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Dayang Chem (Hangzhou) Co.,Ltd.

img heightAppearance:detailed see specifications Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:Used in Synthesis, Pharmaceuticals and other fields Transportation:by air or by sea Port:Shan

1,2-Dimethylbenzene Manufacturer/High quality/Best price/In stock

Cas:95-47-6

Min.Order:1 Kilogram

FOB Price: $7.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

o-Xylene

Cas:95-47-6

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

o-Xylene

Cas:95-47-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

1,2-Dimethylbenzene Basic information Product Name: 1,2-Dimethylbenzene Synonyms: 1,2-Xylene;1,2-DIMETHYLBENZENE;AKOS BBS-00004266;XYLENES;XYLOL;1,2-dimethyl-benzen;2-methyltoluene;2-xyl

1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

1,2-Dimethylbenzene/o-Xylene CAS NO 95-47-6 Appearance:Colorless Liquid Application: Dyestuff Intermediates, Pharmaceutical Intermediates Appearance:Colorless liquid Storage:Preserve in well-closed, light-resistant and airtight contain

1,2-Dimethylbenzene CAS: 95-47-6

Cas:95-47-6

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Changchun Artel lmport and Export trade company

English name ortho-xylene、1,2-dimethylbenzene Chemical formula: C6H4(CH3)2 Molecular weight: 106.16 Belonging to aromatic hydrocarbon, DMB, aromatic hydrocarbon solvent and monocyclic aromatic hydrocarbon Solubility: insolubl

wholesale low price O-xylene,CAS 95-47-6

Cas:95-47-6

Min.Order:1000 Kilogram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:95-47-6

Cas:95-47-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

1,2-Dimethylbenzene CAS:95-47-6 Specification Cas No.: 95-47-6 EINECS: 202-422-2 MF: C8H10 MW: 106.17 Melting Point: -

Factory supply 1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

O-Xylene

Cas:95-47-6

Min.Order:0

Negotiable

Type:Trading Company

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:0

Negotiable

Type:Manufacturers

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EAST CHEMSOURCES LIMITED

I can offer you competitive price and good quality Appearance:colorless transparent liquid Storage:Storage in shady room and dry place. Package:200L plastic drum, IBC(1000L), Application:used as the industrial chemicals and solvent,in the producti

factory of Ortho-Xylene

Cas:95-47-6

Min.Order:1 Kilogram

FOB Price: $860.0 / 900.0

Type:Manufacturers

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

o-Xylene

Cas:95-47-6

Min.Order:0

Negotiable

Type:Other

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Benzene, 1,2-dimethyl-

Cas:95-47-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

o-Xylene

Cas:95-47-6

Min.Order:0

Negotiable

Type:Manufacturers

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

o-Xylene

Cas:95-47-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white powder Storage:Sealing cool to save Package:25kg/ drum, with inner PE bag; or as per your request. Application:Used as a microscope cleaning agents, silicon element and the the

1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 95-47-6 with competitive price

Cas:95-47-6

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

Lowest price 1,2-Dimethylbenzene, o-Xylene 95-47-6 Application:Lowest price 1,2-Dimethylbenzene, o-Xylene 95-47-6

Lowest price 1,2-Dimethylbenzene, o-Xylene 95-47-6

Cas:95-47-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Fandachem Co.,Ltd

1,2-Dimethylbenzene cas 95-47-6Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1,2-Dimethylbenzene cas 95-47-6

Cas:95-47-6

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl

1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

Lowest price 1,2-Dimethylbenzene, o-Xylene 95-47-6Appearance:Colorless liquid Storage:Store in cool and dry places. Keep away from strong light. Package:25kg/drum or as your requirement Application:Animal Pharmaceuticals Transportation:By express (Do

Lowest price 1,2-Dimethylbenzene, o-Xylene 95-47-6

Cas:95-47-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

1,2-Dimethylbenzene 95-47-6

Cas:95-47-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chongqing KonAo Health Co.,Ltd

High quality, Competitive price & Excellent service Application:Chemical,Organic Intermediates

1,2-Dimethylbenzene

Cas:95-47-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Beantown Chemical

in stock Application:95-47-6

o-Xylene, Spectrophotometric, 96.0% min.

Cas:95-47-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

methyl(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium*(tetrahydrofuran)

methyl(o-tolyl)(1,2-bis(diphenylphosphino)benzene)palladium*(tetrahydrofuran)

1,2-Bis(diphenylphosphino)benzene
13991-08-7

1,2-Bis(diphenylphosphino)benzene

A

bis(1,2-bis(diphenylphosphino)benzene)palladium
85318-49-6

bis(1,2-bis(diphenylphosphino)benzene)palladium

B

o-xylene
95-47-6

o-xylene

Conditions
ConditionsYield
In benzene-d6 under N2; in NMR tube; react. of Pd complex and ligand (excess) in benzene-d6 at 40 for 2 h or at 90°C for < 10 min; monitored by (1)H NMR spectra;A n/a
B 99%
2-methyl-benzyl alcohol
89-95-2

2-methyl-benzyl alcohol

o-xylene
95-47-6

o-xylene

Conditions
ConditionsYield
With palladium dichloride In methanol at 40℃; for 18h; Inert atmosphere; Green chemistry; chemoselective reaction;99%
With 2,4,6-trimethyl-pyridine; 4,4'-dimethoxyphenyl disulfide; iridium(lll) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate; triphenylphosphine In toluene for 24h; Irradiation;66 %Chromat.
1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

o-xylene
95-47-6

o-xylene

Conditions
ConditionsYield
With palladium dichloride In methanol at 40℃; for 1h; Green chemistry; chemoselective reaction;99%
2-methyl-1-methylenecyclohexane
2808-75-5, 58396-30-8

2-methyl-1-methylenecyclohexane

o-xylene
95-47-6

o-xylene

Conditions
ConditionsYield
With n-butyllithium; potassium 2-methylbutan-2-olate Mechanism; 1) r.t., 16 h, 2) reflux, 6 h; further reagent: D2O;97%
3,4-dimethylbenzaldehyde
5973-71-7

3,4-dimethylbenzaldehyde

A

o-xylene
95-47-6

o-xylene

B

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With palladium/alumina; hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 96.2%
B 3.8%
With hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 15.9%
B 84.2%
1,2-dimethyl-2,5-cyclohexadiene-1-carboxylic acid
55262-10-7

1,2-dimethyl-2,5-cyclohexadiene-1-carboxylic acid

o-xylene
95-47-6

o-xylene

Conditions
ConditionsYield
With chlorosulfonic acid In dichloromethane at 0℃; for 0.166667h;95%
2-Methylbenzonitrile
529-19-1

2-Methylbenzonitrile

o-xylene
95-47-6

o-xylene

Conditions
ConditionsYield
With hydrogen; aluminum oxide; nickel at 150℃; under 760 Torr; various Nitriles;92%
With nickel-copper at 240℃; Hydrogenation;
4-chloro-1,2-dimethylbenzene
615-60-1

4-chloro-1,2-dimethylbenzene

3-chloro-o-xylene
608-23-1

3-chloro-o-xylene

o-xylene
95-47-6

o-xylene

Conditions
ConditionsYield
With hydrogen; 5%-palladium/activated carbon at 290 - 320℃; for 1h;90%
carbon monoxide
201230-82-2

carbon monoxide

phthalyl alcohol
612-14-6

phthalyl alcohol

A

isochroman-3-one
4385-35-7

isochroman-3-one

B

o-xylene
95-47-6

o-xylene

C

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

Conditions
ConditionsYield
With hydrogen iodide; tetrakis(triphenylphosphine) palladium(0) In acetone at 90℃; under 68400 Torr; for 42h; Carbonylation; reduction;A 88%
B n/a
C 9%
With hydrogen iodide; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane at 120℃; under 68400 Torr; for 42h; Carbonylation; reduction;A 13%
B n/a
C 52%
4-t-butyl-o-xylene
7397-06-0

4-t-butyl-o-xylene

A

2,3-Dimethylmaleic anhydride
766-39-2

2,3-Dimethylmaleic anhydride

B

4-tert-butylphthalic anhydride
32703-79-0

4-tert-butylphthalic anhydride

C

6-(tert-butyl)isobenzofuran-1(3H)-one
74186-27-9

6-(tert-butyl)isobenzofuran-1(3H)-one

D

o-xylene
95-47-6

o-xylene

E

4-tert-butyl-phthalaldehyde

4-tert-butyl-phthalaldehyde

Conditions
ConditionsYield
With oxygen; phosphorus; titanium; oxides of V; aluminium at 345℃; for 0.000119444h; Product distribution; oth. temperature, oth. time, gas phase;A 3%
B 83%
C 1.8%
D n/a
E n/a
3,4-dimethylcyclohex-3-ene-1-carboxaldehyde
18022-66-7

3,4-dimethylcyclohex-3-ene-1-carboxaldehyde

A

o-xylene
95-47-6

o-xylene

B

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 17.5%
B 80.9%
With palladium/alumina; hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 73%
B 27%
1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

[3-(dimethylamino)propyl]dimethyl aluminium(III)

[3-(dimethylamino)propyl]dimethyl aluminium(III)

A

o-xylene
95-47-6

o-xylene

B

2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

Conditions
ConditionsYield
With tetrakis(triphenylphosphine)palladium dichloride In benzene at 80℃;A 80%
B 13%
4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

A

o-xylene
95-47-6

o-xylene

B

4-Methylbenzyl alcohol
589-18-4

4-Methylbenzyl alcohol

C

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

D

1-(4-methylphenyl)-2-(2-methylphenyl)ethanol
113312-69-9

1-(4-methylphenyl)-2-(2-methylphenyl)ethanol

Conditions
ConditionsYield
With lithium In diethyl ether at 0℃; for 0.75h; Further byproducts given. Yields of byproduct given;A n/a
B n/a
C n/a
D 75%
o-Xylylene dichloride
612-12-4

o-Xylylene dichloride

A

o-xylene
95-47-6

o-xylene

B

benzocyclobutene
694-87-1

benzocyclobutene

Conditions
ConditionsYield
With magnesium at 600℃;A 15%
B 73%
2-methylphenyl aldehyde
529-20-4

2-methylphenyl aldehyde

o-xylene
95-47-6

o-xylene

Conditions
ConditionsYield
With polymethylhydrosiloxane; iron(III) chloride hexahydrate In 1,2-dichloro-ethane at 120℃; for 1h; Microwave irradiation;73%
hexane
110-54-3

hexane

A

o-xylene
95-47-6

o-xylene

B

para-xylene
106-42-3

para-xylene

C

ethylbenzene
100-41-4

ethylbenzene

D

m-xylene
108-38-3

m-xylene

E

toluene
108-88-3

toluene

F

benzene
71-43-2

benzene

Conditions
ConditionsYield
540 degC; treated 16 h; U type zeolite at 450℃; Product distribution;A n/a
B n/a
C n/a
D n/a
E 10.8%
F 72.2%
540 degC; treated 16 h; UHS type zeolite at 450℃; Product distribution;A n/a
B n/a
C n/a
D n/a
E 33.3%
F 50%
2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

A

o-xylene
95-47-6

o-xylene

B

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

Conditions
ConditionsYield
With magnesium at 600℃;A 20%
B 70%
2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

A

o-xylene
95-47-6

o-xylene

B

benzocyclobutene
694-87-1

benzocyclobutene

C

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

D

(E)-2,2'-dimethylstilbene
36888-18-3

(E)-2,2'-dimethylstilbene

Conditions
ConditionsYield
With magnesium at 600℃; under 0.15 Torr;A n/a
B n/a
C 70%
D n/a
carbon monoxide
201230-82-2

carbon monoxide

2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

A

o-xylene
95-47-6

o-xylene

B

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

C

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

D

1,3-bis(3,4-methylphenyl)acetone

1,3-bis(3,4-methylphenyl)acetone

Conditions
ConditionsYield
With sodium hydroxide; cobalt tricarbonyl nitrosyl; trimethyldodecylammonium chloride In benzene under 760 Torr; Ambient temperature;A 4%
B 68%
C 12%
D 10%
2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

A

o-xylene
95-47-6

o-xylene

B

o-methylphenylacetic acid
644-36-0

o-methylphenylacetic acid

C

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

D

1,3-bis(3,4-methylphenyl)acetone

1,3-bis(3,4-methylphenyl)acetone

Conditions
ConditionsYield
With sodium hydroxide; cobalt tricarbonyl nitrosyl; carbon monoxide; trimethyldodecylammonium chloride In benzene under 760 Torr; Ambient temperature;A 4%
B 68%
C 12%
D 10%
1,2-dimethyl-2,5-cyclohexadiene-1-carboxylic acid
55262-10-7

1,2-dimethyl-2,5-cyclohexadiene-1-carboxylic acid

A

o-xylene
95-47-6

o-xylene

(1S,5R)-5-Hydroperoxy-1-methyl-6-methylene-cyclohex-2-enecarboxylic acid

(1S,5R)-5-Hydroperoxy-1-methyl-6-methylene-cyclohex-2-enecarboxylic acid

(1S,5S)-5-Hydroperoxy-1-methyl-6-methylene-cyclohex-2-enecarboxylic acid

(1S,5S)-5-Hydroperoxy-1-methyl-6-methylene-cyclohex-2-enecarboxylic acid

Conditions
ConditionsYield
With oxygen; 5,15,10,20-tetraphenylporphyrin In chloroform at -30℃; for 24h; Irradiation;A 19%
B 10%
C 68%
cyclohexanol
108-93-0

cyclohexanol

A

o-xylene
95-47-6

o-xylene

B

methyl-cyclopentane
96-37-7

methyl-cyclopentane

C

cyclohexane
110-82-7

cyclohexane

D

benzene
71-43-2

benzene

Conditions
ConditionsYield
With hydrogen; nickel(II) oxide; aluminum oxide; molybdenum(VI) oxide at 450℃; under 21001.7 Torr; for 0.75h; Further byproducts given;A n/a
B 20%
C 65%
D n/a
Bis(dithiopivalinsaeure)-1,2-xylylenester
137092-35-4

Bis(dithiopivalinsaeure)-1,2-xylylenester

A

o-xylene
95-47-6

o-xylene

B

methyl dithiopivalate
40920-16-9

methyl dithiopivalate

Conditions
ConditionsYield
In methanol cathodic reduction, Pt cathode;A 61%
B 50%
α,α'-dibromo-o-xylene
91-13-4

α,α'-dibromo-o-xylene

A

o-xylene
95-47-6

o-xylene

B

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

C

α,α'-diethoxy-o-xylene
113245-36-6

α,α'-diethoxy-o-xylene

D

1,2-bis(o-ethoxymethylphenyl)ethane

1,2-bis(o-ethoxymethylphenyl)ethane

Conditions
ConditionsYield
With sodium In toluene for 24h; Heating;A 60%
B n/a
C n/a
D n/a
2-ethyl-1-hexene
1632-16-2

2-ethyl-1-hexene

A

o-xylene
95-47-6

o-xylene

B

para-xylene
106-42-3

para-xylene

C

ethylbenzene
100-41-4

ethylbenzene

Conditions
ConditionsYield
With tert-butylethylene; (iPr4PCOP)IrHCl; sodium t-butanolate at 200℃; for 120h; Concentration; Reagent/catalyst; Temperature;A 11%
B 60%
C 7%
n-heptane
142-82-5

n-heptane

A

o-xylene
95-47-6

o-xylene

B

para-xylene
106-42-3

para-xylene

C

ethylbenzene
100-41-4

ethylbenzene

D

m-xylene
108-38-3

m-xylene

E

toluene
108-88-3

toluene

F

benzene
71-43-2

benzene

Conditions
ConditionsYield
540 degC; treated 16 h; U type zeolite at 450℃; Product distribution;A n/a
B n/a
C n/a
D n/a
E 58.5%
F 6%
540 degC; treated 16 h; UHS type zeolite at 450℃; Product distribution;A n/a
B n/a
C n/a
D n/a
E 42.8%
F 8.8%
3,4-Dimethylphenol
95-65-8

3,4-Dimethylphenol

o-xylene
95-47-6

o-xylene

Conditions
ConditionsYield
Stage #1: 3,4-Dimethylphenol With fluorosulfonyl fluoride; triethylamine In dimethyl sulfoxide at 20℃; for 3h;
Stage #2: With formic acid; 1,3-bis-(diphenylphosphino)propane; palladium diacetate In dimethyl sulfoxide at 20℃; for 2h;
58%
2-methylsulfonyloxymethylbenzyl methanesulfonate
1933-71-7

2-methylsulfonyloxymethylbenzyl methanesulfonate

o-xylene
95-47-6

o-xylene

Conditions
ConditionsYield
With lithium; nickel dichloride In tetrahydrofuran at 20℃; Reduction;57%
<4>Radialene
3227-91-6

<4>Radialene

A

styrene
292638-84-7

styrene

B

o-xylene
95-47-6

o-xylene

C

phenylacetylene
536-74-3

phenylacetylene

D

toluene
108-88-3

toluene

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
at 880℃; under 0.001 Torr;A 55%
B 6%
C n/a
D n/a
E n/a
o-xylene
95-47-6

o-xylene

phthalic anhydride
85-44-9

phthalic anhydride

Conditions
ConditionsYield
With oxygen at 340 - 360℃;100%
With oxygen100%
With oxygen100%
o-xylene
95-47-6

o-xylene

1,2-Dimethyl-cyclohexane
583-57-3

1,2-Dimethyl-cyclohexane

Conditions
ConditionsYield
With hydrogen; [(norbornadiene)rhodium(I)chloride]2; phosphinated polydiacetylene In n-heptane at 30℃; under 60800 Torr; for 1.8h;100%
With Ti8O8(14+)*6C8H4O4(2-)*4O(2-)*3.3Li(1+)*0.7Co(2+)*0.7C4H8O*0.7H(1-); hydrogen In neat (no solvent) at 120℃; under 37503.8 Torr; for 18h;100%
With hydrogen In water at 100℃; under 15001.5 Torr; for 5h;99%
o-xylene
95-47-6

o-xylene

A

2-benzofuran-1(3H)-one
87-41-2

2-benzofuran-1(3H)-one

B

phthalic anhydride
85-44-9

phthalic anhydride

Conditions
ConditionsYield
With oxygen at 340 - 360℃; Product distribution / selectivity;A 0.01%
B 100%
With oxygen at 340 - 360℃;A 0.1%
B 100%
With oxygen at 340 - 360℃;A 0.03%
B 100%
o-xylene
95-47-6

o-xylene

ortho-xylene chlorinated products; mixture of

ortho-xylene chlorinated products; mixture of

Conditions
ConditionsYield
With chlorine; manganese trisacetylacetonate; 10H-phenothiazine-10-carbonyl chloride at 10℃; under 760.051 Torr; for 0.833333h; Product distribution / selectivity;100%
o-xylene
95-47-6

o-xylene

ortho-xylene chlorinated products; mixture of

ortho-xylene chlorinated products; mixture of

Conditions
ConditionsYield
With chlorine; manganese trisacetylacetonate; 10H-phenothiazine-10-carbonyl chloride at 10℃; under 760.051 Torr; for 0.666667h; Product distribution / selectivity;100%
o-xylene
95-47-6

o-xylene

bis(1-phenylethyl)ether
93-96-9

bis(1-phenylethyl)ether

1,2-dimethyl-4-(1-phenylethyl)benzene
6196-95-8

1,2-dimethyl-4-(1-phenylethyl)benzene

Conditions
ConditionsYield
With iron(III) chloride; chloro-trimethyl-silane In 1,2-dichloro-ethane at 20℃; for 0.166667h; Friedel-Crafts Alkylation; Inert atmosphere;100%
styrene
292638-84-7

styrene

o-xylene
95-47-6

o-xylene

4-benzyl-1,2-dimethylbenzene
13540-56-2

4-benzyl-1,2-dimethylbenzene

Conditions
ConditionsYield
With phosphotungstic acid at 120℃; for 3h; Reagent/catalyst; Friedel-Crafts Alkylation;100%
o-xylene
95-47-6

o-xylene

2-chloro-5-(2-(3,4-dimethoxyphenyl)-1,1,1-trifluoropropan-2-yl)thiophene

2-chloro-5-(2-(3,4-dimethoxyphenyl)-1,1,1-trifluoropropan-2-yl)thiophene

2-(2-(3,4-dimethoxyphenyl)-1,1,1-trifluoropropan-2-yl)-4-(3,4-dimethylphenyl)thiophene

2-(2-(3,4-dimethoxyphenyl)-1,1,1-trifluoropropan-2-yl)-4-(3,4-dimethylphenyl)thiophene

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In dichloromethane at -40℃; for 6h;100%
styrene
292638-84-7

styrene

o-xylene
95-47-6

o-xylene

1,2-dimethyl-4-(1-phenylethyl)benzene
6196-95-8

1,2-dimethyl-4-(1-phenylethyl)benzene

Conditions
ConditionsYield
With cross-linked poly acidic ionic liquids In N,N-dimethyl-formamide at 120℃; for 3h; Solvent; Temperature; High pressure;99.67%
With phosphotungstic acid at 120℃; for 3h; Reagent/catalyst;98.3%
With 12-tungstophosphoric acid supported 30percent triethylammonium acetate, P123 in micro/mesoporous silica at 119.84℃; for 3h; Catalytic behavior; Reagent/catalyst; Temperature; Friedel-Crafts Alkylation;93.8%
tertiary butyl chloride
507-20-0

tertiary butyl chloride

o-xylene
95-47-6

o-xylene

4-t-butyl-o-xylene
7397-06-0

4-t-butyl-o-xylene

Conditions
ConditionsYield
With iodine at 50℃; Temperature;99.3%
With iron(III) chloride at 0 - 20℃;85%
With aluminium trichloride69%
phthalic anhydride
85-44-9

phthalic anhydride

o-xylene
95-47-6

o-xylene

2-(3,4-dimethylbenzoyl)benzoic acid
2159-42-4

2-(3,4-dimethylbenzoyl)benzoic acid

Conditions
ConditionsYield
With aluminum (III) chloride In neat (no solvent) for 1h; Friedel-Crafts Acylation; Milling;99%
With [bmim]Cl*AlCl3 at 30℃; for 3h; Friedel-Crafts reaction;95%
With aluminium trichloride for 0.166667h; Heating;37%
o-xylene
95-47-6

o-xylene

2-chloropropionyl chloride
625-36-5

2-chloropropionyl chloride

3-chloro-1-(3,4-dimethyl-phenyl)-propan-1-one
22422-23-7

3-chloro-1-(3,4-dimethyl-phenyl)-propan-1-one

Conditions
ConditionsYield
With aluminum (III) chloride; nitromethane at 19 - 22℃; under 760.051 Torr; Friedel Crafts acylation; Inert atmosphere;99%
With aluminum (III) chloride In dichloromethane at 0 - 20℃; Friedel-Crafts acylation; Inert atmosphere;98%
With aluminum (III) chloride In dichloromethane at 25℃; for 3h;96%
o-xylene
95-47-6

o-xylene

1-(3,4-dimethylphenyl)-2-phenyl-1-propanone
135584-30-4

1-(3,4-dimethylphenyl)-2-phenyl-1-propanone

Conditions
ConditionsYield
With aluminium trichloride In carbon disulfide for 14h; Ambient temperature;99%
o-xylene
95-47-6

o-xylene

ortho-xylene chlorinated products; mixture of

ortho-xylene chlorinated products; mixture of

Conditions
ConditionsYield
With chlorine; manganese trisacetylacetonate; 10H-phenothiazine-10-carbonyl chloride at 10℃; under 760.051 Torr; for 0.583333h; Product distribution / selectivity;99%
o-xylene
95-47-6

o-xylene

chromium(0) hexacarbonyl
199620-14-9, 13007-92-6

chromium(0) hexacarbonyl

(η6-o-xylene)tricarbonylchromium(0)
12129-29-2

(η6-o-xylene)tricarbonylchromium(0)

Conditions
ConditionsYield
In tetrahydrofuran; dibutyl ether refluxing for 1 wk; evapn. of solvents under vac., removing unreacted (Cr(CO)6) by sublimation, recrystn. from CH2Cl2 under N2;99%
With catalyst: CH3COOC4H9 In decalin byproducts: CO; (Ar); refluxed for 3 h; cooled to 20°C; filtered through Kieselguhr; catalyst evapd.; chromy.; evapd.; crystd. from benzene/pertoleum ether at -18°C;98%
With catalyst: butyl acetate In decalin byproducts: CO; refluxing for 2.5 h (catalyst: butyl acetate); freezing out at -18°C or quick chromy. of the decaline soln. on a SiO2 column;98%
Reed’s acid

Reed’s acid

o-xylene
95-47-6

o-xylene

[H(m-xylene)][CB11H6Br6]*(o-xylene)

[H(m-xylene)][CB11H6Br6]*(o-xylene)

Conditions
ConditionsYield
In o-xylene Schlenkware or glovebox; o-xylene was added to solid carborane acid; mixt. was stirred for few min; solvent removed (vac.); elem. anal.;99%
o-xylene
95-47-6

o-xylene

perfluoro-o-phenylenemercury trimer
18734-63-9

perfluoro-o-phenylenemercury trimer

perfluoro-ortho-phenylene mercury trimer - ortho-xylene (1:1)
649559-06-8

perfluoro-ortho-phenylene mercury trimer - ortho-xylene (1:1)

Conditions
ConditionsYield
In further solvent(s) Hg-compound was dissolved by boiling in o-xylene, cooled; slow evapd. in a well-aerated fume hood; elem. anal.;99%
o-xylene
95-47-6

o-xylene

benzoic acid
65-85-0

benzoic acid

2-methylbenzyl benzoate
38418-11-0

2-methylbenzyl benzoate

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide In water at 80℃; for 3h;99%
With di-tert-butyl peroxide; C11H23N2(1+)*Br4Fe(1-) at 110℃; for 24h;99%
With tert.-butylhydroperoxide; choline chloride; tetra-(n-butyl)ammonium iodide; urea In water at 80℃; for 12h; Green chemistry;90%
o-xylene
95-47-6

o-xylene

1-bromo-4-tert-butylbenzene
3972-65-4

1-bromo-4-tert-butylbenzene

1-(4-(tert-butyl) benzyl)-2-methylbenzene
70663-11-5

1-(4-(tert-butyl) benzyl)-2-methylbenzene

Conditions
ConditionsYield
With Xantphos-Pd-G3; potassium hexamethylsilazane at 110℃; for 12h; Inert atmosphere; Sealed tube;99%
hexafluoroacetone hydrate
677-71-4

hexafluoroacetone hydrate

o-xylene
95-47-6

o-xylene

4,4'-(hexafluoroisopropylidene)-bis-(o-xylene)
65294-20-4

4,4'-(hexafluoroisopropylidene)-bis-(o-xylene)

Conditions
ConditionsYield
With hydrogen fluoride at 100℃; under 7980.54 Torr; for 13h; Concentration; Temperature; Autoclave;98.7%
succinic acid anhydride
108-30-5

succinic acid anhydride

o-xylene
95-47-6

o-xylene

3-(3,4-dimethylbenzoyl)propionic acid
51036-98-7

3-(3,4-dimethylbenzoyl)propionic acid

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at 20℃; for 2h; Friedel-Crafts Acylation;98%
With [bmim]Cl*AlCl3 at 30℃; for 3h; Friedel-Crafts reaction;95%
With aluminium trichloride In dichloromethane86%
1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

o-xylene
95-47-6

o-xylene

((3,4-dimethylphenyl)methylene)dibenzene
500362-29-8

((3,4-dimethylphenyl)methylene)dibenzene

Conditions
ConditionsYield
With H5CoW12O40 supported on rice husk ash extracted nano silica at 60℃; for 0.5h; Reagent/catalyst; Green chemistry;98%
With boron trifluoride diethyl etherate; water at 80℃; for 2h; regioselective reaction;93%
With (diethylamino)difluorosulfonium tetrafluoroborate In dichloromethane at 20℃; for 48h; Inert atmosphere;89%
With phosphorus pentoxide
With 1-butyl-3-methylimidazolium tetrachloridoferrate(III) at 80℃; for 12h; Friedel-Crafts type benzylation; regioselective reaction;56 %Chromat.
o-xylene
95-47-6

o-xylene

2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

Conditions
ConditionsYield
With bromine In tetrachloromethane Solvent;98%
With bromine In tetrachloromethane for 1.5h; Ambient temperature;97%
With 2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one; silica gel for 4.5h; UV-irradiation;82%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

o-xylene
95-47-6

o-xylene

1-(1-adamantyl)-3,4-dimethylbenzene
62133-11-3

1-(1-adamantyl)-3,4-dimethylbenzene

Conditions
ConditionsYield
With potassium carbonate; palladium on activated charcoal at 120℃; for 12h;98%
With zinc(II) chloride Substitution; Heating;92%
With zinc(II) chloride for 10h; Heating;90%
With molybdenum hexacarbonyl at 120℃; for 2h; Sealed tube; regioselective reaction;72%
t-butyl bromide
507-19-7

t-butyl bromide

o-xylene
95-47-6

o-xylene

4-t-butyl-o-xylene
7397-06-0

4-t-butyl-o-xylene

Conditions
ConditionsYield
With pyrographite for 24h; Heating;98%
o-xylene
95-47-6

o-xylene

tert-Butyl iodide
558-17-8

tert-Butyl iodide

4-t-butyl-o-xylene
7397-06-0

4-t-butyl-o-xylene

Conditions
ConditionsYield
pyrographite for 24h; Heating;98%
o-xylene
95-47-6

o-xylene

trifluoroethyl (phenyl)diazoacetate

trifluoroethyl (phenyl)diazoacetate

2,2,2-trifluoroethyl 2-(3,4-dimethylphenyl)-2-phenylacetate

2,2,2-trifluoroethyl 2-(3,4-dimethylphenyl)-2-phenylacetate

Conditions
ConditionsYield
With C42H63O3P*Au(1+)*C7H5N*F6Sb(1-) at 20℃; for 0.05h; Schlenk technique;98%
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