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Chemsigma International Co.,Ltd.

Bulk supply Application:intermediate

Bulk supply 556-96-7

Cas:556-96-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

5-Bromo-m-xylene Manufacturer/High quality/Best price/In stock

Cas:556-96-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 5-Bromo-M-Xylene with high purity

Cas:556-96-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name 5-Bromo-m-xylene CAS No.

1-Bromo-3,5-dimethylbenzene

Cas:556-96-7

Min.Order:1 Gram

FOB Price: $8.0

Type:Lab/Research institutions

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Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

We can provide GMP validation service that complies with SFDA, FDA, WHO and EU EMPA.Excellent registration team could help us easlily to register our products in different countries.If you and your customer are interested in some products or need C

5-Bromo-m-xylene manufacturer with low price

Cas:556-96-7

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

5-Bromo-m-xylene

Cas:556-96-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi

manufacturer of 3,5-Dimethyl-1-bromobenzene

Cas:556-96-7

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 556-96-7 5-Bromo-m-xylene Manufacturer

Cas:556-96-7

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

5-Bromo-m-xylene

Cas:556-96-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

3,5-Dimethylbromobenzene

Cas:556-96-7

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Benzene,1-bromo-3,5-dimethyl- Henan Tianfu Chemical Co.,LTD was built in 2009 with an ISO certificate in the past 5 years, we have grown up as a famous fine chemicals supplier in china and we had established stable business relationships with sam

CAS no.556-96-7

Cas:556-96-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

5-Bromo-m-xylene CAS NO 556-96-7

Cas:556-96-7

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 556-96-7 with fast shipping

Cas:556-96-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:pale yellow to clear transparent liquid Storage:Store in sea

556-96-7 Pharmaceutical Raw Materials Benzene,1-bromo-3,5-dimethyl-

Cas:556-96-7

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-bromo-3,5-dimethyl- 556-96-7

Cas:556-96-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 5-Bromo-m-xylene CAS: 556-96-7 MF: C8H9Br MW: 185.06 EINECS: 629-686-5 Mol File: 556-96-7.mol 5-Bromo-m-xylene Structure 5-Bromo-m-xylene Chemical Properties Melting point -20.49°C (estimate) Boiling point

3,5-Dimethylbromobenzene

Cas:556-96-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

5-Bromo-m-xylene

Cas:556-96-7

Min.Order:1 Kilogram

FOB Price: $89.0 / 100.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

5-Bromo-m-xylene CAS:556-96-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

5-Bromo-m-xylene CAS:556-96-7

Cas:556-96-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-bromo-3,5-dimethyl-

Cas:556-96-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

cas 556-96-7 5-Bromo-m-xylene

Cas:556-96-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,1-bromo-3,5-dimethyl-

Cas:556-96-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

5-Bromo-M-Xylene

Cas:556-96-7

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis: Trading(Raw Mater

5-Bromo-m-xylene

Cas:556-96-7

Min.Order:0 Metric Ton

FOB Price: $18.0 / 20.0

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

5-BROMO-M-XYLENE

Cas:556-96-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

5-Bromo-m-xylene

Cas:556-96-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

5-Bromo-m-xylene

Cas:556-96-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 5-Bromo-m-xylene

Cas:556-96-7

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als

5-Bromo-m-xylene

Cas:556-96-7

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 5-Bromo-M-Xylene

Cas:556-96-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 1-Bromo-3,5-Dimethylbenzene CAS No.: 556-96-7 Molecule Formula:C8H9Br Molecule Weight:185.06 Purity: 99.0% Package: 25kg/drum Description:Light yellow transparent liquid Manufacture Standards:Enterprise Standard

Lower Price 1-Bromo-3,5-Dimethylbenzene

Cas:556-96-7

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Synthetic route

3,5-dimethylaminoaniline
108-69-0

3,5-dimethylaminoaniline

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
With trimethylsilyl bromide; N-benzyl-N,N,N-triethylammonium chloride; sodium nitrite In tetrachloromethane 1.) 0 deg C, 1.5 h, 2.) r.t., 12 h;89%
With hydrogen bromide Diazotization.Behandlung der Diazoniumsalz-Loesung mit CuBr oder mit Kupfer-Pulver;
(i) (diazotization), aq. HBr, (ii) Cu; Multistep reaction;
m-xylene
108-38-3

m-xylene

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
With copper(ll) bromide; aluminum oxide In tetrachloromethane at 80℃; for 2h;85%
With copper(ll) bromide; aluminum oxide In tetrachloromethane at 80℃; for 2h; Product distribution;85%
3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
With 1,10-Phenanthroline; oxygen; potassium bromide; copper(ll) bromide In N,N-dimethyl-formamide at 130℃; for 20h;71%
4-bromo-2,6-dimethylphenylamine
24596-19-8

4-bromo-2,6-dimethylphenylamine

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
Stage #1: 4-bromo-2,6-dimethylphenylamine With sulfuric acid In ethanol at -10 - 20℃; for 1h;
Stage #2: With sodium nitrite In ethanol; water for 1.5h;
Stage #3: With copper In ethanol; water at 20℃;
51%
Stage #1: 4-bromo-2,6-dimethylphenylamine With sulfuric acid In ethanol at 7 - 20℃; for 1h;
Stage #2: With sodium nitrite In ethanol; water at 20℃; for 1.5h; Cooling;
Stage #3: With copper In ethanol; water at 20℃; Inert atmosphere;
51%
Stage #1: 4-bromo-2,6-dimethylphenylamine With sulfuric acid In ethanol at -10 - 20℃;
Stage #2: With sodium nitrite In ethanol; water for 1.5h; Cooling with ice;
Stage #3: With copper In ethanol; water at 20℃;
63.5 g
<(3,5-Dimethylphenyl)azo>pyrrolidine

<(3,5-Dimethylphenyl)azo>pyrrolidine

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
With hydrogen bromide; copper(I) bromide37%
2-bromo-4,6-dimethylaniline
41825-73-4

2-bromo-4,6-dimethylaniline

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
With hydrogenchloride Diazotization.Behandlung der Diazoniumsalz-Loesung mit wss.-alkal. Stannit-Loesung;
2,4-Xylidine
95-68-1

2,4-Xylidine

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
With hydrogenchloride; hydrogen bromide; bromine Behandeln des Reaktionsgemisches mit Natriumnitrit und anschliessend Behandeln mit Zinn(II)-chlorid und wss. Natronlauge;
Multi-step reaction with 2 steps
1: hydrochloric acid; bromine / ueber mehrere Stufen
View Scheme
1-bromo-2,4-dimethylbenzene
583-70-0

1-bromo-2,4-dimethylbenzene

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
With hydrogen fluoride; antimony pentafluoride
2-Bromo-m-xylene
576-22-7

2-Bromo-m-xylene

A

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

B

1-bromo-2,4-dimethylbenzene
583-70-0

1-bromo-2,4-dimethylbenzene

Conditions
ConditionsYield
TfOH2+B(OTf)4- In toluene for 18h; Product distribution; Ambient temperature;A 3.5 % Chromat.
B 69.1 % Chromat.
2-Bromo-m-xylene
576-22-7

2-Bromo-m-xylene

A

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

B

1-bromo-2,4-dimethylbenzene
583-70-0

1-bromo-2,4-dimethylbenzene

C

m-xylene
108-38-3

m-xylene

Conditions
ConditionsYield
With hydrogen; oxygen at 40℃; under 760 Torr; Product distribution; Mechanism; Irradiation; effect of further reagents;
1-bromo-2,4-dimethylbenzene
583-70-0

1-bromo-2,4-dimethylbenzene

A

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

B

2-Bromo-m-xylene
576-22-7

2-Bromo-m-xylene

C

m-xylene
108-38-3

m-xylene

Conditions
ConditionsYield
With hydrogen; oxygen at 40℃; under 760 Torr; Product distribution; Mechanism; Irradiation; effect of further reagent;
diazotized 5-bromo-4-amino-m-xylene

diazotized 5-bromo-4-amino-m-xylene

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
With sodium hydroxide; tin(ll) chloride
durch Verkochen;
3,6-bis(trifluoromethyl)bromobenzene
328-70-1

3,6-bis(trifluoromethyl)bromobenzene

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
With trityl tetrakis(pentafluorophenyl)borate In 1,2-dichloro-benzene at 22℃; for 24h; Product distribution; Further Variations:; Reagents; Solvents;
With triethylsilane; fluorotris(pentafluorophenyl)phosphonium tetrakis(pentafluorophenyl)borate at 20℃; for 24h;
3,5-dimethylphenyl iodide
22445-41-6

3,5-dimethylphenyl iodide

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
With trans-N,N'-dimethyl-1,2-cyclohexyldiamine; copper(l) iodide; sodium bromide In N,N-dimethyl-formamide at 110℃; for 5h; Product distribution; Further Variations:; Reagents; reaction time; aromatic Finkelstein reaction;
With tetrabutylammomium bromide; trans-N,N'-dimethylcyclohexane-1,2-diamine; copper(l) iodide In DMF (N,N-dimethyl-formamide) at 110℃;
With trans-N,N'-dimethylcyclohexane-1,2-diamine; sodium bromide; copper(l) iodide In DMF (N,N-dimethyl-formamide) at 110℃;
2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
325142-93-6

2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
With copper(ll) bromide In methanol at 80℃;226 mg
2,6-dimethylaniline
87-62-7

2,6-dimethylaniline

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: bromine / methanol / 20 °C
2.1: sulfuric acid / ethanol / 1 h / -10 - 20 °C
2.2: 1.5 h
2.3: 20 °C
View Scheme
Multi-step reaction with 2 steps
1.1: bromine / methanol / 20 °C
2.1: sulfuric acid / ethanol / -10 - 20 °C
2.2: 1.5 h / Cooling with ice
2.3: 20 °C
View Scheme
Multi-step reaction with 2 steps
1.1: bromine / methanol / 20 °C
2.1: sulfuric acid / ethanol / 1 h / 7 - 20 °C
2.2: 1.5 h / 20 °C / Cooling
2.3: 20 °C / Inert atmosphere
View Scheme
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

phenylboronic acid
98-80-6

phenylboronic acid

3,5-dimethylbiphenyl
17057-88-4

3,5-dimethylbiphenyl

Conditions
ConditionsYield
With potassium phosphate; 3-(2,6-diisopropylphenyl)-1-(2-diphenylphosphanylbenzyl)-3H-imidazol-1-ium chloride; bis(η3-allyl-μ-chloropalladium(II)) In 1,4-dioxane at 80℃; for 12h; Suzuki cross-coupling;100%
With potassium tert-butylate; N,N-dimethylthiocarbamate-phosphine ligand; bis(dibenzylideneacetone)-palladium(0) In dimethyl sulfoxide at 80℃; for 4h; Suzuki cross-coupling reaction;99%
With potassium carbonate In toluene at 110℃; for 2h; Suzuki reaction;99%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

tributylphenylstannane
960-16-7

tributylphenylstannane

3,5-dimethylbiphenyl
17057-88-4

3,5-dimethylbiphenyl

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; tetrabutyl ammonium fluoride; palladium diacetate In 1,4-dioxane at 100℃; for 20h; Stille reaction;100%
With 1,4-diaza-bicyclo[2.2.2]octane; potassium hydroxide; poly(ethylene glycol)-400; palladium diacetate In water at 80℃; for 10h; Stille coupling;93%
With potassium fluoride; 1,4-dicyclohexyl-diazabutadiene; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 100℃; for 24h; Stille cross-coupling reaction;82%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

1-bromo-3-(bromomethyl)-5-methylbenzene
51719-69-8

1-bromo-3-(bromomethyl)-5-methylbenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 2h; Heating / reflux;100%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; dibenzoyl peroxide In tetrachloromethane for 7h; Product distribution / selectivity; Reflux;99%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; dibenzoyl peroxide In tetrachloromethane for 7h; Product distribution / selectivity; Reflux;99%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

3,5-dimethylaminoaniline
108-69-0

3,5-dimethylaminoaniline

Conditions
ConditionsYield
With copper(I) oxide; ammonium hydroxide In 1-methyl-pyrrolidin-2-one at 80℃; for 15h;100%
With copper(l) iodide; 2-carboxyquinoline N-oxide; potassium carbonate; ammonium hydroxide In dimethyl sulfoxide at 80℃; for 23h; Inert atmosphere;91%
With copper(l) iodide; ammonia; sodium phosphate In water at 100℃; for 24h;86%
With diethylenetriaminopentaacetic acid; ammonia; copper(II) oxide; potassium hydroxide In water at 100℃; for 6h;74%
Stage #1: 5-bromo-1,3-xylene With magnesium In tetrahydrofuran Inert atmosphere;
Stage #2: With C10H17NO In tetrahydrofuran; toluene at -78℃; for 2h; Inert atmosphere;
Stage #3: With ammonium chloride In tetrahydrofuran; water; toluene Inert atmosphere;
74%
triisopropyl phosphite
116-17-6

triisopropyl phosphite

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

C14H23O3P
1393678-00-6

C14H23O3P

Conditions
ConditionsYield
With nickel dibromide at 150℃; for 3h; Inert atmosphere;100%
fur-2-ylboronic acid
13331-23-2

fur-2-ylboronic acid

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

2-(3,5-dimethylphenyl)furan

2-(3,5-dimethylphenyl)furan

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In methanol; toluene at 100℃; for 16h; Inert atmosphere;100%
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In methanol; toluene at 100℃; for 3h;
diethylphosphoramidous dichloride
1069-08-5

diethylphosphoramidous dichloride

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

bis-(3,5-dimethylphenyl)chlorophosphine
74289-57-9

bis-(3,5-dimethylphenyl)chlorophosphine

Conditions
ConditionsYield
Stage #1: 5-bromo-1,3-xylene With n-butyllithium In diethyl ether; hexane at 0℃; for 4h; Inert atmosphere; Sealed tube;
Stage #2: diethylphosphoramidous dichloride In diethyl ether; hexane at 0℃; for 0.166667h; Inert atmosphere; Sealed tube;
Stage #3: With hydrogenchloride In 1,4-dioxane; diethyl ether; hexane Inert atmosphere; Sealed tube;
100%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

3,3',5,5'-tetramethyl-1,1'-biphenyl
25570-02-9

3,3',5,5'-tetramethyl-1,1'-biphenyl

Conditions
ConditionsYield
With (1E,2E)-N1,N2-bis(2,6-dimethylphenyl)ethane-1,2-diimine; nickel dibromide; zinc In tetrahydrofuran at 70℃; for 10h; Inert atmosphere;99%
With indium; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 100℃; for 48h;88.6%
Stage #1: 5-bromo-1,3-xylene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h;
Stage #2: With copper dichloride In tetrahydrofuran; hexane at -78 - 20℃; for 1h;
65%
With thallium(I) bromide; magnesium 1.) THF, reflux, 2.) THF, benzene, reflux, 4 h;
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

1-Naphthylboronic acid
13922-41-3

1-Naphthylboronic acid

1-(3,5-dimethylphenyl)naphthalene
164172-87-6

1-(3,5-dimethylphenyl)naphthalene

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); dicyclohexyl(1-(naphtho[2,3-b]furan-9-yl)naphthalen-2-yl)phosphine In toluene at 80℃; for 0.5h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;99%
With palladium diacetate; 5A molecular sieve; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 100℃; for 4h;73%
1H-imidazole
288-32-4

1H-imidazole

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

1-(3,5-dimethylphenyl)-1H-imidazole
223762-69-4

1-(3,5-dimethylphenyl)-1H-imidazole

Conditions
ConditionsYield
With copper(I) trifluoromethanesulfonate benzene; caesium carbonate; 1,10-Phenanthroline; (dibenzylidene)acetone In xylene at 125℃; for 36h; Substitution;99%
With caesium carbonate In dimethyl sulfoxide at 120℃; Inert atmosphere;95%
With copper(I) oxide; 1,10-Phenanthroline; tetrabutyl ammonium fluoride at 140 - 145℃; for 24h;86%
With copper(l) iodide; 8-quinolinol; caesium carbonate In water; N,N-dimethyl-formamide at 130℃; for 16h;
With potassium phosphate; copper(l) iodide; tetrabutylammomium bromide; 1,10-phenanthroline-4,7-diol In water at 100℃; for 24h; Ullmann Condensation; Schlenk technique; Inert atmosphere; Green chemistry;73 %Chromat.
morpholine
110-91-8

morpholine

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

N (dimethyl-3,5-phenyl-1) morpholine
16800-77-4

N (dimethyl-3,5-phenyl-1) morpholine

Conditions
ConditionsYield
With [Pd(N,N'-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)-imidazol-2-ylidene)(acetylacetonate)Cl]; lithium hexamethyldisilazane In 1,4-dioxane at 110℃; for 3h; Buchwald-Hartwig Coupling; Inert atmosphere; Sealed tube;99%
With bis(tri-t-butylphosphine)palladium(0); potassium tert-butylate In toluene at 20℃; for 4h;99%
With potassium tert-butylate; johnphos; tris(dibenzylideneacetone)dipalladium (0) In tetrahydrofuran at 20℃; for 20h; Arylation;80%
With copper(l) iodide; potassium carbonate; L-proline In dimethyl sulfoxide at 90℃; for 24h;56%
Benzophenone imine
1013-88-3

Benzophenone imine

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

N-(3,5-dimethylphenyl)-1,1-diphenylmethanimine
384344-10-9

N-(3,5-dimethylphenyl)-1,1-diphenylmethanimine

Conditions
ConditionsYield
With potassium tert-butylate; bis(dibenzylideneacetone)-palladium(0); 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In 1,4-dioxane at 100℃; for 10h;99%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

thiophenol
108-98-5

thiophenol

3,5-dimethylphenyl phenyl sulfide

3,5-dimethylphenyl phenyl sulfide

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine In toluene for 3h; Inert atmosphere; Reflux;99%
With (IPr)Ni(π-allyl)Cl; sodium t-butanolate In N,N-dimethyl-formamide at 100℃; for 24h; Inert atmosphere;95%
Stage #1: 5-bromo-1,3-xylene; thiophenol With sodium iodide; N,N`-dimethylethylenediamine; copper(l) iodide In toluene at 110℃; for 24h;
Stage #2: With potassium carbonate; ethylene glycol In isopropyl alcohol at 80℃; for 18 - 20h;
93%
With copper(l) iodide; 2,2',2''-triaminotriethylamine; caesium carbonate In 1,4-dioxane at 110℃; for 23h;82%
With copper(l) iodide; caesium carbonate In 1-methyl-pyrrolidin-2-one at 195℃; for 6h; microwave irradiation;73%
Octanethiol
111-88-6

Octanethiol

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

3,5-dimethylphenyl octyl sulfide
1264694-60-1

3,5-dimethylphenyl octyl sulfide

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine In toluene for 3h; Inert atmosphere; Reflux;99%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

benzene
71-43-2

benzene

3,5-dimethylbiphenyl
17057-88-4

3,5-dimethylbiphenyl

Conditions
ConditionsYield
With C34H52Cl2N2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 120℃; for 16h;99%
With dichloro bis(acetonitrile) palladium(II); potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 120℃; for 18h; Mechanism; Reagent/catalyst;96%
With 2-Hydroxymethylpyridine; potassium tert-butylate at 20 - 80℃; for 24h; Schlenk technique; Inert atmosphere;69%
styrene
292638-84-7

styrene

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

(E/Z)-3,5-Dimethylstilbene
172878-95-4

(E/Z)-3,5-Dimethylstilbene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 9h; Heck reaction;99%
With 1-methyl-pyrrolidin-2-one; potassium phosphate; [Pd(OAc)(1,3,5-triphenyl pyrazole(-H))]2; tetrabutylammomium bromide at 160℃; for 30h; Heck Reaction; Inert atmosphere;93%
With C19H13N3O2Pd; potassium carbonate In methanol for 2h; Reagent/catalyst; Heck Reaction; Reflux;81%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4′-methoxy-3,5-dimethyl-1,1′-biphenyl

4′-methoxy-3,5-dimethyl-1,1′-biphenyl

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In ethanol; water; toluene for 14h; Suzuki-Miyaura Coupling; Inert atmosphere; Reflux;99%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

ethylene glycol
107-21-1

ethylene glycol

2-(3,5-dimethylphenoxy)ethanol
5960-05-4

2-(3,5-dimethylphenoxy)ethanol

Conditions
ConditionsYield
With potassium carbonate; copper dichloride at 130℃; for 20h; Inert atmosphere; Schlenk technique;99%
5-methylbenzofuran
18441-43-5

5-methylbenzofuran

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

5-methyl-2-(3,5-dimethylphenyl)benzoxazole
920133-32-0

5-methyl-2-(3,5-dimethylphenyl)benzoxazole

Conditions
ConditionsYield
With C13H18Cl2N4OPd; lithium tert-butoxide In N,N-dimethyl-formamide at 130℃; for 24h; Catalytic behavior; Inert atmosphere; Schlenk technique;99%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

zinc(II) chloride
7646-85-7

zinc(II) chloride

(3,5-dimethylphenyl)zinc chloride

(3,5-dimethylphenyl)zinc chloride

Conditions
ConditionsYield
Stage #1: 5-bromo-1,3-xylene With magnesium; lithium chloride In tetrahydrofuran at 25℃; Schlenk technique; Inert atmosphere;
Stage #2: zinc(II) chloride In tetrahydrofuran at 0 - 25℃; for 0.25h; Schlenk technique; Inert atmosphere;
99%
Stage #1: 5-bromo-1,3-xylene With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: zinc(II) chloride In tetrahydrofuran at 20℃; for 1.5h;
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

3,5-dimethyl-1-(trimethylsilylethynyl)benzene
276856-72-5

3,5-dimethyl-1-(trimethylsilylethynyl)benzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 100℃; for 24h;98.5%
With CuI; diisopropylamine; triphenylphosphine; Pd(PPh3)2Cl2
NH-pyrazole
288-13-1

NH-pyrazole

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

1-(3,5-dimethylphenyl)-1H-pyrazole

1-(3,5-dimethylphenyl)-1H-pyrazole

Conditions
ConditionsYield
With caesium carbonate In dimethyl sulfoxide at 120℃; Inert atmosphere;98.2%
With sodium t-butanolate; tert-butyl XPhos; tris-(dibenzylideneacetone)dipalladium(0) In toluene at 80℃; for 22h;88%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

cyclohexylamine
108-91-8

cyclohexylamine

N-(3,5-dimethylphenyl)cyclohexylamine
13342-30-8

N-(3,5-dimethylphenyl)cyclohexylamine

Conditions
ConditionsYield
With C60H86O4P2Pd2(2+)*2BF4(1-); sodium t-butanolate In 1,4-dioxane at 100℃; for 3h;98%
With tris-(dibenzylideneacetone)dipalladium(0); potassium tert-butylate; (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine) In toluene at 80℃; for 18h; Arylation;85%
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃; for 18h;83%
acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

(E)-n-butyl 3-(3,5-dimethylphenyl)acrylate

(E)-n-butyl 3-(3,5-dimethylphenyl)acrylate

Conditions
ConditionsYield
With potassium carbonate; bis(dibenzylideneacetone)-palladium(0); 3-(2,6-diisopropylphenyl)-1-(2-diphenylphosphanylbenzyl)-3H-imidazol-1-ium chloride In N,N-dimethyl acetamide at 140℃; for 12h; Heck reaction;98%
With trans-1,2-cyclohexanediamine-based Pd; cetyltrimethylammonim bromide; potassium carbonate In N,N-dimethyl acetamide at 160℃; for 5h; Heck cross-coupling reaction;88%
With cetyltrimethylammonim bromide; sodium carbonate; binaphthyl-based palladium In N,N-dimethyl acetamide at 160℃; for 18h; Heck cross-coupling;86%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

sodium cyanide
143-33-9

sodium cyanide

3,5-dimethylbenzonitrile
22445-42-7

3,5-dimethylbenzonitrile

Conditions
ConditionsYield
With N,N`-dimethylethylenediamine In toluene at 90℃; for 24h; Rosenmund-von Braun reaction;98%
Stage #1: 5-bromo-1,3-xylene; sodium cyanide With potassium iodide; N,N`-dimethylethylenediamine; copper(l) iodide In toluene at 110℃; for 24h;
Stage #2: With ammonia In dodecane; water; ethyl acetate; toluene at 25℃; for 0.166667h;
86 - 90 %Chromat.
Stage #1: 5-bromo-1,3-xylene; sodium cyanide With potassium iodide; N,N`-dimethylethylenediamine; copper(l) iodide In toluene; benzyl alcohol at 110℃; for 12h;
Stage #2: With ammonia In dodecane; water; ethyl acetate; toluene; benzyl alcohol at 25℃; for 0.166667h;
88 %Chromat.
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

o-(phenylethynyl)trifluoroacetanilide
143360-89-8

o-(phenylethynyl)trifluoroacetanilide

3-(3,5-dimethyl-phenyl)-2-phenyl-1H-indole

3-(3,5-dimethyl-phenyl)-2-phenyl-1H-indole

Conditions
ConditionsYield
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In acetonitrile at 100℃; for 0.5h;98%
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In acetonitrile at 100℃; for 3h;98%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

phenyl trimethylsiloxane
2996-92-1

phenyl trimethylsiloxane

3,5-dimethylbiphenyl
17057-88-4

3,5-dimethylbiphenyl

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride; tris-(o-tolyl)phosphine; dichloro bis(acetonitrile) palladium(II) at 80℃; for 0.583333h; Hiyama cross-coupling reaction;98%
With 1,4-diaza-bicyclo[2.2.2]octane; tetrabutyl ammonium fluoride; palladium diacetate In 1,4-dioxane at 80℃; for 4h; Hiyama cross-coupling reaction;60%
indole
120-72-9

indole

CuOAc

CuOAc

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

(R)-1-phenyl-ethyl-amine
3886-69-9

(R)-1-phenyl-ethyl-amine

N,N-diethylsalicylamide
19311-91-2

N,N-diethylsalicylamide

(R)-α-methyl-N-(3,5-dimethylphenyl)benzylamine

(R)-α-methyl-N-(3,5-dimethylphenyl)benzylamine

Conditions
ConditionsYield
With ammonium hydroxide; potassium phosphate In dodecane; hexane; water; ethyl acetate; N,N-dimethyl-formamide98%
carbon monoxide
201230-82-2

carbon monoxide

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

benzylamine
100-46-9

benzylamine

N-benzyl-3,5-dimethylbenzamide

N-benzyl-3,5-dimethylbenzamide

Conditions
ConditionsYield
With palladium diacetate; sodium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 80℃; under 760.051 Torr; for 15h;98%
2-thienyl chloride
96-43-5

2-thienyl chloride

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

2-chloro-5-(3,5-dimethylphenyl)thiophene
1353658-84-0

2-chloro-5-(3,5-dimethylphenyl)thiophene

Conditions
ConditionsYield
With 2'-(PdPCy3Cl)-2-Aminobiphenyl; potassium carbonate; Trimethylacetic acid at 100℃; Inert atmosphere;98%

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