenyl mercaptan ; p-Methylphenylmercaptan ; p-Methylthiophenol ; p-Thiocresol ; p-Tolyl mercaptan ; p-Tolylthiol ; p-Tolylthiophenol .
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