Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:620-93-9
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:Shanghai, Qingdao
1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:620-93-9
Min.Order:1 Gram
FOB Price: $0.1
Type:Manufacturers
inquiry1) Entity factory, can batch production 2) Sample service 3) the most competitive price with good quality: we have manufactured this product for many years with skilled craft and can control the cost. So, we can provide the most competitive price f
Cas:620-93-9
Min.Order:1 Kilogram
FOB Price: $10.0
Type:Lab/Research institutions
inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:620-93-9
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryProduct Description Product website: http://www.finerchem.com/pro01en/id/1562.html Product Name 4,4'-Dimethyldiphenylamine CAS No. 620-93
Cas:620-93-9
Min.Order:1 Gram
FOB Price: $5.0
Type:Lab/Research institutions
inquiryTriphenylamine And Its Derivatives Organic Light Emitting Display(OLED) Di-p-tolylamine Name Di-p-t
Cas:620-93-9
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu
Cas:620-93-9
Min.Order:1 Kilogram
FOB Price: $1.0 / 10.0
Type:Trading Company
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:620-93-9
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryhebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen
Cas:620-93-9
Min.Order:20 Kilogram
FOB Price: $10.0 / 100.0
Type:Trading Company
inquiry1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd
Cas:620-93-9
Min.Order:1 Kilogram
FOB Price: $100.0 / 112.0
Type:Trading Company
inquiryProduct name 4, 4'-dimethyldiphenylamine Synonym p,p'-ditlylamine CAS No 620-93-9 Molecular
1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:620-93-9
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese
Cas:620-93-9
Min.Order:1 Kilogram
FOB Price: $32.0 / 55.0
Type:Trading Company
inquiryDi-p-tolylamine CAS: 620-93-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermed
Cas:620-93-9
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:620-93-9
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryStable offering reliable quality 4,4'-dimethyldiphenylamine 620-93-9 with excellent Service 1.CAS No. 620-93-9 2.MF: C14H15N 3.Other Names:p,p'-ditlylamine 4.MF: C14H15N 5.EINECS No. :210-659-8 6.Assay(HPLC):99.0%min 7.Appeara
Cas:620-93-9
Min.Order:1 Kilogram
Negotiable
Type:Other
inquiryProduct Detail Minimum Order Qty. 10 Gram
Cas:620-93-9
Min.Order:10 Gram
Negotiable
Type:Trading Company
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:620-93-9
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquirysuperior quality moderate price & quick delivery Appearance:powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used to make other chem
Cas:620-93-9
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:620-93-9
Min.Order:0 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Cas:620-93-9
Min.Order:0 Metric Ton
Negotiable
Type:Other
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:620-93-9
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryDi-p-tolylamine,CAS 620-93-9Appearance:white powder Storage:Store in a cool dry place and keep away from strong light Package:according to customers' requirements Application:in research Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by
Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
We're in good position to supply OLED intermediates . We supply p,p'-Ditolylamine CAS# 620-93-9 at best price in China, Our p,p'-Ditolylamine CAS# 620-93-9 has been exported to many countries and regions. If you are looking for p,p
Conditions | Yield |
---|---|
99.6% | |
99.8% | |
53.7% | |
51.6% | |
With urea In diethylene glycol dimethyl ether; water at 150℃; under 760.051 Torr; for 24h; Schlenk technique; Inert atmosphere; | 84 %Chromat. |
1-methyl-4-nitrobenzene
N-(4-methylcyclohexylidene)-4-methylaniline
di-p-tolylamine
Conditions | Yield |
---|---|
palladium-carbon In water; N,N-dimethyl-formamide; benzene | 99.7% |
Conditions | Yield |
---|---|
With [Pd(N,N'-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)-imidazol-2-ylidene)(acetylacetonate)Cl]; lithium hexamethyldisilazane In 1,4-dioxane at 110℃; for 3h; Buchwald-Hartwig Coupling; Inert atmosphere; Sealed tube; | 99% |
With bis-triphenylphosphine-palladium(II) chloride; caesium carbonate; triphenylphosphine In o-xylene for 8h; Inert atmosphere; Reflux; Schlenk technique; | 90% |
With bis(η3-allyl-μ-chloropalladium(II)); 1,2-bis(diphenylphosphino)-1′-(diisopropylphosphino)-4-tert-butylferrocene; sodium t-butanolate In toluene for 20h; Reflux; Schlenk technique; Inert atmosphere; chemoselective reaction; | 84% |
Conditions | Yield |
---|---|
With bis(η3-allyl-μ-chloropalladium(II)); potassium tert-butylate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 1,4-dioxane at 100℃; for 1.5h; Inert atmosphere; | 99% |
With dihydrogen dichloro-bis(di-tert-butylphosphinito-κP)palladium(2-); sodium t-butanolate In 1,4-dioxane at 110℃; for 4h; | 97% |
With potassium hydroxide; tert-butyl alcohol; cyclopalladated ferrocenylimine monophosphinobiaryl complex In water at 95℃; for 24h; Buchwald-Hartwig amination; | 97% |
1-methyl-4-nitrobenzene
p-toluidine
1-methylcyclohexan-4-one
di-p-tolylamine
Conditions | Yield |
---|---|
palladium-carbon In water; N,N-dimethyl-formamide; benzene | 98.6% |
palladium-carbon In water; N,N-dimethyl-formamide; benzene | 98.6% |
Conditions | Yield |
---|---|
With SingaCycle-A1; sodium t-butanolate In tetrahydrofuran at 60℃; for 4h; Inert atmosphere; regioselective reaction; | 98% |
Conditions | Yield |
---|---|
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; 1,1'-bis(diphenylphosphino)ferrocene; sodium t-butanolate In toluene at 110℃; for 24h; Buchwald-Hartwig coupling; Inert atmosphere; | 96% |
With nickel(II) iodide; potassium phosphate; 2-Phenyl-1,3,2-dioxaborinane In 1,4-dioxane at 115℃; for 24h; Buchwald-Hartwig Coupling; Inert atmosphere; chemoselective reaction; | 96% |
With (1,2-dimethoxyethane)dichloronickel(II); Ir[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]2(4,4'-di-tert-butyl-2,2'-bipyridyl)PF6; triethylamine; 4,4'-di-tert-butyl-2,2'-bipyridine In acetonitrile at 23 - 25℃; for 24h; Sealed tube; Irradiation; chemoselective reaction; | 65% |
With potassium hydroxide In neat (no solvent) at 90℃; for 9h; | 35% |
Conditions | Yield |
---|---|
With C30H25N4O(1-)*3C2H3O2(1-)*2Cu(2+) at 20℃; for 24h; | 95% |
With triethylamine; cupric acetate immobilized onto Wang resin In dichloromethane at 20℃; for 24h; | 94% |
With (1,3-bis(2,6-diisopropyl-4-((E)-3-methoxy-3-oxoprop-1-en-1-yl)phenyl)-2,3-dihydro-1H-imidazole-2-yl)copper(I) chloride In dichloromethane at 20℃; for 24h; Chan-Lam Coupling; | 93% |
Conditions | Yield |
---|---|
copper diacetate In dichloromethane for 2h; Ambient temperature; | 94% |
Conditions | Yield |
---|---|
With pyridine; copper diacetate trihydrate In dichloromethane at 20℃; for 24h; Chan-Lam Coupling; | 94% |
Conditions | Yield |
---|---|
With potassium phosphate; copper(l) iodide; lithium amide In N,N-dimethyl-formamide at 130℃; for 24h; Inert atmosphere; chemoselective reaction; | 93% |
With potassium phosphate; copper(l) iodide; lithium amide In N,N-dimethyl-formamide at 130℃; for 24h; | |
With guanidine nitrate; potassium hydroxide In dimethyl sulfoxide at 130℃; for 36h; Sealed tube; Inert atmosphere; | 83 %Chromat. |
With potassium phosphate; copper(l) iodide; lithium amide In N,N-dimethyl-formamide for 24h; Reflux; |
Conditions | Yield |
---|---|
With copper(II) acetate monohydrate; triethylamine In acetonitrile at 20℃; for 24h; Chan-Lam Coupling; | 91% |
Conditions | Yield |
---|---|
With N/O-doped porous carbon (on base of polypyrrole) supported nanopalladium at 80℃; Inert atmosphere; | 90% |
Conditions | Yield |
---|---|
With bis(acetylacetonato)palladium(II); potassium phosphate tribasic trihydrate; 2-(2,6-diethyl-4-methylphenyl)-5-(2,4,6-triisopropylphenyl)imidazo[1,5-a]pyridin-2-ium chloride In 1,4-dioxane at 130℃; for 24h; Inert atmosphere; | 90% |
di-p-tolylamine
Conditions | Yield |
---|---|
With ammonia; copper(II) acetate monohydrate; benzoic acid In water; Ethyl propionate at 80℃; for 24h; | 85% |
With hydroxylamine hydrochloride; potassium carbonate; copper(I) bromide In acetonitrile at 70℃; for 24h; Chan-Lam reaction; | 70% |
Conditions | Yield |
---|---|
With L-arginine; potassium hydroxide In water at 80℃; under 760.051 Torr; for 8h; Green chemistry; | 84% |
(i) BrCH2CH2Br, Mg, (ii) NOCl; Multistep reaction; |
tetrakis(4-methylphenyl)antimony acetate
p-toluidine
di-p-tolylamine
Conditions | Yield |
---|---|
With copper diacetate; triethylamine In dichloromethane at 40℃; for 6h; Ullmann condensation; In air; | 77% |
Conditions | Yield |
---|---|
With copper(l) iodide; N,N,N,N,-tetramethylethylenediamine In toluene for 3h; Heating; | 76% |
di-p-tolylamine
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol; water for 6h; Inert atmosphere; Heating; | 76% |
N,N-bis-(4-tolyl)acetamide
di-p-tolylamine
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol at 90℃; for 14h; Inert atmosphere; | 75% |
Stage #1: N,N-bis-(4-tolyl)acetamide With Triethoxysilane; sodium triethylborohydride In tert-butyl methyl ether at 80℃; for 6h; Stage #2: With hydrogenchloride In tert-butyl methyl ether; water at 20℃; for 1h; chemoselective reaction; | 70% |
With water; potassium hydroxide In i-Amyl alcohol | |
Multi-step reaction with 2 steps 1: potassium hydroxide; triethyl borane / tetrahydrofuran / 24 h / 25 °C / Inert atmosphere; Schlenk technique; Sealed tube 2: sodium hydroxide; water / tetrahydrofuran / 1 h / 25 °C / Inert atmosphere; Schlenk technique; Sealed tube View Scheme |
Conditions | Yield |
---|---|
In toluene | 74% |
Conditions | Yield |
---|---|
Stage #1: p-cresol; p-toluidine With caesium carbonate; chloroacetyl chloride In N,N-dimethyl-formamide at 20℃; for 0.5h; Smiles rearrangement; Stage #2: In N,N-dimethyl-formamide at 150℃; Smiles rearrangement; Microwave irradiation; | 74% |
at 280℃; under 3750.38 Torr; for 16h; Pressure; Temperature; | 9.8% |
Conditions | Yield |
---|---|
With SingaCycle-A3; potassium hexamethylsilazane In 1,4-dioxane; toluene at 100℃; for 12h; Schlenk technique; Inert atmosphere; | 72% |
Conditions | Yield |
---|---|
With palladium on activated carbon; ammonium formate; lithium hydroxide In m-xylene at 170℃; for 24h; Schlenk technique; Inert atmosphere; | 70% |
With ammonium chlorozincate; ammonium chloride at 330 - 340℃; |
4-tolyl iodide
A
di-p-tolylamine
B
tri(p-tolyl)amine
C
(E)-4,4'-dimethylazobenzene
Conditions | Yield |
---|---|
With copper(l) iodide In pyridine for 5h; Heating; | A 68% B 17% C 13% |
Conditions | Yield |
---|---|
With copper(l) iodide; 4-tolyl iodide In pyridine for 5h; Heating; | A 68% B 17% C 13% |
Conditions | Yield |
---|---|
With potassium phosphate In 1,4-dioxane at 100℃; for 12h; | 65% |
4-tolyl iodide
p-toluidine
phenylboronic acid
A
4-Methylbiphenyl
B
di-p-tolylamine
Conditions | Yield |
---|---|
With potassium phosphate; palladium dichloride In 1,4-dioxane at 115℃; for 24h; Inert atmosphere; chemoselective reaction; | A 65% B 30% |
With potassium phosphate; palladium dichloride In 1,4-dioxane at 115℃; for 24h; Inert atmosphere; chemoselective reaction; | A 37% B 59% |
Conditions | Yield |
---|---|
With bis(tri-ortho-tolylphosphine)palladium(0); (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl-di-tert-butylphosphine; ammonia; sodium t-butanolate In 1,4-dioxane at 100℃; for 10h; Inert atmosphere; | A n/a B 55% |
With bis(η3-allyl-μ-chloropalladium(II)); 2-[di-(3S,5S,7S)-adamantan-1-ylphosphino]-N,N-dimethylaniline; ammonia; sodium t-butanolate In 1,4-dioxane at 110 - 120℃; Buchwald-Hartwig amination; Inert atmosphere; | |
With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; N-[2-(di(1-adamantyl)phosphino)phenyl]piperidine; ammonia; sodium t-butanolate In 1,4-dioxane at 110℃; for 4h; Inert atmosphere; | |
With (R)-(-)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; bis(tri-ortho-tolylphosphine)palladium(0); ammonium chloride; sodium t-butanolate In 1,4-dioxane at 100℃; for 12h; Catalytic behavior; Reagent/catalyst; Temperature; Time; Inert atmosphere; Overall yield = 94 %Chromat.; | |
With ((+/-)-binap)Ni[P(OPh)3]2; ammonia; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In 1,4-dioxane at 120℃; for 18h; Reagent/catalyst; Temperature; Time; Sealed tube; Overall yield = 99 %Chromat.; | A n/a B 51 %Chromat. |
Conditions | Yield |
---|---|
With potassium carbonate In acetonitrile for 18h; Inert atmosphere; Reflux; Glovebox; Sealed tube; | 100% |
Stage #1: di-p-tolylamine With n-butyllithium In tetrahydrofuran at 0 - 20℃; for 1.5h; Inert atmosphere; Stage #2: methyl iodide In tetrahydrofuran at 0 - 20℃; Inert atmosphere; | 87% |
Stage #1: di-p-tolylamine With sodium hydride In tetrahydrofuran at 20℃; for 2h; Stage #2: methyl iodide In tetrahydrofuran at 20℃; for 17h; | 76% |
Conditions | Yield |
---|---|
With dmap; copper(I) bromide dimethylsulfide complex; oxygen In dichloromethane at 20℃; under 760.051 Torr; for 17h; | 99% |
With potassium metaperiodate; potassium iodide In acetonitrile at 20℃; for 8h; Inert atmosphere; | 96% |
With N,N'-di-tert-butyldiaziridinone; copper(I) bromide In acetonitrile at 20℃; for 2h; | 80% |
Conditions | Yield |
---|---|
With (μ-Cl)2Ni2(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)2; IPrNiCl(PPh3); sodium t-butanolate In tetrahydrofuran at 40℃; for 24h; Reagent/catalyst; Buchwald-Hartwig Coupling; Inert atmosphere; Schlenk technique; Glovebox; | 99% |
With palladium diacetate; tri-tert-butyl phosphine; sodium t-butanolate In benzene at 90℃; for 18h; Substitution; | 96.3% |
With [2,2]bipyridinyl; [NiCl(bpy)(IPr)]; sodium t-butanolate In tetrahydrofuran at 40℃; for 24h; Buchwald-Hartwig Coupling; Glovebox; Inert atmosphere; | 91% |
Conditions | Yield |
---|---|
Stage #1: di-p-tolylamine; 1-Chloronaphthalene With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate In toluene Buchwald-Hartwig Coupling; Inert atmosphere; Sealed tube; Stage #2: With n-hexyllithium In hexane; toluene at 105℃; for 2h; Buchwald-Hartwig Coupling; Inert atmosphere; Sealed tube; | 99% |
With 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl; n-hexyllithium; palladium diacetate In hexane; toluene at 105℃; for 2h; Buchwald-Hartwig Coupling; Inert atmosphere; | 99% |
Stage #1: di-p-tolylamine With bis(tricyclohexylphosphine)nickel(II) dichloride; isopropylmagnesium chloride; tricyclohexylphosphine In tetrahydrofuran; 1,4-dioxane at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: 1-Chloronaphthalene In tetrahydrofuran; 1,4-dioxane at 20 - 95℃; for 12.16h; Inert atmosphere; | 70% |
Conditions | Yield |
---|---|
With 1,10-Phenanthroline; palladium(II) trimethylacetate; copper diacetate; trifluoroacetic acid In methanol at 110℃; for 24h; | 99% |
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; lithium hexamethyldisilazane; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran at 65℃; for 16h; Inert atmosphere; | 99% |
Stage #1: 3-bromo-9H-carbazole; di-p-tolylamine With ethylmagnesium bromide In diethyl ether at 25℃; for 0.166667h; Stage #2: With iron(II) chloride tetrahydrate In toluene at 120℃; for 6h; | 78% |
9,9-bis-(n-butyl)-2,7-dibromofluorene
di-p-tolylamine
9,9-dibutyl-N2,N2,N7,N7-tetra-p-tolyl-9H-fluorene-2,7-diamine
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; palladium diacetate; caesium carbonate In toluene for 13h; Buchwald-Hartwig cross-coupling reaction; Reflux; | 98% |
Conditions | Yield |
---|---|
In methanol Reflux; | 98% |
di-p-tolylamine
Conditions | Yield |
---|---|
With potassium hydride In tetrahydrofuran at 50℃; for 6h; Schlenk technique; Inert atmosphere; | 98% |
di-p-tolylamine
4-methyl-N1,N1,N2-tritolylbenzene-1,2-diamine
Conditions | Yield |
---|---|
Stage #1: di-p-tolylamine With n-butyl magnesium bromide In dibutyl ether at 0 - 100℃; for 1h; Stage #2: With ethylene dibromide; iron(II) chloride In dibutyl ether at 60℃; for 24h; | 98% |
1,3,5-trisbromobenzene
di-p-tolylamine
N1,N1,N3,N3,N5,N5-hexakis(4-methylphenyl)-1,3,5-benzenetriamine
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 60℃; for 7h; Inert atmosphere; Schlenk technique; | 98% |
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 60℃; for 7h; Inert atmosphere; | 98% |
1,1,3,3-Tetramethyldisiloxane
di-p-tolylamine
1,1,3,3-tetramethyl-N,N,N',N'-tetra-p-tolyldisiloxane-1,3-diamine
Conditions | Yield |
---|---|
With tris(pentafluorophenyl)borate In dichloromethane at 25℃; for 1h; Inert atmosphere; Glovebox; Schlenk technique; | 97% |
Conditions | Yield |
---|---|
With 1,10-Phenanthroline; palladium(II) trimethylacetate; copper diacetate; trifluoroacetic acid In methanol at 110℃; for 24h; | 97% |
di-p-tolylamine
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; palladium diacetate; caesium carbonate In tetrahydrofuran; toluene at 120℃; for 18h; Time; Buchwald-Hartwig Coupling; Inert atmosphere; Sealed tube; Schlenk technique; | 97% |
4-(4-bromophenyl)bromobenzene
di-p-tolylamine
N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; sodium hydroxide In o-xylene at 200℃; for 2h; Solvent; Temperature; Inert atmosphere; Dean-Stark; | 96.2% |
With sodium tert-pentoxide; palladium diacetate; 1,3,5,7-tetramethyl-2,4,8-trioxa-6-phosphaadamantane In toluene at 20 - 90℃; for 1.58333 - 1.83333h; | 95.1% |
Conditions | Yield |
---|---|
With hydrogenchloride; sodium nitrite In methanol; water Cooling with ice; | 96% |
With hydrogenchloride; ethanol; water; sodium nitrite | |
Stage #1: di-p-tolylamine With hydrogenchloride In ethanol; water at 0℃; for 0.0833333h; Stage #2: With sodium nitrite In ethanol; water at 0℃; for 1.08333h; |
Conditions | Yield |
---|---|
Stage #1: di-p-tolylamine With ethylmagnesium bromide In diethyl ether at 0 - 40℃; for 2h; Inert atmosphere; Stage #2: bromobenzene With lithium bromide; iron(II) chloride In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 72h; Inert atmosphere; | 96% |
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In o-xylene at 120℃; for 20h; Inert atmosphere; | 96% |
With chloro(1-naphthyl)bis(triphenylphosphine)nickel(II); sodium hydride; triphenylphosphine In toluene; white oil at 120℃; for 12h; Inert atmosphere; | 85% |
With bis(triphenylphosphine)nickel(II) chloride; ethylmagnesium bromide; triphenylphosphine In tetrahydrofuran at 90℃; for 5h; | 76% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; potassium tert-butylate In toluene at 80℃; for 14h; Buchwald-Hartwig Coupling; | 96% |
Conditions | Yield |
---|---|
Stage #1: 1-Bromonaphthalene; di-p-tolylamine With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate In toluene Buchwald-Hartwig Coupling; Inert atmosphere; Sealed tube; Stage #2: With n-hexyllithium In hexane; toluene at 105℃; for 2h; Buchwald-Hartwig Coupling; Inert atmosphere; Sealed tube; | 96% |
With 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl; n-hexyllithium; palladium diacetate In hexane; toluene at 105℃; for 2h; Buchwald-Hartwig Coupling; Inert atmosphere; | 96% |
di-p-tolylamine
1-bromo-3,5-dimethoxybenzene
N-(3,5-dimethoxyphenyl)-di-p-tolylamine
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; potassium tert-butylate; bis(dibenzylideneacetone)-palladium(0) In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Reflux; | 96% |
With palladium diacetate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In toluene for 10h; Buchwald-Hartwig Coupling; Reflux; Inert atmosphere; | 65% |
di-p-tolylamine
2-bromo-1-(4-fluorophenyl)ethylene
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane; 1,1,3,3-Tetramethyldisiloxane; copper chromite; F6Sb(1-)*Au(1+)*C2H3N; 1,2-bis-(diphenylphosphino)ethane; silver(I) triflimide at 75℃; for 9h; Reagent/catalyst; | 95.9% |
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tri-tert-butyl phosphine; sodium t-butanolate In hexane; toluene for 8h; Reflux; Inert atmosphere; | 95.6% |
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