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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Methyl 2-bromobenzoate Manufacturer/High quality/Best price/In stock

Cas:610-94-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Methyl 2-Bromobenzoate

Cas:610-94-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

Methyl 2-bromobenzoate Manufacturer

Cas:610-94-6

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl 2-Bromobenzoate

Cas:610-94-6

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Bromobenzoic acid methyl ester

Cas:610-94-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

High purity CAS 610-94-6 Methyl 2-bromobenzoate in stock Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediates (Fluo

High purity CAS 610-94-6 Methyl 2-bromobenzoate in stock

Cas:610-94-6

Min.Order:1 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 610-94-6 with competitive price

Cas:610-94-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

Methyl 2-bromobenzoate CAS610-94-6

Cas:610-94-6

Min.Order:1 Kilogram

FOB Price: $7.0 / 9.0

Type:Trading Company

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Methyl 2-bromobenzoate/ LIDE PHARMA- Factory supply / Best price

Cas:610-94-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoicacid,2-bromo-,methyl ester 610-94-6

Cas:610-94-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Methyl 2-bromobenzoate CAS:610-94-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte

Methyl 2-bromobenzoate CAS:610-94-6

Cas:610-94-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzoicacid,2-bromo-,methyl ester

Cas:610-94-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:610-94-6

Cas:610-94-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe,

Methyl 2-bromobenzoate Cas 610-94-6 2-Bromobenzoic Acid Methyl Ester

Cas:610-94-6

Min.Order:1 Kilogram

FOB Price: $70.0 / 100.0

Type:Trading Company

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methyl 2-Bromobenzoate

Cas:610-94-6

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Methyl 2-bromobenzoate

Cas:610-94-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Methyl 2-bromobenzoate Manufacturer

Cas:610-94-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl 2-bromobenzoate

Cas:610-94-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Methyl 2-Bromobenzoate

Cas:610-94-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless or light yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharm

Methyl 2-bromobenzoate

Cas:610-94-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

Methyl 2-bromobenzoate

Cas:610-94-6

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: Methyl 2-Bromobenzoate CAS No.:610-94-6 Molecule Formula:C8H7BrO2 Molecule Weight:215.04 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS

High Quality Methyl 2-Bromobenzoate in stock

Cas:610-94-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Methyl 2-bromobenzoate

Cas:610-94-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

In Bulk SupplyMethyl 2-bromobenzoate

Cas:610-94-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Methyl 2-bromobenzoate Chemical Properties Melting point 252°C Boiling point 252 °C (lit.) density 1.532 g/mL at 25 °C (lit.) refractive index n20/D 1.559(lit.) Fp >230 °F form Liquid color Clear light y

Methyl 2-bromobenzoate

Cas:610-94-6

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Methyl 2-bromobenzoate

Cas:610-94-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Wuhan BJM Pharm Inc.

Our company focuses on the future and the world, and will continue to devote itself to technological progress and the development of new products in the future, hoping to work hand in hand with new and old friends at home and abroad to create a bett

Manufacturer Supply High Quality Methyl 2-bromobenzoate

Cas:610-94-6

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Methyl 2-bromobenzoate Manufacturer

Cas:610-94-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Methyl 2-bromobenzoate Manufacturer

Cas:610-94-6

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Methyl 2-bromobenzoate

Cas:610-94-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

methanol
67-56-1

methanol

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With sulfuric acid Reflux; Inert atmosphere;99%
With sulfuric acid Reflux;99%
With sulfuric acid at 0℃; for 20.25h; Fischer-Speier Esterification; Reflux;96%
methanol
67-56-1

methanol

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With perchloric acid; sodium percarbonate; vanadia for 1.3h; Cooling;96%
With tert.-butylhydroperoxide; potassium carbonate In water at 60℃; for 6h;87%
With magnesium hydroxide; oxygen at 90℃; under 2250.23 Torr; for 8h;
2-bromophenyl methyl ketone
2142-69-0

2-bromophenyl methyl ketone

A

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

B

o-bromophenyl acetate
1829-37-4

o-bromophenyl acetate

Conditions
ConditionsYield
With hydrogenchloride In chloroform at 20℃; for 12h; Baeyer-Villiger oxidation;A 7%
B 91%
2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

methyl salicylate
119-36-8

methyl salicylate

A

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

B

salicylic acid
69-72-7

salicylic acid

Conditions
ConditionsYield
Stage #1: 2-bromobenzoic-acid With potassium carbonate In N,N-dimethyl acetamide at 110℃; for 0.5h;
Stage #2: methyl salicylate at 110℃; for 24h;
A 91%
B n/a
methanol
67-56-1

methanol

o-bromobenzyl alcohol
18982-54-2

o-bromobenzyl alcohol

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With oxygen; potassium carbonate at 60℃; under 750.075 Torr; for 20h;86%
With potassium chloride; dihydrogen peroxide; C5H12CrMo6O25(3-)*3C16H36N(1+) In water at 65℃; for 36h; Schlenk technique;80%
With sodium hypochlorite; tetrabutylammomium bromide In ethyl acetate at 20℃; for 3.51667h;17%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione at 25℃; for 12h; Temperature; chemoselective reaction;24 %Chromat.
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

A

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

B

phthalic acid dimethyl ester
131-11-3

phthalic acid dimethyl ester

C

benzene-1,2-dicarboxylic acid
88-99-3

benzene-1,2-dicarboxylic acid

Conditions
ConditionsYield
With tert-Amyl alcohol; sodium hydride; cobalt(II) acetate In tetrahydrofuran at 40℃; under 760 Torr; for 18h; Irradiation;A 4%
B 85%
C 3%
carbon monoxide
201230-82-2

carbon monoxide

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

A

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

B

phthalic acid dimethyl ester
131-11-3

phthalic acid dimethyl ester

C

benzene-1,2-dicarboxylic acid
88-99-3

benzene-1,2-dicarboxylic acid

Conditions
ConditionsYield
With methanol; tert-Amyl alcohol; sodium hydride; cobalt(II) acetate In tetrahydrofuran at 40℃; under 760 Torr; for 18h; Irradiation;A 4%
B 85%
C 3%
4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With sulfuric acid In methanol84%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
Stage #1: tert.-butylhydroperoxide; 2-methylphenyl bromide In water; dimethyl sulfoxide
Stage #2: In water; dimethyl sulfoxide at 100℃; for 20h; Sealed tube;
84%
With copper (II)-fluoride In water; dimethyl sulfoxide at 120℃; for 12h; Schlenk technique; Inert atmosphere; Green chemistry;25%
With ultrafine CuO particles dispersed on nitrogen-doped hollow carbon nanospheres In water; dimethyl sulfoxide at 100℃; for 20h; Sealed tube;86 %Chromat.
1-bromo-2-(methoxymethyl)benzene
52711-30-5

1-bromo-2-(methoxymethyl)benzene

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With oxygen In water at 25℃; for 12h; Irradiation; Green chemistry;80%
With copper(II) choride dihydrate; oxygen; hydroquinone at 30℃; for 16h; Sealed tube; Irradiation; Green chemistry;41%
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With N-Bromosuccinimide; silver hexafluoroantimonate; trifluorormethanesulfonic acid; nickel diacetate In 1,2-dichloro-ethane at 80℃; for 12h; regioselective reaction;76%
Stage #1: benzoic acid methyl ester With acetic acid
Stage #2: With bromine; acetic acid at 0 - 25℃; for 12h;
66.9%
With N-Bromosuccinimide; dibenzoyl peroxide
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

o-bromobenzyl alcohol
18982-54-2

o-bromobenzyl alcohol

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With copper (II)-fluoride In water; dimethyl sulfoxide at 120℃; for 12h; Schlenk technique; Inert atmosphere; Green chemistry;72%
With tetraethylammonium bromide; oxygen; potassium carbonate In water; dimethyl sulfoxide at 100℃; under 735.576 Torr; for 16h; Catalytic behavior; Mechanism;71%
methanol
67-56-1

methanol

1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

carbon monoxide
201230-82-2

carbon monoxide

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; under 11251.1 Torr; continuous flow reactor;69%
With palladium diacetate; triethylamine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; hydrazine In tetrahydrofuran; 1,4-dioxane at 100℃; under 11251.1 Torr; Flow reactor;69%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With copper (II)-fluoride In water; dimethyl sulfoxide at 120℃; for 12h; Schlenk technique; Inert atmosphere; Green chemistry;65%
Monomethyl phthalate
4376-18-5

Monomethyl phthalate

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene; bromine In various solvent(s) for 22h; bromodecarboxylation; Heating; irradiation;57%
1-thiopropane
107-03-9

1-thiopropane

methyl 2-bromo-3-aminobenzoate
106896-48-4

methyl 2-bromo-3-aminobenzoate

A

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

B

methyl 2-bromo-3-propylthiobenzoate

methyl 2-bromo-3-propylthiobenzoate

Conditions
ConditionsYield
Stage #1: methyl 2-bromo-3-aminobenzoate With tert.-butylnitrite; boron trifluoride diethyl etherate In diethyl ether; dichloromethane at -15 - 5℃; Diazotization;
Stage #2: 1-thiopropane With triethylamine In acetonitrile at 80℃; for 18h; Alkylation; substitution; decomposition; deamination;
A n/a
B 38%
methanol
67-56-1

methanol

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

A

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

B

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With 3,3'-dimethyl-1,1'-(hexane-1,6-diyl)diimidazolium glutarate; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1-(n-butyl)-3-methylimidazolium triflate In tetrahydrofuran at 55℃; for 16h; Molecular sieve;A 8%
B 37%
With C12H22N6(2+)*2C2F6NO4S2(1-); 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 55℃; for 16h; Reagent/catalyst; Molecular sieve;A 25%
B 17%
With C14H22N2S2(2+)*2F6P(1-); 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 55℃; for 16h; Reagent/catalyst; Molecular sieve;A 8%
B 21%
methanol
67-56-1

methanol

2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With carbon tetrabromide; oxygen for 24h; Irradiation;34%
methanol
67-56-1

methanol

2-bromobenzoic acid chloride
7154-66-7

2-bromobenzoic acid chloride

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

bromobenzene
108-86-1

bromobenzene

Methyl-tert.-butylperoxyoxalat
57031-51-3

Methyl-tert.-butylperoxyoxalat

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
In benzene Heating;
sodium acetoacetonate
15435-71-9

sodium acetoacetonate

copper(I) 2-bromobenzoate
121619-96-3

copper(I) 2-bromobenzoate

A

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

B

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

C

diphenic acid dimethyl ester
5807-64-7

diphenic acid dimethyl ester

D

3-(o-methoxycarbonylphenyl)pentane-2,4-dione
56741-51-6

3-(o-methoxycarbonylphenyl)pentane-2,4-dione

Conditions
ConditionsYield
1.) toluene, 1 h, 80 deg C; 2.) diethyl ether; Yield given. Multistep reaction. Yields of byproduct given;
Mechanism; Product distribution;
mesitylcopper(I)
75732-01-3

mesitylcopper(I)

copper(I) 2-bromobenzoate
121619-96-3

copper(I) 2-bromobenzoate

A

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

B

Mesityl 2-bromobenzoate
128499-36-5

Mesityl 2-bromobenzoate

C

Mesityl 2-mesitylbenzoate
128499-34-3

Mesityl 2-mesitylbenzoate

D

Mesityl methyl biphenyl-2,2'-dicarboxylate
128499-37-6

Mesityl methyl biphenyl-2,2'-dicarboxylate

Conditions
ConditionsYield
With oxygen 1.) toluene, 30 min, roomtemp.; 2.) 2 h, 80 deg C; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
sodium methylate
124-41-4

sodium methylate

1-(2-bromobenzoyl)-3-(4-chlorophenyl)urea
107485-55-2

1-(2-bromobenzoyl)-3-(4-chlorophenyl)urea

A

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

B

N-(4-chlorophenyl)urea
140-38-5

N-(4-chlorophenyl)urea

Conditions
ConditionsYield
In methanol at 25℃; Kinetics; Mechanism; Rate constant;
1-thiopropane
107-03-9

1-thiopropane

C8H6BrN2O2(1+)*BF4(1-)

C8H6BrN2O2(1+)*BF4(1-)

A

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

B

methyl 2-bromo-3-propylthiobenzoate

methyl 2-bromo-3-propylthiobenzoate

Conditions
ConditionsYield
With triethylamine In acetonitrile at 80℃; for 18h; Alkylation; substitution; decomposition;A n/a
B 1.10 g
methyl iodide
74-88-4

methyl iodide

2-bromo-benzoate silver

2-bromo-benzoate silver

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

2-bromo-3-nitro-benzoic acid
573-54-6

2-bromo-3-nitro-benzoic acid

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: PCl5 / 0.08 h / 150 °C
1.2: 94 percent / 1 h / Heating
2.1: 87 percent / glacial acetic acid; iron / 2 h / 120 °C
3.1: 91 percent / BF3*Et2O; t-butyl nitrite / CH2Cl2; diethyl ether / -15 - 5 °C
4.1: triethylamine / acetonitrile / 18 h / 80 °C
View Scheme
Multi-step reaction with 3 steps
1.1: PCl5 / 0.08 h / 150 °C
1.2: 94 percent / 1 h / Heating
2.1: 87 percent / glacial acetic acid; iron / 2 h / 120 °C
3.1: BF3*Et2O; t-butyl nitrite / CH2Cl2; diethyl ether / -15 - 5 °C
3.2: triethylamine / acetonitrile / 18 h / 80 °C
View Scheme
2-bromo-3-nitro-benzoic acid methyl ester
5337-09-7

2-bromo-3-nitro-benzoic acid methyl ester

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 87 percent / glacial acetic acid; iron / 2 h / 120 °C
2: 91 percent / BF3*Et2O; t-butyl nitrite / CH2Cl2; diethyl ether / -15 - 5 °C
3: triethylamine / acetonitrile / 18 h / 80 °C
View Scheme
Multi-step reaction with 2 steps
1.1: 87 percent / glacial acetic acid; iron / 2 h / 120 °C
2.1: BF3*Et2O; t-butyl nitrite / CH2Cl2; diethyl ether / -15 - 5 °C
2.2: triethylamine / acetonitrile / 18 h / 80 °C
View Scheme
methyl 2-bromo-3-aminobenzoate
106896-48-4

methyl 2-bromo-3-aminobenzoate

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 91 percent / BF3*Et2O; t-butyl nitrite / CH2Cl2; diethyl ether / -15 - 5 °C
2: triethylamine / acetonitrile / 18 h / 80 °C
View Scheme
anhydro-2-hydroxymercuri-3-nitrobenzoic acid

anhydro-2-hydroxymercuri-3-nitrobenzoic acid

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: bromine; base
2.1: PCl5 / 0.08 h / 150 °C
2.2: 94 percent / 1 h / Heating
3.1: 87 percent / glacial acetic acid; iron / 2 h / 120 °C
4.1: 91 percent / BF3*Et2O; t-butyl nitrite / CH2Cl2; diethyl ether / -15 - 5 °C
5.1: triethylamine / acetonitrile / 18 h / 80 °C
View Scheme
Multi-step reaction with 4 steps
1.1: bromine; base
2.1: PCl5 / 0.08 h / 150 °C
2.2: 94 percent / 1 h / Heating
3.1: 87 percent / glacial acetic acid; iron / 2 h / 120 °C
4.1: BF3*Et2O; t-butyl nitrite / CH2Cl2; diethyl ether / -15 - 5 °C
4.2: triethylamine / acetonitrile / 18 h / 80 °C
View Scheme
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

2-methoxynaphthylamine
2246-42-6

2-methoxynaphthylamine

methyl 2-[(2-methoxy-1-naphthyl)amino]benzoate

methyl 2-[(2-methoxy-1-naphthyl)amino]benzoate

Conditions
ConditionsYield
With caesium carbonate; palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 20 - 80℃; for 15.525h;100%
With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 20 - 80℃; for 15.5h; Inert atmosphere;100%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

methylmagnesium chloride
676-58-4

methylmagnesium chloride

2-(2-bromophenyl)propanol
7073-69-0

2-(2-bromophenyl)propanol

Conditions
ConditionsYield
Stage #1: 2-bromobenzoic acid methyl ester; methylmagnesium chloride In tetrahydrofuran; 2-methyltetrahydrofuran at 20℃; Cooling with ice;
Stage #2: With hydrogenchloride In tetrahydrofuran; 2-methyltetrahydrofuran; water at 0℃; pH=6; Product distribution / selectivity;
100%
In tetrahydrofuran at 0℃; Inert atmosphere;82%
In tetrahydrofuran at 5 - 20℃; Inert atmosphere;
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With water; sodium hydroxide In ethanol at 10 - 20℃; for 1.08333h;100%
With iodine; aluminium In acetonitrile at 80℃; for 18h;99%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

Conditions
ConditionsYield
With 2-H-1,3-di-tert-butyl-1,3,2-diazaphosphorinane; 2,2'-azobis(isobutyronitrile) In toluene at 90℃; for 5h;99%
Stage #1: 2-bromobenzoic acid methyl ester With sec.-butyllithium In tetrahydrofuran; hexane; cyclohexane at -48℃; for 7.77778E-06h;
Stage #2: With methanol In tetrahydrofuran; hexane; cyclohexane at -48℃; for 0.000638889h;
74%
With copper(I) chloride; methanol; sodium tetrahydroborate at 0℃;93 % Chromat.
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

methyl 3’-nitro-[1,1’-biphenyl]-2-carboxylate
83527-96-2

methyl 3’-nitro-[1,1’-biphenyl]-2-carboxylate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,4-dioxane at 85℃; Suzuki cross-coupling;99%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; toluene at 20 - 80℃; for 6h; Inert atmosphere;17%
With tetra-butylammonium acetate; Pd EnCat-30TM In ethanol Suzuki cross-coupling; microwave irradiation;
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

2'-methoxy-biphenyl-2-carboxylic acid methyl ester
63506-58-1

2'-methoxy-biphenyl-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With palladium diacetate; sodium carbonate; triphenylphosphine; [BMIM][Cl] In water; toluene for 3.5h; Suzuki coupling reaction; Heating;99%
With tetrakis(triphenylphosphine) palladium(0); tetrabutylammomium bromide; potassium carbonate In ethanol; water; toluene at 78 - 80℃; for 8h; Inert atmosphere;92%
With dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II); potassium carbonate In water; acetonitrile at 60℃; Suzuki-Miyaura reaction; Inert atmosphere; Sealed vessel;
With 1,1'-bis-(diphenylphosphino)ferrocene; potassium phosphate; palladium diacetate In 1,2-dimethoxyethane at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

N-Methylurea
598-50-5

N-Methylurea

3-methyl-2,4(1H,3H)-quinazolinedione
607-19-2

3-methyl-2,4(1H,3H)-quinazolinedione

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; for 48h;99%
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; for 24h;61%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

3,4,5-trimethoxyphenylboronic Acid
182163-96-8

3,4,5-trimethoxyphenylboronic Acid

3',4',5'-trimethoxybiphenyl-2-carboxylic acid methyl ester
928847-09-0

3',4',5'-trimethoxybiphenyl-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene at 100℃;99%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In toluene at 100℃; Suzuki reaction;45%
Octanethiol
111-88-6

Octanethiol

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

methyl 2-octylthiobenzenecarboxylate
211228-57-8

methyl 2-octylthiobenzenecarboxylate

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine In toluene for 3h; Inert atmosphere; Reflux;99%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

tri-n-butyl(thien-3-yl)tin
119405-65-1

tri-n-butyl(thien-3-yl)tin

methyl 2-(thiophen-3-yl)benzoate

methyl 2-(thiophen-3-yl)benzoate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In toluene for 24h; Stille Cross Coupling; Reflux; Inert atmosphere;99%
Thien-3-ylboronic acid
6165-69-1

Thien-3-ylboronic acid

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

methyl 2-(thiophen-3-yl)benzoate

methyl 2-(thiophen-3-yl)benzoate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In tetrahydrofuran; water at 70℃; for 16h; Inert atmosphere; Schlenk technique;99%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In tetrahydrofuran; water at 70℃; for 16h; Suzuki Coupling; Inert atmosphere;98%
With trans-bis(triphenylphosphine)palladium dichloride; sodium carbonate In tetrahydrofuran; water at 70℃; Suzuki-Miyaura Coupling; Inert atmosphere;92%
With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate In tetrahydrofuran; water at 70℃; for 36h; Inert atmosphere; Schlenk technique;89%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

2,4-dichlorophenylboronic acid
68716-47-2

2,4-dichlorophenylboronic acid

2',4'-Dichloro-biphenyl-2-carboxylic acid methyl ester

2',4'-Dichloro-biphenyl-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 120℃; for 3h;99%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

4-(pentafluorosulfanyl)aniline
2993-24-0

4-(pentafluorosulfanyl)aniline

N-(4-(pentafluorosulfanyl)phenyl)anthranilic acid methyl ester

N-(4-(pentafluorosulfanyl)phenyl)anthranilic acid methyl ester

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 110℃; for 18h; Buchwald-Hartwig Coupling; Inert atmosphere; Schlenk technique;99%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

(E)-3-methoxy-1-propenylboronic acid pinacol ester
165059-42-7

(E)-3-methoxy-1-propenylboronic acid pinacol ester

methyl (E)-2-(3-methoxyprop-1-en-1-yl)benzoate
1255651-89-8

methyl (E)-2-(3-methoxyprop-1-en-1-yl)benzoate

Conditions
ConditionsYield
With potassium phosphate; chloro(2-dicyclohexylphosphino-2’,4’,6’-triisopropyl-1,1‘-biphenyl)[2-(2’-amino-1,1‘-biphenyl’)]palladium(II) In tetrahydrofuran; water at 45℃; for 23h; Inert atmosphere; Sealed tube;99%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

potassium vinyltrifluoroborate

potassium vinyltrifluoroborate

methyl o-vinylbenzoate
27326-44-9

methyl o-vinylbenzoate

Conditions
ConditionsYield
With caesium carbonate; triphenylphosphine; palladium dichloride In tetrahydrofuran; water at 85℃; for 12h; Suzuki Coupling; Inert atmosphere;99%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

methylmagnesium bromide
75-16-1

methylmagnesium bromide

2-(2-bromophenyl)propanol
7073-69-0

2-(2-bromophenyl)propanol

Conditions
ConditionsYield
Stage #1: 2-bromobenzoic acid methyl ester; methylmagnesium bromide In tetrahydrofuran at 20℃; Cooling with ice;
Stage #2: With hydrogenchloride In water pH=5 - 6;
98.2%
Stage #1: 2-bromobenzoic acid methyl ester; methylmagnesium bromide In tetrahydrofuran; diethyl ether at 2 - 15℃; for 19.5h;
Stage #2: With hydrogenchloride In tetrahydrofuran; diethyl ether; water at 0 - 15℃; for 2h; Product distribution / selectivity;
97.48%
In tetrahydrofuran at 0 - 15℃; Inert atmosphere;97.5%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

N-(3-methylphenyl)anthranilic acid methyl ester
23868-14-6

N-(3-methylphenyl)anthranilic acid methyl ester

Conditions
ConditionsYield
With potassium phosphate; johnphos; tris(dibenzylideneacetone)dipalladium (0) In 1,2-dimethoxyethane at 100℃; for 24h; Arylation;98%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

tributyl(3-methoxyphenyl)stannane
122439-11-6

tributyl(3-methoxyphenyl)stannane

methyl 3'-methoxy-[1,1'-biphenyl]-2-carboxylate

methyl 3'-methoxy-[1,1'-biphenyl]-2-carboxylate

Conditions
ConditionsYield
With lithium chloride; dichlorobis(tris[4-(heptadecafluorooctyl)phenyl]phosphine-kP)palladium In N,N-dimethyl-formamide at 80℃; for 3h; Stille cross-coupling reaction;98%
With carbon dioxide; tetrabutyl-ammonium chloride; [(m-C8H17-C6H4)3P]2*PdCl2 at 90℃; for 24h; Stille coupling;61 % Spectr.
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

phenylacetylene
536-74-3

phenylacetylene

methyl 2-(phenylethynyl)benzoate
33578-05-1

methyl 2-(phenylethynyl)benzoate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; Sonogashira coupling; Inert atmosphere;98%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 80℃; Cooling with liquid nitrogen; Sealed tube;97%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃; for 18h; Sonogashira coupling;96%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With tetra-butylammonium acetate; Pd EnCat-30TM In ethanol at 120℃; for 0.166667h; Suzuki cross-coupling; microwave irradiation;98%
With potassium fluoride; palladium diacetate In toluene at 80℃; for 1h; Suzuki-Miyaura coupling;93%
With sodium carbonate; [(PPh3)2Pd(N-succ)2] In tetrahydrofuran; water at 60℃; for 10h; Suzuki cross-coupling reaction;62%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

tert-Butyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-3,6-dihydro-1(2H)-pyridinecarboxylate
375853-82-0, 286961-14-6

tert-Butyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-3,6-dihydro-1(2H)-pyridinecarboxylate

tert-butyl 4-(2-(methoxycarbonyl)phenyl)-5,6-dihydropyridine-1(2H)-carboxylate

tert-butyl 4-(2-(methoxycarbonyl)phenyl)-5,6-dihydropyridine-1(2H)-carboxylate

Conditions
ConditionsYield
With sodium hydrogencarbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 140℃; for 0.0833333h; Microwave irradiation;98%
With potassium carbonate; PdCl2*1,1'-bis(diphenylphosphine)ferrocene In N,N-dimethyl-formamide at 90℃; for 5h;
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

tributyl(thien-2-yl)stannane
54663-78-4

tributyl(thien-2-yl)stannane

o-(2-thienyl)benzoic acid methyl ester
17595-84-5

o-(2-thienyl)benzoic acid methyl ester

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In toluene for 17h; Stille coupling; Inert atmosphere; Reflux;98%
3‐methyl‐1‐(2‐methylphenyl)‐1H‐pyrazol‐5‐amine
91331-68-9

3‐methyl‐1‐(2‐methylphenyl)‐1H‐pyrazol‐5‐amine

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

methyl 2-((3-methyl-1-(2-methylphenyl)-1H-pyrazol-5-yl)amino)benzenecarboxylate
1209485-73-3

methyl 2-((3-methyl-1-(2-methylphenyl)-1H-pyrazol-5-yl)amino)benzenecarboxylate

Conditions
ConditionsYield
Stage #1: 3‐methyl‐1‐(2‐methylphenyl)‐1H‐pyrazol‐5‐amine; palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: 2-bromobenzoic acid methyl ester With caesium carbonate In toluene at 95℃; Inert atmosphere;
98%
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene for 16h; Buchwald-Hartwig type cross-coupling; Reflux;
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

acetone
67-64-1

acetone

1-(2-bromophenyl)-butane-1,3-dione
57279-20-6

1-(2-bromophenyl)-butane-1,3-dione

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran at 100℃; for 18.5h;98%
With sodium hydride In tetrahydrofuran at 20℃; for 18h; Reflux;
tert-butylisonitrile
119072-55-8, 7188-38-7

tert-butylisonitrile

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

4-(tert-butylamino)phthalazin-1(2H)-one
1346229-07-9

4-(tert-butylamino)phthalazin-1(2H)-one

Conditions
ConditionsYield
With palladium diacetate; hydrazine hydrate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In dimethyl sulfoxide at 150℃; for 0.0833333h; Microwave irradiation; Inert atmosphere; regioselective reaction;98%
tert-butylisonitrile
119072-55-8, 7188-38-7

tert-butylisonitrile

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

hydrazine
302-01-2

hydrazine

4-(tert-butylamino)phthalazin-1(2H)-one
1346229-07-9

4-(tert-butylamino)phthalazin-1(2H)-one

Conditions
ConditionsYield
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In dimethyl sulfoxide at 150℃; for 0.0833333h; Inert atmosphere; Microwave irradiation; Sealed tube;98%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

3-pentafluorosulfuraniline
2993-22-8

3-pentafluorosulfuraniline

N-(3-(pentafluorosulfanyl)phenyl)anthranilic acid methyl ester

N-(3-(pentafluorosulfanyl)phenyl)anthranilic acid methyl ester

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 110℃; for 18h; Buchwald-Hartwig Coupling; Inert atmosphere; Schlenk technique;98%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

(E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane
177573-86-3

(E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane

methyl (E)-2-(3-phenylprop-1-en-1-yl)benzoate
1027255-60-2

methyl (E)-2-(3-phenylprop-1-en-1-yl)benzoate

Conditions
ConditionsYield
With potassium phosphate; chloro(2-dicyclohexylphosphino-2’,4’,6’-triisopropyl-1,1‘-biphenyl)[2-(2’-amino-1,1‘-biphenyl’)]palladium(II) In tetrahydrofuran; water at 45℃; for 17h; Inert atmosphere; Sealed tube;98%

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