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Cas:615-36-1
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inquiry2-Bromoaniline CAS No.:615-36-1 Name: 2-Bromoaniline Synonyms: o-Bromoaniline; 2-Bromobenzenamine Molecular Structure Molecular Formula: C6H6BrN Molecula
Cas:615-36-1
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inquiryhigh quality Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
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Cas:615-36-1
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inquiryTIANFUCHEM--615-36-1--2-Bromoaniline in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relationships
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inquiryProduct Description Name 2-Bromoaniline CAS 615-36-1 Assay 99% Appearance C
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inquiryIdentification Product name: 2-bromoaniline Product name: 2-bromoaniline Molecular formula: C6H6BrN Molecular weight: 172.03 Structural formula:
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Cas:615-36-1
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inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:615-36-1
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inquiryCAS:615-36-1 EINECS:172.02 MW:172.02 MF:C6H6BrN Melting point:29 °C Boiling point:229 °C(lit.) Appearance:White crystalline powder Package:25kg/drum Transportation:by sea/air/courier Port:Shanghai
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2-BromoanilineAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier
Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
Conditions | Yield |
---|---|
With hydrogen In tetrahydrofuran; water at 120℃; under 22502.3 Torr; for 4h; Autoclave; | 99% |
With hydrazine In ethanol at 80℃; for 0.333333h; Catalytic behavior; chemoselective reaction; | 99.6% |
With hydrogen In water at 120℃; under 15001.5 Torr; for 5h; Green chemistry; chemoselective reaction; | 99% |
Conditions | Yield |
---|---|
With 2-((dicyclohexylphosphino)methyl)-1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium iodide; ammonia; palladium diacetate; sodium t-butanolate In 1,4-dioxane at 120℃; under 7500.75 Torr; for 24h; Autoclave; Inert atmosphere; | 99% |
With 2-(di-tert-butylphosphino)-1-mesityl-4,5-diphenyl-1H-imidazole; ammonia; palladium diacetate; sodium t-butanolate In 1,4-dioxane at 120℃; under 7500.75 Torr; for 24h; Autoclave; Inert atmosphere; | > 99 %Chromat. |
Conditions | Yield |
---|---|
Stage #1: o-bromo-N-hydroxybenzamide With acetic anhydride; potassium carbonate In dimethyl sulfoxide at 50℃; for 2h; Lossen Rearrangement; Stage #2: With hydrogenchloride In water; dimethyl sulfoxide at 0℃; | 99% |
With sodium hydroxide In dimethyl sulfoxide at 80℃; for 1.5h; Lossen rearrangement; | |
Stage #1: o-bromo-N-hydroxybenzamide With potassium carbonate In dimethyl sulfoxide at 90℃; for 3h; Lossen Rearrangement; Stage #2: With hydrogenchloride In water; dimethyl sulfoxide at 20℃; for 0.0833333h; |
Conditions | Yield |
---|---|
With hydrazine hydrate In toluene at 20℃; for 3h; Inert atmosphere; | A n/a B 97% |
With hydrogenchloride; zinc(II) chloride In benzene Ambient temperature; electrolysis; Yield given. Yields of byproduct given. Title compound not separated from byproducts; | |
With water; zinc at 250℃; for 0.3h; Reduction; Title compound not separated from byproducts; | |
With 5%-palladium/activated carbon; hydrazine hydrate In methanol at 80℃; for 0.0833333h; Overall yield = 95 %; | |
With hydrogen In toluene at 110℃; under 7500.75 Torr; for 0.75h; Autoclave; |
N-(2-bromophenyl)formamide
2-bromoaniline
Conditions | Yield |
---|---|
With potassium phosphate; C29H55FeNOP2; hydrogen In tetrahydrofuran at 110℃; under 15001.5 Torr; for 3h; Catalytic behavior; | 97% |
With sodium hydroxide In ethanol; water at 40℃; Kinetics; |
Conditions | Yield |
---|---|
With ammonium hydroxide at 90℃; for 1.25h; | 96% |
With D-glucose; potassium hydroxide In water at 85℃; for 0.166667h; Green chemistry; chemoselective reaction; | 85% |
With tributylgermanium hydride; thiophenol In toluene for 0.5h; Heating; | 5% |
bis-(2-bromo-phenyl)-diazene
2-bromoaniline
Conditions | Yield |
---|---|
With aminomethyl polystyrene resin formic acid salt; zinc In methanol at 20℃; for 0.25h; | 94% |
With formic acid; zinc In methanol at 20℃; for 0.116667h; | 93% |
With ammonium formate; nickel In methanol at 20℃; for 0.116667h; | 93% |
(E)-1,2-bis(2-bromophenyl)diazene
2-bromoaniline
Conditions | Yield |
---|---|
With nickel; hydrazinium monoformate In methanol for 0.116667h; Heating; | 93% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; potassium bromide In water; acetonitrile | A 87% B 12% |
With pyridinium hydrobromide perbromide In tetrahydrofuran for 0.25h; Product distribution; other aromatic amines; | A 84% B n/a |
With N-Bromosuccinimide; silver hexafluoroantimonate; 1-methylthiotriptycene In 1,2-dichloro-ethane at 20℃; for 1h; Inert atmosphere; Schlenk technique; Overall yield = 95 percentSpectr.; | A 76% B n/a |
(2-bromophenyl)boronic acid
2-bromoaniline
Conditions | Yield |
---|---|
With copper(I) oxide; ammonium hydroxide; air In methanol at 20℃; for 16h; | 87% |
With copper(I) oxide; ammonium hydroxide; oxygen; sodium hydroxide In water at 25℃; for 15h; | 78% |
With sodium hydroxide; hydroxylamine-O-sulfonic acid In acetonitrile at 20℃; for 16h; | 70% |
N-(2-bromophenyl)-O-benzyl carbamate
2-bromoaniline
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate; ethanethiol for 36h; Ambient temperature; | 85% |
Conditions | Yield |
---|---|
With water Inert atmosphere; | A 51% B 73% |
Conditions | Yield |
---|---|
With [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); formic acid; bis(trifluoromethanesulfonyl)amide; triethylamine; [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In dibutyl ether at 130℃; for 24h; | A n/a B 73% |
2-(2-bromophenyl)-1,3,2-dioxaborolane
2-bromoaniline
Conditions | Yield |
---|---|
With copper(I) oxide; ammonium hydroxide; air In methanol at 20℃; for 15h; | 71% |
Conditions | Yield |
---|---|
With copper(l) iodide; tetra(n-butyl)ammonium hydroxide; ammonia In water at 45℃; for 48h; Inert atmosphere; Sealed tube; chemoselective reaction; | 71% |
Stage #1: 1-Bromo-2-iodobenzene With TurboGrignard In tetrahydrofuran at -45℃; for 2h; Inert atmosphere; Stage #2: With C10H17NO In tetrahydrofuran; toluene at -45℃; for 2h; Inert atmosphere; | 29% |
Conditions | Yield |
---|---|
With methanesulfonic acid; trimethylsilylazide In tetrachloromethane at 80℃; for 4h; | 70% |
Conditions | Yield |
---|---|
With bromine; hydrogen fluoride; antomony(V) at -40℃; for 0.25h; | A 29% B 62% C 3% |
With bromine; hydrogen fluoride; antomony(V) at -40℃; for 0.25h; Mechanism; Product distribution; dependence of product distribution on ammount of catalyst; |
1,8-diazabicyclo[5.4.0]undec-7-ene
2-bromophenyl carbamic acid methyl ester
A
2-bromoaniline
Conditions | Yield |
---|---|
In 1,4-dioxane; water at 80℃; under 760.051 Torr; for 2h; | A 61% B 53% |
Conditions | Yield |
---|---|
A 60% B n/a |
2-(2-bromophenoxy)propanamide
2-bromoaniline
Conditions | Yield |
---|---|
With potassium hydroxide In dimethyl sulfoxide at 140℃; for 4h; Green chemistry; | 60% |
ethanol
2-nitrophenyl bromide
A
2-bromo-N,N-diethylaniline
B
2-bromoaniline
Conditions | Yield |
---|---|
With Au NCs/TiO2 for 4h; Kinetics; Reagent/catalyst; Inert atmosphere; UV-irradiation; | A 24.2% B 52.8% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; copper diacetate; potassium bromide In water at 20℃; for 2h; Concentration; Reagent/catalyst; | 50% |
With D-glucose; Escherichia coli flavin reductase; Bacillus megaterium glucose dehydrogenase; Lechevalieria aerocolonigenes tryptophan-7-halogenase; flavin adenine dinucleotide; NADH In aq. phosphate buffer; isopropyl alcohol pH=7.4; Enzymatic reaction; | |
With hydrogen bromide; dimethyl sulfoxide In water; ethyl acetate at 60℃; for 12h; | |
With N-Bromosuccinimide In dichloromethane |
E-Ethyl ester of 4-methyl-4,5-epoxy-2-pentenoic acid
(2-Bromo-phenyl)-[1-phenyl-meth-(E)-ylidene]-amine
C
benzaldehyde
D
2-bromoaniline
Conditions | Yield |
---|---|
scandium tris(trifluoromethanesulfonate) In tetrahydrofuran at 0℃; Title compound not separated from byproducts; | A n/a B 48% C n/a D n/a |
Conditions | Yield |
---|---|
With O-(4-nitrobenzoyl)hydroxylammonium trifluoromethanesulfonate; iron(II) bromide; silver(I) triflimide In 2,2,2-trifluoroethanol; water at 30℃; for 2h; | A 40.2% B 26.8% |
thiophene boronic acid
1-azido-2-bromobenzene
A
2-(2-azidephenyl)thiophene
B
2-(thiophen-2-yl)aniline
C
2-bromoaniline
Conditions | Yield |
---|---|
With sodium hydrogencarbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane at 100℃; for 6h; Suzuki-Miyaura cross-coupling reaction; | A 40% B 3% C 2% |
bromobenzene
A
3-bromoaniline
B
4-bromo-aniline
C
2-bromoaniline
Conditions | Yield |
---|---|
With tris-(2-chloro-ethyl)-amine; trifluorormethanesulfonic acid; trifluoroacetic acid In chloroform at 60℃; for 3h; | A 10% B 25% C 30% |
With hydroxylamine-O-sulfonic acid; iron(II) sulfate In water; acetic acid at 40℃; for 2h; Yield given. Yields of byproduct given; | |
With hydroxylamine-O-sulfonic acid; iron(II) sulfate In water; acetic acid at 40℃; for 2h; Product distribution; Mechanism; k(C6H5Br)/k(C6H6); |
Conditions | Yield |
---|---|
With 1,10-Phenanthroline In acetonitrile at 90℃; for 1h; Temperature; Inert atmosphere; Sealed tube; | 100% |
In tetrahydrofuran at 20℃; for 24h; | 99% |
With triethylamine In dichloromethane at 0 - 20℃; for 2h; | 99% |
phenyl isothiocyanate
2-bromoaniline
1-(2-bromophenyl)-3-phenylthiourea
Conditions | Yield |
---|---|
In ethanol at 20℃; for 2h; | 100% |
In N,N-dimethyl-formamide Heating; | 99% |
With C64H52CaN6 In neat (no solvent) at 60℃; for 12h; Schlenk technique; Glovebox; Inert atmosphere; | 85% |
2-bromoaniline
p-trifluoromethyl-phenylisocyanate
1-(2-bromophenyl)-3-(4-(trifluoromethyl)phenyl)urea
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 3h; Inert atmosphere; | 100% |
In acetonitrile |
pivaloyl chloride
2-bromoaniline
N-(2-bromophenyl)-2,2-dimethylpropanamide
Conditions | Yield |
---|---|
In ethyl acetate at 85℃; | 100% |
With triethylamine In dichloromethane at 0 - 20℃; for 16h; | 100% |
With triethylamine In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
Stage #1: 2-bromoaniline With n-butyllithium In tetrahydrofuran; hexane at -40℃; Inert atmosphere; Stage #2: benzyl bromide In tetrahydrofuran; hexane at -60 - 20℃; Inert atmosphere; | 100% |
Stage #1: 2-bromoaniline With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Stage #2: benzyl bromide In tetrahydrofuran; hexane at -78 - 20℃; Further stages.; | 95% |
Stage #1: 2-bromoaniline With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere; Schlenk technique; Stage #2: benzyl bromide In tetrahydrofuran; hexane at 20℃; for 10h; Inert atmosphere; Schlenk technique; | 90% |
Conditions | Yield |
---|---|
for 0.5h; Heating; | 100% |
at 70℃; for 20h; | 100% |
With dmap In chloroform for 0.5h; Reflux; | 100% |
Conditions | Yield |
---|---|
In diethyl ether Ring cleavage; Substitution; | 100% |
In diethyl ether at 20℃; |
trimethylsilyl cyanide
N-ethoxycarbonyl-4-piperidone
2-bromoaniline
ethyl 4-(2-bromophenylamino)-4-cyano-1-piperidinecarboxylate
Conditions | Yield |
---|---|
Stage #1: trimethylsilyl cyanide; N-ethoxycarbonyl-4-piperidone; 2-bromoaniline With acetic acid for 40h; Stage #2: With ammonia In water | 100% |
In acetic acid at 20℃; for 112h; Condensation; modified Strecker reaction; | 94% |
2-(2-iodophenyl)acetonitrile
2-bromoaniline
2-{2'-amino-[1,1'-biphenyl]-2-yl}acetonitrile
Conditions | Yield |
---|---|
Stage #1: 2-bromoaniline With Pinacolborane; triethylamine; CyJohnPhos; palladium diacetate In 1,4-dioxane at 80℃; Stage #2: 2-(2-iodophenyl)acetonitrile With barium dihydroxide In 1,4-dioxane at 100℃; Suzuki-Miyaura coupling; Further stages.; | 100% |
Stage #1: 2-bromoaniline With palladium diacetate; triethylamine; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; CyJohnPhos In 1,4-dioxane at 25 - 80℃; Inert atmosphere; Stage #2: 2-(2-iodophenyl)acetonitrile With barium hydroxide octahydrate In 1,4-dioxane; water at 100℃; for 1h; Inert atmosphere; | 99% |
Stage #1: 2-bromoaniline With palladium diacetate; triethylamine; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; CyJohnPhos In 1,4-dioxane at 25 - 80℃; for 1h; Inert atmosphere; Stage #2: 2-(2-iodophenyl)acetonitrile With barium hydroxide octahydrate In 1,4-dioxane at 100℃; for 1h; | 99% |
Stage #1: 2-bromoaniline With palladium diacetate; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; CyJohnPhos In 1,4-dioxane at 80℃; for 1h; Stage #2: 2-(2-iodophenyl)acetonitrile With barium dihydroxide In 1,4-dioxane; water at 100℃; for 1h; Suzuki coupling; Further stages.; | 79% |
Stage #1: 2-bromoaniline With palladium diacetate; triethylamine; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; CyJohnPhos In 1,4-dioxane at 80℃; Stage #2: 2-(2-iodophenyl)acetonitrile With barium hydroxide octahydrate In 1,4-dioxane; water at 100℃; Suzuki Coupling; | 77% |
2-bromoaniline
Acetoxyacetyl chloride
acetic acid (2-bromo-phenylcarbamoyl)-methyl ester
Conditions | Yield |
---|---|
With pyridine In dichloromethane for 2h; | 100% |
With pyridine In dichloromethane at 20℃; for 2h; |
Conditions | Yield |
---|---|
With caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; palladium diacetate In 1,4-dioxane at 110℃; for 16h; | 100% |
With potassium hydroxide In neat (no solvent) at 90℃; for 7.5h; | 60% |
With tris(dibenzylideneacetone)dipalladium (0); sodium t-butanolate In 1,4-dioxane at 45℃; |
1-acetyl-4-piperidinone
2-bromoaniline
1-(4-(2-bromophenylamino)piperidin-1-yl)ethanone
Conditions | Yield |
---|---|
Stage #1: 1-acetyl-4-piperidinone; 2-bromoaniline With sodium tris(acetoxy)borohydride; acetic acid In toluene at 120℃; for 0.25h; Microwave irradiation; Stage #2: With water; sodium hydrogencarbonate In toluene | 100% |
Conditions | Yield |
---|---|
Stage #1: 4-fluoroboronic acid; 2-bromoaniline With potassium carbonate In 1,4-dioxane; water for 0.333333h; Inert atmosphere; Stage #2: With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In 1,4-dioxane; water at 100℃; | 100% |
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In 1,4-dioxane at 100℃; for 3h; Suzuki Coupling; | 94% |
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In 1,4-dioxane at 100℃; for 3h; | 94% |
2-bromoaniline
1-bromo-2-nitrosobenzene
Conditions | Yield |
---|---|
With potassium peroxomonosulphate In dichloromethane; water at 20℃; Inert atmosphere; | 100% |
With Oxone In dichloromethane; water at 20℃; Inert atmosphere; | 99% |
With Oxone In dichloromethane; water at 20℃; for 20h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 20℃; Inert atmosphere; | 100% |
With pyridine In dichloromethane at 0 - 20℃; | 98% |
With pyridine In dichloromethane at 0 - 20℃; | 98% |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 24h; Reflux; | 100% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 100℃; for 24h; Suzuki Coupling; Inert atmosphere; | 85% |
Conditions | Yield |
---|---|
With C11H8Cl4N2O3Pd; tetrabutylammomium bromide; potassium carbonate In methanol; water; N,N-dimethyl-formamide at 100℃; for 0.166667h; Suzuki Coupling; | 100% |
With bis-triphenylphosphine-palladium(II) chloride; tetrabutylammomium bromide; potassium carbonate In chloroform; water at 80 - 100℃; for 0.166667h; Suzuki Coupling; | 99% |
With 2-[5-(4-methylphenyl)isoxazol-3-yl]-5-(5-phenylisoxazol-3-yl)-1,3,4-oxadiazole·2PdCl2; tetrabutylammomium bromide; potassium carbonate In water; N,N-dimethyl-formamide at 100℃; for 0.0166667h; Suzuki Coupling; | 98% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 48h; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 48h; Inert atmosphere; | 100% |
Stage #1: 2-bromoaniline With lithium diisopropyl amide In tetrahydrofuran at 0℃; for 0.25h; Stage #2: benzyl bromide In tetrahydrofuran for 0.25h; Further stages; | 83% |
With N-ethyl-N,N-diisopropylamine In toluene for 24h; Reflux; | |
With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 120℃; for 24h; | 82 %Spectr. |
bis(trichloromethyl) carbonate
2-bromoaniline
2-bromophenyl isocyanate
Conditions | Yield |
---|---|
With triethylamine In dichloromethane | 100% |
Stage #1: bis(trichloromethyl) carbonate; 2-bromoaniline In dichloromethane at 20℃; for 0.5h; Stage #2: With triethylamine In dichloromethane at -35 - 20℃; for 2h; | 81% |
With triethylamine In toluene for 7h; Reflux; Cooling with ice; | 65.6% |
3-bromobenzoyl chloride
2-bromoaniline
2‐(3‐bromophenyl)benzo[d]oxazole
Conditions | Yield |
---|---|
With caesium carbonate; copper(l) iodide; 1,10-Phenanthroline In 1,4-dioxane at 120℃; for 24h; Product distribution / selectivity; Inert atmosphere; | 100% |
With caesium carbonate; copper(l) iodide; 1,10-Phenanthroline In 1,4-dioxane at 120℃; for 8h; | 76% |
Conditions | Yield |
---|---|
With pyridine; copper(I) bromide dimethylsulfide complex; sodium carbonate In acetonitrile at 75℃; for 48h; Inert atmosphere; solid phase reaction; | 100% |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene for 36h; Dean-Stark; Reflux; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With triethylamine In toluene at 20℃; for 19h; | 100% |
Conditions | Yield |
---|---|
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine at 125℃; | 99% |
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine at 125℃; | 88% |
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine at 125℃; | 88% |
2-Thiophenecarbonyl chloride
2-bromoaniline
thiophene-2-carboxylic acid (2-bromophenyl)amide
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 24h; | 99% |
In tetrahydrofuran at 20℃; for 24h; | 96% |
With triethylamine In dichloromethane at 0 - 20℃; | 84% |
In toluene | |
With triethylamine In dichloromethane at 20℃; for 3h; |
Cinnamoyl chloride
2-bromoaniline
E-N-(2-bromophenyl)-3-phenylpropenamide
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 24h; | 99% |
With potassium carbonate In water; acetone at 0℃; for 2h; | 97% |
With potassium carbonate In water; acetone at 0℃; for 2h; | 92% |
2-bromoaniline
trifluoroacetic anhydride
N-(2-bromophenyl)-2,2,2-trifluoroacetamide
Conditions | Yield |
---|---|
With sodium carbonate In diethyl ether for 24h; Ambient temperature; | 99% |
With triethylamine In dichloromethane at 0 - 20℃; | 89% |
With triethylamine In dichloromethane at 0 - 20℃; | 89% |
3-pyridinecarbonyl chloride
2-bromoaniline
N-(2-bromophenyl)-3-pyridinecarboxamide
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 24h; | 99% |
With pyridine at 0 - 20℃; Acylation; | |
With N,N-diethyl-N-isopropylamine In acetonitrile at 60℃; for 24h; Inert atmosphere; Schlenk technique; |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene Heating; | 99% |
at 120℃; | 70% |
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