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Antimex Chemical Limied

ProName: p-Toluidine Manufacturer/High quality/... CasNo: 106-49-0 Molecular Formula: C7H9N Appearance: Powder Application: It is an important raw material and in... DeliveryTime: prompt PackAge: according to the clients

p-Toluidine CAS 106-49-0

Cas:106-49-0

Min.Order:1 Metric Ton

FOB Price: $5.0

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

p-Toluidine Manufacturer/High quality/Best price/In stock

Cas:106-49-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality P-Methyl Aniline supplier in China

Cas:106-49-0

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Toluidine (NH2=1)

Cas:106-49-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Ality Chemical Corporation

Products: p-Toluidine Synonyms: 4-Methylaniline C.A.S: 106-49-0 Assay: 98% Molecular: C7H9N Pack: Stru

Factory Supply 4-Methylbenzenamine

Cas:106-49-0

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

p-Toluidine Basic information Product Name: p-Toluidine Synonyms: P-TOLUIDINE;P-TOLYLAMINE;P-AMINOTOLUENE;PARA-TOLUIDINE;P-METHYLANILINE;1-Amino-4-methylbenzene;4-Aminotoluen;4-aminotolu

TIANFU-CHEM CAS:106-49-0 p-Toluidine

Cas:106-49-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

p-Toluidine with CAS:106-49-0

Cas:106-49-0

Min.Order:1 Kilogram

FOB Price: $23.0 / 33.0

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

p-Toluidine CAS NO.106-49-0

Cas:106-49-0

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

p-Toluidine

Cas:106-49-0

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

p-Toluidine

Cas:106-49-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

p-Toluidine

Cas:106-49-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality P-Methyl Aniline

Cas:106-49-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity p-Toluidine

Cas:106-49-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

p-ToluidineCAS NO.: 106-49-0

Cas:106-49-0

Min.Order:1 Gram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

p-Toluidine

Cas:106-49-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Hangzhou Fandachem Co.,Ltd, a China-based chemical company, specialize in exporting P-Toluidine 99.5%, CAS:106-49-0 Please contact us by email freely. We are leading exporter in China. If you really need this cargo, please do not hes

P-Toluidine 99.5%, CAS:106-49-0 from Fandachem

Cas:106-49-0

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

p-Toluidine

Cas:106-49-0

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

4-Aminotoluene

Cas:106-49-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Colorless or light yellow liquid Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used as Pharmac

P-METHYLANILINE

Cas:106-49-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

p-Toluidine

Cas:106-49-0

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

4-Toluidine

Cas:106-49-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

p-Toluidine, 99+ %

Cas:106-49-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

p-methylaniline

Cas:106-49-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Jiangsu Glory Chemical Co., Ltd.

Para Toluidine (PT) M. F. :C7H9N M. W. :107Appearance:White to yellow brown crystal Package:In 200KGS net weight iron drum; 16MT per 20’FCL

p-Toluidine

Cas:106-49-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 106-49-0 with best price

Cas:106-49-0

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

p-Toluidine

Cas:106-49-0

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

Para Toluidine (PT) manufacture

Cas:106-49-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

106-49-0 Application:intermediate

p-Toluidine

Cas:106-49-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

4-Aminotoluene 106-49-0

Cas:106-49-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

p-Toluidine

Cas:106-49-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With triethylsilane; palladium dichloride In ethanol at 20℃; for 0.5h; Inert atmosphere;100%
With hydrazine hydrate In ethanol; water at 80℃; for 1h; chemoselective reaction;100%
With sodium tetrahydroborate In ethanol; water at 39.84℃; for 2h; Reagent/catalyst;100%
4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With triethylsilane; palladium dichloride In ethanol at 20℃; for 0.5h; Inert atmosphere;100%
With hydrogen In ethanol at 80℃; under 2250.23 Torr; for 5h; Catalytic behavior; Inert atmosphere;95%
With [IrCl(CO)(PPh3)2]; hydrazine hydrate; potassium hydroxide In methanol at 160℃; for 3h; Wolff-Kishner Reduction; Sealed tube;51%
4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With triethylsilane; palladium dichloride In ethanol at 20℃; for 0.75h; Inert atmosphere;100%
With palladium 10% on activated carbon; ammonium formate In ethanol at 100℃; for 24h; Reagent/catalyst;90%
Stage #1: 4-nitrobenzaldehdye With hydrazine hydrate at 135℃; for 3h;
Stage #2: With potassium hydroxide at 135℃; for 24h;
63%
With hydrogen In ethanol; water at 25℃; under 750.075 Torr; for 4h; Schlenk technique;
N-(tert-butoxycarbonyl)-4-methylaniline
14618-59-8

N-(tert-butoxycarbonyl)-4-methylaniline

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With water at 100℃; for 10h; Inert atmosphere;99%
With 3-butyl-l-methyl-1H-imidazol-3-iumtrifloroacetate In 1,4-dioxane; water at 70 - 72℃; for 1h;98%
With Montmorillonite K10 In dichloromethane for 2h; deacylation; Heating;97%
With water at 150℃; for 4h; Subcritical conditions;88%
With zinc(II) iodide In toluene at 120℃; for 24h; Reagent/catalyst; Schlenk technique; Inert atmosphere; Glovebox;
2-oxo-2-phenylethyl p-tolylcarbamate

2-oxo-2-phenylethyl p-tolylcarbamate

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With potassium phosphate; tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; ascorbic acid In water; acetonitrile at 20℃; for 3h; Sealed tube; Irradiation; Inert atmosphere;99%
p-methylazidobenzene
2101-86-2

p-methylazidobenzene

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With butyltriphenylphosphonium tetrahydroborate In dichloromethane at 20℃; for 0.266667h;98%
With iron(III) chloride; sodium iodide In acetonitrile at 20℃; for 0.166667h;97%
With chloro-trimethyl-silane; sodium iodide In acetonitrile for 0.0833333h; Ambient temperature;97%
para-bromotoluene
106-38-7

para-bromotoluene

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With copper(I) oxide; ammonium hydroxide In 1-methyl-pyrrolidin-2-one at 80℃; for 15h;98%
Stage #1: para-bromotoluene With bis(bis(trimethylsilyl)amido)zinc(II); tri-tert-butyl phosphine; lithium chloride; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 50℃; for 9h;
Stage #2: With hydrogenchloride In tetrahydrofuran; diethyl ether
93%
With ammonium hydroxide In neat (no solvent) at 60℃; for 8h;93%
N-(4-methylphenyl)formamide
3085-54-9

N-(4-methylphenyl)formamide

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With water; sodium hydroxide In ethanol at 65 - 70℃; for 1h;98%
With sodium hydroxide; water In 1,4-dioxane at 70℃; Kinetics; Thermodynamic data; isotope effect (D2O); ΔH(excit.), ΔS(excit.);
With sodium hydroxide In ethanol; water at 40℃; Kinetics;
4-Methylacetanilide
103-89-9

4-Methylacetanilide

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With 40% potassium fluoride/alumina at 85℃; for 0.0666667h; Microwave irradiation; Neat (no solvent);98%
With sodium hydroxide In methanol at 80℃;92%
With pepsin immobilized on terephthalaldehyde functionalized chitosan magnetic nanoparticle In acetonitrile at 20℃; for 48h; pH=2;83%
N-hydroxy-4-methylbenzamide
2318-82-3

N-hydroxy-4-methylbenzamide

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 90℃; for 2h; Lossen rearrangement;98%
With palladium diacetate; triethylamine In acetonitrile at 90℃; for 24h; Solvent; Lossen Rearrangement; Sealed tube;98%
With potassium carbonate In dimethyl sulfoxide at 90℃; for 2h; Reagent/catalyst; Solvent; Lossen Rearrangement;98%
3-azidohomoadamantane
63534-35-0

3-azidohomoadamantane

toluene
108-88-3

toluene

A

1-(adamantan-1-ylmethyl)-4-methylbenzene
76429-91-9

1-(adamantan-1-ylmethyl)-4-methylbenzene

B

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With aluminium trichloride at 80℃; for 1.5h; Yields of byproduct given;A 97%
B n/a
p-tolyl triflate
29540-83-8

p-tolyl triflate

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
Stage #1: p-tolyl triflate With bis(bis(trimethylsilyl)amido)zinc(II); tri-tert-butyl phosphine; tetrabutylammomium bromide; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 50℃; for 6h;
Stage #2: With hydrogenchloride In tetrahydrofuran; diethyl ether
97%
Multi-step reaction with 2 steps
1: Trimethyl borate; water; trifluoroacetic acid; acetone / 15 °C / UV-irradiation; Inert atmosphere
2: sodium hydroxide / methanol / 80 °C
View Scheme
N-(p-Tolyl)carbamidsaeure-β-chlorethylester
74552-28-6

N-(p-Tolyl)carbamidsaeure-β-chlorethylester

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With ammonium chloride; zinc; hydroxycobalamine In ethanol; water at 20℃; for 15h;96%
4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With sodium tetrahydroborate; titanium tetrachloride In 1,2-dimethoxyethane for 14h; Ambient temperature;96%
1,1,1-Trimethyl-N-(4-methylphenyl)-N-(trimethylsilyl)silanamine
31935-68-9

1,1,1-Trimethyl-N-(4-methylphenyl)-N-(trimethylsilyl)silanamine

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With hydrogenchloride; water In methanol at 20℃; for 1h;96%
With hydrogenchloride In diethyl ether
With hydrogenchloride In chloroform; water for 1h;23.6 mg
4-tolyl iodide
624-31-7

4-tolyl iodide

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With copper(I) oxide; ammonium hydroxide; C17H14N2O3; potassium hydroxide In ethanol at 60℃; for 24h; Schlenk technique; Inert atmosphere;96%
With ammonia; triethylamine In water at 20℃; for 3.5h;96%
With copper(l) iodide; ascorbic acid In ammonia at 25℃; for 18h; Kinetics; liquid NH3;95%
1,2,3,4-tetrahydroisoquinoline
635-46-1

1,2,3,4-tetrahydroisoquinoline

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

A

quinoline
91-22-5

quinoline

B

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With nickel-nitrogen-doped carbon framework In water at 145℃; for 18h; Inert atmosphere; Sealed tube; Green chemistry;A 94%
B 96%
2-((p-toluidino)methyl)phenol
14674-88-5

2-((p-toluidino)methyl)phenol

A

p-toluidine
106-49-0

p-toluidine

B

C21H18O3

C21H18O3

Conditions
ConditionsYield
at 230℃; under 10 Torr; for 0.0833333h; Product distribution; pyrolysis without solvent;A 95%
B n/a
trifluoroacetic acid
76-05-1

trifluoroacetic acid

S,S-dimethyl-4-methylanilinosulfonium picrate

S,S-dimethyl-4-methylanilinosulfonium picrate

A

2,2,2-trifluoro-N-(4-methylphenyl)acetamide
350-96-9

2,2,2-trifluoro-N-(4-methylphenyl)acetamide

B

p-toluidine
106-49-0

p-toluidine

C

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

Conditions
ConditionsYield
at 50℃; for 5h; Elimination; acylation; retro-Pummerer reaction;A 3%
B 95%
C 67%
N-benzyl-N-(4-methylphenyl)amine
5405-15-2

N-benzyl-N-(4-methylphenyl)amine

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With ammonium formate; zinc In ethylene glycol for 0.05h; microwave irradiation;95%
3-oxo-N-(p-tolyl)butanamide
2415-85-2

3-oxo-N-(p-tolyl)butanamide

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

A

2-Methyl-1H-benzimidazole
615-15-6

2-Methyl-1H-benzimidazole

B

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With 1-n-butyl-3-methylimidazolim bromide In neat (no solvent) at 120℃; for 2h;A 95%
B 90%
4'-methylbenzenesulphenanilide
14933-93-8

4'-methylbenzenesulphenanilide

A

2,7-dimethylphenazine
3236-92-8

2,7-dimethylphenazine

B

p-toluidine
106-49-0

p-toluidine

C

diphenyldisulfane
882-33-7

diphenyldisulfane

Conditions
ConditionsYield
With trifluoroacetic acid In benzene at 25℃;A 35%
B 55%
C 94%
7-methyl-1,2,3,4-tetrahydroquinoline
58960-03-5

7-methyl-1,2,3,4-tetrahydroquinoline

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

A

7-methylquinoline
612-60-2

7-methylquinoline

B

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With nickel-nitrogen-doped carbon framework In water at 145℃; for 18h; Inert atmosphere; Sealed tube; Green chemistry;A 92%
B 94%
4-amino-benzoic acid
150-13-0

4-amino-benzoic acid

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With dimethylsulfide borane complex In chlorobenzene 1) 15 min, r.t. 2) 5 h, reflux;93%
1,2-di(p-tolyl)diazene
501-60-0, 21650-54-4, 30926-02-4

1,2-di(p-tolyl)diazene

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With potassium hydroxide; nickel-incorporated hexagonal mesoporous aluminophosphate In isopropyl alcohol at 82.84℃; for 1.5h;93%
With perchloric acid In isopropyl alcohol; acetonitrile at 25℃; for 0.75h; pH=2; Inert atmosphere; Irradiation;92%
With ethanol; iron; calcium chloride at 60℃; for 0.5h;92%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With copper(I) oxide; ammonium hydroxide; air In methanol at 20℃; for 12h;93%
With sodium hydroxide; hydroxylamine-O-sulfonic acid In acetonitrile at 20℃; for 16h;90%
With N-Bromosuccinimide; CYANAMID; bis-[(trifluoroacetoxy)iodo]benzene In acetonitrile at 20℃; for 1h; chemoselective reaction;90%
N-{(Z)-1,3-Diphenyl-3-[(Z)-p-tolylimino]-propenyl}-methanesulfonamide
126629-91-2

N-{(Z)-1,3-Diphenyl-3-[(Z)-p-tolylimino]-propenyl}-methanesulfonamide

A

3,5-Diphenyl-2H-1,2-thiazin-1,1-dioxid
96355-37-2

3,5-Diphenyl-2H-1,2-thiazin-1,1-dioxid

B

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran at -78 - 25℃; for 12h;A 92%
B n/a
N-{(Z)-3-Phenyl-1-p-tolyl-3-[(Z)-p-tolylimino]-propenyl}-methanesulfonamide
126629-93-4

N-{(Z)-3-Phenyl-1-p-tolyl-3-[(Z)-p-tolylimino]-propenyl}-methanesulfonamide

A

5-Phenyl-3-p-tolyl-2H-[1,2]thiazine 1,1-dioxide
126629-99-0

5-Phenyl-3-p-tolyl-2H-[1,2]thiazine 1,1-dioxide

B

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran at -78 - 25℃; for 12h;A 92%
B n/a
para-chlorotoluene
106-43-4

para-chlorotoluene

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With copper(ll) sulfate pentahydrate; ammonium hydroxide In PEG1000-DIL; methyl cyclohexane at 60℃; for 8h;92%
Stage #1: para-chlorotoluene With bis(bis(trimethylsilyl)amido)zinc(II); tri-tert-butyl phosphine; lithium chloride; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 90℃; for 12h;
Stage #2: With hydrogenchloride In tetrahydrofuran; diethyl ether
90%
With copper(I) oxide; ammonium hydroxide In 1-methyl-pyrrolidin-2-one at 110℃; for 12h; Microwave irradiation;89%
furfural
98-01-1

furfural

p-toluidine
106-49-0

p-toluidine

furfurylidene-p-toluidine
13060-72-5

furfurylidene-p-toluidine

Conditions
ConditionsYield
In methanol at 20℃; for 24h;100%
In methanol at 20℃; for 24h;100%
In methanol at 20℃;85%
phthalic anhydride
85-44-9

phthalic anhydride

p-toluidine
106-49-0

p-toluidine

2-p-tolylisoindoline-1,3-dione
2142-03-2

2-p-tolylisoindoline-1,3-dione

Conditions
ConditionsYield
for 1h; Solid phase reaction; condensation;100%
With 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 80℃; for 8h;97%
In decaethylene glycol at 120℃; for 3h;97%
acetic anhydride
108-24-7

acetic anhydride

p-toluidine
106-49-0

p-toluidine

4-Methylacetanilide
103-89-9

4-Methylacetanilide

Conditions
ConditionsYield
In dichloromethane at 20℃; Inert atmosphere;100%
With Methylenediphosphonic acid at 20℃; for 1h; neat (no solvent);99%
With pyridine; aluminum oxide at 125 - 127℃; for 2h; microwave irradiation;98%
cinnamoyl chloride
102-92-1

cinnamoyl chloride

p-toluidine
106-49-0

p-toluidine

N-(4-methylphenyl)-3-phenyl-2-propenamide
6876-68-2

N-(4-methylphenyl)-3-phenyl-2-propenamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; Inert atmosphere;100%
With triethylamine In ethyl acetate at 0 - 20℃;88%
With potassium hydroxide
3-nitro-benzaldehyde
99-61-6

3-nitro-benzaldehyde

p-toluidine
106-49-0

p-toluidine

N-(3-nitrobenzylidene)-4-methylbenzenamine
17064-95-8

N-(3-nitrobenzylidene)-4-methylbenzenamine

Conditions
ConditionsYield
100%
With chitosan In ethanol; water at 20℃; for 0.333333h;85%
With ethanol
4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

p-toluidine
106-49-0

p-toluidine

N-(4-nitrobenzylidene)-4-methylaniline
730-39-2, 33442-37-4, 149742-47-2

N-(4-nitrobenzylidene)-4-methylaniline

Conditions
ConditionsYield
for 24h; Ambient temperature;100%
100%
With montmorillonite at 20℃; for 0.0666667h; Neat (no solvent);98%
2-Hydroxy-1,4-naphthoquinone
83-72-7

2-Hydroxy-1,4-naphthoquinone

p-toluidine
106-49-0

p-toluidine

2-(p-toluidino)-1,4-naphthoquinone
57182-49-7

2-(p-toluidino)-1,4-naphthoquinone

Conditions
ConditionsYield
In neat (no solvent) at 100℃; under 750.075 Torr; for 0.05h; Microwave irradiation;100%
With acetic acid
With ethanol
p-toluidine
106-49-0

p-toluidine

4-hydroxy-benzaldehyde
123-08-0

4-hydroxy-benzaldehyde

p-hydroxybenzal-p-toluidine
3230-51-1

p-hydroxybenzal-p-toluidine

Conditions
ConditionsYield
for 6h; Ambient temperature;100%
100%
In ethyl 2-hydroxypropionate at 20℃; for 0.0333333h;90%
p-toluidine
106-49-0

p-toluidine

dimedone
126-81-8

dimedone

3-(p-tolylamino)-5,5-dimethylcyclohex-2-enone
36646-78-3

3-(p-tolylamino)-5,5-dimethylcyclohex-2-enone

Conditions
ConditionsYield
at 20℃; for 0.5h; Solid phase reaction; condensation;100%
With fibrous nano silica sulfuric acid In neat (no solvent) at 80℃; for 0.0333333h; Green chemistry;97%
With silica sulfuric acid In acetonitrile for 0.0194444h; Microwave irradiation;96%
p-toluidine
106-49-0

p-toluidine

3,4-dimethoxy-benzaldehyde
120-14-9

3,4-dimethoxy-benzaldehyde

1,2-dimethoxy-4-<<(4-methylphenyl)imino>methyl>benzene
67101-90-0

1,2-dimethoxy-4-<<(4-methylphenyl)imino>methyl>benzene

Conditions
ConditionsYield
In toluene Heating;100%
p-toluidine
106-49-0

p-toluidine

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

4-methyl-N-(4-methylphenyl)benzenesulfonamide
599-86-0

4-methyl-N-(4-methylphenyl)benzenesulfonamide

Conditions
ConditionsYield
With pyridine In dichloromethane at 20℃; for 16h;100%
With pyridine at 0 - 25℃;100%
In water at 110℃; for 0.0833333h; Microwave irradiation; Green chemistry; chemoselective reaction;98%
p-toluidine
106-49-0

p-toluidine

2-chloropropionyl chloride
625-36-5

2-chloropropionyl chloride

3-chloro-N-(4-methylphenyl)propionamide
19342-88-2

3-chloro-N-(4-methylphenyl)propionamide

Conditions
ConditionsYield
In acetone for 1h; Acylation; Heating;100%
In water; acetone for 6h; Reflux;100%
With potassium carbonate In acetone at 0℃; for 1h; Condensation;95%
p-toluidine
106-49-0

p-toluidine

2-nitro-benzaldehyde
552-89-6

2-nitro-benzaldehyde

4-methyl-(2-nitrobenzylidene)aniline
17064-82-3

4-methyl-(2-nitrobenzylidene)aniline

Conditions
ConditionsYield
100%
In ethanol for 3h; Reflux;77.2%
In ethanol for 3h; Reflux;77.2%
p-toluidine
106-49-0

p-toluidine

n-butyl isocyanide
111-36-4

n-butyl isocyanide

N-butyl-N’-(4-methylphenyl)urea
22671-74-5

N-butyl-N’-(4-methylphenyl)urea

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran for 24h; Ambient temperature;100%
With toluene
p-toluidine
106-49-0

p-toluidine

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

dimethyl (Z)-N-(4-methylphenyl)aminofumarate
24559-80-6

dimethyl (Z)-N-(4-methylphenyl)aminofumarate

Conditions
ConditionsYield
at 20℃; for 0.133333h; Michael addition;100%
In benzene at 5 - 10℃;70%
In diethyl ether
maleic anhydride
108-31-6

maleic anhydride

p-toluidine
106-49-0

p-toluidine

4-methylmaleanilic acid
24870-11-9

4-methylmaleanilic acid

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 110℃; for 5h;100%
In diethyl ether at 20℃; for 2h;98%
In chloroform for 7h;97%
benzyl bromide
100-39-0

benzyl bromide

p-toluidine
106-49-0

p-toluidine

N,N-dibenzyl-4-methylbenzenamine
5459-79-0

N,N-dibenzyl-4-methylbenzenamine

Conditions
ConditionsYield
With sodium hydrogencarbonate In N,N,N,N,N,N-hexamethylphosphoric triamide for 0.5h; Heating; 3 equivalents of BzBr;100%
With montmorillonite-KSF clay supported CuO nanoparticles In neat (no solvent) at 20℃; for 0.75h; Sonication; Green chemistry; chemoselective reaction;78%
With sodium dodecyl-sulfate; sodium hydrogencarbonate In water at 80℃; for 1h; Inert atmosphere;71%
With sodium dodecyl-sulfate; sodium hydrogencarbonate In water at 80℃; for 1h;70%
4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

p-toluidine
106-49-0

p-toluidine

N-(4-chlorobenzylidene)-4-toluidine
15485-32-2

N-(4-chlorobenzylidene)-4-toluidine

Conditions
ConditionsYield
for 6h; Ambient temperature;100%
In ethyl 2-hydroxypropionate at 20℃; for 0.0333333h;96%
With montmorillonite at 20℃; for 0.1h; Neat (no solvent);96%
glyoxylic acid ethyl ester
924-44-7

glyoxylic acid ethyl ester

p-toluidine
106-49-0

p-toluidine

ethyl 2-(4-methylphenylimino)acetate
121641-60-9

ethyl 2-(4-methylphenylimino)acetate

Conditions
ConditionsYield
With sodium sulfate In dichloromethane for 0.5h;100%
With magnesium sulfate In toluene at 25℃; for 0.5h;100%
for 1h; Green chemistry;75%
1,1,1-trifluoro-4,4-diethoxy-3-buten-2-one
40657-29-2

1,1,1-trifluoro-4,4-diethoxy-3-buten-2-one

p-toluidine
106-49-0

p-toluidine

(E)-4-Ethoxy-1,1,1-trifluoro-4-p-tolylamino-but-3-en-2-one
128648-64-6

(E)-4-Ethoxy-1,1,1-trifluoro-4-p-tolylamino-but-3-en-2-one

Conditions
ConditionsYield
In acetonitrile for 18h; Ambient temperature;100%
(2-formylphenyl)butyl tellurium dibromide
128346-30-5

(2-formylphenyl)butyl tellurium dibromide

p-toluidine
106-49-0

p-toluidine

2-(4'-methylphenyliminomethinyl)phenyltellurenyl bromide
130191-28-5

2-(4'-methylphenyliminomethinyl)phenyltellurenyl bromide

Conditions
ConditionsYield
With trifluoroacetic acid In benzene100%
2-<(3-Chloropropyl)amino>-4H-3,1-benzoxazin-4-one
94507-26-3

2-<(3-Chloropropyl)amino>-4H-3,1-benzoxazin-4-one

p-toluidine
106-49-0

p-toluidine

N-(4-Methylphenyl)-2-<3-(3-chloropropyl)ureido>benzamide
94507-35-4

N-(4-Methylphenyl)-2-<3-(3-chloropropyl)ureido>benzamide

Conditions
ConditionsYield
for 0.05h; Heating;100%
4-[4a-Methoxy-7-(4-methoxy-3,6-dioxo-cyclohexa-1,4-dienyl)-5,8-dioxo-4-phenyl-4a,5,8,8a-tetrahydro-4H-quinolin-1-yl]-benzoic acid
84410-20-8

4-[4a-Methoxy-7-(4-methoxy-3,6-dioxo-cyclohexa-1,4-dienyl)-5,8-dioxo-4-phenyl-4a,5,8,8a-tetrahydro-4H-quinolin-1-yl]-benzoic acid

p-toluidine
106-49-0

p-toluidine

4-(9-Hydroxy-4a,8-dimethoxy-5,11-dioxo-4-phenyl-6-p-tolyl-4,4a,5,6,11,11a-hexahydro-pyrido[3,2-b]carbazol-1-yl)-benzoic acid
84423-43-8

4-(9-Hydroxy-4a,8-dimethoxy-5,11-dioxo-4-phenyl-6-p-tolyl-4,4a,5,6,11,11a-hexahydro-pyrido[3,2-b]carbazol-1-yl)-benzoic acid

Conditions
ConditionsYield
With sodium hydrogencarbonate In ethanol; water for 4h; Heating;100%
p-toluidine
106-49-0

p-toluidine

vanillin
121-33-5

vanillin

3-methoxy-4-{[(4-methylphenyl)imino]methyl}phenol
53304-12-4

3-methoxy-4-{[(4-methylphenyl)imino]methyl}phenol

Conditions
ConditionsYield
for 2h; Ambient temperature;100%
In ethanol for 0.333333h; Reflux;95.51%
sodium hydrogen sulfate; silica gel at 54 - 56℃; for 0.0236111h; microwave irradiation;91%
p-toluidine
106-49-0

p-toluidine

3-Bromopropionyl chloride
15486-96-1

3-Bromopropionyl chloride

3-bomo-N-(4-methylphenyl)propanamide
21437-82-1

3-bomo-N-(4-methylphenyl)propanamide

Conditions
ConditionsYield
With potassium carbonate In 1,2-dichloro-ethane at 20℃; for 1h; Time; Inert atmosphere;100%
With dmap In tetrahydrofuran at 0 - 20℃; for 1h;75%
With triethylamine In benzene70%
furfural
98-01-1

furfural

p-toluidine
106-49-0

p-toluidine

4-methyl-N-((tetrahydrofuran-2-yl)methyl)aniline

4-methyl-N-((tetrahydrofuran-2-yl)methyl)aniline

Conditions
ConditionsYield
With hydrogen; AV-17-8-Pd In ethanol at 45℃; under 750.06 Torr; Rate constant; Thermodynamic data; E(a);100%
With hydrogen; AV-17-8-Pd In ethanol at 45℃; under 750.06 Torr;100%
With Pd/Al2O3; hydrogen In ethanol at 80℃; under 750.075 Torr; for 12h;94%
p-toluidine
106-49-0

p-toluidine

Cinnamoyl chloride
102-92-1

Cinnamoyl chloride

(2E)-N-(4-methylphenyl)-3-phenylprop-2-enamide
134430-88-9

(2E)-N-(4-methylphenyl)-3-phenylprop-2-enamide

Conditions
ConditionsYield
With potassium carbonate In water; acetone at 0℃; for 2h;100%
Stage #1: Cinnamoyl chloride With pyridine; dmap In dichloromethane at 0℃; for 0.416667h; Inert atmosphere;
Stage #2: p-toluidine In dichloromethane at 0 - 20℃;
86%
With dmap; sodium hydrogencarbonate In dichloromethane at 20℃;84%
cyclohexane-1,2-epoxide
286-20-4

cyclohexane-1,2-epoxide

p-toluidine
106-49-0

p-toluidine

trans-2-(p-tolylamino)cyclohexanol

trans-2-(p-tolylamino)cyclohexanol

Conditions
ConditionsYield
With zirconium(IV) chloride at 20℃; for 0.25h;100%
With [{(CH3)5Cp}2Zr(CH3CN)2(H2O)][OSO2C6F5]2·CH3CN In neat (no solvent) at 20℃; for 0.166667h; diastereospecific reaction;99%
With zinc(II) perchlorate hexahydrate at 20℃; for 0.5h;98%
bromocyane
506-68-3

bromocyane

p-toluidine
106-49-0

p-toluidine

N-(4-methylphenyl)cyanamide
10532-64-6

N-(4-methylphenyl)cyanamide

Conditions
ConditionsYield
With trimethylamine Ambient temperature;100%
In diethyl ether; tetrahydrofyran at 0℃; for 4h;95%
With triethylamine In diethyl ether at 0℃;83%
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