CAS No.606-20-2,2,6-Dinitrotoluene Suppliers,MSDS download

: 88-72-2
1-methyl-2-nitrobenzene

A: 121-14-2
2,4-dinitrotoluene

B: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
With nitric acid; Chloroacetic anhydride at 50℃; for 4h;	A 94% B 5%
With dinitrogen pentoxide; H-faujasite zeolite F-712 In dichloromethane	A 77% B 15%
With nitric acid at 50℃; for 3h;	A 71.5% B 28.5%

: 108-88-3
toluene

A: 121-14-2
2,4-dinitrotoluene

B: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
With succinic acid anhydride; nitric acid at 4℃; for 50h; Product distribution / selectivity;	A 85% B 8.2%
With Perfluorooctanesulfonic acid; nitric acid; ytterbium(III) perfluorooctanesulfonate In hexane at 60℃; for 4h;	A 84% B 16%
With Perfluorooctanesulfonic acid; nitric acid; ytterbium(III) perfluorooctanesulfonate In hexane at 60℃; for 4h;	A 80% B 18%

: 108-88-3
toluene

A: 99-99-0
1-methyl-4-nitrobenzene

B: 121-14-2
2,4-dinitrotoluene

C: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
With succinic acid anhydride; nitric acid at 4℃; for 50h; Product distribution / selectivity;	A 7.9% B 85% C 6.3%
With nitric acid; dichloroacetic anhydride In dichloromethane at 50℃; for 0.166667h; Time;

...Expand

: 603-83-8
3-nitro-o-tolylamine

: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid In 1,2-dichloro-ethane for 10h; Reflux;	63%

: 108-88-3
toluene

A: 99-99-0
1-methyl-4-nitrobenzene

B: 88-72-2
1-methyl-2-nitrobenzene

C: 121-14-2
2,4-dinitrotoluene

D: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
With trinitratooxovanadium(V) In dichloromethane for 0.1h; Ambient temperature; Further byproducts given;	A 41% B 35% C 19% D 3%
With sulfuric acid; nitric acid at 20 - 90℃; Product distribution; Further Variations:; Temperatures; Reagents; Nitration;
With MoO3 upon silica gel; nitric acid In tetrachloromethane at 20℃; for 2.5h; Product distribution; Further Variations:; Reagents;
With sulfuric acid; nitric acid; acetic anhydride at 30℃; Product distribution; Further Variations:; Temperatures; Reagents; residence time;
Stage #1: toluene With nitric acid; acetic anhydride at 20℃; Stage #2: With nitric acid; acetic anhydride In water at 50℃; Reagent/catalyst;

...Expand

: 88-72-2
1-methyl-2-nitrobenzene

: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
Nitrierung;

: 19406-51-0
4-Amino-2,6-dinitrotoluene

: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
With sulfuric acid Diazotization.man schuettet das Produkt in Alkohol;
With hydrogenchloride; hypophosphoric acid; sodium nitrite
(i) (diazotization), (ii) (reduction); Multistep reaction;
Behandlung des Diazoniumsulfats mit siedendem Alkohol.Diazotization;

: 108-88-3
toluene

A: 99-08-1
1-methyl-3-nitrobenzene

B: 99-99-0
1-methyl-4-nitrobenzene

C: 88-72-2
1-methyl-2-nitrobenzene

D: 121-14-2
2,4-dinitrotoluene

E: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
With sulfur dioxide; dinitrogen pentoxide at -78 - -11℃; for 4h; Product distribution; other aromatic comp., var. nitration systems;	A 1 % Chromat. B 8 % Chromat. C 7 % Chromat. D 56 % Chromat. E 15 % Chromat.
With claycop (montmorillonite clay impregnated with copper nitrate); nitric acid; acetic anhydride In tetrachloromethane at 25℃; for 4h; Product distribution; other reagents, solvent, time dependence of yields;

...Expand

: 24431-33-2
2-aci-Nitro-6-nitro-toluol

: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
With perchloric acid; sodium perchlorate at 15 - 80℃; Kinetics;

: 2,6-Dinitro-benzyl-Anion

: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
With sodium perchlorate; acetic acid at 15 - 80℃; Kinetics; other reaction partners;

: 118-96-7
2,4,6-Trinitrotoluene

A: 99-35-4
1,3,5-trinitrobenzene

B: 606-20-2
2,6-dinitrotoluene

C: 29245-51-0
4,6-dinitrobenzo[c]isoxazole

D: 140380-55-8
2-amino-4,6-dinitrobenzoic acid

E: 618-87-1
3, 5-dinitroaniline

F: 2-Amino-4,6-dinitro-benzaldehyde

Conditions

Conditions	Yield
In benzene at 340℃; Product distribution; Kinetics; Rate constant; in sealed tube; other solvent (neat); other temp.;

...Expand

: 7697-37-2
nitric acid

: 108-88-3
toluene

A: 121-14-2
2,4-dinitrotoluene

B: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
in der Waerme bei groesserer Konzentration der Salpetersaeure entsteht zunaechst;

...Expand

: 7664-93-9
sulfuric acid

: 7697-37-2
nitric acid

: 108-88-3
toluene

A: 121-14-2
2,4-dinitrotoluene

B: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
in der Waerme entsteht zunaechst;

...Expand

2.6-dinitro-phenylacetic acid: 2.6-dinitro-phenylacetic acid

: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
beim Schmelzen;

: 88-72-2
1-methyl-2-nitrobenzene

: 7664-93-9
sulfuric acid

: 7732-18-5
water

: 7697-37-2
nitric acid

A: 121-14-2
2,4-dinitrotoluene

B: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
at 40 - 70℃; Product distribution;

...Expand

: 118-96-7
2,4,6-Trinitrotoluene

: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: ammonium sulfhydrate; alcohol 2: Behandlung des Diazoniumsulfats mit siedendem Alkohol.Diazotization View Scheme
Multi-step reaction with 2 steps 1: alcohol; NH4SH / man dampft zur Trochne ein, extrahiert mit siedender Salzsaeure, faellt mit Ammoniak, und krystallisiert es aus 40prozentiger Essigsaeure um 2: Behandlung des Diazoniumsulfats mit siedendem Alkohol.Diazotization View Scheme

: 108-88-3
toluene

: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: HNO3-H2SO4-H2O mixtures / 20 °C 2: Nitrierung View Scheme

: 108-88-3
toluene

A: 118-96-7
2,4,6-Trinitrotoluene

B: 121-14-2
2,4-dinitrotoluene

C: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
Stage #1: toluene With sulfuric acid; nitric acid at 45 - 55℃; Stage #2: With sulfuric acid; nitric acid at 60 - 80℃;

...Expand

: 108-88-3
toluene

A: 99-08-1
1-methyl-3-nitrobenzene

B: 88-72-2
1-methyl-2-nitrobenzene

C: 121-14-2
2,4-dinitrotoluene

D: 606-20-2
2,6-dinitrotoluene

E p-nitrotoluene: p-nitrotoluene

Conditions

Conditions	Yield
With sodium nitrate; sulfuric acid; nitric acid In water at 50℃; for 0.25h; Title compound not separated from byproducts.;

...Expand

: 88-72-2
1-methyl-2-nitrobenzene

A: 118-96-7
2,4,6-Trinitrotoluene

B: 121-14-2
2,4-dinitrotoluene

C: 606-20-2
2,6-dinitrotoluene

Conditions

Conditions	Yield
With ethylene glycol dinitrate In sulfuric acid at 0 - 20℃; Product distribution; Further Variations:; Reagents;

...Expand

: 108-88-3
toluene

A: 121-14-2
2,4-dinitrotoluene

B: 618-85-9
3,5-dinitrotoluene

C: 606-20-2
2,6-dinitrotoluene

D: 610-39-9
3,4-Dinitrotoluene

E: 619-15-8
2,5-dinitrotoluene

Conditions

Conditions	Yield
With ferric nitrate pentahydrate; nitric acid at 100℃; for 99h;

...Expand

: 108-88-3
toluene

A: 121-14-2
2,4-dinitrotoluene

B: 606-20-2
2,6-dinitrotoluene

C: 619-15-8
2,5-dinitrotoluene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: nitric acid; chromium(III) nitrate hexahydrate / water / 5 h / 100 °C 2: nitric acid; ferric nitrate pentahydrate / 9 h / 100 °C View Scheme
Multi-step reaction with 2 steps 1: nitric acid; ferric nitrate pentahydrate / 0.25 h / 100 °C 2: nitric acid; ferric nitrate pentahydrate / 9 h / 100 °C View Scheme

...Expand

: 88-72-2
1-methyl-2-nitrobenzene

A: 121-14-2
2,4-dinitrotoluene

B: 606-20-2
2,6-dinitrotoluene

C: 619-15-8
2,5-dinitrotoluene

Conditions

Conditions	Yield
With ferric nitrate pentahydrate; nitric acid at 100℃; for 9h; Product distribution / selectivity;

...Expand

: 606-20-2
2,6-dinitrotoluene

: 823-40-5
2,6-Diaminotoluene

Conditions

Conditions	Yield
With hydrogen In methanol at 50℃; under 1500.15 Torr; for 0.666667h; Inert atmosphere;	100%
With Fe3O4Rh; hydrazine hydrate In ethanol at 80℃; for 2h; Inert atmosphere;	99%
With hydrogen In ethanol at 20℃; under 760.051 Torr; for 1h;	99%

: 74-93-1
methylthiol

: 606-20-2
2,6-dinitrotoluene

: 82173-72-6
2-nitro-6-(methylthio)toluene

Conditions

Conditions	Yield
With lithium hydroxide In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃;	100%

: 606-20-2
2,6-dinitrotoluene

: 4637-24-5
N,N-dimethyl-formamide dimethyl acetal

: 78283-21-3
3-nitro-trans-2-[β-(dimethylamino)vinyl]-nitrobenzene

Conditions

Conditions	Yield
In N,N-dimethyl-formamide for 4h; Heating;	100%
In N,N-dimethyl-formamide at 115℃; for 6h;	96%
With copper(l) iodide; N,N-dimethyl-formamide at 180℃; under 6000.6 - 7500.75 Torr; for 0.166667h; microwave irradiation;	85%

: 606-20-2
2,6-dinitrotoluene

: 95192-64-6
5-bromo-2-methyl-1,3-dinitrobenzene

Conditions

Conditions	Yield
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; sulfuric acid at 20℃; for 1h;	100%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; sulfuric acid at 20℃; for 1h;	92%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; sulfuric acid at 20℃; for 15h; Reagent/catalyst;	92%

: 606-20-2
2,6-dinitrotoluene

: 75-08-1
ethanethiol

: 83759-96-0
1-Ethylsulfanyl-2-methyl-3-nitro-benzene

Conditions

Conditions	Yield
With lithium hydroxide In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃;	99%

: 606-20-2
2,6-dinitrotoluene

: 603-83-8
3-nitro-o-tolylamine

Conditions

Conditions	Yield
Stage #1: 2,6-dinitrotoluene In 1,4-dioxane; water at 50℃; for 0.0833333h; Stage #2: With formic acid In 1,4-dioxane; water at 50℃; for 2h; Sealed tube;	95%
With ammonium sulfide In ethanol at 79℃; for 2h; Reflux;	79%
With formic acid; triethylamine; palladium on activated charcoal at 100℃; for 0.333333h;	76%

: 50-00-0
formaldehyd

: 606-20-2
2,6-dinitrotoluene

: 77759-08-1
2-(2,6-dinitrophenyl)ethanol

Conditions

Conditions	Yield
With potassium hydroxide at 20℃; Addition;	95%
With tetraethylammonium tosylate In N,N-dimethyl-formamide for 0.833333h; Ambient temperature; 3.3 mAcm-2;	94%
With potassium tert-butylate In dimethyl sulfoxide; tert-butyl alcohol r.t., 5min. then 70-75 degC, 10min.;	77%

: 606-20-2
2,6-dinitrotoluene

: 606-31-5
2,6-dinitrobenzaldehyde

: 859961-12-9
1,2-bis(2,6-dinitrophenyl)ethylene

Conditions

Conditions	Yield
With piperidine In toluene Reflux;	93%

: 606-20-2
2,6-dinitrotoluene

: 4637-24-5
N,N-dimethyl-formamide dimethyl acetal

: [(E)-2-(2,6-Dinitro-phenyl)-vinyl]-dimethyl-amine

Conditions

Conditions	Yield
In N,N-dimethyl-formamide for 9h; Heating;	91%

: 606-20-2
2,6-dinitrotoluene

: 80-62-6
methacrylic acid methyl ester

: C12H14N2O4

Conditions

Conditions	Yield
With caesium carbonate; potassium hydroxide In tetrahydrofuran at 70℃; for 12h; Inert atmosphere; Green chemistry;	91%

: 606-20-2
2,6-dinitrotoluene

: 4637-24-5
N,N-dimethyl-formamide dimethyl acetal

A: 78283-21-3
3-nitro-trans-2-[β-(dimethylamino)vinyl]-nitrobenzene

B: 78283-22-4
(2,6-dinitrophenyl)acetaldehyde

Conditions

Conditions	Yield
In N,N-dimethyl-formamide for 9h; Heating;	A 90.9% B 2.2%

...Expand

: 606-20-2
2,6-dinitrotoluene

: 298-12-4
Glyoxilic acid

: 3-(2,6-dinitro-phenyl)-2-hydroxy-propionic acid

Conditions

Conditions	Yield
With caesium carbonate In methanol Addition; Heating;	88%

: 606-20-2
2,6-dinitrotoluene

: 95-92-1
oxalic acid diethyl ester

: 851786-38-4
ethyl 3-(2,6-dinitrophenyl)pyruvate

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide	85%
With sodium ethanolate In ethanol at 40℃; for 2h;	20%
With sodium ethanolate In ethanol at 40℃; for 4h;

: 606-20-2
2,6-dinitrotoluene

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 78283-21-3
3-nitro-trans-2-[β-(dimethylamino)vinyl]-nitrobenzene

Conditions

Conditions	Yield
With propionic acid at 105℃; for 2h;	84%

: 606-20-2
2,6-dinitrotoluene

A: 95-80-7
4-methylbenzene-1,3-diamine

B: 108-45-2
m-phenylenediamine

C diaminoxylene: diaminoxylene

Conditions

Conditions	Yield
With carbon monoxide; hydrogen sulfide; iron(III) oxide at 325℃; for 1.05h; Product distribution; Mechanism; var. time;	A 80.2% B 4.5% C n/a

...Expand

: 606-20-2
2,6-dinitrotoluene

: 93213-74-2
2-(bromomethyl)-1,3-dinitrobenzene

Conditions

Conditions	Yield
With Perbenzoic acid; bromine In tetrachloromethane Heating; Irradiation;	79%
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane for 48h; Inert atmosphere; Reflux;	35%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; 2,2'-azobis(isobutyronitrile) In tetrachloromethane at 100℃; for 13h; Inert atmosphere;	29%

: 606-20-2
2,6-dinitrotoluene

: 960-16-7
tributylphenylstannane

: 83909-06-2
2′-methyl-1,1′:3′,1′′-terphenyl

Conditions

Conditions	Yield
With bis(acetylacetonato)palladium(II); 18-crown-6 ether; potassium phosphate tribasic trihydrate; XPhos at 140℃; for 24h; Inert atmosphere;	78%

: 606-20-2
2,6-dinitrotoluene

: 35572-79-3
5-chloro-2-methyl-1,3-dinitro-benzene

Conditions

Conditions	Yield
With trichloroisocyanuric acid; sulfuric acid at 130℃; for 2h;	74%
With trichloroisocyanuric acid; sulfuric acid at 130℃; for 4h;	73.6%
With trichloroisocyanuric acid; sulfuric acid at 130℃; for 4h;	73.6%

: 606-20-2
2,6-dinitrotoluene

: 107-13-1
acrylonitrile

: 30980-52-0
5-nitroquinoline-2-carbonitrile

Conditions

Conditions	Yield
With caesium carbonate In tetrahydrofuran at 65℃; for 12h; Inert atmosphere;	74%
With caesium carbonate In tetrahydrofuran at 65℃; for 12h; Inert atmosphere; Green chemistry;	74%

: 606-20-2
2,6-dinitrotoluene

: 609-09-6
Diethyl ketomalonate

: diethyl (2',6'-dinitrophenyl)methyltartronate

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran at 20℃; Condensation;	72%

: 606-20-2
2,6-dinitrotoluene

: 2365-48-2
Methyl thioglycolate

: 73363-64-1
methyl ((2-methyl-3-nitrophenyl)thio)acetate

Conditions

Conditions	Yield
With lithium hydroxide In N,N,N,N,N,N-hexamethylphosphoric triamide for 24h; Ambient temperature;	70%

: 1963-36-6
4-methoxycinnamaldehyde

: 606-20-2
2,6-dinitrotoluene

: (S)-4-(2,6-dinitrophenyl)-3-(2-methoxyphenyl)butanal

Conditions

Conditions	Yield
With (S)-2-(((tert-butyldimethylsilyl)oxy)diphenylmethyl)pyrrolidine; dmap In acetonitrile at 40℃; for 48h; enantioselective reaction;	70%

: 606-20-2
2,6-dinitrotoluene

: 140-88-5
ethyl acrylate

: ethyl 5-nitroquinoline-2-carboxylate

Conditions

Conditions	Yield
With caesium carbonate In tetrahydrofuran at 65℃; for 12h; Inert atmosphere;	66%
With caesium carbonate In tetrahydrofuran at 65℃; for 12h; Inert atmosphere; Green chemistry;	66%

PE: PE

: 606-20-2
2,6-dinitrotoluene

: 77759-08-1
2-(2,6-dinitrophenyl)ethanol

Conditions

Conditions	Yield
With sodium chloride; paraformaldehyde; SiO2 In dimethyl sulfoxide; ethyl acetate; Petroleum ether; tert-butyl alcohol	64%

: 606-20-2
2,6-dinitrotoluene

: 83858-97-3
p-(15NO2)-2,4,6-trinitrotoluene

Conditions

Conditions	Yield
With nitrous acid; sulfuric acid at 90 - 100℃; for 2h;	59%

: 606-20-2
2,6-dinitrotoluene

: 603-12-3
2,6-dinitrobenzoic acid

Conditions

Conditions	Yield
With sodium dichromate; sulfuric acid for 20h; Ambient temperature;	58%
With potassium permanganate; sodium hydrogencarbonate In water for 5h; Oxidation; Heating;	19%
With water; nitric acid at 125 - 130℃; im Druckrohr;

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