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Dayang Chem (Hangzhou) Co.,Ltd.

Hangzhou DaAppearance:white powder Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:LED intermediates Transportation:by sea or by air Port:Shanghai

High purity 4-Bromobiphenyl TOP1 supplier in China

Cas:92-66-0

Min.Order:1 Kilogram

FOB Price: $123.0

Type:Lab/Research institutions

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HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Pharm intermediate

P-Bromobiphenyl

Cas:92-66-0

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------

High purity 92-66-0 4-Bromobiphenyl

Cas:92-66-0

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Bromobi Pheny1 supplier in China

Cas:92-66-0

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name 4-Bromobiphenyl CAS number 92-66-0 Assay ≥99% Appearance White crystalline powder Capacity 200mt/year Application OLED/pharmaceutical/pestic

4-Bromobiphenyl

Cas:92-66-0

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

T he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality service Appearance:s

4-Bromobiphenyl

Cas:92-66-0

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hangzhou Think Chemical Co. Ltd

4-Bromobiphenyl CAS No.:92-66-0 Name: 4-Bromobiphenyl Molecular Structure: Molecular Formula: C12H9Br Molecular Weight: 233.11 CAS Registry Number: 92-66-0 EINECS: 202

High purity 4-Bromobiphenyl CAS No.:92-66-0

Cas:92-66-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Bromobi Pheny1

Cas:92-66-0

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 92-66-0 4-Bromobiphenyl Manufacturer

Cas:92-66-0

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Bromobiphenyl

Cas:92-66-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--92-66-0--4-Bromobiphenyl factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relation

TIANFUCHEM--92-66-0--4-Bromobiphenyl factory price

Cas:92-66-0

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. High quality and competitive price: 1) Standard: BP/USP/EP/ enterprise standard 2) All purity ≥99% 3) We are manufacturers and can provide high quality products at factory prices. 2. Fast and safe delivery 1) The package c

4-BromobiphenylCAS 92-66-0

Cas:92-66-0

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 92-66-0 with best price

Cas:92-66-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

4-Bromobiphenyl CAS92-66-0

Cas:92-66-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 100.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name:4-Bromobiphenyl CAS No:92-66-0 Appearance: White crystals Content:99%min Appearance:White crystals Storage:Store in cool and dry place, away from sun light. Package:25kg/dr

4-Bromobiphenyl CAS:92-66-0

Cas:92-66-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White powder Storage:Store in sealed containers at cool & dr

high quality 4-bromobiphenyl CAS 92-66-0 with best price

Cas:92-66-0

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,1'-Biphenyl,4-bromo- 92-66-0

Cas:92-66-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: 4-Bromobiphenyl CAS: 92-66-0 MF: C12H9Br MW: 233.1 EINECS: 202-176-6 Mol File: 92-66-0.mol 4-Bromobiphenyl Structure 4-Bromobiphenyl Chemical Properties Melting point 82-86 °C(lit.) Boiling point 310 &deg

4-Bromobiphenyl

Cas:92-66-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,5KGS,10KGS,25

High quality 4-Bromobiphenyl with lowest price CAS No.92-66-0

Cas:92-66-0

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

4-Bromobiphenyl

Cas:92-66-0

Min.Order:1 Kilogram

FOB Price: $75.0 / 80.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supply High-quality 4-Bromobiphenyl CAS 92-66-0 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made in China a

High-quality 4-Bromobiphenyl CAS 92-66-0

Cas:92-66-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-Bromobiphenyl

Cas:92-66-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

Name: 4-Bromobiphenyl Synonyms: M-6252; LS-1936; PS-7682; LS10223; RL05835; KB-37356; SC-25958; AC-10043; pbb-no 3; EBD53453; Q-200446; ZB015430; AJ-24496; PBB NO 3; cid_7101; AN-42610; CJ-04610; BC003379; AC1Q26V4; AC1Q24P5; TL806159; I14-1827; AC1L

4-Bromobiphenyl 92-66-0

Cas:92-66-0

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:92-66-0

Cas:92-66-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Triumph International Development Limilted

Lorcaserin(856681-05-5)is an orally administered agent and a selective 5-HT2C receptor agonist for the treatment of obesity. It had been approved for marketing in US by FDA on 27 June in 2012. In clinical studies, lorcaserin h

4-Bromobiphenyl

Cas:92-66-0

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

4-Bromobiphenyl

Cas:92-66-0

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Bromobiphenyl

Cas:92-66-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

4-BROMOBIPHENYL

Cas:92-66-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-bromobiphenyl

Cas:92-66-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

4-Bromobiphenyl

Cas:92-66-0

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Synthetic route

C68H84N4Ni2

C68H84N4Ni2

chlorobenzene
108-90-7

chlorobenzene

A

(μ-Cl)2Ni2(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)2

(μ-Cl)2Ni2(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)2

B

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

C

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 21h;A 100%
B n/a
C n/a
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With sodium carbonate In 1-methyl-pyrrolidin-2-one at 100℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere;99%
With potassium carbonate In water at 90℃; for 1h; Suzuki-Miyaura coupling; chemoselective reaction;98%
With potassium carbonate In ethanol; water at 80℃; for 0.583333h; Catalytic behavior; Suzuki-Miyaura Coupling;96%
4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With sodium nitrite In acetonitrile at 80℃; for 1h; Sealed tube;99%
With N-Bromosuccinimide In acetonitrile at 80℃; for 12h;98%
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; Sealed tube;88%
With N-Bromosuccinimide; potassium acetate In acetonitrile at 50℃; for 4h;85%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

bis(4-bromophenyl)iodonium bromide
65826-67-7

bis(4-bromophenyl)iodonium bromide

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
palladium dichloride In water for 0.00555556h; Suzuki coupling; microwave irradiation;97%
for 0.0833333h; Suzuki coupling; microwave irradiation;94%
In water at 100℃; for 0.05h; Suzuki coupling reaction; microwave irradiation;91%
In water at 100℃; for 0.05h; Suzuki coupling; microwave irradiation;91%
1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 50℃; for 2.5h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;97%
With potassium carbonate In ethanol; water at 100℃; for 1.5h; Suzuki-Miyaura Coupling; Green chemistry;94%
With potassium carbonate In ethanol at 80℃; for 3h; Suzuki-Miyaura Coupling; Schlenk technique;92%
bromochlorobenzene
106-39-8

bromochlorobenzene

phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With C84H60Cl6Fe3N6Pd3; triethylamine at 20℃; for 0.383333h;97%
With sodium carbonate In water at 80℃; for 4.5h; Catalytic behavior; Suzuki Coupling; Green chemistry;90%
With tetrabutylammomium bromide In ethanol; water at 90℃; for 0.666667h; Catalytic behavior; Suzuki Coupling; Inert atmosphere;84%
With potassium carbonate In ethanol; water at 50℃; for 12h; Catalytic behavior; Suzuki-Miyaura Coupling; Green chemistry;65%
bromochlorobenzene
106-39-8

bromochlorobenzene

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With sodium carbonate In water at 80℃; for 4.16667h; Catalytic behavior; Suzuki Coupling; Green chemistry;93%
sodium 4-bromobenzenesulfinate
34176-08-4

sodium 4-bromobenzenesulfinate

phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With copper diacetate; palladium dichloride In dimethyl sulfoxide; acetonitrile at 90℃; for 2h;92%
iodobenzene
591-50-4

iodobenzene

4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With tetrabutylammomium bromide; nickel; sodium carbonate In ethanol at 80℃; for 6h; Suzuki-Miyaura reaction;91%
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 1h; Suzuki Coupling;85%
With aluminum oxide; potassium fluoride; palladium for 0.0333333h; Suzuki reaction; Heating; microwave irradiation;80%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

2-phenyl-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
24341-81-9

2-phenyl-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium tert-butylate; triphenylphosphine In tetrahydrofuran; toluene at 70℃; for 24h; Suzuki-Miyaura Coupling;91%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

tributylphenylstannane
960-16-7

tributylphenylstannane

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With copper(l) iodide; triphenyl-arsane; 1-butyl-3-methylimidazolium Tetrafluoroborate; bis(benzonitrile)palladium(II) dichloride at 80℃; for 18h; Stille coupling;90%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

triphenylindium
3958-47-2

triphenylindium

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran for 2h; Heating;90%
With 3-aminopropyl-functionalized silica supported MCM-41-immobilized palladium(0)-[(pyridin-2-yl)methylidene]amine complex In tetrahydrofuran at 68℃; for 2h; Inert atmosphere;87%
tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Heating;
tributylphenylstannane
960-16-7

tributylphenylstannane

4-Bromobenzenediazonium o-benzenedisulfonimide

4-Bromobenzenediazonium o-benzenedisulfonimide

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
palladium diacetate In tetrahydrofuran at 20℃; for 1h; Stille reaction;90%
4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

benzenesufonyl hydrazide
80-17-1

benzenesufonyl hydrazide

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tert-butyl methyl ether at 60℃; for 6h; Suzuki Coupling;90%
4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With copper diacetate; palladium dichloride In dimethyl sulfoxide; acetonitrile at 90℃; for 2h;90%
p-bromodibenzoyl peroxide
1712-82-9

p-bromodibenzoyl peroxide

benzene
71-43-2

benzene

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
at 100℃; for 12h; Sealed tube;90%
trimethylphenylsilane
768-32-1

trimethylphenylsilane

4-bromobenzenediazonium tetrafluoroborate
673-40-5

4-bromobenzenediazonium tetrafluoroborate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) In acetonitrile at -78 - 20℃; Inert atmosphere; Irradiation;90%
o-benzenedisulfonimide
4482-01-3

o-benzenedisulfonimide

4-bromo-aniline
106-40-1

4-bromo-aniline

phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
Stage #1: o-benzenedisulfonimide; 4-bromo-aniline With acetic acid at 0 - 5℃; for 0.166667h; Inert atmosphere;
Stage #2: With isopentyl nitrite for 0.166667h; Inert atmosphere;
Stage #3: phenylboronic acid With bis[(trifluoromethanesulfonyl)imidate]-2-(dicyclohexyl(2’,6’-dimethoxybiphenyl))phosphine gold(I); caesium carbonate In tetrahydrofuran at 20℃; for 2h; Suzuki-Miyaura Coupling; Inert atmosphere; chemoselective reaction;
90%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

biphenyl
92-52-4

biphenyl

Conditions
ConditionsYield
With hydrogen In methanol at 20℃; for 24h;100%
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In tetrahydrofuran at -50℃; for 0.5h;
Stage #2: With phenylacetonitrile In tetrahydrofuran at -50 - 20℃; for 0.5h; Further stages;
99%
With [RhCl2(p-cymene)]2; potassium tert-butylate In isopropyl alcohol at 20 - 100℃; for 24h; Inert atmosphere;97%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

phenylboronic acid
98-80-6

phenylboronic acid

[1,1';4',1'']terphenyl
92-94-4

[1,1';4',1'']terphenyl

Conditions
ConditionsYield
With potassium phosphate; naphthidine di(radical cation)s-stabilized Pd nanoparticles In 1,4-dioxane at 80℃; for 5h; Suzuki-Miyaura cross-coupling reaction;100%
With potassium carbonate; [1,1'-bis{(S)-4-isopropyloxazolin-2-yl}ferrocene]Pd(II)Cl2 In toluene at 60℃; for 2h; Suzuki cross-coupling reaction;99%
With potassium phosphate; Pd (sulfur-containing palladacycle); tetra(n-tert-butyl)ammonium bromide In N,N-dimethyl-formamide at 130℃; for 2h; Suzuki cross-coupling;99%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-methoxy-phenol
150-76-5

4-methoxy-phenol

4-(4-methoxyphenoxy)-1,1'-biphenyl
40843-54-7

4-(4-methoxyphenoxy)-1,1'-biphenyl

Conditions
ConditionsYield
With copper(l) iodide; N,N-dimethylglycine hydrochoride; caesium carbonate In 1,4-dioxane at 90℃; for 18h; Product distribution / selectivity;100%
With copper(l) iodide; N,N-dimethylglycine hydrochoride; caesium carbonate In 1,4-dioxane at 90℃;91%
With silver(I) hexafluorophosphate; rhodium(II) acetate dimer; N,N-dicyclohexylbenzimidazolium hexafluorophosphate; sodium t-butanolate In toluene at 100℃; for 24h;60%
With potassium phosphate; (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; [nickel(II) (4,4'-di-tert-butyl-2,2'-bipyridine)(bromide)2] at 25℃; for 36h; Schlenk technique; Inert atmosphere; Sealed tube; Irradiation;50%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

1,3-diphenylisobenzofuran
5471-63-6

1,3-diphenylisobenzofuran

2-phenyl-9,10-diphenyl-9,10-epoxyanthracene
1006715-11-2

2-phenyl-9,10-diphenyl-9,10-epoxyanthracene

Conditions
ConditionsYield
With Me2Zn(TMP)Li In tetrahydrofuran at 20℃; for 6h;100%
azetidine-3-ol
45347-82-8

azetidine-3-ol

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

1-biphenyl-4-yl-3-hydroxylcyclobutylamine
1380499-22-8

1-biphenyl-4-yl-3-hydroxylcyclobutylamine

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; CVT-2537 In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere;100%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

2-methyl-1,1’:4’,1’’-terphenyl
31158-32-4

2-methyl-1,1’:4’,1’’-terphenyl

Conditions
ConditionsYield
Stage #1: 2-Methylphenylboronic acid With potassium phosphate; 2C2F6NO4S2(1-)*C44H66Cl2N2P2Pd(2+); 1-butyl-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide In water at 65℃; Suzuki-Miyaura reaction; Inert atmosphere;
Stage #2: 4-bromo-1,1'-biphenyl In water at 65℃; for 2h; Suzuki-Miyaura reaction; Inert atmosphere;
99%
With potassium phosphate; water In toluene at 100℃; for 1h; Suzuki coupling reaction;85%
With potassium carbonate In ethanol; water at 70℃; for 14h; Suzuki coupling;70%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

tributyltin chloride
1461-22-9

tributyltin chloride

[1,1′-biphenyl]-4-yltributylstannane
51533-89-2

[1,1′-biphenyl]-4-yltributylstannane

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h;
Stage #2: tributyltin chloride In tetrahydrofuran; hexane at -78℃; for 1h;
99%
With n-butyllithium In water78%
4,4-dimethylcyclohexenone
1073-13-8

4,4-dimethylcyclohexenone

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-(4,4-dimethylcyclohexa-1,5-dienyl)biphenyl
1263002-06-7

4-(4,4-dimethylcyclohexa-1,5-dienyl)biphenyl

Conditions
ConditionsYield
Stage #1: 4,4-dimethylcyclohexenone With tris-(dibenzylideneacetone)dipalladium(0); toluene-4-sulfonic acid hydrazide; lithium tert-butoxide; XPhos In 1,4-dioxane for 0.0166667h; Inert atmosphere;
Stage #2: 4-bromo-1,1'-biphenyl In 1,4-dioxane at 110℃; Inert atmosphere;
99%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

[(TMEDA)NiBr(C6H4Ph)]

[(TMEDA)NiBr(C6H4Ph)]

Conditions
ConditionsYield
In toluene at 23℃; for 2h;99%
potassium cyanate
590-28-3

potassium cyanate

carbon monoxide
201230-82-2

carbon monoxide

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

isopropyl alcohol
67-63-0

isopropyl alcohol

isopropyl biphenylcarbonylcarbamate

isopropyl biphenylcarbonylcarbamate

Conditions
ConditionsYield
With dichloro(1,5-cyclooctadiene)palladium(II); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene at 70℃; for 8h;99%
2,2-dichloropropane
594-20-7

2,2-dichloropropane

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

dimethyl(4-biphenyl)silyl chloride
41081-31-6

dimethyl(4-biphenyl)silyl chloride

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In diethyl ether; hexane at -78 - 20℃; for 3h; Schlenk technique; Glovebox;
Stage #2: 2,2-dichloropropane In diethyl ether; hexane at -78 - 20℃; for 15h; Schlenk technique; Glovebox;
99%

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