CAS No.108-38-3,1,3-Dimethylbenzene Suppliers,MSDS download

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

m-Xylene

Cas:108-38-3

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Meta-Xylene supplier in China

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance White to off-white powder Conforms Purity ≥98.0%

High purity 108-38-3 m-Xylene

Cas:108-38-3

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

m-Xylene

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Henan Tianfu Chemical Co., Ltd.

m-Xylene Basic information Product Name: m-Xylene Synonyms: [srp]m-methyltoluene;1,3-dimethyl-benzen;2,4-Xylene;3-methyltoluene;3-xylene;ai3-08916;Benzene,1,3-dimethyl-;m-Dimethylben

1,3-Dimethylbenzene 108-38-3

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Henan Sinotech Import&Export Corporation

Product name m-Xylene Synonyms M-XYLENE, 1X1ML, MEOH, 200UG/ML;M-XYLENE, STANDARD FOR GC;M-XYLENE DISTILLED 1 L;M-XYLENE DISTILLED 5 L;M-XYLENE, 1X1ML, MEOH, 5000UG/ML;M-XYLENE, 5000MG, NEAT;M-XYLOL,

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:clear colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application: Meta-Xylene is used for the production of is

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Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

1,3-DimethylbenzeneCAS NO.: 108-38-3

Cas:108-38-3

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Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

1,3-Dimethylbenzene

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

1,3-Dimethylbenzene

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

m-Xylene

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

M-Xylene

Cas:108-38-3

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Meta-Xylene

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Enke Pharma-tech Co.,Ltd. （Cangzhou, China ）

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

m-Xylene

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 108-38-3 with competitive price

Cas:108-38-3

Min.Order:1 Kilogram

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

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Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Meta-Xylene

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Hubei Langyou International Trading Co., Ltd

TIANFUCHEM--High purity 108-38-3 m-Xylene Application:TIANFUCHEM--High purity 108-38-3 m-Xylene

TIANFUCHEM--High purity 108-38-3 m-Xylene

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Hangzhou Fandachem Co.,Ltd

1,3-Dimethylbenzene cas 108-38-3Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1,3-Dimethylbenzene cas 108-38-3

Cas:108-38-3

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Hunan Longxianng Runhui Trading Co.,Ltd

TIANFUCHEM--High purity 108-38-3 m-XyleneAppearance:powder Storage:room tempurature Package:As required Application:medical Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea LCL/FC

TIANFUCHEM--High purity 108-38-3 m-Xylene

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Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

m-Xylene

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Beantown Chemical

in stock Application:108-38-3

m-Xylene, 99%

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HENAN SUNLAKE ENTERPRISE CORPORATION

Our company is a professional production leading factory in China in pharmaceutical area of many years,our products have exported to USA, Greece, Spain, UK, Australia and other countries, and we have got very good feedback from our cust

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Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

1,3-Dimethylbenzene

Cas:108-38-3

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Hebei Ruishun Trade Co.,Ltd

Hebei ruishun trade co.,ltd, registered capital one million,have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center,seek development by credit reputation.our products have a large price advanta

m-Xylene

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Qingdao Sigma Chemical Co., Ltd.

Qingdao Sigma Chemical Ltd is is a global chemical industry manufacturers and suppliers of pharmaceuticals and intermediates, peptide,Nootropis etc API, food and feed additives, herbal extracts, agrochemicals and fine chemicals etc. Our Labo

High Quality m-Xylene

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Synthetic route

: 132636-71-6
3-(3,5-Dimethyl-phenoxy)-benzo[d]isothiazole 1,1-dioxide

A: 108-38-3
m-xylene

B: 81-07-2
saccharin

Conditions

Conditions	Yield
With sodium hypophosphite; palladium on activated charcoal In water; benzene for 2.5h; Heating;	A 100% B n/a

: 620-19-9
1-chloromethyl-3-methyl-benzene

: 108-38-3
m-xylene

Conditions

Conditions	Yield
With palladium dichloride In methanol at 40℃; for 1h; Green chemistry; chemoselective reaction;	99%
With Perbenzoic acid; tri-n-butyl-tin hydride In benzene at 90℃; for 12h; Mechanism; in the presence of α-chlorotoluene (competitor), relative reactivity;

: 587-03-1
3-methylbenzyl alcohol

: 108-38-3
m-xylene

Conditions

Conditions	Yield
With palladium dichloride In methanol at 40℃; for 18h; Inert atmosphere; Green chemistry; chemoselective reaction;	99%
With 2,4,6-trimethyl-pyridine; 4,4'-dimethoxyphenyl disulfide; iridium(lll) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate; triphenylphosphine In toluene for 24h; Irradiation;	68 %Chromat.

: 3101-50-6
1-methyl-3-methylene-cyclohexane

: 108-38-3
m-xylene

Conditions

Conditions	Yield
With n-butyllithium; potassium 2-methylbutan-2-olate Mechanism; 1) r.t., 16 h, 2) reflux, 6 h; further reagent: D2O;	96%

: 100379-00-8
2,6-dimethylbenzene boronic acid

: 108-38-3
m-xylene

Conditions

Conditions	Yield
With water at 20℃; for 48h;	96%
With potassium methanolate In methanol at 120℃; for 12h; Catalytic behavior; Solvent; Sealed tube; Green chemistry;	67 %Chromat.

: 499-06-9
3,5-dimethylbenzoic acid

: 1552-94-9, 28010-12-0, 28010-13-1, 38446-98-9, 54352-97-5
5-phenyl-2,4-pentadienoic acid

: 108-38-3
m-xylene

Conditions

Conditions	Yield
With silver(I) acetate; potassium carbonate In N,N-dimethyl acetamide at 140℃;	94%

: 111-26-2
hexan-1-amine

: 556-96-7
5-bromo-1,3-xylene

A: 108-38-3
m-xylene

B: N-n-hexyl-3,5-dimethylbenzenamine

C: Bis-(3,5-dimethyl-phenyl)-hexyl-amine

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine); sodium t-butanolate In toluene at 80℃; for 2h; Arylation;	A n/a B 88% C n/a
With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate In toluene at 80℃; for 3h; Arylation;

...Expand

: 4214-28-2
1-iodo-2,4-dimethylbenzene

: 108-38-3
m-xylene

Conditions

Conditions	Yield
With formaldehyd; palladium diacetate; caesium carbonate In dimethyl sulfoxide at 80℃; for 12h;	85%

: 7452-79-1
ethyl 2-methylbutyrate

: 201230-82-2
carbon monoxide

: 63509-96-6
2,6-xylyllithium

A: 91873-92-6
1-(2,6-Dimethyl-phenyl)-3-methyl-pentane-1,2-dione

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
In tetrahydrofuran; Dimethyl ether at -135℃;	A 84% B 13%

...Expand

: 576-22-7
2-Bromo-m-xylene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

A: 108-38-3
m-xylene

B: 2-(2,6-bismethylphenyl)-4,4,5,5-tetramethyl[1,3,2]dioxaborolane

Conditions

Conditions	Yield
With triethylamine; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 100℃; for 6h;	A n/a B 82%

...Expand

: 100379-00-8
2,6-dimethylbenzene boronic acid

: 105-36-2
ethyl bromoacetate

A: 105337-15-3
ethyl 2-(2,6-dimethylphenyl)acetate

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
With potassium fluoride; benzyltriethylammonium bromide; tris-(o-tolyl)phosphine; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran for 24h; Product distribution / selectivity; Reflux;	A 81.9% B n/a

...Expand

: 22445-41-6
3,5-dimethylphenyl iodide

: 123-30-8
4-amino-phenol

A: 86823-17-8
4-(3,5-dimethylphenoxy)aniline

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
With copper(l) iodide; potassium carbonate; (1S,2S)-N,N'-dimethyl-1,2-diaminocyclohexane In propyl cyanide at 70℃; for 24h; Inert atmosphere;	A 76% B 14 %Chromat.

...Expand

: 79-20-9
acetic acid methyl ester

: 201230-82-2
carbon monoxide

: 63509-96-6
2,6-xylyllithium

A: 150457-77-5
1-(2,6-Dimethyl-phenyl)-propane-1,2-dione

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether; pentane at -135 - 25℃;	A 9% B 73%
In tetrahydrofuran; Dimethyl ether at -135℃;	A 9% B 48%

...Expand

: 137203-34-0
bis(trimethylaluminum)–1,4-diazabicyclo[2.2.2]octane adduct

: 625-95-6
3-Iodotoluene

: 108-38-3
m-xylene

Conditions

Conditions	Yield
With dichloro bis(acetonitrile) palladium(II); dicyclohexyl(2',6'-diisopropyl-4'-sulfobiphenyl-2-yl)phosphonium hydrogen sulfate In tetrahydrofuran at 65℃; for 4h; Inert atmosphere; Ionic liquid; chemoselective reaction;	73%

: 110-54-3
hexane

A: 95-47-6
o-xylene

B: 106-42-3
para-xylene

C: 100-41-4
ethylbenzene

D: 108-38-3
m-xylene

E: 108-88-3
toluene

F: 71-43-2
benzene

Conditions

Conditions	Yield
540 degC; treated 16 h; U type zeolite at 450℃; Product distribution;	A n/a B n/a C n/a D n/a E 10.8% F 72.2%
540 degC; treated 16 h; UHS type zeolite at 450℃; Product distribution;	A n/a B n/a C n/a D n/a E 33.3% F 50%

...Expand

: 201230-82-2
carbon monoxide

: 22445-41-6
3,5-dimethylphenyl iodide

A: 5779-95-3
3,5-dimethylbenzaldehyde

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
With hydrogen; potassium carbonate In 1,4-dioxane at 120 - 140℃; under 30003 Torr; for 20h; Autoclave;	A 71% B 6%

...Expand

: 623-42-7
butanoic acid methyl ester

: 201230-82-2
carbon monoxide

: 63509-96-6
2,6-xylyllithium

A: 91887-15-9
1-(2,6-Dimethyl-phenyl)-pentane-1,2-dione

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
In tetrahydrofuran; Dimethyl ether at -135℃;	A 66% B 20%

...Expand

: 22445-41-6
3,5-dimethylphenyl iodide

: di(cyclohexa-2,5-dien-1-yl)silane

A: di(cyclohexa-2,5-dien-1-yl)(3,5-dimethylphenyl)silane

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
With bis(tri-t-butylphosphine)palladium(0); diisopropylamine In benzene at 20℃; for 24h; Glovebox; Sealed tube;	A 66% B n/a

...Expand

: 28042-78-6
2,4-dimethylbenzaldazine

A: 78032-06-1
5,7-dimethylphthalazine

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
With aluminium trichloride; aluminum tri-bromide at 185 - 195℃; for 0.5h;	A 65% B n/a

: pyrilium tetrafluoroborate

: 591-51-5
phenyllithium

A: 121077-51-8
(2Z,4E)-5-phenylpenta-2,4-dienal

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
In tetrahydrofuran at -78℃; for 4h; Yields of byproduct given;	A 61% B n/a

...Expand

: 556-97-8
1-chloro-3,5-dimethylbenzene

: 73183-34-3
bis(pinacol)diborane

A: 2,2'-(3,5-dimethyl-1,2-phenylene)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

B: 108-38-3
m-xylene

C: 325142-93-6
2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions

Conditions	Yield
With bis(1,3-dimesityl-1H-imidazol-2(3H)-ylidene)nickel(0); potassium methanolate In hexane at 25℃; for 6h; Inert atmosphere; Irradiation;	A 3% B 19 %Chromat. C 61%

...Expand

: 142-82-5
n-heptane

A: 95-47-6
o-xylene

B: 106-42-3
para-xylene

C: 100-41-4
ethylbenzene

D: 108-38-3
m-xylene

E: 108-88-3
toluene

F: 71-43-2
benzene

Conditions

Conditions	Yield
540 degC; treated 16 h; U type zeolite at 450℃; Product distribution;	A n/a B n/a C n/a D n/a E 58.5% F 6%
540 degC; treated 16 h; UHS type zeolite at 450℃; Product distribution;	A n/a B n/a C n/a D n/a E 42.8% F 8.8%

...Expand

: 87241-52-9
2,4-dimethylphenyl trifluoromethanesulfonate

A: 108-38-3
m-xylene

B: 105-67-9
2,4-Xylenol

Conditions

Conditions	Yield
With lithium; nickel dichloride In tetrahydrofuran at 20℃; Reduction;	A 58% B 15%

: tert-butyl (2,4-dimethylphenyl)carbonate

: 73183-34-3
bis(pinacol)diborane

A: 2-(2,4-bismethylphenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
With cesium fluoride; 2-mercaptopyridine sodium salt In acetonitrile at 30 - 35℃; for 36h; Irradiation; Inert atmosphere;	A 57% B 13 %Chromat.

...Expand

: 5441-52-1
3,5-dimethylcyclohexan-1-ol

A: 2320-30-1
3,5-dimethylcyclohexanone

B: 108-38-3
m-xylene

C: 108-68-9
3,5-Dimethylphenol

Conditions

Conditions	Yield
aluminum oxide; nickel at 350℃; Product distribution; effect of temperature on conversion; various temperatures, catalysts various origin and amount;	A 34.5% B 56% C 0.7%

...Expand

: 31689-43-7
1-methyl-3-methylcyclohexa-2,5-dienecarboxylic acid

A: 108-38-3
m-xylene

: (1S,5S)-1,5-Dimethyl-6-oxa-bicyclo[3.2.1]oct-2-en-7-one

Conditions

Conditions	Yield
With chlorosulfonic acid In dichloromethane at 0℃; for 0.166667h;	A 32% B 53%

: 31689-43-7
1-methyl-3-methylcyclohexa-2,5-dienecarboxylic acid

A: 643749-27-3
C9H12O2

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
With chlorosulfonic acid In dichloromethane at 0℃; for 0.166667h;	A 53% B 32%

: 95-66-9
2,4-dimethylchlorobenzene

A: 3976-36-1
2,2',4,4'-tetramethylbiphenyl

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
With PEG-400; sodium hydroxide; zinc; palladium on activated charcoal In water at 100℃; for 2h; coupling; reduction;	A 51% B 38 % Chromat.

: 617-86-7
triethylsilane

: 22445-41-6
3,5-dimethylphenyl iodide

A: (3,5-dimethylphenyl)triethylsilane

B: 108-38-3
m-xylene

Conditions

Conditions	Yield
With potassium phosphate; bis(tri-t-butylphosphine)palladium(0) In 1-methyl-pyrrolidin-2-one at 20℃; for 60h;	A 51% B 36 % Chromat.

...Expand

: 156-60-5
trans-1,2-dichloroethylene

: 172975-69-8
3,5-dimethylphenyl boronic acid

A: 1-[(E)-2-chlorovinyl]-3,5-dimethylbenzene

B: 13863-27-9
(E)-1,2-bis(3,5-dimethylphenyl)ethene

C: 108-38-3
m-xylene

Conditions

Conditions	Yield
With cesium fluoride; tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis(di-tert-butylphosphino)biphenyl In 1,4-dioxane at 70℃; Suzuki coupling;	A 50% B n/a C n/a

...Expand

: 108-24-7
acetic anhydride

: 108-38-3
m-xylene

: 89-74-7
2,4-dimethylacetophenone.

Conditions

Conditions	Yield
With gallium tri(nonafluorobutane sulfonate); lithium perchlorate In nitromethane at 20℃; for 6h; Acetylation; Friedel-Crafts reaction;	100%
With lithium perchlorate; hafnium tetrakis(trifluoromethanesulfonate) In nitromethane for 6h; Product distribution; Ambient temperature; effect of var. Lewis acid catalysts, LiClO4 and different solvents;	91%
With hafnium(IV) trifluoromethanesulfonate; lithium perchlorate In nitromethane for 6h; Product distribution; Ambient temperature; other aromatic compounds, acylation and alkylation agents, Lewis acids, var. concetration of LiClO4;	91%

: 98-88-4
benzoyl chloride

: 108-38-3
m-xylene

: 1140-14-3
2,4-Dimethyl benzophenone

Conditions

Conditions	Yield
With gallium(III) triflate; 1-dodecyloxy-4-(heptadecafluorooctyl)benzene In carbon dioxide at 100℃; under 60004.8 Torr; for 6h;	100%
Hf[N(SO2C8F17)2]4 In various solvent(s) at 120℃; for 3h;	96%
With VNU-1 In nitrobenzene at 120℃; for 0.0833333h; Friedel-Crafts Acylation; Microwave irradiation;	92%

: 64-19-7
acetic acid

: 108-38-3
m-xylene

: 89-74-7
2,4-dimethylacetophenone.

Conditions

Conditions	Yield
With trifluoroacetic anhydride; bismuth(lll) trifluoromethanesulfonate at 30℃; for 6h; Product distribution; Further Variations:; Catalysts; Reagents; Temperatures; reaction times; Friedel-Crafts acetylation;	100%
With trifluoromethylsulfonic anhydride at 20℃; for 0.0833333h; Friedel-Crafts acylation;	97%
Stage #1: acetic acid; m-xylene With trifluoroacetic anhydride In dichloromethane at 20℃; for 0.25h; Stage #2: With trifluorormethanesulfonic acid In dichloromethane at 20℃; for 1h;	88%

: 108-38-3
m-xylene

: 638-04-0, 2207-03-6, 69685-67-2, 69685-68-3, 129939-72-6, 129939-73-7, 591-21-9
1,3-dimethylcyclohexane

Conditions

Conditions	Yield
With hydrogen; [(norbornadiene)rhodium(I)chloride]2; phosphinated polydiacetylene In n-heptane at 30℃; under 60800 Torr; for 1.5h;	100%
With 5% Ru/MgO; hydrogen In tetrahydrofuran at 120℃; under 7600.51 Torr; for 2.9h;	100%
With Ti8O8(14+)6C8H4O4(2-)4O(2-)3.3Li(1+)0.7Co(2+)0.7C4H8O0.7H(1-); hydrogen In neat (no solvent) at 120℃; under 37503.8 Torr; for 18h;	100%

: 5565-36-6
1,4-bis-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzene

: 108-38-3
m-xylene

: 2712-78-9
bis-[(trifluoroacetoxy)iodo]benzene

: 1417418-28-0
C14H14I(1+)*C2F3O2(1-)

Conditions

Conditions	Yield
With air In dichloromethane at 20℃; for 6h; regioselective reaction;	100%

...Expand

: 108-38-3
m-xylene

: 626-16-4
3-(chloromethyl)benzyl chloride

Conditions

Conditions	Yield
With chlorine; 1-butyl-3-methylimidazolium chloride at 58℃; for 3h; Reagent/catalyst; Temperature; Irradiation; Ionic liquid;	99.18%
With chlorine Sonnenlicht;
With phosphorus pentachloride at 190℃;

: 91-01-0
1,1-Diphenylmethanol

: 108-38-3
m-xylene

: 6944-21-4
((2,4-dimethylphenyl)methylene)dibenzene

Conditions

Conditions	Yield
With silica gel supported sodium hydrogen sulfate at 60℃; for 0.5h; Friedel-Crafts type alkylation;	99%
With boron trifluoride diethyl etherate; water at 80℃; for 2h; regioselective reaction;	92%
With phosphorus pentoxide

: 18734-63-9
perfluoro-o-phenylenemercury trimer

: 108-38-3
m-xylene

: 649559-07-9
perfluoro-ortho-phenylene mercury trimer - meta-xylene (1:1)

Conditions

Conditions	Yield
In further solvent(s) Hg-compound was dissolved by boiling in m-xylene, cooled; slow evapd. in a well-aerated fume hood; elem. anal.;	99%

: 60430-43-5
norborna-2,5-diene(1,2-bis(diphenylphosphino)ethane)rhodium(I) tetrafluoroborate

: 108-38-3
m-xylene

: 188659-74-7
(C6H5)2PCH2CH2P(C6H5)2RhC6H4(CH3)2(1+)*BF4(1-)=[(C6H5)2PCH2CH2P(C6H5)2RhC6H4(CH3)2]BF4

Conditions

Conditions	Yield
With H2 In methanol (N2); solution of Rh complex was bubbled with H2 (5 min), concn. of the solution, addn. of 1,3-dimethylbenzene, stirring (12 h, room temp.); removal of the solvent;	99%

: 531490-86-5
[Ir(2,6-bis(di-tert-butylphosphinomethylene)pyridine)(cyclooctene)][PF6]

: 108-38-3
m-xylene

: 898225-76-8
[Ir(2,6-bis(di-tert-butylphosphinomethylene)pyridine)(H)(m-xylyl)][PF6]

Conditions

Conditions	Yield
In m-xylene under N2 atm. soln. Ir complex in m-xylene was heated at 60°C for1 h; solvent was evapd., residue was washed with pentane and ether and dried in vacuo overnight; elem. anal.;	99%

: 108-38-3
m-xylene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 325142-93-6
2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions

Conditions	Yield
With RhH{κ3-P,O,P-[9,9-dimethyl-4,5-bis-(diisopropylphosphino)xanthene2]}; cyclohexene at 110℃; for 48h; Inert atmosphere; Glovebox;	99%
With IrH2(Bpin){κ3-P,O,P-[9,9-dimethyl-4,5-bis(diisopropylphosphino)xanthene]}; cyclohexene at 110℃; for 18h; Inert atmosphere; Glovebox;	95%
With (N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)CuFp at 25℃; for 48h; Inert atmosphere; Glovebox; UV-irradiation; Sealed tube;	80%

: 14104-20-2
silver tetrafluoroborate

: 12354-84-6, 12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

: 108-38-3
m-xylene

: [pentamethylcyclopentadienyl*iridium(η6-m-xylene)][BF4]2

Conditions

Conditions	Yield
Stage #1: silver tetrafluoroborate; bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] In acetone at 24℃; for 0.25h; Stage #2: m-xylene With trifluoroacetic acid at 24℃;	99%

...Expand

: P,P-diphenyl-N-(8-aminoquinoline)phosphonamide

: 108-38-3
m-xylene

: P-[2-(3-methylbenzyl)phenyl]-P-phenyl-N-(8-aminoquinoline)phosphonamide

Conditions

Conditions	Yield
With dihydrogen peroxide at 100℃; for 24h; Schlenk technique; Inert atmosphere; Green chemistry;	99%

: 108-38-3
m-xylene

: 654-42-2
1,4-dihydroxy-2,6-dimethylbenzene

Conditions

Conditions	Yield
With 2-Ethylhexanoic acid; [Fe(CF3SO3)2((S,S)-N,N’-bis(2-pyridylmethyl)-2,2’-bipyrrolidine)]; dihydrogen peroxide In acetonitrile at 0℃; for 2.5h;	99%

: 108-38-3
m-xylene

A: 56-23-5
tetrachloromethane

B: 118-74-1
hexachlorobenzene

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); chlorine; aluminum oxide; molybdenum(VI) oxide at 380 - 400℃; for 0.00277778h;	A 95.15% B 98.06%

: 108-38-3
m-xylene

: 98-59-9
p-toluenesulfonyl chloride

: 13249-97-3
2,4-dimethyl-1-[(4-methylphenyl)sulfonyl]benzene

Conditions

Conditions	Yield
With tin(II) trifluoromethanesulfonate at 120℃; for 8h; Friedel-Crafts sulfonylation;	98%
With [BTBA]Cl-FeCl3 at 60℃; for 0.0166667h; Friedel-Crafts sulfonylation;	97%
With peroxodisulfate ion; zirconium(IV) oxide at 150℃; for 0.5h; Friedel-Crafts reaction;	89%

: 108-38-3
m-xylene

: 583-70-0
1-bromo-2,4-dimethylbenzene

Conditions

Conditions	Yield
With sulfuric acid; dihydrogen peroxide; sodium bromide In water at 49.84℃;	98%
With N-Bromosuccinimide In acetonitrile at 0 - 20℃; Inert atmosphere;	98%
With N-Bromosuccinimide In 1,2-dichloro-ethane at 60℃; for 10h; Sealed tube;	97%

: 108-38-3
m-xylene

: 65-85-0
benzoic acid

: 1140-14-3
2,4-Dimethyl benzophenone

Conditions

Conditions	Yield
With trifluoroacetic anhydride; bismuth(lll) trifluoromethanesulfonate at 30℃; for 12h; Friedel-Crafts acetylation;	98%
With pyridin-2-yl trifluoromethanesulfonate; trifluoroacetic acid for 5h; Heating;	95%
With trifluoromethylsulfonic anhydride In nitromethane at 20℃; for 0.0833333h; Friedel-Crafts acylation;	90%

: 108-38-3
m-xylene

: 13369-81-8
2-iodo-4-nitro-1(3)H-imidazole

: 4(5)-Nitro-2-(2,4-dimethylphenyl)imidazole

Conditions

Conditions	Yield
In acetonitrile for 4h; Irradiation;	98%

: 108-38-3
m-xylene

: 73183-34-3
bis(pinacol)diborane

: 325142-93-6
2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions

Conditions	Yield
Stage #1: bis(pinacol)diborane With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine In tert-butyl methyl ether Inert atmosphere; Stage #2: m-xylene In tert-butyl methyl ether at 80℃; for 6h; Inert atmosphere;	98%
With 6Zr(4+)4O(2-)4HO(1-)4C18H12O4(2-)2C16H10N2O4(2-)C8H12Ir(1+)*CH3O(1-) In tetrahydrofuran; n-heptane at 115℃; for 16h; Catalytic behavior; Reagent/catalyst; Temperature; Glovebox; Schlenk technique; Inert atmosphere;	97%
With Ir(1+)C8H12CH3O(1-)6C12H6N2O4(2-)4Zr(4+)4HO(1-)4O(2-) In neat (no solvent) at 100℃; for 7h; Time; Reagent/catalyst; Glovebox; Inert atmosphere; Sealed tube;	94%

: 108-38-3
m-xylene

A: 626-17-5
benzene-1,3-dicarbonitrile

B: 3441-01-8
3-cyanobenzamide

C: 620-22-4
3-Methylbenzonitrile

Conditions

Conditions	Yield
With ammonia; oxygen; B0.5CrK0.02Mo0086Na0009P0.007V at 350 - 420℃; under 1500.15 Torr; Gas phase; Heating / reflux;	A 98% B n/a C n/a

...Expand

: 64881-40-9
(3S)-3-methoxycarbonyl-3-trifluoroacetylaminopropanoyl chloride

: 108-38-3
m-xylene

: 1088806-53-4
methyl 4-(2,4-dimethylphenyl)-4-oxo-2-(2,2,2-trifluoroacetamido)butanoate

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid at 0℃; for 1h; Friedel Crafts acylation; Neat (no solvent);	98%

: 108-38-3
m-xylene

: 161553-08-8
(R)-N-trifluoroacetylaspartic acid-4-chloride-1-methyl ester

: 1088806-55-6
methyl 4-(2,4-dimethylphenyl)-4-oxo-2-(2,2,2-trifluoroacetamido)butanoate

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid at 0℃; for 1h; Friedel Crafts acylation; Neat (no solvent);	98%

: 91574-67-3, 91574-68-4, 20766-37-4
2-chlorobenzalacetone

: 108-38-3
m-xylene

: C18H17ClO

Conditions

Conditions	Yield
With di-tert-butyl peroxide; [copper(II)(trifluoroacetylacetonate)2]; salicylic acid at 120℃; for 24h; Inert atmosphere; regioselective reaction;	98%

: 108-38-3
m-xylene

: 264882-00-0
methyl 2-(2-chlorophenyl)-2-diazoacetate

: methyl 2-(2-chlorophenyl)-2-(2,4-dimethylphenyl)acetate

Conditions

Conditions	Yield
With (triphenylphosphine)gold(I) chloride; silver trifluoromethanesulfonate at 20℃; for 0.0666667h; Schlenk technique;	98%
With MCM-41-PPh2-AuOTf at 20℃; for 0.1h; Schlenk technique; Inert atmosphere; regioselective reaction;	87%

: 507-20-0
tertiary butyl chloride

: 108-38-3
m-xylene

: 98-19-1
5-tert-Butyl-m-xylene

Conditions

Conditions	Yield
With 4-Chloropyridine; nickel(II) oxide; aluminum (III) chloride; barium titanate; 4-trifluoromethylpyridine; copper(II) sulfate In ethanol at 25℃; for 0.0666667h; Temperature;	97.7%
With aluminum (III) chloride In dichloromethane at 20℃; for 1.5h;	70%
montmorillonite doped with TiCl4 for 0.333333h; Heating;	60%

: 85-44-9
phthalic anhydride

: 108-38-3
m-xylene

: 2346-63-6
2-(2,4-dimethylbenzoyl)benzoic acid

Conditions

Conditions	Yield
Stage #1: phthalic anhydride; m-xylene With aluminum (III) chloride at 55℃; for 5h; cooling with salt-ice; Stage #2: With hydrogenchloride In water; m-xylene cooling with ice;	97%
With aluminum (III) chloride at 60℃; for 0.416667h; Catalytic behavior; Reagent/catalyst; Time; Concentration; Friedel-Crafts Acylation; Ionic liquid; Irradiation;	85%
With aluminium trichloride