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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Phenyllithium

Cas:591-51-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

Phenyllithium

Cas:591-51-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Phenyllithium

Cas:591-51-5

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Phenyl lithium

Cas:591-51-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Phenyllithium

Cas:591-51-5

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 591-51-5 with competitive price

Cas:591-51-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

PhenyllithiumCAS NO.:591-51-5

Cas:591-51-5

Min.Order:1 Gram

FOB Price: $4.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Lithium, phenyl-

Cas:591-51-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Phenyllithium 99%

Cas:591-51-5

Min.Order:1 Kilogram

FOB Price: $84.0 / 98.0

Type:Trading Company

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Lithium, phenyl-

Cas:591-51-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

LITHIUMPHENYL

Cas:591-51-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Lithium, phenyl-

Cas:591-51-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Phenyllithium

Cas:591-51-5

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:dark brown to black solution Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates Tran

Phenyllithium

Cas:591-51-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: Phenyl-Lithium CAS No.:591-51-5 Molecule Formula:C6H5Li Molecule Weight:84.04 Purity: 98.0% Package: 50kg/drum Description:Red brown or black transparent liquid Manufacture Standards:Enterprise Standard

High Quality Phenyl-Lithium on hot selling

Cas:591-51-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Phenyllithium Chemical Properties Melting point 160-163 °C(Solv: benzene (71-43-2)) Boiling point 140-143 °C density 0.835 g/mL at 25 °C Fp 20 °C storage temp. 2-8°C solubility Miscible with ether and hydro

Phenyllithium

Cas:591-51-5

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Phenyllithium

Cas:591-51-5

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

591-51-5 CAS NO.591-51-5

Cas:591-51-5

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

Phenyllithium

Cas:591-51-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Phenyllithium solution, 1.9M in di-n-butyl ether

Cas:591-51-5

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Phenyllithium

Cas:591-51-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

phenyllithium

Cas:591-51-5

Min.Order:0

Negotiable

Type:Other

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

Phenyllithium

Cas:591-51-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Lithium, phenyl-

Cas:591-51-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

Phenyllithium

Cas:591-51-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Lithium, phenyl-

Cas:591-51-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:White to Off-White Solid Storage:Keep it in dry,shady and cool place Package:as your requirement Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by Sea

Phenyllithium

Cas:591-51-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

DB BIOTECH CO., LTD

best seller Application:API

Phenyllithium

Cas:591-51-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:light beige powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as pri

Phenyllithium

Cas:591-51-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

591-51-5

Cas:591-51-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

bromobenzene
108-86-1

bromobenzene

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
With lithium In diethyl ether ultrasonic agitation;95%
In dibutyl ether at 10 - 30℃; Reagent/catalyst; Temperature; Inert atmosphere; Large scale;80%
With diethyl ether; lithium man erhitzt schliesslich unter Zugabe von Aether zum Sieden;
N,N'-bis(2,6-diisopropylphenyl)-2-bromo-2,3-dihydro-1H-1,3,2-diazaborole
915703-81-0

N,N'-bis(2,6-diisopropylphenyl)-2-bromo-2,3-dihydro-1H-1,3,2-diazaborole

tert-butylamine
75-64-9

tert-butylamine

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
In benzene at 80℃; for 16h; Inert atmosphere; Glovebox; Schlenk technique;84%
diphenylmercury(II)
587-85-9

diphenylmercury(II)

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
With lithium In diethyl ether Inert atmosphere; Schlenk technique;74%
With lithium; benzene
triphenylbismuthane
603-33-8

triphenylbismuthane

lithium
7439-93-2

lithium

A

bismuth
7440-69-9

bismuth

B

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
In diethyl ether 20°C;A n/a
B 22%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

bromobenzene
108-86-1

bromobenzene

diethyl ether
60-29-7

diethyl ether

phenyllithium
591-51-5

phenyllithium

n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

diethyl ether
60-29-7

diethyl ether

hexaphenyl diplumbane
3124-01-4

hexaphenyl diplumbane

A

hexabutyldiplumbum
27980-18-3

hexabutyldiplumbum

B

phenyllithium
591-51-5

phenyllithium

n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

diethyl ether
60-29-7

diethyl ether

diphenylmagnesium
555-54-4

diphenylmagnesium

A

dibutylmagnesium
1191-47-5

dibutylmagnesium

B

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
reversible Reaktion;
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

diphenylselenide
1132-39-4

diphenylselenide

A

butyl phenyl selenide
28622-61-9

butyl phenyl selenide

B

Benzeneselenol
645-96-5

Benzeneselenol

C

phenyllithium
591-51-5

phenyllithium

diethyl ether
60-29-7

diethyl ether

methyllithium
917-54-4

methyllithium

Tetraphenyllead
595-89-1

Tetraphenyllead

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
analoge Umsetzungen erfolgen mit Tetrakis-<4-chlor-phenyl>-zinn und mit Dibenzylquecksilber;
ethyllithium
811-49-4

ethyllithium

triphenylantimony
603-36-1

triphenylantimony

phenyllithium
591-51-5

phenyllithium

ethyllithium
811-49-4

ethyllithium

diphenylmercury(II)
587-85-9

diphenylmercury(II)

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
With benzene
ethyllithium
811-49-4

ethyllithium

diphenylmercury(II)
587-85-9

diphenylmercury(II)

A

diethylmercury
627-44-1

diethylmercury

B

phenyllithium
591-51-5

phenyllithium

n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

diethyl ether
60-29-7

diethyl ether

tetraphenyltin(IV)
595-90-4

tetraphenyltin(IV)

benzene
71-43-2

benzene

A

tetra-n-butyltin(IV)
1461-25-2

tetra-n-butyltin(IV)

B

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
anal.R.mit Tetrakis-<4-chlor-phenyl>-zinn, Tetraphenylblei, Diphenyl-di-p-tolyl-blei, Tetra-p-tolyl-blei, Triphenylblei und Tri-p-tolyl-blei;
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

diethyl ether
60-29-7

diethyl ether

Tetraphenyllead
595-89-1

Tetraphenyllead

benzene
71-43-2

benzene

A

tetra-n-butyl lead
1920-90-7

tetra-n-butyl lead

B

phenyllithium
591-51-5

phenyllithium

iodobenzene
591-50-4

iodobenzene

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
With n-butyllithium In benzene for 0.333333h; Ambient temperature;
With n-butyllithium In pentane Ambient temperature;
With tert.-butyl lithium In diethyl ether -78 deg C, 0.5 h; RT, 1 h;
triphenyl-arsane
603-32-7

triphenyl-arsane

(14C)-Phenyllithium

(14C)-Phenyllithium

A

phenyllithium
591-51-5

phenyllithium

B

(14)C18H15As

(14)C18H15As

Conditions
ConditionsYield
In tetrahydrofuran; benzene at 24.9℃; Rate constant; Kinetics; Thermodynamic data; var. solvents; E, ΔH(excit.), ΔS(excit.), ΔG(excit.);
1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

A

phenyllithium
591-51-5

phenyllithium

B

1,3-bis(lithiumphenylphosphido)propane
60778-68-9

1,3-bis(lithiumphenylphosphido)propane

Conditions
ConditionsYield
With lithium In tetrahydrofuran
1,5-bis-(diphenylphosphino)pentane
27721-02-4

1,5-bis-(diphenylphosphino)pentane

A

phenyllithium
591-51-5

phenyllithium

B

1,5-Bis--pentamethylen
115241-59-3

1,5-Bis--pentamethylen

Conditions
ConditionsYield
With lithium In tetrahydrofuran
C12H10I(1-)*Li(1+)
120416-98-0

C12H10I(1-)*Li(1+)

A

iodobenzene
591-50-4

iodobenzene

B

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
With 1-iodo-butane In tetrahydrofuran at -78℃; Equilibrium constant; solvent effect;
bicyclo<1.1.1>pentyl phenyl sulfide
98585-81-0

bicyclo<1.1.1>pentyl phenyl sulfide

A

lithium thiophenoxide
2973-86-6

lithium thiophenoxide

B

C5H7Li
117632-98-1

C5H7Li

C

Lithium; bicyclo[1.1.1]pentane-1-thiolate
117633-17-7

Lithium; bicyclo[1.1.1]pentane-1-thiolate

D

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
With 4,4'-di-tert-butylbiphenyl; lithium at -60℃;
1,2-diphenyl-3,4-di-t-butyldiphosphete
75600-54-3, 96693-29-7

1,2-diphenyl-3,4-di-t-butyldiphosphete

A

phenyllithium
591-51-5

phenyllithium

B

(2-phenyl-3,4-di-tert-butyl-1,2-diphosphetenyl)lithium
96693-31-1

(2-phenyl-3,4-di-tert-butyl-1,2-diphosphetenyl)lithium

Conditions
ConditionsYield
With lithium In tetrahydrofuran Product distribution; Ambient temperature;
chlorobenzene
108-90-7

chlorobenzene

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
With naphthalene; lithium In tetrahydrofuran at -78℃; for 0.75h; various react. cond.; diff. chloroarenes; further reaction with electrophiles;
With lithium; lithium hydride; biphenyl In dibutyl ether at 35℃; for 6h;
With lithium In tetrahydrofuran at -25℃;
1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

A

phenyllithium
591-51-5

phenyllithium

B

1,4-Bis--tetramethylen
115241-57-1

1,4-Bis--tetramethylen

Conditions
ConditionsYield
With lithium In tetrahydrofuran
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

diphenylmercury(II)
587-85-9

diphenylmercury(II)

benzene
71-43-2

benzene

petroleum ether

petroleum ether

phenyllithium
591-51-5

phenyllithium

n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

bromobenzene
108-86-1

bromobenzene

petroleum ether

petroleum ether

phenyllithium
591-51-5

phenyllithium

n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

diethyl ether
60-29-7

diethyl ether

diphenyl-bis-<4-chloro-phenyl>-lead

diphenyl-bis-<4-chloro-phenyl>-lead

A

4-chlorophenyl lithium
14774-78-8

4-chlorophenyl lithium

B

phenyllithium
591-51-5

phenyllithium

n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

diethyl ether
60-29-7

diethyl ether

triphenyl-<4-chloro-phenyl>-lead

triphenyl-<4-chloro-phenyl>-lead

A

4-chlorophenyl lithium
14774-78-8

4-chlorophenyl lithium

B

phenyllithium
591-51-5

phenyllithium

tert.-butyl lithium
594-19-4

tert.-butyl lithium

diphenylmercury(II)
587-85-9

diphenylmercury(II)

benzene
71-43-2

benzene

petroleum ether

petroleum ether

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
mit Dibenzylquecksilber erfolgt eine analoge Umsetzung;
fluorobenzene
462-06-6

fluorobenzene

phenyllithium
591-51-5

phenyllithium

Conditions
ConditionsYield
With naphthalene; lithium In tetrahydrofuran at -30℃; for 0.583333h; lithiation;
phenyllithium
591-51-5

phenyllithium

S-Phenyldibenzothiophenium

S-Phenyldibenzothiophenium

phenyl o-terphenyl sulfide
34884-36-1

phenyl o-terphenyl sulfide

Conditions
ConditionsYield
Mechanism; 1.) THF, cyclohexane, ether, -100 deg C, 2.) THF, cyclohexane, ether, room temp.;100%
Stage #1: phenyllithium With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: S-Phenyldibenzothiophenium In tetrahydrofuran; hexane at -78 - 23℃; for 1.5h; Inert atmosphere;
100%
In tetrahydrofuran
phenyllithium
591-51-5

phenyllithium

3-(4,5-dihydro-4,4-dimethyl-2-oxazolyl)pyridine
68981-86-2

3-(4,5-dihydro-4,4-dimethyl-2-oxazolyl)pyridine

3-(4,5-dihydro-4,4-dimethyl-2-oxazolyl)-1,4-dihydro-4-phenylpyridine
68981-78-2

3-(4,5-dihydro-4,4-dimethyl-2-oxazolyl)-1,4-dihydro-4-phenylpyridine

Conditions
ConditionsYield
In tetrahydrofuran 1.) -78 deg C, 1 h, 2.) 0 deg C, 1 h;100%
In tetrahydrofuran at -78℃; for 0.166667h;82%
In diethyl ether for 1h; Ambient temperature;78.6%
2-Methylbenzothiazole
120-75-2

2-Methylbenzothiazole

phenyllithium
591-51-5

phenyllithium

(2-Benzothiazolyl)methyllithium
125414-91-7

(2-Benzothiazolyl)methyllithium

Conditions
ConditionsYield
In diethyl ether; benzene at -78℃;100%
(E)-3-phenylpropenal
14371-10-9

(E)-3-phenylpropenal

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

phenyllithium
591-51-5

phenyllithium

(E)-1,3-diphenyl-1-trimethylsilyloxy-2-propene
94740-99-5

(E)-1,3-diphenyl-1-trimethylsilyloxy-2-propene

Conditions
ConditionsYield
Stage #1: (E)-3-phenylpropenal; phenyllithium In tetrahydrofuran at -78℃; for 0.25h;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran Further stages.;
100%
1) THF, -20 deg C, 15 min; 2) THF, RT, 12 h; Yield given. Multistep reaction;
(3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one
13096-62-3

(3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one

phenyllithium
591-51-5

phenyllithium

(2,3,4,6-tetra-O-benzyl-1-C-phenyl)-D-glucopyranose
118436-89-8, 118436-90-1

(2,3,4,6-tetra-O-benzyl-1-C-phenyl)-D-glucopyranose

Conditions
ConditionsYield
at -78℃;100%
In tetrahydrofuran 1.) -78 deg C, 2 h, 2.) from -78 deg C to room temperature, 2 h;85.7%
In tetrahydrofuran at -78℃;
1,4,5,6,7,7a-hexahydro-inden-2-one
39163-29-6, 117780-10-6

1,4,5,6,7,7a-hexahydro-inden-2-one

phenyllithium
591-51-5

phenyllithium

2-phenyl-2,4,5,6,7,7a-hexahydro-1H-inden-2-ol
536976-47-3

2-phenyl-2,4,5,6,7,7a-hexahydro-1H-inden-2-ol

Conditions
ConditionsYield
In diethyl ether; cyclohexane at 0 - 20℃; for 2h;100%
With cerium(III) chloride 1.) THF, -20 deg C, 0.5 h, 2.) THF, from -78 deg C to RT; Multistep reaction;
2-Methyl-2-(tert-butylperoxy)cyclohexanon
25462-04-8

2-Methyl-2-(tert-butylperoxy)cyclohexanon

phenyllithium
591-51-5

phenyllithium

2-tert-Butylperoxy-2-methyl-1-phenyl-cyclohexanol
109139-15-3, 109139-16-4

2-tert-Butylperoxy-2-methyl-1-phenyl-cyclohexanol

Conditions
ConditionsYield
In diethyl ether at -78℃; for 0.666667h;100%
1,4-diiodocubane
97229-08-8

1,4-diiodocubane

phenyllithium
591-51-5

phenyllithium

1-iodo-4-phenylcubane
124225-33-8

1-iodo-4-phenylcubane

Conditions
ConditionsYield
In diethyl ether; cyclohexane for 1h; Ambient temperature;100%
In diethyl ether; pentane for 0.666667h; Ambient temperature;88%
In diethyl ether Ambient temperature;
dodec-1-en-2-yl triflate
103885-03-6

dodec-1-en-2-yl triflate

phenyllithium
591-51-5

phenyllithium

1-methyleneundecylbenzene
115146-99-1

1-methyleneundecylbenzene

Conditions
ConditionsYield
With manganese chloride bis(lithium chloride) In tetrahydrofuran; diethyl ether at 25℃; for 1h;100%
2,2,5,5-Tetramethyl-3,6-diphenyl-2,5-dihydro-pyrazine 1,4-dioxide
132402-19-8

2,2,5,5-Tetramethyl-3,6-diphenyl-2,5-dihydro-pyrazine 1,4-dioxide

phenyllithium
591-51-5

phenyllithium

1,4-dihydroxy-3,3,6,6-tetramethyl-2,2,5,5-tetraphenyl-piperazine

1,4-dihydroxy-3,3,6,6-tetramethyl-2,2,5,5-tetraphenyl-piperazine

Conditions
ConditionsYield
at 20℃; for 3h;100%
at 20℃; for 3h; PhLi excess; Yield given;
C26H24O2S
136964-79-9

C26H24O2S

phenyllithium
591-51-5

phenyllithium

C28H20
99222-19-2

C28H20

Conditions
ConditionsYield
In tetrahydrofuran at 0℃;100%
trans-1-iodo-2-isothiocyanatocyclohexane
60211-89-4, 63616-13-7, 93424-19-2

trans-1-iodo-2-isothiocyanatocyclohexane

phenyllithium
591-51-5

phenyllithium

N-(trans-2-iodocyclohexyl)thiobenzamide
77469-36-4

N-(trans-2-iodocyclohexyl)thiobenzamide

Conditions
ConditionsYield
In diethyl ether at -78℃; for 0.416667h;100%
2-(dimethoxymethyl)-1-naphthaldehyde
103668-60-6

2-(dimethoxymethyl)-1-naphthaldehyde

phenyllithium
591-51-5

phenyllithium

2-(dimethoxymethyl)-α-phenyl-1-naphthalenemethanol
114469-02-2

2-(dimethoxymethyl)-α-phenyl-1-naphthalenemethanol

Conditions
ConditionsYield
In diethyl ether; hexane at -78 - 0℃; for 3.25h;100%
phenyllithium
591-51-5

phenyllithium

3-Methyl-1-oxa-5-sila-spiro[4.4]nonane
139017-06-4

3-Methyl-1-oxa-5-sila-spiro[4.4]nonane

2-Methyl-3-(1-phenyl-silolan-1-yl)-propan-1-ol
139017-23-5

2-Methyl-3-(1-phenyl-silolan-1-yl)-propan-1-ol

Conditions
ConditionsYield
In diethyl ether; cyclohexane for 1h; Ambient temperature;100%
phenyllithium
591-51-5

phenyllithium

(1S*,2R*,7S*,8R*,11S*)-11-Carbomethoxy-3,3-dimethyltricyclo<5.3.1.02,8>undecane
144534-06-5

(1S*,2R*,7S*,8R*,11S*)-11-Carbomethoxy-3,3-dimethyltricyclo<5.3.1.02,8>undecane

(1S*,2R*,7S*,8R*,11S*)-3,3-Dimethyl-11-(diphenylhydroxymethyl)-tricyclo<5.3.1.02,8>undecane
144534-08-7

(1S*,2R*,7S*,8R*,11S*)-3,3-Dimethyl-11-(diphenylhydroxymethyl)-tricyclo<5.3.1.02,8>undecane

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether 1) rt, 1.5 h, 2) reflux, 3 h;100%
phenyllithium
591-51-5

phenyllithium

(4S)-3-benzyl-2-oxo-oxazolidine-4-carboxylic acid methyl ester
157823-76-2

(4S)-3-benzyl-2-oxo-oxazolidine-4-carboxylic acid methyl ester

(S)-4-Benzoyl-3-benzyl-oxazolidin-2-one
157823-78-4

(S)-4-Benzoyl-3-benzyl-oxazolidin-2-one

Conditions
ConditionsYield
In tetrahydrofuran at -78℃; for 0.5h;100%
phenyllithium
591-51-5

phenyllithium

4,4-dimethyl-2,5-diphenyl-4H-imidazole 1-oxide
38870-61-0

4,4-dimethyl-2,5-diphenyl-4H-imidazole 1-oxide

1-hydroxy-2,5,5-triphenyl-4,4-dimethyl-2-imidazoline
155126-64-0

1-hydroxy-2,5,5-triphenyl-4,4-dimethyl-2-imidazoline

Conditions
ConditionsYield
In diethyl ether for 0.25h;100%
In diethyl ether for 0.25h; Yield given;
phenyllithium
591-51-5

phenyllithium

bromoacetaldehyde
17157-48-1

bromoacetaldehyde

2-Bromo-1-phenylethanol
2425-28-7

2-Bromo-1-phenylethanol

Conditions
ConditionsYield
at -78℃; for 0.25h;100%
phenyllithium
591-51-5

phenyllithium

5-Phenyl-dibenzoselenophenium; bromide

5-Phenyl-dibenzoselenophenium; bromide

phenyl o-terphenyl selenide
136004-59-6

phenyl o-terphenyl selenide

Conditions
ConditionsYield
Mechanism; 1.) THF, cyclohexane, ether, -78 deg C, 2.) THF, cyclohexane, ether, room temp.;100%
phenyllithium
591-51-5

phenyllithium

(2S)-5-oxo-1-(9'-phenylfluoren-9'-yl)pyrrolidine-2-carboxylic acid methyl ester
185121-30-6

(2S)-5-oxo-1-(9'-phenylfluoren-9'-yl)pyrrolidine-2-carboxylic acid methyl ester

(5S)-5-benzoyl-1-(9'-phenylfluoren-9'-yl)pyrrolidin-2-one

(5S)-5-benzoyl-1-(9'-phenylfluoren-9'-yl)pyrrolidin-2-one

Conditions
ConditionsYield
In tetrahydrofuran at -78℃; for 1h;100%
phenyllithium
591-51-5

phenyllithium

diphenyl(phenylethynyl)selenium trifluoromethanesulfonate

diphenyl(phenylethynyl)selenium trifluoromethanesulfonate

A

1,4-diphenyl-1,3-butadiyne
886-66-8

1,4-diphenyl-1,3-butadiyne

B

diphenylselenide
1132-39-4

diphenylselenide

C

2-(phenylethynyl)-1,1'-biphenyl
10271-65-5

2-(phenylethynyl)-1,1'-biphenyl

D

phenylacetylene
536-74-3

phenylacetylene

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether; cyclohexane at 20℃; for 3h; Substitution; Further byproducts given;A 2%
B 100%
C 4%
D 60%
(E)-3-phenylpropenal
14371-10-9

(E)-3-phenylpropenal

phenyllithium
591-51-5

phenyllithium

isopropyl bromide
75-26-3

isopropyl bromide

(+/-)-4-methyl-1,3-diphenylpentan-1-one
85267-90-9

(+/-)-4-methyl-1,3-diphenylpentan-1-one

Conditions
ConditionsYield
Stage #1: (E)-3-phenylpropenal; phenyllithium In tetrahydrofuran at 20℃; for 7h;
Stage #2: isopropyl bromide In tetrahydrofuran Further stages.;
100%
Stage #1: (E)-3-phenylpropenal; phenyllithium In tetrahydrofuran at 20℃; for 7h; Addition;
Stage #2: isopropyl bromide In tetrahydrofuran at 20℃; Alkylation;
100 % Chromat.
2,3,7,8,12,13,17,18-octaethyl-porphyrin
2683-82-1

2,3,7,8,12,13,17,18-octaethyl-porphyrin

phenyllithium
591-51-5

phenyllithium

2,3,7,8,12,13,17,18-octaethyl-5-phenylporphyrine
60188-33-2

2,3,7,8,12,13,17,18-octaethyl-5-phenylporphyrine

Conditions
ConditionsYield
Stage #1: 2,3,7,8,12,13,17,18-octaethyl-porphyrin; phenyllithium In tetrahydrofuran; cyclohexane at 40℃; for 0.25h; Addition;
Stage #2: With water In tetrahydrofuran; cyclohexane Hydrolysis;
Stage #3: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran; dichloromethane; cyclohexane for 0.0833333h; Oxidation; Further stages.;
100%
Stage #1: 2,3,7,8,12,13,17,18-octaethyl-porphyrin; phenyllithium In tetrahydrofuran at -40 - 20℃;
Stage #2: With water In tetrahydrofuran
Stage #3: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran Further stages.;
100%
(E)-3-phenylpropenal
14371-10-9

(E)-3-phenylpropenal

[(E)-2-bromoethenyl]benzene
588-72-7

[(E)-2-bromoethenyl]benzene

phenyllithium
591-51-5

phenyllithium

trans-1,3,5-triphenylpent-4-en-1-one
251635-75-3

trans-1,3,5-triphenylpent-4-en-1-one

Conditions
ConditionsYield
Stage #1: (E)-3-phenylpropenal; phenyllithium In tetrahydrofuran at 20℃; for 7h;
Stage #2: [(E)-2-bromoethenyl]benzene In tetrahydrofuran Further stages.;
100%
(1E,2E)-N,3-diphenylprop-2-en-1-imine
953-21-9

(1E,2E)-N,3-diphenylprop-2-en-1-imine

phenyllithium
591-51-5

phenyllithium

(E)-N-(1,3-diphenylallyl)aniline

(E)-N-(1,3-diphenylallyl)aniline

Conditions
ConditionsYield
Stage #1: (1E,2E)-N,3-diphenylprop-2-en-1-imine; phenyllithium In tetrahydrofuran; diethyl ether at -78℃;
Stage #2: With water; ammonium chloride In tetrahydrofuran; diethyl ether
100%
Stage #1: (1E,2E)-N,3-diphenylprop-2-en-1-imine; phenyllithium In tetrahydrofuran at -45℃; for 1h;
Stage #2: With oxonium In tetrahydrofuran Further stages.;
92%
bicyclo<5.3.0>-dec-1(10)-en-9-one
61154-46-9

bicyclo<5.3.0>-dec-1(10)-en-9-one

phenyllithium
591-51-5

phenyllithium

2-phenyl-1,2,4,5,6,7,8,8a-octahydroazulen-2-ol
536976-48-4

2-phenyl-1,2,4,5,6,7,8,8a-octahydroazulen-2-ol

Conditions
ConditionsYield
In diethyl ether; cyclohexane at 0 - 20℃; for 2h;100%
phenyllithium
591-51-5

phenyllithium

1,4,5,6,7,8,9,9a-octahydro-2H-cyclopenta[8]annulen-2-one
225650-45-3

1,4,5,6,7,8,9,9a-octahydro-2H-cyclopenta[8]annulen-2-one

2-phenyl-2,4,5,6,7,8,9,9a-octahydro-1H-cyclopenta[8]annulen-2-ol
536976-49-5

2-phenyl-2,4,5,6,7,8,9,9a-octahydro-1H-cyclopenta[8]annulen-2-ol

Conditions
ConditionsYield
In diethyl ether; cyclohexane at 0 - 20℃; for 2h;100%
2-(methylsulfanyl)pyrimidine
823-09-6

2-(methylsulfanyl)pyrimidine

phenyllithium
591-51-5

phenyllithium

2-(methylsulfanyl)-4-phenylpyrimidine
56734-10-2

2-(methylsulfanyl)-4-phenylpyrimidine

Conditions
ConditionsYield
Stage #1: 2-(methylsulfanyl)pyrimidine; phenyllithium In tetrahydrofuran at 0℃; for 2h;
Stage #2: With acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran at 20℃; for 0.75h;
100%
2-(methylsulfanyl)-4-phenylpyrimidine
56734-10-2

2-(methylsulfanyl)-4-phenylpyrimidine

phenyllithium
591-51-5

phenyllithium

2-(methylsulfanyl)-4,6-diphenylpyrimidine
59807-21-5

2-(methylsulfanyl)-4,6-diphenylpyrimidine

Conditions
ConditionsYield
Stage #1: 2-(methylsulfanyl)-4-phenylpyrimidine; phenyllithium In tetrahydrofuran at 20℃; for 4h;
Stage #2: With acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran at 20℃; for 0.75h;
100%
1-Bromoanthraquinone
632-83-7

1-Bromoanthraquinone

phenyllithium
591-51-5

phenyllithium

1-bromo-9,10-diphenyl-9,10-dihydroanthracene-9,10-diol
955123-64-5

1-bromo-9,10-diphenyl-9,10-dihydroanthracene-9,10-diol

Conditions
ConditionsYield
In tetrahydrofuran; dibutyl ether at 20℃; for 24h;100%

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