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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3-Nitrophenylboronic Acid supplier in China

Cas:13331-27-6

Min.Order:0 Metric Ton

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Jinan Finer Chemical Co., Ltd

Product Description Product Name 3-Nitrophenylboronic acid CAS No. 13331-27-6 Appearance White powder Assay ≥99% Capacity 100mt/year Min.packing 100gram

3-Nitrophenylboronic acid

Cas:13331-27-6

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

3-Nitrobenzeneboronic acid

Cas:13331-27-6

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-Nitrophenylboronic Acid

Cas:13331-27-6

Min.Order:1

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Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Large Stock 99.0% 3-Nitrophenylboronic acid 13331-27-6 Producer

Cas:13331-27-6

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

3-Nitrophenylboronic acid

Cas:13331-27-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Nitrobenzeneboronic acid

Cas:13331-27-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

big discount 3-Nitrophenylboronic acid

Cas:13331-27-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

3-Nitrophenylboronic acid CAS 13331-27-6

Cas:13331-27-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 13331-27-6 with fast shipping

Cas:13331-27-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:liquid Storage:Store in sealed containers at cool & dry plac

3-Nitrophenylboronic acid CAS NO 13331-27-6

Cas:13331-27-6

Min.Order:100 Gram

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Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Boronicacid, B-(3-nitrophenyl)- 13331-27-6

Cas:13331-27-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

3-Nitrophenylboronic acid CAS:13331-27-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

3-Nitrophenylboronic acid CAS:13331-27-6

Cas:13331-27-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Boronicacid, B-(3-nitrophenyl)-

Cas:13331-27-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

3-Nitrophenylboronic acid

Cas:13331-27-6

Min.Order:1 Kilogram

FOB Price: $10.0 / 100.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Boronicacid, B-(3-nitrophenyl)-

Cas:13331-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3-Nitrophenylboronic Acid

Cas:13331-27-6

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:As

3-Nitrophenylboronic acid 13331-27-6

Cas:13331-27-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

big discount 3-Nitrophenylboronic acid

Cas:13331-27-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Nitrophenylboronic Acid

Cas:13331-27-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 3-Nitrophenylboronic Acid

Cas:13331-27-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

big discount 3-Nitrophenylboronic acid

Cas:13331-27-6

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:White to light yellow crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Catalyzes ene carbocyclization of

3-Nitrophenylboronic acid

Cas:13331-27-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

3-Nitrophenylboronicacid

Cas:13331-27-6

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

Product Name: 3-Nitrophenylboronic acid CAS: 13331-27-6 MF: C6H6BNO4 MW: 166.93 EINECS: Mol File: 13331-27-6.mol 3-Nitrophenylboronic acid Structure 3-Nitrophenylboronic acid Chemical Properties Melting point 284-285 °C (

3-Nitrophenylboronic acid

Cas:13331-27-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

big discount 3-Nitrophenylboronic acid

Cas:13331-27-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

big discount 3-Nitrophenylboronic acid

Cas:13331-27-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

BEST PRICE/3-Nitrophenylboronic acid CAS NO.13331-27-6

Cas:13331-27-6

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

Boronicacid, B-(3-nitrophenyl)-

Cas:13331-27-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

M-NITROPHENYLBORONIC ACID

Cas:13331-27-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

4,4,5,5-tetramethyl-2-(3-nitrophenyl)-1,3,2-dioxaborolane
68716-48-3

4,4,5,5-tetramethyl-2-(3-nitrophenyl)-1,3,2-dioxaborolane

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
With hydrogenchloride; polystyrene boronic acid In acetonitrile at 20℃; for 18h;88%
potassium 3-nitrophenyltrifluoroborate

potassium 3-nitrophenyltrifluoroborate

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
With water; silica gel at 20℃; for 24h; Inert atmosphere;86%
With water In tetrahydrofuran at 55℃; Kinetics; Reagent/catalyst;
5-(4-methoxyphenyl)-4,4-dimethyl-2-(3-nitrophenyl)[1,3,2]dioxaborolane

5-(4-methoxyphenyl)-4,4-dimethyl-2-(3-nitrophenyl)[1,3,2]dioxaborolane

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane; water at 50℃; for 24h;65%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

3-nitro-aniline
99-09-2

3-nitro-aniline

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
Stage #1: 3-nitro-aniline With hydrogenchloride; sodium nitrite In water at 0℃; for 0.25h;
Stage #2: tetrahydroxydiboron With sodium acetate In water at 20℃; for 0.333333h;
64%
phenylboronic acid
98-80-6

phenylboronic acid

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
nitration according to W. Seaman and J. R. Johnson, J. Am. Chem. Soc., 1931, 53, 711;47%
With nitric acid at -15 - -9℃;28%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

3-nitrophenyldiazonium tetrafluoroborate
586-36-7

3-nitrophenyldiazonium tetrafluoroborate

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; for 0.25h;38%
phenylboronic acid
98-80-6

phenylboronic acid

A

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

B

2-nitrophenylboronic acid
5570-19-4

2-nitrophenylboronic acid

Conditions
ConditionsYield
With nitric acid; urea
With sulfuric acid; nitric acid
C6H4LiNO2

C6H4LiNO2

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
With Trimethyl borate; hydrogen cation
3-Bromonitrobenzene
585-79-5

3-Bromonitrobenzene

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
With n-butyllithium; Triisopropyl borate In tetrahydrofuran; hexane; toluene at -70 - -20℃;13 % Chromat.
C6H4BF3NO2(1-)

C6H4BF3NO2(1-)

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
In phosphate buffer pH=6.9 - 7.0; Kinetics;
water
7732-18-5

water

potassium 3-nitrophenyltrifluoroborate

potassium 3-nitrophenyltrifluoroborate

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
With glass or Cs2CO3 In tetrahydrofuran; water Kinetics; hydrolysis at 55°C in THF/H2O in the presence of glass powder or Cs2CO3; not isolated;
C17H18BN2O5Pol

C17H18BN2O5Pol

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
With water; acetic acid In tetrahydrofuran at 20℃; for 2h;
3-nitro-aniline
99-09-2

3-nitro-aniline

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: water / 0.03 h / 20 °C
1.2: 0.25 h / 0 °C
2.1: N,N-dimethyl-formamide / 0.25 h / 20 °C
View Scheme
triphenylboroxine
3262-89-3

triphenylboroxine

2-nitrobenzo[d]isothiazol-3(2H)-one 1,1-dioxide
80283-99-4

2-nitrobenzo[d]isothiazol-3(2H)-one 1,1-dioxide

A

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

B

nitrobenzene
98-95-3

nitrobenzene

Conditions
ConditionsYield
With 1,1,1,3',3',3'-hexafluoro-propanol; magnesium sulfate at 60℃; for 17h; Reagent/catalyst;A 24 %Chromat.
B 38 %Chromat.
4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

3'-nitro-[1,1'-biphenyl]-4-carboxylic acid methyl ester
89900-93-6

3'-nitro-[1,1'-biphenyl]-4-carboxylic acid methyl ester

Conditions
ConditionsYield
With sodium carbonate; bis(dibenzylideneacetone)-palladium(0); C78H99N6P(6+)*6Br(1-) In methanol; water at 65℃; for 3h; Suzuki-Miyaura cross-coupling; Inert atmosphere;100%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; toluene at 20 - 80℃; for 5h; Inert atmosphere;21%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,4-dioxane at 85℃; Suzuki cross-coupling;16%
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

1-tert-butoxycarbonyl-4-(5-trifluoromethanesulfonyloxy-3-pyridyl)homopiperazine
223797-51-1

1-tert-butoxycarbonyl-4-(5-trifluoromethanesulfonyloxy-3-pyridyl)homopiperazine

1-[5-(3-nitrophenyl)-pyridin-3-yl]-4-tert-butoxycarbonylhomopiperazine
223797-57-7

1-[5-(3-nitrophenyl)-pyridin-3-yl]-4-tert-butoxycarbonylhomopiperazine

Conditions
ConditionsYield
With potassium carbonate; lithium chloride; trimethyleneglycol; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane for 2h; Heating / reflux;100%
1-[3-bromo-2-hydroxy-5-(1 H-tetrazol-5-yl)-phenyl]-ethanone

1-[3-bromo-2-hydroxy-5-(1 H-tetrazol-5-yl)-phenyl]-ethanone

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

1-[2-Hydroxy-3-nitro-5-(1H-tetrazol-5-yl)-biphenyl-3-yl]-ethanone

1-[2-Hydroxy-3-nitro-5-(1H-tetrazol-5-yl)-biphenyl-3-yl]-ethanone

Conditions
ConditionsYield
With sodium carbonate; Pd(PPh3)4 In ethanol; toluene100%
With sodium carbonate; Pd(PPh3)4 In ethanol; toluene1.22%
N-(3-iodo-4-methyl-phenyl)-3-(trifluoromethyl)benzamide
913067-90-0

N-(3-iodo-4-methyl-phenyl)-3-(trifluoromethyl)benzamide

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

N-(6-methyl-3'-nitrobiphenyl-3-yl)-3-(trifluoromethyl)benzamide
1036376-84-7

N-(6-methyl-3'-nitrobiphenyl-3-yl)-3-(trifluoromethyl)benzamide

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 90℃; for 16h; Heating / reflux;100%
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

meta-nitrophenol
554-84-7

meta-nitrophenol

Conditions
ConditionsYield
With dihydrogen peroxide In water at 30℃; Green chemistry;99%
With 2,5-dimethylfuran; zinc(II) phthalocyanine; oxygen In tetrahydrofuran at 25℃; under 760.051 Torr; for 1.5h; Irradiation; Sealed tube; Schlenk technique;98%
With water; 3-chloro-benzenecarboperoxoic acid In ethanol at 20℃; for 6h;97%
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1-(3'-nitrobiphenyl-4-yl)ethanone
5002-11-9

1-(3'-nitrobiphenyl-4-yl)ethanone

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 70℃; for 14h; Suzuki-Miyaura reaction;99%
With lithium niobate; palladium diacetate; potassium carbonate In ethanol; water; paraffin oil at 87 - 88℃; for 0.2h; Suzuki Coupling;99%
With tetrabutylammomium bromide; palladium diacetate; potassium carbonate In water at 70℃; for 3.33h; Suzuki Coupling; Inert atmosphere;96.5%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

methyl 3’-nitro-[1,1’-biphenyl]-2-carboxylate
83527-96-2

methyl 3’-nitro-[1,1’-biphenyl]-2-carboxylate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,4-dioxane at 85℃; Suzuki cross-coupling;99%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; toluene at 20 - 80℃; for 6h; Inert atmosphere;17%
With tetra-butylammonium acetate; Pd EnCat-30TM In ethanol Suzuki cross-coupling; microwave irradiation;
iodobenzene
591-50-4

iodobenzene

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

3-nitro-1,1'-biphenyl

3-nitro-1,1'-biphenyl

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0); tri-tert-butyl phosphine In 1,1,1,2,3,3,3-Heptafluoropropane; ethanol; 1,1,1,3,3-pentafluorobutane at 20℃; for 24h; Suzuki-Miyaura cross-coupling reaction; Inert atmosphere;99%
With C22H24Cl2N6O2Pd2; potassium carbonate In ethanol; water for 4h; Catalytic behavior; Suzuki-Miyaura Coupling; Reflux;99%
With potassium carbonate In water at 20℃; for 0.5h; Suzuki-Miyaura Coupling;97%
4-bromo-3,5-diphenylisothiazole
942227-99-8

4-bromo-3,5-diphenylisothiazole

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

3,5-diphenyl-4-(3-nitrobenzene)isothiazole

3,5-diphenyl-4-(3-nitrobenzene)isothiazole

Conditions
ConditionsYield
With potassium carbonate; palladium diacetate In N,N-dimethyl-formamide at 20 - 110℃; for 0.916667h;99%
2-bromo-3,5-difluorobenzonitrile
425379-37-9

2-bromo-3,5-difluorobenzonitrile

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

4,6-difluoro-3'-nitrobiphenyl-2-carbonitrile
731817-91-7

4,6-difluoro-3'-nitrobiphenyl-2-carbonitrile

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine In tetrahydrofuran; hexane; water at 50℃; for 4h;99%
(E)-2-fluorovinyl 4-methylbenzenesulfonate
1262431-28-6

(E)-2-fluorovinyl 4-methylbenzenesulfonate

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

(E)-1-(2-fluorovinyl)-3-nitrobenzene
1262431-33-3

(E)-1-(2-fluorovinyl)-3-nitrobenzene

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium phosphate; tricyclohexylphosphine In 1,4-dioxane at 100℃; for 14h; Suzuki-Miyaura reaction; Inert atmosphere; stereoselective reaction;99%
di-tert-butyl fumarate
7633-38-7

di-tert-butyl fumarate

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

(S)-di-tert-butyl-2-(3-nitrophenyl)succinate
1378314-51-2

(S)-di-tert-butyl-2-(3-nitrophenyl)succinate

Conditions
ConditionsYield
Stage #1: m-nitrobenzene boronic acid With chlorobis(ethylene)rhodium(I) dimer; (S,S)-1,7,7-trimethyl-2,5-diphenylbicyclo[2.2.1]hepta-2,5-diene; potassium tert-butylate In methanol; dichloromethane at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: di-tert-butyl fumarate In methanol; dichloromethane; isopropyl alcohol at 60℃; for 1h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
99%
C25H25BrFNO
1373125-72-4

C25H25BrFNO

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

C31H29FN2O3

C31H29FN2O3

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); tri tert-butylphosphoniumtetrafluoroborate In water; toluene at 90℃; for 14h; Heck-Suzuki cascade reaction; optical yield given as %de; diastereoselective reaction;99%
2-iodobenzyl alcohol
5159-41-1

2-iodobenzyl alcohol

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

(3'-nitro-[1,1'-biphenyl]-2-yl)methanol
893743-35-6

(3'-nitro-[1,1'-biphenyl]-2-yl)methanol

Conditions
ConditionsYield
With C22H24Cl2N6O2Pd2; potassium carbonate In ethanol; water for 4h; Catalytic behavior; Suzuki-Miyaura Coupling; Reflux;99%
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

acetonitrile
75-05-8

acetonitrile

3-nitrobenzonitrile
619-24-9

3-nitrobenzonitrile

Conditions
ConditionsYield
With N-iodo-succinimide; 1,10-Phenanthroline; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; 1,1,1,2,2,2-hexamethyldisilane; oxygen; copper diacetate; diisopropylamine at 20 - 150℃; Schlenk technique;99%
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

C19H15FeIN2

C19H15FeIN2

5-ferrocenyl-4-(3-nitrophenyl)-1-phenyl-1H-pyrazole

5-ferrocenyl-4-(3-nitrophenyl)-1-phenyl-1H-pyrazole

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium hydrogencarbonate In water; N,N-dimethyl-formamide at 110℃; for 4h; Suzuki-Miyaura Coupling; Inert atmosphere;99%
3,5-dibromobenzaldehyde
56990-02-4

3,5-dibromobenzaldehyde

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

3,5-di(3-nitrophenyl)-benzaldehyde

3,5-di(3-nitrophenyl)-benzaldehyde

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 90℃; for 24h; Schlenk technique; Inert atmosphere;99%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 90℃; for 24h; Inert atmosphere;80%
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

3,3'-dinitro-1,1'-biphenyl
958-96-3

3,3'-dinitro-1,1'-biphenyl

Conditions
ConditionsYield
With air In N,N-dimethyl-formamide at 20℃; for 16h; Green chemistry;98%
With potassium permanganate; potassium carbonate In methanol; water at 20℃; Catalytic behavior; Reagent/catalyst;97%
With [(μ4-Te)Fe3(CO)9Cu2(Me2Im)2]; oxygen In methanol at 25℃; for 24h; Kinetics;97%
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

3-Bromonitrobenzene
585-79-5

3-Bromonitrobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; copper(I) bromide In acetonitrile at 80℃; for 1h;98%
With N-Bromosuccinimide In acetonitrile at 80℃; for 12h;98%
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; Sealed tube;80%
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

N-(tert-butoxycarbonyl)-D-tyrosine methyl ester
76757-90-9

N-(tert-butoxycarbonyl)-D-tyrosine methyl ester

(R)-2-tert-Butoxycarbonylamino-3-[4-(3-nitro-phenoxy)-phenyl]-propionic acid methyl ester

(R)-2-tert-Butoxycarbonylamino-3-[4-(3-nitro-phenoxy)-phenyl]-propionic acid methyl ester

Conditions
ConditionsYield
With pyridine; copper diacetate; 4 A molecular sieve In dichloromethane at 25℃; for 18h;98%
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

3-Chloronitrobenzene
121-73-3

3-Chloronitrobenzene

Conditions
ConditionsYield
With 1,3-dichloro-5,5-dimethylhydantoin; copper(l) chloride In acetonitrile at 80℃; for 2h;98%
With N-chloro-succinimide In acetonitrile at 80℃; for 12h;97%
With 1,3-dichloro-5,5-dimethylhydantoin; sodium methylate In methanol; water; acetonitrile at 60℃;43 % Chromat.
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

di-tert-butyl (E)-azodicarboxylate
870-50-8

di-tert-butyl (E)-azodicarboxylate

di-tert-butyl 1-(3-nitrophenyl)hydrazine-1,2-dicarboxylate

di-tert-butyl 1-(3-nitrophenyl)hydrazine-1,2-dicarboxylate

Conditions
ConditionsYield
With copper diacetate In tetrahydrofuran at 20℃; for 20h;98%
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

N-3-benzoylthymine
4330-20-5

N-3-benzoylthymine

3-benzoyl-5-methyl-1-(3-nitrophenyl)pyrimidine-2,4(1H,3H)-dione

3-benzoyl-5-methyl-1-(3-nitrophenyl)pyrimidine-2,4(1H,3H)-dione

Conditions
ConditionsYield
With pyridine; air; copper diacetate In dichloromethane at 20℃; for 75h; Chan-Lam-Evans-modified Ullmann condensation;98%
para-iodoanisole
696-62-8

para-iodoanisole

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

4-methoxy-3'-nitrobiphenyl
53059-31-7

4-methoxy-3'-nitrobiphenyl

Conditions
ConditionsYield
With potassium carbonate In water at 50℃; for 2h; Suzuki Coupling;98%
With magnesium hydroxide; potassium hydroxide; barium(II) hydroxide; calcium hydroxide In water at 20℃; for 2h; Suzuki Coupling;98%
With 0.1 % Cu/C; potassium carbonate In water at 50℃; for 3h; Suzuki Coupling; Green chemistry;95%
o-trifluoromethylbenzyl bromide
395-44-8

o-trifluoromethylbenzyl bromide

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

1-(3-nitrobenzyl)-2-(trifluoromethyl)benzene
886211-35-4

1-(3-nitrobenzyl)-2-(trifluoromethyl)benzene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water at 50℃; for 16h;98%
2,3-dimethyl-2,3-butane diol
76-09-5

2,3-dimethyl-2,3-butane diol

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

4,4,5,5-tetramethyl-2-(3-nitrophenyl)-1,3,2-dioxaborolane
68716-48-3

4,4,5,5-tetramethyl-2-(3-nitrophenyl)-1,3,2-dioxaborolane

Conditions
ConditionsYield
With sodium sulfate In tetrahydrofuran at 20℃; for 24h; Schlenk technique; Inert atmosphere;98%
In toluene at 120℃; for 1h;92.1%
In benzene for 1h; Inert atmosphere; Reflux;75%
With magnesium sulfate In tetrahydrofuran at 20℃; for 16h;70%
In diethyl ether at 20℃; for 18h;60%
diphenyl diselenide
1666-13-3

diphenyl diselenide

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

(3-nitrophenyl)(phenyl)selane
301329-93-1

(3-nitrophenyl)(phenyl)selane

Conditions
ConditionsYield
With copper(II) oxide In dimethyl sulfoxide at 100℃; for 24h; Air atmosphere;98%
With potassium carbonate In water at 70℃; for 9h;88%
With iodine; dimethyl sulfoxide In neat (no solvent) at 100℃; for 0.166667h; Sealed tube; Microwave irradiation; Green chemistry;86%
With potassium carbonate at 80℃; for 10h; Green chemistry;85%
With sodium tetrahydroborate; 1,10-Phenanthroline; copper(ll) sulfate pentahydrate In ethanol at 20℃; for 8h;79%
m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

3'-Chloroacetophenone
99-02-5

3'-Chloroacetophenone

1-(3'-nitrobiphenyl-3-yl)ethanone
371157-19-6

1-(3'-nitrobiphenyl-3-yl)ethanone

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); potassium phosphate monohydrate; 2-(2-methoxyphenyl)-1-methyl-3-(diphenylphosphino)-1H-indole In 1,4-dioxane at 90℃; for 24h; Suzuki-Miyaura coupling; Inert atmosphere;98%
(2S)-2-[(5-bromo-6-phenylfuro[2,3-d]pyrimidin-4-yl)amino]-2-phenylethanol
1226548-51-1

(2S)-2-[(5-bromo-6-phenylfuro[2,3-d]pyrimidin-4-yl)amino]-2-phenylethanol

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

(2S)-2-{[5-(3-nitrophenyl)-6-phenylfuro[2,3-d]pyrimidin-4-yl]amino}-2-phenylethanol
1226549-62-7

(2S)-2-{[5-(3-nitrophenyl)-6-phenylfuro[2,3-d]pyrimidin-4-yl]amino}-2-phenylethanol

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate In 1,4-dioxane; water at 100℃; for 2h; Inert atmosphere;98%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate In 1,4-dioxane; water at 95℃; for 16h; Inert atmosphere;75%
With palladium bis[bis(diphenylphosphino)ferrocene] dichloride; sodium carbonate In 1,4-dioxane; water Suzuki Coupling; Inert atmosphere; Reflux;43%
N-phenyl-N-methyl-2-propynamide
15249-31-7

N-phenyl-N-methyl-2-propynamide

m-nitrobenzene boronic acid
13331-27-6

m-nitrobenzene boronic acid

N-methyl-3-(3-nitrophenyl)-N-phenylpropiolamide
1238625-89-2

N-methyl-3-(3-nitrophenyl)-N-phenylpropiolamide

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; silver(l) oxide In acetonitrile at 70℃; for 12h; Sonogashira coupling;98%

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