As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t
Cas:589-87-7
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inquiryBest Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP
Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:589-87-7
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inquiryOur Services 1. Certificate Of Analysis (COA) 2. Material Safety Data Sheet (MSDS) 3. Route of synthesis (ROS) 4. Method of Aanlysis (MOA)
Cas:589-87-7
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inquiry1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; ...... Appearance:Off-white crystal Storage:Store below +30°C. Package:1kg/
Cas:589-87-7
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inquiryhigh quality Appearance:solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:shanghai
1-Bromo-4-iodobenzene CAS NO.:589-87-7 HANGZHOU THINK CHEMICAL CO., LTD. (THINKCHEM) is an integrative corporation of trade, research and contract manufacture. With about ten years of business experiences on the marketing & di
Cas:589-87-7
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:589-87-7
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inquiryColorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:589-87-7
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Type:Manufacturers
inquiry1-Bromo-4-iodobenzene Basic information Product Name: 1-Bromo-4-iodobenzene Synonyms: 4-IODOBROMOBENZENE;4-BROMO-1-IODOBENZENE;4-BROMOIODOBENZENE;1-BROMO-4-IODOBENZENE;1-bromo-4-iodo-ben
Cas:589-87-7
Min.Order:1 Kilogram
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
Cas:589-87-7
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:589-87-7
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inquiryProduct Name: 1-Bromo-4-iodobenzene CAS No.: 589-87-7 Molecular Formula:C6H4BrI Molecular Weight:282.9 Appearance: White crystal Specification: GC>99.5% Impurity max<0.2% Melting point: 89-91℃ Packaging:30kg/drum
We are leading fine chemicals supplier in China and Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediat
Cas:589-87-7
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:589-87-7
Min.Order:1 Kilogram
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inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen
Cas:589-87-7
Min.Order:5 Gram
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Type:Trading Company
inquiryBeluga chemical professional supply High quality 1-Bromo-4-iodobenzene CAS 589-87-7 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made in C
Cas:589-87-7
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:589-87-7
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryMinimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,
Cas:589-87-7
Min.Order:10 Gram
Negotiable
Type:Trading Company
inquiryHangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting 1-Bromo-4-iodobenzene,cas:589-87-7;Please contact us by email freely. We are leading exporter in China. If you really need this c
Cas:589-87-7
Min.Order:0 Metric Ton
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Type:Other
inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Superiority : 1.ISO certificate 2..Powerful R & D team 3.The ability of quantized production,from grams to tons; 4.Various kinds of advanced equipment in the laboratory and plant; 5.Strict QC standard to meet the demand of customers,a
Cas:589-87-7
Min.Order:10 Gram
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Type:Other
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:589-87-7
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Cas:589-87-7
Min.Order:4 Kilogram
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Type:Lab/Research institutions
inquiryChemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff
Cas:589-87-7
Min.Order:100 Gram
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Type:Other
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:589-87-7
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquirySuperior quality Appearance:white to brown cryst. powder, crystals or needles Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:suzuki reaction Tran
Conditions | Yield |
---|---|
Stage #1: 4-bromo-aniline With hydrogenchloride; sodium nitrite In water at 0 - 5℃; for 0.5h; Inert atmosphere; Stage #2: With potassium iodide In ethyl acetate for 0.5h; | 100% |
With sulfuric acid; potassium iodide; sodium nitrite In water at -5 - 60℃; Inert atmosphere; | 92% |
Stage #1: 4-bromo-aniline With sulfuric acid; silica gel; sodium nitrite at 20℃; grinding; Neat (no solvent); Stage #2: With water at 20℃; grinding; Neat (no solvent); Stage #3: With potassium iodide at 20℃; for 0.166667h; Sandmeyer reaction; grinding; Neat (no solvent); | 87% |
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With potassium iodide for 24h; | 100% |
Conditions | Yield |
---|---|
With potassium iodide In water at 25℃; for 0.0833333h; Solvent; Sandmeyer Reaction; | 99% |
With diiodomethane; tetrabutylammonium perchlorate In methanol; N,N-dimethyl-formamide at 20℃; for 3h; Sandmeyer Reaction; Electrochemical reaction; | 61% |
With iodine; potassium iodide In dimethyl sulfoxide at 15℃; |
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In N,N-dimethyl-formamide at 20℃; for 4h; | 96% |
(4-bromophenyl)triethylgermane
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With N-iodo-succinimide In N,N-dimethyl-formamide at 50℃; for 4h; | 96% |
Conditions | Yield |
---|---|
With potassium bromide In acetonitrile at 20℃; for 1h; Sandmeyer Reaction; Inert atmosphere; | 95% |
With N-Bromosuccinimide; tetrabutylammonium perchlorate In methanol; N,N-dimethyl-formamide at 20℃; for 3h; Sandmeyer Reaction; Electrochemical reaction; | 68% |
With (triphenylphosphine)gold(I) chloride; sodium bromide In acetonitrile at 50℃; for 5h; Sandmeyer Reaction; | 73 %Chromat. |
1-(4-Bromophenyl)-3,3-diethyltriazene
methyl iodide
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
at 110 - 120℃; for 6h; | 94% |
Conditions | Yield |
---|---|
With sodium nitrite In acetonitrile at 80℃; for 1.5h; Sealed tube; | 94% |
With N-iodo-succinimide In acetonitrile at 81℃; for 6h; | 88% |
With potassium fluoride; iodine In 1,4-dioxane at 80℃; for 1h; | 86% |
potassium 4-bromophenyltrifluoroborate
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With caesium tribromide In water; N,N-dimethyl-formamide at 80℃; for 5h; chemoselective reaction; | 94% |
With chloroamine-T; sodium iodide In tetrahydrofuran; water at 20℃; for 0.25h; | 87% |
Cyclohexanone oxime
(4-bromophenyl)-λ3-iodanediyl diacetate
A
1,4-bromoiodobenzene
B
acetoxy-1 nitroso-1 cyclohexane
Conditions | Yield |
---|---|
In acetic acid at -15℃; for 0.25h; | A n/a B 94% |
4-dibenzofurylboronic acid
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
94% |
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid; [bis(pyridine)iodine]+ tetrafluoroborate In dichloromethane for 2h; Ambient temperature; | 90% |
With sodium periodate; sulfuric acid; iodine In acetic anhydride; acetic acid at 20℃; for 5h; Iodination; | 87% |
With cerium(III) chloride heptahydrate; dihydrogen peroxide; sodium iodide In water for 12h; Reflux; regioselective reaction; | 86% |
Conditions | Yield |
---|---|
With iodine; fluorine In chloroform; trichlorofluoromethane at -20℃; for 0.5h; | A 5% B 90% |
With dipotassium peroxodisulfate; iodine In dichloromethane; trifluoroacetic acid at 36 - 38℃; for 44h; | A n/a B 74% |
With sulfuric acid; iodine; nitric acid In acetic acid at 80 - 100℃; Product distribution; |
Conditions | Yield |
---|---|
With tert.-butylnitrite; tetrabutylammomium bromide; copper(I) bromide; 10-camphorsulfonic acid In acetonitrile at 20℃; for 24h; Reagent/catalyst; Time; Solvent; | 90% |
With tert.-butylnitrite; tetrabutylammomium bromide; toluene-4-sulfonic acid; copper(ll) bromide In acetonitrile at 20℃; for 1h; | 78% |
With tert.-butylnitrite; tetrabutylammomium bromide; toluene-4-sulfonic acid; copper(ll) bromide | 64% |
bis-[(trifluoroacetoxy)iodo]benzene
A
1-Bromo-2-iodobenzene
B
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With bromine In chloroform Ambient temperature; | A 10% B 89% |
(4-bromophenyl)-λ3-iodanediyl diacetate
acetone oxime
A
2-acetoxy-2-nitrosopropane
B
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
In acetic acid at -15℃; for 0.25h; | A 88% B n/a |
1-(4-Bromophenyl)-3,3-diethyltriazene
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With sulfonic acid resin (H+ form, Bio-Rad AG 50W-12); sodium iodide In acetonitrile at 75℃; for 0.133333h; | 85% |
Conditions | Yield |
---|---|
With N-iodo-succinimide; [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; iodine; caesium carbonate In 1,2-dichloro-ethane at 50℃; for 24h; Inert atmosphere; Irradiation; Sealed tube; | 85% |
With 3-iodo-4,4-dimethyloxazolidin-2-one In 1,2-dichloro-ethane for 24h; Concentration; Time; Solvent; Reagent/catalyst; Reflux; Irradiation; | 51% |
Cyclopentanone oxime
(4-bromophenyl)-λ3-iodanediyl diacetate
A
1,4-bromoiodobenzene
B
1-acetoxy-1-nitrosocyclopentane
Conditions | Yield |
---|---|
In acetic acid at -15℃; for 0.25h; | A n/a B 83% |
Conditions | Yield |
---|---|
With potassium bromide; sodium nitrite In water; trifluoroacetic acid at 20℃; for 2h; Product distribution; under argon, other time, other reagent; | A 18% B 82% |
With oxygen; potassium bromide; potassium nitrate In water; trifluoroacetic acid at 20℃; for 8h; Product distribution; | A 18% B 82% |
With lead(II,IV) oxide; trifluoroacetic acid; potassium bromide at 20℃; Product distribution; |
Conditions | Yield |
---|---|
Stage #1: 1.4-dibromobenzene With tert.-butyl lithium In diethyl ether at -78℃; for 0.5h; Stage #2: With iodine In tetrahydrofuran; diethyl ether at -78 - 20℃; for 4.75h; | 82% |
Stage #1: 1.4-dibromobenzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere; Stage #2: With iodine In tetrahydrofuran; hexane at -78 - 25℃; for 1.5h; Inert atmosphere; | 75% |
With caesium carbonate; potassium iodide; copper(l) iodide In toluene at 110℃; for 12h; |
1-(4-bromophenyl)-2-(pyrrolidin-1-yl)diazene
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With iodine In 1,2-dichloro-ethane at 80℃; for 4h; | 80% |
bis(trifluoromethanesulfonyl)amide
4-bromo-aniline
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
Stage #1: bis(trifluoromethanesulfonyl)amide With tert.-butylnitrite; acetic acid In ethanol Cooling with ice; Stage #2: 4-bromo-aniline With tetraethylammonium iodide In water at 20℃; | 80% |
ethyl acetohydroximate
bis(4-bromophenyl)iodonium triflate
A
1,4-bromoiodobenzene
B
ethyl N-4-bromophenoxyacetimidate
Conditions | Yield |
---|---|
Stage #1: ethyl acetohydroximate With sodium t-butanolate In acetonitrile at 0 - 20℃; for 0.25h; Stage #2: bis(4-bromophenyl)iodonium triflate In acetonitrile at 20℃; for 0.5h; chemoselective reaction; | A 144 mg B 78% |
ethyl acetohydroximate
bis(4-bromophenyl)iodonium triflate
acetophenone
A
5-bromo-2-phenylbenzo[b]furan
B
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
Stage #1: ethyl acetohydroximate With sodium t-butanolate In acetonitrile at 0 - 20℃; for 0.25h; Stage #2: bis(4-bromophenyl)iodonium triflate In acetonitrile at 20℃; for 0.5h; Stage #3: acetophenone With hydrogenchloride In water; acetonitrile at 20 - 70℃; for 3.25h; Inert atmosphere; chemoselective reaction; | A 73% B 147 mg |
chloroform
4,4'-dibromodiphenyliodonium chloride
A
1,4-bromoiodobenzene
B
4-Bromobenzoic acid
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; potassium hydroxide at 50℃; for 1h; Carbonylation; | A n/a B 72% |
(4-bromophenyl)zinc iodide
A
1,4-bromoiodobenzene
B
4-(4-bromophenyl)bromobenzene
Conditions | Yield |
---|---|
Stage #1: (4-bromophenyl)zinc iodide With N-chloro-succinimide; tetrakis(triphenylphosphine) palladium(0) In various solvent(s) at 20℃; for 4h; Stage #2: With iodine In various solvent(s) | A 36% B 63% |
carbon monoxide
1-bromo-4-iodoxybenzene
A
1,4-bromoiodobenzene
B
4-Bromobenzoic acid
C
terephthalic acid
Conditions | Yield |
---|---|
With sodium tetrachloropalladate; sodium carbonate In water at 40℃; for 5h; Yields of byproduct given; | A n/a B 61% C 15% |
C7H6BrN7
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With tertamethylammonium iodide; trifluoroacetic acid In acetonitrile at 70 - 80℃; | 61% |
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With acetic acid; lithium bromide In dimethyl sulfoxide at 100℃; for 8h; Schlenk technique; | 51% |
1,4-bromoiodobenzene
methyl 2-(tributylstannanyl)-2-propenoate
Conditions | Yield |
---|---|
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 20℃; Inert atmosphere; | 100% |
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide for 24h; Ambient temperature; | 92% |
1,4-bromoiodobenzene
trimethylsilylacetylene
(4-bromophenyl)(trimethylsilyl)acetylene
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 100℃; for 0.5h; Inert atmosphere; | 100% |
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran Sonogashira Cross-Coupling; Inert atmosphere; | 100% |
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine at 0℃; Schlenk technique; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With amphiphilic resin-supported phosphine-palladium; water; potassium carbonate at 25℃; under 760 Torr; for 12h; hydroxycarbonylation; | 100% |
With water; potassium carbonate In acetonitrile at 100℃; under 3750.38 Torr; for 0.0161111h; | 93% |
With water; palladium diacetate; potassium carbonate at 20℃; under 760.051 Torr; for 6h; | 91% |
1,4-bromoiodobenzene
tris-iso-propylsilyl acetylene
(2-(4-bromophenyl)ethynyl)triisopropylsilane
Conditions | Yield |
---|---|
With copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran at 20℃; for 16h; | 100% |
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In tetrahydrofuran at 20℃; for 16h; Sonogashira Coupling; | 100% |
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In tetrahydrofuran at 20℃; for 16h; Sonogashira Coupling; | 100% |
Conditions | Yield |
---|---|
With copper(l) iodide; triethylamine; tetrakis(triphenylphosphine) palladium(0) In dichloromethane at 50℃; Sonogashira reaction; | 100% |
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran for 4h; Inert atmosphere; Reflux; | 85% |
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide Schlenk technique; | 82% |
acenaphthene-5-boronic acid
1,4-bromoiodobenzene
5-(4-bromophenyl)acenaphthene
Conditions | Yield |
---|---|
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 6h; Heating / reflux; | 100% |
4-bromo-1-ethynylbenzene
1,4-bromoiodobenzene
1,2-bis(4-bromophenyl)acetylene
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran Sonogashira Cross-Coupling; Inert atmosphere; | 100% |
With C18H18N2O8PdS2(2-)*2Na(1+)*3H2O; triethylamine In water at 80℃; for 8h; Sonogashira Cross-Coupling; | 97% |
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide | 91% |
5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)
1,4-bromoiodobenzene
5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-bromophenyl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); water; caesium carbonate In toluene Suzuki-Miyaura cross-coupling; Inert atmosphere; Reflux; | 100% |
1,4-bromoiodobenzene
5,10-bis[3,5-di(tert-butyl)phenyl]-15,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)
5,10-bis[3,5-di(tert-butyl)phenyl]-15,20-bis(4-bromophenyl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); water; caesium carbonate In toluene Suzuki-Miyaura cross-coupling; Inert atmosphere; Reflux; | 100% |
Conditions | Yield |
---|---|
With potassium thioacyanate; cetyltrimethylammonim bromide; potassium hydroxide In water at 135℃; for 7h; Green chemistry; | 100% |
With copper(l) iodide; sodiumsulfide nonahydrate; potassium carbonate In N,N-dimethyl-formamide at 120℃; for 18h; Inert atmosphere; chemoselective reaction; | 94% |
With copper(l) iodide; sodiumsulfide nonahydrate; potassium carbonate In N,N-dimethyl-formamide at 120℃; for 18h; Inert atmosphere; Darkness; | 94% |
Conditions | Yield |
---|---|
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine In tetrahydrofuran for 16h; Sonogashira Cross-Coupling; Inert atmosphere; | 100% |
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran at 50℃; for 4h; Sonogashira Cross-Coupling; Inert atmosphere; | 100% |
1,4-bromoiodobenzene
(R)-(+)-4-methylpyrrolidin-2-one
Conditions | Yield |
---|---|
With copper(l) iodide; cesium fluoride; N,N`-dimethylethylenediamine In ethyl acetate at 50℃; for 16h; Inert atmosphere; | 100% |
4,4-dimethylpyrrolidin-2-one
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With copper(l) iodide; cesium fluoride; N,N`-dimethylethylenediamine In ethyl acetate at 50℃; for 16h; Inert atmosphere; | 100% |
(S)-(-)-4-methylpyrrolidin-2-one
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With copper(l) iodide; cesium fluoride; N,N`-dimethylethylenediamine In ethyl acetate at 50℃; for 16h; Inert atmosphere; | 100% |
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With copper(l) iodide; cesium fluoride; N,N`-dimethylethylenediamine In ethyl acetate at 50℃; for 16h; Inert atmosphere; | 100% |
1,4-bromoiodobenzene
Conditions | Yield |
---|---|
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium hydroxide In tetrahydrofuran at 20℃; for 12h; Inert atmosphere; Schlenk technique; | 100% |
1,4-bromoiodobenzene
N-(cyclopropylmethyl)-1,1,1-trifluoromethanesulfonamide
Conditions | Yield |
---|---|
With t-Boc-L-valine; sodium 2,2,2-trifluoroacetate; palladium diacetate; silver carbonate In tert-butyl alcohol at 80℃; for 18h; Sealed tube; enantioselective reaction; | 99.9% |
Conditions | Yield |
---|---|
With copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide In 1,2-dimethoxyethane; water at 95℃; for 20h; Catalytic behavior; Solvent; Schlenk technique; Inert atmosphere; Sealed tube; | 99% |
With copper; potassium carbonate In N,N-dimethyl-formamide at 130℃; for 42h; Inert atmosphere; | 96% |
With copper(I) oxide; 2,2,6,6-tetramethylheptane-3,5-dione; potassium hydroxide In N,N-dimethyl-formamide at 110℃; for 24h; Inert atmosphere; Schlenk technique; | 95% |
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran at 20℃; | 99% |
Stage #1: 1,4-bromoiodobenzene With piperidine; copper(l) iodide; dichlorobis(tri-O-tolylphosphine)palladium In toluene at 20℃; for 0.0333333h; Inert atmosphere; Stage #2: propargyl alcohol In toluene at 35℃; Sonogashira coupling; Inert atmosphere; | 98% |
With piperidine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In toluene at 60℃; for 2h; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In acetonitrile at 20℃; for 17h; Inert atmosphere; | 99% |
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; triethylamine In acetonitrile at 20℃; Sonogashira Cross-Coupling; Inert atmosphere; | 99% |
With triethylamine In neat (no solvent) at 20℃; for 6h; Sonogashira Cross-Coupling; | 97% |
Conditions | Yield |
---|---|
(4-F(13)C6-C6H4)3P; bis(dibenzylideneacetone)-palladium(0) In toluene at 60℃; | 99% |
acrylic acid n-butyl ester
1,4-bromoiodobenzene
butyl (E)-4-bromocinnamate
Conditions | Yield |
---|---|
With dichloro bis(acetonitrile) palladium(II); potassium phosphate; N,N'-(1,2-ethanediylidene)bishexahydro-1H-azepin-1-amine In N,N-dimethyl-formamide at 80℃; for 6h; Mizoroki-Heck reaction; | 99% |
With potassium carbonate In N,N-dimethyl-formamide at 85℃; for 1h; Heck Reaction; | 98% |
With tributyl-amine In water at 90℃; for 7h; Heck Reaction; | 95% |
Conditions | Yield |
---|---|
With sodium carbonate In 1-methyl-pyrrolidin-2-one at 100℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; | 99% |
With potassium carbonate In water at 90℃; for 1h; Suzuki-Miyaura coupling; chemoselective reaction; | 98% |
With potassium carbonate In ethanol; water at 80℃; for 0.583333h; Catalytic behavior; Suzuki-Miyaura Coupling; | 96% |
Conditions | Yield |
---|---|
With (tris(3,5-dimethyl-1-pyrazolyl)methane)CuI; lithium tert-butoxide In 1,4-dioxane at 110℃; for 24h; Ullmann condensation; Inert atmosphere; chemoselective reaction; | 99% |
With copper(l) iodide; potassium carbonate In 1-methyl-pyrrolidin-2-one at 100℃; for 16h; | 96% |
With copper(l) iodide; 8-Hydroxyquinoline-N-oxide; caesium carbonate In dimethyl sulfoxide at 80℃; for 24h; Inert atmosphere; chemoselective reaction; | 96% |
Conditions | Yield |
---|---|
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diethylamine In N,N-dimethyl-formamide at 40℃; | 99% |
With CuI(xantphos); caesium carbonate In N,N-dimethyl-formamide at 135℃; for 0.166667h; Sonogashira type reaction; Inert atmosphere; Microwave irradiation; | 78% |
With copper(I) oxide; caesium carbonate In N,N-dimethyl-formamide at 135℃; for 24h; Sonogashira Cross-Coupling; Inert atmosphere; | 67% |
Conditions | Yield |
---|---|
With potassium carbonate In water at 50℃; for 1.5h; Suzuki Coupling; | 99% |
With magnesium hydroxide; potassium hydroxide; barium(II) hydroxide; calcium hydroxide In water at 20℃; for 1.5h; Suzuki Coupling; | 99% |
With sodium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 60℃; for 12h; Suzuki; | 98% |
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