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SICHUAN ZHONGBANG NEW MATERIAL CO., LTD

SICHUAN ZHONGBANG with its subsidiaries LUZHOU FUBANG& LUZHOU DAZHOU are specializing in the research, development, manufacturing and trade of fine chemicals, pesticide intermediates and pharmaceutical intermediates.

1-Bromoadamantane

Cas:768-90-1

Min.Order:0 Metric Ton

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Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

1-Bromoadamantane

Cas:768-90-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1-Bromoadamantane supplier in China

Cas:768-90-1

Min.Order:0 Metric Ton

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Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

The company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance: White to yellow Powder Storage:Sealed, dry

1-BroMoadaMantane

Cas:768-90-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1-bromotricyclo[3.3.1.13,7]decane

Cas:768-90-1

Min.Order:1

Negotiable

Type:Other

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

1-Bromoadamantane

Cas:768-90-1

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1-Bromoadamantane

Cas:768-90-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--768-90-1--2-Adamantanol in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relationships

TIANFUCHEM--768-90-1--2-Adamantanol in stock

Cas:768-90-1

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

1-Bromoadamantane

Cas:768-90-1

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 768-90-1 with fast shipping

Cas:768-90-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

1-BroMoadaMantane CAS768-90-1 Lower price

Cas:768-90-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta

high quality 768-90-1 1-Bromoadamantane with best price

Cas:768-90-1

Min.Order:10 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1-Bromoadamantane 768-90-1

Cas:768-90-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

1-Bromoadamantane with CAS:768-90-1

Cas:768-90-1

Min.Order:25 Kilogram

FOB Price: $51.0 / 55.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

1-Bromoadamantane CAS:768-90-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedi

1-Bromoadamantane CAS:768-90-1

Cas:768-90-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1-Bromoadamantane

Cas:768-90-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Wonda Pharm Limited

1.high quality: quality is life. quality is the most important element for all goods. we have a lab doing research in wuhan china. hplc and nmr is available if needed. 2.reasonable price: we provide high quality products wi

Best manufacturer Cas:768-90-1 1-Bromoadamantane

Cas:768-90-1

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Leader Biochemical Group

Overview of Our Factories Our Factories production lines Our Factories R&D ability Our Factories warehouse Our Factorie

China Biggest Factory & Manufacturer supply 1-Bromoadamantane

Cas:768-90-1

Min.Order:1 Kilogram

FOB Price: $30.0 / 35.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:768-90-1

Cas:768-90-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

1-Bromoadamantane

Cas:768-90-1

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Appearance:powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common products:Sea/Air/Courier Dang

1-Bromoadamantane

Cas:768-90-1

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 768-90-1 1-Bromoadamantane

Cas:768-90-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1-Bromoadamantane

Cas:768-90-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

1-BROMOADAMANTANE

Cas:768-90-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-Bromoadamantane

Cas:768-90-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1-Bromoadamantane

Cas:768-90-1

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1-Bromoadamantane

Cas:768-90-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

1-BroMoadaMantane

Cas:768-90-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Name 1-Bromoadamantane Cas 768-90-1

1-Bromoadamantane

Cas:768-90-1

Min.Order:1 Gram

FOB Price: $63.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 1-Bromoadamantane CAS No.:768-90-1 Molecule Formula:C10H15Br Molecule Weight:215.13 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard TEST

Best Quality 1-Bromoadamantane

Cas:768-90-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Synthetic route

1-chloroadamantane
935-56-8

1-chloroadamantane

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

Conditions
ConditionsYield
With iron(III)-acetylacetonate; carbon tetrabromide at 120℃; for 2h; Sealed tube; Inert atmosphere;99%
With hydrogen bromide at 130℃; for 2h;90%
With boron tribromide for 0.5h;86%
adamantane
281-23-2

adamantane

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

1,3-dibromoadamantane
876-53-9

1,3-dibromoadamantane

Conditions
ConditionsYield
With iron(III)-acetylacetonate; carbon tetrabromide Reagent/catalyst; Sealed tube; Inert atmosphere;A 99%
B 23%
With bromine; iron at 0 - 50℃; for 3h;A n/a
B 93%
With iodine(I) bromide In tetrachloromethane for 3h; Heating;A 75 % Chromat.
B 25 % Chromat.
With iodine(I) bromide In tetrachloromethane for 3h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
1-adamanthanol
768-95-6

1-adamanthanol

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

Conditions
ConditionsYield
With oxygen; 1,2-dibromomethane for 10h; Reflux;99%
With iron(III)-acetylacetonate; carbon tetrabromide at 120℃; for 2h; Sealed tube; Inert atmosphere;99%
With dibromo sulfoxide In toluene for 22h;96%
adamantane
281-23-2

adamantane

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

Conditions
ConditionsYield
With bromine; Nitrogen dioxide In trifluoroacetic acid at 20℃; for 0.5h;98%
With water; bromine for 0.166667h;93%
With bromine at 85 - 110℃; Temperature;93%
1-Adamantanecarbonyl chloride
2094-72-6

1-Adamantanecarbonyl chloride

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

2-<(trichloromethyl)thio>pyridine
66832-24-4

2-<(trichloromethyl)thio>pyridine

Conditions
ConditionsYield
With Bromotrichloromethane; 2-mercaptopyridine-1-oxide sodium salt; dmap at 105℃; for 0.5h;A 98%
B n/a
1-adamantyl n-butyl ether

1-adamantyl n-butyl ether

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

Conditions
ConditionsYield
With bromine In tetrachloromethane at 20℃; for 12h;97%
1-(Dibromoamino)adamantane
34913-44-5

1-(Dibromoamino)adamantane

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

Conditions
ConditionsYield
In acetone at 250 - 260℃;94%
In acetone at 250 - 260℃; also at 250 deg C, 6 Torr, without solvent;94%
1-adamantyl fluoride
768-92-3

1-adamantyl fluoride

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

Conditions
ConditionsYield
With hydrogen bromide at 105℃; for 0.5h;92%
With boron tribromide In hexane at 0℃; for 0.0833333h;90%
4-(1-adamantyl)benzene-1,3-diol
74131-25-2

4-(1-adamantyl)benzene-1,3-diol

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

2,4,6-tribromoresorcinol
2437-49-2

2,4,6-tribromoresorcinol

C

2,6-Dibromo-4-(1-adamantyl)resorcinol
74131-27-4

2,6-Dibromo-4-(1-adamantyl)resorcinol

Conditions
ConditionsYield
With bromine In methanol; acetic acid for 1h; Ambient temperature;A n/a
B n/a
C 91.5%
Bromotrichloromethane
75-62-7

Bromotrichloromethane

adamantane
281-23-2

adamantane

acetonitrile
75-05-8

acetonitrile

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

chloroform
67-66-3

chloroform

C

N-(1-adamantyl)acetamide
880-52-4

N-(1-adamantyl)acetamide

Conditions
ConditionsYield
With water; molybdenum hexacarbonyl at 140℃; for 2h;A n/a
B n/a
C 90%
1-Adamantanecarboxylic acid
828-51-3

1-Adamantanecarboxylic acid

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

Conditions
ConditionsYield
With Ag(Phen)2OTf; dibromoisocyanuric acid In 1,2-dichloro-ethane at 20℃; for 1h; Inert atmosphere; Schlenk technique;89%
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; caesium carbonate; Diethyl 2-bromomalonate In ethyl acetate at 20℃; for 4h; Solvent; Inert atmosphere; Irradiation;70%
With Bromotrichloromethane; 2-mercaptopyridine-1-oxide sodium salt; dmap 2.) reflux; Yield given. Multistep reaction;
Multi-step reaction with 2 steps
1: (COBr)2
2: Fe / 1 h / Ambient temperature
View Scheme
1-nitroxyadamantane
32314-61-7

1-nitroxyadamantane

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

Conditions
ConditionsYield
With sulfuric acid; potassium bromide for 1h;89%
adamantane
281-23-2

adamantane

acetonitrile
75-05-8

acetonitrile

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

Bromoform
75-25-2

Bromoform

C

1-adamantanecarbonitrile
23074-42-2

1-adamantanecarbonitrile

Conditions
ConditionsYield
With carbon tetrabromide; molybdenum hexacarbonyl at 140 - 160℃; for 6h; Reactivity; Mechanism; Reagent/catalyst;A 15%
B n/a
C 85%
adamantane
281-23-2

adamantane

benzoyl chloride
98-88-4

benzoyl chloride

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

2-adamantyl bromide
7314-85-4

2-adamantyl bromide

C

benzaldehyde
100-52-7

benzaldehyde

Conditions
ConditionsYield
With aluminum tri-bromide In various solvent(s) at 20℃; for 2h;A 70%
B 3%
C 82%
With aluminum tri-bromide In various solvent(s) at 20℃; for 2h;A 70%
B 3%
C 82%
1-(1-adamantyl)-3,4-dimethylbenzene
62133-11-3

1-(1-adamantyl)-3,4-dimethylbenzene

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

1,3-dibromoadamantane
876-53-9

1,3-dibromoadamantane

C

1,2,3,4-tetrabromo-5,6-dimethylbenzene
2810-69-7

1,2,3,4-tetrabromo-5,6-dimethylbenzene

Conditions
ConditionsYield
With bromine; iron for 3.5h; Product distribution; Ambient temperature;A n/a
B n/a
C 82%
1-chloroadamantane
935-56-8

1-chloroadamantane

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

2-adamantyl bromide
7314-85-4

2-adamantyl bromide

C

adamantane
281-23-2

adamantane

D

1,3-dibromoadamantane
876-53-9

1,3-dibromoadamantane

Conditions
ConditionsYield
With hydrogen bromide; ferric(III) bromide In dichloromethane at 25℃; for 0.3h;A 78%
B 3%
C 9%
D 9 % Chromat.
With hydrogen bromide; ferric(III) bromide In dichloromethane at 25℃; for 0.3h;A 78%
B 3%
C 9%
D 3 % Chromat.
adamantane
281-23-2

adamantane

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

2-Adamantanone
700-58-3

2-Adamantanone

C

1-chloroadamantane
935-56-8

1-chloroadamantane

D

2-adamantyl bromide
7314-85-4

2-adamantyl bromide

E

1-adamanthanol
768-95-6

1-adamanthanol

F

1-adamantanol
700-57-2

1-adamantanol

Conditions
ConditionsYield
With Bromotrichloromethane; 3,3-dimethyldioxirane In acetone at 20℃; Product distribution; Mechanism;A 12.2%
B 1.8%
C 0.7%
D 2.3%
E 77.2%
F 1.1%
With Bromotrichloromethane; 3,3-dimethyldioxirane In acetone for 1h; Mechanism; Product distribution; Ambient temperature; concentration depending investigated;
adamantane
281-23-2

adamantane

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

1-chloroadamantane
935-56-8

1-chloroadamantane

C

2-adamantyl bromide
7314-85-4

2-adamantyl bromide

Conditions
ConditionsYield
With tert.-butylhydroperoxide; Bromotrichloromethane; iron(III) chloride In pyridine; acetic acid at 60℃; for 18h;A 69.2%
B 4.1%
C 26.7%
With tert.-butylhydroperoxide; Bromotrichloromethane; iron(III) chloride In pyridine; acetic acid at 60℃; for 18h; Product distribution; Mechanism; various conditions;A 69.2%
B 4.1%
C 26.7%
(1s,3s)-adamantan-1-yl(phenyl)sulfide
88459-01-2

(1s,3s)-adamantan-1-yl(phenyl)sulfide

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

Conditions
ConditionsYield
With bromine In dichloromethane at 20℃; for 1h;68%
1-(Dibromoamino)adamantane
34913-44-5

1-(Dibromoamino)adamantane

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

1,3-dibromoadamantane
876-53-9

1,3-dibromoadamantane

Conditions
ConditionsYield
at 95 - 250℃; under 6 Torr; for 1h;A 65%
B n/a
adamantane
281-23-2

adamantane

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

(1s,3s,5s,7s)-1,3-dibromoadamantane

(1s,3s,5s,7s)-1,3-dibromoadamantane

Conditions
ConditionsYield
Stage #1: adamantane With [2,2]bipyridinyl; N-Bromosuccinimide; manganese(II) acetate for 0.0833333h; Inert atmosphere;
Stage #2: With trimethylsilylazide at 60℃; for 0.5h; Inert atmosphere; Sealed tube; regioselective reaction;
A 62%
B 15%
Stage #1: adamantane With [2,2]bipyridinyl; N-Bromosuccinimide; manganese(II) acetate for 0.0833333h; Inert atmosphere;
Stage #2: With trimethylsilylazide at 60℃; for 18h; Inert atmosphere; Sealed tube; regioselective reaction;
A 16%
B 62%
C10H15Ge(CH3)3
52044-18-5

C10H15Ge(CH3)3

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

1-adamantyldimethylbromogermane
100203-98-3

1-adamantyldimethylbromogermane

Conditions
ConditionsYield
With bromine In tetrachloromethane soln. of Br2 added to soln. of 1-AdGeMe3; boiled (18 h, 78°C); solvent removed; recrystd. (hexane); elem.anal.;A 54.7%
B 28.7%
adamantane
281-23-2

adamantane

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

2-adamantyl bromide
7314-85-4

2-adamantyl bromide

Conditions
ConditionsYield
With dihydrogen peroxide; bromine In water; 1,2-dichloro-ethane for 4h;A 48.7%
B 51.3%
With Li2MnO3; bromine; oxygen at 100℃; under 760.051 Torr; for 24h; Photolysis;A 42%
B 5%
With hydrogenchloride; oxygen; potassium bromide; sodium nitrite In chloroform; water at 20 - 30℃; under 760.051 Torr; for 24h; Sealed tube; Irradiation;A 20%
B 17%
adamantane
281-23-2

adamantane

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With [(hydrotris(3,5-diphenyl-pyrazol-1-yl)borate)FeII(benzilate)]; tetrabutylammomium bromide; oxygen; pyridinium perchlorate In acetonitrile at 20℃;A 7%
B 48%
With ruthenium hydroxide trichloride; carbon tetrabromide; water at 160℃; for 9h; Inert atmosphere; regioselective reaction;A 30%
B 30%
adamantane
281-23-2

adamantane

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

1-chloroadamantane
935-56-8

1-chloroadamantane

C

2-adamantyl bromide
7314-85-4

2-adamantyl bromide

D

1-adamanthanol
768-95-6

1-adamanthanol

E

1-adamantanol
700-57-2

1-adamantanol

F

2-chloroadamantane
7346-41-0

2-chloroadamantane

Conditions
ConditionsYield
With Bromotrichloromethane; 3,3-dimethyldioxirane In acetone at 20℃; for 3.5h; Rate constant; Product distribution; Kinetics;A 42.3%
B 9.2%
C 10.5%
D 33%
E 2%
F 2.5%
1-(Bromoamino)adamantane
5511-20-6

1-(Bromoamino)adamantane

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

1-Adamantanamine
768-94-5

1-Adamantanamine

Conditions
ConditionsYield
In dichloromethane at 250 - 260℃; 15-30percent SE-30 on Chromosorb W;A 30%
B n/a
tetrabutylammomium bromide
1643-19-2

tetrabutylammomium bromide

3-chloro-benzenecarboperoxoic acid
937-14-4

3-chloro-benzenecarboperoxoic acid

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

2-adamantyl bromide
7314-85-4

2-adamantyl bromide

C

n-butyl 3-chlorobenzoate
63987-54-2

n-butyl 3-chlorobenzoate

Conditions
ConditionsYield
With adamantane In acetonitrile at 20℃; for 1h; Yields of byproduct given;A n/a
B n/a
C 24%
tetramethylammonium bromide
64-20-0

tetramethylammonium bromide

3-chloro-benzenecarboperoxoic acid
937-14-4

3-chloro-benzenecarboperoxoic acid

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

2-adamantyl bromide
7314-85-4

2-adamantyl bromide

C

methyl 3-chlorobenzoate
2905-65-9

methyl 3-chlorobenzoate

Conditions
ConditionsYield
With adamantane In acetonitrile at 20℃; for 1h; Yields of byproduct given;A n/a
B n/a
C 19%
Acetyl bromide
506-96-7

Acetyl bromide

1-chloroadamantane
935-56-8

1-chloroadamantane

A

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

B

acetyl chloride
75-36-5

acetyl chloride

Conditions
ConditionsYield
With iron(III) chloride at 25℃; for 168h; Equilibrium constant; Thermodynamic data; ΔG;
With iron(III) chloride In chloroform at 25℃; for 168h; Equilibrium constant; Thermodynamic data; ΔG;
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

methoxybenzene
100-66-3

methoxybenzene

1-(4-methoxyphenyl)adamantane
726-94-3

1-(4-methoxyphenyl)adamantane

Conditions
ConditionsYield
With molybdenum hexacarbonyl Sealed tube; regioselective reaction;100%
With potassium carbonate; palladium on activated charcoal at 120℃; for 12h;91%
With palladium 10% on activated carbon; potassium carbonate for 20h; Heating;82.65%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

adamantane
281-23-2

adamantane

Conditions
ConditionsYield
With triethylsilane; dilauryl peroxide; 1-dodecylthiol at 70℃; for 1h;100%
With triethylsilane; dilauryl peroxide; 1-dodecylthiol In cyclohexane at 80℃; for 1h;100%
With sodium tetrahydroborate; 2,2'-azobis(isobutyronitrile); cPS-SnBu2Cl In 1,2-dimethoxyethane at 80℃; for 0.5h;100%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

acetic acid
64-19-7

acetic acid

1-acetyloxyadamantane
22635-62-7

1-acetyloxyadamantane

Conditions
ConditionsYield
With iron(III)-acetylacetonate Heating;100%
With bromine for 0.05h;90%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

(2S,4R)-1-(tert-butoxycarbonyl)-4-((tert-butyldimethylsilyl)oxy)pyrrolidine-2-carboxylic acid
149814-40-4

(2S,4R)-1-(tert-butoxycarbonyl)-4-((tert-butyldimethylsilyl)oxy)pyrrolidine-2-carboxylic acid

1-adamantyl (2S,4R)-1-(tert-butoxycarbonyl)-4-(tert-butyldimethylsilyloxy)pyrrolidine-2-carboxylate
400724-37-0

1-adamantyl (2S,4R)-1-(tert-butoxycarbonyl)-4-(tert-butyldimethylsilyloxy)pyrrolidine-2-carboxylate

Conditions
ConditionsYield
With silver(l) oxide In diethyl ether at 20℃; for 30h;100%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

propargyl alcohol
107-19-7

propargyl alcohol

1-adamantyl propargyl ether
119728-80-2

1-adamantyl propargyl ether

Conditions
ConditionsYield
With triethylamine100%
1,4-bis(3-phenyl-1,2,4-triazol-4-yl)benzene

1,4-bis(3-phenyl-1,2,4-triazol-4-yl)benzene

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

4,4'-(1,4-phenylene)bis[1-(1-adamantyl)-3-phenyl-1,2,4-triazolium] dibromide

4,4'-(1,4-phenylene)bis[1-(1-adamantyl)-3-phenyl-1,2,4-triazolium] dibromide

Conditions
ConditionsYield
In acetic acid Heating;100%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

toluene
108-88-3

toluene

4-(1-adamantyl)toluene
1459-55-8

4-(1-adamantyl)toluene

Conditions
ConditionsYield
With molybdenum hexacarbonyl at 100℃; for 2h; Catalytic behavior; Reagent/catalyst; Temperature; Time; Sealed tube; regioselective reaction;99%
With potassium carbonate; palladium on activated charcoal at 120℃; for 12h;97%
With iron pentacarbonyl; Bromotrichloromethane at 80℃; for 5h; Friedel-Crafts Alkylation;95%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

methylmagnesium bromide
75-16-1

methylmagnesium bromide

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
In dibutyl ether at 85℃; for 1h;99%
In dibutyl ether at 105℃; for 4.5h;80%
In dibutyl ether at 70 - 90℃; Rate constant; Thermodynamic data; ΔE;
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

ortho-cresol
95-48-7

ortho-cresol

4-((3r,5r,7r)-adamantan-1-yl)-2-methylphenol
53799-14-7

4-((3r,5r,7r)-adamantan-1-yl)-2-methylphenol

Conditions
ConditionsYield
With molybdenum hexacarbonyl at 120℃; for 0.5h; Sealed tube; regioselective reaction;99%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide In acetic anhydride; acetic acid; N,N-dimethyl-formamide at 0 - 10℃; for 4h; Substitution; Electrochemical reaction;98%
With water; bromine for 1h;95.5%
With hydrogenchloride In N,N-dimethyl-formamide at 105℃; for 0.5h;95%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

4-methylquinoline trifluoroacetate
143671-61-8

4-methylquinoline trifluoroacetate

4-methyl-2-(tricyclo[3.3.1.13,7]dec-1-yl)quinolone
77492-66-1

4-methyl-2-(tricyclo[3.3.1.13,7]dec-1-yl)quinolone

Conditions
ConditionsYield
With {Au(dppm)}2Cl2 In methanol Inert atmosphere; UV-irradiation;98%
With 2,2'-azobis(isobutyronitrile); 1,1,2,2-tetraphenyldisilane In ethanol for 24h; Product distribution; Heating; other reagents;93%
With 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane In benzene for 14h; Heating;90%
With tetrakis(trimethylsilyl)silane In dichloromethane at 30℃; for 14h; Irradiation;83%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

1-iodoadamantane
768-93-4

1-iodoadamantane

Conditions
ConditionsYield
With hydrogen iodide; cetyltributylphosphonium bromide at 105℃; for 1.75h;98%
With hydrogen iodide at 105℃; for 0.5h;90%
Stage #1: 1-Adamantyl bromide With zinc In tetrahydrofuran for 2h; Reflux;
Stage #2: With iodine In tetrahydrofuran at 20℃;
79%
With potassium iodide at 19.9℃; under 45003600 Torr; under shear deformation (360 deg);19%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

4,4'-bipyridine
553-26-4

4,4'-bipyridine

1-Adamantan-1-yl-[4,4']bipyridinyl-1-ium; bromide
112671-78-0

1-Adamantan-1-yl-[4,4']bipyridinyl-1-ium; bromide

Conditions
ConditionsYield
With water at 180℃; for 4h;98%
styrene
292638-84-7

styrene

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

1-[(1E)-2-phenylethenyl]-tricyclo[3.3.1.13,7]decane
70624-80-5

1-[(1E)-2-phenylethenyl]-tricyclo[3.3.1.13,7]decane

Conditions
ConditionsYield
Stage #1: 1-Adamantyl bromide With palladium diacetate; heptakis(6-amino-6-deoxy)-β-cyclodextrin In water; N,N-dimethyl-formamide for 0.5h;
Stage #2: styrene With potassium carbonate In water; N,N-dimethyl-formamide at 80℃; for 8h;
98%
With (trimethylsilyl)methylmagnesium chloride; Co(1,3-bis(diphenylphosphino)hexane)Cl2 In diethyl ether at 20℃; for 8h; Heck reaction;87%
With Co(1,3-bis(diphenylphosphino)hexane)Cl2; (trimethylsilyl)methylmagnesium chloride In diethyl ether at 20℃; for 8h; Heck reaction;87%
With potassium carbonate; palladium on activated charcoal In N,N-dimethyl-formamide at 100 - 120℃;41%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

o-xylene
95-47-6

o-xylene

1-(1-adamantyl)-3,4-dimethylbenzene
62133-11-3

1-(1-adamantyl)-3,4-dimethylbenzene

Conditions
ConditionsYield
With potassium carbonate; palladium on activated charcoal at 120℃; for 12h;98%
With zinc(II) chloride Substitution; Heating;92%
With zinc(II) chloride for 10h; Heating;90%
With molybdenum hexacarbonyl at 120℃; for 2h; Sealed tube; regioselective reaction;72%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

Tetraethylene glycol
112-60-7

Tetraethylene glycol

2-(2-(2-(2-(((3s,5s,7s)-adamantan-1-yl)oxy)ethoxy)ethoxy)ethoxy)ethan-1-ol

2-(2-(2-(2-(((3s,5s,7s)-adamantan-1-yl)oxy)ethoxy)ethoxy)ethoxy)ethan-1-ol

Conditions
ConditionsYield
With triethylamine at 180℃; for 23h;98%
With triethylamine93%
With triethylamine In dichloromethane at 180℃;91%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

pentafluorophenyl potassium carboxylate
58521-27-0

pentafluorophenyl potassium carboxylate

1-(perfluorophenyl)adamantane
74867-23-5

1-(perfluorophenyl)adamantane

Conditions
ConditionsYield
With copper(l) iodide In diethylene glycol dimethyl ether at 130℃; for 24h; Inert atmosphere;98%
pyridine
110-86-1

pyridine

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

1-(adamantan-1-yl)pyridinium bromide
19984-57-7

1-(adamantan-1-yl)pyridinium bromide

Conditions
ConditionsYield
With water at 180℃; for 6h;97%
at 180℃; for 6h;97%
at 180℃; for 24h;12%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

1-adamantyl fluoride
768-92-3

1-adamantyl fluoride

Conditions
ConditionsYield
With sodium nitrate; (HF)x*C5H5N In dichloromethane for 5h; Ambient temperature;97%
With nitronium tetrafluoborate; pyridine polyhydrogen fluoride In dichloromethane for 3h; Ambient temperature;96%
With n-Bu4PF at 150℃; for 5h;91%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

2-[(1-benzyloxycarbonylamino-ethyl)-hydroxy-phosphinoylmethyl]-4-phenyl-butyric acid ethyl ester
237394-19-3

2-[(1-benzyloxycarbonylamino-ethyl)-hydroxy-phosphinoylmethyl]-4-phenyl-butyric acid ethyl ester

2-[(adamantan-1-yloxy)-(1-benzyloxycarbonylamino-ethyl)-phosphinoylmethyl]-4-phenyl-butyric acid ethyl ester
237394-33-1

2-[(adamantan-1-yloxy)-(1-benzyloxycarbonylamino-ethyl)-phosphinoylmethyl]-4-phenyl-butyric acid ethyl ester

Conditions
ConditionsYield
With silver(l) oxide In chloroform for 0.5h; Heating;97%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

2-[(1-benzyloxycarbonylamino-ethyl)-hydroxy-phosphinoylmethyl]-5-phenyl-pentanoic acid ethyl ester
237394-20-6

2-[(1-benzyloxycarbonylamino-ethyl)-hydroxy-phosphinoylmethyl]-5-phenyl-pentanoic acid ethyl ester

2-[(adamantan-1-yloxy)-(1-benzyloxycarbonylamino-ethyl)-phosphinoylmethyl]-5-phenyl-pentanoic acid ethyl ester
237394-34-2

2-[(adamantan-1-yloxy)-(1-benzyloxycarbonylamino-ethyl)-phosphinoylmethyl]-5-phenyl-pentanoic acid ethyl ester

Conditions
ConditionsYield
With silver(l) oxide In chloroform for 0.5h; Heating;97%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

silver(I)-di(4-methylbenzolsulfonyl)amide
71665-89-9

silver(I)-di(4-methylbenzolsulfonyl)amide

N,N-bis(p-toluenesulfonyl)-1-adamantylamine

N,N-bis(p-toluenesulfonyl)-1-adamantylamine

Conditions
ConditionsYield
In benzene at 20℃; for 96h; Substitution;97%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

trimethyleneglycol
504-63-2

trimethyleneglycol

3-(adamantane-1-yloxy)propan-1-ol
359827-31-9

3-(adamantane-1-yloxy)propan-1-ol

Conditions
ConditionsYield
With triethylamine Heating;97%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

(R,S)-2-isopropyl-3-((1-(N-(9-fluorenylmethoxycarbonyl)amino)methyl)phosphinic acid) propanoic acid allyl ester
937785-33-6

(R,S)-2-isopropyl-3-((1-(N-(9-fluorenylmethoxycarbonyl)amino)methyl)phosphinic acid) propanoic acid allyl ester

(R,S)-2-isopropyl-3-((1-(N-(9-fluorenylmethoxycarbonyl)amino)methyl)adamantyloxyphosphinyl) propanoic acid allyl ester

(R,S)-2-isopropyl-3-((1-(N-(9-fluorenylmethoxycarbonyl)amino)methyl)adamantyloxyphosphinyl) propanoic acid allyl ester

Conditions
ConditionsYield
With silver(l) oxide In chloroform for 2h; Heating;97%
With silver(l) oxide In chloroform for 2.83333h; Heating / reflux;97%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

trimethylstannane
1631-73-8

trimethylstannane

A

adamantane
281-23-2

adamantane

B

n-butyltrimethyltin
1527-99-7

n-butyltrimethyltin

Conditions
ConditionsYield
With n-butyllithium In hexane 1-bromoadamantane (1 equiv.) and TMTH (1 equiv.) in hexane cooled to 0°C under Ar, n-BuLi (1 equiv., 2.40 M in hexane) added, stirred for 15 min, quenched with water; analyzed by GC;A 97%
B 95%

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