CAS No.118-96-7,2,4,6-Trinitrotoluene Suppliers,MSDS download

Synthetic route

: 99-99-0
1-methyl-4-nitrobenzene

: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid at 110℃; for 4h; Temperature;	92.2%
With sulfuric acid; nitric acid at 20 - 100℃; Nitration;	89%
With sulfuric acid; nitric acid 1.) 0 deg C, 10 min, 2.) 95 deg C, 6 h, then room temp., 12 h;	69%

: 88-72-2
1-methyl-2-nitrobenzene

: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid at 110℃; for 4h;	92.2%
With sulfuric acid; nitric acid
durch Nitrierung;

: 108-88-3
toluene

: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid at 20 - 90℃; Nitration;	84%
With nitric acid; Petroleum ether azeotropes Abdestillieren des gebildeten Wassers;
With sulfuric acid; nitric acid

: 121-14-2
2,4-dinitrotoluene

: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid 1.) 90-100 deg C, 2 h, 2.) 25 deg C, overnight;	62%
Nitrierung;
durch Nitrierung;

: 99-35-4
1,3,5-trinitrobenzene

: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
With lead(IV) acetate; acetic acid

: 99-87-6
4-methylisopropylbenzene

: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid at 60 - 70℃;

: 606-20-2
2,6-dinitrotoluene

: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid at 93 - 103℃;
With ammonium nitrate In sulfuric acid at 0 - 25℃;

: 77601-83-3
2,4,6-trinitrophenylacetic acid

: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
With water
With ethanol

: 99-65-0
meta-dinitrobenzene

: 546-67-8
lead(IV) tetraacetate

: 64-19-7
acetic acid

A: 118-96-7
2,4,6-Trinitrotoluene

B: 632-92-8
2,4-dimethyl-1,3,5-trinitrobenzene

Conditions

Conditions	Yield
Erwaermen des Reaktionsprodukts mit rauchender Salpetersaeure und konz. H2SO4 auf 75-120grad;

...Expand

: 99-35-4
1,3,5-trinitrobenzene

: 546-67-8
lead(IV) tetraacetate

: 64-19-7
acetic acid

A: 118-96-7
2,4,6-Trinitrotoluene

B: 632-92-8
2,4-dimethyl-1,3,5-trinitrobenzene

...Expand

: 121-14-2
2,4-dinitrotoluene

A: 118-96-7
2,4,6-Trinitrotoluene

B: 201230-82-2
carbon monoxide

Conditions

Conditions	Yield
With sulfuric acid; nitric acid Thermodynamic data; ΔH, E(a);

: 121-14-2
2,4-dinitrotoluene

A: 118-96-7
2,4,6-Trinitrotoluene

B: 18242-38-1
1-bromo-2-methyl-3,5-dinitrobenzene

Conditions

Conditions	Yield
With sulfuric acid; bromine; nitric acid at 90℃; for 0.166667h; Title compound not separated from byproducts;	A 0.4 % Chromat. B 94.7 % Chromat.

: 121-14-2
2,4-dinitrotoluene

A: 118-96-7
2,4,6-Trinitrotoluene

B: 18242-38-1
1-bromo-2-methyl-3,5-dinitrobenzene

C: 96-90-2
1-chloro-2-methyl-3,5-dinitrobenzene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid; chlorine at 90℃; for 0.8h; Rate constant; Mechanism; Product distribution; further reaction times; oleum instead of sulphuric acid;	A 19.1 % Chromat. B 8.8 % Chromat. C 52.3 % Chromat.

...Expand

: C12H11N4O8(1-)

A: 118-96-7
2,4,6-Trinitrotoluene

B: 31124-95-5
ethyl cyanoacetate anion

Conditions

Conditions	Yield
With sodium methylate In methanol at 25℃; Equilibrium constant; Rate constant;

: C12H12N3O10(1-)

A: 33673-07-3
bis-methoxycarbonyl-methanide

B: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
With sodium methylate In methanol at 25℃; Equilibrium constant; Rate constant;

: C16H10N5O6(1-)

A: 118-96-7
2,4,6-Trinitrotoluene

B: 64764-41-6
p-cyano-phenyl-acetonitrile anion

Conditions

Conditions	Yield
With sodium methylate In methanol at 25℃; Equilibrium constant; Rate constant;

: C16H10N5O6(1-)

A: 118-96-7
2,4,6-Trinitrotoluene

B: 163977-20-6
2-cyanobenzyl cyanide anion

Conditions

Conditions	Yield
With sodium methylate In methanol at 25℃; Equilibrium constant; Rate constant;

: C15H10N5O8(1-)

A: 118-96-7
2,4,6-Trinitrotoluene

B: 48129-94-8
4-nitrobenzyl cyanide anion

Conditions

Conditions	Yield
With sodium methylate In methanol at 25℃; Equilibrium constant; Rate constant;

: C10H13N4O6(1-)

A: 118-96-7
2,4,6-Trinitrotoluene

B: 75-31-0
isopropylamine

Conditions

Conditions	Yield
With Isopropylamine hydroperchlorate In dimethyl sulfoxide at 25℃; Equilibrium constant;

: C11H15N4O6(1-)

A: 118-96-7
2,4,6-Trinitrotoluene

B: 109-73-9
N-butylamine

Conditions

Conditions	Yield
With n-butylammonium perchlorate In dimethyl sulfoxide at 25℃; Equilibrium constant;

: C7H5N3O9S(2-)

: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
With sodium sulfite In water at 25℃; Equilibrium constant; variation with solvent composition;

: C12H15N4O6(1-)

A: 110-89-4
piperidine

B: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
With piperidine hydrochloride In dimethyl sulfoxide at 25℃; Equilibrium constant;

: C14H13N4O6(1-)

A: 118-96-7
2,4,6-Trinitrotoluene

B: 100-46-9
benzylamine

Conditions

Conditions	Yield
With benzylamine hydrogenperchlorate In dimethyl sulfoxide at 25℃; Equilibrium constant;

: C9H16N2*C7H4N3O6(1-)*H(1+)

A: 118-96-7
2,4,6-Trinitrotoluene

B: 6674-22-2
1,8-diazabicyclo[5.4.0]undec-7-ene

Conditions

Conditions	Yield
In acetonitrile at 25℃; Rate constant; different solvents;

: C8H8N3O7(1-)*Na(1+)

A: 118-96-7
2,4,6-Trinitrotoluene

B: 124-41-4
sodium methylate

Conditions

Conditions	Yield
In methanol; dimethyl sulfoxide at 25℃; Rate constant; Equilibrium constant;

: 6-methyl-5-(2,4,6-trinitro-benzyl)-5,6,7,8-tetrahydro-[1,3]dioxolo[4,5-g]isoquinoline

: 64-19-7
acetic acid

A: 118-96-7
2,4,6-Trinitrotoluene

B hydrastinine acetate: hydrastinine acetate

...Expand

: 7697-37-2
nitric acid

: 108-88-3
toluene

: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
unter azeotropem Abdestillieren des entstehenden Wassers;
in der Waerme bei groesserer Konzentration der Salpetersaeure;
unter azeotropem Abdestillieren des entstehenden Wassers;

: 7664-93-9
sulfuric acid

: 7697-37-2
nitric acid

: 108-88-3
toluene

: 118-96-7
2,4,6-Trinitrotoluene

Conditions

Conditions	Yield
in der Waerme;

...Expand

: 99-87-6
4-methylisopropylbenzene

: 7664-93-9
sulfuric acid

: 7697-37-2
nitric acid

A: 118-96-7
2,4,6-Trinitrotoluene

B: 16533-71-4
3,5-dinitro-p-toluic acid

Conditions

Conditions	Yield
at 60 - 70℃;

...Expand

: 118-96-7
2,4,6-Trinitrotoluene

: 623-27-8
terephthalaldehyde,

: 1,4-bis(2,4,6-trinitrostyryl)benzene

Conditions

Conditions	Yield
With piperidine In benzene for 12h; Knoevenagel Condensation; Dean-Stark; Reflux;	95.1%

: 118-96-7
2,4,6-Trinitrotoluene

: 35113-75-8
1-nitromethyl-2,4,6-trinitrobenzene

Conditions

Conditions	Yield
With potassium hydroxide; fluorotrinitromethane In tetrahydrofuran; methanol; water for 0.0333333h; Nitration;	95%

: 118-96-7
2,4,6-Trinitrotoluene

: C7H17N3*3ClH

Conditions

Conditions	Yield
Stage #1: 2,4,6-Trinitrotoluene With hydrogen; pyrographite In methanol at 120℃; under 45004.5 Torr; for 5h; Large scale; Stage #2: With hydrogenchloride In water for 1h; Reagent/catalyst; Solvent; Pressure; Large scale;	95%

: 118-96-7
2,4,6-Trinitrotoluene

: 606-34-8
2,4,6-trinitrobenzaldehyde

: 20062-22-0
2,2’,4,4’,6,6’-hexanitrostilbene

Conditions

Conditions	Yield
With piperidine In toluene Reflux;	94.2%

: 118-96-7
2,4,6-Trinitrotoluene

: 2,4,6-triaminotoluene hydrochloride

Conditions

Conditions	Yield
Stage #1: 2,4,6-Trinitrotoluene With hydrogen In toluene at 120℃; under 30003 Torr; for 10h; Autoclave; Stage #2: With hydrogenchloride In water for 0.5h; Solvent; Pressure; Temperature;	93.1%

: 118-96-7
2,4,6-Trinitrotoluene

: 3163-76-6
benzene-1,3,5-trialdehyde

: 1,3,5-tris(2,4,6-trinitrostyryl)benzene

Conditions

Conditions	Yield
With piperidine In benzene for 14h; Knoevenagel Condensation; Dean-Stark; Reflux;	90.3%

: 118-96-7
2,4,6-Trinitrotoluene

: 104-87-0
4-methyl-benzaldehyde

: 1,3,5-trinitro-2-[2-(4-methylphenyl)ethenyl]benzene

Conditions

Conditions	Yield
With piperidine In benzene for 6h; Knoevenagel Condensation; Dean-Stark; Reflux;	90.2%

: 1125-80-0
3-methylisoquinoline

: 118-96-7
2,4,6-Trinitrotoluene

: 98-88-4
benzoyl chloride

: 94170-03-3
[3-Methyl-1-(2,4,6-trinitro-benzyl)-1H-isoquinolin-2-yl]-phenyl-methanone

Conditions

Conditions	Yield
In chloroform at 60 - 70℃; for 1h;	90%

...Expand

: 118-96-7
2,4,6-Trinitrotoluene

: 634-87-7
2,4,6-triaminotoluene trihydrochloride

Conditions

Conditions	Yield
With hydrogenchloride; palladium on activated charcoal; hydrogen In methanol at 20℃; under 18751.9 Torr; for 2h; Solvent; Pressure; Time;	90%
With iron(III) chloride; pyrographite; hydrazine hydrate In methanol for 7h; Heating;	67.8%

: 118-96-7
2,4,6-Trinitrotoluene

: 544676-41-7
3-formyl-4,6-dinitro-1-phenyl-1H-indazole

: 1-(4,6-dinitro-1-phenyl-1H-indazol-3-yl)-2-(2,4,6-trinitrophenyl)ethanol

Conditions

Conditions	Yield
With potassium carbonate In ethanol at 20℃; for 24h;	90%

: 118-96-7
2,4,6-Trinitrotoluene

: 4637-24-5
N,N-dimethyl-formamide dimethyl acetal

: β-N,N-dimethylamino-2,4,6-trinitrostyrene

Conditions

Conditions	Yield
	90%
In toluene at 20℃; for 24h;	70%

: 626-19-7
Isophthalaldehyde

: 118-96-7
2,4,6-Trinitrotoluene

: 1,3-bis(2,4,6-trinitrostyryl)benzene

Conditions

Conditions	Yield
With piperidine In benzene for 11h; Knoevenagel Condensation; Dean-Stark; Reflux;	89.5%

: 118-96-7
2,4,6-Trinitrotoluene

: 129-66-8
2,4,6-trinitrobenzoic acid

Conditions

Conditions	Yield
With sodium chlorate; nitric acid	88%
With sodium dichromate; sulfuric acid at 45 - 55℃; for 2h; Oxidation;	14%
With sodium chlorate; nitric acid Reinigung ueber das Natrium-Salz;

: 118-96-7
2,4,6-Trinitrotoluene

: 100-52-7
benzaldehyde

: 61599-68-6
1,3,5-trinitro-2-[(E)-2-phenylvinyl]benzene

Conditions

Conditions	Yield
With piperidine; silica gel In neat (no solvent) at 120℃; for 0.333333h; Microwave irradiation;	88%
With piperidine In benzene for 6h; Condensation; Heating;	81%
With HTc-4-Cal In toluene for 15h; Reagent/catalyst; Time; Reflux; Dean-Stark;	70%
With piperidine
With piperidine; ethanol at 40℃;

: 118-96-7
2,4,6-Trinitrotoluene

: 2365-48-2
Methyl thioglycolate

A: 321596-17-2
2,4-dinitro-6-[(methoxycarbonyl)methylthio]toluene

B: (4-methyl-3,5-dinitro-phenylsulfanyl)-acetic acid methyl ester

Conditions

Conditions	Yield
With potassium carbonate In 1-methyl-pyrrolidin-2-one at 20℃; for 24h;	A 88% B n/a

...Expand

: 118-96-7
2,4,6-Trinitrotoluene

: 104-88-1
4-chlorobenzaldehyde

: 65200-05-7
2-[(E)-2-(4-Chloro-phenyl)-vinyl]-1,3,5-trinitro-benzene

Conditions

Conditions	Yield
With piperidine In benzene for 5.5h; Knoevenagel Condensation; Dean-Stark; Reflux;	87.6%

: 118-96-7
2,4,6-Trinitrotoluene

: 89-98-5
2-chloro-benzaldehyde

: C14H8ClN3O6

Conditions

Conditions	Yield
With piperidine In benzene for 6h; Knoevenagel Condensation; Dean-Stark; Reflux;	87%

: 19788-49-9
Ethyl 2-mercaptopropionate

: 118-96-7
2,4,6-Trinitrotoluene

A: 2-(2-methyl-3,5-dinitro-phenylsulfanyl)-propionic acid ethyl ester

B: 2-(4-methyl-3,5-dinitro-phenylsulfanyl)-propionic acid ethyl ester

Conditions

Conditions	Yield
With potassium carbonate In 1-methyl-pyrrolidin-2-one at 20℃; for 24h;	A 86% B n/a

...Expand

: 118-96-7
2,4,6-Trinitrotoluene

: 52886-05-2
2,4,6-trinitro(α,αα-D3)toluene

Conditions

Conditions	Yield
With tributyl-amine; water-d2 In N,N-dimethyl-formamide for 5h;	85%
With [(2)H6]acetone; deuteromethanol; water-d2; triethylamine for 1.5h; Ambient temperature;	63%

: 118-96-7
2,4,6-Trinitrotoluene

: 540-63-6
ethane-1,2-dithiol

: 1608182-18-8
1,2-bis((2-methyl-3,5-dinitrophenyl)thio)ethane

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 2h;	85%

: 118-96-7
2,4,6-Trinitrotoluene

: 623-51-8
ethyl 2-sulfanylacetate

: 367925-03-9
(2-methyl-3,5-dinitro-phenylsulfanyl)-acetic acid ethyl ester

Conditions

Conditions	Yield
With alkaline resin In acetone at 50℃; for 20h; Large scale;	85%

: 118-96-7
2,4,6-Trinitrotoluene

: 123-11-5
4-methoxy-benzaldehyde

: 61599-69-7
2-[(E)-2-(4-methoxyphenyl)vinyl]-1,3,5-trinitrobenzene

Conditions

Conditions	Yield
With HTc-4-Cal In toluene for 24h; Knoevenagel Condensation; Reflux; Dean-Stark;	83%
With piperidine In benzene for 6h; Condensation; Heating;	60%
With piperidine

: 118-96-7
2,4,6-Trinitrotoluene

: 587-04-2
3-Chlorobenzaldehyde

: trans-3′-chloro-2,4,6-trinitrostilbene

Conditions

Conditions	Yield
With piperidine; silica gel In neat (no solvent) at 120℃; for 0.333333h; Microwave irradiation;	83%
With HTc-4-Cal In toluene for 24h; Knoevenagel Condensation; Reflux; Dean-Stark;	71%

: 107-03-9
1-thiopropane

: 118-96-7
2,4,6-Trinitrotoluene

: 1608182-14-4
(2-methyl-3,5-dinitrophenyl)(propyl)sulfane

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 2h;	83%

: 118-96-7
2,4,6-Trinitrotoluene

: 100-53-8
phenylmethanethiol

: (2-methyl-5-nitro-1,3-phenylene)bis(benzylsulfane)

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 20℃;	83%

: 118-96-7
2,4,6-Trinitrotoluene

: 104-87-0
4-methyl-benzaldehyde

: trans-4′-methyl-2,4,6-trinitrostilbene

Conditions

Conditions	Yield
With piperidine; silica gel In neat (no solvent) at 120℃; for 0.333333h; Microwave irradiation;	82%
With piperazine at 80 - 90℃;

: 118-96-7
2,4,6-Trinitrotoluene

: 104-88-1
4-chlorobenzaldehyde

: 61599-70-0
trans-4′-chloro-2,4,6-trinitrostilbene

Conditions

Conditions	Yield
With piperidine; silica gel In neat (no solvent) at 120℃; for 0.333333h; Microwave irradiation;	82%
With HTc-4-Cal In toluene for 24h; Knoevenagel Condensation; Reflux; Dean-Stark;	70%
With piperidine at 120℃;