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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Dioxirane, dimethyl- 74087-85-7

Cas:74087-85-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd. established since 2009 , has been always focusing on supplying products and services to our clients in the field of small molecule drug. Huarong Pharm has built platforms for the research, development and manufac

Dimethyldioxirane

Cas:74087-85-7

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

dimethyldioxirane CAS:74087-85-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interme

dimethyldioxirane CAS:74087-85-7

Cas:74087-85-7

Min.Order:1 Gram

Negotiable

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Dioxirane, dimethyl-

Cas:74087-85-7

Min.Order:1 Kilogram

Negotiable

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Dimethyldioxirane(DMD)

Cas:74087-85-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

dimethyldioxirane

Cas:74087-85-7

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Best Offerdimethyldioxirane

Cas:74087-85-7

Min.Order:0

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Dimethyldioxirane CAS NO.74087-85-7

Cas:74087-85-7

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Dimethyldioxirane CAS NO.74087-85-7

Cas:74087-85-7

Min.Order:1 Gram

Negotiable

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Dimethyldioxirane CAS NO.74087-85-7

Cas:74087-85-7

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

dimethyldioxirane

Cas:74087-85-7

Min.Order:1 Kilogram

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Type:Other

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Dimethyldioxirane CAS NO.74087-85-7

Cas:74087-85-7

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

dimethyldioxirane cas no. 74087-85-7 98%

Cas:74087-85-7

Min.Order:0

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

dimethyldioxirane

Cas:74087-85-7

Min.Order:0

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Type:Other

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Dioxirane, dimethyl-

Cas:74087-85-7

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

dimethyldioxirane

Cas:74087-85-7

Min.Order:0

Negotiable

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Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Dioxirane, dimethyl-

Cas:74087-85-7

Min.Order:0

Negotiable

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

dimethyldioxirane

Cas:74087-85-7

Min.Order:0

Negotiable

Type:Manufacturers

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Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

dimethyldioxirane

Cas:74087-85-7

Min.Order:0

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Dioxirane, dimethyl-

Cas:74087-85-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

Dimethyldioxirane CAS NO.74087-85-7 Application:Dimethyldioxirane CAS NO.74087-85-7

Dimethyldioxirane CAS NO.74087-85-7

Cas:74087-85-7

Min.Order:0

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Type:Other

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DB BIOTECH CO., LTD

best seller Application:API

dimethyldioxirane

Cas:74087-85-7

Min.Order:0

Negotiable

Type:Trading Company

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

dimethyldioxirane

Cas:74087-85-7

Min.Order:0

Negotiable

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

dimethyldioxirane

Cas:74087-85-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

74087-85-7

Cas:74087-85-7

Min.Order:0

Negotiable

Type:Trading Company

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Hunan Longxianng Runhui Trading Co.,Ltd

Dimethyldioxirane CAS NO.74087-85-7Appearance:off-white fine crystalline powder Storage:Dry and ventilated Package:Standard or as customer's require Application:intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small

Dimethyldioxirane CAS NO.74087-85-7

Cas:74087-85-7

Min.Order:0

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Hebei Muhuang Technology Co., Ltd

best seller Application:API

dimethyldioxirane

Cas:74087-85-7

Min.Order:0

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Type:Trading Company

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

dimethyldioxirane

Cas:74087-85-7

Min.Order:0

Negotiable

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Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Dimethyldioxirane(DMD)

Cas:74087-85-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hebei youze Biotechnology Co.,Ltd

1. Professional manufacturing and R&D department 2.Sperior quality and good package 3.Fast and safety delivery by well-reputed shipping line; 4.Better payment term and cost advantage: the origin of medicinal materials for the low purchase pric

Top quality Dimethyldioxirane

Cas:74087-85-7

Min.Order:1 Kilogram

FOB Price: $8.9

Type:Trading Company

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Synthetic route

1,1,1-trifluoro-2-propanone
421-50-1

1,1,1-trifluoro-2-propanone

A

methyltrifluoromethyldioxirane
115464-59-0

methyltrifluoromethyldioxirane

B

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

Conditions
ConditionsYield
With potassium sulfate; potassium hydrogensulfate; potassium peroxomonosulfate; edetate disodium; sodium hydrogencarbonate In water at -20℃; under 650 - 700 Torr;A 6%
B n/a
acetone
67-64-1

acetone

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

Conditions
ConditionsYield
With potassium hydroxide; potassium sulfate; potassium hydrogensulfate; oxone; sodium hydrogencarbonate In water at 5 - 10℃; for 0.05h; pH=7.4;5%
With oxone; sodium hydrogencarbonate In water at 0 - 25℃; under 75.0075 - 750.075 Torr; for 0.716667 - 0.766667h; Product distribution / selectivity;3.8%
With caro's acid; [[(phosphonomethyl)imino]bis[(ethylenenitrilo)bis(methylene)]]tetrakisphosphonic acid sodium salt; sodium hydrogencarbonate at 10 - 25℃; Rate constant; Mechanism; other ketones; var. pH;
2,3-Dimethyl-2-butene
563-79-1

2,3-Dimethyl-2-butene

A

2,3-dimethyl-2,3-epoxybutane
5076-20-0

2,3-dimethyl-2,3-epoxybutane

B

formaldehyd
50-00-0

formaldehyd

C

3,3-dimethyl-butan-2-one
75-97-8

3,3-dimethyl-butan-2-one

D

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

E

hydroxy-2-propanone
116-09-6

hydroxy-2-propanone

F

acetone
67-64-1

acetone

Conditions
ConditionsYield
With ozone at -254.16 - -238.16℃; for 19h; Irradiation; Inert atmosphere;
3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

<6S,8R(1'S,2'S,3'R),9R,10R,11R>-11-(benzyloxy)-8-<4-((tert-butyldimethylsilyl)oxy)-2-methoxy-1,3-dimethylbutyl>-10-<(methoxymethyl)oxy>-9-methyl-1,7-dioxaspiro<5.5>undec-2-ene

<6S,8R(1'S,2'S,3'R),9R,10R,11R>-11-(benzyloxy)-8-<4-((tert-butyldimethylsilyl)oxy)-2-methoxy-1,3-dimethylbutyl>-10-<(methoxymethyl)oxy>-9-methyl-1,7-dioxaspiro<5.5>undec-2-ene

C32H54O8Si

C32H54O8Si

Conditions
ConditionsYield
In dichloromethane; acetone at 0℃;100%
3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

<6R,8R(1'S,2'S,3'R),9R,10R,11R>-11-(benzyloxy)-8-<4-((tert-butyldimethylsilyl)oxy)-2-methoxy-1,3-dimethylbutyl>-10-<(methoxymethyl)oxy>-9-methyl-1,7-dioxaspiro<5.5>undec-2-ene

<6R,8R(1'S,2'S,3'R),9R,10R,11R>-11-(benzyloxy)-8-<4-((tert-butyldimethylsilyl)oxy)-2-methoxy-1,3-dimethylbutyl>-10-<(methoxymethyl)oxy>-9-methyl-1,7-dioxaspiro<5.5>undec-2-ene

C32H54O8Si

C32H54O8Si

Conditions
ConditionsYield
In dichloromethane; acetone at 0℃;100%
3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

2-methoxy-phenylamine
90-04-0

2-methoxy-phenylamine

2-Nitroanisole
91-23-6

2-Nitroanisole

Conditions
ConditionsYield
With potassium hydroxide; disodium hydrogenphosphate; tetra(n-butyl)ammonium hydrogensulfate In dichloromethane; acetone other substituted anilines;100%
(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride
34557-72-7, 32195-55-4

(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

{Mn(O)(tetraphenylporphyrin(2-))}
76077-77-5

{Mn(O)(tetraphenylporphyrin(2-))}

Conditions
ConditionsYield
In acetone Kinetics; oxidn. of the Mn compd. in abs. acetone at 0°C;100%
iron(II) meso-tetramesitylporphyrin
81567-13-7

iron(II) meso-tetramesitylporphyrin

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(5,10,15,20-tetramesitylporphyrinato)oxoiron(IV)
93085-16-6

(5,10,15,20-tetramesitylporphyrinato)oxoiron(IV)

Conditions
ConditionsYield
In acetone byproducts: (CH3)2CO; oxidn. of the Fe compd. in abs. acetone at -10°C with dimethyldioxirane;100%
3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

Nitrite

Nitrite

Nitrate

Nitrate

Conditions
ConditionsYield
In water; acetonitrile Kinetics; 25.6+/-0.1°C, 0. 5 h, phosphate buffer (pH 7.4); followed by HPLC;100%
manganese(II) 5,10,15,20-tetraphenylporphyrinate
31004-82-7

manganese(II) 5,10,15,20-tetraphenylporphyrinate

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

{Mn(O)(tetraphenylporphyrin(2-))}
76077-77-5

{Mn(O)(tetraphenylporphyrin(2-))}

Conditions
ConditionsYield
In acetone byproducts: (CH3)2CO; oxidn. of the Mn compd. in abs. acetone at -50°C with dimethyldioxirane and allowing the soln. to warm to -20°C;100%
manganese(III)OH tetraphenylporphyrin
85135-24-6

manganese(III)OH tetraphenylporphyrin

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

{Mn(O)(tetraphenylporphyrin(2-))}
76077-77-5

{Mn(O)(tetraphenylporphyrin(2-))}

Conditions
ConditionsYield
In acetone Kinetics; oxidn. of the Mn compd. in abs. acetone at 0°C;100%
dioxo[hydridotris(3,5-dimethyl-1-pyrazolyl)borato](4-methyl-3-pentenyl)tungsten(VI)

dioxo[hydridotris(3,5-dimethyl-1-pyrazolyl)borato](4-methyl-3-pentenyl)tungsten(VI)

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(E)-dioxo[hydridotris(3,5-dimethyl-1-pyrazolyl)borato](4-methyl-3,4-oxiranylpentyl)tungsten(VI)

(E)-dioxo[hydridotris(3,5-dimethyl-1-pyrazolyl)borato](4-methyl-3,4-oxiranylpentyl)tungsten(VI)

Conditions
ConditionsYield
In dichloromethane stirring (room temp., 30 min); evapn. (20 Torr, 20°C); elem. anal.;100%
(2-methylallyl)dioxo{tris(3,5-dimethyl-1-pyrazolyl)boranato}tungsten(VI)

(2-methylallyl)dioxo{tris(3,5-dimethyl-1-pyrazolyl)boranato}tungsten(VI)

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(E)-dioxo[hydridotris(3,5-dimethyl-1-pyrazolyl)borato](2-methyl-2,3-oxiranylpropyl)tungsten(VI)

(E)-dioxo[hydridotris(3,5-dimethyl-1-pyrazolyl)borato](2-methyl-2,3-oxiranylpropyl)tungsten(VI)

Conditions
ConditionsYield
In dichloromethane stirring (room temp., 45 min); evapn. (20 Torr, 20°C); elem. anal.;100%
Zn4O(6+)*3S((C6H3)(C(O)O)CH2)2(2-)*99(CH3)2NCHO=[Zn4O(S((C6H3)(C(O)O)CH2)2)3]*99(CH3)2NCHO

Zn4O(6+)*3S((C6H3)(C(O)O)CH2)2(2-)*99(CH3)2NCHO=[Zn4O(S((C6H3)(C(O)O)CH2)2)3]*99(CH3)2NCHO

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

Zn4O(6+)*3S(O)2((C6H3)(C(O)O)CH2)2(2-)=Zn4O(S(O)2((C6H3)(C(O)O)CH2)2)3

Zn4O(6+)*3S(O)2((C6H3)(C(O)O)CH2)2(2-)=Zn4O(S(O)2((C6H3)(C(O)O)CH2)2)3

Conditions
ConditionsYield
In acetone crystals of complex soaked in Me2CO to exchange DMF; soln. of Me2-dioxirane (approx. 7-8 equiv.) in Me2CO added; react. at 4°C for 3 h;100%
pent-4-en-1-aminium 4-methylbenzenesulfonate
1236459-33-8

pent-4-en-1-aminium 4-methylbenzenesulfonate

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

3-(oxiran-2-yl)propan-1-aminium 4-methylbenzenesulfonate
1236459-35-0

3-(oxiran-2-yl)propan-1-aminium 4-methylbenzenesulfonate

Conditions
ConditionsYield
In dichloromethane; acetone at 0℃; for 3h; Inert atmosphere;100%
In dichloromethane at 0℃; for 3h; Inert atmosphere;0.109 mg
(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5SCH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5SCH3)]PF6

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5SCH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5SCH3)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5S(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5S(O)CH3)]PF6

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5S(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5S(O)CH3)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether);99%
In acetone inert atmosphere; DMD added slowly at 0°C; 45 min;; evapd.; recrystd. from acetone/Et2O; elem. anal.;;>90
[Cp(2(S),3(S)-bis(diphenylphosphino)butane)Ru(BzSMe)]PF6

[Cp(2(S),3(S)-bis(diphenylphosphino)butane)Ru(BzSMe)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

[Cp(2(S),3(S)-bis(diphenylphosphino)butane)Ru(BzS(O)Me)]PF6

[Cp(2(S),3(S)-bis(diphenylphosphino)butane)Ru(BzS(O)Me)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether); diastereomer mixt. not sepd., diastereomeric excess 98%;99%
In acetone inert atmosphere; DMD added slowly at 0°C; Rs/Ss 99/1;;90%
(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5SCH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5SCH3)]PF6

(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5SCH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5SCH3)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5S(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5S(O)CH3)]PF6

(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5S(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5S(O)CH3)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether);99%
In acetone inert atmosphere; DMD added slowly at 0°C; 45 min;; evapd.; recrystd. from acetone/Et2O; elem. anal.;;>90
(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2SCH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2SCH3)]PF6

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2SCH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2SCH3)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2S(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2S(O)CH3)]PF6

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2S(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2S(O)CH3)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether);99%
In acetone inert atmosphere; DMD added slowly at 0°C; 45 min;; evapd.; recrystd. from acetone/Et2O; elem. anal.;;>90
{cpRu(dppe)(PhCH2SMe)}PF6

{cpRu(dppe)(PhCH2SMe)}PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2S(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2S(O)CH3)]PF6

(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2S(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2S(O)CH3)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether);99%
In acetone inert atmosphere; DMD added slowly at 0°C; 45 min;; evapd.; recrystd. from acetone/Et2O; elem. anal.;;>90
[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(i-PrSMe)]PF6
189881-25-2

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(i-PrSMe)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(i-PrS(O)Me)]PF6
189881-57-0, 189958-85-8

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(i-PrS(O)Me)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether); diastereomer mixt. not sepd., diastereomeric excess 60%;99%
(C5H5)Ru(CO)(P(C6H5)3)(C6H5SCH3)(1+)*PF6(1-)=[(C5H5)Ru(CO)(P(C6H5)3)(C6H5SCH3)]PF6
189881-19-4

(C5H5)Ru(CO)(P(C6H5)3)(C6H5SCH3)(1+)*PF6(1-)=[(C5H5)Ru(CO)(P(C6H5)3)(C6H5SCH3)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(C5H5)Ru(CO)(P(C6H5)3)(C6H5S(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru(CO)(P(C6H5)3)(C6H5S(O)CH3)]PF6
190145-91-6, 189881-49-0

(C5H5)Ru(CO)(P(C6H5)3)(C6H5S(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru(CO)(P(C6H5)3)(C6H5S(O)CH3)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 2 h; removal of volatiles (vac.), recrystn. (CH2Cl2/ether); diastereomer mixt. not sepd., diastereomeric excess 8%;99%
[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(PhSMe)]PF6
189881-23-0

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(PhSMe)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(PhS(O)Me)]PF6
189958-83-6, 189881-55-8

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(PhS(O)Me)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether); diastereomer mixt. not sepd., diastereomeric excess 60%;99%
[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(BzSMe)]PF6
189881-28-5

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(BzSMe)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(BzS(O)Me)]PF6
189958-87-0, 189881-59-2

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(BzS(O)Me)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether); diastereomer mixt. not sepd., diastereomeric excess 50%;99%
[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(BzS-i-Pr)]PF6
189881-31-0

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(BzS-i-Pr)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(BzS(O)-i-Pr)]PF6
189958-89-2, 189881-61-6

[Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(BzS(O)-i-Pr)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether); diastereomer mixt. not sepd., diastereomeric excess 34%;99%
(C5H5)Ru((C6H5)2PCH2P(C6H5)2)((CH3)2CHSCH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)((CH3)2CHSCH3)]PF6
189881-07-0

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)((CH3)2CHSCH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)((CH3)2CHSCH3)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)((CH3)2CHS(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)((CH3)2CHS(O)CH3)]PF6
189881-41-2

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)((CH3)2CHS(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)((CH3)2CHS(O)CH3)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether);99%
(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)((CH3)2CHSCH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)((CH3)2CHSCH3)]PF6
189881-13-8

(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)((CH3)2CHSCH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)((CH3)2CHSCH3)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)((CH3)2CHS(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)((CH3)2CHS(O)CH3)]PF6
189881-45-6

(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)((CH3)2CHS(O)CH3)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)((CH3)2CHS(O)CH3)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether);99%
(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2SCH(CH3)2)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2SCH(CH3)2)]PF6
189881-09-2

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2SCH(CH3)2)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2SCH(CH3)2)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2S(O)CH(CH3)2)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2S(O)CH(CH3)2)]PF6
189881-43-4

(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2S(O)CH(CH3)2)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2P(C6H5)2)(C6H5CH2S(O)CH(CH3)2)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether);99%
(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2SCH(CH3)2)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2SCH(CH3)2)]PF6
189881-15-0

(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2SCH(CH3)2)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2SCH(CH3)2)]PF6

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2S(O)C3H7)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2S(O)C3H7)]PF6
189881-47-8

(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2S(O)C3H7)(1+)*PF6(1-)=[(C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)(C6H5CH2S(O)C3H7)]PF6

Conditions
ConditionsYield
In acetone slow addn. of excess oxirane soln. (cooled to -30°C) to Ru-complex soln. (cooled to 0°C), standing for 45 min; removal of volatiles (vac.), recrystn. (CH2Cl2/ether);99%
(3,3-difluoro-2-methyleneindolin-1-yl)(phenyl)methanone

(3,3-difluoro-2-methyleneindolin-1-yl)(phenyl)methanone

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(3,3-difluorospiro[indoline-2,2'-oxiran]-1-yl)(phenyl)methanone

(3,3-difluorospiro[indoline-2,2'-oxiran]-1-yl)(phenyl)methanone

Conditions
ConditionsYield
In acetone at 0 - 20℃; for 20h;99%
1-Phenylethanol
98-85-1, 13323-81-4

1-Phenylethanol

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

A

1-phenyl-2-hydroxyethanone
582-24-1

1-phenyl-2-hydroxyethanone

B

acetophenone
98-86-2

acetophenone

Conditions
ConditionsYield
In acetone at 25℃; for 3h;A 2%
B 98%
In acetone at 25℃; for 3h; Thermodynamic data; Rate constant; Mechanism; Ea, ΔH(excit.), ΔS(excit.), ΔG(excit.); effect of reaction parameters and p-substituents on the rate constant and the yields;A 2%
B 98%
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical
2564-83-2, 45842-10-2

2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

A

1-methoxy-2,2,6,6-tetramethylpiperidine
34672-84-9

1-methoxy-2,2,6,6-tetramethylpiperidine

B

1-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propan-2-one
30764-40-0

1-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propan-2-one

Conditions
ConditionsYield
In acetone at 20℃;A 98%
B n/a
In acetone at 20℃; for 4h;
(η5-C5H5)Fe(CO)2Si(t-Bu)2H
140149-26-4

(η5-C5H5)Fe(CO)2Si(t-Bu)2H

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

(η5-C5H5)Fe(CO)2Si(t-Bu)2OH
140149-30-0

(η5-C5H5)Fe(CO)2Si(t-Bu)2OH

Conditions
ConditionsYield
In acetone N2 atmosphere; rapid addn. of soln. of org. compd. in acetone to soln. of Fe-compd. in acetone (-78°C), stirring (0.3 h); filtration over Celite, removal of solvent (-10°C, 0.01 Torr), chromy. (silylated silica gel, cyclohexane/toluene 20:1), pptn. (pentane); elem. anal.;98%
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