DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:589-92-4
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:589-92-4
Min.Order:1 Metric Ton
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inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
Cas:589-92-4
Min.Order:1 Kilogram
Negotiable
Type:Manufacturers
inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:589-92-4
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryOur advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
Cas:589-92-4
Min.Order:1 Kilogram
FOB Price: $9.0 / 99.0
Type:Trading Company
inquiry4-Methylcyclohexanone Basic information Product Name: 4-Methylcyclohexanone Synonyms: TETRAHYDRO-P-CRESOL;P-METHYLCYCLOHEXANONE;4-Methyl-1-cyclohexanone;4-methyl-cyclohexanon;Methyl-4 cy
Cas:589-92-4
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:589-92-4
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryWe are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED
Cas:589-92-4
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:589-92-4
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen
Cas:589-92-4
Min.Order:25 Milliliter
FOB Price: $119.7 / 239.4
Type:Trading Company
inquiry4-Methylcyclohexanone CAS:589-92-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inter
Cas:589-92-4
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:589-92-4
Min.Order:1 Kilogram
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inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:589-92-4
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiryTriumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis: Trading(Raw Mater
Cas:589-92-4
Min.Order:0 Metric Ton
FOB Price: $18.0 / 20.0
Type:Lab/Research institutions
inquiryCompany Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
Cas:589-92-4
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:589-92-4
Min.Order:0 Metric Ton
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Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:589-92-4
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryMassive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als
Cas:589-92-4
Min.Order:1 Gram
FOB Price: $1.0
Type:Lab/Research institutions
inquiryProduct name: 4-Methylcyclohexanone CAS No.:589-92-4 Molecule Formula:C7H12O Molecule Weight:112.17 Purity: 99.0% Package: 25kg/drum Description:White or off-white powder Manufacture Standards:Enterprise Standard TESTING ITEMS
Cas:589-92-4
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiry4-Methylcyclohexanone Basic information Description Product Name: 4-Methylcyclohexanone Synonyms: TETRAHYDRO-P-CRESOL;P-METHYLCYCLOHEXANONE;4-Methyl-1-cyclohexanone;4-methyl-cyclohexanon;Methyl-4 cyclohexanone-1;methyl-4cyclohexanone-1;4-METHYL
Cas:589-92-4
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:589-92-4
Min.Order:1 Kilogram
FOB Price: $18.0 / 20.0
Type:Trading Company
inquiryHangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu
Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:589-92-4
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:589-92-4
Min.Order:1 Metric Ton
FOB Price: $1.5
Type:Trading Company
inquiryWe are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:589-92-4
Min.Order:1 Metric Ton
FOB Price: $1.0
Type:Trading Company
inquiryWe produce carbomer by our own factory,carbomer 940 is our best seller.It is used for cosmetic and medical.And we also become agent for lubrizol.Our carbomer 940 get high viscosity and good transparency.The price will depond on the market,surely supp
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou
Conditions | Yield |
---|---|
With jones reagent; silica gel In dichloromethane for 0.0833333h; | 98% |
With aluminum oxide; sodium bromite In dichloromethane for 24h; Ambient temperature; | 96% |
With oxygen; benzaldehyde In chloroform at 60℃; for 6h; | 96% |
4-methylcyclohexanone oxime
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With bismuth(III) nitrate; silica gel In tetrahydrofuran; water for 2h; Heating; | 97% |
p-cresol
A
trans-4-methylcyclohexan-1-ol
B
cis-4-methylcyclohexanol
C
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With hydrogen; palladium on activated charcoal In methyl cyclohexane at 80℃; under 1125.09 Torr; Product distribution; Rate constant; other pressures, samples of Pd/C of the various sodium content; | A n/a B n/a C 88.4% |
With hydrogen; Rh/Zr zeolite beta-supported In isopropyl alcohol at 80℃; under 3750.38 Torr; for 8h; Product distribution; Further Variations:; Catalysts; Solvents; |
4-methylcyclohexanone dimethyl acetal
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate; silica gel In water for 0.0166667h; microwave irradiation; | 88% |
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate; silica gel In water for 0.05h; microwave irradiation; | 82% |
With sulfuric acid In tetrahydrofuran; water |
Conditions | Yield |
---|---|
With 5% palladium on Al2O3; hydrogen In 1,2-dichloro-ethane at 60℃; under 3750.38 Torr; for 24h; chemoselective reaction; | 81% |
With hydrogen; palladium In water at 100℃; under 750.075 Torr; for 6h; Sealed; | |
With hydrogen In dichloromethane at 50℃; under 7500.75 Torr; for 1h; |
Conditions | Yield |
---|---|
With jones' reagent In acetone at 15 - 20℃; for 0.5h; | 80% |
1,2-bis(4-methylcyclohexylidene)hydrazine
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With HOF* CH3CN In dichloromethane at 0℃; for 0.0166667h; | 80% |
p-methylcyclohexanol
A
4-methyl-2-(4-methyl-1-cyclohexenyl)cyclohexanone
B
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With bromobenzene; sodium hydride; 1,2-bis-(diphenylphosphino)ethane; palladium diacetate In N,N-dimethyl-formamide at 70℃; for 3h; Product distribution; tetrakis(triphenylphosphine)palladium, K2CO3, 110 degC, 7 h; | A 20% B 73% |
With bromobenzene; sodium hydride; palladium diacetate; 1,2-bis-(diphenylphosphino)ethane In N,N-dimethyl-formamide at 70℃; for 3h; | A 20% B 73% |
Conditions | Yield |
---|---|
With dimethyl sulfoxide; triethylamine; trichloromethyl chloroformate In dichloromethane | 71% |
With potassium dichromate; sulfuric acid | |
With chromium(VI) oxide |
4-Methylanisole
A
p-cresol
B
4-methyl-2-cyclohexenone
C
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium In tetrahydrofuran; ethanol at -30℃; for 2h; | A 41% B 50% C 4% |
cis-1-Methoxy-4-methylcyclohexane
A
5-methyloxepan-2-one
B
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With HOF* CH3CN; sodium fluoride In chloroform; water; acetonitrile Ambient temperature; | A 50% B 40% |
B
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
Stage #1: tert-butyldimethyl((4-methylcyclohex-1-en-1-yl)oxy)silane With C116H73F10N3O8P2S2 In toluene at 25℃; for 0.0833333h; Resolution of racemate; Stage #2: With 2-Biphenylcarboxylic acid In toluene at -30℃; for 20h; Resolution of racemate; | A 42% B 50% |
p-methylcyclohexanol
A
trans-4-methylcyclohexan-1-ol
B
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; dimethylsulfide; oxygen; copper(I) bromide dimethylsulfide complex; 6,6'-bis(C8F17(CH2)4)-2,2'-bipyridine In chlorobenzene at 90℃; for 1.8h; | A 49% B 45% |
methyl cyclohexane
A
1-Methylcyclohexanol
B
1-methylcyclohexan-4-one
C
3-Methylcyclohexanone
Conditions | Yield |
---|---|
With [FeCl(ind)]2O; dihydrogen peroxide In acetonitrile at 25℃; for 10h; | A 4.2% B 2.8% C 6.2% |
With C12H6N2O4(2-)*Al(3+)*HO(1-)*0.5H2O; oxygen In acetonitrile at 0 - 150℃; under 7500.75 Torr; for 4h; Autoclave; |
1-Nitrooxy-bicyclo[2.2.1]heptane
A
3-ethylcyclopentanone
B
1-norbornyl alcohol
C
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With azobisisobutyronitrile; tri-n-butyl-tin hydride In benzene for 48h; Ring cleavage; Heating; | A n/a B 3% C n/a |
4-methylcyclohexene
A
1-methylcyclohexan-4-one
B
3-Methylcyclohexanone
Conditions | Yield |
---|---|
With palladium(II) sulfate; oxygen; H3PMo6W6O40 In cyclohexane; water at 29.9℃; under 760 Torr; for 18h; Rate constant; | A 0.8% B 1.7% |
With dinitrogen monoxide at 220℃; for 5h; pressure; |
3-methyl-7-oxabicyclo[4.1.0]heptane
(+/-)-cis-3-methyl-cyclopentane-carbaldehyde-(1)
B
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With kieselguhr at 220 - 230℃; |
Conditions | Yield |
---|---|
With potassium dichromate; sulfuric acid | |
With chromium(VI) oxide | |
With oxygen; acetic acid; [Pd{N,N'-di(2,6-di-iPrC6H3)dihydroimidazol-2-yl}(OAc)2(H2O)] In toluene at 60℃; for 13h; | |
With (1,3-diarylimidazol-2-ylidene)-based Pd; oxygen; acetic acid In toluene at 60℃; for 13h; |
methoxy-1 methyl-4 cyclohexene-1
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
Hydrolysis; |
1-hydroxy-4-methyl-cyclohexanecarboxylic acid
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With sulfuric acid at -10℃; |
1-hydroxy-4-methyl-cyclohexanecarboxylic acid-(4-methyl-cyclohex-1-enyl ester)
A
1-hydroxy-4-methyl-cyclohexanecarboxylic acid
B
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With potassium hydroxide substance of mp: 82 degree; |
ethanol
1-hydroxy-4-methyl-cyclohexanecarbonitrile
A
hydrogen cyanide
B
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
at 25℃; Equilibrium constant; |
methanol
4-Methylanisole
A
4-methoxy-4-methylcyclohexan-1-one
B
4-methyl-3-cyclohexen-1-one
C
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
Yield given. Multistep reaction; |
4-Methylanisole
A
4-methyl-3-cyclohexen-1-one
B
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
1) Birch reduction, 2) acid hydrolysis; Multistep reaction; |
Conditions | Yield |
---|---|
With oxalic acid Multistep reaction; |
Conditions | Yield |
---|---|
aluminum oxide; lithium hydroxide; copper at 220℃; under 11400 Torr; for 0.3h; Product distribution; Mechanism; |
Conditions | Yield |
---|---|
With lead(IV) acetate; acetic acid; lithium chloride In benzene at 70 - 80℃; for 0.166667h; Yield given. Yields of byproduct given; | |
With lead(IV) acetate; acetic acid; lithium chloride In benzene at 70 - 80℃; for 0.166667h; Product distribution; Mechanism; percent of conversion, ratio of cis:trans isomers of alcohol after the reaction; | A 35 % Turnov. B 63 % Turnov. |
Conditions | Yield |
---|---|
Equilibrium constant; Thermodynamic data; Gas phase. Determ. by ICR spect.; |
1-methylcyclohexan-4-one
3-methyladipic acid
Conditions | Yield |
---|---|
With oxygen; trifluoroacetic acid; sodium nitrite at 0 - 20℃; for 5.25h; Product distribution / selectivity; | 100% |
With water; oxygen im Licht; | |
With potassium permanganate; sodium carbonate |
chloro-trimethyl-silane
1-methylcyclohexan-4-one
4-methyl-1-(trimethylsilyloxy)-1-cyclohexene
Conditions | Yield |
---|---|
Stage #1: 1-methylcyclohexan-4-one With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 0.5h; Stage #2: chloro-trimethyl-silane With triethylamine In tetrahydrofuran; hexane at -78 - 20℃; for 1h; | 100% |
With lithium diisopropyl amide In tetrahydrofuran 1.) -78 deg C, 1 h, 2.) room temperature, 1 h; | 96% |
With triethylamine In benzene for 72h; Heating; | 92% |
trimethylsilyl trifluoromethanesulfonate
1-methylcyclohexan-4-one
4-methyl-1-(trimethylsilyloxy)-1-cyclohexene
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; for 1.5h; | 100% |
With triethylamine In dichloromethane for 1h; |
benzaldehyde
1-methylcyclohexan-4-one
2-benzylidene-4-methylcyclohexanone
Conditions | Yield |
---|---|
sodium hydroxide In water at 97℃; for 4h; | 100% |
With sodium hydroxide In water at 100℃; | |
With CoFe2O4 nanoparticles/lamellar mesopore silica anchored to melamine nanocomposite In ethanol at 25℃; |
Conditions | Yield |
---|---|
99.6% | |
99.8% | |
53.7% | |
51.6% | |
With urea In diethylene glycol dimethyl ether; water at 150℃; under 760.051 Torr; for 24h; Schlenk technique; Inert atmosphere; | 84 %Chromat. |
1-methylcyclohexan-4-one
5-methyloxepan-2-one
Conditions | Yield |
---|---|
With acyltransferase from Mycobacterium smegmatis; dihydrogen peroxide; ethyl acetate In water at 35℃; for 60h; Baeyer-Villiger Ketone Oxidation; Enzymatic reaction; | 99% |
With oxygen; benzaldehyde In 1,2-dichloro-ethane at 20℃; for 14h; Baeyer-Villiger Ketone Oxidation; | 99% |
With N-hydroxyphthalimide; oxygen; benzaldehyde In 1,2-dichloro-ethane at 40℃; for 8h; Baeyer-Villiger Ketone Oxidation; | 99.7% |
Conditions | Yield |
---|---|
With isopropyl alcohol; zirconium(IV) oxide for 2h; Rate constant; Heating; | 99% |
With isopropyl alcohol; zirconium(IV) oxide for 2h; Heating; | 99% |
With isopropyl alcohol; 20% of binder (alumina) and 60% of a β zeolite at 80℃; for 5 - 12h; Heating / reflux; | 99.5% |
ethane-1,2-dithiol
1-methylcyclohexan-4-one
8-methyl-1,4-dithia-spiro[4.5]decane
Conditions | Yield |
---|---|
With silica gel; iron(III) chloride In dichloromethane Ambient temperature; | 99% |
sulfonated charcoal In benzene Heating; | 93% |
With silica gel; toluene-4-sulfonic acid In dichloromethane for 6h; Heating; | 87% |
With hydrogenchloride; zinc(II) chloride |
1-methylcyclohexan-4-one
phenylhydrazine
3-methyl-2,3,4,9-tetrahydro-1H-carbazole
Conditions | Yield |
---|---|
With trichloroacetic acid at 100℃; for 0.0833333h; Fischer indole synthesis; | 99% |
With potassium hydrogensulfate; silica gel for 0.0166667h; microwave irradiation; | 95% |
With 1,3-bis(3-sulfopropyl)-1H-imidazol-3-ium hydrogensulfate In water at 100℃; for 1h; Fischer indole synthesis; | 90% |
1-methylcyclohexan-4-one
ethyl (triphenylphosphoranylidene)acetate
ethyl 4-methylcyclohexylideneacetate
Conditions | Yield |
---|---|
In acetonitrile at 190℃; for 0.333333h; microwave heating; | 99% |
With (-)-trans-2,3-bis(hydroxydiphenylmethyl)-1,4-dioxaspiro<4.4>nonane(1b) at 70℃; for 4h; solid state reaction; | 73% |
In acetonitrile at 190℃; for 0.333333h; Wittig reaction; microwave irradiation; | 60% |
With (-)-trans-4,5-bis(hydroxydiphenylmethyl)-2,2-dimethyl-1,3-dioxacyclopentane(1a) at 70℃; for 4h; Product distribution; solid state reaction;other cyclohexanone; other optically active hosts; optical. induc.; | 50.8% |
at 160℃; for 4h; | 50% |
1-methylcyclohexan-4-one
4-methylcyclohexane-2,2,6,6-2H4
Conditions | Yield |
---|---|
With water-d2; sodium carbonate at 120℃; for 16h; Sealed tube; | 99% |
With water-d2; base |
triisopropylsilyl trifluoromethanesulfonate
1-methylcyclohexan-4-one
4-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; | 99% |
With triethylamine In dichloromethane for 0.5h; | 99% |
2-nitrobenzamide
1-methylcyclohexan-4-one
1'-hydroxy-4-methylspiro[cyclohexane-1,2'(1'H)-quinazolin]-4'(3'H)-one
Conditions | Yield |
---|---|
With tin(ll) chloride In ethanol; water at 20℃; for 2h; | 99% |
Conditions | Yield |
---|---|
With acetic acid; (2S)-N-phenylpyrrolidine-2-carboxamide In m-xylene at -20℃; for 24h; aldol reaction; optical yield given as %ee; enantioselective reaction; | 99% |
With C15H21NO4; water at 20℃; for 12h; asymmetric aldol reaction; optical yield given as %ee; diastereoselective reaction; | 98% |
Stage #1: 1-methylcyclohexan-4-one With (S)-N-cyclopropyl-pyrrolidine-2-carboxamide; acetic acid In m-xylene at 20℃; for 0.166667h; Stage #2: 4-nitrobenzaldehdye In m-xylene at -20℃; for 24h; optical yield given as %ee; enantioselective reaction; | 95% |
Conditions | Yield |
---|---|
With C35H47N4O6(1+)*F6P(1-); water at 20℃; for 24h; Aldol Addition; enantioselective reaction; | 99% |
With O-(n-hexanoyl)-L-serine hydrochloride; triethylamine In water at 20℃; for 30h; Aldol reaction; optical yield given as %ee; enantioselective reaction; | 90% |
With (S)-N-{(R)-1-[3-(3,5-bis(trifluoromethyl)phenyl)ureido]-2-phenylethyl}pyrrolidine-2-carboxamide; 4-nitro-benzoic acid In toluene at -20℃; for 24h; Aldol Addition; enantioselective reaction; | 90% |
3-(diethyoxyphosphorylmethyl)benzoic acid methyl ester
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
With sodium hydride In tetrahydrofuran at 20℃; for 12h; Inert atmosphere; | 99% |
5-chloro-pyridin-2-yl hydrazine
1-methylcyclohexan-4-one
Conditions | Yield |
---|---|
In ethanol for 0.5h; Reflux; | 99% |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene for 8h; Reflux; Dean-Stark; | 99% |
Conditions | Yield |
---|---|
With core-shell Fe3O4/saponin/Cd nanoparticles In ethanol at 20℃; for 0.916667h; Mannich Aminomethylation; | 99% |
1-methyl-4-nitrobenzene
p-toluidine
1-methylcyclohexan-4-one
di-p-tolylamine
Conditions | Yield |
---|---|
palladium-carbon In water; N,N-dimethyl-formamide; benzene | 98.6% |
palladium-carbon In water; N,N-dimethyl-formamide; benzene | 98.6% |
ethylene glycol
1-methylcyclohexan-4-one
8-methyl-1,4-dioxaspiro[4.5]decane.
Conditions | Yield |
---|---|
sulfonated charcoal In benzene Heating; | 98% |
With iodine at 20℃; Ionic liquid; | 94% |
With iodine for 16h; | 90% |
3-methoxy-1,5-dihydro-3H-2,4-benzodioxepine
1-methylcyclohexan-4-one
C15H20O2
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In 1,2-dimethoxyethane for 0.5h; Ambient temperature; | 98% |
Conditions | Yield |
---|---|
sulfonated charcoal In benzene Heating; | 98% |
1-methylcyclohexan-4-one
ethyl 2-cyanoacetate
2-amino-6-methyl-4,5,6,7-tetrahydro-benzo[b]thiophene-3-carboxylic acid ethyl ester
Conditions | Yield |
---|---|
With morpholine; sulfur In ethanol at 50℃; | 98% |
With morpholine; aluminum oxide; sulfur for 0.166667h; microwave irradiation; | 87% |
With morpholine; sulfur In ethanol at 85℃; for 5h; | 86.98% |
1-methylcyclohexan-4-one
1,2-diamino-benzene
4'-methyl-1,3-dihydro-2H-benzimidazole-2-spirocyclohexane
Conditions | Yield |
---|---|
In sulfolane for 2h; Heating; | 98% |
1-methylcyclohexan-4-one
(2R,4S)-4-azido-2-hydroxypentane
Conditions | Yield |
---|---|
Stage #1: 1-methylcyclohexan-4-one; (2S,4R)-2-azido-4-hydroxypentane With boron trifluoride diethyl etherate Stage #2: With potassium hydroxide | 98% |
1-methylcyclohexan-4-one
4-methylcyclohexane-1,1-diyl dihydroperoxide
Conditions | Yield |
---|---|
With dihydrogen peroxide; iodine In acetonitrile at 20℃; for 5h; | 98% |
With dihydrogen peroxide; iodine In acetonitrile at 22℃; for 5h; | 98% |
With oxygen; 9,10-phenanthrenequinone; isopropyl alcohol for 10h; visible light irradiation; | 97% |
trimethylsilyl cyanide
1-methylcyclohexan-4-one
4-methyl-1-(trimethylsiloxy)cyclohexanecarbonitrile
Conditions | Yield |
---|---|
With gold(III) chloride In dichloromethane at 20℃; for 0.5h; | 98% |
With [In2(diphenic acid)3(1,10-phenanthroline)2]·H2O at 80℃; for 1h; Schlenk technique; Inert atmosphere; | 70% |
With TBA8H2[(γ-SiYW10O36)2]*7H2O In 1,2-dichloro-ethane at 30℃; under 760.051 Torr; for 0.5h; Air atmosphere; | 97 %Chromat. |
With [In4(OH)4((hexafluoroisopropylidene)bis benzoate)4(4,4'-bipyridine)] at 80℃; for 4h; Catalytic behavior; Schlenk technique; Inert atmosphere; | > 99 %Spectr. |
With [In(iminodiacetato)Cl] In neat (no solvent) at 25℃; for 4h; Catalytic behavior; Schlenk technique; Inert atmosphere; | 97 %Chromat. |
Conditions | Yield |
---|---|
With O-(n-octanoyl)-L-threonine hydrochloride; water; triethylamine at 20℃; for 24h; optical yield given as %ee; enantioselective reaction; | 98% |
With benzyl 3,4,6-tri-O-benzyl-2-deoxy-2-(L-prolylamino)-α-D-glucopyranoside at 0℃; for 8h; Aldol Condensation; enantioselective reaction; | 97% |
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