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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

Methylboronic acid

Cas:13061-96-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methylboronic Acid

Cas:13061-96-6

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 13061-96-6 Methylboronic acid Manufacturer

Cas:13061-96-6

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product specifica

Methylboronic acid

Cas:13061-96-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Methaneboronic acid

Cas:13061-96-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Methylboronic acid / LIDE PHARMA- Factory supply / Best price

Cas:13061-96-6

Min.Order:1 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU CHEM----Methylboronic acid

Cas:13061-96-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

TopCAS 13061-96-6 with fast shipping

Cas:13061-96-6

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Methylboronic acid 13061-96-6

Cas:13061-96-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

Methylboronic Acid CAS No. 13061-96-6

Cas:13061-96-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Methylboronic acid

Cas:13061-96-6

Min.Order:1 Kilogram

FOB Price: $76.0 / 85.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Methylboronic acid CAS:13061-96-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm

Methylboronic acid CAS:13061-96-6

Cas:13061-96-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Methylboronic acid

Cas:13061-96-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe,

Methylboronic acid Cas 13061-96-6

Cas:13061-96-6

Min.Order:1 Kilogram

FOB Price: $135.0 / 150.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Methylboronic acid

Cas:13061-96-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methylboronic Acid

Cas:13061-96-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

Methylboronic acid

Cas:13061-96-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Methylboronic acid

Cas:13061-96-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

METHYL BORONIC ACID

Cas:13061-96-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methylboronic acid

Cas:13061-96-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products Methylboronic acid

Cas:13061-96-6

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Methylboronic acid/High quality/Best price

Cas:13061-96-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Methylboronic Acid

Cas:13061-96-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:white to light yellow crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:suzuki reaction Transportation:as

Methylboronic acid-

Cas:13061-96-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Methylboron dihydroxide, GLC Grade

Cas:13061-96-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: Methylboronic acid CAS: 13061-96-6 MF: CH5BO2 MW: 59.86 EINECS: 629-203-8 Mol File: 13061-96-6.mol Methylboronic acid Structure Methylboronic acid Chemical Properties Melting point 91-94 °C (lit.) Boiling poi

Methylboronic acid

Cas:13061-96-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Methylboronic acid

Cas:13061-96-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

Methylboronic acid

Cas:13061-96-6

Min.Order:0

Negotiable

Type:Other

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/Methylboronic acid/SAGECHEM/Manufacturer in China

Cas:13061-96-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Methylboronic acid cas no. 13061-96-6 98%

Cas:13061-96-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

dimethyl sulfide borane
13292-87-0

dimethyl sulfide borane

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

Conditions
ConditionsYield
With carbon monoxide; water In tetrahydrofuran byproducts: S(CH3)2; a soln. of BH3*S(CH3)2 flushed with CO; a soln. of catalyst added, stirred rapidly and maintained at 25°C for 12-16 h; water added; evapd.;94%
Triisopropyl borate
5419-55-6

Triisopropyl borate

methyllithium
917-54-4

methyllithium

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

Conditions
ConditionsYield
With hydrogenchloride In diethyl ether byproducts: LiCl, i-propanol; (N2); a soln. of B(O-i-Pr)3 cooled with a dry ice-acetone bath; CH3Li added slowly and stirred for 1 h; allowed to warm to room temp. with stirring for 3 h; cooled to 0°C; a soln. of HCl in ether added and stirred for 0.5 h; decanted; hydrolyzed with water; distd.; dried;79%
methyl magnesium iodide
917-64-6

methyl magnesium iodide

Trimethyl borate
121-43-7

Trimethyl borate

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

Conditions
ConditionsYield
With diethyl ether Zers. des Reaktionsproduktes durch angesaeuertes Wasser, wobei Verseifung des intermediaer gebildeten Methylborsaeureesters stattfindet;
Trimethyl borate
121-43-7

Trimethyl borate

methylmagnesium bromide
75-16-1

methylmagnesium bromide

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

Conditions
ConditionsYield
With diethyl ether und anschliessend mit wss.H2SO4;
Trimethyl borate
121-43-7

Trimethyl borate

methylmagnesium iodide

methylmagnesium iodide

A

trimethylborane
593-90-8

trimethylborane

B

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

Conditions
ConditionsYield
Zers. des entstandenen 'Methylborsaeuredimethylesters' CH3B(OCH3)2 durch angesaeuertes Wasser;
dibromomethylborane
17933-16-3

dibromomethylborane

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

Conditions
ConditionsYield
With water
With water
2,4,6-Trimethyl-[1,3,5,2,4,6]triazatriborinane
5314-85-2

2,4,6-Trimethyl-[1,3,5,2,4,6]triazatriborinane

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

Conditions
ConditionsYield
With water at 150℃;
1,2-Dimethylboran
16321-94-1

1,2-Dimethylboran

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

Conditions
ConditionsYield
With water at 150℃;
hydrogenchloride
7647-01-0

hydrogenchloride

hexamethylborazine
877-07-6

hexamethylborazine

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

methylamine hydrochloride
593-51-1

methylamine hydrochloride

Conditions
ConditionsYield
at 100℃; Hydrolysis;
Trimethyl borate
121-43-7

Trimethyl borate

CH3MgCl

CH3MgCl

A

trimethylborane
593-90-8

trimethylborane

B

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

trimethylborane
593-90-8

trimethylborane

water
7732-18-5

water

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

Trimethylboroxine
823-96-1

Trimethylboroxine

C

Dimethylborinsaeure-anhydrid
19163-04-3

Dimethylborinsaeure-anhydrid

Conditions
ConditionsYield
at 320℃;
2,4,6-Trimethyl-[1,3,5,2,4,6]triazatriborinane
5314-85-2

2,4,6-Trimethyl-[1,3,5,2,4,6]triazatriborinane

water
7732-18-5

water

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
at 150℃;
hydrogenchloride
7647-01-0

hydrogenchloride

2-methyl-borazine
21127-95-7

2-methyl-borazine

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

ammonium chloride

ammonium chloride

C

H3BO3

H3BO3

D

hydrogen

hydrogen

Conditions
ConditionsYield
at 200 - 250℃;
hydrogenchloride
7647-01-0

hydrogenchloride

B-dimethylborazole
23208-27-7

B-dimethylborazole

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

ammonium chloride

ammonium chloride

C

H3BO3

H3BO3

D

hydrogen

hydrogen

Conditions
ConditionsYield
at 200 - 250℃;
methyl-borane; compound with borane

methyl-borane; compound with borane

water

water

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

H3BO3

H3BO3

dimethyl-borane; compound with methylborane

dimethyl-borane; compound with methylborane

water

water

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

dimethylboronynoic acid

dimethylboronynoic acid

C

hydrogen

hydrogen

dimethylsulfoxonium methylide*borane
502622-26-6

dimethylsulfoxonium methylide*borane

water
7732-18-5

water

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

Conditions
ConditionsYield
In neat (no solvent) holding at room temp. in screw-cap vials, crystn. near the cap; identification by single-crystal X-ray analysis;
methyl magnesium iodide
917-64-6

methyl magnesium iodide

Trimethyl borate
121-43-7

Trimethyl borate

A

trimethylborane
593-90-8

trimethylborane

B

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

Conditions
ConditionsYield
In diethyl ether
In diethyl ether
methyl diborane
23777-55-1

methyl diborane

A

hydroxy-dimethyl-borane
13061-97-7

hydroxy-dimethyl-borane

B

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

C

boric acid
11113-50-1

boric acid

Conditions
ConditionsYield
With water byproducts: H2; at room temp.;
With H2O byproducts: H2; at room temp.;
methyl diborane
23777-55-1

methyl diborane

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

boric acid
11113-50-1

boric acid

Conditions
ConditionsYield
With water hydrolysis;;
With H2O hydrolysis;;
1.1-dimethyl borane(6)
16924-32-6

1.1-dimethyl borane(6)

A

hydroxy-dimethyl-borane
13061-97-7

hydroxy-dimethyl-borane

B

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

C

boric acid
11113-50-1

boric acid

Conditions
ConditionsYield
With water byproducts: H2; at room temp.;
With H2O byproducts: H2; at room temp.;

A

hydroxy-dimethyl-borane
13061-97-7

hydroxy-dimethyl-borane

B

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

C

boric acid
11113-50-1

boric acid

Conditions
ConditionsYield
With water byproducts: H2; at room temp.;
With H2O byproducts: H2; at room temp.;
2-methyl-borazine
21127-95-7

2-methyl-borazine

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

ammonia
7664-41-7

ammonia

C

boric acid
11113-50-1

boric acid

Conditions
ConditionsYield
With hydrogenchloride; water byproducts: H2; at 200-250°C for 6 h with 20% aq. HCl;
With H2O; HCl byproducts: H2; at 200-250°C for 6 h with 20% aq. HCl;
tetramethyl diborane
21482-59-7

tetramethyl diborane

A

hydroxy-dimethyl-borane
13061-97-7

hydroxy-dimethyl-borane

B

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

C

boric acid
11113-50-1

boric acid

Conditions
ConditionsYield
With water byproducts: H2; at room temp.;
With H2O byproducts: H2; at room temp.;
trimethyldiborane(6)
21107-27-7

trimethyldiborane(6)

A

hydroxy-dimethyl-borane
13061-97-7

hydroxy-dimethyl-borane

B

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

Conditions
ConditionsYield
With water byproducts: H2;
With H2O byproducts: H2;
trimethyldiborane(6)
21107-27-7

trimethyldiborane(6)

A

hydroxy-dimethyl-borane
13061-97-7

hydroxy-dimethyl-borane

B

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

C

boric acid
11113-50-1

boric acid

Conditions
ConditionsYield
With water byproducts: H2; at room temp.;
With H2O byproducts: H2; at room temp.;
B-dimethylborazole
23208-27-7

B-dimethylborazole

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

ammonia
7664-41-7

ammonia

C

boric acid
11113-50-1

boric acid

Conditions
ConditionsYield
With hydrogenchloride; water byproducts: H2; at 200-250°C for 6 h with 20% aq. HCl;
With H2O; HCl byproducts: H2; at 200-250°C for 6 h with 20% aq. HCl;
2,4,6-Trimethyl-[1,3,5,2,4,6]triazatriborinane
5314-85-2

2,4,6-Trimethyl-[1,3,5,2,4,6]triazatriborinane

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

ammonia
7664-41-7

ammonia

C

boric acid
11113-50-1

boric acid

Conditions
ConditionsYield
With hydrogenchloride; water byproducts: H2; at 200-250°C for 6 h with 20% aq. HCl;
With H2O; HCl byproducts: H2; at 200-250°C for 6 h with 20% aq. HCl;
N-B,B'-trimethylborazole

N-B,B'-trimethylborazole

A

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

B

boric acid
11113-50-1

boric acid

Conditions
ConditionsYield
With hydrogenchloride; water byproducts: NH3, CH3NH2, H2; by heating;
With HCl; H2O byproducts: NH3, CH3NH2, H2; by heating;
ethyl 2-(4-fluorophenyl)-6-nitro-5-(trifluoromethylsulfonyloxy)benzofuran-3-carboxylate
691857-51-9

ethyl 2-(4-fluorophenyl)-6-nitro-5-(trifluoromethylsulfonyloxy)benzofuran-3-carboxylate

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

ethyl 2-(4-fluorophenyl)-5-methyl-6-nitro-1-benzofuran-3-carboxylate
1378428-85-3

ethyl 2-(4-fluorophenyl)-5-methyl-6-nitro-1-benzofuran-3-carboxylate

Conditions
ConditionsYield
With potassium fluoride; sodium bromide; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 25h; Inert atmosphere; Reflux;100%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

(S)-3-bromo-2,6-difluoro-N-(thiazol-4-yl)-4-((1-((6-(trifluoromethyl)pyridin-2-yl)methyl)pyrrolidin-3-yl)amino)benzenesulfonamide

(S)-3-bromo-2,6-difluoro-N-(thiazol-4-yl)-4-((1-((6-(trifluoromethyl)pyridin-2-yl)methyl)pyrrolidin-3-yl)amino)benzenesulfonamide

(S)-2,6-difluoro-3-methyl-N-(thiazol-4-yl)-4-((1-((6-(trifluoromethyl)pyridin-2-yl)methyl)pyrrolidin-3-yl)amino)benzenesulfonamide

(S)-2,6-difluoro-3-methyl-N-(thiazol-4-yl)-4-((1-((6-(trifluoromethyl)pyridin-2-yl)methyl)pyrrolidin-3-yl)amino)benzenesulfonamide

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane for 12h; Inert atmosphere; Reflux;100%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

ethyl 9'-(benzyloxy)-10'-bromo-2'-oxo-2',7'-dihydrospiro[cyclohexane-1,6'pyrido[2,1-a]isoquinoline]-3'-carboxylate

ethyl 9'-(benzyloxy)-10'-bromo-2'-oxo-2',7'-dihydrospiro[cyclohexane-1,6'pyrido[2,1-a]isoquinoline]-3'-carboxylate

ethyl 9'-(benzyloxy)-10'-methyl-2'-oxo-2',7'dihydrospiro[cyclohexane-1,6'-pyrido[2,1-a]isoquinoline]-3'-carboxylate

ethyl 9'-(benzyloxy)-10'-methyl-2'-oxo-2',7'dihydrospiro[cyclohexane-1,6'-pyrido[2,1-a]isoquinoline]-3'-carboxylate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In water; toluene at 85℃; for 6h;100%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

tert-butyl ((5-chloro-2-fluoro-4-((6-fluoro-2-((isopropyl(methyl)amino)methyl)-3-methoxybenzyl)amino)phenyl)sulfonyl)(thiazol-4-yl)carbamate

tert-butyl ((5-chloro-2-fluoro-4-((6-fluoro-2-((isopropyl(methyl)amino)methyl)-3-methoxybenzyl)amino)phenyl)sulfonyl)(thiazol-4-yl)carbamate

tert-butyl ((2-fluoro-4-((6-fluoro-2-((isopropyl(methyl)amino)methyl)-3-methoxybenzyl)amino)-5-methylphenyl)sulfonyl)(thiazol-4-yl)carbamate

tert-butyl ((2-fluoro-4-((6-fluoro-2-((isopropyl(methyl)amino)methyl)-3-methoxybenzyl)amino)-5-methylphenyl)sulfonyl)(thiazol-4-yl)carbamate

Conditions
ConditionsYield
Stage #1: dihydroxy-methyl-borane; tert-butyl ((5-chloro-2-fluoro-4-((6-fluoro-2-((isopropyl(methyl)amino)methyl)-3-methoxybenzyl)amino)phenyl)sulfonyl)(thiazol-4-yl)carbamate With potassium phosphate In 1,4-dioxane for 0.333333h; Suzuki-Miyaura Coupling; Inert atmosphere;
Stage #2: With palladium diacetate; tricyclohexylphosphine tetrafluoroborate In 1,4-dioxane at 105℃;
100%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

tert-butyl 2-bromo-6-[3-fluoro-2-methoxy-4-(trifluoromethoxy)phenoxy]-3-(trifluoromethyl)benzoate

tert-butyl 2-bromo-6-[3-fluoro-2-methoxy-4-(trifluoromethoxy)phenoxy]-3-(trifluoromethyl)benzoate

tert-butyl 6-[3-fluoro-2-methoxy-4-(trifluoromethoxy)phenoxy]-2-methyl-3-(trifluoromethyl)benzoate

tert-butyl 6-[3-fluoro-2-methoxy-4-(trifluoromethoxy)phenoxy]-2-methyl-3-(trifluoromethyl)benzoate

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate In 2-methyltetrahydrofuran at 80℃; for 1h;100%
Stage #1: dihydroxy-methyl-borane; tert-butyl 2-bromo-6-[3-fluoro-2-methoxy-4-(trifluoromethoxy)phenoxy]-3-(trifluoromethyl)benzoate With caesium carbonate In 2-methyltetrahydrofuran for 0.5h; Inert atmosphere;
Stage #2: With (bis-(2-methoxyethyl)amino)sulfur trufluoride In 2-methyltetrahydrofuran at 80℃; for 1h;
100%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

(1-bromo-4-hydroxy-7-phenoxyisoquinoline-3-carbonyl)glycine methyl ester

(1-bromo-4-hydroxy-7-phenoxyisoquinoline-3-carbonyl)glycine methyl ester

[(4-hydroxy-1-methyl-7-phenoxy-isoquinoline-3-carbonyl)-amino]-acetic acid

[(4-hydroxy-1-methyl-7-phenoxy-isoquinoline-3-carbonyl)-amino]-acetic acid

Conditions
ConditionsYield
With potassium dihydrogenphosphate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water at 100℃; for 16h; Inert atmosphere;100%
With bis-triphenylphosphine-palladium(II) chloride; potassium phosphate; water In 2-methoxy-ethanol at 110℃; for 4h;91%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

C20H28INO2

C20H28INO2

(S)-(3-ethyl-3-pentyl-2,3-dihydrobenzofuran-6-yl)(piperidin-1-yl)methanone

(S)-(3-ethyl-3-pentyl-2,3-dihydrobenzofuran-6-yl)(piperidin-1-yl)methanone

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); (R)-N-((S)-(3,5-di-tert-butyl-4-methoxyphenyl)(2-(dicyclohexylphosphanyl)phenyl)methyl)-N,2-dimethylpropane-2-sulfinamide; potassium hydroxide In toluene at 20 - 85℃; Inert atmosphere; Sealed tube; enantioselective reaction;99.2%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

9-chloroanthracene
716-53-0

9-chloroanthracene

9-methylanthracene
779-02-2

9-methylanthracene

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In tetrahydrofuran; toluene at 100℃; for 24h; Suzuki-Miyaura reaction;99%
2-(3-chloro-8-methyl-azulen-5-yl)-propionic acid methyl ester
867380-21-0

2-(3-chloro-8-methyl-azulen-5-yl)-propionic acid methyl ester

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

2-(3,8-Dimethyl-azulen-5-yl)-propionic acid methyl ester
111415-94-2

2-(3,8-Dimethyl-azulen-5-yl)-propionic acid methyl ester

Conditions
ConditionsYield
With palladium diacetate; potassium phosphate In toluene at 100℃; for 24h;99%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

5-(2-aminophenyl)-1H-pyrazole
111562-32-4

5-(2-aminophenyl)-1H-pyrazole

5-methyl-5,6-dihydrobenzo[e]pyrazolo[1,5-c][1,3,2]diazaborinine
1350934-17-6

5-methyl-5,6-dihydrobenzo[e]pyrazolo[1,5-c][1,3,2]diazaborinine

Conditions
ConditionsYield
In toluene for 1h; Inert atmosphere; Dean-Stark; Reflux;99%
In toluene for 1h; Inert atmosphere; Reflux;89%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

2-formyl-4,6-dimethylphenyl trifluoromethanesulfonate
1628799-95-0

2-formyl-4,6-dimethylphenyl trifluoromethanesulfonate

2,3,5-trimethylbenzaldehyde
5779-71-5

2,3,5-trimethylbenzaldehyde

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In tetrahydrofuran; water Suzuki Coupling; Reflux;99%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

2-formyl-3,6-dimethylphenyl trifluoromethanesulfonate
1403381-95-2

2-formyl-3,6-dimethylphenyl trifluoromethanesulfonate

2,3,6-trimethylbenzaldehyde
34341-29-2

2,3,6-trimethylbenzaldehyde

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In tetrahydrofuran; water Suzuki Coupling; Reflux;99%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In tetrahydrofuran; water Suzuki Coupling; Enzymatic reaction;93%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

N-methyliminodiacetic acid
4408-64-4

N-methyliminodiacetic acid

2,6-dimethyl-1,3,6,2-dioxazaborocane-4,8-dione

2,6-dimethyl-1,3,6,2-dioxazaborocane-4,8-dione

Conditions
ConditionsYield
In acetonitrile at 130℃; under 12929 Torr; for 0.0833333h; Solvent; Microwave irradiation;99%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

3-methyl-1-(pyrimidin-2-yl)-1H-indole
1310708-89-4

3-methyl-1-(pyrimidin-2-yl)-1H-indole

2,3-dimethyl-1-(pyrimidin-2-yl)-1H-indole

2,3-dimethyl-1-(pyrimidin-2-yl)-1H-indole

Conditions
ConditionsYield
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver carbonate In neat (no solvent) at 46℃; for 1h; Milling; regioselective reaction;99%
With potassium fluoride; palladium diacetate; silver carbonate; p-benzoquinone In tert-Amyl alcohol at 110℃; for 6h; Sealed tube; regioselective reaction;95%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

ethyl 7-bromo-1-methyl-1H-indole-5-carboxylate

ethyl 7-bromo-1-methyl-1H-indole-5-carboxylate

ethyl 1,7-dimethyl-1H-indole-5-carboxylate

ethyl 1,7-dimethyl-1H-indole-5-carboxylate

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In toluene at 100℃; for 3h; Inert atmosphere;99%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

(4S,5S)-2-{(1S,3S,4S,5R,6S)-1-chlor-5-(benzyloxy)-3-[(4-methoxybenzyl)oxy]-4,6-dimethyloctyl}-4,5-dicyclohexyl-1,3,2-dioxaborolane

(4S,5S)-2-{(1S,3S,4S,5R,6S)-1-chlor-5-(benzyloxy)-3-[(4-methoxybenzyl)oxy]-4,6-dimethyloctyl}-4,5-dicyclohexyl-1,3,2-dioxaborolane

A

(3S,4S,5R,6S)-5-(benzyloxy)-3-[(4-methoxybenzyl)oxy]-4,6-dimethyloctanal

(3S,4S,5R,6S)-5-(benzyloxy)-3-[(4-methoxybenzyl)oxy]-4,6-dimethyloctanal

Conditions
ConditionsYield
Stage #1: (4S,5S)-2-{(1S,3S,4S,5R,6S)-1-chlor-5-(benzyloxy)-3-[(4-methoxybenzyl)oxy]-4,6-dimethyloctyl}-4,5-dicyclohexyl-1,3,2-dioxaborolane With dihydrogen peroxide; sodium carbonate In tetrahydrofuran; water at 20℃; for 24h;
Stage #2: With Sodium thiosulfate pentahydrate; sodium iodide In tetrahydrofuran; water for 0.5h;
Stage #3: dihydroxy-methyl-borane With magnesium sulfate at 20℃; for 19h;
A 64%
B 99%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

(Z)-N'-hydroxy-N-(4-sulfamoylphenyl)benzimidamide

(Z)-N'-hydroxy-N-(4-sulfamoylphenyl)benzimidamide

4-(5-methyl-3-phenyl-1,2,4,5-oxadiazaborol-4(5H)-yl)benzenesulfonamide

4-(5-methyl-3-phenyl-1,2,4,5-oxadiazaborol-4(5H)-yl)benzenesulfonamide

Conditions
ConditionsYield
In toluene at 110℃; for 1h; Molecular sieve; Inert atmosphere; Sealed tube;99%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

1,1',1''‐nitrilotris(propan‐2‐one)trioxime
672-92-4

1,1',1''‐nitrilotris(propan‐2‐one)trioxime

benzyl bromide
100-39-0

benzyl bromide

C17H25BN4O3

C17H25BN4O3

Conditions
ConditionsYield
Stage #1: dihydroxy-methyl-borane; 1,1',1''‐nitrilotris(propan‐2‐one)trioxime; benzyl bromide In methanol at 20℃; for 20h;
Stage #2: With lithium carbonate In methanol at 20℃; for 4h;
99%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

(R)-3-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-amine hydrochloride

(R)-3-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-amine hydrochloride

(R)-(1-amino-3-methylbutyl)boronic acid hydrochloride
1158974-93-6

(R)-(1-amino-3-methylbutyl)boronic acid hydrochloride

Conditions
ConditionsYield
With hydrogenchloride In water; acetone at 20℃;99%
3-carboxyphenylboronic acid pinacol ester
269409-73-6

3-carboxyphenylboronic acid pinacol ester

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

3-Carboxyphenylboronic acid
25487-66-5

3-Carboxyphenylboronic acid

Conditions
ConditionsYield
With trifluoroacetic acid In dichloromethane at 20℃;99%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)piperidine hydrochloride
1218790-99-8

4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)piperidine hydrochloride

piperidin-4-ylboronic acid hydrochloride

piperidin-4-ylboronic acid hydrochloride

Conditions
ConditionsYield
Stage #1: dihydroxy-methyl-borane; 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)piperidine hydrochloride With trifluoroacetic acid In dichloromethane at 20℃;
Stage #2: With hydrogenchloride In water at 20℃;
99%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

4-chlorobenzophenone
134-85-0

4-chlorobenzophenone

4-Methylbenzophenone
134-84-9

4-Methylbenzophenone

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); 3-(dicyclohexylphosphino)-2-(2,6-dimethoxyphenyl)-1-methyl-1H-indole In 1,4-dioxane at 100℃; for 6h; Suzuki-Miyaura Coupling; Schlenk technique; Sealed tube; Inert atmosphere;99%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

C40H27AgBr2N4

C40H27AgBr2N4

3,17-dimethyl-meso-tris(p-tolylcorrolato)silver(III)

3,17-dimethyl-meso-tris(p-tolylcorrolato)silver(III)

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In toluene at 90℃; for 18h; Suzuki Coupling; Inert atmosphere;99%
1-chloro-4-methyl-azulene
867380-15-2

1-chloro-4-methyl-azulene

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

1,4-dimethylazulene
1127-69-1

1,4-dimethylazulene

Conditions
ConditionsYield
With palladium diacetate; potassium phosphate In toluene at 100℃; for 24h;98%
methyl 3-chloro-4-fluoro-5-methoxybenzoate

methyl 3-chloro-4-fluoro-5-methoxybenzoate

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

4-fluoro-3-methoxy-5-methylbenzoate

4-fluoro-3-methoxy-5-methylbenzoate

Conditions
ConditionsYield
With potassium phosphate; palladium diacetate; phosphine ligand In tetrahydrofuran; water; toluene at 100℃; for 0.166667h; microwave irradiation;98%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

C20H30Br2N2O2S
1446202-04-5

C20H30Br2N2O2S

C22H36N2O2S
1446202-05-6

C22H36N2O2S

Conditions
ConditionsYield
With potassium fluoride; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 20℃; for 11h; Reflux; Inert atmosphere;98%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

(S)-5-chloro-2-fluoro-4-((1-(pyridin-2-ylmethyl)pyrrolidin-3-yl)amino)-N-(thiazol-4-yl)benzenesulfonamide 2,2,2-trifluoroacetate

(S)-5-chloro-2-fluoro-4-((1-(pyridin-2-ylmethyl)pyrrolidin-3-yl)amino)-N-(thiazol-4-yl)benzenesulfonamide 2,2,2-trifluoroacetate

(S)-2-fluoro-5-methyl-4-((1-(pyridin-2-ylmethyl)pyrrolidin-3-yl)amino)-N-(thiazol-4-yl)benzenesulfonamide

(S)-2-fluoro-5-methyl-4-((1-(pyridin-2-ylmethyl)pyrrolidin-3-yl)amino)-N-(thiazol-4-yl)benzenesulfonamide

Conditions
ConditionsYield
With potassium phosphate; palladium diacetate; tricyclohexylphosphine tetrafluoroborate In 1,4-dioxane for 4h; Inert atmosphere; Reflux;98%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

3-aminophenylboronic acid pinacolate
210907-84-9

3-aminophenylboronic acid pinacolate

3-aminophenylboronic acid hydrochloric salt

3-aminophenylboronic acid hydrochloric salt

Conditions
ConditionsYield
Stage #1: dihydroxy-methyl-borane; 3-aminophenylboronic acid pinacolate With trifluoroacetic acid In dichloromethane at 20℃;
Stage #2: With hydrogenchloride In water at 20℃; Reagent/catalyst; Temperature; Solvent;
98%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

tert-butyl 2-bromo-6-[2-(trideuteriomethoxy)-4-(trifluoromethoxy)phenoxy]-3-(trifluoromethyl)benzoate

tert-butyl 2-bromo-6-[2-(trideuteriomethoxy)-4-(trifluoromethoxy)phenoxy]-3-(trifluoromethyl)benzoate

tert-butyl 2-methyl-6-[2-(trideuteriomethoxy)-4-(trifluoromethoxy)phenoxy]-3-(trifluoromethyl)benzoate

tert-butyl 2-methyl-6-[2-(trideuteriomethoxy)-4-(trifluoromethoxy)phenoxy]-3-(trifluoromethyl)benzoate

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In 1,4-dioxane; water at 120℃; for 0.5h; Inert atmosphere; Sealed tube; Microwave irradiation;98%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

methyl 6-(2,6-difluoro-3-(trifluoromethyl-sulfonyloxy)phenyl)-5-fluoropicolinate
1210419-44-5

methyl 6-(2,6-difluoro-3-(trifluoromethyl-sulfonyloxy)phenyl)-5-fluoropicolinate

6-(2,6-difluoro-3-methylphenyl)-5-fluoropicolinic acid
1210419-49-0

6-(2,6-difluoro-3-methylphenyl)-5-fluoropicolinic acid

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 100℃; for 3h; Inert atmosphere;97%
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