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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t

High purity 1-Bromo-4-iodobenzene 98% TOP1 supplier in China

Cas:589-87-7

Min.Order:100 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

1-Bromo-4-iodobenzene

Cas:589-87-7

Min.Order:0

Negotiable

Type:Trading Company

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1-Bromo-4-Iodobenzene supplier in China

Cas:589-87-7

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Our Services 1. Certificate Of Analysis (COA) 2. Material Safety Data Sheet (MSDS) 3. Route of synthesis (ROS) 4. Method of Aanlysis (MOA)

1-Bromo-4-iodobenzene

Cas:589-87-7

Min.Order:1 Gram

FOB Price: $8.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; ...... Appearance:Off-white crystal Storage:Store below +30°C. Package:1kg/

High purity 1-Bromo-4-iodobenzene CAS 589-87-7 supplied by manufacturer

Cas:589-87-7

Min.Order:5 Kilogram

FOB Price: $120.0 / 150.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:shanghai

1-Bromo-4-iodobenzene

Cas:589-87-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hangzhou Think Chemical Co. Ltd

1-Bromo-4-iodobenzene CAS NO.:589-87-7 HANGZHOU THINK CHEMICAL CO., LTD. (THINKCHEM) is an integrative corporation of trade, research and contract manufacture. With about ten years of business experiences on the marketing & di

High purity 1-Bromo-4-iodobenzene CAS NO.:589-87-7 Supplier from China

Cas:589-87-7

Min.Order:1 Kilogram

FOB Price: $10.0 / 20.0

Type:Other

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1-Bromo-4-Iodobenzene

Cas:589-87-7

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 589-87-7 1-BroMo-4-iodobenzene Manufacturer

Cas:589-87-7

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

1-Bromo-4-Iodobenzene

Cas:589-87-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Bromoiodobenzene

Cas:589-87-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

1-Bromo-4-iodobenzene Basic information Product Name: 1-Bromo-4-iodobenzene Synonyms: 4-IODOBROMOBENZENE;4-BROMO-1-IODOBENZENE;4-BROMOIODOBENZENE;1-BROMO-4-IODOBENZENE;1-bromo-4-iodo-ben

589-87-7 1-Bromo-4-iodobenzene

Cas:589-87-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

1-Bromo-4-iodobenzene

Cas:589-87-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Best CAS 589-87-7 with competitive price

Cas:589-87-7

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name: 1-Bromo-4-iodobenzene CAS No.: 589-87-7 Molecular Formula:C6H4BrI Molecular Weight:282.9 Appearance: White crystal Specification: GC>99.5% Impurity max<0.2% Melting point: 89-91℃ Packaging:30kg/drum

1-Bromo-4-iodobenzene

Cas:589-87-7

Min.Order:30 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediat

589-87-7 1-Bromo-4-iodobenzeneCAS NO.: 589-87-7

Cas:589-87-7

Min.Order:1 Gram

FOB Price: $4.0 / 5.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-bromo-4-iodo- 589-87-7

Cas:589-87-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen

589-87-71-bromo-4-iodobenzene

Cas:589-87-7

Min.Order:5 Gram

FOB Price: $166.67 / 333.33

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supply High quality 1-Bromo-4-iodobenzene CAS 589-87-7 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made in C

High quality 1-Bromo-4-iodobenzene CAS 589-87-7

Cas:589-87-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-bromo-4-iodo-

Cas:589-87-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

1-Bromo-4-iodobenzene supplier in China CAS NO.589-87-7

Cas:589-87-7

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Hangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting 1-Bromo-4-iodobenzene,cas:589-87-7;Please contact us by email freely. We are leading exporter in China. If you really need this c

1-Bromo-4-iodobenzene,cas:589-87-7 from Fandachem

Cas:589-87-7

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

1-Bromo-4-Iodobenzene

Cas:589-87-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Kemi-Works Chemical Co., Ltd

Superiority : 1.ISO certificate 2..Powerful R & D team 3.The ability of quantized production,from grams to tons; 4.Various kinds of advanced equipment in the laboratory and plant; 5.Strict QC standard to meet the demand of customers,a

4-Iodobromobenzene/ 1-Bromo-4-iodobenzene CAS No.589-87-7

Cas:589-87-7

Min.Order:10 Gram

Negotiable

Type:Other

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1-Bromo-4-iodobenzene

Cas:589-87-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-Bromo-4-iodobenzene

Cas:589-87-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

4-Bromobenzyl bromide

Cas:589-87-7

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 1-Bromo-4-iodobenzene

Cas:589-87-7

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High purity 1-Bromo-4-iodobenzene

Cas:589-87-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:white to brown cryst. powder, crystals or needles Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:suzuki reaction Tran

1-Bromo-4-iodobenzene

Cas:589-87-7

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Synthetic route

4-bromo-aniline
106-40-1

4-bromo-aniline

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
Stage #1: 4-bromo-aniline With hydrogenchloride; sodium nitrite In water at 0 - 5℃; for 0.5h; Inert atmosphere;
Stage #2: With potassium iodide In ethyl acetate for 0.5h;
100%
With sulfuric acid; potassium iodide; sodium nitrite In water at -5 - 60℃; Inert atmosphere;92%
Stage #1: 4-bromo-aniline With sulfuric acid; silica gel; sodium nitrite at 20℃; grinding; Neat (no solvent);
Stage #2: With water at 20℃; grinding; Neat (no solvent);
Stage #3: With potassium iodide at 20℃; for 0.166667h; Sandmeyer reaction; grinding; Neat (no solvent);
87%
4-bromophenyldiazonium nitrate

4-bromophenyldiazonium nitrate

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With potassium iodide for 24h;100%
4-bromobenzenediazonium tetrafluoroborate
673-40-5

4-bromobenzenediazonium tetrafluoroborate

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With potassium iodide In water at 25℃; for 0.0833333h; Solvent; Sandmeyer Reaction;99%
With diiodomethane; tetrabutylammonium perchlorate In methanol; N,N-dimethyl-formamide at 20℃; for 3h; Sandmeyer Reaction; Electrochemical reaction;61%
With iodine; potassium iodide In dimethyl sulfoxide at 15℃;
triethyl(4-iodophenyl)germane

triethyl(4-iodophenyl)germane

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide In N,N-dimethyl-formamide at 20℃; for 4h;96%
(4-bromophenyl)triethylgermane
23268-74-8

(4-bromophenyl)triethylgermane

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With N-iodo-succinimide In N,N-dimethyl-formamide at 50℃; for 4h;96%
4-iodobenzenediazonium tetrafluoroborate
1514-50-7

4-iodobenzenediazonium tetrafluoroborate

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With potassium bromide In acetonitrile at 20℃; for 1h; Sandmeyer Reaction; Inert atmosphere;95%
With N-Bromosuccinimide; tetrabutylammonium perchlorate In methanol; N,N-dimethyl-formamide at 20℃; for 3h; Sandmeyer Reaction; Electrochemical reaction;68%
With (triphenylphosphine)gold(I) chloride; sodium bromide In acetonitrile at 50℃; for 5h; Sandmeyer Reaction;73 %Chromat.
1-(4-Bromophenyl)-3,3-diethyltriazene
52010-62-5

1-(4-Bromophenyl)-3,3-diethyltriazene

methyl iodide
74-88-4

methyl iodide

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
at 110 - 120℃; for 6h;94%
4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With sodium nitrite In acetonitrile at 80℃; for 1.5h; Sealed tube;94%
With N-iodo-succinimide In acetonitrile at 81℃; for 6h;88%
With potassium fluoride; iodine In 1,4-dioxane at 80℃; for 1h;86%
potassium 4-bromophenyltrifluoroborate
374564-35-9

potassium 4-bromophenyltrifluoroborate

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With caesium tribromide In water; N,N-dimethyl-formamide at 80℃; for 5h; chemoselective reaction;94%
With chloroamine-T; sodium iodide In tetrahydrofuran; water at 20℃; for 0.25h;87%
Cyclohexanone oxime
100-64-1

Cyclohexanone oxime

(4-bromophenyl)-λ3-iodanediyl diacetate
41018-52-4

(4-bromophenyl)-λ3-iodanediyl diacetate

A

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

B

acetoxy-1 nitroso-1 cyclohexane
10259-08-2

acetoxy-1 nitroso-1 cyclohexane

Conditions
ConditionsYield
In acetic acid at -15℃; for 0.25h;A n/a
B 94%
4-dibenzofurylboronic acid
100124-06-9

4-dibenzofurylboronic acid

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
94%
bromobenzene
108-86-1

bromobenzene

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; [bis(pyridine)iodine]+ tetrafluoroborate In dichloromethane for 2h; Ambient temperature;90%
With sodium periodate; sulfuric acid; iodine In acetic anhydride; acetic acid at 20℃; for 5h; Iodination;87%
With cerium(III) chloride heptahydrate; dihydrogen peroxide; sodium iodide In water for 12h; Reflux; regioselective reaction;86%
bromobenzene
108-86-1

bromobenzene

A

1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

B

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With iodine; fluorine In chloroform; trichlorofluoromethane at -20℃; for 0.5h;A 5%
B 90%
With dipotassium peroxodisulfate; iodine In dichloromethane; trifluoroacetic acid at 36 - 38℃; for 44h;A n/a
B 74%
With sulfuric acid; iodine; nitric acid In acetic acid at 80 - 100℃; Product distribution;
p-aminoiodobenzene
540-37-4

p-aminoiodobenzene

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With tert.-butylnitrite; tetrabutylammomium bromide; copper(I) bromide; 10-camphorsulfonic acid In acetonitrile at 20℃; for 24h; Reagent/catalyst; Time; Solvent;90%
With tert.-butylnitrite; tetrabutylammomium bromide; toluene-4-sulfonic acid; copper(ll) bromide In acetonitrile at 20℃; for 1h;78%
With tert.-butylnitrite; tetrabutylammomium bromide; toluene-4-sulfonic acid; copper(ll) bromide64%
bis-[(trifluoroacetoxy)iodo]benzene
2712-78-9

bis-[(trifluoroacetoxy)iodo]benzene

A

1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

B

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With bromine In chloroform Ambient temperature;A 10%
B 89%
(4-bromophenyl)-λ3-iodanediyl diacetate
41018-52-4

(4-bromophenyl)-λ3-iodanediyl diacetate

acetone oxime
127-06-0

acetone oxime

A

2-acetoxy-2-nitrosopropane
6931-04-0

2-acetoxy-2-nitrosopropane

B

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
In acetic acid at -15℃; for 0.25h;A 88%
B n/a
1-(4-Bromophenyl)-3,3-diethyltriazene
52010-62-5

1-(4-Bromophenyl)-3,3-diethyltriazene

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With sulfonic acid resin (H+ form, Bio-Rad AG 50W-12); sodium iodide In acetonitrile at 75℃; for 0.133333h;85%
4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With N-iodo-succinimide; [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; iodine; caesium carbonate In 1,2-dichloro-ethane at 50℃; for 24h; Inert atmosphere; Irradiation; Sealed tube;85%
With 3-iodo-4,4-dimethyloxazolidin-2-one In 1,2-dichloro-ethane for 24h; Concentration; Time; Solvent; Reagent/catalyst; Reflux; Irradiation;51%
Cyclopentanone oxime
1192-28-5

Cyclopentanone oxime

(4-bromophenyl)-λ3-iodanediyl diacetate
41018-52-4

(4-bromophenyl)-λ3-iodanediyl diacetate

A

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

B

1-acetoxy-1-nitrosocyclopentane
10259-07-1

1-acetoxy-1-nitrosocyclopentane

Conditions
ConditionsYield
In acetic acid at -15℃; for 0.25h;A n/a
B 83%
iodobenzene
591-50-4

iodobenzene

A

1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

B

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With potassium bromide; sodium nitrite In water; trifluoroacetic acid at 20℃; for 2h; Product distribution; under argon, other time, other reagent;A 18%
B 82%
With oxygen; potassium bromide; potassium nitrate In water; trifluoroacetic acid at 20℃; for 8h; Product distribution;A 18%
B 82%
With lead(II,IV) oxide; trifluoroacetic acid; potassium bromide at 20℃; Product distribution;
1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
Stage #1: 1.4-dibromobenzene With tert.-butyl lithium In diethyl ether at -78℃; for 0.5h;
Stage #2: With iodine In tetrahydrofuran; diethyl ether at -78 - 20℃; for 4.75h;
82%
Stage #1: 1.4-dibromobenzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere;
Stage #2: With iodine In tetrahydrofuran; hexane at -78 - 25℃; for 1.5h; Inert atmosphere;
75%
With caesium carbonate; potassium iodide; copper(l) iodide In toluene at 110℃; for 12h;
1-(4-bromophenyl)-2-(pyrrolidin-1-yl)diazene
147227-33-6

1-(4-bromophenyl)-2-(pyrrolidin-1-yl)diazene

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With iodine In 1,2-dichloro-ethane at 80℃; for 4h;80%
bis(trifluoromethanesulfonyl)amide
82113-65-3

bis(trifluoromethanesulfonyl)amide

4-bromo-aniline
106-40-1

4-bromo-aniline

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
Stage #1: bis(trifluoromethanesulfonyl)amide With tert.-butylnitrite; acetic acid In ethanol Cooling with ice;
Stage #2: 4-bromo-aniline With tetraethylammonium iodide In water at 20℃;
80%
ethyl acetohydroximate
10576-12-2

ethyl acetohydroximate

bis(4-bromophenyl)iodonium triflate
139139-81-4

bis(4-bromophenyl)iodonium triflate

A

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

B

ethyl N-4-bromophenoxyacetimidate
1644570-70-6

ethyl N-4-bromophenoxyacetimidate

Conditions
ConditionsYield
Stage #1: ethyl acetohydroximate With sodium t-butanolate In acetonitrile at 0 - 20℃; for 0.25h;
Stage #2: bis(4-bromophenyl)iodonium triflate In acetonitrile at 20℃; for 0.5h; chemoselective reaction;
A 144 mg
B 78%
ethyl acetohydroximate
10576-12-2

ethyl acetohydroximate

bis(4-bromophenyl)iodonium triflate
139139-81-4

bis(4-bromophenyl)iodonium triflate

acetophenone
98-86-2

acetophenone

A

5-bromo-2-phenylbenzo[b]furan
13141-26-9

5-bromo-2-phenylbenzo[b]furan

B

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
Stage #1: ethyl acetohydroximate With sodium t-butanolate In acetonitrile at 0 - 20℃; for 0.25h;
Stage #2: bis(4-bromophenyl)iodonium triflate In acetonitrile at 20℃; for 0.5h;
Stage #3: acetophenone With hydrogenchloride In water; acetonitrile at 20 - 70℃; for 3.25h; Inert atmosphere; chemoselective reaction;
A 73%
B 147 mg
chloroform
67-66-3

chloroform

4,4'-dibromodiphenyliodonium chloride
53601-22-2

4,4'-dibromodiphenyliodonium chloride

A

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

B

4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium hydroxide at 50℃; for 1h; Carbonylation;A n/a
B 72%
(4-bromophenyl)zinc iodide
148651-39-2

(4-bromophenyl)zinc iodide

A

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

B

4-(4-bromophenyl)bromobenzene
92-86-4

4-(4-bromophenyl)bromobenzene

Conditions
ConditionsYield
Stage #1: (4-bromophenyl)zinc iodide With N-chloro-succinimide; tetrakis(triphenylphosphine) palladium(0) In various solvent(s) at 20℃; for 4h;
Stage #2: With iodine In various solvent(s)
A 36%
B 63%
carbon monoxide
201230-82-2

carbon monoxide

1-bromo-4-iodoxybenzene
79054-62-9

1-bromo-4-iodoxybenzene

A

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

B

4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

C

terephthalic acid
100-21-0

terephthalic acid

Conditions
ConditionsYield
With sodium tetrachloropalladate; sodium carbonate In water at 40℃; for 5h; Yields of byproduct given;A n/a
B 61%
C 15%
C7H6BrN7
93680-30-9

C7H6BrN7

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With tertamethylammonium iodide; trifluoroacetic acid In acetonitrile at 70 - 80℃;61%
potassium (4-iodophenyl)trifluoroborate

potassium (4-iodophenyl)trifluoroborate

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

Conditions
ConditionsYield
With acetic acid; lithium bromide In dimethyl sulfoxide at 100℃; for 8h; Schlenk technique;51%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

methyl 2-(tributylstannanyl)-2-propenoate
124582-37-2

methyl 2-(tributylstannanyl)-2-propenoate

methyl 2-(4-bromophenyl)acrylate

methyl 2-(4-bromophenyl)acrylate

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 20℃; Inert atmosphere;100%
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide for 24h; Ambient temperature;92%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

(4-bromophenyl)(trimethylsilyl)acetylene
16116-78-2

(4-bromophenyl)(trimethylsilyl)acetylene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 100℃; for 0.5h; Inert atmosphere;100%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran Sonogashira Cross-Coupling; Inert atmosphere;100%
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine at 0℃; Schlenk technique; Inert atmosphere;99%
carbon monoxide
201230-82-2

carbon monoxide

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

Conditions
ConditionsYield
With amphiphilic resin-supported phosphine-palladium; water; potassium carbonate at 25℃; under 760 Torr; for 12h; hydroxycarbonylation;100%
With water; potassium carbonate In acetonitrile at 100℃; under 3750.38 Torr; for 0.0161111h;93%
With water; palladium diacetate; potassium carbonate at 20℃; under 760.051 Torr; for 6h;91%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

tris-iso-propylsilyl acetylene
89343-06-6

tris-iso-propylsilyl acetylene

(2-(4-bromophenyl)ethynyl)triisopropylsilane
271242-20-7

(2-(4-bromophenyl)ethynyl)triisopropylsilane

Conditions
ConditionsYield
With copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran at 20℃; for 16h;100%
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In tetrahydrofuran at 20℃; for 16h; Sonogashira Coupling;100%
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In tetrahydrofuran at 20℃; for 16h; Sonogashira Coupling;100%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

1-butyn-4-ol
927-74-2

1-butyn-4-ol

4-(4-bromophenyl)-3-butyn-1-ol
59099-79-5

4-(4-bromophenyl)-3-butyn-1-ol

Conditions
ConditionsYield
With copper(l) iodide; triethylamine; tetrakis(triphenylphosphine) palladium(0) In dichloromethane at 50℃; Sonogashira reaction;100%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran for 4h; Inert atmosphere; Reflux;85%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide Schlenk technique;82%
acenaphthene-5-boronic acid
183158-33-0

acenaphthene-5-boronic acid

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

5-(4-bromophenyl)acenaphthene
871320-08-0

5-(4-bromophenyl)acenaphthene

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 6h; Heating / reflux;100%
4-bromo-1-ethynylbenzene
766-96-1

4-bromo-1-ethynylbenzene

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

1,2-bis(4-bromophenyl)acetylene
2789-89-1

1,2-bis(4-bromophenyl)acetylene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran Sonogashira Cross-Coupling; Inert atmosphere;100%
With C18H18N2O8PdS2(2-)*2Na(1+)*3H2O; triethylamine In water at 80℃; for 8h; Sonogashira Cross-Coupling;97%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide91%
5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)
1039027-73-0

5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-bromophenyl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)
1202170-65-7

5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-bromophenyl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); water; caesium carbonate In toluene Suzuki-Miyaura cross-coupling; Inert atmosphere; Reflux;100%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

5,10-bis[3,5-di(tert-butyl)phenyl]-15,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)
1187734-92-4

5,10-bis[3,5-di(tert-butyl)phenyl]-15,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)

5,10-bis[3,5-di(tert-butyl)phenyl]-15,20-bis(4-bromophenyl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)
1202170-64-6

5,10-bis[3,5-di(tert-butyl)phenyl]-15,20-bis(4-bromophenyl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II)

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); water; caesium carbonate In toluene Suzuki-Miyaura cross-coupling; Inert atmosphere; Reflux;100%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

4,4'-dibromodiphenyl sulfide
3393-78-0

4,4'-dibromodiphenyl sulfide

Conditions
ConditionsYield
With potassium thioacyanate; cetyltrimethylammonim bromide; potassium hydroxide In water at 135℃; for 7h; Green chemistry;100%
With copper(l) iodide; sodiumsulfide nonahydrate; potassium carbonate In N,N-dimethyl-formamide at 120℃; for 18h; Inert atmosphere; chemoselective reaction;94%
With copper(l) iodide; sodiumsulfide nonahydrate; potassium carbonate In N,N-dimethyl-formamide at 120℃; for 18h; Inert atmosphere; Darkness;94%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

C12H13BrO

C12H13BrO

C18H16Br2O

C18H16Br2O

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine In tetrahydrofuran for 16h; Sonogashira Cross-Coupling; Inert atmosphere;100%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

N-(3,3-dimethoxypropyl)hex-5-ynamide

N-(3,3-dimethoxypropyl)hex-5-ynamide

N-(3,3-dimethoxypropyl)-6-(4-bromophenyl)hex-5-ynamide

N-(3,3-dimethoxypropyl)-6-(4-bromophenyl)hex-5-ynamide

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran at 50℃; for 4h; Sonogashira Cross-Coupling; Inert atmosphere;100%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

(R)-(+)-4-methylpyrrolidin-2-one
260061-31-2

(R)-(+)-4-methylpyrrolidin-2-one

(R)-1-(4-bromophenyl)-4-methylpyrrolidin-2-one

(R)-1-(4-bromophenyl)-4-methylpyrrolidin-2-one

Conditions
ConditionsYield
With copper(l) iodide; cesium fluoride; N,N`-dimethylethylenediamine In ethyl acetate at 50℃; for 16h; Inert atmosphere;100%
4,4-dimethylpyrrolidin-2-one
66899-02-3

4,4-dimethylpyrrolidin-2-one

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

1-(4-bromophenyl)-4,4-dimethylpyrrolidin-2-one

1-(4-bromophenyl)-4,4-dimethylpyrrolidin-2-one

Conditions
ConditionsYield
With copper(l) iodide; cesium fluoride; N,N`-dimethylethylenediamine In ethyl acetate at 50℃; for 16h; Inert atmosphere;100%
(S)-(-)-4-methylpyrrolidin-2-one
31551-66-3

(S)-(-)-4-methylpyrrolidin-2-one

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

(S)-1-(4-bromophenyl)-4-methylpyrrolidin-2-one

(S)-1-(4-bromophenyl)-4-methylpyrrolidin-2-one

Conditions
ConditionsYield
With copper(l) iodide; cesium fluoride; N,N`-dimethylethylenediamine In ethyl acetate at 50℃; for 16h; Inert atmosphere;100%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

5-azaspiro[2.4]heptan-6-one

5-azaspiro[2.4]heptan-6-one

5-(4-bromophenyl)-5-azaspiro[2.4]heptan-6-one

5-(4-bromophenyl)-5-azaspiro[2.4]heptan-6-one

Conditions
ConditionsYield
With copper(l) iodide; cesium fluoride; N,N`-dimethylethylenediamine In ethyl acetate at 50℃; for 16h; Inert atmosphere;100%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

2-(5-(4-(tert-butyl)phenyl)-4-(4-chlorophenyl)-2-(4-fluorophenyl)furan-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(5-(4-(tert-butyl)phenyl)-4-(4-chlorophenyl)-2-(4-fluorophenyl)furan-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

3-(4-bromophenyl)-5-(4-(tert-butyl)phenyl)-4-(4-chlorophenyl)-2-(4-fluorophenyl)furan

3-(4-bromophenyl)-5-(4-(tert-butyl)phenyl)-4-(4-chlorophenyl)-2-(4-fluorophenyl)furan

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium hydroxide In tetrahydrofuran at 20℃; for 12h; Inert atmosphere; Schlenk technique;100%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

N-(cyclopropylmethyl)-1,1,1-trifluoromethanesulfonamide
357383-42-7

N-(cyclopropylmethyl)-1,1,1-trifluoromethanesulfonamide

N-((2-(4-bromophenyl)cyclopropyl)methyl)-1,1,1-trifluoromethanesulfonamide

N-((2-(4-bromophenyl)cyclopropyl)methyl)-1,1,1-trifluoromethanesulfonamide

Conditions
ConditionsYield
With t-Boc-L-valine; sodium 2,2,2-trifluoroacetate; palladium diacetate; silver carbonate In tert-butyl alcohol at 80℃; for 18h; Sealed tube; enantioselective reaction;99.9%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

9H-carbazole
86-74-8

9H-carbazole

N-(4-bromophenyl)carbazole
57102-42-8

N-(4-bromophenyl)carbazole

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide In 1,2-dimethoxyethane; water at 95℃; for 20h; Catalytic behavior; Solvent; Schlenk technique; Inert atmosphere; Sealed tube;99%
With copper; potassium carbonate In N,N-dimethyl-formamide at 130℃; for 42h; Inert atmosphere;96%
With copper(I) oxide; 2,2,6,6-tetramethylheptane-3,5-dione; potassium hydroxide In N,N-dimethyl-formamide at 110℃; for 24h; Inert atmosphere; Schlenk technique;95%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

propargyl alcohol
107-19-7

propargyl alcohol

3-(4-bromophenyl)prop-2-yn-1-ol
37614-58-7

3-(4-bromophenyl)prop-2-yn-1-ol

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran at 20℃;99%
Stage #1: 1,4-bromoiodobenzene With piperidine; copper(l) iodide; dichlorobis(tri-O-tolylphosphine)palladium In toluene at 20℃; for 0.0333333h; Inert atmosphere;
Stage #2: propargyl alcohol In toluene at 35℃; Sonogashira coupling; Inert atmosphere;
98%
With piperidine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In toluene at 60℃; for 2h; Inert atmosphere;95%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

phenylacetylene
536-74-3

phenylacetylene

1-bromo-4-phenylethynylbenzene
13667-12-4

1-bromo-4-phenylethynylbenzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In acetonitrile at 20℃; for 17h; Inert atmosphere;99%
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; triethylamine In acetonitrile at 20℃; Sonogashira Cross-Coupling; Inert atmosphere;99%
With triethylamine In neat (no solvent) at 20℃; for 6h; Sonogashira Cross-Coupling;97%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

C15H25BrOSiZn

C15H25BrOSiZn

(4'-Bromo-biphenyl-4-yloxy)-triisopropyl-silane

(4'-Bromo-biphenyl-4-yloxy)-triisopropyl-silane

Conditions
ConditionsYield
(4-F(13)C6-C6H4)3P; bis(dibenzylideneacetone)-palladium(0) In toluene at 60℃;99%
acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

butyl (E)-4-bromocinnamate
91911-22-7, 131061-14-8

butyl (E)-4-bromocinnamate

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II); potassium phosphate; N,N'-(1,2-ethanediylidene)bishexahydro-1H-azepin-1-amine In N,N-dimethyl-formamide at 80℃; for 6h; Mizoroki-Heck reaction;99%
With potassium carbonate In N,N-dimethyl-formamide at 85℃; for 1h; Heck Reaction;98%
With tributyl-amine In water at 90℃; for 7h; Heck Reaction;95%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With sodium carbonate In 1-methyl-pyrrolidin-2-one at 100℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere;99%
With potassium carbonate In water at 90℃; for 1h; Suzuki-Miyaura coupling; chemoselective reaction;98%
With potassium carbonate In ethanol; water at 80℃; for 0.583333h; Catalytic behavior; Suzuki-Miyaura Coupling;96%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

thiophenol
108-98-5

thiophenol

phenyl(4-bromophenyl)sulfide
65662-88-6

phenyl(4-bromophenyl)sulfide

Conditions
ConditionsYield
With (tris(3,5-dimethyl-1-pyrazolyl)methane)CuI; lithium tert-butoxide In 1,4-dioxane at 110℃; for 24h; Ullmann condensation; Inert atmosphere; chemoselective reaction;99%
With copper(l) iodide; potassium carbonate In 1-methyl-pyrrolidin-2-one at 100℃; for 16h;96%
With copper(l) iodide; 8-Hydroxyquinoline-N-oxide; caesium carbonate In dimethyl sulfoxide at 80℃; for 24h; Inert atmosphere; chemoselective reaction;96%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

hex-1-yne
693-02-7

hex-1-yne

1-bromo-4-(hex-1-yn-1-yl)benzene
190649-11-7

1-bromo-4-(hex-1-yn-1-yl)benzene

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diethylamine In N,N-dimethyl-formamide at 40℃;99%
With CuI(xantphos); caesium carbonate In N,N-dimethyl-formamide at 135℃; for 0.166667h; Sonogashira type reaction; Inert atmosphere; Microwave irradiation;78%
With copper(I) oxide; caesium carbonate In N,N-dimethyl-formamide at 135℃; for 24h; Sonogashira Cross-Coupling; Inert atmosphere;67%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

phenylboronic acid
98-80-6

phenylboronic acid

[1,1';4',1'']terphenyl
92-94-4

[1,1';4',1'']terphenyl

Conditions
ConditionsYield
With potassium carbonate In water at 50℃; for 1.5h; Suzuki Coupling;99%
With magnesium hydroxide; potassium hydroxide; barium(II) hydroxide; calcium hydroxide In water at 20℃; for 1.5h; Suzuki Coupling;99%
With sodium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 60℃; for 12h; Suzuki;98%

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