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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Diadamantylphosphine Manufacturer/High quality/Best price/In stock

Cas:131211-27-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high purity Storage:Sealed, dry, microtherm , avoid light and smell. Package:meet customer's demand Application:organic synthesis Transportation:by sea or by air Port:Shanghai, Qingdao

Bis(1-adamantyl)phosphine

Cas:131211-27-3

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 131211-27-3 DI-1-ADAMANTYLPHOSPHINE Manufacturer

Cas:131211-27-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Qingdao Greenchem international Trading Co.,Ltd. is the commercial company which is invested by BeiJing Greenchem Technology Co.,Ltd. in Qingdao. It takes charge of export and production promotion, as well as imports and selling relevant produc

DI-1-ADAMANTYLPHOSPHINE

Cas:131211-27-3

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Di-1-adamantylphosphine

Cas:131211-27-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

DI-1-ADAMANTYLPHOSPHINE

Cas:131211-27-3

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

High purity CAS 131211-27-3 DI-1-ADAMANTYLPHOSPHINE in stock Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediates (

High purity CAS 131211-27-3 DI-1-ADAMANTYLPHOSPHINE in stock

Cas:131211-27-3

Min.Order:1 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 131211-27-3 with best quality

Cas:131211-27-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name: DI-1-ADAMANTYLPHOSPHINE Synonyms: DI-1-ADAMANTYLPHOSPHINE;Di-1-adamantylphosphine,min.97%;Bis(adamant-1-yl)phosphine, Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine;Di-1-adamantylphosphine, min. 97%;Bis(1-adamantyl)phosphine,

Bis(1-adamantyl)phosphine

Cas:131211-27-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

DI-1-ADAMANTYLPHOSPHINE 1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store i

DI-1-ADAMANTYLPHOSPHINE

Cas:131211-27-3

Min.Order:10 Gram

Negotiable

Type:Other

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Shanghai Minstar Chemical Co., Ltd

DI-1-ADAMANTYLPHOSPHINE Basic information Appearance Product Name: DI-1-ADAMANTYLPHOSPHINE Synonyms: DI-1-ADAMANTYLPHOSPHINE;Bis(adamant-1-yl)phosphine, Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine;Di-1-adamantylphosphine, min. 97%;Bis(1-adamanty

DI-1-ADAMANTYLPHOSPHINE,

Cas:131211-27-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

DI-1-ADAMANTYLPHOSPHINE CAS:131211-27-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

DI-1-ADAMANTYLPHOSPHINE CAS:131211-27-3

Cas:131211-27-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

DI-1-ADAMANTYLPHOSPHINE

Cas:131211-27-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

Di-1-adamantylphosphine

Cas:131211-27-3

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

DI-1-ADAMANTYLPHOSPHINE

Cas:131211-27-3

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Di-1-adamantylphosphine

Cas:131211-27-3

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

DI-1-ADAMANTYLPHOSPHINE

Cas:131211-27-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products Di-1-adamantylphosphine

Cas:131211-27-3

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

DI-1-ADAMANTYLPHOSPHINE/High quality/Best price

Cas:131211-27-3

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Di-1-adamantylphosphine

Cas:131211-27-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: Di-1-Adamantylphosphine CAS No.:131211-27-3 Molecule Formula:C20H31P Molecule Weight:302.43 Purity: 98.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS

High Quality Di-1-Adamantylphosphine on stock

Cas:131211-27-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

DI-1-ADAMANTYLPHOSPHINECAS NO.: 131211-27-3

Cas:131211-27-3

Min.Order:1 Kilogram

FOB Price: $4.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

DI-1-ADAMANTYLPHOSPHINE

Cas:131211-27-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

DI-1-ADAMANTYLPHOSPHINE

Cas:131211-27-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

DI-1-ADAMANTYLPHOSPHINE

Cas:131211-27-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

DI-1-ADAMANTYLPHOSPHINE

Cas:131211-27-3

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/Di-1-adamantylphosphine

Cas:131211-27-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

DI-1-ADAMANTYLPHOSPHINE

Cas:131211-27-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Di-1-adamantylphosphine cas no. 131211-27-3 98%

Cas:131211-27-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

DI-1-ADAMANTYLPHOSPHINE CAS 131211-27-3

Cas:131211-27-3

Min.Order:0

Negotiable

Type:Other

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Synthetic route

1-(1-adamantyl)chlorophosphinoyladamantane
126683-99-6

1-(1-adamantyl)chlorophosphinoyladamantane

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran for 16h; Ambient temperature;94.3%
With trichlorosilane In toluene for 264h; Ambient temperature;93%
With lithium aluminium tetrahydride In tetrahydrofuran at -10 - 20℃; for 14h;90%
di-1-adamantylchlorophosphane
157282-19-4

di-1-adamantylchlorophosphane

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether at 20℃; for 4h;70%
(1-adamantyl)magnesium chloride
97580-87-5

(1-adamantyl)magnesium chloride

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 69 percent / diethyl ether / Heating
2: 70 percent / LiAlH4 / diethyl ether / 4 h / 20 °C
View Scheme
(1-adamantyl)dichlorophosphine
23906-91-4

(1-adamantyl)dichlorophosphine

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 69 percent / diethyl ether / Heating
2: 70 percent / LiAlH4 / diethyl ether / 4 h / 20 °C
View Scheme
adamantane
281-23-2

adamantane

Fe(CO)5

Fe(CO)5

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1.) PCl3, AlCl3, 2.) H2O / 1.) reflux, 6 h, 2.) chloroform
2: 94.3 percent / LiAlH4 / tetrahydrofuran / 16 h / Ambient temperature
View Scheme
adamantane
281-23-2

adamantane

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 95 percent / phosphorus trichloride, aluminum chloride / 5 h / Heating
2: 62 percent / LiAlH4 / diethyl ether / 3 h / Heating
View Scheme
Multi-step reaction with 2 steps
1: phosphorus trichloride; aluminum (III) chloride / 6.17 h / Reflux
2: lithium aluminium tetrahydride / tetrahydrofuran / 20 h / -10 - 20 °C
View Scheme
Multi-step reaction with 2 steps
1.1: aluminum (III) chloride; phosphorus trichloride / Reflux
1.2: Cooling with ice
2.1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere
View Scheme
bis(1-adamantyl)phosphine oxide
131266-79-0

bis(1-adamantyl)phosphine oxide

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

Conditions
ConditionsYield
With copper(II) trifluoromethanesulfonate; 1,1,3,3-Tetramethyldisiloxane In toluene at 100℃; for 9h; Inert atmosphere;
With diethoxymethylane; Bis(p-nitrophenyl) phosphate In toluene at 110℃; Inert atmosphere; chemoselective reaction;99 %Spectr.
di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

di-1-adamantylchlorophosphane
157282-19-4

di-1-adamantylchlorophosphane

Conditions
ConditionsYield
With tetrachloromethane at 50℃; for 16h;100%
With tetrachloromethane at 50℃; for 24h;98%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene for 16h; Ambient temperature;93.7%
With phosgene; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at -10℃;67%
Multi-step reaction with 2 steps
1: phosgen / toluene / Ambient temperature
2: Et3N / toluene / a) 60 deg C, 4 h, b) reflux, 3 h
View Scheme
benzyl bromide
100-39-0

benzyl bromide

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

di(1-adamantyl)benzylphosphonium hydrobromide

di(1-adamantyl)benzylphosphonium hydrobromide

Conditions
ConditionsYield
In toluene Glovebox; Schlenk technique; Inert atmosphere; Reflux;100%
In toluene Glovebox; Schlenk technique; Inert atmosphere; Reflux;100%
In toluene at 90℃; for 14h;92%
di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

C20H30P(1-)*Li(1+)

C20H30P(1-)*Li(1+)

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 3h;100%
di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

bis(1-adamantyl)phosphine oxide
131266-79-0

bis(1-adamantyl)phosphine oxide

Conditions
ConditionsYield
With dihydrogen peroxide In toluene for 1h; Ambient temperature;99.3%
With oxygen In tetrahydrofuran for 6h;90%
Multi-step reaction with 2 steps
1: toluene / 16 h / Ambient temperature
2: H2O / CH2Cl2 / 72 h / Ambient temperature
View Scheme
Multi-step reaction with 2 steps
1: 93.7 percent / COCl2, DBU / toluene / 16 h / Ambient temperature
2: 84.5 percent / H2O, DBU / CH2Cl2 / 72 h / Ambient temperature
View Scheme
With oxygen
borane-THF
14044-65-6

borane-THF

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

di-adamantan-1-yl-phosphane; compound with borane

di-adamantan-1-yl-phosphane; compound with borane

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 16h;98%
BH3-THP
92348-80-6

BH3-THP

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

[di-1-adamantylphosphine]trihydroboron
512185-48-7

[di-1-adamantylphosphine]trihydroboron

Conditions
ConditionsYield
for 5h;98%
3-bromo-4-morpholinobenzonitrile
1207541-01-2

3-bromo-4-morpholinobenzonitrile

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

C31H41N2OP

C31H41N2OP

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In toluene at 110℃; Inert atmosphere;98%
di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

2-Bromoethyl methyl ether
6482-24-2

2-Bromoethyl methyl ether

di(1-adamantyl)-2-methoxyethylphosphonium bromide

di(1-adamantyl)-2-methoxyethylphosphonium bromide

Conditions
ConditionsYield
at 80℃; for 8h;95%
di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

bromo-di(1-adamantyl)phosphine

bromo-di(1-adamantyl)phosphine

Conditions
ConditionsYield
With carbon tetrabromide In dichloromethane for 0.0833333h; Inert atmosphere;95%
Multi-step reaction with 2 steps
1: Br2 / toluene / 0 °C
2: Et3N / toluene / 1 h / Heating
View Scheme
1-{[dimethyl(1,1-dimethylethyl)silyl]oxy}-4-iodobutane
92511-12-1

1-{[dimethyl(1,1-dimethylethyl)silyl]oxy}-4-iodobutane

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

di-adamantan-1-yl-[4-(tert-butyl-dimethyl-silanyloxy)-butyl]-phosphane; hydriodide

di-adamantan-1-yl-[4-(tert-butyl-dimethyl-silanyloxy)-butyl]-phosphane; hydriodide

Conditions
ConditionsYield
In toluene at 90℃; for 14h;94%
[(1,3-bis-(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)PdCl(μ-Cl)]2

[(1,3-bis-(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)PdCl(μ-Cl)]2

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

[(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)Pd(Cl)2(PH(C10H15)2]

[(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)Pd(Cl)2(PH(C10H15)2]

Conditions
ConditionsYield
In not given by a react. of Pd-contg. compd. with a ligand (2 equivs.) at room temp. for 1 h; (31)P NMR spectra monitoring;94%
C32H20BrF12N

C32H20BrF12N

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

C52H50F12NP

C52H50F12NP

Conditions
ConditionsYield
Stage #1: C32H20BrF12N With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In toluene at 24℃; for 0.25h; Inert atmosphere; Schlenk technique;
Stage #2: di-1-adamantylphosphine In toluene at 120℃; for 16h; Inert atmosphere;
94%
di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

methyl iodide
74-88-4

methyl iodide

di(1-adamantyl)methylphosphonium iodide

di(1-adamantyl)methylphosphonium iodide

Conditions
ConditionsYield
In toluene for 24h; Ambient temperature;93%
In dibutyl ether at 20℃; for 24h;90%
1-iodo-butane
542-69-8

1-iodo-butane

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

di(1-adamantyl)-N-butylphosphine hydroiodide

di(1-adamantyl)-N-butylphosphine hydroiodide

Conditions
ConditionsYield
In dibutyl ether at 130℃; for 8h;93%
di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

4-(monomethyl polyethylene glycol 2000)-CH2C6H4CH2Br

4-(monomethyl polyethylene glycol 2000)-CH2C6H4CH2Br

4-(monomethyl polyethylene glycol 2000)-CH2C6H4CH2P(1-Ad)2*HBr

4-(monomethyl polyethylene glycol 2000)-CH2C6H4CH2P(1-Ad)2*HBr

Conditions
ConditionsYield
In toluene at 90℃; for 14h;92%
di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

(2-bromophenoxy)-triisopropylsilane
378787-34-9

(2-bromophenoxy)-triisopropylsilane

OTips-DalPhos
1384966-55-5

OTips-DalPhos

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 12h; Concentration; Inert atmosphere; Sealed tube;91%
With 1,1'-bis(diisopropylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 12h; Inert atmosphere; Sealed vial;83%
1,8-bis(bromomethyl)-3,6-di-tert-butyl-9H-carbazole
1421060-68-5

1,8-bis(bromomethyl)-3,6-di-tert-butyl-9H-carbazole

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

1,8-bis(di-1-adamantylphosphinomethyl)-3,6-di-tert-butyl-9H-carbazole

1,8-bis(di-1-adamantylphosphinomethyl)-3,6-di-tert-butyl-9H-carbazole

Conditions
ConditionsYield
In acetone for 24h; Schlenk technique; Inert atmosphere; Reflux;90%
di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)

di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

chloro-{[2-(N,N-dimethylamino)methyl]phenyl-C,N}(di-1-adamantylphosphine-P)palladium

chloro-{[2-(N,N-dimethylamino)methyl]phenyl-C,N}(di-1-adamantylphosphine-P)palladium

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 20℃; for 0.5h; Solvent; Temperature; Schlenk technique; Glovebox; Inert atmosphere;90%
2-(2-bromo-4,5-dimethoxyphenyl)-1,3-dioxolane
103477-58-3

2-(2-bromo-4,5-dimethoxyphenyl)-1,3-dioxolane

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

(2-(1,3-dioxolan-2-yl)-4,5-dimethoxyphenyl)di((3S,5S,7S)-adamant-an-1-yl)phosphane

(2-(1,3-dioxolan-2-yl)-4,5-dimethoxyphenyl)di((3S,5S,7S)-adamant-an-1-yl)phosphane

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 10h; Inert atmosphere;90%
4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

trifluoroacetic acid
76-05-1

trifluoroacetic acid

di(1-adamantyl)-4-(N,N-dimethyl)amino-phenyl-phosphane trifluoroacetic acid

di(1-adamantyl)-4-(N,N-dimethyl)amino-phenyl-phosphane trifluoroacetic acid

Conditions
ConditionsYield
Stage #1: 4-bromo-N,N-dimethylaniline; di-1-adamantylphosphine With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate In toluene at 100℃; Inert atmosphere;
Stage #2: trifluoroacetic acid In water; acetonitrile
89.6%
di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

di-adamantan-1-yl-(4-bromo-benzyl)-phosphane; hydrobromide

di-adamantan-1-yl-(4-bromo-benzyl)-phosphane; hydrobromide

Conditions
ConditionsYield
In toluene at 90℃; for 14h;89%
trimethylsilylazide
4648-54-8

trimethylsilylazide

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

di-1-adamantylphosphinsaeure-(N-trimethylsilylamid)-N-trimethylsilylimid

di-1-adamantylphosphinsaeure-(N-trimethylsilylamid)-N-trimethylsilylimid

Conditions
ConditionsYield
In toluene for 72h; Heating;88.9%
4-(2-bromopyridin-3-yl)morpholine
54231-45-7

4-(2-bromopyridin-3-yl)morpholine

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

C29H41N2OP

C29H41N2OP

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In toluene at 110℃; Inert atmosphere;88%
C14H15BrN4

C14H15BrN4

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

N-(2-(diadamantylphosphino)phenyl)-2-(piperazin-1-yl)pyrimidine

N-(2-(diadamantylphosphino)phenyl)-2-(piperazin-1-yl)pyrimidine

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate In toluene at 110℃; Inert atmosphere; Schlenk technique; Sealed tube;88%
C33H19BrF15N

C33H19BrF15N

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

C53H49F15NP

C53H49F15NP

Conditions
ConditionsYield
Stage #1: C33H19BrF15N With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In toluene at 24℃; for 0.25h; Inert atmosphere; Schlenk technique;
Stage #2: di-1-adamantylphosphine In toluene at 120℃; for 14h; Inert atmosphere;
88%
di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

C20H30IP*HI

C20H30IP*HI

Conditions
ConditionsYield
With iodine In tetrachloromethane at 0℃; for 2h;87.7%
4-(2-bromo-5-methylphenyl)morpholine

4-(2-bromo-5-methylphenyl)morpholine

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

C31H44NOP

C31H44NOP

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In toluene at 110℃; Inert atmosphere;87%
4-bromopyridin
1120-87-2

4-bromopyridin

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

trifluoroacetic acid
76-05-1

trifluoroacetic acid

di(1-adamantantyl)-4-pyridyl-phosphane trifluoroacetic acid

di(1-adamantantyl)-4-pyridyl-phosphane trifluoroacetic acid

Conditions
ConditionsYield
Stage #1: 4-bromopyridin; di-1-adamantylphosphine With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate In toluene at 100℃; Inert atmosphere;
Stage #2: trifluoroacetic acid In water; acetonitrile
87%
1-Adamantanecarbonyl chloride
2094-72-6

1-Adamantanecarbonyl chloride

di-1-adamantylphosphine
131211-27-3

di-1-adamantylphosphine

Di-1-adamantyl-(1-adamantoyl)phosphin

Di-1-adamantyl-(1-adamantoyl)phosphin

Conditions
ConditionsYield
With triethylamine In toluene for 336h; Ambient temperature;86.6%

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