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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Bromobenzoic Acid

Cas:88-65-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

2-Bromobenzoic acid CAS NO.88-65-3

Cas:88-65-3

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Bromobenzoic Acid

Cas:88-65-3

Min.Order:1

Negotiable

Type:Other

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Name 2-Bromobenzoic acid Molecular Structure Molecular Formula C7H5BrO2 Molecular Weight 2

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

2-Bromobenzoic acid Basic information Product Name: 2-Bromobenzoic acid Synonyms: RARECHEM AL BO 0014;O-BROMOBENZOIC ACID;2-BROMOBENZOIC ACID;2-bromo-benzoicaci;Benzoic acid, o-bromo-;be

2-Bromobenzoic acid_

Cas:88-65-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 88-65-3 with best quality

Cas:88-65-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

factory supply 99% 2-Bromobenzoic acid

Cas:88-65-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Leader Biochemical Group

About Product Details

China Biggest factory Supply High Quality 2-Bromobenzoic acid CAS 88-65-3

Cas:88-65-3

Min.Order:1 Kilogram

FOB Price: $1.0 / 5.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Bromobenzoic acid 88-65-3

Cas:88-65-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality 2-Bromobenzoic acid Basic information Product Name: 2-Bromobenzoic acid Synonyms: RARECHEM AL BO 0014;O-BROMOBENZOIC ACID;2-BROMOBENZOIC ACID;2-bromo

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:1 Pound

Negotiable

Type:Manufacturers

inquiry

Shanghai Minstar Chemical Co., Ltd

2-Bromobenzoic acid Chemical Properties Melting point 147-150 °C (lit.) Boiling point 86 °C(Press: 4-5 Torr) density 1,929 g/cm3 vapor pressure >1 mm Hg ( 20 °C) refractive index 1.6080 (estimate) Fp >100&deg

2-Bromobenzoic acid.

Cas:88-65-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-Bromobenzoic acid CAS:88-65-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interme

2-Bromobenzoic acid CAS:88-65-3

Cas:88-65-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:88-65-3

Cas:88-65-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Bromobenzoic Acid

Cas:88-65-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2-Bromobenzoic Acid

Cas:88-65-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-Bromobenzoic acid CAS NO.88-65-3

Cas:88-65-3

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality Appearance:White to light yellow crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermedia

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

benzoicacid,2-bromo-

Cas:88-65-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Wuhan BJM Pharm Inc.

Our company focuses on the future and the world, and will continue to devote itself to technological progress and the development of new products in the future, hoping to work hand in hand with new and old friends at home and abroad to create a bett

Manufacturer Supply High Quality 2-Bromobenzoic acid

Cas:88-65-3

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-Bromobenzoic acid CAS NO.88-65-3

Cas:88-65-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Bromobenzoic acid

Cas:88-65-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With water; sodium hydroxide In ethanol at 10 - 20℃; for 1.08333h;100%
With iodine; aluminium In acetonitrile at 80℃; for 18h;99%
1-(2-bromophenyl)-4,4,4-trifluorobutane-1,3-dione
23975-63-5

1-(2-bromophenyl)-4,4,4-trifluorobutane-1,3-dione

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With oxygen; sodium hydrogencarbonate In acetonitrile for 4h; Molecular sieve; Irradiation;96%
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With ruthenium trichloride; sodium hypochlorite; tetrabutylammomium bromide In 1,2-dichloro-ethane at 25℃; for 2h;95%
With ruthenium trichloride; sodium hypochlorite; tetrabutylammomium bromide In 1,2-dichloro-ethane at 25℃; for 2h; Rate constant; pH 9;95%
With potassium acetate In water93.2%
ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With oxygen; Langlois reagent In acetonitrile at 25℃; under 760.051 Torr; for 12h; Irradiation; Green chemistry;95%
With tert.-butylhydroperoxide; potassium tert-butylate In water at 60℃; for 5h;90%
With oxygen at 120℃; for 5h; Neat (no solvent);85%
o-bromobenzyl alcohol
18982-54-2

o-bromobenzyl alcohol

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With sodium bromate; sodium hydrogen sulfate In acetonitrile for 20h; Heating;95%
With Langlois reagent In acetonitrile at 25℃; for 12h; Irradiation; Sealed tube;91%
With 3,5-Lutidine; 4-acetylamino-2,2,6,6-tetramethylpiperidine-N-oxyl; sodium persulfate; tris(2,2'‐bipyridine)ruthenium(II) hexafluorophosphate In water; acetonitrile at 20℃; for 48h; Sealed tube; Irradiation;75%
2-bromostyrene
2039-88-5

2-bromostyrene

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
Stage #1: 2-bromostyrene With tert.-butylhydroperoxide; iron(III) chloride hexahydrate; sodium hydroxide In water at 80℃; for 10h;
Stage #2: With hydrogenchloride In water at 20℃;
95%
With Oxone; 2-iodo-3,4,5,6-tetramethylbenzoic acid In water; acetonitrile for 24h;81%
With Oxone In water; acetonitrile for 24h; Reflux;77%
1-(2-bromophenyl)-1,2-ethanediol

1-(2-bromophenyl)-1,2-ethanediol

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; potassium tert-butylate In water at 80℃; for 8h;94%
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

water
7732-18-5

water

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With potassium bromide; potassium acetate92.7%
2-(2-bromophenyl)-2-oxoacetaldehyde

2-(2-bromophenyl)-2-oxoacetaldehyde

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With iodine; dimethyl sulfoxide at 180℃; for 0.0833333h; Inert atmosphere; Microwave irradiation;92%
C12H13BrOS2

C12H13BrOS2

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With sodium hydroxide In water at 100℃; for 9h; Reflux; chemoselective reaction;92%
ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

A

o-bromobenzyl alcohol
18982-54-2

o-bromobenzyl alcohol

B

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
Stage #1: ortho-bromobenzaldehyde With potassium hydroxide for 0.0833333h; Cannizzaro Reaction; Milling; Inert atmosphere; Sealed tube; Green chemistry;
Stage #2: With hydrogenchloride In water for 0.0833333h; Green chemistry;
A 91%
B 90%
5-[(2-bromophenyl)methylene]-2,2-dimethyl-1,3-dioxane-4,6-dione
15795-61-6

5-[(2-bromophenyl)methylene]-2,2-dimethyl-1,3-dioxane-4,6-dione

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With oxone In water for 16h; Reflux;91%
2-bromo-N,N-diisopropylbenzamide
79839-66-0

2-bromo-N,N-diisopropylbenzamide

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With hydrogenchloride; zinc(II) chloride at 160℃; for 72h;90%
2-bromo-N-(2-(pyridin-2-yl)propan-2-yl)benzamide

2-bromo-N-(2-(pyridin-2-yl)propan-2-yl)benzamide

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With hydrogenchloride In water at 145℃; for 48h; Schlenk technique;89%
With hydrogenchloride; water at 145℃; for 48h;80%
2-bromophenyl methyl ketone
2142-69-0

2-bromophenyl methyl ketone

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With Oxone; trifluoroacetic acid In 1,4-dioxane for 10h; Reflux; Green chemistry;88%
With hydroxylamine hydrochloride; iodine In dimethyl sulfoxide at 100℃; for 5h;58%
1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

carbon monoxide
201230-82-2

carbon monoxide

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With C22H28Br2N4Pd; water; potassium carbonate In tetrahydrofuran at 100℃; under 750.075 Torr; for 24h; Autoclave;86%
With water; palladium diacetate; potassium carbonate at 20℃; under 760.051 Torr; for 12h;84%
With water; palladium diacetate; triethylamine; triphenylphosphine In 1,4-dioxane at 110℃; under 11251.1 Torr; for 2h; Flow reactor;70%
2-(2-bromophenyl)-2-hydroxyacetonitrile
52923-21-4, 1269472-47-0, 548478-30-4

2-(2-bromophenyl)-2-hydroxyacetonitrile

A

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

B

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
Stage #1: 2-(2-bromophenyl)-2-hydroxyacetonitrile With (η(6)-benzene)chloro[1,2-bis(diphenylphosphino)ethane]ruthenium(II) chloride In benzene at 120℃; for 24h; Inert atmosphere; Schlenk technique;
Stage #2: With water In dichloromethane; ethyl acetate; benzene for 24h;
A 81%
B 17%
1-Bromo-2-bromomethyl-benzene
3433-80-5

1-Bromo-2-bromomethyl-benzene

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With Oxone In water; acetonitrile for 24h; Reflux;80%
2,5-dibromobenzoic acid
610-71-9

2,5-dibromobenzoic acid

A

m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

B

benzoic acid
65-85-0

benzoic acid

C

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuranA 78%
B 13%
C 2%
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

A

1-Bromo-2-bromomethyl-benzene
3433-80-5

1-Bromo-2-bromomethyl-benzene

B

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper(ll) bromide In acetic anhydrideA 77%
B 10%
1-(Bis-tert-butylperoxy-methyl)-2-bromo-benzene
106914-56-1

1-(Bis-tert-butylperoxy-methyl)-2-bromo-benzene

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With piperidine In water at 90℃; for 3h;76%
2-b romo-N-(quinolin-8-yl)benzamide

2-b romo-N-(quinolin-8-yl)benzamide

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
Stage #1: 2-b romo-N-(quinolin-8-yl)benzamide With ozone In dichloromethane at -78℃; Inert atmosphere;
Stage #2: With lithium hydroxide monohydrate; dihydrogen peroxide In tetrahydrofuran; water at 20℃; for 24h; Inert atmosphere;
66%
benzoic acid
65-85-0

benzoic acid

A

2,6-dibromobenzoic acid
601-84-3

2,6-dibromobenzoic acid

B

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
Stage #1: With [bis(acetoxy)iodo]benzene; iodine In 1,2-dichloro-ethane at 20℃; for 1h;
Stage #2: benzoic acid With tetrabutylammomium bromide; palladium diacetate In 1,2-dichloro-ethane at 100℃; for 24h;
A n/a
B 65%
carbon dioxide
124-38-9

carbon dioxide

(2-bromophenyl)boronic acid
244205-40-1

(2-bromophenyl)boronic acid

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I); potassium methanolate In N,N-dimethyl acetamide at 70℃; for 24h; Schlenk technique; Sealed tube;65%
o-bromobenzyl alcohol
18982-54-2

o-bromobenzyl alcohol

A

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

B

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; [O-Cu4(triethanolamine)4(BOH)4][BF4]2 In acetonitrile at 69.84℃; for 6h;A 61.8%
B n/a
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; Ir(4,4'-di-tert-butyl-2,2'-bipyridyl)(2-phenylpyridine)2(PF6); tetrabutyl-ammonium chloride; oxygen; sodium hydrogencarbonate In dichloromethane; water at 20℃; for 48h; Reagent/catalyst; Solvent; Irradiation; Green chemistry; chemoselective reaction;A > 99 %Chromat.
B 9%
With oxygen; potassium carbonate In water at 80℃; for 48h;
4-(2-bromophenyl)but-3-en-2-one
72454-54-7

4-(2-bromophenyl)but-3-en-2-one

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With hydroxylamine hydrochloride; iodine In dimethyl sulfoxide at 100℃; for 6h;60%
1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

diphenylmethylsilanecarboxylic acid
18414-58-9

diphenylmethylsilanecarboxylic acid

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With potassium trimethylsilonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 60℃; Sealed tube;60%
benzoic acid
65-85-0

benzoic acid

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With 1,2-dibromo-1,1,2,2-tetrachloroethane; N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium In tetrahydrofuran; hexane; cyclohexane 1.) -90 deg C, 60 min, 2.) -78 deg C;55%
With 1,2-dibromo-1,1,2,2-tetrachloroethane; N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium In tetrahydrofuran 1.) -90 deg C, 30 min, 2.) -78 deg C;55%
With chlorosulfonic acid; bromine at 10℃; for 2.5h; Temperature; Inert atmosphere;
1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

carbon monoxide
201230-82-2

carbon monoxide

phenylboronic acid
98-80-6

phenylboronic acid

A

o-bromobenzophenone
13047-06-8

o-bromobenzophenone

B

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With C57H43IP2Pd; potassium carbonate In 1,4-dioxane at 90℃; under 3750.38 Torr; for 12h; carbonylative Suzuki coupling; Autoclave;A 50%
B n/a
1-(2-bromophenyl)-butane-1,3-dione
57279-20-6

1-(2-bromophenyl)-butane-1,3-dione

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Conditions
ConditionsYield
With oxygen; sodium hydrogencarbonate In acetonitrile for 4h; Molecular sieve; Irradiation;50%
2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-bromobenzoic acid chloride
7154-66-7

2-bromobenzoic acid chloride

Conditions
ConditionsYield
With thionyl chloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 3h;100%
Stage #1: 2-bromobenzoic-acid With oxalyl dichloride In dichloromethane at 20℃; for 0.0833333h;
Stage #2: With N,N-dimethyl-formamide In dichloromethane at 20℃; for 5h;
100%
With thionyl chloride In N,N-dimethyl-formamide at 70℃; Inert atmosphere;100%
2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-bromobenzoic anhydride
49619-44-5

2-bromobenzoic anhydride

Conditions
ConditionsYield
With trimethylsilylethoxyacetylene In dichloromethane at 20℃; for 3h;100%
With potassium carbonate In dichloromethane at 20℃; for 0.583333h;91%
With potassium carbonate; p-toluenesulfonyl chloride In acetonitrile at 20℃; for 2h;70%
anthranilic acid
118-92-3

anthranilic acid

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

Vanadox
579-92-0

Vanadox

Conditions
ConditionsYield
With copper(I) oxide; copper; potassium carbonate In N,N-dimethyl-formamide at 130℃; for 20h; Inert atmosphere;100%
With copper; potassium carbonate; copper(II) oxide In N,N-dimethyl-formamide at 130℃; for 20h;94%
With copper; potassium carbonate In N,N-dimethyl-formamide Jourdan-Ullmann reaction; Inert atmosphere; Reflux;91%
2-amino-3-methoxybenzoic acid
3177-80-8

2-amino-3-methoxybenzoic acid

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-(2-carboxyphenylamino)-3-methoxybenzoic acid
88377-32-6

2-(2-carboxyphenylamino)-3-methoxybenzoic acid

Conditions
ConditionsYield
With copper; potassium carbonate In ethanol for 1h; Reflux; Inert atmosphere;100%
With copper; potassium carbonate In ethanol for 1.5h; Reflux;5.07 g
With copper; potassium carbonate In ethanol for 1.5h; Reflux;
2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With dibromoisocyanuric acid In dichloromethane at 20℃; for 24h; Reagent/catalyst; Solvent; Temperature; UV-irradiation;100%
methanol
67-56-1

methanol

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Conditions
ConditionsYield
With sulfuric acid Reflux; Inert atmosphere;99%
With sulfuric acid Reflux;99%
With sulfuric acid at 0℃; for 20.25h; Fischer-Speier Esterification; Reflux;96%
phenylboronic acid
98-80-6

phenylboronic acid

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-Biphenylcarboxylic acid
947-84-2

2-Biphenylcarboxylic acid

Conditions
ConditionsYield
With trans-[PdBr2(1-n-butyl-3-(1-O-methyl-6-deoxy-α-D-glucopyrano-6-yl)imidazol-2-ylidene)2]; sodium methylate In water at 100℃; for 15h; Suzuki coupling;99%
With potassium carbonate In water at 50℃; for 1.5h; Suzuki Coupling;98%
With magnesium hydroxide; potassium hydroxide; barium(II) hydroxide; calcium hydroxide In water at 20℃; for 15h; Suzuki Coupling;98%
1,3-cylohexanedione
504-02-9

1,3-cylohexanedione

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-bromo-benzoic acid 3-oxo-cyclohex-1-enyl ester
252679-98-4

2-bromo-benzoic acid 3-oxo-cyclohex-1-enyl ester

Conditions
ConditionsYield
With 2-chloro-1-methyl-pyridinium iodide; triethylamine In tetrahydrofuran at 20℃; Acylation;99%
With 2-chloro-1-methyl-pyridinium iodide; triethylamine In tetrahydrofuran at 20℃; for 10h;99%
4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-<(4-methoxyphenyl)thio>benzoic acid
19862-91-0

2-<(4-methoxyphenyl)thio>benzoic acid

Conditions
ConditionsYield
With copper(I) oxide; copper; potassium carbonate In 2-ethoxy-ethanol at 130℃; for 4h;99%
Hexanethiol
111-31-9

Hexanethiol

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-(hexylthio)benzoic acid
15823-57-1

2-(hexylthio)benzoic acid

Conditions
ConditionsYield
With copper(I) oxide; copper; potassium carbonate In 2-ethoxy-ethanol at 130℃; for 12h;99%
thiophenol
108-98-5

thiophenol

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-(phenylthio)benzoic acid
1527-12-4

2-(phenylthio)benzoic acid

Conditions
ConditionsYield
With copper(I) oxide; copper; potassium carbonate In 2-ethoxy-ethanol at 130℃; for 4h;99%
With tetra(n-butyl)ammonium hydroxide In water at 80℃; for 48h; Inert atmosphere; Sealed tube; chemoselective reaction;87%
With copper(I) oxide; copper; potassium carbonate In 2-ethoxy-ethanol at 130℃; for 4h;76%
benzamidine monohydrochloride
1670-14-0

benzamidine monohydrochloride

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-phenyl-4(3H)-quinazolinone
1022-45-3

2-phenyl-4(3H)-quinazolinone

Conditions
ConditionsYield
With C26H24Cu2N8(2+)*2F6P(1-); caesium carbonate In N,N-dimethyl-formamide at 70℃; for 6h; Inert atmosphere; Sealed tube;99%
With caesium carbonate In N,N-dimethyl-formamide at 20℃; for 10h; Inert atmosphere; Sealed tube;95%
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 25℃; for 12h; Inert atmosphere;85%
3-nitro-aniline
99-09-2

3-nitro-aniline

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-bromo-N-(3-nitrophenyl)benzamide
316139-21-6

2-bromo-N-(3-nitrophenyl)benzamide

Conditions
ConditionsYield
Stage #1: 2-bromobenzoic-acid With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane for 20h; Inert atmosphere; Cooling with ice;
Stage #2: 3-nitro-aniline With pyridine In dichloromethane at 45℃; for 1h; Inert atmosphere;
99%
Stage #1: 2-bromobenzoic-acid With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide for 20h; Sealed tube; Inert atmosphere; Cooling with ice;
Stage #2: 3-nitro-aniline With pyridine In dichloromethane; N,N-dimethyl-formamide at 45℃; for 1h;
99%
p-tolylboronic pinacol ester
195062-57-8

p-tolylboronic pinacol ester

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

o-tolylbenzoic acid
7148-03-0

o-tolylbenzoic acid

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium hydroxide In neat (no solvent) at 110℃; for 24h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;99%
4-iodoanisol
529-28-2

4-iodoanisol

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

1-methoxyphenanthrene
834-99-1

1-methoxyphenanthrene

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; tricyclohexylphosphine In 1,4-dioxane at 130℃; for 18h; Schlenk technique; Sealed tube; Inert atmosphere;99%
bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

1-iodo-2-(trifluoromethoxy)benzene
175278-00-9

1-iodo-2-(trifluoromethoxy)benzene

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

1-(trifluoromethoxy)phenanthrene

1-(trifluoromethoxy)phenanthrene

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; tricyclohexylphosphine In 1,4-dioxane at 130℃; for 18h; Schlenk technique; Sealed tube; Inert atmosphere;99%
1-Fluoro-2-iodobenzene
348-52-7

1-Fluoro-2-iodobenzene

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

1-fluorophenanthrene
440-38-0

1-fluorophenanthrene

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; tricyclohexylphosphine In 1,4-dioxane at 130℃; for 18h; Schlenk technique; Sealed tube; Inert atmosphere;99%
ethyl 5-(2-iodophenoxy)pentanoic acid
132902-33-1

ethyl 5-(2-iodophenoxy)pentanoic acid

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

ethyl 5-(phenanthren-1-yloxy)pentanoate

ethyl 5-(phenanthren-1-yloxy)pentanoate

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; tricyclohexylphosphine In 1,4-dioxane at 130℃; for 18h; Schlenk technique; Sealed tube; Inert atmosphere;99%
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-((2-bromobenzyl)oxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-((2-bromobenzyl)oxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
In neat (no solvent) at 30℃; Inert atmosphere; Schlenk technique; Glovebox; chemoselective reaction;99%
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 In neat (no solvent) at 60℃; for 24h;
With (4-Me)Triaz(NHPiPr2)2Mn(CO)2Br In toluene at 25℃; for 6h; Catalytic behavior; Inert atmosphere; chemoselective reaction;> 99 %Spectr.
2-(2-iodophenyl)-1-methyl-1H-indole

2-(2-iodophenyl)-1-methyl-1H-indole

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

9-methyl-9H-dibenzo[a,c]carbazole
54880-07-8

9-methyl-9H-dibenzo[a,c]carbazole

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate; p-benzoquinone In dimethyl sulfoxide at 140℃; for 9h; Schlenk technique; Inert atmosphere;99%
2-isopropyliodobenzene
19099-54-8

2-isopropyliodobenzene

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

1-isopropyltriphenylene

1-isopropyltriphenylene

Conditions
ConditionsYield
With norborn-2-ene; bis-triphenylphosphine-palladium(II) chloride; potassium carbonate; p-benzoquinone In dimethyl sulfoxide at 140℃; for 3h; Schlenk technique; Inert atmosphere;99%
ethyl acetoacetate
141-97-9

ethyl acetoacetate

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-(ethoxycarbonylmethyl)benzoic acid
22479-46-5

2-(ethoxycarbonylmethyl)benzoic acid

Conditions
ConditionsYield
Stage #1: ethyl acetoacetate With sodium ethanolate In ethanol at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: 2-bromobenzoic-acid With copper(I) bromide In ethanol at 80℃; for 16h; Inert atmosphere;
98%
With sodium ethanolate; copper
Indole-3-carboxaldehyde
487-89-8

Indole-3-carboxaldehyde

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

N-(o-bromobenzoyl)indole-3-carboxaldehyde

N-(o-bromobenzoyl)indole-3-carboxaldehyde

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In tetrahydrofuran Ambient temperature;98%
Thiosalicylic acid
147-93-3

Thiosalicylic acid

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2,2'-thiodibenzoic acid
22219-02-9

2,2'-thiodibenzoic acid

Conditions
ConditionsYield
With potassium carbonate; copper In water at 130 - 140℃; for 3h; Product distribution / selectivity; Ullmann Condensation;98%
With copper; potassium carbonate In water at 130 - 140℃; for 3h;96%
With potassium carbonate In water52.8 g (97%)
2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

salicylic acid
69-72-7

salicylic acid

Conditions
ConditionsYield
Stage #1: 2-bromobenzoic-acid With water; sodium carbonate for 1h; Heating / reflux;
Stage #2: With water; trans-N,N'-dimethyl-1,2-cyclohexyldiamine; copper(ll) bromide at 80℃; for 1h;
Stage #3: With hydrogenchloride In water at 25℃; Product distribution / selectivity;
98%
Stage #1: 2-bromobenzoic-acid With water; sodium carbonate for 1h; Heating / reflux;
Stage #2: trans-N,N'-dimethyl-1,2-cyclohexyldiamine; copper(I) bromide In acetonitrile at 80℃; for 2h;
Stage #3: With hydrogenchloride In water; acetonitrile at 25℃; Product distribution / selectivity;
98%
Stage #1: 2-bromobenzoic-acid With water; sodium carbonate at 80℃;
Stage #2: With water; trans-N,N'-dimethyl-1,2-cyclohexyldiamine; copper(I) bromide In water; acetonitrile at 80℃; for 3h;
Stage #3: With hydrogenchloride In water; acetonitrile at 20℃; Product distribution / selectivity;
96%
1-(pyridin-2-yl)hept-2-yn-1-ol
934399-67-4

1-(pyridin-2-yl)hept-2-yn-1-ol

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

C19H18BrNO2
1256742-75-2

C19H18BrNO2

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0 - 20℃;98%
[3-(methoxycarbonyl)phenyl]boronic acid
99769-19-4

[3-(methoxycarbonyl)phenyl]boronic acid

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

3'-(methoxycarbonyl)-[1,1'-biphenyl]-2-carboxylic acid
171905-91-2

3'-(methoxycarbonyl)-[1,1'-biphenyl]-2-carboxylic acid

Conditions
ConditionsYield
With palladium bis[bis(diphenylphosphino)ferrocene] dichloride; potassium carbonate In chloroform; water at 80 - 100℃; for 0.25h; Suzuki Coupling;98%
With PdCl2-[5-(naphth-1-yl)isoxazole-3-carbaldehyde oxime]; potassium carbonate In methanol; water at 100℃; for 0.166667h; Suzuki Coupling;97%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

1-methylphenanthrene
832-69-9

1-methylphenanthrene

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; tricyclohexylphosphine In 1,4-dioxane at 130℃; for 18h; Catalytic behavior; Reagent/catalyst; Solvent; Schlenk technique; Sealed tube; Inert atmosphere;98%
2-iodo-5-methylthiophene
16494-36-3

2-iodo-5-methylthiophene

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

2-methylnaphtho[2,1-b]thiophene
16587-35-2

2-methylnaphtho[2,1-b]thiophene

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; tricyclohexylphosphine In 1,4-dioxane at 130℃; for 18h; Schlenk technique; Sealed tube; Inert atmosphere;98%

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