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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

1,2,4-trimethylbenzene CAS NO.95-63-6

Cas:95-63-6

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,2,4-trimethylbenzene

Cas:95-63-6

Min.Order:25 Kilogram

Negotiable

Type:Lab/Research institutions

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Dayang Chem (Hangzhou) Co.,Ltd.

best service, quality anAppearance:Colorless transparent liquid Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:It is an important raw material and intermediate used in Organic Synthesis, Ph

1,2,4-TRIMETHYL BENZENE 95-63-6

Cas:95-63-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hefei TNJ chemical industry co.,ltd

1.Hefei TNJ Chemical Industry Co.Limited(ISO9001:2008),are strong in the field of Pharmaceuticals,food additives,plant extract and fine chemical for more than 10 years. 2.Full experience of large numbers container loading in main Chinese seap

1,2,4-trimethylbenzene

Cas:95-63-6

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1,2,4-trimethylbenzene

Cas:95-63-6

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Pseudocumene

Cas:95-63-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

CHENGDU YANXI is a comprehensive manufacturer and an international distribution of products throughout the world. Specialized in Scrap metal, Chemical raw materials, Paper products and color industry. We aim to become leading position in global dis

1,2,4-Trimethylbenzene 95-63-6 Pharmaceutical Intermediates

Cas:95-63-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

1,2,4-Trimethylbenzene Basic information Product Name: 1,2,4-Trimethylbenzene Synonyms: 1,3,4-TRIMETHYLBENZENE;1,2,4-TRIMETHYLBENZENE;PSI-CUMENE;PSEUDOCUMENE;PSEUDOCUMOL;PSC;TRIMETHYLBEN

1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Pseudocumene (PSC) Chemical name: 1,2,4-Trimethylbenzene (TMB) Molecular formula: C9H12 Molecular weight: 546.78 Structural formula: UN No.: 3295 CAS NO.: 95-63-6 Appearance: Colorless Clear Liquid Storage:Store in cool and dry p

1,2,4-Trimethylbenzene CAS: 95-63-6

Cas:95-63-6

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:95-63-6

Cas:95-63-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,2,4-trimethyl benzen

Cas:95-63-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1,2,4-Trimethyl Benzene from Wuxi TAA Chemical Industry Co.,Ltd. 1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic an

Hot sale 1,2,4-Trimethylbenzene CAS 95-63-6

Cas:95-63-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Other

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

1,2,4-TRIMETHYL BENZENE

Cas:95-63-6

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Hebei Lead Bio-Chemicals Co., Ltd.

Hebei Lead Bio-Chemicals Co., Ltd. established in 2006, devolved in resurching, manufacturing and supplying of pharmaceuticals,food ingredients, cosmetics,health care products, Chinese herb, plant extracts and some fine chemicals,is one of leading gr

Hot sale 1,2,4-Trimethyl Benzene 95-63-6 supplier with immediately delivery

Cas:95-63-6

Min.Order:0

Negotiable

Type:Manufacturers

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colorless transparent liquid Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used as Pharmaceuti

1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:1 Pound

Negotiable

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Benzene,1,2,4-trimethyl-

Cas:95-63-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Best service,high quality and cheap price. Storage:Keep away from heat,sparks and flames. Package:25kg/50kg/200kg drum or Customer demand Application:Used as pharmaceutical intermediates Transportation:BY sea/air or by courier

1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 95-63-6 with competitive price

Cas:95-63-6

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,2,4-TRIMETHYL BENZENE

Cas:95-63-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

sell high purity of 1,2,4-Trimethylbenzene Application:sell high purity of 1,2,4-Trimethylbenzene

sell high purity of 1,2,4-Trimethylbenzene

Cas:95-63-6

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl

Benzene,1,2,4-trimethyl-

Cas:95-63-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

1,2,4-trimethyl benzen manufacture

Cas:95-63-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

3,4-dimethylbenzaldehyde
5973-71-7

3,4-dimethylbenzaldehyde

A

o-xylene
95-47-6

o-xylene

B

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With palladium/alumina; hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 96.2%
B 3.8%
With hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 15.9%
B 84.2%
2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

crotonaldehyde
123-73-9

crotonaldehyde

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
Stage #1: 2,3-dimethyl-buta-1,3-diene; crotonaldehyde at 150℃; for 3h; Diels-Alder Cycloaddition;
Stage #2: With 5%-palladium/activated carbon In ethyl acetate at 260℃;
95%
2,3,5-Trimethyl-(4-methylphenylsulfonyloxy)benzene
312609-91-9

2,3,5-Trimethyl-(4-methylphenylsulfonyloxy)benzene

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With sodium tetrahydroborate; bis(triphenylphosphine)nickel(II) chloride; tricyclohexylphosphine In tetrahydrofuran at 60℃; for 14h;93%
prop-1-yne
74-99-7

prop-1-yne

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With (η4-1,5-hexadiene)(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)nickel In BENZENE-d6 at 20℃;91%
triplal
854432-99-8

triplal

A

para-xylene
106-42-3

para-xylene

B

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With palladium/alumina; hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 84.8%
B 6.5%
With hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 19.5%
B 73.2%
3,4-dimethylcyclohex-3-ene-1-carboxaldehyde
18022-66-7

3,4-dimethylcyclohex-3-ene-1-carboxaldehyde

A

o-xylene
95-47-6

o-xylene

B

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 17.5%
B 80.9%
With palladium/alumina; hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 73%
B 27%
2,4-dimethyl-benzyl chloride
824-55-5

2,4-dimethyl-benzyl chloride

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With sodium tetrahydroborate; (-) In ethanol at 20℃; for 2h;63%
With phosphorus; hydrogen iodide
With diethyl ether; magnesium Zersetzen der Reaktionsprodukte mit Wasser;
CpZr{(Me)CCHC(Me)CH}(dmpe)Cl

CpZr{(Me)CCHC(Me)CH}(dmpe)Cl

prop-1-yne
74-99-7

prop-1-yne

A

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

B

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

Conditions
ConditionsYield
In benzene-d6 1 turnover/day, catalytic react., 25°C; products detd. by NMR and GC;A 45%
B 55%
o-xylene
95-47-6

o-xylene

A

2-Ethyltoluene
611-14-3

2-Ethyltoluene

B

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

C

1,2,3-trimethylbenzene
526-73-8

1,2,3-trimethylbenzene

D

2-methyl-benzyl alcohol
89-95-2

2-methyl-benzyl alcohol

E

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

Conditions
ConditionsYield
With peracetic acid at 20 - 22℃; Product distribution; Irradiation; λ>2900 Angstroem;A 9.3%
B n/a
C n/a
D 36.9%
E n/a
para-xylene
106-42-3

para-xylene

A

4-Methylbenzyl alcohol
589-18-4

4-Methylbenzyl alcohol

B

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

C

4-methylethylbenzene
622-96-8

4-methylethylbenzene

D

1,2-di-p-tolylethane
538-39-6

1,2-di-p-tolylethane

Conditions
ConditionsYield
With peracetic acid at 20 - 22℃; Product distribution; Irradiation; λ>2900 Angstroem;A 32.3%
B 5.9%
C 10.2%
D n/a
m-xylene
108-38-3

m-xylene

A

1-Methyl-3-ethylbenzene
620-14-4

1-Methyl-3-ethylbenzene

B

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

C

1,2,3-trimethylbenzene
526-73-8

1,2,3-trimethylbenzene

D

1,2-di-m-tolylethane
4662-96-8

1,2-di-m-tolylethane

E

3-methylbenzyl alcohol
587-03-1

3-methylbenzyl alcohol

F

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

Conditions
ConditionsYield
With peracetic acid at 20 - 22℃; Product distribution; Irradiation; λ>2900 Angstroem;A 7.4%
B n/a
C n/a
D n/a
E 30%
F n/a
o-xylene
95-47-6

o-xylene

A

3,4-Dimethylphenol
95-65-8

3,4-Dimethylphenol

B

2-Ethyltoluene
611-14-3

2-Ethyltoluene

C

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

D

2,3-Dimethylphenol
526-75-0

2,3-Dimethylphenol

E

2-methyl-benzyl alcohol
89-95-2

2-methyl-benzyl alcohol

F

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

Conditions
ConditionsYield
With peracetic acid at 20 - 22℃; Product distribution; Irradiation; λ=2537 Angstroem;A n/a
B 24.3%
C n/a
D n/a
E 15.1%
F n/a
para-xylene
106-42-3

para-xylene

A

2,5-Dimethylphenol
95-87-4

2,5-Dimethylphenol

B

4-Methylbenzyl alcohol
589-18-4

4-Methylbenzyl alcohol

C

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

D

4-methylethylbenzene
622-96-8

4-methylethylbenzene

E

1,2-di-p-tolylethane
538-39-6

1,2-di-p-tolylethane

Conditions
ConditionsYield
With peracetic acid at 20 - 22℃; Product distribution; Irradiation; λ=2537 Angstroem;A 6.1%
B 13.5%
C 8.4%
D 23.5%
E n/a
acetone
67-64-1

acetone

A

ethane
74-84-0

ethane

B

propane
74-98-6

propane

C

o-xylene
95-47-6

o-xylene

D

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

E

toluene
108-88-3

toluene

F

benzene
71-43-2

benzene

G

Mixture of alkanes C4,C5 and m,p-Xylenes and O-compounds

Mixture of alkanes C4,C5 and m,p-Xylenes and O-compounds

Conditions
ConditionsYield
Zeolite HZSM-5(1) at 350℃; under 760 Torr; for 1h; Product distribution; Mechanism; 1)other times 2)other zeolites 3) impregnation of zeolites with basic oxides;A 3.4%
B 8.1%
C 11%
D 7.8%
E 15.4%
F 3.7%
G n/a
para-xylene
106-42-3

para-xylene

A

o-xylene
95-47-6

o-xylene

B

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

C

m-xylene
108-38-3

m-xylene

D

toluene
108-88-3

toluene

Conditions
ConditionsYield
Product distribution; Irradiation; other xylene, also with DCA;A 0.4%
B 13.2%
C 1.2%
D 5%
tetrachloromethane
56-23-5

tetrachloromethane

formaldehyd
50-00-0

formaldehyd

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With hydrogenchloride at 50 - 60℃; Einleiten von HCl, Kochen des Reaktionsprodukts mit aethanol. NaOH und Hydrogenolyse des gebildeten Aethylaether-Gemisches an Kupferchromit bei 300grad unter Druck;
tetrachloromethane
56-23-5

tetrachloromethane

methylene chloride
74-87-3

methylene chloride

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With aluminium trichloride at 95℃;
tetrachloromethane
56-23-5

tetrachloromethane

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With aluminium trichloride at 130 - 140℃;
formaldehyd
50-00-0

formaldehyd

o-xylene
95-47-6

o-xylene

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With hydrogenchloride Erwaermen der Reaktionsprodukte mit Zinkstaub und wss. NaOH auf 100grad;
With hydrogenchloride Erwaermen der Reaktionsprodukte mit Zinkstaub und wss. NaOH auf 100grad;
formaldehyd
50-00-0

formaldehyd

para-xylene
106-42-3

para-xylene

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With hydrogenchloride Erwaermen der Reaktionsprodukte mit Zinkstaub und wss. NaOH auf 100grad;
With hydrogenchloride Erwaermen der Reaktionsprodukte mit Zinkstaub und wss. NaOH auf 100grad;
3,5,5-Trimethylcyclohex-2-en-1-one
78-59-1

3,5,5-Trimethylcyclohex-2-en-1-one

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With phosphorus pentoxide
methylene chloride
74-87-3

methylene chloride

o-xylene
95-47-6

o-xylene

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With aluminium trichloride at 80℃;
phorone
504-20-1

phorone

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With phosphorus pentaoxide
With zinc(II) chloride
With phosphorus pentoxide
phorone
504-20-1

phorone

A

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

B

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

Conditions
ConditionsYield
With phosphorus pentoxide
With zinc(II) chloride
ethanol
64-17-5

ethanol

nitroso-(2,4,5-trimethyl-phenyl)-amidosulfuric acid

nitroso-(2,4,5-trimethyl-phenyl)-amidosulfuric acid

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
unter geringem Ueberdruck;
1,1,3-trimethylcyclohexane
3073-66-3, 150927-19-8, 150927-30-3

1,1,3-trimethylcyclohexane

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With Pt/Al2O3; hydrogen at 300℃;
With Pt/Al2O3; s-butyl chloride at 300℃;
bis-(2,4-dimethyl-phenyl)methane
32588-46-8

bis-(2,4-dimethyl-phenyl)methane

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With hydrogen; nickel; tungsten at 450℃; under 13974.6 Torr;
With molybdenum oxide-aluminium oxide; hydrogen at 300℃;
2,5-dimethylbenzyl chloride
824-45-3

2,5-dimethylbenzyl chloride

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With tetrahydrofuran; lithium aluminium tetrahydride; lithium hydride
With diethyl ether; magnesium Zersetzen der Reaktionsprodukte mit Wasser;
2,4,5-trimethylaniline
137-17-7

2,4,5-trimethylaniline

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
Diazotization.Reduktion mit Zinn in alkal. Loesung;
5-methyl-2-isopropylidenecyclopentanone
6784-16-3

5-methyl-2-isopropylidenecyclopentanone

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Conditions
ConditionsYield
With phosphorus pentoxide
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

1,2,4-tribromo-3,5,6-trimethyl-benzene
90326-72-0

1,2,4-tribromo-3,5,6-trimethyl-benzene

Conditions
ConditionsYield
With benzyltrimethylazanium tribroman-2-uide; zinc(II) chloride In acetic acid at 70℃; for 24h;99%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

1-bromo-2,4,5-trimethylbenzene
5469-19-2

1-bromo-2,4,5-trimethylbenzene

Conditions
ConditionsYield
With sulfuric acid; dihydrogen peroxide; iodine; iron(II) sulfate; sodium bromide In dichloromethane; water at 0℃;97.3%
With hydrogenchloride; sodium hypochlorite; sodium bromide In water at 29.85℃; for 8h; Product distribution; Further Variations:; Temperatures;96.2%
With bromine; iron; acetic acid
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

1-iodo-2,4,5-trimethylbenzene
2100-23-4

1-iodo-2,4,5-trimethylbenzene

Conditions
ConditionsYield
With N,N,N-trimethylbenzenemethanaminium dichloroiodate; zinc(II) chloride In acetic acid for 48h; Ambient temperature;97%
With iodine; Selectfluor In acetonitrile at 55 - 65℃; for 1.5h;88%
With aluminum oxide; iodine; copper dichloride at 60℃; for 3h; also other polymethylbenzenes;97 % Chromat.
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

1,2,4-benzene tricarboxylic acid
528-44-9

1,2,4-benzene tricarboxylic acid

Conditions
ConditionsYield
With air; acetic acid; 1N,3N,5N-trihydroxy-1,3,5-triazin-2,4,6[1H,3H,5H]-trione; cobalt(II) acetate; zirconyl acetate at 150℃; under 15200 Torr; for 6h;97%
With 7H2O*3H3N*3H(1+)*[FeMo6O18(OH)6](3-); sodium carbonate; acetic acid at 100℃; under 750.075 Torr; for 12h; Reagent/catalyst; Temperature; Inert atmosphere;97%
With cobalt(II) acetate; manganese(II) acetate; acetic acid at 110 - 220℃; under 14251.4 - 16501.7 Torr; Pressure; Temperature;96.32%
2-mesitylenesulphonyl chloride
773-64-8

2-mesitylenesulphonyl chloride

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

1,3,5-trimethyl-2-(2,4,5-trimethyl-benzenesulfonyl)-benzene
1417718-29-6

1,3,5-trimethyl-2-(2,4,5-trimethyl-benzenesulfonyl)-benzene

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at 25℃; for 2h; Inert atmosphere;96%
With aluminum (III) chloride In dichloromethane at 20℃; for 2h;96%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

ethyl-methyl-malonyl dichloride
5659-96-1

ethyl-methyl-malonyl dichloride

2-ethyl-2,4,5,7-tetramethylindan-1,3-dione
178387-33-2

2-ethyl-2,4,5,7-tetramethylindan-1,3-dione

Conditions
ConditionsYield
AlCl3 In dichloromethane93%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

2,3,5-Trimethyl-1,4-benzoquinone
935-92-2

2,3,5-Trimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With phthalic anhydride; dihydrogen peroxide In neat (no solvent) at 118 - 120℃; for 2.5h; Reagent/catalyst; Temperature; Time; Solvent;92%
With dihydrogen peroxide; acetic anhydride; methyltrioxorhenium(VII) In water at 60℃;37%
With 3-chloro-benzenecarboperoxoic acid In chloroform at 60 - 70℃; for 0.5h;16.5%
[(η6-benzene)IrH2(P(iPr)3)]BF4
252913-37-4

[(η6-benzene)IrH2(P(iPr)3)]BF4

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

[(η6-1,2,4-trimethylbenzene)IrH2(P(iPr)3)]BF4
252913-45-4

[(η6-1,2,4-trimethylbenzene)IrH2(P(iPr)3)]BF4

Conditions
ConditionsYield
In acetone under Ar; a soln. of Ir complex in acetone was treated with a 10-fold excess of the arene and stirred for 1 h; the soln. was concd., treated with a mixt. of (C2H5)2O/THF, the ppt. wasfiltered, washed with (C2H5)2O, dried in vac.; elem. anal.;92%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

5-chloro-1,2,4-trimethylbenzene
31053-96-0

5-chloro-1,2,4-trimethylbenzene

Conditions
ConditionsYield
With hydrogenchloride; sodium chloride; sodium hydroxide In water; acetonitrile Solvent; Reagent/catalyst;91.2%
With benzyltrimethylazanium tetrachloro-λ3-iodanuide In acetic acid for 20h; Ambient temperature;52%
With chlorine im Dunkeln;
With aluminium trichloride; sulfuryl dichloride
carbon monoxide
201230-82-2

carbon monoxide

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

A

2,4,5-trimethylbenzaldehyde
5779-72-6

2,4,5-trimethylbenzaldehyde

B

3-Formyl-2,5,6-trimethylbenzenesulfonyl fluoride

3-Formyl-2,5,6-trimethylbenzenesulfonyl fluoride

Conditions
ConditionsYield
With antimony pentafluoride; fluorosulphonic acid at 0℃; for 1h;A 90%
B 1%
With antimony pentafluoride; fluorosulphonic acid at 0℃; for 1h; Yields of byproduct given. Title compound not separated from byproducts;A 90 % Chromat.
B n/a
3,3-Dimethylacryloyl chloride
3350-78-5

3,3-Dimethylacryloyl chloride

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

2',3,4',5'-tetramethylcrotonophenone
10425-85-1

2',3,4',5'-tetramethylcrotonophenone

Conditions
ConditionsYield
With aluminium trichloride89%
With aluminium trichloride In nitromethane
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

4-Methoxycarbonylbenzoyl chloride
7377-26-6

4-Methoxycarbonylbenzoyl chloride

4-(2,4,5-trimethyl-benzoyl)-benzoic acid methyl ester

4-(2,4,5-trimethyl-benzoyl)-benzoic acid methyl ester

Conditions
ConditionsYield
With In(OSO2CF3)3 for 0.133333h; Friedel-Crafts acylation reaction; microwave irradiation;89%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

A

isophthalic acid
121-91-5

isophthalic acid

B

terephthalic acid
100-21-0

terephthalic acid

C

1,2,4-benzene tricarboxylic acid
528-44-9

1,2,4-benzene tricarboxylic acid

Conditions
ConditionsYield
With oxygen; titanium(IV) isopropylate; tetrabutoxytitanium; manganese(II) acetate; cobalt(II) acetate; ammonium bromide; cerous nitrate In water; acetic acid at 150 - 225℃; under 5250.53 - 18751.9 Torr; for 1.2 - 1.25h; Product distribution / selectivity;A n/a
B n/a
C 88.3%
aluminium trichloride
7446-70-0

aluminium trichloride

thallium chloride

thallium chloride

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

di-μ-tetrachloroaluminato-1κCl,1κCl':2κCl,2κCl''-bis(bis(η(6)-1,2,4-trimethylbenzene)thallium)

di-μ-tetrachloroaluminato-1κCl,1κCl':2κCl,2κCl''-bis(bis(η(6)-1,2,4-trimethylbenzene)thallium)

Conditions
ConditionsYield
In further solvent(s) N2-atmosphere; equimolar amts. of TlCl and AlCl3, stirring in 1,2,4-trimethylbenzene at room temp.; filtration, slow cooling to 0°C (crystn.); elem. anal.;86%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

2-bromo-5-(2-trimethylsilyloxy-1,1,1-trifluoroeth-2-yl)thiophene

2-bromo-5-(2-trimethylsilyloxy-1,1,1-trifluoroeth-2-yl)thiophene

2-(2,2,2-trifluoro-1-(2,4,5-trimethylphenyl)ethyl)thiophene

2-(2,2,2-trifluoro-1-(2,4,5-trimethylphenyl)ethyl)thiophene

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In dichloromethane at -40℃; for 0.0166667h;86%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Trimethylhydroquinone
700-13-0

Trimethylhydroquinone

Conditions
ConditionsYield
Stage #1: 1,2,4-Trimethylbenzene With formic acid; dihydrogen peroxide; calcium chloride at 50 - 90℃; for 5h;
Stage #2: With sodium dithionite In water at 45℃; for 2h; Temperature; Reagent/catalyst;
85.6%
With peracetic acid; sodium disulfite 1) acetic acid, 70 deg C, 1 h; 2) water, 20 deg C, 0.5 h.; Yield given. Multistep reaction;
Multi-step reaction with 3 steps
1: sodium bromide; sulfuric acid; iron(II) sulfate; iodine; dihydrogen peroxide / dichloromethane; water / 0 °C
2: potassium dichromate; sulfuric acid; copper(II) sulfate / water; acetonitrile / 45 °C
3: sodium carbonate; hydrogen / 80 °C
View Scheme
copper(II) hexafluoro-2,4-pentanedionate

copper(II) hexafluoro-2,4-pentanedionate

4,4,5,5-pentamethyl-2-(1'-n-butyl-pyrazole-4'-yl)-4,5-dihydro-1H-imidazolyl-3-oxide-1-oxyl
872209-62-6

4,4,5,5-pentamethyl-2-(1'-n-butyl-pyrazole-4'-yl)-4,5-dihydro-1H-imidazolyl-3-oxide-1-oxyl

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

Cu(hexafluoroacetylacetonate)2(2-(1-butyl-1H-pyrazol-4-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl)*1/2C9H12 Cu(CH(COCF3)2)2(C14H23N4O2)*0.5C9H12, high temperature

Cu(hexafluoroacetylacetonate)2(2-(1-butyl-1H-pyrazol-4-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl)*1/2C9H12 Cu(CH(COCF3)2)2(C14H23N4O2)*0.5C9H12, high temperature

Conditions
ConditionsYield
In further solvent(s) dissolving mixt. of copper compd. and nitronyl nitroxide deriv. in 1,2,4-trimethylbenzene with heating to 70°C for 2-3 min; cooling to room temp., keeping with slow evapn. at 5°C for 1-2 d,filtration, washing with cold heptane, air drying, elem. anal.;85%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

(E)-5-(4-chlorophenyl)-1-phenylpent-4-en-2-yn-1-one

(E)-5-(4-chlorophenyl)-1-phenylpent-4-en-2-yn-1-one

(E)-2-(3-(4-chlorophenyl)-4,5,7-trimethyl-2,3-dihydro-1H-inden-1-ylidene)-1-phenylethan-1-one

(E)-2-(3-(4-chlorophenyl)-4,5,7-trimethyl-2,3-dihydro-1H-inden-1-ylidene)-1-phenylethan-1-one

Conditions
ConditionsYield
Stage #1: 1,2,4-Trimethylbenzene; (E)-5-(4-chlorophenyl)-1-phenylpent-4-en-2-yn-1-one With trifluorormethanesulfonic acid In dichloromethane at 20℃;
Stage #2: With water In dichloromethane
85%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

acetic acid
64-19-7

acetic acid

A

2,3,5-Trimethyl-1,4-benzoquinone
935-92-2

2,3,5-Trimethyl-1,4-benzoquinone

B

Duroquinone
527-17-3, 70128-24-4

Duroquinone

C

2,3,5-trimethylanisole
20469-61-8

2,3,5-trimethylanisole

D

2,3,6-trimethylphenyl acetate
62687-45-0

2,3,6-trimethylphenyl acetate

E

1-methoxy-2,4,5-trimethylbenzene
21573-38-6

1-methoxy-2,4,5-trimethylbenzene

F

3-acetoxy-2,5-dihydroxy-5-carboxy-2,3,5-trimethylpentan-4-olide
109576-73-0

3-acetoxy-2,5-dihydroxy-5-carboxy-2,3,5-trimethylpentan-4-olide

Conditions
ConditionsYield
With peracetic acid at 70℃; for 0.5h; Product distribution; Kinetics; Thermodynamic data; other reaction time: 4 h.;A 16%
B 0.03%
C 0.02%
D 0.03%
E 0.04%
F 82.6%
formaldehyd
50-00-0

formaldehyd

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

benzamide
55-21-0

benzamide

C17H19NO

C17H19NO

Conditions
ConditionsYield
With water at 100℃; for 10h; Sealed tube; Green chemistry; regioselective reaction;82%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

C144H168O24

C144H168O24

C144H168O24*C9H12

C144H168O24*C9H12

Conditions
ConditionsYield
at 160℃; for 72h; complexation;81%
[IrCl(C8H3(CH3)3C4F4)]2
94363-96-9

[IrCl(C8H3(CH3)3C4F4)]2

1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

silver perchlorate

silver perchlorate

[Ir(C8H3(CH3)3C4F4)(C6H3(CH3)3)](1+)*ClO4(1-)=[Ir(C8H3(CH3)3C4F4)(C6H3(CH3)3)]ClO4
94364-06-4

[Ir(C8H3(CH3)3C4F4)(C6H3(CH3)3)](1+)*ClO4(1-)=[Ir(C8H3(CH3)3C4F4)(C6H3(CH3)3)]ClO4

Conditions
ConditionsYield
In dichloromethane byproducts: AgCl; stirring, 1h; filtering off pptd. AgCl (kieselgur); concentrating; addn. of ether; pptn.; recrystn. (dichloromethane/ether); elem. anal.;81%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

4-chlorobenzoyl chloride
586-75-4

4-chlorobenzoyl chloride

4'-bromo-2,4,5-trimethylbenzophenone
1166846-04-3

4'-bromo-2,4,5-trimethylbenzophenone

Conditions
ConditionsYield
Stage #1: 4-chlorobenzoyl chloride With aluminum (III) chloride In dichloromethane at -20℃; Friedel Crafts acylation; Inert atmosphere;
Stage #2: 1,2,4-Trimethylbenzene In dichloromethane Friedel Crafts acylation;
Stage #3: With hydrogenchloride; water In dichloromethane
81%
1,2,4-Trimethylbenzene
95-63-6

1,2,4-Trimethylbenzene

(E)-5-phenyl-1-(4-methylphenyl)pent-4-en-2-yn-1-one
1260102-46-2

(E)-5-phenyl-1-(4-methylphenyl)pent-4-en-2-yn-1-one

(E)-1-(4-methylphenyl)-2-(4,5,7-trimethyl-3-phenyl-2,3-dihydro-1H-inden-1-ylidene)ethan-1-one

(E)-1-(4-methylphenyl)-2-(4,5,7-trimethyl-3-phenyl-2,3-dihydro-1H-inden-1-ylidene)ethan-1-one

Conditions
ConditionsYield
Stage #1: 1,2,4-Trimethylbenzene; (E)-5-phenyl-1-(4-methylphenyl)pent-4-en-2-yn-1-one With trifluorormethanesulfonic acid In dichloromethane at 20℃;
Stage #2: With water In dichloromethane
80%
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