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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

4-Bromobenzyl bromide Manufacturer/High quality/Best price/In stock

Cas:589-15-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Bromobenzylbromide supplier in China

Cas:589-15-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

4-Bromobenzylbromide CAS NO.589-15-1

Cas:589-15-1

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply α,4-dibromotoluene

Cas:589-15-1

Min.Order:1

Negotiable

Type:Other

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

4-Bromobenzyl bromide Basic information Product Name: 4-Bromobenzyl bromide Synonyms: P-BROMOBENZYL BROMIDE;PBBB;,4-Dibromotoluene;1-bromo-4-(bromomethyl)-benzen;1-Bromo-4-(bromomethyl)b

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name 4-Bromobenzyl bromide CAS No. 589-15-1

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:1 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

4-Bromobenzyl Bromide CAS 589-15-1

Cas:589-15-1

Min.Order:1 Kilogram

FOB Price: $70.0 / 90.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Hot selling CAS 589-15-1 with best price

Cas:589-15-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

factory supply 99% 4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

4-Bromobenzyl bromideCAS NO.:589-15-1

Cas:589-15-1

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shijiazhuang Sdyano Fine Chemical Co., Ltd

1. Best prices with satisfied quality; 2. It's clients' right to choose the package's Courier (EMS, DHL, FedEx, UPS); 3.It's clients' right to choose the packing way for his produccts from many recent effective packing w

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-Bromobenzyl bromide 589-15-1

Cas:589-15-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pharmaceutical Intermediate, 4-Bromobenzyl bromide CAS:589-15-1

Cas:589-15-1

Min.Order:1 Kilogram

FOB Price: $24.7 / 28.3

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supply High quality 4-Bromobenzyl bromide CAS 589-15-1 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made in C

High quality 4-Bromobenzyl bromide CAS 589-15-1

Cas:589-15-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several

4-Bromobenzyl bromide cas:589-15-1

Cas:589-15-1

Min.Order:25 Gram

FOB Price: $90.0 / 100.0

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Bromobenzylbromide

Cas:589-15-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Huaian Yishu techonology Co.,Ltd

Product Name P-Bromobenzyl Bromide CAS No 589-15-1 Formula C7H6Br2 Structural Formula

P-Bromobenzyl Bromide

Cas:589-15-1

Min.Order:500 Kilogram

Negotiable

Type:Manufacturers

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

P-BROMO BENZYL BROMIDEAppearance:Colorless transparent liquid Storage:Keep away of light, cool place Package:according to customers' requirements Application:pharmaceutical intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by

P-BROMO BENZYL BROMIDE

Cas:589-15-1

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermed

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

4-Bromobenzyl bromide

Cas:589-15-1

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: P-Bromobenzyl Bromide CAS No.: 589-15-1 Molecule Formula:C7H6Br2 Molecule Weight:249.93 Purity: 99.0% Package: 25kg/drum Description:White to yellowish crystalline powder Manufacture Standards:Enterprise Standard TE

Lower Price P-Bromobenzyl Bromide on stock

Cas:589-15-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

4-(methylthio)benzyl alcohol
3446-90-0

4-(methylthio)benzyl alcohol

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
Stage #1: 4-(methylthio)benzyl alcohol With triphenylphosphine dibromide 1:1 addition complex In acetonitrile at 0℃; for 0.166667h; Bromination;
Stage #2: With aluminum oxide; Oxone In chloroform for 2h; Hydrolysis; Heating;
100%
4-bromobenzenemethanol
873-75-6

4-bromobenzenemethanol

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With bromine; triphenylphosphine In dichloromethane at -78 - 20℃; for 18h; Inert atmosphere;99%
With 1,1,1,2,2,2-hexamethyldisilane In chloroform for 2h; Reflux;98%
With phosphorus tribromide In chloroform at 0 - 20℃; for 1h;94%
1,1-dimethoxy-1-(4-bromophenyl)methane
24856-58-4

1,1-dimethoxy-1-(4-bromophenyl)methane

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With triethylsilane; Acetyl bromide; tin(II) bromide In dichloromethane for 7h; Ambient temperature;97%
1-Chloro-4-(chloromethyl)benzene
104-83-6

1-Chloro-4-(chloromethyl)benzene

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With hydrogen bromide; ferric(III) bromide In dichloromethane at 25℃; for 0.2h;96%
para-bromotoluene
106-38-7

para-bromotoluene

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide In tetrachloromethane Heating;95.8%
With N-Bromosuccinimide; dibenzoyl peroxide In Diethyl carbonate for 0.333333h; Reflux; Microwave irradiation;95%
With bromine at 40℃; for 4h; Inert atmosphere; Irradiation;95%
para-bromotoluene
106-38-7

para-bromotoluene

A

4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

B

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper(ll) bromide In acetic anhydrideA 3%
B 95%
4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With isopinocampheyl-boron dibromide dimethylsulfide complex In hexane at 20℃; for 3h; Reduction; bromination;87%
Multi-step reaction with 2 steps
1: sodium tetrahydroborate / methanol / 1 h / 0 - 20 °C
2: acetic acid; hydrogen bromide / 0.5 h / 0 °C
View Scheme
Multi-step reaction with 2 steps
1: sodium tetrahydroborate / methanol / 1 h / 0 - 20 °C
2: hydrogen bromide / acetic acid / 0.5 h / 0 °C
View Scheme
4-bromo-1-[(ethoxymethoxy)methyl]benzene
216443-67-3

4-bromo-1-[(ethoxymethoxy)methyl]benzene

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With phosphotungstic acid; tetrabutylammomium bromide at 130 - 142℃; for 0.0416667h; Microwave irradiation; Ionic liquid; chemoselective reaction;87%
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.0833333h; Microwave irradiation; Neat (no solvent); chemoselective reaction;81%
1-bromo-4-[(methoxymethyloxy)methyl]benzene
130534-91-7

1-bromo-4-[(methoxymethyloxy)methyl]benzene

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.0833333h; Microwave irradiation; Neat (no solvent); chemoselective reaction;80%
ethylbenzene
100-41-4

ethylbenzene

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane at 80℃; for 4h; Wohl-Ziegler reaction;77%
2-(4-bromophenyl)-acetic acid
1878-68-8

2-(4-bromophenyl)-acetic acid

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene; potassium bromide at 25℃; Irradiation;76%
p-Toluic acid
99-94-5

p-Toluic acid

A

3-bromo-4-methylbenzoic acid
7697-26-9

3-bromo-4-methylbenzoic acid

B

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With Oxone; sodium carbonate; sodium bromide In methanol; water at 20℃; for 24h;A 71%
B 8%
4-bromobenzenemethanol
873-75-6

4-bromobenzenemethanol

A

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

B

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; water In 1,4-dioxane at 70℃; for 1h;A n/a
B 13%
bromobenzene
108-86-1

bromobenzene

bis(bromomethyl) ether
4497-29-4

bis(bromomethyl) ether

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With zinc(II) chloride
bromocyane
506-68-3

bromocyane

(4-bromo-benzyl)-(3-chloro-benzyl)-methyl-amine
876476-05-0

(4-bromo-benzyl)-(3-chloro-benzyl)-methyl-amine

A

(3-chloro-benzyl)-methyl-carbamonitrile
59709-66-9

(3-chloro-benzyl)-methyl-carbamonitrile

B

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

para-bromotoluene
106-38-7

para-bromotoluene

2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With bromine
benzyl chloride
100-44-7

benzyl chloride

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
With beryllium; diethyl ether; bromine
benzyl bromide
100-39-0

benzyl bromide

A

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

B

1-Bromo-2-bromomethyl-benzene
3433-80-5

1-Bromo-2-bromomethyl-benzene

Conditions
ConditionsYield
With bromine; Aliquat 336 at 65℃; for 1h; Product distribution; other α-substituted alkylbenzenes; other catalysts and reaction conditions;
With bromine; Aliquat 336 at 65℃; for 1h; Yield given. Yields of byproduct given;
para-bromotoluene
106-38-7

para-bromotoluene

A

para-chlorotoluene
106-43-4

para-chlorotoluene

B

1-Chloro-4-(chloromethyl)benzene
104-83-6

1-Chloro-4-(chloromethyl)benzene

C

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

D

p-bromobenzyl chloride
589-17-3

p-bromobenzyl chloride

Conditions
ConditionsYield
With sodium chlorite; trichloroacetic acid In dichloromethane for 3h; Bromination; chlorination; substitution; Further byproducts given;A 20 % Chromat.
B 18 % Chromat.
C 20 % Chromat.
D 25 % Chromat.
diethyl ether
60-29-7

diethyl ether

bromine
7726-95-6

bromine

benzyl chloride
100-44-7

benzyl chloride

beryllium

beryllium

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

para-bromotoluene
106-38-7

para-bromotoluene

A

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

B

p-bromo-benzyl chloride

p-bromo-benzyl chloride

Conditions
ConditionsYield
beim Chlorieren;
beim Chlorieren;
benzyl chloride
100-44-7

benzyl chloride

A

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

B

p-bromo-benzyl chloride

p-bromo-benzyl chloride

Conditions
ConditionsYield
With iodine beim Bromieren;
bromine
7726-95-6

bromine

iodine
7553-56-2

iodine

benzyl chloride
100-44-7

benzyl chloride

A

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

B

p-bromo-benzyl chloride

p-bromo-benzyl chloride

para-bromotoluene
106-38-7

para-bromotoluene

bromine
7726-95-6

bromine

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Conditions
ConditionsYield
Sonnenlicht;
Quecksilberdampflicht;
bei Siedetemperatur;
sulfuryl dichloride
7791-25-5

sulfuryl dichloride

para-bromotoluene
106-38-7

para-bromotoluene

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

A

para-chlorotoluene
106-43-4

para-chlorotoluene

B

1-Chloro-4-(chloromethyl)benzene
104-83-6

1-Chloro-4-(chloromethyl)benzene

C

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

D

p-bromobenzyl chloride
589-17-3

p-bromobenzyl chloride

Conditions
ConditionsYield
at 110℃;
para-bromotoluene
106-38-7

para-bromotoluene

chlorine
7782-50-5

chlorine

A

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

B

p-bromo-benzyl chloride

p-bromo-benzyl chloride

Conditions
ConditionsYield
in direktem Sonnenlicht;
Benzyl acetate
140-11-4

Benzyl acetate

bromine
7726-95-6

bromine

A

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

B

o-bromo-benzyl bromide

o-bromo-benzyl bromide

toluene
108-88-3

toluene

I2, Al2O3

I2, Al2O3

A

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

B

4-bromo-2.2.3.3-tetramethyl-bicyclo-<0.1.2>-pentanol-(1)-one-(5)

4-bromo-2.2.3.3-tetramethyl-bicyclo-<0.1.2>-pentanol-(1)-one-(5)

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium bromide; aq. HBr / H2O; CHCl3 / 0 - 2 °C / Electrolysis
2: 89 percent / sodium bromide; aq. HBr / H2O; CHCl3 / 0 - 2 °C / Electrolysis
View Scheme
toluene
108-88-3

toluene

mercury

mercury

A

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

B

(C6H5)2C=N-CH2-COO-Wang-resin

(C6H5)2C=N-CH2-COO-Wang-resin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NaBrO3; NaHSO3 / acetonitrile; H2O / 4 h / 20 °C
2: 76 percent / NaBrO3; NaHSO3 / ethyl acetate; H2O / 4 h / 20 °C
View Scheme
pyridine
110-86-1

pyridine

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

1-(4'-bromobenzyl)pyridinium bromide
125713-97-5

1-(4'-bromobenzyl)pyridinium bromide

Conditions
ConditionsYield
In acetonitrile at 20℃; for 24h;100%
In nitrobenzene at 40℃; Rate constant; Mechanism;
potassium phtalimide
1074-82-4

potassium phtalimide

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

2-(4-bromobenzyl)-1H-isoindole-1,3(2H)-dione
153171-22-3

2-(4-bromobenzyl)-1H-isoindole-1,3(2H)-dione

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 100℃; for 6h;100%
In N,N-dimethyl-formamide at 120℃; for 15h; Inert atmosphere;82%
at 200℃;
1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

4,4'-dibromobibenzyl
19829-56-2

4,4'-dibromobibenzyl

Conditions
ConditionsYield
With Wilkinson's catalyst; dimethyl zinc(II) In tetrahydrofuran; hexane at 20℃; for 1h;100%
With copper nickel; pyrographite In 1,2-dimethoxyethane at 85℃; for 20h;90%
With N,N,N,N,N,N-hexamethylphosphoric triamide; samarium; nickel dichloride In tetrahydrofuran for 8h; Inert atmosphere; Reflux; chemoselective reaction;90%
1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

(4-bomophenyl)(methyl)sulfide
20883-11-8

(4-bomophenyl)(methyl)sulfide

Conditions
ConditionsYield
With dithiooxamide; sodium hydroxide In water at 30 - 35℃; for 0.5h; Green chemistry;100%
With sodium sulfide
With sodium sulfide; ethanol
1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

triphenylphosphine
603-35-0

triphenylphosphine

4-bromobenzyl triphenylphosphonium bromide
51044-13-4

4-bromobenzyl triphenylphosphonium bromide

Conditions
ConditionsYield
In chloroform for 4h; Heating / reflux;100%
In acetonitrile for 4.5h; Reflux;100%
In acetone at 20℃; for 12h;99%
methyl 2,3-di-O-p-tolylsulfonyl-α-D-glucopyranoside
66605-19-4

methyl 2,3-di-O-p-tolylsulfonyl-α-D-glucopyranoside

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

methyl 4,6-di-O-p-bromobenzyl-2,3-di-O-p-tolylsulfonyl-α-D-glucopyranoside
146195-48-4

methyl 4,6-di-O-p-bromobenzyl-2,3-di-O-p-tolylsulfonyl-α-D-glucopyranoside

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate In dichloromethane for 72h; Heating;100%
1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

p-bromobenzylazide
107047-10-9

p-bromobenzylazide

Conditions
ConditionsYield
With sodium azide In N,N-dimethyl-formamide at 80℃;100%
With sodium azide In dimethyl sulfoxide100%
With sodium azide In dimethyl sulfoxide at 20℃;100%
1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

sodium 4-bromobenzylsulfanesulfonate

sodium 4-bromobenzylsulfanesulfonate

Conditions
ConditionsYield
With sodium thiosulfate In water; toluene100%
With Sodium thiosulfate pentahydrate In methanol; water for 24h; Reflux;100%
With Sodium thiosulfate pentahydrate In methanol; water at 65℃; for 1h; Green chemistry;93%
1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

triethyl phosphite
122-52-1

triethyl phosphite

diethyl (4-bromobenzyl)phosphonate
38186-51-5

diethyl (4-bromobenzyl)phosphonate

Conditions
ConditionsYield
at 100℃; for 24h;100%
for 1h; Reflux;100%
at 130℃; for 18h; Arbuzov reaction;99%
(S)-(+)-(2,2-dimethyl-[1,3]dioxolan-4-yl)methanol
22323-82-6

(S)-(+)-(2,2-dimethyl-[1,3]dioxolan-4-yl)methanol

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

(S)-4-(4-bromobenzyloxymethyl)-2,2-dimethyl-1,3-dioxolane
201275-55-0

(S)-4-(4-bromobenzyloxymethyl)-2,2-dimethyl-1,3-dioxolane

Conditions
ConditionsYield
With potassium hydroxide In toluene for 16h; Heating;100%
With potassium hydroxide In toluene for 20h; Reflux;93%
With sodium hydride In tetrahydrofuran
Stage #1: (S)-(+)-(2,2-dimethyl-[1,3]dioxolan-4-yl)methanol With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 1-bromomethyl-4-bromobenzene With tetra-(n-butyl)ammonium iodide In tetrahydrofuran; mineral oil at 0 - 20℃; for 2h; Inert atmosphere;
(S,S)-4-methyl-5-oxo-2-phenyl-oxazolidine-3-carboxylic acid benzyl ester
171860-41-6

(S,S)-4-methyl-5-oxo-2-phenyl-oxazolidine-3-carboxylic acid benzyl ester

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

(R,S)-4-(4-bromobenzyl)-4-methyl-5-oxo-2-phenyl-oxazolidine-3-carboxylic acid benzyl ester
330795-80-7

(R,S)-4-(4-bromobenzyl)-4-methyl-5-oxo-2-phenyl-oxazolidine-3-carboxylic acid benzyl ester

Conditions
ConditionsYield
With potassium hexamethylsilazane In tetrahydrofuran; toluene at -30 - 20℃;100%
1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

(2S,4S)-2-(biphenyl-4-yl)-4-methyl-5-oxo-oxazolidine-3-carboxylic acid isobutyl ester
346577-99-9

(2S,4S)-2-(biphenyl-4-yl)-4-methyl-5-oxo-oxazolidine-3-carboxylic acid isobutyl ester

(2S,4R)-2-Biphenyl-4-yl-4-(4-bromo-benzyl)-4-methyl-5-oxo-oxazolidine-3-carboxylic acid isobutyl ester
346578-01-6

(2S,4R)-2-Biphenyl-4-yl-4-(4-bromo-benzyl)-4-methyl-5-oxo-oxazolidine-3-carboxylic acid isobutyl ester

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran; hexane at -27℃;100%
With lithium hexamethyldisilazane In tetrahydrofuran at -25 - 20℃; for 3.5h;
1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

phenyl 4,6-O-benzylidene-1-thio-α-D-mannopyranoside
159407-19-9

phenyl 4,6-O-benzylidene-1-thio-α-D-mannopyranoside

S-phenyl 2,3-di-O-p-bromobenzyl-4,6-O-benzylidene-1-thia-α-D-mannopyranoside
407616-83-5

S-phenyl 2,3-di-O-p-bromobenzyl-4,6-O-benzylidene-1-thia-α-D-mannopyranoside

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 20℃; for 3h;100%
1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

methyl (2S,3S)-3,4-O-isopropylidene-2,3,4-trihydroxybutyrate
186754-07-4

methyl (2S,3S)-3,4-O-isopropylidene-2,3,4-trihydroxybutyrate

methyl (2S,3S)-2-(4-bromobenzyloxy)-3,4-dihydroxy-3,4-O-isopropylidene-butyrate
552887-05-5

methyl (2S,3S)-2-(4-bromobenzyloxy)-3,4-dihydroxy-3,4-O-isopropylidene-butyrate

Conditions
ConditionsYield
With potassium iodide; silver(l) oxide In toluene at 20℃; for 0.25h;100%
3-deoxy-1,2-O-isopropylidene-D-glucose
4005-46-3, 4494-96-6, 22248-87-9, 142941-40-0

3-deoxy-1,2-O-isopropylidene-D-glucose

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

6-(4-bromobenzyloxy)-3-deoxy-1,2-O-isopropylidene-D-glucose
724733-47-5

6-(4-bromobenzyloxy)-3-deoxy-1,2-O-isopropylidene-D-glucose

Conditions
ConditionsYield
Stage #1: 3-deoxy-1,2-O-isopropylidene-D-glucose With di(n-butyl)tin oxide In toluene for 5h; Heating;
Stage #2: 1-bromomethyl-4-bromobenzene With tetrabutylammomium bromide In toluene at 90℃;
100%
Stage #1: 3-deoxy-1,2-O-isopropylidene-D-glucose With di(n-butyl)tin oxide In toluene for 5h; Heating / reflux;
Stage #2: 1-bromomethyl-4-bromobenzene With tetrabutylammomium bromide In toluene at 90℃;
87%
Stage #1: 3-deoxy-1,2-O-isopropylidene-D-glucose With di(n-butyl)tin oxide In toluene for 5h; Reflux;
Stage #2: 1-bromomethyl-4-bromobenzene With tetrabutylammomium bromide In toluene at 90℃;
87%
propylamine
107-10-8

propylamine

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

N-(4-bromophenylmethyl)-N-propylamine
150869-52-6

N-(4-bromophenylmethyl)-N-propylamine

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 4h;100%
(2'R,3'S,5'R,7'S,8'R)-2'-(tret-butyldimethylsilyloxymethyl)-7'-hydroxy-8'-hydroxymethyl-5'-methyl-oxocan-3'-yl 2,2-dimethylpropionate
876288-70-9

(2'R,3'S,5'R,7'S,8'R)-2'-(tret-butyldimethylsilyloxymethyl)-7'-hydroxy-8'-hydroxymethyl-5'-methyl-oxocan-3'-yl 2,2-dimethylpropionate

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

(2'R,3'S,5'R,7'S,8'R)-7'-(4-bromobenzyloxy)-8'-(4-bromobenzyloxymethyl)-2'-(tret-butyldimethylsilyloxymethyl)-5'-methyl-oxocan-3'-yl 2,2-dimethylpropionate
876288-71-0

(2'R,3'S,5'R,7'S,8'R)-7'-(4-bromobenzyloxy)-8'-(4-bromobenzyloxymethyl)-2'-(tret-butyldimethylsilyloxymethyl)-5'-methyl-oxocan-3'-yl 2,2-dimethylpropionate

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; sodium hydride In tetrahydrofuran at 25℃; for 14h;100%
With tetra-(n-butyl)ammonium iodide; sodium hydride In tetrahydrofuran at 0 - 25℃; for 16h;100%
2-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethanol
32233-43-5

2-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethanol

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

(S)-4-[2-(4-bromobenzyloxy)ethyl]-2,2-dimethyl-1,3-dioxolane

(S)-4-[2-(4-bromobenzyloxy)ethyl]-2,2-dimethyl-1,3-dioxolane

Conditions
ConditionsYield
With potassium hydroxide In toluene for 16h; Heating;100%
2-(methylamino)-1-phenylethanol
68579-60-2

2-(methylamino)-1-phenylethanol

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

α-[[[(4-bromophenyl)methyl]methylamino]methyl]benzenemethanol
415954-71-1

α-[[[(4-bromophenyl)methyl]methylamino]methyl]benzenemethanol

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 20℃;100%
Polyglycol A 500, poly(ethylene glycol) mono-allyl ether MW = 500 g/mol

Polyglycol A 500, poly(ethylene glycol) mono-allyl ether MW = 500 g/mol

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

poly(ethylene glycol) [α-mono-allyl-ω-(4-bromophenyl)] ether, poly(ethylene glycol) mono-allyl ether MW = 500 g/mol

poly(ethylene glycol) [α-mono-allyl-ω-(4-bromophenyl)] ether, poly(ethylene glycol) mono-allyl ether MW = 500 g/mol

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran at 75℃; for 20h;100%
Polyglycol A 1100, poly(ethylene glycol) mono-allyl ether MW = 1100 g/mol

Polyglycol A 1100, poly(ethylene glycol) mono-allyl ether MW = 1100 g/mol

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

poly(ethylene glycol) [α-mono-allyl-ω-(4-bromophenyl)] ether, poly(ethylene glycol) mono-allyl ether MW = 1100 g/mol

poly(ethylene glycol) [α-mono-allyl-ω-(4-bromophenyl)] ether, poly(ethylene glycol) mono-allyl ether MW = 1100 g/mol

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran at 75℃; for 20h;100%
(2-hydroxyethyl)(methyl)amine
109-83-1

(2-hydroxyethyl)(methyl)amine

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

2-[(4-bromo-benzyl)-methyl-amino]-ethanol
918642-06-5

2-[(4-bromo-benzyl)-methyl-amino]-ethanol

Conditions
ConditionsYield
In 1,2-dimethoxyethane at 40℃; for 1h;100%
With potassium carbonate In acetonitrile at 20℃; for 2h;
ethyl 1-(6-(2-hydroxyphenyl)pyridin-2-yl)-5-(trifluoromethyl)-1H-pyrazole-4-carboxylate
1128268-02-9

ethyl 1-(6-(2-hydroxyphenyl)pyridin-2-yl)-5-(trifluoromethyl)-1H-pyrazole-4-carboxylate

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

Ethyl 1-(6-{2-[(4-bromobenzyl)oxy]phenyl}pyridin-2-yl)-5-(trifluoromethyl)-1H-pyrazole-4-carboxylate
1128268-07-4

Ethyl 1-(6-{2-[(4-bromobenzyl)oxy]phenyl}pyridin-2-yl)-5-(trifluoromethyl)-1H-pyrazole-4-carboxylate

Conditions
ConditionsYield
Stage #1: ethyl 1-[6-(2-hydroxylphenyl)pyridine-2-yl]-5-trifluoromethyl-1H-pyrazole-4-carboxylate With caesium carbonate In acetone at 20℃; for 0.166667h;
Stage #2: 1-bromomethyl-4-bromobenzene In acetone for 2h; Heating / reflux;
100%
With caesium carbonate In N,N-dimethyl-formamide for 1.5h;
2-[(3'R,5'S)-5'-(tert-butyldimethylsilanyloxy)-3'-fluoro-2',6'-dioxopiperidin-3'-yl]isoindole-1,3-dione
1164294-57-8

2-[(3'R,5'S)-5'-(tert-butyldimethylsilanyloxy)-3'-fluoro-2',6'-dioxopiperidin-3'-yl]isoindole-1,3-dione

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

2-[(3'R,5'S)-1'-(4"-bromobenzyl)-3'-fluoro-5'-(isopropyldimethylsilanyloxy)-2',6'-dioxopiperidin-3'-yl]isoindole-1,3-dione
1164294-64-7

2-[(3'R,5'S)-1'-(4"-bromobenzyl)-3'-fluoro-5'-(isopropyldimethylsilanyloxy)-2',6'-dioxopiperidin-3'-yl]isoindole-1,3-dione

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 0 - 20℃; for 4h;100%
phenylacetylene
536-74-3

phenylacetylene

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

1-(4-bromobenzyl)-4-phenyl-1H-1,2,3-triazole
126800-09-7

1-(4-bromobenzyl)-4-phenyl-1H-1,2,3-triazole

Conditions
ConditionsYield
With sodium azide In water at 55℃; for 4h; Green chemistry; regioselective reaction;100%
With sodium azide; sodium ascorbate In ethanol; water at 20℃; for 0.333333h; Reagent/catalyst; Solvent; Concentration; regioselective reaction;99%
With sodium azide at 50℃; for 48h;99%
2-[1,2,3]triazol-2-yl-malonic acid diethyl ester
817176-69-5

2-[1,2,3]triazol-2-yl-malonic acid diethyl ester

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

2-(4-bromo-benzyl)-2-[1,2,3]triazol-2-yl-malonic acid diethyl ester

2-(4-bromo-benzyl)-2-[1,2,3]triazol-2-yl-malonic acid diethyl ester

Conditions
ConditionsYield
Stage #1: 2-[1,2,3]triazol-2-yl-malonic acid diethyl ester With potassium carbonate In N,N-dimethyl-formamide for 0.333333h;
Stage #2: 1-bromomethyl-4-bromobenzene With tetrabutylammomium bromide In 1,2-dimethoxyethane at 20℃; for 20h;
100%
Thiomorpholin
123-90-0

Thiomorpholin

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

4-(4-bromobenzyl)thiomorpholine
17494-28-9

4-(4-bromobenzyl)thiomorpholine

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 20℃; for 16h;100%
In acetonitrile for 1h; Reflux;92%
2-aza-bicyclo[2.2.1]heptane
279-24-3

2-aza-bicyclo[2.2.1]heptane

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

2-(4-bromobenzyl)-2-azabicyclo[2.2.1]heptane
1200131-54-9

2-(4-bromobenzyl)-2-azabicyclo[2.2.1]heptane

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran for 5h; Reflux;100%
1-Methyl-9H-carbazol-3-carbonsaeure-ethylester
118042-94-7

1-Methyl-9H-carbazol-3-carbonsaeure-ethylester

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

ethyl 9-(4-bromobenzyl)-1-methyl-9H-carbazole-3-carboxylate
953797-82-5

ethyl 9-(4-bromobenzyl)-1-methyl-9H-carbazole-3-carboxylate

Conditions
ConditionsYield
Stage #1: 1-Methyl-9H-carbazol-3-carbonsaeure-ethylester With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 0.5h;
Stage #2: 1-bromomethyl-4-bromobenzene In N,N-dimethyl-formamide at 0 - 20℃; for 0.5h;
100%
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