Product Description Product website: http://www.finerchem.com/pro01en/id/853.html Product Name 1-Adamantanol
DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:768-95-6
Min.Order:1 Kilogram
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:768-95-6
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inquiryManufacturer supply 1-Adamantanol Cas 768-95-6 with best price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed additi
Cas:768-95-6
Min.Order:10 Kilogram
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inquiryThe company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance:White to off-white Crystalline Powder or Ne
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
TIANFUCHEM--768-95-6--1-Adamantanol in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relationships
Cas:768-95-6
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
Cas:768-95-6
Min.Order:1 Gram
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:768-95-6
Min.Order:1 Kilogram
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inquiryProduct Name 1-Adamantanol Melting Point 247 °C (subl.) (lit.) CAS Number 768-95-6 Boiling Point 214.73°C (rough estimate) Appear
1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta
Cas:768-95-6
Min.Order:10 Gram
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inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:768-95-6
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inquiry1-Adamantanol CAS:768-95-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates
Cas:768-95-6
Min.Order:1 Gram
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Overview of Our Factories Our Factories production lines Our Factories R&D ability Our Factories warehouse Our Factorie
Cas:768-95-6
Min.Order:1 Kilogram
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Appearance: white to off-white crystalline powder... Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:C
Cas:768-95-6
Min.Order:100 Metric Ton
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inquiry1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie
Cas:768-95-6
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:768-95-6
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inquiryCompany Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:768-95-6
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryFactory 1-Adamantanol in stock CAS No.768-95-6Appearance:powder Storage:Dry, ventilated Package:according to customers' requirements Application:API, Used as pharmaceutical intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by
Cas:768-95-6
Min.Order:1 Gram
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inquiryProduct name: 1-Adamantanol CAS No.:768-95-6 Molecule Formula:C10H16O Molecule Weight:152.23 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard TESTING I
Cas:768-95-6
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiryCangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, in
Cas:768-95-6
Min.Order:1 Kilogram
FOB Price: $777.0 / 888.0
Type:Lab/Research institutions
inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:768-95-6
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryConditions | Yield |
---|---|
With tert-butyldibutyltin chloride; sodium cyanoborohydride In tert-butyl alcohol at 33℃; for 18h; Ultrasound with 20 KHz and bubbling of air; | 100% |
With 2,2'-azobis(isobutyronitrile); PVS; N-ethylpiperidinium hypophosphite In 1,4-dioxane; water at 100℃; for 0.5h; | 72% |
With PVS; (CH3)3N(+)(CH2)15CH3*H2PO2(-); 4,4'-dicyano-4,4'-azo-di-valeric acid In water at 100℃; for 1h; | 70% |
Conditions | Yield |
---|---|
With Fe(AAEMA)3; oxygen; isovaleraldehyde In 1,2-dichloro-ethane under 760 Torr; for 60h; Ambient temperature; | 99% |
With oxone; 1,1,1-trifluoro-2-propanone; sodium hydrogencarbonate In dichloromethane; water at 0 - 25℃; under 3878.71 Torr; for 0.0222222h; Reagent/catalyst; Temperature; Solvent; | 99% |
With water; bromine for 1h; Ambient temperature; | 95% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate; [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; oxygen; caesium carbonate In dichloromethane at 40℃; for 40h; Irradiation; | 99% |
With manganese(IV) oxide; sulfuric acid at 25 - 30℃; | 82% |
Stage #1: 1-Adamantanecarboxylic acid With dipotassium hydrogenphosphate; oxygen; 9-(2-mesityl)-10-methylacridinium perchlorate In chloroform at 20℃; for 48h; Schlenk technique; Irradiation; Green chemistry; Stage #2: With sodium tetrahydroborate In methanol; chloroform for 0.5h; Green chemistry; | 40% |
2-(tricyclo[3.3.1.13,7]dec-1-yloxy)tetrahydro-2H-pyran
1-adamanthanol
Conditions | Yield |
---|---|
poly(4-vinylpyridinium) p-toluenesulfonate In tetrahydrofuran; ethanol at 75℃; for 50h; Hydrolysis; | 99% |
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In methanol; water for 1h; Ambient temperature; | 96% |
With methanol at 20℃; for 0.666667h; | 92% |
1-trimethylsiloxyadamantane
1-adamanthanol
Conditions | Yield |
---|---|
With methanol; 1,3-disulfonic acid imidazolium hydrogen sulfate at 20℃; for 0.1h; Green chemistry; | 99% |
With poly (ethylene glycol)-sulfonated sodium montmorillonite nanocomposite In methanol at 20℃; for 0.333333h; | 96% |
With silicaphosphite (silphos), [PCl3-n(SiO2)n] In acetonitrile at 20℃; for 0.0333333h; | 95% |
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide In acetic anhydride; acetic acid; N,N-dimethyl-formamide at 0 - 10℃; for 4h; Substitution; Electrochemical reaction; | 98% |
With water; bromine for 1h; | 95.5% |
With hydrogenchloride In N,N-dimethyl-formamide at 105℃; for 0.5h; | 95% |
Conditions | Yield |
---|---|
With [2,2]bipyridinyl; Ba; trifluoroacetic acid In dichloromethane at 20℃; for 0.0333333h; Product distribution; | A n/a B 97% C n/a |
With [2,2]bipyridinyl; Ba; trifluoroacetic acid In dichloromethane at 20℃; for 0.0333333h; Yields of byproduct given; | A n/a B 97% C n/a |
With ammonium cerium(IV) nitrate; oxygen In acetonitrile for 5h; Ambient temperature; Irradiation; | A 5% B 85% C 5% |
1-adamanthanol
Conditions | Yield |
---|---|
With ytterbium(III) triflate In methanol at 50℃; for 36h; | 97% |
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile); oxygen; tert-butyldibutyltin chloride; sodium cyanoborohydride In tert-butyl alcohol at 60℃; for 20h; Yields of byproduct given; | A n/a B 96% |
With 2-(2-methoxyethoxy)ethyl alcohol; oxygen; sodium hydride In 1,4-dioxane at 20℃; for 24h; Schlenk technique; chemoselective reaction; | A 42% B n/a |
1-(tert-butyldimethylsiloxy)tricyclo[3.3.1.1]decane
1-adamanthanol
Conditions | Yield |
---|---|
With 2,5-bis(perfluorohexyl)-3,6-dichloro-1,4-benzoquinone In water; acetonitrile at 50℃; for 6h; | 96% |
With N-iodo-succinimide In methanol at 20℃; for 24h; | 69% |
sulfonic acid functionalized nanoporous silica In methanol at 35℃; for 24h; | 50 % Chromat. |
1-adamanthanol
Conditions | Yield |
---|---|
With zinc diacetate In methanol; dichloromethane at 38℃; for 30h; | 96% |
Conditions | Yield |
---|---|
Stage #1: adamantane; trifluoroacetic acid With oxygen; sodium nitrite at 20℃; for 3h; Stage #2: With hydrogenchloride Further stages.; | 96% |
adamantan-1-yl 4-methylbenzoate
1-adamanthanol
Conditions | Yield |
---|---|
With tetrabutylammonium tetrafluoroborate In 1-methyl-pyrrolidin-2-one; isopropyl alcohol at 90℃; Electrochemical reaction; chemoselective reaction; | 95% |
With tetrabutylammonium tetrafluoroborate; isopropyl alcohol In 1-methyl-pyrrolidin-2-one at 90 - 100℃; Inert atmosphere; Electrolysis; | 95% |
(3S,5S,7S)-1-((4-methoxybenzyl)oxy)adamantane
1-adamanthanol
Conditions | Yield |
---|---|
With ammonium peroxydisulfate; 9-(2-mesityl)-10-methylacridinium perchlorate In water; acetonitrile at 20 - 30℃; for 5h; Irradiation; Green chemistry; | 95% |
1-(2-propenyloxy)tricyclo<3.3.1.13,7>decane
1-adamanthanol
Conditions | Yield |
---|---|
With tert.-butyl lithium In pentane at -78 - 20℃; Substitution; | 94% |
With 1,3-dimethylbarbituric acid; Pd(PPh3) In tetrahydrofuran at 90℃; for 24h; | 87% |
With aminomethyl resin-supported N-propylbarbituric acid; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 90℃; for 24h; | 86% |
1-adamanthanol
Conditions | Yield |
---|---|
Stage #1: 4-benzyloxy-butyric acid adamantan-1-yl ester With hydrogen; palladium on activated charcoal In tetrahydrofuran under 760 Torr; for 24h; Stage #2: With potassium tert-butylate In tetrahydrofuran for 0.166667h; | 93% |
1-adamantyl benzyl ether
1-adamanthanol
Conditions | Yield |
---|---|
With water; 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate In acetonitrile at 20℃; for 8h; | 93% |
With triphenylphosphine hydrobromide In acetonitrile at 100℃; for 0.5h; Microwave irradiation; sealed tube; | 83% |
Di(1-adamantyl)-tert-butylmethanol
A
1-adamanthanol
B
tert-butyl alcohol
Conditions | Yield |
---|---|
With n-butyllithium In N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at 20℃; Product distribution; | A 8.6% B 92.4% |
adamantane
3,3-dimethyldioxirane
A
2-Adamantanone
B
1-adamanthanol
C
1-adamantanol
D
1,3-adamantandiol
E
1-acetyloxyadamantane
Conditions | Yield |
---|---|
In acetone at 20℃; for 7.6h; Rate constant; Product distribution; Kinetics; | A 1.5% B 91.5% C 1% D 4.5% E 1.5% |
1-(adamantane-1-carbonyloxy)pyridine-2(1H)-thione
1-adamanthanol
Conditions | Yield |
---|---|
With antimony triphenylsulphide In diethyl ether for 1h; Ambient temperature; | 91% |
With oxygen; thiophenol; antimony tris-benzenethiolate In diethyl ether for 0.5h; Ambient temperature; | 91% |
(3r,5r,7r)-adamantan-1-ylboronic acid
1-adamanthanol
Conditions | Yield |
---|---|
With rose bengal; triethylamine In ethanol at 25℃; for 12h; Schlenk technique; Irradiation; | 91% |
2-((3r,5r,7r)-adamantan-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1-adamanthanol
Conditions | Yield |
---|---|
With rose bengal; triethylamine In ethanol at 25℃; for 12h; Schlenk technique; Irradiation; | 91% |
1-adamanthanol
Conditions | Yield |
---|---|
With trimethyltin(IV) hydroxide In 1,2-dichloro-ethane at 60℃; for 16h; Inert atmosphere; chemoselective reaction; | 91% |
acetonitrile
trans-N,N'-bis(1-adamantyl)diazene
A
1,1'-Biadamantane
B
adamantane
C
1-adamanthanol
D
N-(1-adamantyl)acetamide
Conditions | Yield |
---|---|
With thianthrene cation radical perchlorate Ambient temperature; Further byproducts given; | A 3% B 0.3% C 0.6% D 90% |
acetonitrile
trans-N,N'-bis(1-adamantyl)diazene
A
1,1'-Biadamantane
B
1-adamanthanol
C
N-(1-adamantyl)acetamide
D
1-acetyladamantane
Conditions | Yield |
---|---|
With thianthrenium perchlorate Ambient temperature; Further byproducts given; | A 2.5% B 0.6% C 90% D 5.5% |
adamantane
A
1-adamanthanol
B
1-nitroadamantane
C
1-nitroxyadamantane
Conditions | Yield |
---|---|
With Nitrogen dioxide; ozone In dichloromethane at -78℃; for 0.5h; | A n/a B 90% C n/a |
With methanesulfonic acid; dinitrogen pentoxide In dichloromethane at 0℃; for 1h; |
Di(1-adamantyl)(1-norbornyl)methanol
A
1-adamanthanol
B
1-norbornyl alcohol
Conditions | Yield |
---|---|
With n-butyllithium In N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at 20℃; Product distribution; | A 89.7% B 10.3% |
1-adamantyl trifluoroacetate
1-adamanthanol
Conditions | Yield |
---|---|
With sodium hydroxide In water at 100℃; for 0.5h; | 89% |
With potassium hydroxide In ethanol; water at 25℃; for 0.5h; Yield given; | |
With sodium carbonate for 2h; Heating; Yield given; |
adamantane
trifluoroacetic acid
A
1-adamanthanol
B
2-adamantyl trifluoroacetate
Conditions | Yield |
---|---|
With peracetic acid; ruthenium trichloride In dichloromethane; ethyl acetate at 20℃; for 2h; | A 89% B 9% |
trityl tetrafluoroborate
1-<(methylthio)methoxy>tricyclo<3.3.1.13,7>decane
A
triphenylmethyl alcohol
B
1-adamanthanol
C
triphenmethyl methyl sulfide
Conditions | Yield |
---|---|
In dichloromethane for 0.25h; Ambient temperature; | A 77% B 88% C 16% |
In dichloromethane for 0.25h; Product distribution; Mechanism; Ambient temperature; quenching with aq. NaHCO3, other trityl salts; | A 77% B 88% C 16% |
Conditions | Yield |
---|---|
With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 18h; | 100% |
With chlorosulfonic acid In chloroform at 10 - 15℃; for 8h; | 96% |
With indium(III) chloride; dimethylmonochlorosilane; benzil In dichloromethane at 20℃; for 82h; | 93% |
carbon disulfide
1-adamanthanol
methyl iodide
O-(adamantan-1-yl) S-methyl carbonodithioate
Conditions | Yield |
---|---|
Stage #1: carbon disulfide; 1-adamanthanol With 1H-imidazole; sodium hydride In tetrahydrofuran at 20℃; for 0.5h; Stage #2: methyl iodide In tetrahydrofuran at 20℃; for 0.5h; | 100% |
Stage #1: carbon disulfide; 1-adamanthanol With sodium hydride In tetrahydrofuran at 20℃; for 10h; Addition; Stage #2: methyl iodide In tetrahydrofuran at 20℃; for 1h; Methylation; | 78% |
Stage #1: 1-adamanthanol With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 2h; Stage #2: carbon disulfide In tetrahydrofuran; mineral oil at 0 - 20℃; for 15h; Stage #3: methyl iodide In tetrahydrofuran; mineral oil at 0℃; for 2h; | 72% |
Conditions | Yield |
---|---|
With sulfuric acid; acetic acid at 20℃; for 48h; Friedel Crafts alkylation; | 100% |
With sulfuric acid; acetic acid In dichloromethane at 20℃; for 24h; | 100% |
With sulfuric acid; acetic acid In dichloromethane at 20℃; for 48h; Friedel-Crafts Alkylation; Large scale; | 99% |
Conditions | Yield |
---|---|
With magnesium(II) perchlorate at 20℃; for 0.33h; | 100% |
With tin(IV) tetraphenylporphyrin perchlorate at 20℃; for 0.25h; | 99% |
With silica gel for 0.0583333h; Microwave irradiation; neat (no solvent); | 99% |
1-adamanthanol
4-bromo-4'-hydroxybiphenyl
4-(4'-bromophenyl)-2-(adamantan-1-yl)phenol
Conditions | Yield |
---|---|
With sulfuric acid; acetic acid at 25℃; for 72h; Friedel-Crafts reaction; | 100% |
With sulfuric acid; acetic acid at 20℃; for 96h; | 100% |
With sulfuric acid; acetic acid at 20℃; for 96h; | 100% |
With sulfuric acid In acetone at 20℃; for 96h; Cooling with ice; | 100% |
Friedel-Crafts alkylation; |
Conditions | Yield |
---|---|
With sulfuric acid at 20℃; for 4h; | 100% |
With phosphoric acid; acetic acid at 40 - 42℃; for 5h; | 100% |
Conditions | Yield |
---|---|
With N-Methyldicyclohexylamine; copper diacetate In toluene at 20℃; for 1h; | 100% |
Conditions | Yield |
---|---|
With trifluoroacetic acid at 20℃; for 6h; Inert atmosphere; | 100% |
With trifluoroacetic acid at 20℃; for 12h; | 85% |
With trifluoroacetic acid | 79% |
With sulfuric acid In dichloromethane at 20℃; Inert atmosphere; | 23% |
With sulfuric acid In dichloromethane at 20℃; Inert atmosphere; |
1-adamanthanol
cobalt(II) bis(trimethylsilyl)amide
Conditions | Yield |
---|---|
In benzene under Ar, refluxed briefly; filtered, washed with ether, elem. anal.; | 100% |
Conditions | Yield |
---|---|
With indium(III) triflate; acetylacetone for 2h; Reflux; Green chemistry; | 100% |
With trifluoroacetic acid at 20℃; for 12h; | 86% |
Conditions | Yield |
---|---|
With tungsten hexacarbonyl at 180℃; for 1h; chemoselective reaction; | 100% |
1-adamanthanol
2,3,4-tri-O-benzyl-L-rhamnopyranosyl ortho-hex-1-ynylbenzoate
Conditions | Yield |
---|---|
Stage #1: 1-adamanthanol; 2,3,4-tri-O-benzyl-L-rhamnopyranosyl ortho-hex-1-ynylbenzoate In dichloromethane at 20℃; for 0.5h; Inert atmosphere; Molecular sieve; Stage #2: With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere; Molecular sieve; | 100% |
1-adamanthanol
Conditions | Yield |
---|---|
With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78℃; Molecular sieve; Inert atmosphere; stereoselective reaction; | 100% |
Conditions | Yield |
---|---|
With triisopropylborane; trifluorormethanesulfonic acid In 1,1,2-Trichloro-1,2,2-trifluoroethane 1.) -30 deg C, 30 min 2.) room temp., 6 h; | A 99.9% B 0.1% |
Conditions | Yield |
---|---|
Stage #1: 1-adamanthanol; chloroacetonitrile With sulfuric acid In acetic acid; N,N-dimethyl-formamide at 20 - 80℃; Stage #2: With water In acetic acid; N,N-dimethyl-formamide at 70℃; | 99.6% |
Stage #1: 1-adamanthanol; chloroacetonitrile With acetic acid In N,N-dimethyl-formamide Stage #2: With sulfuric acid; water In N,N-dimethyl-formamide at 20 - 80℃; Product distribution / selectivity; | 99.6% |
With sulfuric acid; acetic acid at 20℃; for 5h; Ritter reaction; | 95% |
With indium(III) triflate In sulfur dioxide at -50 - 100℃; for 24h; Ritter Amidation; Inert atmosphere; Autoclave; liquid SO2; | 79% |
Conditions | Yield |
---|---|
With copper(ll) bromide at 150℃; for 8h; Reagent/catalyst; Ritter Amidation; Inert atmosphere; Sealed tube; | 99% |
With trifluoromethylsulfonic anhydride; sodium hydrogencarbonate In dichloromethane for 2h; Ambient temperature; | 98% |
With water; tert-butylammonium hexafluorophosphate(V); calcium(II) trifluoromethanesulfonate In neat (no solvent) at 140℃; for 0.416667h; Ritter Amidation; Microwave irradiation; Green chemistry; | 95% |
Conditions | Yield |
---|---|
With oxygen; 1,2-dibromomethane for 10h; Reflux; | 99% |
With iron(III)-acetylacetonate; carbon tetrabromide at 120℃; for 2h; Sealed tube; Inert atmosphere; | 99% |
With dibromo sulfoxide In toluene for 22h; | 96% |
Conditions | Yield |
---|---|
With hydrogen; aluminum oxide; nickel at 180℃; | 99% |
With indium(III) chloride; diphenylsilyl chloride In 1,2-dichloro-ethane at 80℃; for 3h; | 99% |
With boron trifluoride diethyl etherate In water for 2h; Inert atmosphere; Reflux; | 29% |
Conditions | Yield |
---|---|
With iron(III) chloride In 1,2-dichloro-ethane at 50℃; for 24h; Inert atmosphere; Sealed tube; | 99% |
With oxalic acid; 2,3,4,5-tetrafluorophenyl(dihydroxy)borane In nitromethane at 20℃; | 87% |
With sulfuric acid for 2h; | 66% |
1-adamanthanol
1,1,1,3,3,3-hexamethyl-disilazane
1-trimethylsiloxyadamantane
Conditions | Yield |
---|---|
iodine In dichloromethane at 20℃; for 0.1h; Substitution; | 99% |
With silica-supported ZnCl2 (30%) In acetonitrile at 20℃; for 0.35h; | 98% |
With aluminum tris(dihydrogen phosphate) at 20℃; for 0.933333h; | 97% |
Conditions | Yield |
---|---|
With sodium hydride In tetrahydrofuran | 99% |
With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 20h; | 81% |
With sodium hydride In tetrahydrofuran | |
Stage #1: 1-adamanthanol With sodium hydride In tetrahydrofuran at 0℃; for 1h; Inert atmosphere; Stage #2: methyl iodide In tetrahydrofuran at 0 - 20℃; Inert atmosphere; |
Conditions | Yield |
---|---|
With zinc(II) fluoride In dichloromethane for 18h; | 99% |
Conditions | Yield |
---|---|
With copper(ll) bromide at 150℃; for 6h; Ritter Amidation; Inert atmosphere; Sealed tube; | 99% |
With bismuth(lll) trifluoromethanesulfonate; water Ritter reaction; | 91% |
With water; tert-butylammonium hexafluorophosphate(V); calcium(II) trifluoromethanesulfonate In neat (no solvent) at 140℃; for 0.416667h; Ritter Amidation; Microwave irradiation; Green chemistry; | 90% |
1-adamanthanol
2,3,4-tri-O-acetyl-L-rhamnopyranosyl (N-phenyl)-2,2,2-trifluoroacetimidate
Conditions | Yield |
---|---|
With trimethylsilyl trifluoromethanesulfonate In dichloromethane at 25℃; for 3h; | 99% |
1-adamanthanol
2,3,4,6-tetra-O-benzoyl-D-glucopyranosyl 1-(N-phenyl)-2,2,2-trifluoroacetimidate
Conditions | Yield |
---|---|
With trimethylsilyl trifluoromethanesulfonate In dichloromethane at 25℃; for 3h; | 99% |
1-adamanthanol
25,27-bis(benzyloxy)-26,28-dihydroxycalix[4]arene
Conditions | Yield |
---|---|
With trifluoroacetic acid In chloroform at 60 - 65℃; for 9h; | 99% |
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