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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Cyclohexene, 4-methyl-

Cas:591-47-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Methyl-1-cyclohexene

Cas:591-47-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU-CHEM_Cyclohexene, 4-methyl-591-47-9

Cas:591-47-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Appearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:As customer request Port:Qingda

4-METHYL-1-CYCLOHEXENE 591-47-9

Cas:591-47-9

Min.Order:1 Kilogram

FOB Price: $10.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-Methyl-1-cyclohexene

Cas:591-47-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 591-47-9 with competitive price

Cas:591-47-9

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

4-Methyl-1-cyclohexene

Cas:591-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

4-methylcyclohexene Application:4-methylcyclohexene

4-methylcyclohexene

Cas:591-47-9

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

4-methylcyclohexeneAppearance:ask Storage:keep in dry and cool condition Package:foil aluminium bag/vacuum packing Application:intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport)

4-methylcyclohexene

Cas:591-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Simson Pharma Limited

The system can just identify the products information in first sheet, it is not be permitted to add or edit new sheet by userself.Our products are required in MG to Gram only. · Pharmaceutical Reference Standards· Traceable workin

4-methyl-1-cyclohexane

Cas:591-47-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

changchun tuocai technology co.,ltld

4-methylcyclohexeneAppearance:ask Storage:keep in dry and cool condition Package:foil aluminium bag/vacuum packing Application:intermediates Transportation:by air or by sea

4-methylcyclohexene

Cas:591-47-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Minshang Biotechnology Co., Ltd

4-methylcyclohexene Application:intermediates

591-47-9

Cas:591-47-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fenjun Chemical Co Ltd.

4-methylcyclohexene Application:4-methylcyclohexene

4-methylcyclohexene

Cas:591-47-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changzhou Foreign Trade Corp

CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

4-methylcyclohexene

Cas:591-47-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Sigma-Aldrich Chemie GmbH

Package:5 g in glass bottle Application:4-Methylcyclohexene is used in the synthesis of an enantiomerically pure oxaliplatin derivative, {(1R,2R,4R)-4-Methyl-1,2-cyclohexanediamine}oxalatoplatinum(II), which exhibits good anticancer act...

4-Methylcyclohexene

Cas:591-47-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

r-5-methyl-c-2-(trimethylsilyl)cyclohexan-t-yl 2,4-dinitrobenzoate

r-5-methyl-c-2-(trimethylsilyl)cyclohexan-t-yl 2,4-dinitrobenzoate

A

4-methylcyclohexene
591-47-9

4-methylcyclohexene

B

trimethylsilyl 2,4-dinitrobenzoate

trimethylsilyl 2,4-dinitrobenzoate

2,4-Dinitro-benzoic acid (1S,2S,4S)-4-methyl-2-trimethylsilanyl-cyclohexyl ester

2,4-Dinitro-benzoic acid (1S,2S,4S)-4-methyl-2-trimethylsilanyl-cyclohexyl ester

Conditions
ConditionsYield
In chloroform-d1 for 24h; Ambient temperature;A 90%
B n/a
C 10%
In chloroform-d1 for 24h; Product distribution; Mechanism; Ambient temperature;A 90%
B n/a
C 10%
1-methyl-3,4-threo-bis(benzenesulphonyl)cyclohexane

1-methyl-3,4-threo-bis(benzenesulphonyl)cyclohexane

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
With sodium dihydrogenphosphate; sodium amalgam In methanol Ambient temperature;85%
5-(4-Methyl-cyclohexyloxy)-thianthren-5-ium; perchlorate

5-(4-Methyl-cyclohexyloxy)-thianthren-5-ium; perchlorate

A

thianthrene-5-oxide
2362-50-7

thianthrene-5-oxide

B

1-iodo-4-methylcyclohexane
66922-10-9, 66922-11-0, 65500-78-9

1-iodo-4-methylcyclohexane

C

4-methylcyclohexene
591-47-9

4-methylcyclohexene

D

Thianthrene
92-85-3

Thianthrene

Conditions
ConditionsYield
With potassium iodide In acetonitrile for 2h; Product distribution; Substitution; elimination;A 76%
B 38%
C 35%
D 23%
N,N-dimethyl-4-methylcyclohexylamine N-oxide
72390-34-2

N,N-dimethyl-4-methylcyclohexylamine N-oxide

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
In various solvent(s) at 96℃; for 4h;75%
at 96℃; for 4h; Product distribution; in cholesteric liquid crystals;75%
2,5-dihydrotoluene
4313-57-9

2,5-dihydrotoluene

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

4-methylcyclohexene
591-47-9

4-methylcyclohexene

D

methyl cyclohexane
82166-21-0

methyl cyclohexane

Conditions
ConditionsYield
With hydrogen; bis(acetylacetonate)nickel(II); triphenylphosphine In toluene at 40℃; for 8h; Yields of byproduct given;A 67%
B n/a
C n/a
D 2%
With hydrogen; bis(acetylacetonate)nickel(II); triphenylphosphine In toluene at 40℃; under 760 Torr; for 8h; Product distribution; Mechanism; different 1,4-cyclohexadienes and reaction times;A 67%
B n/a
C n/a
D 2%
5-methyl-1,3-cyclohexadiene
19656-98-5

5-methyl-1,3-cyclohexadiene

A

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

B

4-methylcyclohexene
591-47-9

4-methylcyclohexene

C

2-methylcyclohexa-1,3-diene
1489-57-2

2-methylcyclohexa-1,3-diene

D

1-methyl-1,3-cyclohexadiene
1489-56-1

1-methyl-1,3-cyclohexadiene

E

toluene
108-88-3

toluene

Conditions
ConditionsYield
rhodium(III) chloride In nitromethane; water at 45℃; for 1.33333h; Product distribution; Mechanism; variation of time; with Kat2;A n/a
B n/a
C 14.3%
D 66%
E 4.6%
p-methylcyclohexanol
589-91-3

p-methylcyclohexanol

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
With methyltriphenoxyphosphonium iodide In N,N,N,N,N,N-hexamethylphosphoric triamide at 50 - 60℃; for 2h;54%
durch Behandeln mit wasserabspaltenden Mitteln;
With phosphoric acid at 105℃;
5-(cis-4-methylcyclohexyloxy)thianthreniumyl perchlorate

5-(cis-4-methylcyclohexyloxy)thianthreniumyl perchlorate

A

thianthrene-5-oxide
2362-50-7

thianthrene-5-oxide

B

4-methylcyclohexene
591-47-9

4-methylcyclohexene

C

cis-4-methylcyclohexanol
7731-28-4

cis-4-methylcyclohexanol

D

Thianthrene
92-85-3

Thianthrene

Conditions
ConditionsYield
With potassium iodide In acetonitrile for 2h; Product distribution; Substitution; elimination;A 52%
B 52%
C 46%
D 48%
With potassium carbonate In acetonitrile for 1.33333h; Product distribution; other reaction time, temperature; effect of absence of K2CO3; other reaction conditions;A 104 % Chromat.
B 2.13 % Chromat.
C 88.4 % Chromat.
D 8.64 % Chromat.
C8H14O

C8H14O

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

A

4-methylcyclohexene
591-47-9

4-methylcyclohexene

C9H16

C9H16

Conditions
ConditionsYield
With triisopropoxytitanium(IV) chloride In diethyl ether at 20℃; Inert atmosphere; stereoselective reaction;A 40%
B 25%
C7H12Pt(Cl)4
108296-73-7

C7H12Pt(Cl)4

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

Cycloheptene
628-92-2

Cycloheptene

D

4-methylcyclohexene
591-47-9

4-methylcyclohexene

E

methylenecyclohexane
1192-37-6

methylenecyclohexane

Conditions
ConditionsYield
With potassium cyanide In diethyl ether Refluxing in ether for 1 h, evapn. of ether in vac., treating of residue with aq. KCN.; Extg. with CHCl3, NMR, MS. Further products.;A 13.6%
B 10%
C 2.8%
D 4.3%
E 9.8%
p-methylcyclohexanol
589-91-3

p-methylcyclohexanol

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
With zinc(II) chloride at 140℃;
With zinc(II) chloride at 140℃; inactive form;
p-methylcyclohexanol
589-91-3

p-methylcyclohexanol

A

1-chloro-4-methylcyclohexane
931-68-0

1-chloro-4-methylcyclohexane

B

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
With phosphorus pentachloride substance of Zelinsky;
3-methylcyclohexyl bromide
13905-48-1

3-methylcyclohexyl bromide

A

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

B

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
durch Destillation; 1-methyl-cyclohexene-(2);
With alkali 1-methyl-cyclohexene-(2);
trans-4-methylcyclohexan-1-ol
7731-29-5

trans-4-methylcyclohexan-1-ol

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
With toluene-4-sulfonic acid
4-methylcyclohexanone oxime
4994-13-2, 128925-57-5, 128925-58-6

4-methylcyclohexanone oxime

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
With hydrogen; nickel at 280℃;
cis-3-methylcyclohexanol
5454-79-5

cis-3-methylcyclohexanol

A

4-methylcyclohexene
591-47-9

4-methylcyclohexene

rac-(1S,3R)-1-chloro-3-methylcyclohexane
931-84-0, 28046-86-8, 28046-87-9

rac-(1S,3R)-1-chloro-3-methylcyclohexane

Conditions
ConditionsYield
With hydrogenchloride
phthalic acid mono-(3-methyl-cyclohexyl ester)
111499-39-9

phthalic acid mono-(3-methyl-cyclohexyl ester)

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
durch Destillation; dextrorotatory form;
dithiocarbonic acid S-ethyl ester-O-(4-methyl-cyclohexyl ester)

dithiocarbonic acid S-ethyl ester-O-(4-methyl-cyclohexyl ester)

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
at 175 - 178℃; zuletzt bei 200grad;
at 175 - 200℃;
propene
187737-37-7

propene

buta-1,3-diene
106-99-0

buta-1,3-diene

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
at 300℃; under 102971 - 106649 Torr;
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

A

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

B

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
bis(acetylacetonate)nickel(II); triphenylphosphine In toluene at 40℃; for 2.5h; Product distribution; different reaction times;
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
at 139.9℃; under 760 Torr; Equilibrium constant; Thermodynamic data; ΔrH and ΔrS;
1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

A

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

B

4-methylcyclohexene
591-47-9

4-methylcyclohexene

C

methyl cyclohexane
82166-21-0

methyl cyclohexane

D

methylenecyclohexane
1192-37-6

methylenecyclohexane

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In pentane at 17℃; for 0.0333333h; Product distribution;A n/a
B 29 % Spectr.
C 56 % Spectr.
D n/a
p-methylcyclohexanol
589-91-3

p-methylcyclohexanol

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
copper(II) sulfate In 1,1,2,2-tetrachloroethylene for 0.833333h; Heating; Yields of byproduct given;A 2 % Chromat.
B n/a
C n/a
copper(II) sulfate In 1,1,2,2-tetrachloroethylene for 0.833333h; Heating; Yield given;A 2 % Chromat.
B n/a
C n/a
aluminum oxide at 250℃;A 0.3 % Chromat.
B 0.1 % Chromat.
C 99.6 % Chromat.
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

rac-cis-3-methylcyclohexyl p-toluenesulfonate
37690-41-8

rac-cis-3-methylcyclohexyl p-toluenesulfonate

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

4-methylcyclohexene
591-47-9

4-methylcyclohexene

D

1-methylcyclohexyl trifluoroethyl ether
80764-78-9

1-methylcyclohexyl trifluoroethyl ether

trans-3-methylcyclohexyl trifluoroethyl ether
80764-82-5

trans-3-methylcyclohexyl trifluoroethyl ether

cis-3-methylcyclohexyl trifluoroethyl ether
80764-81-4

cis-3-methylcyclohexyl trifluoroethyl ether

Conditions
ConditionsYield
With pyridine at 90℃; for 0.5h; Product distribution; other fluorinated alcohols; hydride shift in cyclohexyl tosylate solvolysis;
2-Methylcyclohexanol
583-59-5

2-Methylcyclohexanol

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
copper(II) sulfate In 1,1,2,2-tetrachloroethylene for 1h; Heating; Yields of byproduct given;A 71 % Chromat.
B n/a
C n/a
magnesium oxide at 315.9℃; Mechanism; Product distribution; product distribution depends on temperature and pretreatment of catalyst(H2, or O2), further temperatures, further catalyst CaO;
copper(II) sulfate In 1,1,2,2-tetrachloroethylene for 1h; Heating; Yield given;A 71 % Chromat.
B n/a
C n/a
3-methylene-cyclohexene
1888-90-0

3-methylene-cyclohexene

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

4-methylcyclohexene
591-47-9

4-methylcyclohexene

D

methyl cyclohexane
82166-21-0

methyl cyclohexane

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In pentane at 17℃; for 0.0333333h; Product distribution;A 21 % Spectr.
B n/a
C n/a
D 60 % Spectr.
3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

4-methylcyclohexene
591-47-9

4-methylcyclohexene

C

methyl cyclohexane
82166-21-0

methyl cyclohexane

D

methylenecyclohexane
1192-37-6

methylenecyclohexane

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In pentane at 17℃; for 0.0333333h; Product distribution;A 48 % Spectr.
B n/a
C 48 % Spectr.
D n/a
Cycloheptene
628-92-2

Cycloheptene

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

1,2-dimethylcyclopentene
765-47-9

1,2-dimethylcyclopentene

C

1-ethylcyclopentene
2146-38-5

1-ethylcyclopentene

D

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

E

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
With hydrogenchloride; water In decalin at 225℃; for 49h; Product distribution; Mechanism; in sealed tube; also with DCl/D2O, deuteration investigated; also at 175 deg C;A 54.9 % Chromat.
B n/a
C n/a
D n/a
E n/a
(+/-)-trans-2-methylcyclohexanol
7443-52-9

(+/-)-trans-2-methylcyclohexanol

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
magnesium oxide at 334.9℃; Mechanism; Product distribution; product distribution depends on temperature and pretreatment of catalyst(H2, or O2), further temperatures, further catalyst CaO;
cis-2-methylcyclohexanol
7443-70-1

cis-2-methylcyclohexanol

A

1-methylcyclohex-1-ene
591-49-1

1-methylcyclohex-1-ene

B

3-methyl-1-cyclohexene
591-48-0

3-methyl-1-cyclohexene

C

4-methylcyclohexene
591-47-9

4-methylcyclohexene

Conditions
ConditionsYield
calcium oxide at 344.9℃; Mechanism; Product distribution; product distribution depends on temperature and pretreatment of catalyst(H2, or O2), further temperatures;
4-methylcyclohexene
591-47-9

4-methylcyclohexene

3-methyl-7-oxabicyclo[4.1.0]heptane
36099-51-1, 103189-46-4, 103189-47-5

3-methyl-7-oxabicyclo[4.1.0]heptane

Conditions
ConditionsYield
With oxygen; isobutyraldehyde In acetonitrile at 60℃; for 4h;100%
With disodium hydrogenphosphate; dihydrogen peroxide; Hexafluoroacetone; dibutyl ether In various solvent(s) at 20℃; for 6h;91%
With dihydrogen peroxide In dichloromethane at 0℃; for 3h;62%
(permethylcyclopentadienyl-methoxo-ruthenium)2

(permethylcyclopentadienyl-methoxo-ruthenium)2

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

4-methylcyclohexene
591-47-9

4-methylcyclohexene

η5-C5(methyl)5ruthenium(η6-toluene)OTf

η5-C5(methyl)5ruthenium(η6-toluene)OTf

Conditions
ConditionsYield
In further solvent(s) addn. of 1 equiv. of methylcyclohexene to a soln. of Ru-compd. in CF3SO3H; monitored by (1)H NMR;100%
In further solvent(s) react. of Ru-compd. with CF3SO3H in presence of methylcyclohexene; recrystn.;40-60
In dichloromethane gentle warming of react. soln. to 40°C;
4-methylcyclohexene
591-47-9

4-methylcyclohexene

methyl cyclohexane
82166-21-0

methyl cyclohexane

Conditions
ConditionsYield
With hydrogen; Rhodium chloride tri(triphenylphosphine-meta-trisulfonate) In water for 10h; Ambient temperature;95%
With hydrogen; In toluene at 109℃; effect of polymer supported catalysts on velocity;
With hydrogen; rhodium In acetone at 40℃; Rate constant; under atmospheric pressure; different types of catalysts; other solvent;
4-methylcyclohexene
591-47-9

4-methylcyclohexene

Acetic acid (1S,2S)-2-iodo-4-methyl-cyclohexyl ester

Acetic acid (1S,2S)-2-iodo-4-methyl-cyclohexyl ester

Conditions
ConditionsYield
With iodine In acetic acid Ambient temperature;91%
4-methylcyclohexene
591-47-9

4-methylcyclohexene

(1R,2R)-1-Azido-2-iodo-4-methyl-cyclohexane

(1R,2R)-1-Azido-2-iodo-4-methyl-cyclohexane

Conditions
ConditionsYield
With (polystyrene resin)-para-CH2N(CH3)3(1+)*I(N3)2(1-) for 5h;88%
phthalimide
136918-14-4

phthalimide

4-methylcyclohexene
591-47-9

4-methylcyclohexene

2-methyl-1,3,4,4a,5,11a-hexahydro-6H-dibenzo[b,e]azepine-6,11(2H)-dione

2-methyl-1,3,4,4a,5,11a-hexahydro-6H-dibenzo[b,e]azepine-6,11(2H)-dione

Conditions
ConditionsYield
With Fe(II)-meso-tetraphenylporphyrin; triethylamine In water; acetonitrile at 30℃; for 2h; Inert atmosphere; Irradiation;87.4%
Conditions
ConditionsYield
With bromine In chloroform at 0℃;A 5%
B 82%
With (C6H5NH)Br3 In dichloromethane at 25℃; for 2h; Product distribution;
4-methylcyclohexene
591-47-9

4-methylcyclohexene

(1α,2β,4α)-4-methylcyclohexane-1,2-diol
23832-27-1, 52188-67-7, 52188-68-8, 116453-29-3, 116453-30-6

(1α,2β,4α)-4-methylcyclohexane-1,2-diol

Conditions
ConditionsYield
With formic acid; dihydrogen peroxide at 20℃; for 3h;81%
With formic acid; dihydrogen peroxide26%
Multi-step reaction with 2 steps
1: 62 percent / 30percentaq. hydrogen peroxide / CH2Cl2; various solvent(s) / 3 h / 0 °C
2: 1.) AcONa, AcOH, 2.) KOH / 1.) reflux, 72 h, 2.) aq. EtOH, reflux, 3.5 h
View Scheme
Multi-step reaction with 2 steps
1: H2O2, CCl3CN, K2HPO4 / CH2Cl2
2: NaOH / H2O / Heating
View Scheme
4-methylcyclohexene
591-47-9

4-methylcyclohexene

5-methylcyclohex-2-en-1-one
7214-50-8

5-methylcyclohex-2-en-1-one

Conditions
ConditionsYield
With tert.-butylhydroperoxide; chromia-pillared montmorillonite catalyst (Cr-PILC) In 2,2,4-trimethylpentane; dichloromethane for 37h; Ambient temperature;76%
4-methylcyclohexene
591-47-9

4-methylcyclohexene

acetyl chloride
75-36-5

acetyl chloride

methyl-4 cyclohexenyl-1 methyle cetone
22273-97-8

methyl-4 cyclohexenyl-1 methyle cetone

Conditions
ConditionsYield
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction;72.6%
4-methylcyclohexene
591-47-9

4-methylcyclohexene

propionyl chloride
79-03-8

propionyl chloride

1-(4-methyl-cyclohex-1-enyl)-propan-1-one
22755-48-2

1-(4-methyl-cyclohex-1-enyl)-propan-1-one

Conditions
ConditionsYield
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction;66.4%
4-methylcyclohexene
591-47-9

4-methylcyclohexene

butyryl chloride
141-75-3

butyryl chloride

1-(4-Methyl-cyclohex-1-enyl)-butan-1-one
22755-49-3

1-(4-Methyl-cyclohex-1-enyl)-butan-1-one

Conditions
ConditionsYield
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction;54.6%
4-methylcyclohexene
591-47-9

4-methylcyclohexene

cobalt(III) acetate

cobalt(III) acetate

5-methylcyclohex-2-enyl acetate
51139-00-5, 73610-85-2, 85317-77-7

5-methylcyclohex-2-enyl acetate

Conditions
ConditionsYield
With sodium bromide In acetic acid at 49.9℃; for 24h;50%
In acetic acid at 50℃; for 24h;59 % Chromat.
4-methylcyclohexene
591-47-9

4-methylcyclohexene

A

3-methyl-7-oxabicyclo[4.1.0]heptane
36099-51-1, 103189-46-4, 103189-47-5

3-methyl-7-oxabicyclo[4.1.0]heptane

B

5-methylcyclohex-2-en-1-one
7214-50-8

5-methylcyclohex-2-en-1-one

D

Methyl-2-cyclohexen-1-ol
21592-97-2

Methyl-2-cyclohexen-1-ol

E

5-methyl-2-cyclohexen-1-ol
3718-55-6

5-methyl-2-cyclohexen-1-ol

Conditions
ConditionsYield
With 6C16H36N(1+)*2Zn(2+)*4Na(1+)*[Bi2Zn2(ZnW9O34)2](14-); urea hydrogen peroxide adduct In acetonitrile at 70℃; for 24h; Ene Reaction;A 7%
B 22%
C 49%
D 7%
E 10%
4-nitrophenyl azide
1516-60-5

4-nitrophenyl azide

4-methylcyclohexene
591-47-9

4-methylcyclohexene

A

C13H16N2O2

C13H16N2O2

B

C13H16N2O2

C13H16N2O2

C

4-nitro-aniline
100-01-6

4-nitro-aniline

Conditions
ConditionsYield
With cobalt(II) 5,10,15,20-tetraphenylporphyrin In benzene at 75℃; for 15h; Inert atmosphere;A n/a
B n/a
C 48%
4-methylcyclohexene
591-47-9

4-methylcyclohexene

n-valeryl chloride
638-29-9

n-valeryl chloride

C12H20O
1219688-24-0

C12H20O

Conditions
ConditionsYield
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction;46.5%
pentamethylcyclopentadienyltricarbonylrhenium
12130-88-0

pentamethylcyclopentadienyltricarbonylrhenium

4-methylcyclohexene
591-47-9

4-methylcyclohexene

(η5-C5Me5)Re(CO)2(η2-4-methyl-1-cyclohexene)

(η5-C5Me5)Re(CO)2(η2-4-methyl-1-cyclohexene)

Conditions
ConditionsYield
In hexane Irradiation (UV/VIS); (N2); irradiated at 0°C for 90 min; chromy.; elem. anal.;42%
In neat (no solvent) photolysis of 4-methyl-1-cyclohexene soln. containing (η5-C5Me5)Re(CO)3;
4-methylcyclohexene
591-47-9

4-methylcyclohexene

Hexanoyl chloride
142-61-0

Hexanoyl chloride

C13H22O
1219688-25-1

C13H22O

Conditions
ConditionsYield
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction;40.6%
4-methylcyclohexene
591-47-9

4-methylcyclohexene

2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester
1680-21-3

2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

(12E,18E)-15-Methyl-1,4,7,10-tetraoxa-cycloicosa-12,18-diene-11,20-dione

(12E,18E)-15-Methyl-1,4,7,10-tetraoxa-cycloicosa-12,18-diene-11,20-dione

Conditions
ConditionsYield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane for 12h; Heating;37%
4-methylcyclohexene
591-47-9

4-methylcyclohexene

Heptanoic acid chloride
2528-61-2

Heptanoic acid chloride

C14H24O
1219688-26-2

C14H24O

Conditions
ConditionsYield
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction;35.8%
4-methylcyclohexene
591-47-9

4-methylcyclohexene

cobalt(III) acetate

cobalt(III) acetate

A

4-methylcyclohex-2-enyl acetate
27227-42-5

4-methylcyclohex-2-enyl acetate

B

5-methylcyclohex-2-enyl acetate
51139-00-5, 73610-85-2, 85317-77-7

5-methylcyclohex-2-enyl acetate

Conditions
ConditionsYield
With sodium bromide In acetic acid at 49.9℃; for 1h;A 33%
B 4%

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