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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Nitrotoluene Manufacturer/High quality/Best price/In stock

Cas:99-99-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hefei TNJ chemical industry co.,ltd

Technology: Technology innovation is our eternal pursuit,or we will be left behind.Our technology experts,all from famous universities and institutes,has rich experience and high achievements in chemical research.This makes sure that our technology

Para-Nitrotoluene

Cas:99-99-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Wuhan Kemi-Works Chemical Co., Ltd

Product name: 4-Nitrotoluene CAS No. 99-99-0 Molecular formula : C7H7NO2 1.We have been specializing in special fine chemical for long, with strong R&D strength. 2.ISO9001. 3.We have been cooperating with oversea from Europe, USA, Korea

4-Nitrotoluene

Cas:99-99-0

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

99-99-0,4-Nitrotoluene

Cas:99-99-0

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

4-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Para Nitro Toluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

4-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

Para Nitro Toluene (PNT) manufacture

Cas:99-99-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HWRK Chem

in store Package:100g Application:Organic Chemicals

4-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

1-Methyl-4-nitrobenzene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Other

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Our Services 1.Certificate Of Analysis (COA) 2.Material Safety Data Sheet (MSDS) 3.Route of synthesis (ROS) 4.Method of Aanlysis (MOA) 5.Nuclear Magnetic Resonance (NMR) 6.Packing pictures and loading video before loading 7.Free Sampl

4-Nitrotoluene 99-99-0

Cas:99-99-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

SuZhou LaiTeou

1, Quality: Our company is a professional production of intermediates and chemicals for many years, our products have exported to Germany, Spain, UK, USA, Australia, Middle East, and so on other country, and we have got very good feedback fro

4-Nitrotoluene

Cas:99-99-0

Min.Order:1 Gram

FOB Price: $45.0

Type:Trading Company

inquiry

Watson International Ltd

Watson International Ltd' has a very strong R&D and technical capacity supported by FCAD's platform. The subsidiaries under FCAD Group have accumulated much know-how of different fine chemical branches. For example, Apnoke Scientific L

4-Nitrotoluene

Cas:99-99-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai AngewChem Co., Ltd.

99%, in stock Shanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale

4-Nitrotoluene

Cas:99-99-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Chemical Technology Co.,LTD

1. Production capacity: we have three production base with high-tech production equipment and instruments, equipped with professional production personnel, meet your requirements.2. Quality assurance: we have a first-class testing equipment and testi

4-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Other

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

sub/micron to mesh powders (near/spheres, whiskers, flake, fiber, porous) and grain/ball, thin/ thick metal / alloys pieces / parts, thin and thick (particle) film materials /target, and custom-made crystals, substrates/parts. In the industries and a

p-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

4-Nitrotoluene

Cas:99-99-0

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

ORCHID CHEMICAL SUPPLIES LTD

4-Nitrotoluene CAS#99-99-0 Storage:Keep container tightly closed in a dry, cool and well-ventilated place. Package:25Kg/drum, 150Kg/drum, 200kg/drum, According to request. Transportation:By sea, by air.

4-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Other

inquiry

Nanjing Chemlin Chemical Co., Ltd.

Nanjing Chemlin Chemical Industry Co., Ltd was established in Aug,1999, located in the industrial park of Nanjing University of Technology, It is a private enterprises in Jiangsu Province with 1200 square meters’ R&D center. Our R&D center has a well

99-99-0

Cas:99-99-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Kunshan Yalong Trading Co,.Ltd

4-Nitrotoluene Package:25kg/fiber can

4-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Skyrun Industrial Co.,Ltd

SkyRun Industrial CO.,LTD is a leading chemical producer in China. We supply Intermediate, Agro-Chemical and Petrol Chemicals for different usage.SkyRun Industrial CO.,LTD is a leading chemical producer in China. We supply Intermediate, Agro-Chemic

4-Nitrotoluene, 99%

Cas:99-99-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Raymon Biotech Co., Ltd.

Benzene,1-methyl-4-nitro- Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen

Benzene,1-methyl-4-nitro-

Cas:99-99-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuxi Morality Chemical Co., Ltd

Do best quality products, erect the morality model Application:please email us, thanks

4-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Other

inquiry

Antaeus Bio-technology Co., LTD

Antaeus-biotech with Established in July 5871 is a high-technical enterprise which focus on the development of health products. We have excellent professionals, first-class facilities and perfect management system. Through persistent efforts, we cont

4-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai united Scientific Co.,Ltd.

Benzene,1-methyl-4-nitro-

Cas:99-99-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Langchem

1.We are specializing in providing customers with complete chemical raw materials.2.Superior quality, moderate price & quick delivery.3. Extensive international cooperation experience.4. Outstanding communication skills. Application:contact us for de

4-Nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changzhou Foreign Trade Corp

CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

4-nitrotoluene

Cas:99-99-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

yuyongmei

YUYONGMEI was established in Aug,1999, located in the industrial park of Nanjing University of Technology, It is a private enterprises in Jiangsu Province with 1200 square meters’ R&D center. Our R&D center has a well-equipped synthetic laboratory a

Benzene,1-methyl-4-nitro-

Cas:99-99-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

4-nitrobenzeneacetic acid
104-03-0

4-nitrobenzeneacetic acid

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
copper(I) oxide In acetonitrile at 50℃;100%
With [Rh(OH)(cod)]2; 1,3-bis-(diphenylphosphino)propane; water; sodium hydroxide In toluene at 100℃; for 16h; Inert atmosphere;87%
With potassium carbonate In chloroform at 20℃; for 24h; Irradiation; Inert atmosphere;81%
p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

(CH3)4Sn

(CH3)4Sn

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
polymer supported palladium catalyst In N,N,N,N,N,N-hexamethylphosphoric triamide at 70℃; for 1h; Stille coupling reaction;100%
4-nitrobenzenediazonium o-benzenedisulfonimide

4-nitrobenzenediazonium o-benzenedisulfonimide

tetramethylstannane
594-27-4

tetramethylstannane

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
palladium diacetate In tetrahydrofuran at 40℃; for 0.5h;100%
4-nitrobenzyl chloride
100-14-1

4-nitrobenzyl chloride

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With sodium tetrahydroborate; cetyltributylphosphonium bromide In water; toluene at 40℃; for 0h; Product distribution;99%
With phosphonic Acid; iodine In benzene at 100℃; for 36h; Inert atmosphere;42%
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) In toluene for 3h; Mechanism; Irradiation;24%
1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With sodium tetrahydroborate; cetyltributylphosphonium bromide In water; toluene at 18℃; for 0h; Product distribution;99%
With sodium tetrahydroborate In aq. phosphate buffer at 70℃; for 2.5h; pH=12; Reagent/catalyst; Green chemistry;95%
With sodium tetrahydroborate In various solvent(s) at 70℃; for 10h;88%
potassium (4-methylphenyl)trifluoroborate

potassium (4-methylphenyl)trifluoroborate

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With bismuth (III) nitrate pentahydrate In toluene at 120℃; for 0.333333h; Reagent/catalyst; Microwave irradiation;99%
With sodium dihydrogen phosphate monohydrate; dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II); sodium nitrite In toluene at 120℃; for 0.5h; Microwave irradiation; Inert atmosphere;33%
p-toluidine
106-49-0

p-toluidine

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With calcium tungstate; dihydrogen peroxide In water at 50℃; for 0.5h; Reagent/catalyst; Green chemistry; Large scale;98%
With oxaziridinium tetrafluoroborate derived from N-methyl-1,2,3,4-tetrahydroisoquinoline In dichloromethane at 0℃; for 10h;92%
With 1,9-diperoxynonanedioic acid In acetonitrile at 50℃; for 0.5h;92%
p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

tetramethylstannane
594-27-4

tetramethylstannane

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With C31H33INPPd In N,N-dimethyl-formamide at 80℃; for 24h; Stille coupling;98%
With iodophenylbis(triphenylphosphine)palladium In N,N,N,N,N,N-hexamethylphosphoric triamide at 70℃; for 0.5h;87%
toluene
108-88-3

toluene

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With sodium nitrate In neat (no solvent) at 20℃; for 0.05h; Catalytic behavior; Reagent/catalyst; Green chemistry;96%
With nitric acid; sodium dodecyl-sulfate In water at 25℃; for 0.333333h; Micellar solution; Green chemistry; regioselective reaction;86%
With tetrammine copper(II) sulphate; nitric acid In dichloromethane; water at 20℃; for 3h; regioselective reaction;85%
2-methyl-5-nitrobenzenediazonium o-benzenedisulfonimide

2-methyl-5-nitrobenzenediazonium o-benzenedisulfonimide

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With dihydrogen peroxide In tetrahydrofuran for 0.166667h; Heating;94%
Trimethylboroxine
823-96-1

Trimethylboroxine

4-chlorobenzonitrile
100-00-5

4-chlorobenzonitrile

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With potassium fluoride; 18-crown-6 ether; bis-phenanthrylimidazolium chloride; palladium diacetate In tetrahydrofuran at 20℃; for 8h; Suzuki-Miyaura coupling;93%
5-methyl-2-nitrobenzoic acid
3113-72-2

5-methyl-2-nitrobenzoic acid

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With sulfolane; sodium hydrogencarbonate at 230℃; for 2.5h; Temperature; Reagent/catalyst;92%
With copper(l) iodide; triethylamine In dimethyl sulfoxide at 120℃; under 760.051 Torr; for 20h; Inert atmosphere; Schlenk technique;88%
With copper(I) oxide; 1,10-Phenanthroline In 1-methyl-pyrrolidin-2-one; quinoline at 190℃; for 0.0833333h; Microwave irradiation;80%
With copper(I) oxide at 120℃; for 24h; Ionic liquid;
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With Iron(III) nitrate nonahydrate In toluene at 80℃; for 18h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Inert atmosphere;92%
With N-Bromosuccinimide; [bis(trifluoroacetoxy)iodo]benzene; sodium nitrite In acetonitrile at 20℃; for 3h; regioselective reaction;92%
With bismuth (III) nitrate pentahydrate In toluene at 70 - 80℃; for 1.5h; Inert atmosphere;87%
toluene
108-88-3

toluene

A

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

B

1-methyl-2-nitrobenzene
88-72-2

1-methyl-2-nitrobenzene

Conditions
ConditionsYield
With nickel ammonium sulfate; nitric acid In chloroform; water at 20℃; for 4h;A 88%
B 12%
With sodium nitrite for 0.0166667h; Reagent/catalyst; Microwave irradiation;A 82%
B 15%
With bismuth(III) nitrate In tetrachloromethaneA 80%
B n/a
4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With n-butylsilane; tris(pentafluorophenyl)borate In dichloromethane87%
With hydrogen; palladium on activated charcoal In methanol under 760 Torr; for 18h;33%
p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

tris(diethylamino)sulfonium difluorotrimethylsiliconate
59201-86-4

tris(diethylamino)sulfonium difluorotrimethylsiliconate

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
π-allyl-palladium chloride In tetrahydrofuran 1.) room temperature; 2.) 50 deg C, 20 h;86%
p-tolyllithium
2417-95-0

p-tolyllithium

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With dinitrogen tetraoxide In tetrahydrofuran -190 deg C -> room temperature;86%
4-methyl-N'-[(4-nitrophenyl)methylidene]benzene-1-sulfonohydrazide
1747-50-8

4-methyl-N'-[(4-nitrophenyl)methylidene]benzene-1-sulfonohydrazide

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With dichloro bis(1,4-diazabicyclo[2.2.2]octane)(BH4)Zr(IV); toluene-4-sulfonic acid In sulfolane; N,N-dimethyl-formamide at 110℃; for 6h;86%
para-nitrophenyl triflate
17763-80-3

para-nitrophenyl triflate

potassium trifluoro(methyl)boranuide

potassium trifluoro(methyl)boranuide

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; water; caesium carbonate In tetrahydrofuran Suzuki coupling reaction; Heating;85%
toluene
108-88-3

toluene

A

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

B

1-methyl-2-nitrobenzene
88-72-2

1-methyl-2-nitrobenzene

C

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With methanesulfonic acid; 1-butyl-3-methylimidazolium nitrate In water for 48h; Heating / reflux;A n/a
B n/a
C 85%
With nitric acid; 1-butyl-3-methylimidazolium nitrate In water for 48h; Heating / reflux;A n/a
B n/a
C 85%
With nitric acid; 1-n-butyl-3-methylimidazolium methanesulfonate In water for 48h; Heating / reflux;A n/a
B n/a
C 70%
With nitric acid; 1-n-butyl-3-methylimidazolium methanesulfonate In water for 48h; Heating / reflux;A n/a
B n/a
C 70%
toluene
108-88-3

toluene

A

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

B

2,4-dinitrotoluene
121-14-2

2,4-dinitrotoluene

C

2,6-dinitrotoluene
606-20-2

2,6-dinitrotoluene

Conditions
ConditionsYield
With succinic acid anhydride; nitric acid at 4℃; for 50h; Product distribution / selectivity;A 7.9%
B 85%
C 6.3%
With nitric acid; dichloroacetic anhydride In dichloromethane at 50℃; for 0.166667h; Time;
p-Toluic acid
99-94-5

p-Toluic acid

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With nitronium tetrafluoborate; silver carbonate In N,N-dimethyl acetamide at 90℃; for 12h; Inert atmosphere; Schlenk technique; regioselective reaction;85%
With 1,3-disulfonic acid imidazolium nitrate In neat (no solvent) at 50℃; for 0.5h; Inert atmosphere;76%
Dimethyl-p-toluidine
99-97-8

Dimethyl-p-toluidine

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With tert.-butylhydroperoxide; ammonium iodide; water In dimethyl sulfoxide at 90℃; for 4h; Mechanism; Temperature; Reagent/catalyst; Solvent; Time; Sealed tube;85%
C12H13NO4

C12H13NO4

A

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

B

C11H13NO2

C11H13NO2

Conditions
ConditionsYield
With C53H50IrNO2P(1-)*ClO4(1-); 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20℃; for 14h; Reagent/catalyst; Inert atmosphere; Sealed tube; enantioselective reaction;A n/a
B 83%
p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

methylmercury(II) iodide
143-36-2

methylmercury(II) iodide

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With bis(benzonitrile)palladium(II) dichloride; sodium iodide In N,N-dimethyl-formamide at 20℃; for 0.333333h; Inert atmosphere;82%
With PhPd(PPh3)2 In N,N,N,N,N,N-hexamethylphosphoric triamide at 70℃; for 1.5h; Product distribution; other solvent, reaction time, temperature;91 % Chromat.
With iodide; iodophenylbis(triphenylphosphine)palladium In acetone at 20℃; for 0.5h;98 % Chromat.
tetramethylstannane
594-27-4

tetramethylstannane

p-nitrobenzenediazonium hydrogen sulfate

p-nitrobenzenediazonium hydrogen sulfate

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
palladium diacetate In water; acetonitrile at 20℃; for 2h;81%
With palladium diacetate In water; acetonitrile at 20℃; for 2h;81%
palladium diacetate In water; acetonitrile at 20℃; for 2h; other aryldiazonium salts;81%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

para-nitrophenyl triflate
17763-80-3

para-nitrophenyl triflate

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With potassium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In tetrahydrofuran; water for 18h; Suzuki coupling reaction; Heating;80%
para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

(CH3)4Sn

(CH3)4Sn

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
polymer supported palladium catalyst In N,N-dimethyl-formamide at 70℃; for 4h; Stille coupling reaction;80%
bis(4-methylphenyl)iodonium trifluoromethanesulfonate
123726-16-9

bis(4-methylphenyl)iodonium trifluoromethanesulfonate

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With sodium nitrite In ethyl acetate at 70℃; for 16h; Sealed tube;80%
toluene
108-88-3

toluene

A

1-methyl-3-nitrobenzene
99-08-1

1-methyl-3-nitrobenzene

B

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

C

1-methyl-2-nitrobenzene
88-72-2

1-methyl-2-nitrobenzene

Conditions
ConditionsYield
With copper(II) nitrate on K10 montmorillonite; acetic anhydride In tetrachloromethane for 120h; Ambient temperature;A 1%
B 79%
C 20%
With nitric acid In trifluoroacetic acid at 25℃; Rate constant;A 0.7%
B 66.7%
C 32.6%
With ortho-methylphenyl iodide; potassium nitrate In trifluoroacetic acid for 0.5h; Product distribution; nitration of aromatic compounds in the presence of aryl iodides; other temperatures, other reagents;A n/a
B 64%
C 33%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

2,4-dinitrotoluene
121-14-2

2,4-dinitrotoluene

Conditions
ConditionsYield
With nitric acid at 50℃; for 3h;100%
With nitrourea; sulfuric acid at 25℃; for 24h;99%
With ethylene glycol dinitrate In sulfuric acid at 0 - 20℃;99%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

N-(4-methylphenyl)hydroxylamine
623-10-9

N-(4-methylphenyl)hydroxylamine

Conditions
ConditionsYield
With 5% rhodium-on-charcoal; hydrazine hydrate In tetrahydrofuran at 0℃; for 2.5h; Inert atmosphere;100%
With 5% rhodium-on-charcoal; hydrazine hydrate In tetrahydrofuran at 0℃; Inert atmosphere;100%
With rhodium contaminated with carbon; hydrazine hydrate In tetrahydrofuran at 0℃; for 2.5h; Inert atmosphere;100%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

2-methyl-5-nitrobenzene-1-sulfonyl chloride
121-02-8

2-methyl-5-nitrobenzene-1-sulfonyl chloride

Conditions
ConditionsYield
With chlorosulfonic acid100%
With chlorosulfonic acid at 60℃; for 20h;96%
With chlorosulfonic acid at 5 - 140℃; for 22.5h;80.6%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

p-toluidine
106-49-0

p-toluidine

Conditions
ConditionsYield
With triethylsilane; palladium dichloride In ethanol at 20℃; for 0.5h; Inert atmosphere;100%
With hydrazine hydrate In ethanol; water at 80℃; for 1h; chemoselective reaction;100%
With sodium tetrahydroborate In ethanol; water at 39.84℃; for 2h; Reagent/catalyst;100%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With dihydrogen peroxide; bromine In dichloromethane; water for 4h; Reagent/catalyst; Reflux;100%
With 2,2'-azobis(isobutyronitrile); hydrogen bromide; dihydrogen peroxide at 70 - 120℃; Reagent/catalyst; Temperature;99.3%
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 3h; Reflux;95%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

acetic anhydride
108-24-7

acetic anhydride

4-Methylacetanilide
103-89-9

4-Methylacetanilide

Conditions
ConditionsYield
With ammonium formate; titanium(IV) oxide; β‐cyclodextrin In water for 3.5h; Irradiation; Inert atmosphere;100%
Stage #1: 1-methyl-4-nitrobenzene With sodium tetrahydroborate In water at 60 - 70℃; Green chemistry;
Stage #2: acetic anhydride In water at 60 - 70℃; Green chemistry;
95%
Stage #1: 1-methyl-4-nitrobenzene With sodium tetrahydroborate In water at 20℃; for 0.5h; Green chemistry;
Stage #2: acetic anhydride In water at 20℃; for 2.16667h; Green chemistry;
95%
propyl cyanide
109-74-0

propyl cyanide

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

A

N,N-dibutyl-4-methylaniline
31144-33-9

N,N-dibutyl-4-methylaniline

B

N-butyl-4-methylaniline
10387-24-3

N-butyl-4-methylaniline

Conditions
ConditionsYield
Stage #1: 1-methyl-4-nitrobenzene With ammonium formate; palladium on activated charcoal In methanol; water at 20℃;
Stage #2: propyl cyanide In methanol; water
A n/a
B 100%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

propiononitrile
107-12-0

propiononitrile

A

N-propyl-p-tolylamine
54837-90-0

N-propyl-p-tolylamine

B

4-methyl-N,N-dipropylaniline
3480-93-1

4-methyl-N,N-dipropylaniline

Conditions
ConditionsYield
Stage #1: 1-methyl-4-nitrobenzene With ammonium formate; palladium on activated charcoal In methanol; water at 20℃;
Stage #2: propiononitrile In methanol; water
A 100%
B n/a
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

2,5-hexanedione
110-13-4

2,5-hexanedione

2,5-dimethyl-1-p-tolyl-1H-pyrrole
5044-26-8

2,5-dimethyl-1-p-tolyl-1H-pyrrole

Conditions
ConditionsYield
With formic acid for 12h; Autoclave; Inert atmosphere; Green chemistry;100%
With indium; acetic acid In toluene at 80℃; for 2.5h; Inert atmosphere;98%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

1-nitro-4-(trichloromethyl)benzene
3284-64-8

1-nitro-4-(trichloromethyl)benzene

Conditions
ConditionsYield
With hypochlorous anhydride In tetrachloromethane at 25℃; for 96h;99%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

benzaldehyde
100-52-7

benzaldehyde

trans-4-nitrostilbene
1694-20-8

trans-4-nitrostilbene

Conditions
ConditionsYield
With 18-crown-6 ether; graphitic carbon nitride In toluene at 25℃; for 0.5h; Catalytic behavior; Reagent/catalyst; Temperature; Solvent; Knoevenagel Condensation;99%
With potassium carbonate at 90℃; for 2h; neat (no solvent); stereoselective reaction;71%
heptanal
111-71-7

heptanal

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

N-heptyl-4-methylbenzene amine
371959-15-8

N-heptyl-4-methylbenzene amine

Conditions
ConditionsYield
With Au/Al2O3; hydrogen In toluene at 80℃; under 37503.8 Torr; Temperature; Flow reactor; chemoselective reaction;99%
With hydrogen In toluene at 110℃; under 22502.3 Torr; Catalytic behavior; Temperature; Flow reactor;92 %Chromat.
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

p-toluidine
106-49-0

p-toluidine

1-methylcyclohexan-4-one
589-92-4

1-methylcyclohexan-4-one

di-p-tolylamine
620-93-9

di-p-tolylamine

Conditions
ConditionsYield
palladium-carbon In water; N,N-dimethyl-formamide; benzene98.6%
palladium-carbon In water; N,N-dimethyl-formamide; benzene98.6%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

4-nitrotoluene-2-sulfonic acid sodium salt
5258-64-0

4-nitrotoluene-2-sulfonic acid sodium salt

Conditions
ConditionsYield
Stage #1: 1-methyl-4-nitrobenzene With chlorosulfonic acid at 115℃; for 3h;
Stage #2: With sodium carbonate In water at 20℃;
98.2%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

2-bromo-4-nitrotoluene
7745-93-9

2-bromo-4-nitrotoluene

Conditions
ConditionsYield
With bromine fluoride In ethanol; chloroform at -40℃; for 1h;98%
With thallium (III) oxide; trifluoroacetic acid; potassium bromide at 20℃; for 165h;98%
With N-Bromosuccinimide; sulfuric acid In water at 20℃; for 24h;93%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

Conditions
ConditionsYield
With oxygen; 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt In tetrahydrofuran Ambient temperature; laccase from Coriolus versicolor;98%
With dihydrogen peroxide In acetonitrile at 50 - 80℃; for 24h; Reagent/catalyst;95%
With nickel-doped graphene carbon nitride nanoparticles; air In ethanol at 25℃; for 8h; Irradiation; Green chemistry;95%
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

N-(4-methylphenyl)formamide
3085-54-9

N-(4-methylphenyl)formamide

Conditions
ConditionsYield
With cobalt nanoparticles coated by N,P-codoped carbon shell pyrolyzed at 800°C In tetrahydrofuran at 120℃; for 12h; Schlenk technique; Inert atmosphere;98%
With hydrogen; palladium on activated charcoal In acetonitrile at 95℃; for 7h;89%
With gold nanoparticles supported on titanium dioxide (TiO2) In acetonitrile for 3h; Inert atmosphere; Reflux;88%
With glycolic Acid at 30℃; for 48h; Catalytic behavior; Reagent/catalyst; Temperature; Irradiation; Inert atmosphere;85 %Spectr.
1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

N-(tert-butoxycarbonyl)-4-methylaniline
14618-59-8

N-(tert-butoxycarbonyl)-4-methylaniline

Conditions
ConditionsYield
Stage #1: 1-methyl-4-nitrobenzene With sodium tetrahydroborate In water at 20℃; for 0.5h; Green chemistry;
Stage #2: di-tert-butyl dicarbonate In water at 20℃; for 1.16667h; Green chemistry;
98%
With tin; ammonium chloride In methanol at 25℃; for 4.5h; Sonication;87%
formaldehyd
50-00-0

formaldehyd

1-methyl-4-nitrobenzene
99-99-0

1-methyl-4-nitrobenzene

ethyl acetoacetate
141-97-9

ethyl acetoacetate

ethyl 3-(N-methyl-N-4-tolylamino)butanoate

ethyl 3-(N-methyl-N-4-tolylamino)butanoate

Conditions
ConditionsYield
Stage #1: 1-methyl-4-nitrobenzene; ethyl acetoacetate With Decaborane; palladium on activated charcoal In methanol for 1.5h; Heating;
Stage #2: With Decaborane In methanol at 20℃; for 2h;
Stage #3: formaldehyd With Decaborane In methanol; water at 20℃; for 3h;
98%

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