Product Description Product Name 4'-Methyl-2-cyanobiphenyl CAS No. 114772-53-1 Appearance White crystalline powder Assay ≥99% Capacity 300mt/year Min.packi
Cas:114772-53-1
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inquiryDayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:114772-53-1
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryItems Standard Result Assay 99.9%min 99.9% Hangzhou Dingyan Chem is a leading manufacturer and supplier of che
Cas:114772-53-1
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inquiryhebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm
Cas:114772-53-1
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inquiry1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; ...... Appearance:Off-white crystalline powder Storage:2-8°C Package:25kg/drum
Cas:114772-53-1
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inquiryGood quality Good price Promptly delivery Appearance:white powder Storage:dry dondition Package:According to the demand of custom Application:intermediate Transportation:According to the demand of custom Port:shanghai
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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Cas:114772-53-1
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inquiry
Cas:114772-53-1
Min.Order:1 Metric Ton
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Type:Manufacturers
inquiryAbout Product Details Item Specification Test Results Appearance White crystalline powder Conform
Cas:114772-53-1
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryTIANFUCHEM-- 114772-53-1--High purity 4'-Methyl-2-cyanobiphenyl in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established s
Cas:114772-53-1
Min.Order:1 Metric Ton
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
Cas:114772-53-1
Min.Order:1 Kilogram
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:114772-53-1
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inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:114772-53-1
Min.Order:10 Kilogram
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inquiryAdvantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&
Cas:114772-53-1
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inquiryName: 2-Cyano-4'-methylbiphenyl (4'-Methyl-2-biphenylcarbonitrile) Reference: OTBN CAS RN: 114772-53-1 Assay: ≥99.0%(HPLC) MF: C1
Cas:114772-53-1
Min.Order:5 Metric Ton
FOB Price: $1.0 / 2.0
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inquiryOur Adwantage: 1.We have stock so we can delivery quickly at the very day when receive the payment. 2.Best price, first class service, high successful delivery rate. A discount would be given when you make a large order. 3.High quality gua
Cas:114772-53-1
Min.Order:10 Gram
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Type:Other
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:114772-53-1
Min.Order:1 Kilogram
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inquiryHanways Chempharm Co., Limited, the former is Hubei Hanways Pharchem CO.,Limited, set up in 2009 in Wuhan, China. We specialize in sourcing and supplying APIs, pharmaceutical intermediates, and fine chemicals for worldwide markets. The founder has d
Cas:114772-53-1
Min.Order:1 Kilogram
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Type:Trading Company
inquiryProduct Name: 4'-Methyl-2-cyanobiphenyl CAS: 114772-53-1 MF: C14H11N MW: 193.24 EINECS: 422-310-9 Mol File: 114772-53-1.mol 4'-Methyl-2-cyanobiphenyl Structure 4'-Methyl-2-cyanobiphenyl Chemical Properties Melting poin
Cas:114772-53-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiry4'-Methyl-2-cyanobiphenyl CAS:114772-53-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality or
Cas:114772-53-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:114772-53-1
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryProduct Detail Minimum Order Qty. 10 Gram
Cas:114772-53-1
Min.Order:10 Gram
Negotiable
Type:Trading Company
inquiry1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie
Cas:114772-53-1
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryCompany information: Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big custo
Cas:114772-53-1
Min.Order:1 Kilogram
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:114772-53-1
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inquiryHangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting4'-Methyl-2-cyanobiphenyl 99% (OTBN) CAS:114772-53-1, Please contact us by email freely. We are leading exporter in China. If y
Cas:114772-53-1
Min.Order:1 Metric Ton
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inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Appearance:white powder/ Refer to COA Storage:Refer to COA
Cas:114772-53-1
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiry2-Chlorobenzonitrile
4-methylphenylboronic acid
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With potassium carbonate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate In n-heptane; water at 60℃; for 1.66667h; Suzuki Coupling; Inert atmosphere; | 100% |
With potassium carbonate In water; isopropyl alcohol at 100℃; for 7h; Catalytic behavior; Suzuki-Miyaura Coupling; Inert atmosphere; | 100% |
With bis({5-chloro-2-[(4-chlorophenyl)(hydroxyimino)methyl]phenyl})cyclodipalladachl-orane-1,3,4-tris(ylium)-2-uide; tetra(n-butyl)ammonium hydroxide; potassium carbonate; tri tert-butylphosphoniumtetrafluoroborate In N,N-dimethyl-formamide at 130℃; for 0.666667h; Suzuki-Miyaura coupling; Microwave irradiation; | 99% |
o-cyanobromobenzene
4-methylphenylboronic acid
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; caesium carbonate In 1,4-dioxane; water at 50℃; for 5h; Suzuki-Miyaura Coupling; Inert atmosphere; | 100% |
With potassium carbonate; [1-cyclohexyl-3-(di-pyridin-2-yl-methyl)-urea][PdCl2] In water at 100℃; for 1h; Suzuki-Miyaura coupling; | 99% |
With potassium carbonate; palladium dichloride In water; N,N-dimethyl-formamide at 20℃; for 0.0833333h; Suzuki cross-coupling reaction; | 99% |
Conditions | Yield |
---|---|
With dichloro[1,1′-bis[bis(1,1-dimethylethyl)phosphino]ferrocene-P,P′]palladium; TPGS-750-M; triethylamine In water at 40℃; Inert atmosphere; | 99% |
With potassium carbonate In ethanol; water at 120℃; for 2.5h; Suzuki-Miyaura reaction; continuous flow reactor; | 54% |
2-Chlorobenzonitrile
para-methylphenylmagnesium bromide
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With C35H31BrN4NiP In tetrahydrofuran at 25℃; for 17h; Schlenk technique; Inert atmosphere; | 98% |
Stage #1: para-methylphenylmagnesium bromide With zinc(II) chloride In tetrahydrofuran at 20℃; for 0.333333h; Stage #2: 2-Chlorobenzonitrile With bis(tri-t-butylphosphine)palladium(0) In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 100℃; for 24h; Negishi reaction; Further stages.; | 97% |
With chloro(1,3-bis(pyridin-2-ylmethyl)imidazolylidene)nickel(II) hexafluorophosphate In tetrahydrofuran at 20℃; for 12h; Kumada-Corriu coupling reaction; Inert atmosphere; | 85% |
2-Chlorobenzonitrile
4'-methyl-2-acetyl-1,1'-biphenyl
4-methylphenylboronic acid
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With cesium fluoride; Pd(dba)2 In 1,4-dioxane | 98% |
2-Chlorobenzonitrile
di(p-tolyl)borinic acid
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With NiCl2(Tris-(4-methoxy-phenyl)-phosphin)2; potassium phosphate tribasic trihydrate; P(p-CH3OC6H4)3 In toluene at 110℃; for 5h; Reagent/catalyst; Inert atmosphere; | 98% |
With triphenyl phosphite; potassium phosphate tribasic trihydrate; N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride; palladium diacetate In tert-butyl alcohol at 80℃; for 16h; Inert atmosphere; | 97% |
With bis(triphenylphosphine)nickel(II) chloride; potassium phosphate tribasic trihydrate; 1-n-butyl-3-methylimidazolim bromide In toluene at 110℃; for 6h; Inert atmosphere; | 97% |
o-cyanobromobenzene
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With 5%-palladium/activated carbon; oxygen; potassium carbonate In ethanol; water at 80℃; for 0.416667h; Suzuki-Miyaura Coupling; | 97% |
With palladium diacetate; potassium carbonate In ethanol; water at 25℃; for 2h; Suzuki-Miyaura Coupling; | 95% |
4,4-dimethyl-2-(4'-methyl-biphenyl-2-yl)-4,5-dihydrooxazole
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With pyridine; trichlorophosphate at 100℃; for 3h; | 96% |
With pyridine; trichlorophosphate at 10 - 100℃; for 3h; | |
Multi-step reaction with 2 steps 1: hydrogenchloride 2: thionyl chloride / water; toluene View Scheme |
o-cyanobromobenzene
4-tolylmagnesium chloride
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With 1,2-dimethoxyethane; Cl4Li2Pd; 1,3-bis-(diphenylphosphino)propane | 95% |
With 1,2-dimethoxyethane; lithium chloride; manganese(ll) chloride; 1,3-bis-(diphenylphosphino)propane; palladium dichloride In tetrahydrofuran at 20℃; for 1 - 3.5h; | 95% |
With 1,2-dimethoxyethane; 1,3-bis-(diphenylphosphino)propane; palladium diacetate | 94% |
2-Chlorobenzonitrile
sodium 4-methylbenzenesulfinate
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With palladium diacetate; XPhos In toluene at 120℃; for 40h; Inert atmosphere; Sealed tube; | 95% |
2-Chlorobenzonitrile
p-tolylzinc(II) chloride
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine)nickel(0) Negishi-like coupling reaction; | 94% |
With C26H24ClN2NiP*0.1C7H8 In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 80℃; for 24h; Negishi Coupling; Schlenk technique; Inert atmosphere; | 92% |
tris(dibenzylideneacetone)dipalladium (0); tris[tert-butyl]phosphonium tetrafluoroborate In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 175℃; for 0.166667h; Negishi cross-coupling; microwave irradiation; | 90% |
With C21H18N8Ni2O(2+)*2F6P(1-) In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 20 - 80℃; Negishi coupling reaction; | 88% |
Conditions | Yield |
---|---|
Stage #1: para-chlorotoluene With magnesium In tetrahydrofuran at 50 - 70℃; Inert atmosphere; Stage #2: 2-Chlorobenzonitrile With magnesium chloride In tetrahydrofuran at 5 - 10℃; Inert atmosphere; | 93.6% |
o-cyanobromobenzene
4-tolylmagnesium chloride
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With hydrogenchloride In tetrahydrofuran; 1,2-dimethoxyethane | 93% |
Conditions | Yield |
---|---|
Stage #1: p-toluidine With toluene-4-sulfonic acid; sodium nitrite In water at 25℃; Stage #2: benzonitrile With copper(l) iodide; sodium acetate In water at 80℃; Solvent; Temperature; Reagent/catalyst; | 92.1% |
Stage #1: p-toluidine With tetrafluoroboric acid; sodium nitrite In water at 0 - 5℃; for 0.5h; Inert atmosphere; Stage #2: benzonitrile With Tetrakis(dimethylamino)ethylen; 9-methylamino-1-ethoxyphenalenium tetrafluoroborate In dimethyl sulfoxide at 20℃; for 12h; Glovebox; Inert atmosphere; regioselective reaction; | 50% |
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With phosphorus pentoxide In tetrahydrofuran at 20℃; for 1h; | 92% |
Conditions | Yield |
---|---|
With dichloro[1,1′-bis[bis(1,1-dimethylethyl)phosphino]ferrocene-P,P′]palladium; TPGS-750-M; triethylamine In water at 20℃; Inert atmosphere; | 92% |
With Pd/Nb2O5; potassium carbonate In ethanol; water at 120℃; for 2h; Suzuki-Miyaura cross-coupling; Microwave irradiation; |
4-methylphenylboronic acid
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With C26H16Cl6N2O2Pd2; tetrabutylammomium bromide; potassium hydroxide In methanol; water at 110℃; for 0.333333h; Suzuki coupling; Microwave irradiation; | 92% |
o-cyanobromobenzene
tributyl(p-tolyl)stannane
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; lithium chloride In N,N-dimethyl-formamide Inert atmosphere; | 92% |
Conditions | Yield |
---|---|
With palladium diacetate; potassium carbonate; diisopropylamine In ethanol; water at 25℃; for 4h; | 92% |
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With formic acid | 91% |
2-iodobenzonitrile
4-methylphenylboronic acid
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With potassium phosphate Reflux; | 90.4% |
With sodium carbonate In water; ethyl acetate; isopropyl alcohol at 50℃; for 0.00111111h; Suzuki-Miyaura coupling; Microchannel flow reactor; | 99 %Chromat. |
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In N,N-dimethyl-formamide for 6h; Suzuki Coupling; Inert atmosphere; Reflux; |
2-Chlorobenzonitrile
4-tolylmagnesium chloride
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
Stage #1: 2-Chlorobenzonitrile With bis(triphenylphosphine)nickel(II) chloride; methoxydichlorozinc acid In tetrahydrofuran at 20℃; for 0.25h; Stage #2: 4-tolylmagnesium chloride In tetrahydrofuran at 28 - 32℃; Inert atmosphere; | 90% |
Stage #1: 2-Chlorobenzonitrile With chloro-trimethyl-silane; manganese(ll) chloride In tetrahydrofuran at -5 - 0℃; Inert atmosphere; Green chemistry; Stage #2: 4-tolylmagnesium chloride In tetrahydrofuran at -5 - 25℃; for 9h; Inert atmosphere; Green chemistry; | 86% |
With nickel; zinc(II) chloride In tetrahydrofuran at 50 - 60℃; Product distribution; various double metal catalysts, various yield of products; | |
With iron(III) chloride In tetrahydrofuran at 0 - 130℃; for 3h; Temperature; Grignard Reaction; Large scale; | 6.93 kg |
sodium 4-methylbenzenesulfinate
2-<(trifluoromethanesulfonyl)oxy>benzonitrile
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With palladium diacetate; XPhos In toluene at 120℃; for 24h; Sealed tube; Inert atmosphere; | 90% |
o-cyanobromobenzene
sodium 4-methylbenzenesulfinate
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With palladium diacetate; XPhos In toluene at 120℃; for 40h; Inert atmosphere; Sealed tube; | 90% |
With caesium carbonate; palladium dichloride In N,N-dimethyl-formamide at 185℃; for 20h; Inert atmosphere; Sealed tube; | 54% |
Conditions | Yield |
---|---|
With Ti0.97Pd0.03O1.97; potassium carbonate In water at 100℃; for 6h; Suzuki-Miyaura Coupling; | 89% |
Conditions | Yield |
---|---|
With hydrogenchloride; tert.-butyl lithium; zinc(II) chloride In tetrahydrofuran; pentane | 88% |
With hydrogenchloride; tert.-butyl lithium; zinc(II) chloride In tetrahydrofuran; pentane | 88% |
With hydrogenchloride; tert.-butyl lithium; zinc(II) chloride In tetrahydrofuran; pentane | 88% |
Conditions | Yield |
---|---|
With hydrogenchloride; tert.-butyl lithium; zinc(II) chloride In tetrahydrofuran; pentane | 88% |
With hydrogenchloride; tert.-butyl lithium; zinc(II) chloride In tetrahydrofuran; hexane; ethyl acetate; pentane | |
With hydrogenchloride; tert.-butyl lithium; zinc(II) chloride In tetrahydrofuran; hexane; ethyl acetate; pentane |
o-cyanobromobenzene
4-tolylmagnesium chloride
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With triphenylphosphine In tetrahydrofuran; water; toluene | 88% |
para-bromotoluene
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
Stage #1: para-bromotoluene With chloro-trimethyl-silane; ethylene dibromide; lithium chloride; zinc In tetrahydrofuran at 25℃; for 24h; Knochel Zinc Vinyl Coupling; Inert atmosphere; Stage #2: 2-(cyano)halobenzene With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride In tetrahydrofuran at 25℃; for 1h; Knochel Zinc Vinyl Coupling; Inert atmosphere; Schlenk technique; | 88% |
2-Chlorobenzonitrile
4-methylphenylboronic acid
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
With cesium fluoride In 1,4-dioxane | 87% |
2-Cyano-4'-methylbiphenyl
2-(tetrazol-5-yl)-4'-methyl-1,1'-biphenyl
Conditions | Yield |
---|---|
With trimethylsilylazide; tetrabutyl ammonium fluoride at 120℃; for 36h; | 97% |
With sodium azide; zinc(II) chloride In N,N-dimethyl-formamide for 36h; Heating; | 96% |
With sodium azide; triethylamine hydrochloride In N,N-dimethyl-formamide at 35℃; for 3h; Temperature; Sonication; | 96% |
2-Cyano-4'-methylbiphenyl
Conditions | Yield |
---|---|
Stage #1: 2-Cyano-4'-methylbiphenyl With dirhodium tetraacetate In chloroform at 70℃; Stage #2: methyl 2-diazo-2-(fluorosulfonyl)acetate In chloroform at 70℃; for 12h; | 97% |
2-Cyano-4'-methylbiphenyl
4'-(bromomethyl)-1,1'-biphenyl-2-carbonitrile
Conditions | Yield |
---|---|
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane | 96% |
With bromine In water; 1,2-dichloro-ethane at 84℃; for 0.25h; Temperature; Solvent; Irradiation; Flow reactor; | 96.3% |
With bromine In 1,2-dichloro-ethane at 70℃; for 0.5h; Reagent/catalyst; Temperature; Time; Irradiation; | 94% |
2-Cyano-4'-methylbiphenyl
5-<4'-Methyl-1,1'-biphenyl-2-yl>-1H-tetrazole
Conditions | Yield |
---|---|
Stage #1: 2-Cyano-4'-methylbiphenyl With sodium azide; zinc(II) chloride In N,N-dimethyl-formamide for 36h; Heating; Stage #2: With hydrogenchloride In N,N-dimethyl-formamide for 1h; cooling; Further stages.; | 96% |
With hydrogenchloride; sodium azide; triethylamine hydrochloride In 5,5-dimethyl-1,3-cyclohexadiene at 28 - 142℃; for 29h; | 87% |
Stage #1: 2-Cyano-4'-methylbiphenyl With sodium azide In N,N-dimethyl-formamide at 135℃; for 37h; Stage #2: With hydrogenchloride In water; ethyl acetate; N,N-dimethyl-formamide | 82% |
2-Cyano-4'-methylbiphenyl
4-Methylbiphenyl-2'-carboxamidoxime
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride In methanol; dimethyl sulfoxide | 96% |
With hydroxylamine hydrochloride; triethylamine In dimethyl sulfoxide at 80 - 85℃; for 24h; Reagent/catalyst; Solvent; | 89.6% |
2-Cyano-4'-methylbiphenyl
2-(tetrazol-5-yl)-4'-methyl-1,1'-biphenyl
Conditions | Yield |
---|---|
Zinc chloride In (2S)-N-methyl-1-phenylpropan-2-amine hydrate; N,N-dimethyl-formamide | 94% |
2-Cyano-4'-methylbiphenyl
o-(p-tolyl)-benzylamine hydrochloride
Conditions | Yield |
---|---|
Stage #1: 2-Cyano-4'-methylbiphenyl With C46H178O41Si42; titanium(IV)isopropoxide In toluene at 60℃; for 9h; Inert atmosphere; Stage #2: With hydrogenchloride; water In toluene at 20℃; for 9h; Inert atmosphere; | 94% |
2-Cyano-4'-methylbiphenyl
o-tolylbenzoic acid
Conditions | Yield |
---|---|
With potassium hydroxide In ethylene glycol at 170℃; for 48h; | 93% |
With sodium hydroxide In methanol; water at 80℃; for 10h; Temperature; Large scale; | 91.06% |
Stage #1: 2-Cyano-4'-methylbiphenyl With sodium hydroxide In ethylene glycol at 170℃; for 8h; Stage #2: With hydrogenchloride In water; toluene | 90.4% |
2-Cyano-4'-methylbiphenyl
4-methyl-2'-thiocarboxamido-1,1'-biphenyl
Conditions | Yield |
---|---|
With hydrogenchloride In methanol | 92% |
Stage #1: 2-Cyano-4'-methylbiphenyl With magnesium(II) chloride hexahydrate; sodium monohydrogensulphide hydrate In water; N,N-dimethyl-formamide at 20℃; for 2h; Stage #2: With hydrogenchloride In water for 0.333333h; | 92.1% |
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