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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Methyl 4'-methylbiphenyl-2-carboxylate Manufacturer/High quality/Best price/In stock

Cas:114772-34-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Methyl Biphenyl-2-Carboxylate supplier in China

Cas:114772-34-8

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

Methyl 4'-methylbiphenyl-2-carboxylate Manufacturer/High quality/Best price/In stock CAS NO.114772-34-8

Cas:114772-34-8

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Methyl Biphenyl-2-Carboxylate

Cas:114772-34-8

Min.Order:1

Negotiable

Type:Other

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Methyl 4'-Methylbiphenyl-2-Carboxylate

Cas:114772-34-8

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Methyl 4'-methylbiphenyl-2-carboxylate -- CHemwill

Cas:114772-34-8

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

Methyl 4'-methylbiphenyl-2-carboxylate CAS 114772-34-8

Cas:114772-34-8

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Henan Tianfu Chemical Co., Ltd. is located in Zhengzhou High-tech Development Zone with import and export license. We passed ISO 9001:2008 in 2009, and won "High-tech Enterprise" by provincial government in 2013.The objective of the com

TIANFU-CHEM - Methyl 4'-methylbiphenyl-2-carboxylate

Cas:114772-34-8

Min.Order:1 Gram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 114772-34-8 with best quality

Cas:114772-34-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Methyl 4'-methylbiphenyl-2-carboxylate Manufacturer/High quality/Best price/In stock CAS NO.114772-34-8

Cas:114772-34-8

Min.Order:10 Gram

FOB Price: $0.5 / 1.0

Type:Trading Company

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Methyl 4'-methylbiphenyl-2-carboxylate/ LIDE PHARMA- Factory supply / Best price

Cas:114772-34-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Product name Methyl 4'-methylbiphenyl-2-carboxylate CAS 114772-34-8 Synonyms METHYL 4'-METHYL[1,1'-BIPHENYL]-2-CARBOXYLATE;METHYL 4'-METHYLBIPHENYL-2-CARBOXYLATE;

Methyl 4'-methylbiphenyl-2-carboxylate

Cas:114772-34-8

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

[1,1'-Biphenyl]-2-carboxylicacid, 4'-methyl-, methyl ester 114772-34-8

Cas:114772-34-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Methyl 4'-methylbiphenyl-2-carboxylate CAS:114772-34-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in hi

Methyl 4'-methylbiphenyl-2-carboxylate CAS:114772-34-8

Cas:114772-34-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-methyl biphenyl-2-carboxylate

Cas:114772-34-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

[1,1'-Biphenyl]-2-carboxylicacid, 4'-methyl-, methyl ester

Cas:114772-34-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methyl 4'-Methylbiphenyl-2-Carboxylate

Cas:114772-34-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4'-Methylbiphenyl-2-carboxylic acid methyl ester

Cas:114772-34-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

METHYL 4'-METHYLBIPHENYL-2-CARBOXYLATE 114772-34-8

Cas:114772-34-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl 4'-methylbiphenyl-2-carboxylate

Cas:114772-34-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Methyl 4'-methylbiphenyl-2-carboxylate

Cas:114772-34-8

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 4-Methyl Biphenyl-2-Carboxylate

Cas:114772-34-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Methyl 4'-methylbiphenyl-2-carboxylate Manufacturer/High quality/Best price/In stock CAS NO.114772-34-8

Cas:114772-34-8

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Methyl4'-methylbiphenyl-2-carboxylate

Cas:114772-34-8

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: 4'-Methylbiphenyl-2-carboxylic Acid Methyl Ester CAS No.: 114772-34-8 Molecule Formula:C15H14O2 Molecule Weight:226.27 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Ente

Lower Price 4'-Methylbiphenyl-2-carboxylic Acid Methyl Ester

Cas:114772-34-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4'-Methylbiphenyl-2-carboxylic acid methyl ester

Cas:114772-34-8

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 4′-Methylbiphenyl-2-carboxylic acid methyl ester Synonyms: RARECHEM AL BF 1359;METHYL 4'-METHYL[1,1'-BIPHENYL]-2-CARBOXYLATE;METHYL 4'-METHYLBIPHENYL-2-CARBOXYLATE;METHYL 4'-METHYL-2-BIPHENYLCARBOXYLATE;METHY

4′-Methylbiphenyl-2-carboxylic acid methyl ester

Cas:114772-34-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Methyl 4'-methylbiphenyl-2-carboxylate

Cas:114772-34-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

4'-Methylbiphenyl-2-carboxylic acid methyl ester

Cas:114772-34-8

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

[1,1'-Biphenyl]-2-carboxylicacid, 4'-methyl-, methyl ester

Cas:114772-34-8

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

methanol
67-56-1

methanol

o-tolylbenzoic acid
7148-03-0

o-tolylbenzoic acid

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide at 25℃; for 3h; Temperature; Large scale;98.05%
With sulfuric acid for 5h; Reflux;94%
With acetyl chloride 1.) 0 deg C, 0.25 h, 2.) reflux, 4 h; Yield given. Multistep reaction;
With sulfuric acid for 5h; Time; Reflux;13.9 g
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With tetra-butylammonium acetate; Pd EnCat-30TM In ethanol at 120℃; for 0.166667h; Suzuki cross-coupling; microwave irradiation;98%
With potassium fluoride; palladium diacetate In toluene at 80℃; for 1h; Suzuki-Miyaura coupling;93%
With sodium carbonate; [(PPh3)2Pd(N-succ)2] In tetrahydrofuran; water at 60℃; for 10h; Suzuki cross-coupling reaction;62%
o-tolylbenzoic acid
7148-03-0

o-tolylbenzoic acid

diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
In methanol for 4h;97%
In methanol; hexane at 20℃; for 4h;97%
With methanol In hexane; benzene Methylation;
In methanol; hexane; benzene
o-tolylbenzoic acid
7148-03-0

o-tolylbenzoic acid

methyl iodide
74-88-4

methyl iodide

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
Stage #1: o-tolylbenzoic acid With potassium carbonate In acetone for 0.25h;
Stage #2: methyl iodide In acetone for 24h; Reflux;
96%
methyl chlorobenzoate
610-96-8

methyl chlorobenzoate

5,5-dimethyl-2-(4-methylphenyl)-1,3,2-dioxaborinane
380481-66-3

5,5-dimethyl-2-(4-methylphenyl)-1,3,2-dioxaborinane

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With potassium phosphate tribasic hydrate; NiIICl(1-naphthyl)(tricyclohexylphosphine)2; tricyclohexylphosphine In tetrahydrofuran at 23℃; for 4h; Suzuki-Miyaura Coupling; Inert atmosphere; Glovebox; Sealed tube;94%
o-iodo-methyl-benzoic acid
610-97-9

o-iodo-methyl-benzoic acid

p-tolyltriethoxysilane
18412-57-2

p-tolyltriethoxysilane

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); tetrabutyl ammonium fluoride In tetrahydrofuran; water at 80℃; for 40h; Hiyama Coupling;88%
o-iodo-methyl-benzoic acid
610-97-9

o-iodo-methyl-benzoic acid

tributyl(p-tolyl)stannane
31614-66-1

tributyl(p-tolyl)stannane

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; lithium chloride In N,N-dimethyl-formamide Inert atmosphere;86%
methyl 2-fluorobenzoate
394-35-4

methyl 2-fluorobenzoate

p-tolylzinc(II) chloride
90252-89-4

p-tolylzinc(II) chloride

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
Stage #1: methyl 2-fluorobenzoate; p-tolylzinc(II) chloride With bis(tricyclohexylphosphine)nickel(II) dichloride In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 25 - 100℃; for 10h; Schlenk technique; Inert atmosphere;
Stage #2: p-tolylzinc(II) chloride In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 100℃; for 10h; Inert atmosphere; Schlenk technique;
86%
methyl chlorobenzoate
610-96-8

methyl chlorobenzoate

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With potassium fluoride; palladium diacetate In toluene at 80℃; for 2h; Suzuki-Miyaura coupling;85%
With potassium phosphate; triphenylphosphine; bis(triphenylphosphine)nickel(II) chloride In toluene at 100℃; for 2h; Substitution;83%
methyl 2-((methylsulfonyl)oxy)benzoate
95667-98-4

methyl 2-((methylsulfonyl)oxy)benzoate

p-tolylzinc bromide
126403-71-2

p-tolylzinc bromide

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With hydrogenchloride; n-butyllithium; triphenylphosphine; lithium chloride; nickel dichloride In tetrahydrofuran; water82%
With hydrogenchloride; n-butyllithium; triphenylphosphine; lithium chloride; nickel dichloride In tetrahydrofuran; water82%
o-tolylbenzoic acid
7148-03-0

o-tolylbenzoic acid

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With sulfuric acid; acetic acid for 10h; Neat (no solvent); Reflux;75.23%
methyl 2-((N,N-dimethylsulfamoyl)oxy)benzoate

methyl 2-((N,N-dimethylsulfamoyl)oxy)benzoate

p-tolylzinc(II) chloride
90252-89-4

p-tolylzinc(II) chloride

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With 1-Methylpyrrolidine; C20H20ClN3Ni In tetrahydrofuran at 50℃; for 12h; Schlenk technique; Inert atmosphere;62%
o-iodo-methyl-benzoic acid
610-97-9

o-iodo-methyl-benzoic acid

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium carbonate; N-benzyl-N-(1-octynyl)-p-toluenesulfonamide In water; acetonitrile at 0 - 70℃; under 760.051 Torr; for 18h; Suzuki-Miyaura Coupling; Inert atmosphere;27%
palladium
With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate In tetrahydrofuran; water at 20 - 80℃; Suzuki Coupling; Schlenk technique; Inert atmosphere;
4-tolyl iodide
624-31-7

4-tolyl iodide

o-iodo-methyl-benzoic acid
610-97-9

o-iodo-methyl-benzoic acid

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With copper at 210℃; for 1h;11%
With bis-triphenylphosphine-palladium(II) chloride; tributyltin chloride; iodine; magnesium; lithium chloride 1.) THF, reflux, 30 min; THF, reflux, 20 h, 2.) DMF, 98 deg C, 24 h; Yield given. Multistep reaction;
sodium methylate
124-41-4

sodium methylate

2,6-di-tert-butyl-4-methylphenyl 4'-methylbiphenyl-2-carboxylate
146017-83-6

2,6-di-tert-butyl-4-methylphenyl 4'-methylbiphenyl-2-carboxylate

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
In toluene for 2.5h; Heating;
para-bromotoluene
106-38-7

para-bromotoluene

o-iodo-methyl-benzoic acid
610-97-9

o-iodo-methyl-benzoic acid

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With bis(triphenylphosphine)nickel(II) chloride; n-butyllithium; methylmagnesium bromide; zinc(II) chloride Yield given. Multistep reaction;
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

methyl 2-((methylsulfonyl)oxy)benzoate
95667-98-4

methyl 2-((methylsulfonyl)oxy)benzoate

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; potassium phosphate; n-butyllithium; [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride; potassium iodide 1.) toluene, room temperature, 30 min, 2.) toluene, 80 deg C, 16 h; Yield given. Multistep reaction;
MeO-PEG5000-[2-(4-methylphenyl)benzoate]

MeO-PEG5000-[2-(4-methylphenyl)benzoate]

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With potassium cyanide In methanol at 20℃;
methanol
67-56-1

methanol

ethyl 4′-methyl-[1,1′-biphenyl]-2-carboxylate
143573-45-9

ethyl 4′-methyl-[1,1′-biphenyl]-2-carboxylate

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With boron trifluoride diethyl etherate Heating;
ethyl 2-chlorobenzoate
7335-25-3

ethyl 2-chlorobenzoate

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: K3PO4; 2-(dicyclohexylphosphino)biphenyl based D-gluconamide / Pd(OAc)2 / H2O / 16 h / 80 °C
2: BF3*OEt2 / Heating
View Scheme
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: K3PO4; 2-(dicyclohexylphosphino)biphenyl based D-gluconamide / Pd(OAc)2 / H2O / 16 h / 80 °C
2: BF3*OEt2 / Heating
View Scheme
Multi-step reaction with 2 steps
1: PdCl2; aq. NaOH
2: benzene; methanol; hexane
View Scheme
Multi-step reaction with 2 steps
1: PdCl2; aq. NaOH
2: MeOH / hexane; benzene
View Scheme
Multi-step reaction with 2 steps
1: palladium diacetate; triphenylphosphine / acetonitrile
2: water / Acidic conditions
View Scheme
Multi-step reaction with 2 steps
1.1: palladium diacetate / water / 0.08 h / 20 °C / Inert atmosphere
1.2: 5 h / Inert atmosphere; Reflux
2.1: sulfuric acid / 5 h / Reflux
View Scheme
2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: PdCl2; aq. NaOH
2: benzene; methanol; hexane
View Scheme
Multi-step reaction with 2 steps
1: PdCl2; aq. NaOH
2: MeOH / hexane; benzene
View Scheme
Multi-step reaction with 2 steps
1: sulfuric acid / 5 h / Reflux
2: palladium diacetate; sodium carbonate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / acetonitrile; water / Reflux
View Scheme
Multi-step reaction with 2 steps
1.1: palladium diacetate / water / 0.08 h / 20 °C / Inert atmosphere
1.2: 5 h / Inert atmosphere; Reflux
2.1: sulfuric acid / 5 h / Reflux
View Scheme
2,6-di-tert-butyl-4-methylphenyl 2-methoxybenzoate
137600-70-5

2,6-di-tert-butyl-4-methylphenyl 2-methoxybenzoate

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 91 percent / diethyl ether; various solvent(s) / room temp., 17 h; reflux, 1 h
2: toluene; various solvent(s) / 2.5 h / Heating
View Scheme
2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 92 percent / trifluoroacetic anhydride / benzene / 23 h / Ambient temperature
2: 91 percent / diethyl ether; various solvent(s) / room temp., 17 h; reflux, 1 h
3: toluene; various solvent(s) / 2.5 h / Heating
View Scheme
Multi-step reaction with 6 steps
1: 95 percent / thionyl chloride / 18 h / 20 °C
2: CH2Cl2 / 2 h / 20 °C
3: thionyl chloride / 1 h / 25 °C
4: tetrahydrofuran / 2 h / 20 °C
5: 88 percent / 4.5 N aq. HCl / 12 h / Heating
6: 1.) acetyl chloride / 1.) 0 deg C, 0.25 h, 2.) reflux, 4 h
View Scheme
2-(2-methoxyphenyl)-4,4-dimethyl-2-oxazoline
57598-33-1

2-(2-methoxyphenyl)-4,4-dimethyl-2-oxazoline

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: tetrahydrofuran / 2 h / 20 °C
2: 88 percent / 4.5 N aq. HCl / 12 h / Heating
3: 1.) acetyl chloride / 1.) 0 deg C, 0.25 h, 2.) reflux, 4 h
View Scheme
Multi-step reaction with 3 steps
1: magnesium / tetrahydrofuran
2: hydrogenchloride
3: methanol
View Scheme
N-(2-hydroxy-1,1-dimethyl)-2-methoxybenzamide
74201-13-1

N-(2-hydroxy-1,1-dimethyl)-2-methoxybenzamide

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: thionyl chloride / 1 h / 25 °C
2: tetrahydrofuran / 2 h / 20 °C
3: 88 percent / 4.5 N aq. HCl / 12 h / Heating
4: 1.) acetyl chloride / 1.) 0 deg C, 0.25 h, 2.) reflux, 4 h
View Scheme
4,4-dimethyl-2-(4'-methyl-biphenyl-2-yl)-4,5-dihydrooxazole
84392-32-5

4,4-dimethyl-2-(4'-methyl-biphenyl-2-yl)-4,5-dihydrooxazole

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 88 percent / 4.5 N aq. HCl / 12 h / Heating
2: 1.) acetyl chloride / 1.) 0 deg C, 0.25 h, 2.) reflux, 4 h
View Scheme
Multi-step reaction with 2 steps
1: hydrogenchloride
2: methanol
View Scheme
2-Methoxybenzoyl chloride
21615-34-9

2-Methoxybenzoyl chloride

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: CH2Cl2 / 2 h / 20 °C
2: thionyl chloride / 1 h / 25 °C
3: tetrahydrofuran / 2 h / 20 °C
4: 88 percent / 4.5 N aq. HCl / 12 h / Heating
5: 1.) acetyl chloride / 1.) 0 deg C, 0.25 h, 2.) reflux, 4 h
View Scheme
ethylene diaminetetracetic acid

ethylene diaminetetracetic acid

para-bromotoluene
106-38-7

para-bromotoluene

o-iodo-methyl-benzoic acid
610-97-9

o-iodo-methyl-benzoic acid

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Conditions
ConditionsYield
With n-butyllithium; Zinc chloride; tetrakis(triphenylphosphine)palladium (0) In tetrahydrofuran; hexane; chloroform; water
With n-butyllithium; Zinc chloride; tetrakis(triphenylphosphine)palladium (0) In tetrahydrofuran; hexane; chloroform; water
methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

o-tolylbenzoic acid
7148-03-0

o-tolylbenzoic acid

Conditions
ConditionsYield
With sodium hydroxide In methanol; water Heating;99%
With sodium hydroxide In ethanol for 18h; Ambient temperature;47%
With sodium hydroxide In ethanol for 5h; Reflux;43%
methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

A

C15H12Br2O2

C15H12Br2O2

B

Methyl 4'-(bromomethyl)biphenyl-2-carboxylate
114772-38-2

Methyl 4'-(bromomethyl)biphenyl-2-carboxylate

Conditions
ConditionsYield
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; 2,2'-azobis(isobutyronitrile) In chloroform at 60 - 65℃;A n/a
B 92.6%
methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Methyl 4'-(bromomethyl)biphenyl-2-carboxylate
114772-38-2

Methyl 4'-(bromomethyl)biphenyl-2-carboxylate

Conditions
ConditionsYield
With N-Bromosuccinimide In dichloromethane at 25℃; for 5h; Temperature; Irradiation; Large scale;90%
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane Reflux;88%
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane85%
methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

methyl 4-(bromomethyl)-[1,1’-biphenyl]-2-carboxylate
152620-34-3

methyl 4-(bromomethyl)-[1,1’-biphenyl]-2-carboxylate

Conditions
ConditionsYield
With sulfuric acid; sodium bromide In dichloromethane; water at 25℃;80.5%
(S,Z)-1-(2-bromophenyl)-3-iodo-3-(trimethylsilyl)prop-2-en-1-ol

(S,Z)-1-(2-bromophenyl)-3-iodo-3-(trimethylsilyl)prop-2-en-1-ol

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

(Ra)-(1-(4'-methyl-[1,1'-biphenyl]-2-yl)naphthalen-2-yl)trimethylsilane

(Ra)-(1-(4'-methyl-[1,1'-biphenyl]-2-yl)naphthalen-2-yl)trimethylsilane

Conditions
ConditionsYield
Stage #1: (S,Z)-1-(2-bromophenyl)-3-iodo-3-(trimethylsilyl)prop-2-en-1-ol With isopropylmagnesium chloride; magnesium; lithium chloride In diethyl ether at 40℃; for 0.75h; Inert atmosphere;
Stage #2: methyl 4'-methylbiphenyl-2-carboxylate In diethyl ether at 20℃; for 1h; Inert atmosphere;
Stage #3: With titanium tetra-n-propoxide In tetrahydrofuran; diethyl ether at 20℃; for 3h; Inert atmosphere; stereoselective reaction;
65%
phthalic anhydride
85-44-9

phthalic anhydride

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

A

1-(2-carboxybenzoyl)-2-methylfluorenone

1-(2-carboxybenzoyl)-2-methylfluorenone

B

3'-(2-Carboxy-benzoyl)-4'-methyl-biphenyl-2-carboxylic acid methyl ester

3'-(2-Carboxy-benzoyl)-4'-methyl-biphenyl-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With aluminium trichloride; N,N-dimethyl-formamide at 70℃; for 1h;A 7%
B 60%
With aluminium trichloride; N,N-dimethyl-formamide at 70℃; for 1h;A 5%
B 60%
methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

methyl 4'-cyano-[1,1'-biphenyl]-2-carboxylate

methyl 4'-cyano-[1,1'-biphenyl]-2-carboxylate

Conditions
ConditionsYield
With hydroxylamine hydrochloride; 2,4,6-triphenylpyrylium tetrafluoroborate; oxygen; ammonium bromide In acetonitrile at 40℃; under 750.075 Torr; for 24h; Molecular sieve; Irradiation;60%
azobisisobutyronitrile
34241-39-9

azobisisobutyronitrile

methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

Methyl 4'-(bromomethyl)biphenyl-2-carboxylate
114772-38-2

Methyl 4'-(bromomethyl)biphenyl-2-carboxylate

Conditions
ConditionsYield
With N-Bromosuccinimide In tetrachloromethane59%
With N-Bromosuccinimide In tetrachloromethane
methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

(4′-methyl-[1,1′-biphenyl]-2-yl)methanol
114772-78-0

(4′-methyl-[1,1′-biphenyl]-2-yl)methanol

Conditions
ConditionsYield
With diisobutylaluminium hydride In toluene at -78 - -70℃; for 0.25h;42.55 g
methyl 4'-methylbiphenyl-2-carboxylate
114772-34-8

methyl 4'-methylbiphenyl-2-carboxylate

C14H12(2)H2O

C14H12(2)H2O

Conditions
ConditionsYield
With lithium aluminium deuteride
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