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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/853.html Product Name 1-Adamantanol

1-Adamantanol

Cas:768-95-6

Min.Order:1 Gram

FOB Price: $34.0

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

1-Adamantanol

Cas:768-95-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1-Adamantanol supplier in China

Cas:768-95-6

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

Manufacturer supply 1-Adamantanol Cas 768-95-6 with best price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed additi

Manufacturer supply 1-Adamantanol Cas 768-95-6 with best price

Cas:768-95-6

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

The company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance:White to off-white Crystalline Powder or Ne

1-AdaMantanol

Cas:768-95-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1-Adamantanol

Cas:768-95-6

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1-Adamantanol

Cas:768-95-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--768-95-6--1-Adamantanol in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relationships

TIANFUCHEM--768-95-6--1-Adamantanol in stock

Cas:768-95-6

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

1-Adamantanol CAS 768-95-6

Cas:768-95-6

Min.Order:1 Gram

FOB Price: $6.0 / 9.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 768-95-6 with best quality

Cas:768-95-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name 1-Adamantanol Melting Point 247 °C (subl.) (lit.) CAS Number 768-95-6 Boiling Point 214.73°C (rough estimate) Appear

1-Adamantanol CAS:768-95-6

Cas:768-95-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta

high quality 768-95-6 1-Adamantanol with best price

Cas:768-95-6

Min.Order:10 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1-Adamantanol 768-95-6

Cas:768-95-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

1-Adamantanol CAS:768-95-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates

1-Adamantanol CAS:768-95-6

Cas:768-95-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1-Adamantanol

Cas:768-95-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Leader Biochemical Group

Overview of Our Factories Our Factories production lines Our Factories R&D ability Our Factories warehouse Our Factorie

China Biggest Factory & Manufacturer supply 1-Adamantanol

Cas:768-95-6

Min.Order:1 Kilogram

FOB Price: $30.0 / 35.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:768-95-6

Cas:768-95-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

1-Adamantanol

Cas:768-95-6

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Appearance: white to off-white crystalline powder... Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:C

1-Hydroxyadamantane

Cas:768-95-6

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS768-95-6 1-Adamantanol

Cas:768-95-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1-adamantanol; 1-hydroxyadamantane

Cas:768-95-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

1-ADAMANTANOL

Cas:768-95-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-Adamantanol

Cas:768-95-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1-Adamantanol

Cas:768-95-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

1-Adamantanol

Cas:768-95-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1-Adamantanol

Cas:768-95-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

Factory 1-Adamantanol in stock CAS No.768-95-6Appearance:powder Storage:Dry, ventilated Package:according to customers' requirements Application:API, Used as pharmaceutical intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by

Factory 1-Adamantanol in stock CAS No.768-95-6

Cas:768-95-6

Min.Order:1 Gram

Negotiable

Type:Other

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Siwei Development Group Ltd.

Product name: 1-Adamantanol CAS No.:768-95-6 Molecule Formula:C10H16O Molecule Weight:152.23 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard TESTING I

High Quality 1-Adamantanol

Cas:768-95-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, in

1-Adamantanol

Cas:768-95-6

Min.Order:1 Kilogram

FOB Price: $777.0 / 888.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High quality 1-Adamantanol supplier in China

Cas:768-95-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Synthetic route

1-iodoadamantane
768-93-4

1-iodoadamantane

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With tert-butyldibutyltin chloride; sodium cyanoborohydride In tert-butyl alcohol at 33℃; for 18h; Ultrasound with 20 KHz and bubbling of air;100%
With 2,2'-azobis(isobutyronitrile); PVS; N-ethylpiperidinium hypophosphite In 1,4-dioxane; water at 100℃; for 0.5h;72%
With PVS; (CH3)3N(+)(CH2)15CH3*H2PO2(-); 4,4'-dicyano-4,4'-azo-di-valeric acid In water at 100℃; for 1h;70%
adamantane
281-23-2

adamantane

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With Fe(AAEMA)3; oxygen; isovaleraldehyde In 1,2-dichloro-ethane under 760 Torr; for 60h; Ambient temperature;99%
With oxone; 1,1,1-trifluoro-2-propanone; sodium hydrogencarbonate In dichloromethane; water at 0 - 25℃; under 3878.71 Torr; for 0.0222222h; Reagent/catalyst; Temperature; Solvent;99%
With water; bromine for 1h; Ambient temperature;95%
1-Adamantanecarboxylic acid
828-51-3

1-Adamantanecarboxylic acid

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With sodium tetrahydroborate; [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; oxygen; caesium carbonate In dichloromethane at 40℃; for 40h; Irradiation;99%
With manganese(IV) oxide; sulfuric acid at 25 - 30℃;82%
Stage #1: 1-Adamantanecarboxylic acid With dipotassium hydrogenphosphate; oxygen; 9-(2-mesityl)-10-methylacridinium perchlorate In chloroform at 20℃; for 48h; Schlenk technique; Irradiation; Green chemistry;
Stage #2: With sodium tetrahydroborate In methanol; chloroform for 0.5h; Green chemistry;
40%
2-(tricyclo[3.3.1.13,7]dec-1-yloxy)tetrahydro-2H-pyran
88773-89-1

2-(tricyclo[3.3.1.13,7]dec-1-yloxy)tetrahydro-2H-pyran

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
poly(4-vinylpyridinium) p-toluenesulfonate In tetrahydrofuran; ethanol at 75℃; for 50h; Hydrolysis;99%
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In methanol; water for 1h; Ambient temperature;96%
With methanol at 20℃; for 0.666667h;92%
1-trimethylsiloxyadamantane
36960-53-9

1-trimethylsiloxyadamantane

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With methanol; 1,3-disulfonic acid imidazolium hydrogen sulfate at 20℃; for 0.1h; Green chemistry;99%
With poly (ethylene glycol)-sulfonated sodium montmorillonite nanocomposite In methanol at 20℃; for 0.333333h;96%
With silicaphosphite (silphos), [PCl3-n(SiO2)n] In acetonitrile at 20℃; for 0.0333333h;95%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide In acetic anhydride; acetic acid; N,N-dimethyl-formamide at 0 - 10℃; for 4h; Substitution; Electrochemical reaction;98%
With water; bromine for 1h;95.5%
With hydrogenchloride In N,N-dimethyl-formamide at 105℃; for 0.5h;95%
adamantane
281-23-2

adamantane

A

2-Adamantanone
700-58-3

2-Adamantanone

B

1-adamanthanol
768-95-6

1-adamanthanol

C

1-adamantanol
700-57-2

1-adamantanol

Conditions
ConditionsYield
With [2,2]bipyridinyl; Ba; trifluoroacetic acid In dichloromethane at 20℃; for 0.0333333h; Product distribution;A n/a
B 97%
C n/a
With [2,2]bipyridinyl; Ba; trifluoroacetic acid In dichloromethane at 20℃; for 0.0333333h; Yields of byproduct given;A n/a
B 97%
C n/a
With ammonium cerium(IV) nitrate; oxygen In acetonitrile for 5h; Ambient temperature; Irradiation;A 5%
B 85%
C 5%
1-adamantyl methoxyacetate

1-adamantyl methoxyacetate

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With ytterbium(III) triflate In methanol at 50℃; for 36h;97%
1-iodoadamantane
768-93-4

1-iodoadamantane

A

adamantane
281-23-2

adamantane

B

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); oxygen; tert-butyldibutyltin chloride; sodium cyanoborohydride In tert-butyl alcohol at 60℃; for 20h; Yields of byproduct given;A n/a
B 96%
With 2-(2-methoxyethoxy)ethyl alcohol; oxygen; sodium hydride In 1,4-dioxane at 20℃; for 24h; Schlenk technique; chemoselective reaction;A 42%
B n/a
1-(tert-butyldimethylsiloxy)tricyclo[3.3.1.1]decane
76358-85-5

1-(tert-butyldimethylsiloxy)tricyclo[3.3.1.1]decane

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With 2,5-bis(perfluorohexyl)-3,6-dichloro-1,4-benzoquinone In water; acetonitrile at 50℃; for 6h;96%
With N-iodo-succinimide In methanol at 20℃; for 24h;69%
sulfonic acid functionalized nanoporous silica In methanol at 35℃; for 24h;50 % Chromat.
pyridine-2-carboxylic acid adamantan-1-yl ester

pyridine-2-carboxylic acid adamantan-1-yl ester

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With zinc diacetate In methanol; dichloromethane at 38℃; for 30h;96%
adamantane
281-23-2

adamantane

trifluoroacetic acid
76-05-1

trifluoroacetic acid

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
Stage #1: adamantane; trifluoroacetic acid With oxygen; sodium nitrite at 20℃; for 3h;
Stage #2: With hydrogenchloride Further stages.;
96%
adamantan-1-yl 4-methylbenzoate
1036648-27-7

adamantan-1-yl 4-methylbenzoate

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With tetrabutylammonium tetrafluoroborate In 1-methyl-pyrrolidin-2-one; isopropyl alcohol at 90℃; Electrochemical reaction; chemoselective reaction;95%
With tetrabutylammonium tetrafluoroborate; isopropyl alcohol In 1-methyl-pyrrolidin-2-one at 90 - 100℃; Inert atmosphere; Electrolysis;95%
(3S,5S,7S)-1-((4-methoxybenzyl)oxy)adamantane
220235-72-3

(3S,5S,7S)-1-((4-methoxybenzyl)oxy)adamantane

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With ammonium peroxydisulfate; 9-(2-mesityl)-10-methylacridinium perchlorate In water; acetonitrile at 20 - 30℃; for 5h; Irradiation; Green chemistry;95%
1-(2-propenyloxy)tricyclo<3.3.1.13,7>decane
135394-83-1

1-(2-propenyloxy)tricyclo<3.3.1.13,7>decane

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With tert.-butyl lithium In pentane at -78 - 20℃; Substitution;94%
With 1,3-dimethylbarbituric acid; Pd(PPh3) In tetrahydrofuran at 90℃; for 24h;87%
With aminomethyl resin-supported N-propylbarbituric acid; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 90℃; for 24h;86%
4-benzyloxy-butyric acid adamantan-1-yl ester

4-benzyloxy-butyric acid adamantan-1-yl ester

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
Stage #1: 4-benzyloxy-butyric acid adamantan-1-yl ester With hydrogen; palladium on activated charcoal In tetrahydrofuran under 760 Torr; for 24h;
Stage #2: With potassium tert-butylate In tetrahydrofuran for 0.166667h;
93%
1-adamantyl benzyl ether
23569-25-7

1-adamantyl benzyl ether

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With water; 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate In acetonitrile at 20℃; for 8h;93%
With triphenylphosphine hydrobromide In acetonitrile at 100℃; for 0.5h; Microwave irradiation; sealed tube;83%
Di(1-adamantyl)-tert-butylmethanol
80514-85-8

Di(1-adamantyl)-tert-butylmethanol

A

1-adamanthanol
768-95-6

1-adamanthanol

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With n-butyllithium In N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at 20℃; Product distribution;A 8.6%
B 92.4%
adamantane
281-23-2

adamantane

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

A

2-Adamantanone
700-58-3

2-Adamantanone

B

1-adamanthanol
768-95-6

1-adamanthanol

C

1-adamantanol
700-57-2

1-adamantanol

D

1,3-adamantandiol
5001-18-3

1,3-adamantandiol

E

1-acetyloxyadamantane
22635-62-7

1-acetyloxyadamantane

Conditions
ConditionsYield
In acetone at 20℃; for 7.6h; Rate constant; Product distribution; Kinetics;A 1.5%
B 91.5%
C 1%
D 4.5%
E 1.5%
1-(adamantane-1-carbonyloxy)pyridine-2(1H)-thione
91233-19-1

1-(adamantane-1-carbonyloxy)pyridine-2(1H)-thione

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With antimony triphenylsulphide In diethyl ether for 1h; Ambient temperature;91%
With oxygen; thiophenol; antimony tris-benzenethiolate In diethyl ether for 0.5h; Ambient temperature;91%
(3r,5r,7r)-adamantan-1-ylboronic acid
660427-99-6

(3r,5r,7r)-adamantan-1-ylboronic acid

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With rose bengal; triethylamine In ethanol at 25℃; for 12h; Schlenk technique; Irradiation;91%
2-((3r,5r,7r)-adamantan-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1357000-33-9

2-((3r,5r,7r)-adamantan-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With rose bengal; triethylamine In ethanol at 25℃; for 12h; Schlenk technique; Irradiation;91%
C13H17Cl3O3

C13H17Cl3O3

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With trimethyltin(IV) hydroxide In 1,2-dichloro-ethane at 60℃; for 16h; Inert atmosphere; chemoselective reaction;91%
acetonitrile
75-05-8

acetonitrile

trans-N,N'-bis(1-adamantyl)diazene
24325-56-2

trans-N,N'-bis(1-adamantyl)diazene

A

1,1'-Biadamantane
3732-31-8

1,1'-Biadamantane

B

adamantane
281-23-2

adamantane

C

1-adamanthanol
768-95-6

1-adamanthanol

D

N-(1-adamantyl)acetamide
880-52-4

N-(1-adamantyl)acetamide

Conditions
ConditionsYield
With thianthrene cation radical perchlorate Ambient temperature; Further byproducts given;A 3%
B 0.3%
C 0.6%
D 90%
acetonitrile
75-05-8

acetonitrile

trans-N,N'-bis(1-adamantyl)diazene
24325-56-2

trans-N,N'-bis(1-adamantyl)diazene

A

1,1'-Biadamantane
3732-31-8

1,1'-Biadamantane

B

1-adamanthanol
768-95-6

1-adamanthanol

C

N-(1-adamantyl)acetamide
880-52-4

N-(1-adamantyl)acetamide

D

1-acetyladamantane
1660-04-4

1-acetyladamantane

Conditions
ConditionsYield
With thianthrenium perchlorate Ambient temperature; Further byproducts given;A 2.5%
B 0.6%
C 90%
D 5.5%
adamantane
281-23-2

adamantane

A

1-adamanthanol
768-95-6

1-adamanthanol

B

1-nitroadamantane
7575-82-8

1-nitroadamantane

C

1-nitroxyadamantane
32314-61-7

1-nitroxyadamantane

Conditions
ConditionsYield
With Nitrogen dioxide; ozone In dichloromethane at -78℃; for 0.5h;A n/a
B 90%
C n/a
With methanesulfonic acid; dinitrogen pentoxide In dichloromethane at 0℃; for 1h;
Di(1-adamantyl)(1-norbornyl)methanol
89849-39-8

Di(1-adamantyl)(1-norbornyl)methanol

A

1-adamanthanol
768-95-6

1-adamanthanol

B

1-norbornyl alcohol
51566-98-4

1-norbornyl alcohol

Conditions
ConditionsYield
With n-butyllithium In N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at 20℃; Product distribution;A 89.7%
B 10.3%
1-adamantyl trifluoroacetate
58652-54-3

1-adamantyl trifluoroacetate

1-adamanthanol
768-95-6

1-adamanthanol

Conditions
ConditionsYield
With sodium hydroxide In water at 100℃; for 0.5h;89%
With potassium hydroxide In ethanol; water at 25℃; for 0.5h; Yield given;
With sodium carbonate for 2h; Heating; Yield given;
adamantane
281-23-2

adamantane

trifluoroacetic acid
76-05-1

trifluoroacetic acid

A

1-adamanthanol
768-95-6

1-adamanthanol

B

2-adamantyl trifluoroacetate
34909-02-9

2-adamantyl trifluoroacetate

Conditions
ConditionsYield
With peracetic acid; ruthenium trichloride In dichloromethane; ethyl acetate at 20℃; for 2h;A 89%
B 9%
trityl tetrafluoroborate
341-02-6

trityl tetrafluoroborate

1-<(methylthio)methoxy>tricyclo<3.3.1.13,7>decane
133859-39-9

1-<(methylthio)methoxy>tricyclo<3.3.1.13,7>decane

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

B

1-adamanthanol
768-95-6

1-adamanthanol

C

triphenmethyl methyl sulfide
62575-83-1

triphenmethyl methyl sulfide

Conditions
ConditionsYield
In dichloromethane for 0.25h; Ambient temperature;A 77%
B 88%
C 16%
In dichloromethane for 0.25h; Product distribution; Mechanism; Ambient temperature; quenching with aq. NaHCO3, other trityl salts;A 77%
B 88%
C 16%
1-adamanthanol
768-95-6

1-adamanthanol

1-chloroadamantane
935-56-8

1-chloroadamantane

Conditions
ConditionsYield
With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 18h;100%
With chlorosulfonic acid In chloroform at 10 - 15℃; for 8h;96%
With indium(III) chloride; dimethylmonochlorosilane; benzil In dichloromethane at 20℃; for 82h;93%
carbon disulfide
75-15-0

carbon disulfide

1-adamanthanol
768-95-6

1-adamanthanol

methyl iodide
74-88-4

methyl iodide

O-(adamantan-1-yl) S-methyl carbonodithioate
79057-62-8

O-(adamantan-1-yl) S-methyl carbonodithioate

Conditions
ConditionsYield
Stage #1: carbon disulfide; 1-adamanthanol With 1H-imidazole; sodium hydride In tetrahydrofuran at 20℃; for 0.5h;
Stage #2: methyl iodide In tetrahydrofuran at 20℃; for 0.5h;
100%
Stage #1: carbon disulfide; 1-adamanthanol With sodium hydride In tetrahydrofuran at 20℃; for 10h; Addition;
Stage #2: methyl iodide In tetrahydrofuran at 20℃; for 1h; Methylation;
78%
Stage #1: 1-adamanthanol With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 2h;
Stage #2: carbon disulfide In tetrahydrofuran; mineral oil at 0 - 20℃; for 15h;
Stage #3: methyl iodide In tetrahydrofuran; mineral oil at 0℃; for 2h;
72%
4-bromo-phenol
106-41-2

4-bromo-phenol

1-adamanthanol
768-95-6

1-adamanthanol

2-(1-adamantyl)-4-bromophenol
104224-68-2

2-(1-adamantyl)-4-bromophenol

Conditions
ConditionsYield
With sulfuric acid; acetic acid at 20℃; for 48h; Friedel Crafts alkylation;100%
With sulfuric acid; acetic acid In dichloromethane at 20℃; for 24h;100%
With sulfuric acid; acetic acid In dichloromethane at 20℃; for 48h; Friedel-Crafts Alkylation; Large scale;99%
1-adamanthanol
768-95-6

1-adamanthanol

acetic anhydride
108-24-7

acetic anhydride

1-acetyloxyadamantane
22635-62-7

1-acetyloxyadamantane

Conditions
ConditionsYield
With magnesium(II) perchlorate at 20℃; for 0.33h;100%
With tin(IV) tetraphenylporphyrin perchlorate at 20℃; for 0.25h;99%
With silica gel for 0.0583333h; Microwave irradiation; neat (no solvent);99%
1-adamanthanol
768-95-6

1-adamanthanol

4-bromo-4'-hydroxybiphenyl
29558-77-8

4-bromo-4'-hydroxybiphenyl

4-(4'-bromophenyl)-2-(adamantan-1-yl)phenol
496868-80-5

4-(4'-bromophenyl)-2-(adamantan-1-yl)phenol

Conditions
ConditionsYield
With sulfuric acid; acetic acid at 25℃; for 72h; Friedel-Crafts reaction;100%
With sulfuric acid; acetic acid at 20℃; for 96h;100%
With sulfuric acid; acetic acid at 20℃; for 96h;100%
With sulfuric acid In acetone at 20℃; for 96h; Cooling with ice;100%
Friedel-Crafts alkylation;
1-adamanthanol
768-95-6

1-adamanthanol

2,4-dihydro-[1,2,4]triazole-3-thione
3179-31-5

2,4-dihydro-[1,2,4]triazole-3-thione

1-(1-adamantyl)-3-[(1-adamantyl)sulfanyl]-1,2,4-triazole

1-(1-adamantyl)-3-[(1-adamantyl)sulfanyl]-1,2,4-triazole

Conditions
ConditionsYield
With sulfuric acid at 20℃; for 4h;100%
With phosphoric acid; acetic acid at 40 - 42℃; for 5h;100%
tetraphenylbismuth(V) fluoride

tetraphenylbismuth(V) fluoride

1-adamanthanol
768-95-6

1-adamanthanol

(3s,5s,7s)-1-phenoxyadamantane
38614-05-0

(3s,5s,7s)-1-phenoxyadamantane

Conditions
ConditionsYield
With N-Methyldicyclohexylamine; copper diacetate In toluene at 20℃; for 1h;100%
1-adamanthanol
768-95-6

1-adamanthanol

phenol
108-95-2

phenol

4-adamantylphenol
29799-07-3

4-adamantylphenol

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃; for 6h; Inert atmosphere;100%
With trifluoroacetic acid at 20℃; for 12h;85%
With trifluoroacetic acid79%
With sulfuric acid In dichloromethane at 20℃; Inert atmosphere;23%
With sulfuric acid In dichloromethane at 20℃; Inert atmosphere;
1-adamanthanol
768-95-6

1-adamanthanol

cobalt(II) bis(trimethylsilyl)amide
18544-54-2, 122676-68-0, 14760-23-7

cobalt(II) bis(trimethylsilyl)amide

bis(1-adamantoxo)cobalt(II)

bis(1-adamantoxo)cobalt(II)

Conditions
ConditionsYield
In benzene under Ar, refluxed briefly; filtered, washed with ether, elem. anal.;100%
1-adamanthanol
768-95-6

1-adamanthanol

toluene
108-88-3

toluene

4-(1-adamantyl)toluene
1459-55-8

4-(1-adamantyl)toluene

Conditions
ConditionsYield
With indium(III) triflate; acetylacetone for 2h; Reflux; Green chemistry;100%
With trifluoroacetic acid at 20℃; for 12h;86%
1-adamanthanol
768-95-6

1-adamanthanol

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

1-methoxyadamantane
6221-74-5

1-methoxyadamantane

Conditions
ConditionsYield
With tungsten hexacarbonyl at 180℃; for 1h; chemoselective reaction;100%
1-adamanthanol
768-95-6

1-adamanthanol

2,3,4-tri-O-benzyl-L-rhamnopyranosyl ortho-hex-1-ynylbenzoate
1391992-92-9

2,3,4-tri-O-benzyl-L-rhamnopyranosyl ortho-hex-1-ynylbenzoate

C37H38O8

C37H38O8

Conditions
ConditionsYield
Stage #1: 1-adamanthanol; 2,3,4-tri-O-benzyl-L-rhamnopyranosyl ortho-hex-1-ynylbenzoate In dichloromethane at 20℃; for 0.5h; Inert atmosphere; Molecular sieve;
Stage #2: With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere; Molecular sieve;
100%
2,3-di-O-benzyl-4,6-O-benzylidene-α-D-mannopyranosyl trichloroacetimidate

2,3-di-O-benzyl-4,6-O-benzylidene-α-D-mannopyranosyl trichloroacetimidate

1-adamanthanol
768-95-6

1-adamanthanol

1-(adamantan-1-yl)-2,3-di-O-benzyl-4,6-benzylidene-β-D-mannopyranose

1-(adamantan-1-yl)-2,3-di-O-benzyl-4,6-benzylidene-β-D-mannopyranose

Conditions
ConditionsYield
With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78℃; Molecular sieve; Inert atmosphere; stereoselective reaction;100%
1-adamanthanol
768-95-6

1-adamanthanol

A

adamantane
281-23-2

adamantane

B

2-(1-adamantyl)propane
773-32-0

2-(1-adamantyl)propane

Conditions
ConditionsYield
With triisopropylborane; trifluorormethanesulfonic acid In 1,1,2-Trichloro-1,2,2-trifluoroethane 1.) -30 deg C, 30 min 2.) room temp., 6 h;A 99.9%
B 0.1%
1-adamanthanol
768-95-6

1-adamanthanol

chloroacetonitrile
107-14-2

chloroacetonitrile

N-(1-adamantyl)-2-chloroacetamide
5689-59-8

N-(1-adamantyl)-2-chloroacetamide

Conditions
ConditionsYield
Stage #1: 1-adamanthanol; chloroacetonitrile With sulfuric acid In acetic acid; N,N-dimethyl-formamide at 20 - 80℃;
Stage #2: With water In acetic acid; N,N-dimethyl-formamide at 70℃;
99.6%
Stage #1: 1-adamanthanol; chloroacetonitrile With acetic acid In N,N-dimethyl-formamide
Stage #2: With sulfuric acid; water In N,N-dimethyl-formamide at 20 - 80℃; Product distribution / selectivity;
99.6%
With sulfuric acid; acetic acid at 20℃; for 5h; Ritter reaction;95%
With indium(III) triflate In sulfur dioxide at -50 - 100℃; for 24h; Ritter Amidation; Inert atmosphere; Autoclave; liquid SO2;79%
1-adamanthanol
768-95-6

1-adamanthanol

acetonitrile
75-05-8

acetonitrile

N-(1-adamantyl)acetamide
880-52-4

N-(1-adamantyl)acetamide

Conditions
ConditionsYield
With copper(ll) bromide at 150℃; for 8h; Reagent/catalyst; Ritter Amidation; Inert atmosphere; Sealed tube;99%
With trifluoromethylsulfonic anhydride; sodium hydrogencarbonate In dichloromethane for 2h; Ambient temperature;98%
With water; tert-butylammonium hexafluorophosphate(V); calcium(II) trifluoromethanesulfonate In neat (no solvent) at 140℃; for 0.416667h; Ritter Amidation; Microwave irradiation; Green chemistry;95%
1-adamanthanol
768-95-6

1-adamanthanol

1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

Conditions
ConditionsYield
With oxygen; 1,2-dibromomethane for 10h; Reflux;99%
With iron(III)-acetylacetonate; carbon tetrabromide at 120℃; for 2h; Sealed tube; Inert atmosphere;99%
With dibromo sulfoxide In toluene for 22h;96%
1-adamanthanol
768-95-6

1-adamanthanol

adamantane
281-23-2

adamantane

Conditions
ConditionsYield
With hydrogen; aluminum oxide; nickel at 180℃;99%
With indium(III) chloride; diphenylsilyl chloride In 1,2-dichloro-ethane at 80℃; for 3h;99%
With boron trifluoride diethyl etherate In water for 2h; Inert atmosphere; Reflux;29%
1-adamanthanol
768-95-6

1-adamanthanol

toluene-4-sulfonamide
70-55-3

toluene-4-sulfonamide

1-tosylaminoadamantane
56432-99-6

1-tosylaminoadamantane

Conditions
ConditionsYield
With iron(III) chloride In 1,2-dichloro-ethane at 50℃; for 24h; Inert atmosphere; Sealed tube;99%
With oxalic acid; 2,3,4,5-tetrafluorophenyl(dihydroxy)borane In nitromethane at 20℃;87%
With sulfuric acid for 2h;66%
1-adamanthanol
768-95-6

1-adamanthanol

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

1-trimethylsiloxyadamantane
36960-53-9

1-trimethylsiloxyadamantane

Conditions
ConditionsYield
iodine In dichloromethane at 20℃; for 0.1h; Substitution;99%
With silica-supported ZnCl2 (30%) In acetonitrile at 20℃; for 0.35h;98%
With aluminum tris(dihydrogen phosphate) at 20℃; for 0.933333h;97%
1-adamanthanol
768-95-6

1-adamanthanol

methyl iodide
74-88-4

methyl iodide

1-methoxyadamantane
6221-74-5

1-methoxyadamantane

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran99%
With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 20h;81%
With sodium hydride In tetrahydrofuran
Stage #1: 1-adamanthanol With sodium hydride In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

1-adamanthanol
768-95-6

1-adamanthanol

1-trimethylsiloxyadamantane
36960-53-9

1-trimethylsiloxyadamantane

Conditions
ConditionsYield
With zinc(II) fluoride In dichloromethane for 18h;99%
1-adamanthanol
768-95-6

1-adamanthanol

benzonitrile
100-47-0

benzonitrile

N-(adamantan-1-yl)benzamide
19026-84-7

N-(adamantan-1-yl)benzamide

Conditions
ConditionsYield
With copper(ll) bromide at 150℃; for 6h; Ritter Amidation; Inert atmosphere; Sealed tube;99%
With bismuth(lll) trifluoromethanesulfonate; water Ritter reaction;91%
With water; tert-butylammonium hexafluorophosphate(V); calcium(II) trifluoromethanesulfonate In neat (no solvent) at 140℃; for 0.416667h; Ritter Amidation; Microwave irradiation; Green chemistry;90%
1-adamanthanol
768-95-6

1-adamanthanol

2,3,4-tri-O-acetyl-L-rhamnopyranosyl (N-phenyl)-2,2,2-trifluoroacetimidate
339276-10-7

2,3,4-tri-O-acetyl-L-rhamnopyranosyl (N-phenyl)-2,2,2-trifluoroacetimidate

Acetic acid (2R,3R,4R,5S,6S)-4,5-diacetoxy-2-(adamantan-1-yloxy)-6-methyl-tetrahydro-pyran-3-yl ester

Acetic acid (2R,3R,4R,5S,6S)-4,5-diacetoxy-2-(adamantan-1-yloxy)-6-methyl-tetrahydro-pyran-3-yl ester

Conditions
ConditionsYield
With trimethylsilyl trifluoromethanesulfonate In dichloromethane at 25℃; for 3h;99%
1-adamanthanol
768-95-6

1-adamanthanol

2,3,4,6-tetra-O-benzoyl-D-glucopyranosyl 1-(N-phenyl)-2,2,2-trifluoroacetimidate
339276-12-9

2,3,4,6-tetra-O-benzoyl-D-glucopyranosyl 1-(N-phenyl)-2,2,2-trifluoroacetimidate

1-adamantanyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside

1-adamantanyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside

Conditions
ConditionsYield
With trimethylsilyl trifluoromethanesulfonate In dichloromethane at 25℃; for 3h;99%
1-adamanthanol
768-95-6

1-adamanthanol

25,27-bis(benzyloxy)-26,28-dihydroxycalix[4]arene
125065-63-6, 134309-08-3

25,27-bis(benzyloxy)-26,28-dihydroxycalix[4]arene

5,11,17,23-tetrakis(1-adamantyl)-calix[4]arene

5,11,17,23-tetrakis(1-adamantyl)-calix[4]arene

Conditions
ConditionsYield
With trifluoroacetic acid In chloroform at 60 - 65℃; for 9h;99%
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