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Cas:591-47-9
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:591-47-9
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryOur company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
Cas:591-47-9
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryAppearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:As customer request Port:Qingda
Cas:591-47-9
Min.Order:1 Kilogram
FOB Price: $10.0
Type:Lab/Research institutions
inquiryhigh quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:591-47-9
Min.Order:1 Kilogram
FOB Price: $112.0
Type:Trading Company
inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
4-methylcyclohexeneAppearance:ask Storage:keep in dry and cool condition Package:foil aluminium bag/vacuum packing Application:intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport)
The system can just identify the products information in first sheet, it is not be permitted to add or edit new sheet by userself.Our products are required in MG to Gram only. · Pharmaceutical Reference Standards· Traceable workin
4-methylcyclohexeneAppearance:ask Storage:keep in dry and cool condition Package:foil aluminium bag/vacuum packing Application:intermediates Transportation:by air or by sea
4-methylcyclohexene Application:intermediates
CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio
Package:5 g in glass bottle Application:4-Methylcyclohexene is used in the synthesis of an enantiomerically pure oxaliplatin derivative, {(1R,2R,4R)-4-Methyl-1,2-cyclohexanediamine}oxalatoplatinum(II), which exhibits good anticancer act...
A
4-methylcyclohexene
Conditions | Yield |
---|---|
In chloroform-d1 for 24h; Ambient temperature; | A 90% B n/a C 10% |
In chloroform-d1 for 24h; Product distribution; Mechanism; Ambient temperature; | A 90% B n/a C 10% |
4-methylcyclohexene
Conditions | Yield |
---|---|
With sodium dihydrogenphosphate; sodium amalgam In methanol Ambient temperature; | 85% |
A
thianthrene-5-oxide
B
1-iodo-4-methylcyclohexane
C
4-methylcyclohexene
D
Thianthrene
Conditions | Yield |
---|---|
With potassium iodide In acetonitrile for 2h; Product distribution; Substitution; elimination; | A 76% B 38% C 35% D 23% |
N,N-dimethyl-4-methylcyclohexylamine N-oxide
4-methylcyclohexene
Conditions | Yield |
---|---|
In various solvent(s) at 96℃; for 4h; | 75% |
at 96℃; for 4h; Product distribution; in cholesteric liquid crystals; | 75% |
2,5-dihydrotoluene
A
1-methylcyclohex-1-ene
B
3-methyl-1-cyclohexene
C
4-methylcyclohexene
D
methyl cyclohexane
Conditions | Yield |
---|---|
With hydrogen; bis(acetylacetonate)nickel(II); triphenylphosphine In toluene at 40℃; for 8h; Yields of byproduct given; | A 67% B n/a C n/a D 2% |
With hydrogen; bis(acetylacetonate)nickel(II); triphenylphosphine In toluene at 40℃; under 760 Torr; for 8h; Product distribution; Mechanism; different 1,4-cyclohexadienes and reaction times; | A 67% B n/a C n/a D 2% |
5-methyl-1,3-cyclohexadiene
A
3-methyl-1-cyclohexene
B
4-methylcyclohexene
C
2-methylcyclohexa-1,3-diene
D
1-methyl-1,3-cyclohexadiene
E
toluene
Conditions | Yield |
---|---|
rhodium(III) chloride In nitromethane; water at 45℃; for 1.33333h; Product distribution; Mechanism; variation of time; with Kat2; | A n/a B n/a C 14.3% D 66% E 4.6% |
Conditions | Yield |
---|---|
With methyltriphenoxyphosphonium iodide In N,N,N,N,N,N-hexamethylphosphoric triamide at 50 - 60℃; for 2h; | 54% |
durch Behandeln mit wasserabspaltenden Mitteln; | |
With phosphoric acid at 105℃; |
A
thianthrene-5-oxide
B
4-methylcyclohexene
C
cis-4-methylcyclohexanol
D
Thianthrene
Conditions | Yield |
---|---|
With potassium iodide In acetonitrile for 2h; Product distribution; Substitution; elimination; | A 52% B 52% C 46% D 48% |
With potassium carbonate In acetonitrile for 1.33333h; Product distribution; other reaction time, temperature; effect of absence of K2CO3; other reaction conditions; | A 104 % Chromat. B 2.13 % Chromat. C 88.4 % Chromat. D 8.64 % Chromat. |
Conditions | Yield |
---|---|
With triisopropoxytitanium(IV) chloride In diethyl ether at 20℃; Inert atmosphere; stereoselective reaction; | A 40% B 25% |
C7H12Pt(Cl)4
A
1-methylcyclohex-1-ene
B
3-methyl-1-cyclohexene
C
Cycloheptene
D
4-methylcyclohexene
E
methylenecyclohexane
Conditions | Yield |
---|---|
With potassium cyanide In diethyl ether Refluxing in ether for 1 h, evapn. of ether in vac., treating of residue with aq. KCN.; Extg. with CHCl3, NMR, MS. Further products.; | A 13.6% B 10% C 2.8% D 4.3% E 9.8% |
Conditions | Yield |
---|---|
With zinc(II) chloride at 140℃; | |
With zinc(II) chloride at 140℃; inactive form; |
p-methylcyclohexanol
A
1-chloro-4-methylcyclohexane
B
4-methylcyclohexene
Conditions | Yield |
---|---|
With phosphorus pentachloride substance of Zelinsky; |
3-methylcyclohexyl bromide
A
3-methyl-1-cyclohexene
B
4-methylcyclohexene
Conditions | Yield |
---|---|
durch Destillation; 1-methyl-cyclohexene-(2); | |
With alkali 1-methyl-cyclohexene-(2); |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid |
4-methylcyclohexanone oxime
4-methylcyclohexene
Conditions | Yield |
---|---|
With hydrogen; nickel at 280℃; |
cis-3-methylcyclohexanol
A
4-methylcyclohexene
rac-(1S,3R)-1-chloro-3-methylcyclohexane
Conditions | Yield |
---|---|
With hydrogenchloride |
phthalic acid mono-(3-methyl-cyclohexyl ester)
4-methylcyclohexene
Conditions | Yield |
---|---|
durch Destillation; dextrorotatory form; |
4-methylcyclohexene
Conditions | Yield |
---|---|
at 175 - 178℃; zuletzt bei 200grad; | |
at 175 - 200℃; |
Conditions | Yield |
---|---|
at 300℃; under 102971 - 106649 Torr; |
Conditions | Yield |
---|---|
bis(acetylacetonate)nickel(II); triphenylphosphine In toluene at 40℃; for 2.5h; Product distribution; different reaction times; |
Conditions | Yield |
---|---|
at 139.9℃; under 760 Torr; Equilibrium constant; Thermodynamic data; ΔrH and ΔrS; |
1-methylcyclohex-1-ene
A
3-methyl-1-cyclohexene
B
4-methylcyclohexene
C
methyl cyclohexane
D
methylenecyclohexane
Conditions | Yield |
---|---|
With hydrogen; palladium on activated charcoal In pentane at 17℃; for 0.0333333h; Product distribution; | A n/a B 29 % Spectr. C 56 % Spectr. D n/a |
p-methylcyclohexanol
A
1-methylcyclohex-1-ene
B
3-methyl-1-cyclohexene
C
4-methylcyclohexene
Conditions | Yield |
---|---|
copper(II) sulfate In 1,1,2,2-tetrachloroethylene for 0.833333h; Heating; Yields of byproduct given; | A 2 % Chromat. B n/a C n/a |
copper(II) sulfate In 1,1,2,2-tetrachloroethylene for 0.833333h; Heating; Yield given; | A 2 % Chromat. B n/a C n/a |
aluminum oxide at 250℃; | A 0.3 % Chromat. B 0.1 % Chromat. C 99.6 % Chromat. |
2,2,2-trifluoroethanol
rac-cis-3-methylcyclohexyl p-toluenesulfonate
A
1-methylcyclohex-1-ene
B
3-methyl-1-cyclohexene
C
4-methylcyclohexene
D
1-methylcyclohexyl trifluoroethyl ether
trans-3-methylcyclohexyl trifluoroethyl ether
cis-3-methylcyclohexyl trifluoroethyl ether
Conditions | Yield |
---|---|
With pyridine at 90℃; for 0.5h; Product distribution; other fluorinated alcohols; hydride shift in cyclohexyl tosylate solvolysis; |
2-Methylcyclohexanol
A
1-methylcyclohex-1-ene
B
3-methyl-1-cyclohexene
C
4-methylcyclohexene
Conditions | Yield |
---|---|
copper(II) sulfate In 1,1,2,2-tetrachloroethylene for 1h; Heating; Yields of byproduct given; | A 71 % Chromat. B n/a C n/a |
magnesium oxide at 315.9℃; Mechanism; Product distribution; product distribution depends on temperature and pretreatment of catalyst(H2, or O2), further temperatures, further catalyst CaO; | |
copper(II) sulfate In 1,1,2,2-tetrachloroethylene for 1h; Heating; Yield given; | A 71 % Chromat. B n/a C n/a |
3-methylene-cyclohexene
A
1-methylcyclohex-1-ene
B
3-methyl-1-cyclohexene
C
4-methylcyclohexene
D
methyl cyclohexane
Conditions | Yield |
---|---|
With hydrogen; palladium on activated charcoal In pentane at 17℃; for 0.0333333h; Product distribution; | A 21 % Spectr. B n/a C n/a D 60 % Spectr. |
3-methyl-1-cyclohexene
A
1-methylcyclohex-1-ene
B
4-methylcyclohexene
C
methyl cyclohexane
D
methylenecyclohexane
Conditions | Yield |
---|---|
With hydrogen; palladium on activated charcoal In pentane at 17℃; for 0.0333333h; Product distribution; | A 48 % Spectr. B n/a C 48 % Spectr. D n/a |
Cycloheptene
A
1-methylcyclohex-1-ene
B
1,2-dimethylcyclopentene
C
1-ethylcyclopentene
D
3-methyl-1-cyclohexene
E
4-methylcyclohexene
Conditions | Yield |
---|---|
With hydrogenchloride; water In decalin at 225℃; for 49h; Product distribution; Mechanism; in sealed tube; also with DCl/D2O, deuteration investigated; also at 175 deg C; | A 54.9 % Chromat. B n/a C n/a D n/a E n/a |
(+/-)-trans-2-methylcyclohexanol
A
1-methylcyclohex-1-ene
B
3-methyl-1-cyclohexene
C
4-methylcyclohexene
Conditions | Yield |
---|---|
magnesium oxide at 334.9℃; Mechanism; Product distribution; product distribution depends on temperature and pretreatment of catalyst(H2, or O2), further temperatures, further catalyst CaO; |
cis-2-methylcyclohexanol
A
1-methylcyclohex-1-ene
B
3-methyl-1-cyclohexene
C
4-methylcyclohexene
Conditions | Yield |
---|---|
calcium oxide at 344.9℃; Mechanism; Product distribution; product distribution depends on temperature and pretreatment of catalyst(H2, or O2), further temperatures; |
4-methylcyclohexene
3-methyl-7-oxabicyclo[4.1.0]heptane
Conditions | Yield |
---|---|
With oxygen; isobutyraldehyde In acetonitrile at 60℃; for 4h; | 100% |
With disodium hydrogenphosphate; dihydrogen peroxide; Hexafluoroacetone; dibutyl ether In various solvent(s) at 20℃; for 6h; | 91% |
With dihydrogen peroxide In dichloromethane at 0℃; for 3h; | 62% |
Conditions | Yield |
---|---|
In further solvent(s) addn. of 1 equiv. of methylcyclohexene to a soln. of Ru-compd. in CF3SO3H; monitored by (1)H NMR; | 100% |
In further solvent(s) react. of Ru-compd. with CF3SO3H in presence of methylcyclohexene; recrystn.; | 40-60 |
In dichloromethane gentle warming of react. soln. to 40°C; |
4-methylcyclohexene
methyl cyclohexane
Conditions | Yield |
---|---|
With hydrogen; Rhodium chloride tri(triphenylphosphine-meta-trisulfonate) In water for 10h; Ambient temperature; | 95% |
With hydrogen; In toluene at 109℃; effect of polymer supported catalysts on velocity; | |
With hydrogen; rhodium In acetone at 40℃; Rate constant; under atmospheric pressure; different types of catalysts; other solvent; |
4-methylcyclohexene
bismuth(III) acetate
Conditions | Yield |
---|---|
With iodine In acetic acid Ambient temperature; | 91% |
4-methylcyclohexene
Conditions | Yield |
---|---|
With (polystyrene resin)-para-CH2N(CH3)3(1+)*I(N3)2(1-) for 5h; | 88% |
phthalimide
4-methylcyclohexene
Conditions | Yield |
---|---|
With Fe(II)-meso-tetraphenylporphyrin; triethylamine In water; acetonitrile at 30℃; for 2h; Inert atmosphere; Irradiation; | 87.4% |
4-methylcyclohexene
3(e),4(e)-dibromo-1(e)-methylcyclohexane
3(a),4(a)-dibromo-1(e)-methylcyclohexane
Conditions | Yield |
---|---|
With bromine In chloroform at 0℃; | A 5% B 82% |
With (C6H5NH)Br3 In dichloromethane at 25℃; for 2h; Product distribution; |
4-methylcyclohexene
(1α,2β,4α)-4-methylcyclohexane-1,2-diol
Conditions | Yield |
---|---|
With formic acid; dihydrogen peroxide at 20℃; for 3h; | 81% |
With formic acid; dihydrogen peroxide | 26% |
Multi-step reaction with 2 steps 1: 62 percent / 30percentaq. hydrogen peroxide / CH2Cl2; various solvent(s) / 3 h / 0 °C 2: 1.) AcONa, AcOH, 2.) KOH / 1.) reflux, 72 h, 2.) aq. EtOH, reflux, 3.5 h View Scheme | |
Multi-step reaction with 2 steps 1: H2O2, CCl3CN, K2HPO4 / CH2Cl2 2: NaOH / H2O / Heating View Scheme |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; chromia-pillared montmorillonite catalyst (Cr-PILC) In 2,2,4-trimethylpentane; dichloromethane for 37h; Ambient temperature; | 76% |
4-methylcyclohexene
acetyl chloride
methyl-4 cyclohexenyl-1 methyle cetone
Conditions | Yield |
---|---|
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction; | 72.6% |
4-methylcyclohexene
propionyl chloride
1-(4-methyl-cyclohex-1-enyl)-propan-1-one
Conditions | Yield |
---|---|
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction; | 66.4% |
4-methylcyclohexene
butyryl chloride
1-(4-Methyl-cyclohex-1-enyl)-butan-1-one
Conditions | Yield |
---|---|
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction; | 54.6% |
4-methylcyclohexene
5-methylcyclohex-2-enyl acetate
Conditions | Yield |
---|---|
With sodium bromide In acetic acid at 49.9℃; for 24h; | 50% |
In acetic acid at 50℃; for 24h; | 59 % Chromat. |
4-methylcyclohexene
A
3-methyl-7-oxabicyclo[4.1.0]heptane
B
5-methylcyclohex-2-en-1-one
C
4-methyl-2-cyclohexenone
D
Methyl-2-cyclohexen-1-ol
E
5-methyl-2-cyclohexen-1-ol
Conditions | Yield |
---|---|
With 6C16H36N(1+)*2Zn(2+)*4Na(1+)*[Bi2Zn2(ZnW9O34)2](14-); urea hydrogen peroxide adduct In acetonitrile at 70℃; for 24h; Ene Reaction; | A 7% B 22% C 49% D 7% E 10% |
Conditions | Yield |
---|---|
With cobalt(II) 5,10,15,20-tetraphenylporphyrin In benzene at 75℃; for 15h; Inert atmosphere; | A n/a B n/a C 48% |
Conditions | Yield |
---|---|
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction; | 46.5% |
pentamethylcyclopentadienyltricarbonylrhenium
4-methylcyclohexene
Conditions | Yield |
---|---|
In hexane Irradiation (UV/VIS); (N2); irradiated at 0°C for 90 min; chromy.; elem. anal.; | 42% |
In neat (no solvent) photolysis of 4-methyl-1-cyclohexene soln. containing (η5-C5Me5)Re(CO)3; |
Conditions | Yield |
---|---|
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction; | 40.6% |
Conditions | Yield |
---|---|
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane for 12h; Heating; | 37% |
Conditions | Yield |
---|---|
With SnCl4 on a solid carrier HNa-modernit at -10 - 0℃; regioselective reaction; | 35.8% |
4-methylcyclohexene
A
4-methylcyclohex-2-enyl acetate
B
5-methylcyclohex-2-enyl acetate
Conditions | Yield |
---|---|
With sodium bromide In acetic acid at 49.9℃; for 1h; | A 33% B 4% |
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