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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.

High purity 4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Biphenyl Boronic Acid supplier in China

Cas:5122-94-1

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production 2-phenylacetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carbon environ

4-Biphenylboronic acid CAS NO.5122-94-1

Cas:5122-94-1

Min.Order:100 Gram

FOB Price: $2.0

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

Factory supply 4-Biphenylboronic acid CAS 5122-94-1 with good quality Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed

Factory supply 4-Biphenylboronic acid CAS 5122-94-1 with good quality

Cas:5122-94-1

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 5122-94-1 4-Biphenylboronic acid Manufacturer

Cas:5122-94-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

5122-94-1 4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

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Leader Biochemical Group

About Product Details

China Biggest factory Manufacturer Supply High Quality 4-Biphenylboronic acid CAS 5122-94-1

Cas:5122-94-1

Min.Order:1 Kilogram

FOB Price: $1.0 / 5.0

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name 4-Biphenylboronic acid CAS No. 51

4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:1 Gram

FOB Price: $53.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

4-Biphenylboronic acid CAS NO 5122-94-1

Cas:5122-94-1

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Pure CAS 5122-94-1 with best quality

Cas:5122-94-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name 4-Biphenylboronic acid/[1,1'-Biphenyl]-4-ylboronic acid CAS NO. 5122-94-1 Molecular Formula C12H11BO2 Molecular Weight 198.03

4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:liquid Storage:Store in sealed containers at cool & dry plac

Hot sale CAS 5122-94-1 4-Biphenyl Boronic Acid

Cas:5122-94-1

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Boronicacid, B-[1,1'-biphenyl]-4-yl- 5122-94-1

Cas:5122-94-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

4-Biphenylboronic acid CAS:5122-94-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

4-Biphenylboronic acid CAS:5122-94-1

Cas:5122-94-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Boronicacid, B-[1,1'-biphenyl]-4-yl-

Cas:5122-94-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Boronicacid, B-[1,1'-biphenyl]-4-yl-/ LIDE PHARMA- Factory supply / Best price

Cas:5122-94-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Boronicacid, B-[1,1'-biphenyl]-4-yl-

Cas:5122-94-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

4-Biphenylboronic acid 5122-94-1

Cas:5122-94-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Biphenyl Boronic Acid

Cas:5122-94-1

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

BIPHENYL-4-YLBORONIC ACID

Cas:5122-94-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:0 Metric Ton

Negotiable

Type:Other

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als

4-Biphenylboronic acid

Cas:5122-94-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Synthetic route

4-bromophenylboronic acid MIDA ester

4-bromophenylboronic acid MIDA ester

phenylboronic acid
98-80-6

phenylboronic acid

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; water In tetrahydrofuran at 90℃; for 4h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube; Microwave irradiation;95%
Trimethyl borate
121-43-7

Trimethyl borate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2.5h;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃;
Stage #3: With hydrogenchloride In tetrahydrofuran; hexane at 20℃; for 1h; Further stages.;
86%
With hydrogenchloride; n-butyllithium In tetrahydrofuran soln. of n-BuLi in hexanes added dropwise to soln. of bipyridyl compd. at -78°C, stirred at this temp. for 2.5 h, soln. of borate added over 30 min, allowed to warm to room temp. overnight, 10% aq. HCl added, stirred for 1 h at room temp.; extd. into Et2O, washed with concd. soln. of Na2CO3 then with H2O, evapd., recrystd. from H2O/EtOH (95/5), dried in vac. overnight at 60°C;86%
With hydrogenchloride; n-butyllithium In tetrahydrofuran; hexane BuLi soln. (hexane) addn. to biphenylbromide soln. (THF), mixt. stirring1 h, mixt. addn. to B-compd. soln. (THF) via canula (N2) at -78° C., stirring 1 h, gradual warming to room temp., aq. HCl addn., stirringat room temp. 15 h, solvent removal; under reduced pressure, Et2O addn., org. layer sepn., drying (MgSO4), soln. concn.. oil triturating with hexane, solid repptn. from MeOH/H2O;40%
Stage #1: 4-bromo-1,1'-biphenyl With diisobutylaluminium hydride; magnesium; lithium chloride In tetrahydrofuran; toluene at 0℃; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran; toluene at 0℃; Inert atmosphere;
C18H14B2Br2O6(2-)*2K(1+)

C18H14B2Br2O6(2-)*2K(1+)

phenylboronic acid
98-80-6

phenylboronic acid

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 50℃; for 5h; Inert atmosphere;86%
Triisopropyl borate
5419-55-6

Triisopropyl borate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

water
7732-18-5

water

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2.5h; Inert atmosphere;
Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 2h; Inert atmosphere;
Stage #3: water With hydrogenchloride In tetrahydrofuran; hexane Inert atmosphere;
85%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1.5h; Inert atmosphere;
Stage #2: With Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 4.5h;
Stage #3: With water In tetrahydrofuran; hexane; ethyl acetate
84%
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2.5h;
Stage #2: With Triisopropyl borate In tetrahydrofuran; hexane at -78 - 20℃;
76%
Stage #1: 4-bromo-1,1'-biphenyl With magnesium In tetrahydrofuran for 4h; Heating;
Stage #2: With Trimethyl borate In tetrahydrofuran at 0 - 20℃;
67%
methanol
67-56-1

methanol

diisopropylamine borane
55124-35-1

diisopropylamine borane

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
Stage #1: diisopropylamine borane With magnesium; phenylmagnesium bromide In tetrahydrofuran at 20℃; for 0.166667h;
Stage #2: 4-bromo-1,1'-biphenyl In tetrahydrofuran at 70℃;
Stage #3: methanol Further stages;
78%
Triisopropyl borate
5419-55-6

Triisopropyl borate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In diethyl ether; hexane at -78℃; for 0.5h;
Stage #2: Triisopropyl borate In diethyl ether; hexane at -78 - 20℃;
74%
With n-butyllithium In tetrahydrofuran1.53 g (90%)
2-([1,1'-biphenyl]-4-yl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione
1104636-67-0

2-([1,1'-biphenyl]-4-yl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With 2,3-dimethyl-2,3-butane diol; water In tetrahydrofuran at 90℃; for 1h; Inert atmosphere;74%
boric acid tributyl ester
688-74-4

boric acid tributyl ester

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

water
7732-18-5

water

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In tetrahydrofuran at -85 - -80℃; for 1h; Inert atmosphere;
Stage #2: boric acid tributyl ester In tetrahydrofuran at -85 - -80℃; for 2h; Inert atmosphere;
Stage #3: water With hydrogenchloride In tetrahydrofuran for 0.0833333h; Inert atmosphere;
70%
2-(4-bromophenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

2-(4-bromophenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

phenylboronic acid
98-80-6

phenylboronic acid

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; water In tetrahydrofuran at 90℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube; chemoselective reaction;63%
2-(biphenyl-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
144432-80-4

2-(biphenyl-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With boric acid In acetonitrile at 80℃; for 16h; Sealed tube;32%
para-bromoacetophenone
99-90-1

para-bromoacetophenone

phenylboronic acid
98-80-6

phenylboronic acid

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With C40H28N12Pd4S12; potassium carbonate In ethanol at 80℃; for 6h; Inert atmosphere;8%
boric acid tributyl ester
688-74-4

boric acid tributyl ester

4-biphenylylmagnesium bromide
3315-91-1

4-biphenylylmagnesium bromide

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With diethyl ether at -70℃; und anschliessenden Hydrolyse;
4-iodo-biphenyl
1591-31-7

4-iodo-biphenyl

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
(i) nBuLi, (ii) B(OiBu)3, (iii) aq. HCl; Multistep reaction;
2,4,6-tris([1,1'-biphenyl]-4-yl)boroxine
105123-35-1

2,4,6-tris([1,1'-biphenyl]-4-yl)boroxine

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With water In chloroform-d1 at 25℃; Equilibrium constant; Thermodynamic data;
C14H15BO2

C14H15BO2

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride for 3h; pH=6 - 7;
With water; sodium hydroxide In tetrahydrofuran
triethyl borate
150-46-9

triethyl borate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With tert.-butyl lithium In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: triethyl borate In tetrahydrofuran at -78 - 20℃; Further stages.;
800 mg
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium phosphate; water / tetrahydrofuran / 24 h / 18 °C / Inert atmosphere; Sealed tube
2: 2,3-dimethyl-2,3-butane diol; water / tetrahydrofuran / 1 h / 90 °C / Inert atmosphere
View Scheme
2-(4-bromophenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

2-(4-bromophenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium phosphate; water / tetrahydrofuran / 24 h / 18 °C / Inert atmosphere; Sealed tube
2: 2,3-dimethyl-2,3-butane diol; water / tetrahydrofuran / 1 h / 90 °C / Inert atmosphere
View Scheme
water
7732-18-5

water

C14H15BO2

C14H15BO2

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran for 0.5h; Inert atmosphere;1.82 g
Triisopropyl borate
5419-55-6

Triisopropyl borate

C17H18O2Zn

C17H18O2Zn

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With copper(I) iodide-lithium chloride In tetrahydrofuran at 20℃; Schlenk technique; Inert atmosphere;
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
ConditionsYield
With potassium tert-butylate In methanol at 0 - 20℃;
4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

9,15-bis(trifluoromethylsulfonyloxy)<212,13><5.2>metacyclophane
135019-26-0

9,15-bis(trifluoromethylsulfonyloxy)<212,13><5.2>metacyclophane

C45H40

C45H40

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 110 - 120℃; for 24h; Suzuki coupling reaction;100%
4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

6-bromo-5-isopropyl-3-methylpyrazine-2-carboxylic acid ethyl ester
816458-62-5

6-bromo-5-isopropyl-3-methylpyrazine-2-carboxylic acid ethyl ester

6-(biphenyl-4-yl)-5-isopropyl-3-methylpyrazine-2-carboxylic acid ethyl ester

6-(biphenyl-4-yl)-5-isopropyl-3-methylpyrazine-2-carboxylic acid ethyl ester

Conditions
ConditionsYield
With caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In toluene at 90℃; for 1.5h; Suzuki coupling;100%
4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

6-bromo-5-isopropyl-3-phenylpyrazine-2-carboxylic acid ethyl ester
816458-63-6

6-bromo-5-isopropyl-3-phenylpyrazine-2-carboxylic acid ethyl ester

6-(biphenyl-4-yl)-5-isopropyl-3-phenylpyrazine-2-carboxylic acid ethyl ester

6-(biphenyl-4-yl)-5-isopropyl-3-phenylpyrazine-2-carboxylic acid ethyl ester

Conditions
ConditionsYield
With caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In toluene at 90℃; Suzuki coupling;100%
trifluoro-methanesulfonic acid 3,5-dichloro-4-[3-(4,4-difluoro-piperidin-1-yl)-2-oxo-pyrrolidin-1-ylmethyl]-phenyl ester
956319-50-9

trifluoro-methanesulfonic acid 3,5-dichloro-4-[3-(4,4-difluoro-piperidin-1-yl)-2-oxo-pyrrolidin-1-ylmethyl]-phenyl ester

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

1-(3,5-dichloro-[1,1';4',1'']terphenyl-4-ylmethyl)-3-(4,4-difluoro-piperidin-1-yl)-pyrrolidin-2-one

1-(3,5-dichloro-[1,1';4',1'']terphenyl-4-ylmethyl)-3-(4,4-difluoro-piperidin-1-yl)-pyrrolidin-2-one

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; water at 80℃; for 1h; Suzuki Coupling;100%
2,3-dimethyl-2,3-butane diol
76-09-5

2,3-dimethyl-2,3-butane diol

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

2-(biphenyl-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
144432-80-4

2-(biphenyl-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With potassium phosphate; water In tetrahydrofuran at 90℃; for 1h; Inert atmosphere;100%
With air In dichloromethane at 25℃; for 16h; Molecular sieve;46%
In diethyl ether at 20℃; Inert atmosphere; Molecular sieve;
9,10-dimethyl-2,3,6,7,14,15-hexahydroxy-9,10-[1',2']benzenoanthracene
865539-66-8

9,10-dimethyl-2,3,6,7,14,15-hexahydroxy-9,10-[1',2']benzenoanthracene

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

C58H39B3O6

C58H39B3O6

Conditions
ConditionsYield
In neat (no solvent) at 130℃; for 0.25h;100%
10-(biphenyl-4-yl)-2-bromo-9,9-dimethyl-7-phenylacridan
1352002-20-0

10-(biphenyl-4-yl)-2-bromo-9,9-dimethyl-7-phenylacridan

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

2,10-bis(biphenyl-4-yl)-9,9-dimethyl-7-phenylacridan
1403981-72-5

2,10-bis(biphenyl-4-yl)-9,9-dimethyl-7-phenylacridan

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 68℃; for 4h; Suzuki Coupling; Inert atmosphere;100%
2-chloro-4,5-dimethoxypyrimidine
1333240-17-7

2-chloro-4,5-dimethoxypyrimidine

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

2-(4-biphenyl)-4,5-dimethoxypyrimidine

2-(4-biphenyl)-4,5-dimethoxypyrimidine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,4-dioxane; water for 8h; Suzuki Coupling; Reflux; Inert atmosphere;100%
2-(4-fluorophenyl)-3-iodo-6-(thien-3-yl)imidazo[1,2-a]pyridine
1443986-20-6

2-(4-fluorophenyl)-3-iodo-6-(thien-3-yl)imidazo[1,2-a]pyridine

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

3-(biphen-4-yl)-2-(4-fluorophenyl)-6-(thien-3-yl)imidazo[1,2-a]pyridine

3-(biphen-4-yl)-2-(4-fluorophenyl)-6-(thien-3-yl)imidazo[1,2-a]pyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water at 120℃; for 1h; Suzuki Coupling; Inert atmosphere; Microwave irradiation;100%
pinacolboronic acid
25240-59-9

pinacolboronic acid

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

2-(biphenyl-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
144432-80-4

2-(biphenyl-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With potassium phosphate; water In tetrahydrofuran at 90℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere;100%
4-bromo-1-(3-methoxyphenyl)-1-hydropyrazole

4-bromo-1-(3-methoxyphenyl)-1-hydropyrazole

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

4-(biphenyl-4-yl)-1-(3-methoxyphenyl)-1H-pyrazole

4-(biphenyl-4-yl)-1-(3-methoxyphenyl)-1H-pyrazole

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); tricyclohexylphosphine In 1,4-dioxane; water at 95 - 105℃; for 20h; Inert atmosphere;100%
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); tricyclohexylphosphine In 1,4-dioxane; water at 95 - 105℃; for 20h; Inert atmosphere;100%
4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

C25H27N3O3

C25H27N3O3

C35H31N3O

C35H31N3O

Conditions
ConditionsYield
Stage #1: C25H27N3O3 With trichlorophosphate In toluene at 100℃; for 0.5h; Microwave irradiation;
Stage #2: 4-biphenylboronic acid With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In 1,4-dioxane at 90℃; for 16h;
Stage #3: With hydrogenchloride In tetrahydrofuran; water at 20℃;
100%
N-(2-cyanophenyl)benzamide
40288-69-5

N-(2-cyanophenyl)benzamide

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

4-([1,1'-biphenyl]-4-yl)-2-phenylquinazoline

4-([1,1'-biphenyl]-4-yl)-2-phenylquinazoline

Conditions
ConditionsYield
With [2,2]bipyridinyl; lanthanum(III) acetate; trifluoroacetic acid In tetrahydrofuran at 20 - 70℃; for 22h; Reagent/catalyst; Temperature;99.5%
With [2,2]bipyridinyl; palladium diacetate; trifluoroacetic acid In tetrahydrofuran at 80℃; for 24h; Schlenk technique;95%
4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

2,5-dibromo-1,4-di-N-dodecylbenzene
117635-23-1

2,5-dibromo-1,4-di-N-dodecylbenzene

4-Bromo-2,5-didodecyl-[1,1';4',1'']terphenyl

4-Bromo-2,5-didodecyl-[1,1';4',1'']terphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In toluene for 72h; Heating;99%
4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

3-benzyloxy-4-iodo-5-(1-methoxycarbonyl-4-piperidyl)isoxazol
841259-40-3

3-benzyloxy-4-iodo-5-(1-methoxycarbonyl-4-piperidyl)isoxazol

3-benzyloxy-4-(4-biphenyl)-5-(1-methoxycarbonyl-4-piperidinyl)isoxazole

3-benzyloxy-4-(4-biphenyl)-5-(1-methoxycarbonyl-4-piperidinyl)isoxazole

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In N,N-dimethyl-formamide at 70℃; for 22h; Suzuki coupling;99%
di-isopropyl azodicarboxylate
2446-83-5

di-isopropyl azodicarboxylate

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

1,2-bis(isopropoxycarbonyl)-1-(biphenyl-4-yl)hydrazine

1,2-bis(isopropoxycarbonyl)-1-(biphenyl-4-yl)hydrazine

Conditions
ConditionsYield
2,9-dimethyl-1,10-phenanthroline-based palladium(II) complex In 1,2-dichloro-ethane at 60℃; for 12h;99%
9-Bromoanthracene
1564-64-3

9-Bromoanthracene

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

9-([1,1'-biphenyl]-4-yl)anthracene

9-([1,1'-biphenyl]-4-yl)anthracene

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; triphenylphosphine In 1,2-dimethoxyethane; water at 80℃; for 17h; Inert atmosphere;99%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 24h; Inert atmosphere; Reflux; Sealed tube;90%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 90℃; for 16h; Inert atmosphere;90%
methyl o-formylbenzoate
4122-56-9

methyl o-formylbenzoate

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

3-([1,1'-biphenyl]-4-yl)isobenzofuran-1(3H)-one
135381-46-3

3-([1,1'-biphenyl]-4-yl)isobenzofuran-1(3H)-one

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); C27H30N2S(1+)*Cl(1-); cesium fluoride In toluene at 80℃; for 1h; Inert atmosphere;99%
C11H8O3
1202929-10-9

C11H8O3

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

C23H18O3

C23H18O3

Conditions
ConditionsYield
With [Pd(S,S)-bdpp(H2O)2](2+)(BF4(1-))2 In 1,4-dioxane at 20℃; for 0.416667h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

4-Phenylphenol
92-69-3

4-Phenylphenol

Conditions
ConditionsYield
With [Rh2(bpy)2(μ-OAc)2(OAc)2]; oxygen; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide under 760.051 Torr; for 18h; Catalytic behavior; Reagent/catalyst; Solvent; Irradiation;99%
With oxygen; triethylamine In acetonitrile at 20℃; under 760.051 Torr; for 4h; Reagent/catalyst; Irradiation;99%
With dihydrogen peroxide In acetonitrile at 30 - 35℃; for 0.0833333h; Schlenk technique;98%
cyclohexenone
930-68-7

cyclohexenone

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

3-([1,1’-biphenyl]-4-yl)cyclohexan-1-one
86921-83-7

3-([1,1’-biphenyl]-4-yl)cyclohexan-1-one

Conditions
ConditionsYield
With 1,1'-dimesityl-3,3'-methylenediimidazolin-2,2'-diylidene-di(trifluoroacetato)palladium(II); potassium hydroxide In tetrahydrofuran; water at 20℃; for 36h;99%
With potassium fluoride; C32H33ClO3P2Pd In toluene at 60℃; for 18h; Sealed tube; Inert atmosphere;96%
2-phenyl-5-methyl-7-chlorobenzo[b]furan
1248340-80-8

2-phenyl-5-methyl-7-chlorobenzo[b]furan

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

C27H20O
1335094-23-9

C27H20O

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 2h; Suzuki-Miyaura cross-coupling;99%
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 2h; Suzuki-Miyaura Coupling;99%
7-chloro-2,5-diphenylbenzo[b]furan
1335094-11-5

7-chloro-2,5-diphenylbenzo[b]furan

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

7-(biphenyl-4-yl)-2,5-diphenylbenzo[b]furan
1335094-18-2

7-(biphenyl-4-yl)-2,5-diphenylbenzo[b]furan

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 2h; Suzuki-Miyaura cross-coupling;99%
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 2h; Suzuki-Miyaura Coupling;99%
7-chloro-5-fluoro-2-phenylbenzo[b]furan
1335094-14-8

7-chloro-5-fluoro-2-phenylbenzo[b]furan

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

7-(biphenyl-4-yl)-5-fluoro-2-phenylbenzo[b]furan
1335094-28-4

7-(biphenyl-4-yl)-5-fluoro-2-phenylbenzo[b]furan

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 2h; Suzuki-Miyaura cross-coupling;99%
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 2h; Suzuki-Miyaura Coupling;99%
isatoic anhydride
118-48-9

isatoic anhydride

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

biphenyl-4-yl 2-aminobenzoate

biphenyl-4-yl 2-aminobenzoate

Conditions
ConditionsYield
With N-methylcyclohexylamine; tris-(dibenzylideneacetone)dipalladium(0); oxygen; bis[2-(diphenylphosphino)phenyl] ether In tetrahydrofuran at 60℃; for 24h;99%
di-tert-butyl fumarate
7633-38-7

di-tert-butyl fumarate

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

(S)-di-tert-butyl-2-(biphenyl-4-yl)succinate
1378314-25-0

(S)-di-tert-butyl-2-(biphenyl-4-yl)succinate

Conditions
ConditionsYield
Stage #1: 4-biphenylboronic acid With chlorobis(ethylene)rhodium(I) dimer; (S,S)-1,7,7-trimethyl-2,5-diphenylbicyclo[2.2.1]hepta-2,5-diene; potassium tert-butylate In methanol; dichloromethane at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: di-tert-butyl fumarate In methanol; dichloromethane; isopropyl alcohol at 60℃; for 1h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
99%
methyl 2-(2-oxo-2-phenylacetyl)benzoate
92965-01-0

methyl 2-(2-oxo-2-phenylacetyl)benzoate

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

3-([1,1'-biphenyl]-4-yl)-3-phenylisochroman-1,4-dione
1452219-94-1

3-([1,1'-biphenyl]-4-yl)-3-phenylisochroman-1,4-dione

Conditions
ConditionsYield
Stage #1: methyl 2-(2-oxo-2-phenylacetyl)benzoate; 4-biphenylboronic acid With chlorobis(cyclooctene)rhodium(I) dimer; (R)-N-cinnamyl-2-methylpropane-2-sulfinamide In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere; Schlenk technique;
Stage #2: With potassium hydroxide In tetrahydrofuran; water at 20℃; for 3h;
Stage #3: With sulfuric acid In tetrahydrofuran; methanol; water at 20℃; for 1h; enantioselective reaction;
99%
C18H15ClO4
1422250-63-2

C18H15ClO4

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

2-(7-(biphenyl-4-yl)-2-phenylbenzo[b]furan-5-yl)ethyl methyl carbonate
1422250-78-9

2-(7-(biphenyl-4-yl)-2-phenylbenzo[b]furan-5-yl)ethyl methyl carbonate

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 24h; Suzuki-Miyaura Coupling;99%
7-chloro-2-pentyl-5-phenylbenzo[b]furan
1422250-61-0

7-chloro-2-pentyl-5-phenylbenzo[b]furan

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

7-(biphenyl-4-yl)-2-pentyl-5-phenylbenzo[b]furan
1422250-68-7

7-(biphenyl-4-yl)-2-pentyl-5-phenylbenzo[b]furan

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 2h; Suzuki-Miyaura Coupling;99%
7-chloro-5-methyl-2-phenethylbenzo[b]furan
1422250-62-1

7-chloro-5-methyl-2-phenethylbenzo[b]furan

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

7-(biphenyl-4-yl)-5-methyl-2-phenethylbenzo[b]furan
1422250-73-4

7-(biphenyl-4-yl)-5-methyl-2-phenethylbenzo[b]furan

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 2h; Suzuki-Miyaura Coupling;99%

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