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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Large Stock 99.0% (2-Aminophenyl)boronic acid 5570-18-3 Producer

Cas:5570-18-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/764.html Product Name 2-Aminophenylboronic acid CAS No. 55

2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:1 Gram

FOB Price: $63.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

5570-18-3 2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

2-Aminophenylboronic acid CAS 5570-18-3

Cas:5570-18-3

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 5570-18-3 with competitive price

Cas:5570-18-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:powder Storage:Store in sealed containers at cool & dry pla

2-Aminophenylboronic acid hydrochloride(CAS:5570-18-3)

Cas:5570-18-3

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Aminophenylboronic acid 5570-18-3

Cas:5570-18-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-Aminophenylboronic acid CAS:5570-18-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

2-Aminophenylboronic acid CAS:5570-18-3

Cas:5570-18-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

2-Amino phenyl boronic acid 5570-18-3

Cas:5570-18-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply (2-Aminophenyl)boronic acid, hydrochloride

Cas:5570-18-3

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:Crystalline powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates Transportation

2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

2-Aminophenylboronic acid Chemical Properties Melting point 188-190°C Boiling point 346.9±44.0 °C(Predicted) density 1.23±0.1 g/cm3(Predicted) pka 8.83±0.53(Predicted) BRN 2962939 CAS DataBase Reference

2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-AMINOBENZENEBORONIC ACID

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2-aminophenylboronic Acid

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

(2-Aminophenyl)boronic acid

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-aminophenylboronic acid hydrochloride cas no. 5570-18-3 98%

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Greenutra Resource Inc

(2-Aminophenyl)boronic acidAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air

(2-Aminophenyl)boronic acid

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

(2-Aminophenyl)boronic acid

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Other

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

2-Aminophenylboronic acid- CAS 5570-18-3

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

2-Aminophenylboronic acid

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

manufacture Application:The refence standard products, for lab use, also we could produce bigger quantity on yr requirement.

2-aminophenylboronic acid

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 2-Aminobenzeneboronic acid 5g

Cas:5570-18-3

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

(2-Aminophenyl)boronic acid

Cas:5570-18-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

2-nitrophenylboronic acid
5570-19-4

2-nitrophenylboronic acid

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride; iron In ethanol; water at 50℃; for 3h; Inert atmosphere;83%
With H2; catalyst: Pd/C In ethanol shaken for 15 h; filtd., the filtrate is evapd., the oily residue is recrystd. (methanol-water);67%
With hydrogen; palladium 10% on activated carbon In ethanol under 750.075 Torr; for 8h;50%
2-iodophenylamine
615-43-0

2-iodophenylamine

water
7732-18-5

water

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

Conditions
ConditionsYield
Stage #1: 2-iodophenylamine; bis(pinacol)diborane With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In dimethyl sulfoxide at 80℃; for 18h; Inert atmosphere;
Stage #2: water With sodium periodate; ammonium chloride In methanol at 20℃; for 18h;
78.1%
2-anilineboronic acid pinacol ester
191171-55-8

2-anilineboronic acid pinacol ester

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

Conditions
ConditionsYield
With boron trichloride In dichloromethane at 25℃; for 3h;52%
nitric acid
7697-37-2

nitric acid

phenylboronic acid
98-80-6

phenylboronic acid

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

Conditions
ConditionsYield
With palladium on activated charcoal; hydrogen; urea In acetic anhydride 1) HNO3, Ac2O, urea; 2) H2, Pd(C), EtOH;31%
phenylboronic acid
98-80-6

phenylboronic acid

polymer; monomer(s): Actitex 1500-1, modified with [BF4][4-N2C6H4CH2Cl]; 4-halogenobenzenethiol

polymer; monomer(s): Actitex 1500-1, modified with [BF4][4-N2C6H4CH2Cl]; 4-halogenobenzenethiol

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: HNO3; Ac2O; urea
2: H2 / Pd/C / ethanol
View Scheme
phenylboronic acid
98-80-6

phenylboronic acid

Merrifield resin-CH2O(CH2)4S-CH2C6H4-Ph-4

Merrifield resin-CH2O(CH2)4S-CH2C6H4-Ph-4

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: HNO3; Ac2O; urea
2: H2 / Pd/C / ethanol
View Scheme
tris(2-methylene(phenyl)imino phenyl)boroxin
17604-35-2

tris(2-methylene(phenyl)imino phenyl)boroxin

A

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

B

1-Hydroxy-2-phenyl-2,3-dihydro-1H-2,1-benzazaborol

1-Hydroxy-2-phenyl-2,3-dihydro-1H-2,1-benzazaborol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran refluxing for 1 h, decompn. of excess of LiAlH4 by water, filtering, extracting; recrystn. from benzene-hexane;
phenylboronic acid
98-80-6

phenylboronic acid

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: acetic anhydride; nitric acid / 3 h / -15 - 10 °C
2: iron; hydrogenchloride / ethanol; water / 3 h / 50 °C / Inert atmosphere
View Scheme
phenylboronic acid
98-80-6

phenylboronic acid

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

Conditions
ConditionsYield
With nitric acid; palladium on carbon In ethanol; water
3-(6-bromo-quinolin-4-yloxy)-5,6-dimethyl-[2,2']bipyridine
863783-61-3

3-(6-bromo-quinolin-4-yloxy)-5,6-dimethyl-[2,2']bipyridine

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

2-[4-(5,6-Dimethyl-[2,2']bipyridin-3-yloxy)-quinolin-6-yl]-phenylamine

2-[4-(5,6-Dimethyl-[2,2']bipyridin-3-yloxy)-quinolin-6-yl]-phenylamine

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; N,N-dimethyl-formamide at 70℃; for 3h;100%
3-(7-bromo-quinolin-4-yloxy)-5,6-dimethyl-[2,2']bipyridine
863783-73-7

3-(7-bromo-quinolin-4-yloxy)-5,6-dimethyl-[2,2']bipyridine

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

2-[4-(5,6-Dimethyl-[2,2']bipyridinyl-3-yloxy)-quinolin-7-yl]-phenylamine

2-[4-(5,6-Dimethyl-[2,2']bipyridinyl-3-yloxy)-quinolin-7-yl]-phenylamine

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; dimethyl sulfoxide at 70℃; for 5h;100%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

1-hydroxy-3-methyl-1H-2,4,1-benzoxaborine
157524-26-0

1-hydroxy-3-methyl-1H-2,4,1-benzoxaborine

Conditions
ConditionsYield
With (CH3CO)2O In 1,4-dioxane under Ar, heated at 60°C for 17 h; the volatiles are removed by evapn. in vac.;100%
trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

1-hydroxy-3-(trifluoromethyl)-1H-2,4,1-benzoxazaborine
157524-32-8

1-hydroxy-3-(trifluoromethyl)-1H-2,4,1-benzoxazaborine

Conditions
ConditionsYield
With H2O In 1,4-dioxane stirred at 0°C for 30 min, at room temp. for 3 h, the solvent isremoved by evapn. in vac. at 30°C, the residue is treated with water; evapn. at 30°C;100%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

Acetic formic anhydride
2258-42-6

Acetic formic anhydride

1-hydroxy-1H-2,4,1-benzoxazaborine
157524-27-1

1-hydroxy-1H-2,4,1-benzoxazaborine

Conditions
ConditionsYield
In 1,4-dioxane under Ar, atirred at 11°C for 12 h; the volatiles are removed by evapn.;100%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

C14H11ClN4O2

C14H11ClN4O2

3-phenyl-3H-benzo[c]pyrazolo[4,3-f][2,7]naphthyridin-6(7H)-one

3-phenyl-3H-benzo[c]pyrazolo[4,3-f][2,7]naphthyridin-6(7H)-one

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; toluene; tert-butyl alcohol at 75℃; for 18h; Suzuki Coupling; Inert atmosphere;100%
5-nitrosalicylic acid
96-97-9

5-nitrosalicylic acid

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

C13H10BN2O6(1-)*H(1+)

C13H10BN2O6(1-)*H(1+)

Conditions
ConditionsYield
In acetonitrile at 49.84℃; for 1h;99%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

ethyl (E)-crotonate
623-70-1

ethyl (E)-crotonate

4-methyl-3,4-dihydroquinolin-2(1H)-one
30696-28-7

4-methyl-3,4-dihydroquinolin-2(1H)-one

Conditions
ConditionsYield
With [Rh(OH)(cod)]2; potassium carbonate In water at 50℃; for 5h; Inert atmosphere;99%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

2-(2-pyridyl)aniline
29528-30-1

2-(2-pyridyl)aniline

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate In 1,4-dioxane; water at 100℃; for 5h; Suzuki Coupling; Inert atmosphere;98%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

[2-[N-(deoxy-D-ribofuranosyl)amino]phenyl]boronic acid

[2-[N-(deoxy-D-ribofuranosyl)amino]phenyl]boronic acid

Conditions
ConditionsYield
In ethanol at 20℃; for 24h; Substitution;97%
1-bromo-2-(4-cyanobenzyl)benzene

1-bromo-2-(4-cyanobenzyl)benzene

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

4-((2'-amino-[1,1'-biphenyl]-2-yl)methyl)benzonitrile

4-((2'-amino-[1,1'-biphenyl]-2-yl)methyl)benzonitrile

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 12h; Inert atmosphere; Reflux;97%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

4-benzyl-2-iodo-1-methylbenzene

4-benzyl-2-iodo-1-methylbenzene

5'-benzyl-2'-methyl-[1,1'-biphenyl]-2-amine

5'-benzyl-2'-methyl-[1,1'-biphenyl]-2-amine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,2-dimethoxyethane; water for 12h; Inert atmosphere; Reflux;97%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

benzalacetophenone
94-41-7

benzalacetophenone

2,4-diphenylquinoline
1039-51-6

2,4-diphenylquinoline

Conditions
ConditionsYield
Stage #1: 2-aminophenylboronic acid; benzalacetophenone With potassium hydroxide; chloro(1,5-cyclooctadiene)rhodium(I) dimer In toluene at 20℃; for 24h; Inert atmosphere;
Stage #2: With palladium 10% on activated carbon In toluene for 4h; Reflux; regiospecific reaction;
96%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

methyl 2-bromo-5-methylbenzoate
90971-88-3

methyl 2-bromo-5-methylbenzoate

8-methylphenanthridin-6(5H)-one
107622-36-6

8-methylphenanthridin-6(5H)-one

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In 1,4-dioxane; water at 100℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere;96%
1-bromo-9-methyl-9H-carbazole

1-bromo-9-methyl-9H-carbazole

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

2-(9-methyl-9H-carbazol-1-yl)aniline

2-(9-methyl-9H-carbazol-1-yl)aniline

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; ethanol at 70℃; for 2h; Suzuki-Miyaura Coupling; Microwave irradiation; Inert atmosphere;96%
(E)-3,4-dimethoxycinnamic chloride
39856-08-1, 141236-46-6

(E)-3,4-dimethoxycinnamic chloride

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

C17H18BNO5

C17H18BNO5

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at -5 - 20℃; for 2h;95.1%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

3-chlorobenzoate
535-80-8

3-chlorobenzoate

2'-aminobiphenyl-3-carboxylic acid
177171-15-2

2'-aminobiphenyl-3-carboxylic acid

Conditions
ConditionsYield
With sodium 2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐[1,1'‐biphenyl]‐3‐sulfonate; palladium diacetate; potassium carbonate In water at 100℃; for 12h; Suzuki-Miyaura coupling;95%
6-chloropyridin-2-amine
45644-21-1

6-chloropyridin-2-amine

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

6-(2-amino-phenyl)-pyridin-2-ylamine

6-(2-amino-phenyl)-pyridin-2-ylamine

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium carbonate; palladium diacetate In water; acetonitrile at 100℃; for 10h; Suzuki-Miyaura cross-coupling;95%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

2-bromo-4-methyl-benzoic acid methyl ester
87808-49-9

2-bromo-4-methyl-benzoic acid methyl ester

9-methylphenanthridin-6(5H)-one

9-methylphenanthridin-6(5H)-one

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In 1,4-dioxane; water at 100℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere;95%
ethyl crotonate
10544-63-5

ethyl crotonate

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

4-methyl-3,4-dihydroquinolin-2(1H)-one
30696-28-7

4-methyl-3,4-dihydroquinolin-2(1H)-one

Conditions
ConditionsYield
With [Rh(OH)(cod)]2; surfactant TPGS-750-M; potassium carbonate In water at 20℃; for 24h; Green chemistry;95%
4-(trifluoromethyl)phenyl isothiocyanate
1645-65-4

4-(trifluoromethyl)phenyl isothiocyanate

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

C14H10BF3N2OS

C14H10BF3N2OS

Conditions
ConditionsYield
In N,N-dimethyl-formamide Inert atmosphere;95%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

salicylic acid
69-72-7

salicylic acid

cyanomethyl bromide
590-17-0

cyanomethyl bromide

2-bromo-N-(2-(4-oxo-4H-benzo[d][1,3,2]dioxaborinin-2-yl)phenyl)acetimidamide

2-bromo-N-(2-(4-oxo-4H-benzo[d][1,3,2]dioxaborinin-2-yl)phenyl)acetimidamide

Conditions
ConditionsYield
for 2h; Inert atmosphere; Heating;95%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

4-[Bromo-(4-diethylcarbamoyl-phenyl)-methylene]-piperidine-1-carboxylic acid tert-butyl ester
209808-18-4

4-[Bromo-(4-diethylcarbamoyl-phenyl)-methylene]-piperidine-1-carboxylic acid tert-butyl ester

4-[(2-aminophenyl)[4-[(diethylamino)carbonyl]phenyl]methylene]-1-piperidinecarboxylic acid 1,1-dimethylethyl ester
798550-18-2

4-[(2-aminophenyl)[4-[(diethylamino)carbonyl]phenyl]methylene]-1-piperidinecarboxylic acid 1,1-dimethylethyl ester

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 90℃;94%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

6(5H)-phenanthridinone
1015-89-0

6(5H)-phenanthridinone

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In 1,4-dioxane; water at 100℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere;94%
5-(2-chlorophenyl)-4-iodo-2,6-dimethoxypyrimidine

5-(2-chlorophenyl)-4-iodo-2,6-dimethoxypyrimidine

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

4-(2-aminophenyl)-5-(2-chlorophenyl)-2,6-dimethoxypyrimidine

4-(2-aminophenyl)-5-(2-chlorophenyl)-2,6-dimethoxypyrimidine

Conditions
ConditionsYield
With triphenylphosphine; cesium fluoride; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 105℃; for 18h; Suzuki Coupling; Inert atmosphere;94%
bromobenzene
108-86-1

bromobenzene

2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

2-phenylaniline
90-41-5

2-phenylaniline

Conditions
ConditionsYield
With potassium carbonate In water; isopropyl alcohol at 20℃; for 2h; Suzuki-Miyaura Coupling; Green chemistry;94%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

C12H10BrF2N3O

C12H10BrF2N3O

N-(2'-amino-[1,1'-biphenyl]-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide

N-(2'-amino-[1,1'-biphenyl]-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In 1,4-dioxane; water at 100℃; for 1.5h; Inert atmosphere;93.96%
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

(S,S)-(-)-1,2-dicyclohexyl-ethane-1,2-diol
120850-91-1

(S,S)-(-)-1,2-dicyclohexyl-ethane-1,2-diol

2-aminophenylboronic acid (-)-1,2-dicyclohexyl-1,2-ethanediol

2-aminophenylboronic acid (-)-1,2-dicyclohexyl-1,2-ethanediol

Conditions
ConditionsYield
In tetrahydrofuran stirred under N2; flash chromy. (silica, pre-absorption, Et2O/hexane); obtained as an oil;93%
In tetrahydrofuran
2-aminophenylboronic acid
5570-18-3

2-aminophenylboronic acid

(1R,2R)-1,2-dicyclohexyl-1,2-ethanediol
120850-92-2

(1R,2R)-1,2-dicyclohexyl-1,2-ethanediol

2-aminophenylboronic acid (-)-1,2-dicyclohexyl-1,2-ethanediol ester
616227-07-7

2-aminophenylboronic acid (-)-1,2-dicyclohexyl-1,2-ethanediol ester

Conditions
ConditionsYield
In tetrahydrofuran93%

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