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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.

purchase High purity and quality T1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:100 Gram

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Type:Manufacturers

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis 1. Beijing High-Tech Enterprises 2. Strong R&D Team 3. 8 years of experiences in R & D of high-tech Catalyst; 4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on

1,4-Bis(diphenylphosphino)butane,DPPB

Cas:7688-25-7

Min.Order:1 Gram

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Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1,4-Bis(Diphenylphosphino)Butane supplier in China

Cas:7688-25-7

Min.Order:1 Metric Ton

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Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

chengdu and import and export trade co., LTD., who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do res

1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:10 Kilogram

FOB Price: $120.0

Type:Manufacturers

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Hefei TNJ chemical industry co.,ltd

1. Quality Our products meet MSDS safe standard and we have ISO and other certificate so yan can get high quality products from our company. 2. Price We are the company which is the joint of trade and industry so we cao provide the competiti

1,4-Bis(diphenylphosphino)butane/CAS 7688-25-7

Cas:7688-25-7

Min.Order:25 Kilogram

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Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high purity Storage:Sealed, dry, microtherm , avoid light and smell. Package:meet customer's demand Application:organic synthesis Transportation:by sea or by air Port:Shanghai, Qingdao

1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 7688-25-7 1,4-Bis(diphenylphosphino)butane Manufacturer

Cas:7688-25-7

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,4-Bis-(diphenylphosphino)-butane

Cas:7688-25-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Product Name: 1,4-Bis(diphenylphosphino)butane Synonyms: DPPB;Butane-1,4-diylbis[diphenylphosphine];1,4-BIS(DIPHENYLPHOSPHINE)BUTANE;1,4-BIS(DIPHENYLPHOSPHINO)BUTANE;TETRAMETHYLENEBIS(DIPHENYLPHOSPHINE);[4-

1,4-Bis(diphenylphosphino)butane_

Cas:7688-25-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 7688-25-7 with best quality

Cas:7688-25-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Items Technical index Product name 1,4-Bis(diphenylphosphino)butane CAS No 7688-25-7 Molecular formula

1,4-Bis(diphenylphosphino)butane CAS 7688-25-7

Cas:7688-25-7

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,4-Bis(diphenylphosphino)butane 7688-25-7

Cas:7688-25-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pharmaceutical Intermediate, 1,4-Bis(diphenylphosphino)butane CAS:7688-25-7

Cas:7688-25-7

Min.Order:1 Kilogram

FOB Price: $136.0 / 148.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

1,4-Bis(diphenylphosphino)butane CAS: 7688-25-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality

1,4-Bis(diphenylphosphino)butane CAS: 7688-25-7

Cas:7688-25-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:7688-25-7

Cas:7688-25-7

Min.Order:0

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Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

1,4-Bis(Diphenylphosphino)Butane

Cas:7688-25-7

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1,4-bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

1,4-Bis(diphenylphosphino)butane/High quality/Best price

Cas:7688-25-7

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1,4-bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 1,4-Bis(Diphenylphosphino)Butane CAS No.:7688-25-7 Molecule Formula:C28H28P2 Molecule Weight:426.47 Purity: 98.0% Package: 25kg/drum Description:Light yellow crystalline powder Manufacture Standards:Enterprise Standard

High Quality 1,4-Bis(Diphenylphosphino)Butane in stock

Cas:7688-25-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

1,4-Bis(diphenylphosphino)butane Basic information Product Name: 1,4-Bis(diphenylphosphino)butane Synonyms: [4-(Diphenylphosphino)butyl](diphenyl)phosphine;TETRAMETHYLENEBIS(DIPHENYLPHOSPHINE);98% DPPB;Tetramethylenebis(diphenylphosphine) DPPB

1,4-Bis(diphenylphosphino)butane

Cas:7688-25-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Synthetic route

1,4-bis(diphenylphosphinyl)butane
4151-27-3

1,4-bis(diphenylphosphinyl)butane

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
With 1,1,3,3-Tetramethyldisiloxane; titanium(IV) isopropylate In various solvent(s) at 100℃; for 7h;95%
1,4-bis(diphenylphosphinyl)butan-1-one

1,4-bis(diphenylphosphinyl)butan-1-one

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
With tetramethyldisilazane; isopropyl titanoate(IV) In methyl cyclohexane at 60℃;94%
1,4-dibromo-butane
110-52-1

1,4-dibromo-butane

diphenylphosphane
829-85-6

diphenylphosphane

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
With cesium hydroxide; 4 Angstroem MS In N,N-dimethyl-formamide at 23℃; for 47h;87%
With cesium hydroxide; 4 A molecular sieve In N,N-dimethyl-formamide at 23℃; for 47h;87%
1,4-dibromo-butane
110-52-1

1,4-dibromo-butane

chloro-diphenylphosphine
1079-66-9

chloro-diphenylphosphine

A

Tetraphenyldiphosphin
1101-41-3

Tetraphenyldiphosphin

B

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
With tetrabutylammonium tetrafluoroborate; tetra-(n-butyl)ammonium iodide In various solvent(s) Ambient temperature; elektrochemical reaction, anode Mg bar, cathode stainless steel; var. solv.; Yields of byproduct given;A n/a
B 85%
potassium diphenylphosphine
15475-27-1, 4346-39-8

potassium diphenylphosphine

(S)-2-(dibenzylamino)-3-phenyl-1-bromopropane
208103-10-0

(S)-2-(dibenzylamino)-3-phenyl-1-bromopropane

A

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

B

Dibenzyl-((S)-1-benzyl-2-diphenylphosphanyl-ethyl)-amine
208103-11-1

Dibenzyl-((S)-1-benzyl-2-diphenylphosphanyl-ethyl)-amine

Conditions
ConditionsYield
In tetrahydrofuran at -78 - -40℃;A 30%
B 64%
1,4-dichlorobutane
110-56-5

1,4-dichlorobutane

sodium diphenylphosphide
4376-01-6

sodium diphenylphosphide

A

(4-chlorobutyl)diphenylphosphane
79369-66-7

(4-chlorobutyl)diphenylphosphane

B

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
In tetrahydrofuran; toluene 1) -50 deg C, 2) 50 deg C;A 53%
B n/a
tetrachlorure d'octaphenyl-1,1,4,4,9,9,12,12 tetraphosphonia-1,4,9,12 cyclohexadecane
113237-54-0

tetrachlorure d'octaphenyl-1,1,4,4,9,9,12,12 tetraphosphonia-1,4,9,12 cyclohexadecane

A

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

B

1,4-bis(diphenylphosphinyl)butane
4151-27-3

1,4-bis(diphenylphosphinyl)butane

Conditions
ConditionsYield
With sodium hydroxide In ethanol for 14h; Heating; Yield given. Yields of byproduct given;
1,4-dichlorobutane
110-56-5

1,4-dichlorobutane

diphenylphosphane
829-85-6

diphenylphosphane

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
With potassium hydroxide 1.) DMSO, 20 deg C, 2.) 50 deg C, 1 h; Yield given. Multistep reaction;
triphenylphosphine
603-35-0

triphenylphosphine

1,4-dichlorobutane
110-56-5

1,4-dichlorobutane

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
With lithium In tetrahydrofuran at 0℃; for 0.5h;
tetrachlorure d'octaphenyl-1,1,6,6,9,9,14,14 tetraphosphonia-1,6,9,14 cyclohexadecadiene-3,11
113237-53-9

tetrachlorure d'octaphenyl-1,1,6,6,9,9,14,14 tetraphosphonia-1,6,9,14 cyclohexadecadiene-3,11

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 95 percent / Hydrogen / Raney-Ni / 2.5 h / 20 °C / 41253.3 Torr
2: 5N NaOH / aq. ethanol / 14 h / Heating
View Scheme
1,2-bis-(diphenylphosphino)ethane
1663-45-2

1,2-bis-(diphenylphosphino)ethane

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 80 percent / toluene / 4 h / Heating
2: 95 percent / Hydrogen / Raney-Ni / 2.5 h / 20 °C / 41253.3 Torr
3: 5N NaOH / aq. ethanol / 14 h / Heating
View Scheme
Multi-step reaction with 3 steps
1: 80 percent / toluene / 96 h / Heating; var. conc. and time
2: 95 percent / Hydrogen / Raney-Ni / 2.5 h / 20 °C / 41253.3 Torr
3: 5N NaOH / aq. ethanol / 14 h / Heating
View Scheme
iodo(cyclopentadienyl)dicarbonylruthenium(II)

iodo(cyclopentadienyl)dicarbonylruthenium(II)

phosphorous acid trimethyl ester
121-45-9

phosphorous acid trimethyl ester

A

(η5-C5H5)(CO)I(P(OMe)3)ruthenium(II)

(η5-C5H5)(CO)I(P(OMe)3)ruthenium(II)

B

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene under N2; soln. of Ru complex and 1 equiv of ligand in toluene heated to 105-110 °C, added catalyst, completion of react. detected by IR; cooled, evapd., sepd. by chromy. (SiO2, benzene), recrystd. from toluene/hexane; elem. anal.;
RuCl2(η6-p-cymene)(η1-dppb)

RuCl2(η6-p-cymene)(η1-dppb)

A

[RuCl2(η6-p-cymene)]2(μ-dppb)
853907-92-3

[RuCl2(η6-p-cymene)]2(μ-dppb)

B

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
In dichloromethane-d2 at 25℃; Equilibrium constant; Inert atmosphere; Schlenk technique;
1,4-dibromo-butane
110-52-1

1,4-dibromo-butane

chloro-diphenylphosphine
1079-66-9

chloro-diphenylphosphine

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Conditions
ConditionsYield
Stage #1: 1,4-dibromo-butane With iodine; magnesium In tetrahydrofuran for 3h; Inert atmosphere;
Stage #2: chloro-diphenylphosphine In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere;

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

(1,4-bis(diphenylphosphino)butane)molybdenum tetracarbonyl
15553-69-2

(1,4-bis(diphenylphosphino)butane)molybdenum tetracarbonyl

B

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

C15H15BrO4

C15H15BrO4

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

C2H3O2(1-)*C54H50Br2O4P2

C2H3O2(1-)*C54H50Br2O4P2

Conditions
ConditionsYield
In acetonitrile at 20℃; for 1h;100%
hexafluoro-1,4-naphthoquinone
1024-60-8

hexafluoro-1,4-naphthoquinone

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

3,3'-(butane-1,4-diylbis(diphenylphosphonionediyl))bis(5,6,7,8-tetrafluoro-1,4-dioxo-1,4-dihydronaphthalen-2-olate)

3,3'-(butane-1,4-diylbis(diphenylphosphonionediyl))bis(5,6,7,8-tetrafluoro-1,4-dioxo-1,4-dihydronaphthalen-2-olate)

Conditions
ConditionsYield
With air In water; dimethyl sulfoxide at 20℃; for 1h; Inert atmosphere;100%
(S)-(-)-2-naphthyl-3-trifluoromethanesulfonyloxybiphenyl
170647-29-7, 173300-95-3

(S)-(-)-2-naphthyl-3-trifluoromethanesulfonyloxybiphenyl

Diphenylphosphine oxide
4559-70-0

Diphenylphosphine oxide

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

(S)-(+)-2-naphthyl-3-diphenylphosphinylbiphenyl
170647-33-3

(S)-(+)-2-naphthyl-3-diphenylphosphinylbiphenyl

Conditions
ConditionsYield
With sodium hydrogencarbonate; N-ethyl-N,N-diisopropylamine; palladium diacetate In dimethyl sulfoxide99%
carbonylgold(I) chloride
50960-82-2

carbonylgold(I) chloride

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

1,4-bis(diphenylphosphino)butane digold(I) dichloride
63640-04-0

1,4-bis(diphenylphosphino)butane digold(I) dichloride

Conditions
ConditionsYield
In benzene byproducts: CO; soln. of Ph2PCH2CH2CH2CH2PPh2 dropped to soln. of (OC)AuCl at 20°C under dry N2, stirred for 1 h (CO removed); filtered;99%
Pt(Sn(CH3)3)2(P(CH3C6H4)3)2

Pt(Sn(CH3)3)2(P(CH3C6H4)3)2

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

Pt(Sn(CH3)3)2(C6H5)2P(CH2)4P(C6H5)2

Pt(Sn(CH3)3)2(C6H5)2P(CH2)4P(C6H5)2

Conditions
ConditionsYield
99%
benzene ruthenium(II) dichloride dimer

benzene ruthenium(II) dichloride dimer

ethylenediamine
107-15-3

ethylenediamine

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

(dppb)RuCl2(enethylenediamine)
1158920-26-3, 200259-42-3

(dppb)RuCl2(enethylenediamine)

Conditions
ConditionsYield
Stage #1: benzene ruthenium(II) dichloride dimer; 1,4-di(diphenylphosphino)-butane In N,N-dimethyl-formamide at 120℃; for 1.5h;
Stage #2: ethylenediamine In dichloromethane at 40℃; for 1.5h;
99%
hydrogenchloride
7647-01-0

hydrogenchloride

palladium
7440-05-3

palladium

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

[1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride
29964-62-3

[1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride

Conditions
ConditionsYield
Stage #1: hydrogenchloride; palladium With nitric acid In water
Stage #2: 1,4-di(diphenylphosphino)-butane In water; N,N-dimethyl-formamide at 50℃; for 1h;
98.9%
bis(1,5-cyclooctadiene)diiridium(I) dichloride
12112-67-3

bis(1,5-cyclooctadiene)diiridium(I) dichloride

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

IrCl(1,5-cyclooctadiene)(1,4-bis(diphenylphosphino)butane)
688063-92-5

IrCl(1,5-cyclooctadiene)(1,4-bis(diphenylphosphino)butane)

Conditions
ConditionsYield
With dimethyl 2,2-diallylmalonate In dichloromethane byproducts: cyclooctadiene; to a soln. of complex in CH2Cl2 was added diphosphine, then a soln. of 3equiv of diallyl ether in CH2Cl2, the mixt. was stirred at room temp. f or 3 h (inert atm.); volatiles were removed in vac., recrystd. from CH2Cl2/n-hexane; elem. anal.;98%
[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2
52462-29-0

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

A

[RuCl2(η6-p-cymene)]2(μ-dppb)
853907-92-3

[RuCl2(η6-p-cymene)]2(μ-dppb)

B

[(p-cymene)Ru(dppb)Cl](1+)

[(p-cymene)Ru(dppb)Cl](1+)

Conditions
ConditionsYield
In dichloromethane stirred for 4 h; filtered, solvent-removed; elem. anal.;A 98%
B 0%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

silver perchlorate

silver perchlorate

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

[Ag2(2,2'-bipyridyl)2(dppb)][ClO4]2

[Ag2(2,2'-bipyridyl)2(dppb)][ClO4]2

Conditions
ConditionsYield
In acetonitrile stoich. mixt. in CH3CN stirred for 12 h at room temp.; evapd., washed (Et2O), elem. anal.;98%
nickel(II) chloride hexahydrate

nickel(II) chloride hexahydrate

dimercaptomaleonitrile disodium salt hydrate

dimercaptomaleonitrile disodium salt hydrate

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

(maleonitriledithilato)(1,4-bis(diphenylphosphino)butane)nickel(II)
81098-03-5

(maleonitriledithilato)(1,4-bis(diphenylphosphino)butane)nickel(II)

Conditions
ConditionsYield
In acetone mixt. of solids NiCl2*6H2O (1 mmol) and Ph2P(CH2)4P(Ph)2 (0.42 g) in acetone stirred for 1 h; pptd. by H2O addn. with stirring; ppt. filtered off; washed (H2O, EtOH, Et2O); dried at room temp.; elem. anal.;98%
dichloro(tetraethylcyclobutadiene)platinum(II)
56664-81-4

dichloro(tetraethylcyclobutadiene)platinum(II)

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

(PtCl2(C4(C2H5)4))2((C6H5)2P(CH2)4P(C6H5)2)
217475-40-6

(PtCl2(C4(C2H5)4))2((C6H5)2P(CH2)4P(C6H5)2)

Conditions
ConditionsYield
In dichloromethane Ar-atmosphere; stirring Pt-complex with 0.5 equiv. of phosphine (room temp., 5-10 h); pptn. on Et2O addn., filtration, washing (Et2O), drying (vac.); elem. anal.;97%
dichloro(tetraethylcyclobutadiene)platinum(II)
56664-81-4

dichloro(tetraethylcyclobutadiene)platinum(II)

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

(C4(C2H5)4)PtCl((C6H5)2P(CH2)4P(C6H5)2)(1+)*Cl(1-)*CH2Cl2=[(C4(C2H5)4)PtCl((C6H5)2P(CH2)4P(C6H5)2)]Cl*CH2Cl2

(C4(C2H5)4)PtCl((C6H5)2P(CH2)4P(C6H5)2)(1+)*Cl(1-)*CH2Cl2=[(C4(C2H5)4)PtCl((C6H5)2P(CH2)4P(C6H5)2)]Cl*CH2Cl2

Conditions
ConditionsYield
In dichloromethane Ar-atmosphere; stirring Pt-complex with equimolar amt. of phosphine (room temp., 2-3 h); pptn. on Et2O addn., standing (overnight), filtration, washing (Et2O), drying (vac.);97%
[Pd(o-C6H4C=NCH=CHNMe)(μ-Cl)]2

[Pd(o-C6H4C=NCH=CHNMe)(μ-Cl)]2

sodium perchlorate

sodium perchlorate

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

[Pd(o-C6H4C=NCH=CHNMe)((C6H5)2P(CH2)4P(C6H5)2-P,P)]ClO4
202066-49-7

[Pd(o-C6H4C=NCH=CHNMe)((C6H5)2P(CH2)4P(C6H5)2-P,P)]ClO4

Conditions
ConditionsYield
In acetone N2-atmosphere; stirring equimolar amts. of Pd-complex and phosphine (room temp., 2 h), addn. of NaClO4, stirring for 2 h, addn. of H2O, stirringfor 4 h (pptn.); filtration, drying (vac.), recrystn. (CH2Cl2/hexane); elem. anal.;97%
RuBr2(P(C6H5)3)3
56586-92-6, 15709-75-8

RuBr2(P(C6H5)3)3

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

RuBr2(1,4-bis(diphenylphosphino)butane)(PPh3)
184014-42-4

RuBr2(1,4-bis(diphenylphosphino)butane)(PPh3)

Conditions
ConditionsYield
In further solvent(s) Ar-atmosphere; equimolar amts., stirring in CH2Br2 at room temp. for 2 h; vol. reduction, pptn. on EtOH addn., collection (filtration), washing (EtOH, hexanes), drying (vac.); elem. anal.;97%
tris(triphenylphosphine)ruthenium(II) chloride
15529-49-4, 41756-81-4

tris(triphenylphosphine)ruthenium(II) chloride

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

[Ru(dppp)2]Cl2

[Ru(dppp)2]Cl2

Conditions
ConditionsYield
In hexane for 2h; Reflux;97%
Ru(OAc)2(CO)(PPh3)2

Ru(OAc)2(CO)(PPh3)2

ethylenediamine
107-15-3

ethylenediamine

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

[Ru(acetate)(CO)(1,4-bis(diphenylphosphino)butane)(1,2-ethylendiamine)]acetate

[Ru(acetate)(CO)(1,4-bis(diphenylphosphino)butane)(1,2-ethylendiamine)]acetate

Conditions
ConditionsYield
Stage #1: Ru(OAc)2(CO)(PPh3)2; 1,4-di(diphenylphosphino)-butane In dichloromethane at 20℃; for 6h;
Stage #2: ethylenediamine In dichloromethane at 20℃; for 2h;
97%
3,4,5-tris(tetradecyloxy)benzyl chloride

3,4,5-tris(tetradecyloxy)benzyl chloride

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

3,4,5-tris(tetradecyloxy)1,4-bis(diphenylphosphonium chloride)butane

3,4,5-tris(tetradecyloxy)1,4-bis(diphenylphosphonium chloride)butane

Conditions
ConditionsYield
In chloroform at 61℃; for 65h; Inert atmosphere;97%
[Ru(η1-OAc)(η2-OAc)(PPh3)2(CO)]
142215-87-0, 38596-65-5, 52746-32-4, 61990-12-3

[Ru(η1-OAc)(η2-OAc)(PPh3)2(CO)]

ethylenediamine
107-15-3

ethylenediamine

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

[Ru(acetate)(CO)(1,4-bis(diphenylphosphino)butane)(1,2-ethylendiamine)]acetate

[Ru(acetate)(CO)(1,4-bis(diphenylphosphino)butane)(1,2-ethylendiamine)]acetate

Conditions
ConditionsYield
Stage #1: [Ru(η1-OAc)(η2-OAc)(PPh3)2(CO)]; 1,4-di(diphenylphosphino)-butane In dichloromethane at 20℃; for 6h; Inert atmosphere; Schlenk technique;
Stage #2: ethylenediamine In dichloromethane at 20℃; for 2h; Inert atmosphere; Schlenk technique;
97%
formaldehyd
50-00-0

formaldehyd

rhodium(III) trichloride hydrate

rhodium(III) trichloride hydrate

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

RhCl(CO)(1,4-bis(diphenylphosphino)butane)
62795-67-9

RhCl(CO)(1,4-bis(diphenylphosphino)butane)

Conditions
ConditionsYield
In ethanol; water for 0.5h; Inert atmosphere; Reflux;96.6%
potassium tetrachloroplatinate

potassium tetrachloroplatinate

water
7732-18-5

water

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

[PtCl2(dppb)]*2H2O

[PtCl2(dppb)]*2H2O

Conditions
ConditionsYield
In methanol; dichloromethane for 24h; Schlenk technique; Inert atmosphere; Reflux;96.3%
pentacarbonyl(acetonitrile)tungsten
15096-68-1

pentacarbonyl(acetonitrile)tungsten

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

A

{1,4-bis(diphenylphosphino)butane}tetracarbonyltungsten(0)
54111-75-0

{1,4-bis(diphenylphosphino)butane}tetracarbonyltungsten(0)

B

{W(CO)5}2(P(C6H5)2(CH2)4P(C6H5)2)
120950-72-3

{W(CO)5}2(P(C6H5)2(CH2)4P(C6H5)2)

Conditions
ConditionsYield
In toluene (W(CO)5(NCMe)) and diphosphine (molar ratio: 5:1) refluxed in toluene under nitrogen (2-2.5 h), soln. filtered through cellulose, pumped to dryness; washing with hexane or chromy. (silica gel, benzene); 31P-NMR;A 4%
B 96%
In chloroform (W(CO)5(NCMe)) and diphosphine (molar ratio: 2:1) refluxed in CHCl3 under nitrogen (55°C, 2-2.5 h), soln. filtered through cellulose, pumped to dryness; washing with hexane or chromy. (silica gel, benzene); 31P-NMR;A 87%
B 13%
In chloroform (W(CO)5(NCMe)) and diphosphine (molar ratio: 2:1) refluxed in CHCl3 under nitrogen (55°C, 2-2.5 h), soln. filtered through cellulose, pumped to dryness; washing with hexane or chromy. (silica gel, benzene); 31P-NMR;A 76%
B 24%
In toluene (W(CO)5(NCMe)) and diphosphine (molar ratio: 2:1) refluxed in toluene under nitrogen (2-2.5 h), soln. filtered through cellulose, pumped to dryness; washing with hexane or chromy. (silica gel, benzene); 31P-NMR;A 43%
B 57%
[,14-bis(diphenylphosphino)butane] (1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

[,14-bis(diphenylphosphino)butane] (1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

{Rh((C6H5)2PCH2CH2CH2CH2P(C6H5)2)2}(1+)*BF4(1-)={Rh((C6H5)2PCH2CH2CH2CH2P(C6H5)2)2}BF4
70196-23-5

{Rh((C6H5)2PCH2CH2CH2CH2P(C6H5)2)2}(1+)*BF4(1-)={Rh((C6H5)2PCH2CH2CH2CH2P(C6H5)2)2}BF4

Conditions
ConditionsYield
In methanol; dichloromethane H2-atmosphere; stirring (room temp., 20 min), phosphine soln. (CH2Cl2) addn., stirring (2 h); evapn. (vac.);96%
dichloro(1,5-cyclooctadiene)platinum(ll)
12080-32-9

dichloro(1,5-cyclooctadiene)platinum(ll)

phosphoric acid monophenyl ester
701-64-4

phosphoric acid monophenyl ester

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

{Pt(O2P(O)OC6H5)((C6H5)2P(CH2)4P(C6H5)2)}*H2O

{Pt(O2P(O)OC6H5)((C6H5)2P(CH2)4P(C6H5)2)}*H2O

Conditions
ConditionsYield
With Ag2O In dichloromethane react. under dry N2, addn. of (C6H5)2P(CH2)4P(C6H5)2, phenyl dihydrogenphosphate (molar ratio = 1:1) and an excess of Ag2O to a stirred soln. of PtCl2(cycloocta-1,5-diene) in CH2Cl2, refluxing for 4 h, cooling; filtration,, evapg. the filtrate to dryness under reduced pressure, oily residue, dissolving the oil in CH2Cl2, addn. of light petroleum, crystn. on standing, recrystn. from CH2Cl2-light petroleum, drying in vac., elem. anal.;96%
dichloro(1,5-cyclooctadiene)platinum(ll)
12080-32-9

dichloro(1,5-cyclooctadiene)platinum(ll)

ammonium hexafluorophosphate

ammonium hexafluorophosphate

2,6-dimethylphenyl isonitrile
119072-54-7, 2769-71-3

2,6-dimethylphenyl isonitrile

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

[(1,4-bis(diphenylphosphino)butane)(2,6-dimethylphenyl isocyanide)platinum(II)](PF6)2*0.5dichloromethane

[(1,4-bis(diphenylphosphino)butane)(2,6-dimethylphenyl isocyanide)platinum(II)](PF6)2*0.5dichloromethane

Conditions
ConditionsYield
In dichloromethane; acetone under N2; successive addn. of diphosphine, isocyanide and excess of NH4PF6 to Pt-compd. dissolved in CH2Cl2 and acetone, stirring at room temp.for 2 h; evapn. of solvent to dryness under reduced pressure, extn. of residue with CH2Cl2, washing with H2O and drying over Na2SO4, concg. of soln., crystn. by addn. of Et2O; elem. anal.;96%
[Pd(μ-N3)(2-(2'-thienyl)pyridine(-H))]2
1190631-16-3

[Pd(μ-N3)(2-(2'-thienyl)pyridine(-H))]2

1,4-di(diphenylphosphino)-butane
7688-25-7

1,4-di(diphenylphosphino)-butane

[Pd(N3)(2-(2'-thienyl)pyridine)]2(μ-1,4-bis(diphenylphosphino)butane)
1190630-94-4

[Pd(N3)(2-(2'-thienyl)pyridine)]2(μ-1,4-bis(diphenylphosphino)butane)

Conditions
ConditionsYield
In dichloromethane (under N2 or Ar, Schlenk); CH2Cl2 soln. of ligand added to soln. of Pd-complex in CH2Cl2, stirred for 5 h; solvent removed, washed with Et2O, recrystd. from CH2Cl2-n-hexane; elem.anal.;96%

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