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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

We can provide GMP validation service that complies with SFDA, FDA, WHO and EU EMPA.Excellent registration team could help us easlily to register our products in different countries.If you and your customer are interested in some products or need C

1,2-Dibromobenzene manufacturer with low price

Cas:583-53-9

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

1,2-Dibromobenzene CAS NO.583-53-9

Cas:583-53-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Product Description Product Name 1,2-dibromobenzene CAS No. 583-53-9 Appearance

1,2-dibromobenzene

Cas:583-53-9

Min.Order:10 Gram

FOB Price: $20.0 / 30.0

Type:Lab/Research institutions

inquiry

Hangzhou Think Chemical Co. Ltd

1,2-Dibromobenzene CAS No.:583-53-9 Name: 1,2-Dibromobenzene Molecular Structure Molecular Formula: C6H4Br2 Molecular Weight: 235.90 CAS Registry Number: 583-53-9 EINECS 209-507-3 Density: 1.956

High purity 1,2-Dibromobenzene CAS No.:583-53-9

Cas:583-53-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,2-dibromobenzene

Cas:583-53-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

o-Dibromobenzene

Cas:583-53-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

1,2-Dibromobenzene Basic information Product Name: 1,2-Dibromobenzene Synonyms: 1,2-DIBROMOBENZENE;O-DIBROMOBENZENE;1,2-Dibrombenzol;1,2-dibromo-benzen;Benzene, o-dibromo-;Benzene,1,2-di

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Name 1,2-Dibromobenzene CAS NO. 583-53-9 Molecular Formula C6H4Br2 Molecular Weight 235.90 EINECS 209-507-3 Den

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

O-DIBROMOBENZENECAS NO.:583-53-9

Cas:583-53-9

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,2-dibromobenzene

Cas:583-53-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

1,2-Dibromobenzene/Manufacturer/High quality/Best price

Cas:583-53-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

High quality 1,2-dibromobenzene CAS NO.583-53-9Appearance:White powder Storage:Sealed, a cool, store transport Package:according to customers' requirements Application:Dyestuff Intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect...) or

High quality 1,2-dibromobenzene CAS NO.583-53-9

Cas:583-53-9

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Nanjing Fred Technology Co.,Ltd.

Taizhou FredChem Co. Ltd. is a high-tech enterprise located in China Medical City specializing in R&D, manufacturing, sales of new APIS, pharmaceutical intermediates and fine chemicals. All of our company is committed to provide high quality ch

1,2-dibromobenzene

Cas:583-53-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1,2-dibromobenzene

Cas:583-53-9

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

1,2-DibroMobenzene

Cas:583-53-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers658.Safe and fa

1,2-dibromobenzene

Cas:583-53-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:light yellow liquid Storage:Sealed in a cool ,dry and microtherm place , avoid light . Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:It is an important

1,2-dibromobenzene supplier in China

Cas:583-53-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech bar

1,2-dibromobenzene china manufacture

Cas:583-53-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 583-53-9 with competitive price

Cas:583-53-9

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,2-DibroMobenzene

Cas:583-53-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

1,2-Dibromobenzene

Cas:583-53-9

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With dibromoisocyanuric acid In dichloromethane at 20℃; for 24h; Reagent/catalyst; Solvent; Temperature; UV-irradiation;100%
3,4-dibromoaniline
615-55-4

3,4-dibromoaniline

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
Stage #1: 3,4-dibromoaniline With hydrogenchloride In diethyl ether; water for 0.0833333h;
Stage #2: With hydrogenchloride; sodium nitrite In water at 0℃; for 0.5h;
Stage #3: With hypophosphorous acid In water at 4 - 25℃; for 72h;
81%
bromobenzene
108-86-1

bromobenzene

A

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

B

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With PyHBrCl2; iron(III) chloride In dichloromethane at 20℃; for 2h;A 19%
B 72%
With lead(IV) acetate; trifluoroacetic acid; potassium bromide at 25℃; for 0.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With bromine; ZnBr2 on silica (100 Angstroem) In hexane at 25℃; for 0.116667h; Yields of byproduct given;
o-Bromobenzenediazonium o-benzenedisulfonimide

o-Bromobenzenediazonium o-benzenedisulfonimide

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With tetrabutylammomium bromide In acetonitrile at 60℃; for 0.75h; Substitution;53%
With tetrabutylammomium bromide; copper In acetonitrile at 20℃; for 0.75h; Substitution;51%
1,2-dibromobenzene-4-sulfonic acid
107573-20-6

1,2-dibromobenzene-4-sulfonic acid

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With hydrogen bromide at 250℃;
1,2-Dinitrobenzene
528-29-0

1,2-Dinitrobenzene

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With hydrogen bromide at 250 - 260℃;
2-bromoaniline
615-36-1

2-bromoaniline

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

benzene
71-43-2

benzene

A

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

B

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With bromine; Nitrogen dioxide In water; trifluoroacetic acid at 20℃; for 0.16h; Product distribution;
With bromine
With ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; bromine; zinc(II) oxide In dichloromethane for 3h; Heating;
Multi-step reaction with 2 steps
1: bromine / 1.5 h / 40 °C / Darkness; Inert atmosphere; Green chemistry
2: bromine / dichloromethane / 2 h / 40 °C / Darkness; Inert atmosphere; Green chemistry
View Scheme
bromobenzene
108-86-1

bromobenzene

A

bromochlorobenzene
106-39-8

bromochlorobenzene

B

para-dichlorobenzene
106-46-7

para-dichlorobenzene

C

2-bromo-1-chlorobenzene
694-80-4

2-bromo-1-chlorobenzene

D

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

E

chlorobenzene
108-90-7

chlorobenzene

F

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With potassium chloride; cobalt(III) acetate; trifluoroacetic acid at 20℃; for 15h; Product distribution; Mn(CH3COO)3, 600 - 216 h, various conc. of aq. CF3COOH;
bromobenzene
108-86-1

bromobenzene

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

C

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With hypobromous acid In 1,4-dioxane; water at 25℃; Rate constant;A 1 % Chromat.
B 64.3 % Chromat.
C 35.7 % Chromat.
benzene
71-43-2

benzene

A

bromobenzene
108-86-1

bromobenzene

B

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

C

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With oxygen; potassium bromide; sodium nitrite In water; trifluoroacetic acid at 20℃; for 24h; Product distribution;
With hydrogen bromide; oxygen; ruthenium trichloride at 145℃; under 750.075 Torr; for 17h;
1,2,4-tribromobenzene
615-54-3

1,2,4-tribromobenzene

A

bromobenzene
108-86-1

bromobenzene

B

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

C

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

D

benzene
71-43-2

benzene

E

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With potassium hydroxide; hydrogen; palladium on activated charcoal In 2,2,4-trimethylpentane at 50℃; for 0.666667h; Product distribution; var. cat.: Raney-Ni, add. of Aliquat 336;A 18 % Chromat.
B 3 % Chromat.
C 1 % Chromat.
D 42 % Chromat.
E 30 % Chromat.
2-bromo-benzene-sulfonic acid-(1)

2-bromo-benzene-sulfonic acid-(1)

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With copper(ll) bromide
2-bromo-phenylmercury acetate

2-bromo-phenylmercury acetate

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With bromine; acetic acid
bromobenzene
108-86-1

bromobenzene

bromine
7726-95-6

bromine

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
at 200 - 700℃; Quantum yield;
chlorosulfonic acid
7790-94-5

chlorosulfonic acid

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

iodine
7553-56-2

iodine

benzene
71-43-2

benzene

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

diazotized o-bromo-aniline

diazotized o-bromo-aniline

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
man fuehrt in das Perbromid ueber und zersetzt dieses mit Soda;
sulfate 3.4-dibromo-aniline

sulfate 3.4-dibromo-aniline

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With ethyl nitrite; ethanol
bromobenzene
108-86-1

bromobenzene

A

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

B

1.3-dibromo-benzene; 1.4-dibromo-benzene

1.3-dibromo-benzene; 1.4-dibromo-benzene

Conditions
ConditionsYield
With bromine at 480℃;
aluminium trichloride
7446-70-0

aluminium trichloride

bromobenzene
108-86-1

bromobenzene

A

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

B

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
at 90℃;
carbon disulfide
75-15-0

carbon disulfide

bromobenzene
108-86-1

bromobenzene

bromine
7726-95-6

bromine

aluminium bromide
7727-15-3

aluminium bromide

A

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

B

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
at 55℃; Kinetics;
bromine
7726-95-6

bromine

benzene
71-43-2

benzene

A

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

B

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

bromobenzene
108-86-1

bromobenzene

bromine
7726-95-6

bromine

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

C

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
at 375 - 500℃;
bromobenzene
108-86-1

bromobenzene

bromine
7726-95-6

bromine

aluminium

aluminium

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

C

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
at 55℃; Product distribution;
bromobenzene
108-86-1

bromobenzene

bromine
7726-95-6

bromine

iron

iron

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

C

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
at 55℃; Product distribution;
benzene
71-43-2

benzene

A

bromobenzene
108-86-1

bromobenzene

B

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

C

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

D

1,2,3,4,5,6-hexabromocyclohexane
1837-91-8

1,2,3,4,5,6-hexabromocyclohexane

E

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

F

HBr

HBr

Conditions
ConditionsYield
With bromine at 55℃; for 16h; Product distribution; Irradiation; temperature;
bromobenzene
108-86-1

bromobenzene

A

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

B

m and p-dibromo-benzene

m and p-dibromo-benzene

Conditions
ConditionsYield
With bromine; aluminium at 55℃;
With bromine; iron at 55℃;
biphenyl
92-52-4

biphenyl

benzene
71-43-2

benzene

A

bromobenzene
108-86-1

bromobenzene

B

2-Bromobiphenyl
2052-07-5

2-Bromobiphenyl

C

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

D

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

E

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

F

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

G

HBr

HBr

Conditions
ConditionsYield
With bromine at 50℃; for 20h; Product distribution; Irradiation; other time, reagents ratio;
Methyl phenyl sulfone
3112-85-4

Methyl phenyl sulfone

bromine
7726-95-6

bromine

A

methyl bromide
74-83-9

methyl bromide

B

bromobenzene
108-86-1

bromobenzene

C

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
at 250℃;
2,4,6-trimethylaniline
88-05-1

2,4,6-trimethylaniline

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

N1,N2-bis(2,4,6-trimethylphenyl)-1,2-benzenediamine
852414-57-4

N1,N2-bis(2,4,6-trimethylphenyl)-1,2-benzenediamine

Conditions
ConditionsYield
With ammonium chloride; sodium t-butanolate; palladium diacetate In water; argon; toluene100%
With tri-tert-butylphosphonium tetrafluoroborate; palladium diacetate; sodium t-butanolate In toluene at 60 - 135℃; Inert atmosphere;87%
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; palladium diacetate In toluene for 12h; Heating;86%
5-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribono-1,4-lactone
130222-84-3

5-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribono-1,4-lactone

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

1-(2-bromophenyl)-5-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribofuranose
881423-76-3

1-(2-bromophenyl)-5-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribofuranose

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; diethyl ether; hexane at -110℃; for 3.5h;100%
1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

N,N'-diphenyl-o-phenylenediamine
28394-83-4

N,N'-diphenyl-o-phenylenediamine

Conditions
ConditionsYield
With ammonium chloride; aniline; sodium t-butanolate; palladium diacetate In water; argon; toluene100%
2,5-Dimethylaniline
95-78-3

2,5-Dimethylaniline

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

N,N'-bis(2,5-dimethylphenyl)-o-phenylenediamine
1068437-88-6

N,N'-bis(2,5-dimethylphenyl)-o-phenylenediamine

Conditions
ConditionsYield
With ammonium chloride; sodium t-butanolate; palladium diacetate In water; argon; toluene100%
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 14h; Inert atmosphere;100 %Chromat.
3,5-dimethylaminoaniline
108-69-0

3,5-dimethylaminoaniline

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

N,N'-di(3,5-dimethylphenyl)benzene-1,2-diamine
1068437-89-7

N,N'-di(3,5-dimethylphenyl)benzene-1,2-diamine

Conditions
ConditionsYield
With ammonium chloride; sodium t-butanolate; palladium diacetate In water; argon; toluene100%
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 14h; Inert atmosphere;100 %Chromat.
2,5-di-tert-butylaniline
21860-03-7

2,5-di-tert-butylaniline

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

A

N,N'-bis(2,5-di-1-butylphenyl)-o-phenylenediamine

N,N'-bis(2,5-di-1-butylphenyl)-o-phenylenediamine

B

N,N'-bis(2,5-di-t-butylphenyl)-o-phenylenediamine
1068437-90-0

N,N'-bis(2,5-di-t-butylphenyl)-o-phenylenediamine

Conditions
ConditionsYield
With ammonium chloride; sodium t-butanolate; palladium diacetate In water; argon; tolueneA n/a
B 100%
3,4,5-trimethoxyphenylboronic Acid
182163-96-8

3,4,5-trimethoxyphenylboronic Acid

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

2-bromo-3′,4′,5′-trimethoxybiphenyl

2-bromo-3′,4′,5′-trimethoxybiphenyl

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate In ethanol; N,N-dimethyl acetamide at 20℃; for 3h; Suzuki Coupling;100%
1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

Conditions
ConditionsYield
With C24H12Cu2F9N4O7; tetrabutylammomium bromide; ammonia; caesium carbonate In water at 110 - 140℃; for 16h;99%
With ammonium hydroxide; copper(l) iodide; N,N-dimethylethylenediamine In dimethyl sulfoxide at 130℃; for 18h; Reagent/catalyst; Time; Sealed tube; Inert atmosphere;92%
With ammonium hydroxide In water at 20℃; for 12h; Green chemistry;92%
With ammonia; water; copper(II) sulfate at 180 - 190℃;
With [Cu2(2,7-bis(pyridin-2-yl)-l,8-naphthyridine)(OH)(CF3COO)3]; tetrabutylammomium bromide; ammonia; caesium carbonate In water at 120℃; for 16h; Sealed tube;100 %Spectr.
ethyl trifluoroacetate,
383-63-1

ethyl trifluoroacetate,

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

1-(2-bromophenyl)-2,2,2-trifluoroethan-1-one
244229-34-3

1-(2-bromophenyl)-2,2,2-trifluoroethan-1-one

Conditions
ConditionsYield
Stage #1: 2,3-dibromobenzene With n-butyllithium
Stage #2: ethyl trifluoroacetate,
99%
Stage #1: 2,3-dibromobenzene With n-butyllithium at -110℃; Metallation;
Stage #2: ethyl trifluoroacetate, Acylation;
acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

2E,2′E-3,3′-(1,2-phenylene) bis[2-propenoic acid] dibutyl ester

2E,2′E-3,3′-(1,2-phenylene) bis[2-propenoic acid] dibutyl ester

Conditions
ConditionsYield
With potassium carbonate; bis(dibenzylideneacetone)-palladium(0); 3-(2,6-diisopropylphenyl)-1-(2-diphenylphosphanylbenzyl)-3H-imidazol-1-ium chloride In N,N-dimethyl acetamide at 120℃; for 16h; Heck reaction;99%
With palladium diacetate; tri-tert-butyl phosphine; sodium acetate In N,N-dimethyl acetamide at 130℃; for 24h; Heck reaction;60%
(2,6-dimethylphenyl)magnesium bromide
21450-64-6

(2,6-dimethylphenyl)magnesium bromide

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

4-methylfluorene
1556-99-6

4-methylfluorene

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine In tetrahydrofuran at 20℃; for 20h;99%
palladium diacetate In tetrahydrofuran at 20℃; for 20h;99%
2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

2’-bromo-2-methoxybiphenyl
20837-12-1

2’-bromo-2-methoxybiphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In methanol; toluene for 24h; Suzuki reaction; Reflux; Inert atmosphere;99%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane at 50℃; for 4h; Suzuki coupling;71%
1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

2-mesitylmagnesium bromide
2633-66-1

2-mesitylmagnesium bromide

2,4-dimethyl-9H-fluorene
2928-44-1

2,4-dimethyl-9H-fluorene

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine In tetrahydrofuran at 20℃; for 20h;99%
palladium diacetate In tetrahydrofuran at 20℃; for 20h;99%
tert-butylamine
75-64-9

tert-butylamine

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

N1,N2-di-tert-butylbenzene-1,2-diamine

N1,N2-di-tert-butylbenzene-1,2-diamine

Conditions
ConditionsYield
99%
With palladium diacetate; sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
With palladium diacetate; sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride
1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

2-bromoaniline
615-36-1

2-bromoaniline

Conditions
ConditionsYield
With 2-((dicyclohexylphosphino)methyl)-1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium iodide; ammonia; palladium diacetate; sodium t-butanolate In 1,4-dioxane at 120℃; under 7500.75 Torr; for 24h; Autoclave; Inert atmosphere;99%
With 2-(di-tert-butylphosphino)-1-mesityl-4,5-diphenyl-1H-imidazole; ammonia; palladium diacetate; sodium t-butanolate In 1,4-dioxane at 120℃; under 7500.75 Torr; for 24h; Autoclave; Inert atmosphere;> 99 %Chromat.
9,9-dimethyl-3,6-dimethoxy-9-stannafluorene
5565-83-3

9,9-dimethyl-3,6-dimethoxy-9-stannafluorene

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

2,11-dimethoxytriphenylene
1115023-89-6

2,11-dimethoxytriphenylene

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0) In tetrahydrofuran at 60℃; for 12h;99%
thiophenol
108-98-5

thiophenol

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

1,2-bis(phenylthio)benzene
3379-36-0

1,2-bis(phenylthio)benzene

Conditions
ConditionsYield
With 1,2,3,4-tetrahydroquinolin-8-ol; caesium carbonate; copper(I) bromide In N,N-dimethyl-formamide at 130℃; for 48h; Inert atmosphere; chemoselective reaction;99%
N-phenylacetamidine
14277-00-0

N-phenylacetamidine

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

2-methyl-1-phenyl-1H-benzimidazole
1484-39-5

2-methyl-1-phenyl-1H-benzimidazole

Conditions
ConditionsYield
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; sodium t-butanolate In toluene at 140℃; for 24h; Molecular sieve; Inert atmosphere; regiospecific reaction;99%
N-cyclohexylbenzimidamide
19673-06-4

N-cyclohexylbenzimidamide

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

1-cyclohexyl-2-phenyl-1H-benzo[d]imidazole
1350628-99-7

1-cyclohexyl-2-phenyl-1H-benzo[d]imidazole

Conditions
ConditionsYield
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; sodium t-butanolate In toluene at 140℃; for 24h; Molecular sieve; Inert atmosphere; regiospecific reaction;99%
N-(naphthalen-1-yl)benzimidamide
607-54-5

N-(naphthalen-1-yl)benzimidamide

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

1-(naphthalen-1-yl)-2-phenyl-1H-benzo[d]imidazole
1350628-96-4

1-(naphthalen-1-yl)-2-phenyl-1H-benzo[d]imidazole

Conditions
ConditionsYield
With 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 140℃; for 24h; Molecular sieve; Inert atmosphere; regiospecific reaction;99%
N-phenylbenzamidine
1527-91-9

N-phenylbenzamidine

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

1,2-diphenyl-1H-benzoimidazole
2622-67-5

1,2-diphenyl-1H-benzoimidazole

Conditions
ConditionsYield
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; sodium t-butanolate In toluene at 140℃; for 24h; Molecular sieve; Inert atmosphere; regiospecific reaction;99%
With potassium phosphate; 1,10-Phenanthroline; copper(II) oxide In diethylene glycol dimethyl ether at 140℃; for 24h; Inert atmosphere; regiospecific reaction;51%
(R)-2-methoxy-1-phenylethylamine
64715-85-1, 91298-74-7, 127180-88-5

(R)-2-methoxy-1-phenylethylamine

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

(2-bromophenyl)-(R)-2-methoxy-1-phenylethylamine
361979-02-4

(2-bromophenyl)-(R)-2-methoxy-1-phenylethylamine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃; for 48h; Buchwald-Hartwig amination;98%
1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

phenylboronic acid
98-80-6

phenylboronic acid

o-terphenyl
84-15-1

o-terphenyl

Conditions
ConditionsYield
With {2,6-bis[(di-1-piperidinylphosphino)amino]phenyl}palladium(II) chloride; potassium carbonate In 1,4-dioxane; water; butan-1-ol at 100℃; for 0.5h; Suzuki-Miyaura reaction;98%
With potassium phosphate; dichloro{bis[1-(dicyclohexylphosphanyl)piperidine]}palladium(II) In toluene at 80℃; for 0.166667h; Suzuki-Miyaura cross-coupling reaction; Air;98%
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine In tetrahydrofuran at 20℃; for 6h; Suzuki coupling;96%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

4,4′′-dimethyl-o-terphenyl
64586-14-7

4,4′′-dimethyl-o-terphenyl

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine In tetrahydrofuran at 20℃; for 6h; Suzuki coupling;98%
With bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tricyclohexylphosphine In tetrahydrofuran for 20h; Suzuki Coupling; Inert atmosphere;97%
With potassium carbonate In ethanol; water at 20℃; for 8h; Suzuki-Miyaura coupling;85%
With sodium tetrachloropalladate(II); C22H16O8S2(2-)*2Na(1+); sodium hydroxide In ethanol; water at 100℃; for 8h; Suzuki-Miyaura Coupling; Schlenk technique;83%
With potassium carbonate In methanol at 80℃; for 0.5h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;
aminoferrocene
1273-82-1

aminoferrocene

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

[C6H4(NH(C5H4)Fe(C5H5))2]
1198580-93-6

[C6H4(NH(C5H4)Fe(C5H5))2]

Conditions
ConditionsYield
With t-BuONa; Pd(O2CCH3)2; 1,3-bis(2,6-diisopropylphenyl)imidazolim chloride In toluene mixt. of Fe complex, imidazolium salt, t-BuONa, Pd compd. and C6H4Br2 intoluene was heated at 110°C for 12 h;98%
(3-(tert-butyl)-2-methoxyphenyl)boronic acid
1205536-16-8

(3-(tert-butyl)-2-methoxyphenyl)boronic acid

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

2'-bromo-3-tert-butyl-2-methoxybiphenyl
1205536-18-0

2'-bromo-3-tert-butyl-2-methoxybiphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); water; potassium carbonate In 1,2-dimethoxyethane at 67℃; for 60h; Suzuki coupling; Inert atmosphere;98%
4-(dimethylamino)-N-phenylbenzimidamide
52379-48-3

4-(dimethylamino)-N-phenylbenzimidamide

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

1-phenyl-2-(4-N,N-dimethylamino-phenyl)-1H-benzo[d]imidazole
2562-73-4

1-phenyl-2-(4-N,N-dimethylamino-phenyl)-1H-benzo[d]imidazole

Conditions
ConditionsYield
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; sodium t-butanolate In toluene at 140℃; for 24h; Molecular sieve; Inert atmosphere; regiospecific reaction;98%
bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

2-(3,4-dibromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1075719-78-6

2-(3,4-dibromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; cyclopentyl methyl ether; 1,1'-di(pyridin-2-yl)-1,1',3,3'-tetrahydro-2,2'-bibenzo[d][1,3,2]diazaborole at 80℃; for 16h; Schlenk technique; Inert atmosphere;98%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; 1-(4,4'-di-tert-butyl-[2,2'-bipyridin]-6-yl)-2-(dimethyl(phenyl)silyl)-2,3-dihydro-1H-benzo[d][1,3,2]diazaborole Inert atmosphere; Schlenk technique; Sealed tube;97%
With (1,5-cyclooctadiene)(methoxy)iridium(l) dimer; 4,4'-ditert-butyl-2,2'-bipyridine In tetrahydrofuran at 80℃; for 18h; Inert atmosphere; regioselective reaction;
Stage #1: bis(pinacol)diborane With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine In tetrahydrofuran for 0.0333333h; Inert atmosphere; Sonication;
Stage #2: 2,3-dibromobenzene In tetrahydrofuran at 80℃; for 24h; Inert atmosphere;
With (1,5-cyclooctadiene)(methoxy)iridium(l) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine In tetrahydrofuran at 80℃; for 24h; Inert atmosphere;
N'-(1-(2-aminophenyl)ethylidene)-4-methylbenzenesulfonohydrazide
1433772-22-5

N'-(1-(2-aminophenyl)ethylidene)-4-methylbenzenesulfonohydrazide

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

9-methyl-acridine
611-64-3

9-methyl-acridine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); lithium tert-butoxide; ruphos In 1,4-dioxane; water at 110℃; for 12h; Reagent/catalyst; Temperature; Microwave irradiation; Inert atmosphere;98%

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