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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

p-Toluic acid Manufacturer/High quality/Best price/In stock

Cas:99-94-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality P-Toluic Acid supplier in China

Cas:99-94-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hangzhou Johoo Chemical Co., Ltd

High quality products. Always supply highest grade to you. Purity:≥99% Reasonable & Competitive Price. Huge capacity determines the lowest shared cost. The more you buy the more competitive prices you will get. The sincerest and most pro

Professional supplier of p-Toluic acid in china

Cas:99-94-5

Min.Order:1 Metric Ton

FOB Price: $5.5 / 6.5

Type:Trading Company

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Jinan Finer Chemical Co., Ltd

Product Description: Product Name p-Toluic acid CAS No. 99-94-5 Appearance White powder Assay ≥99% Capacity 3000mt/year Min.packing 100gram Appl

p-Toluic acid

Cas:99-94-5

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply p-toluic acid

Cas:99-94-5

Min.Order:1

Negotiable

Type:Other

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Taixing Hehao Chemical Materials Co.,Ltd

Product description: product name p-toluic acid cas no. 99-94-5 appearance white powder assay ≥99% capacity 3000mt/year min.packing 100gram application ph

p-Toluic acid

Cas:99-94-5

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% -----------------------------------------------------------------------------------------------------------

High purity 99-94-5 p-toluic acid

Cas:99-94-5

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

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Wuhan Fortuna Chemical Co.,Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; ...... Appearance:White crystalline powder Storage:Store at RT. Package:25kg/ba

High purity p-Toluic acid CAS 99-94-5 with low price

Cas:99-94-5

Min.Order:1 Metric Ton

FOB Price: $3200.0 / 4000.0

Type:Trading Company

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Hefei TNJ chemical industry co.,ltd

1.5-Methylanthranilic acid 2.2941-78-8 3.assay no less than 98.5% 4.Competitive price 5. Usually have it in stock Appearance:white powder Storage:Warehouse ventilation, away from open flame, high temperature, and antioxidant Package:25kg/ba

p-Toluic acid

Cas:99-94-5

Min.Order:3 Metric Ton

Negotiable

Type:Trading Company

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EAST CHEMSOURCES LIMITED

p-Toluic acid Molecular Formula:: C8H8O2 Molecular Weight:: 136.15 Structural formula: EINECS NO: 204-284-9 Boiling Point: 274~275°C

p-Toluic acid

Cas:99-94-5

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

p-Toluic acid

Cas:99-94-5

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

4-Methylbenzoic acid

Cas:99-94-5

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

ANQING CHICO PHARMACEUTICAL CO.,LTD.

High quality. Factory supply. In stock. Best price.1.Quick response within 24 hours;2.Best quality in your requirement;?3.We pay more attention on delivery time, and usually ship on time;4.Under the premise of safety and effectiveness, we can produce

p-Toluic acid

Cas:99-94-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

p-Toluic acid

Cas:99-94-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: p-Toluic acid Synonyms: p-Tolylcarboxylic acid;4-Toluic acid ,99%;4-Carboxytoluene, p-Toluic acid;p-Toluic acid, 98% 100GR;p-carboxytoluene;p-toluic;p-Toluic acid ,99%;p-Toluic acid,4-Methylbenzoic acid CAS: 99-94-5 MF: C8H8O2 MW:

99-94-5 p-Toluic acid

Cas:99-94-5

Min.Order:1 Kilogram

FOB Price: $500.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

p-Toluic acid In stock

Cas:99-94-5

Min.Order:1 Gram

FOB Price: $1000.0 / 1300.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 99-94-5 with best price

Cas:99-94-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

English Name: p-Toluic acid CAS: 99-94-5 Molecular formula: C8H8O2 Molecular weight: 1

p-Toluic acid

Cas:99-94-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:colourless crystals or white crystalline powder Storage:Stor

Pharmaceutical Raw Materials CAS 99-94-5 4-Methylbenzoic acid

Cas:99-94-5

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

p-Toluic acid 99-94-5

Cas:99-94-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: p-Toluic acid CAS: 99-94-5 MF: C8H8O2 MW: 136.15 EINECS: 202-803-3 Mol File: 99-94-5.mol p-Toluic acid Structure p-Toluic acid Chemical Properties Melting point 177-180 °C (lit.) Boiling point 274-275 &de

p-Toluic acid

Cas:99-94-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

p-Toluic acid Aromatic acid

Cas:99-94-5

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

p-Toluic acid CAS:99-94-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates

p-Toluic acid CAS:99-94-5

Cas:99-94-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

p-Toluic acid

Cas:99-94-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Superiority We can customize and synthesize products that other suppliers may not be able to provide. Advantage cof, mof ligand manufacturer Product Detail

95%-99.999% p-Toluic acid 4-Methylbenzoic acid 95+%;, CAS 99-94-5, C8H8O2

Cas:99-94-5

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

inquiry

Wuhan Wonda Pharm Limited

1.high quality: quality is life. quality is the most important element for all goods. we have a lab doing research in wuhan china. hplc and nmr is available if needed. 2.reasonable price: we provide high quality products with competi

supply pharma grade intermediate cas 99-94-5 Para Toluic Acid for API

Cas:99-94-5

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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HUBEI RISON CHEMICAL CO.,LTD.

Located in Wuhan City of Hubei Province, Wuhan Rison Trading co., Ltd is engaged in the supply of fine specialty chemicals. Our business includes metal surface treatment, such as nickel/zinc/copper plating, perfluoro chemicals, tin salts (stannous su

High Quality/P-Toluic acid

Cas:99-94-5

Min.Order:3000 Kilogram

FOB Price: $10.0 / 100.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:99-94-5

Cas:99-94-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in lead acetate, diphenyl ethylamine and other chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countrie

plenty of p-Toluylic acid on stock p-Toluylic acid

Cas:99-94-5

Min.Order:1 Kilogram

FOB Price: $25.0

Type:Trading Company

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

4-Methylbenzoic acid

Cas:99-94-5

Min.Order:1 Kilogram

FOB Price: $30.0 / 50.0

Type:Lab/Research institutions

inquiry

Synthetic route

4-Methylbenzyl alcohol
589-18-4

4-Methylbenzyl alcohol

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With oxygen; potassium hydroxide In methanol; water at 50℃; under 760.051 Torr; for 4h;100%
With oxygen; potassium hydroxide In toluene at 100℃; under 760.051 Torr; for 12h;99%
With periodic acid; pyridinium chlorochromate In acetonitrile98%
4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With phosphate-buffered silica gel supported KMnO4 In cyclohexane at 65℃;100%
With periodic acid; tripropylammonium fluorochromate (VI) In acetonitrile at 0℃; for 1.5h;100%
With [Cu2C6H4(CHNCH2CH2N(CH2C5H4N)2)2](2+)*2ClO4(1-)=C36H38Cu2N8(ClO4)2; oxygen In acetone at -90.16℃;100%
methanol
67-56-1

methanol

1-pyrenylmethyl p-toluate
111077-41-9

1-pyrenylmethyl p-toluate

A

methyl 1-pyrenylmethyl ether
91385-15-8

methyl 1-pyrenylmethyl ether

B

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
for 0.5h; Irradiation;A 95%
B 100%
for 0.5h; Product distribution; Irradiation; recovery of carboxylic acids from their 1-pyrenylmethyl esters;A 95%
B 100%
for 2h; Quantum yield; Irradiation;A n/a
B 80%
carbon monoxide
201230-82-2

carbon monoxide

4-tolyl iodide
624-31-7

4-tolyl iodide

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With potassium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 25℃; under 760 Torr; for 4h;100%
With potassium hydroxide; amphiphilic resin-supported phosphine-palladium; water at 25℃; under 760 Torr; for 12h; Product distribution; Further Variations:; Reagents; hydroxycarbonylation;100%
With dichloro bis(acetonitrile) palladium(II); sodium dodecyl-sulfate; potassium carbonate In water; toluene; butan-1-ol at 50℃; under 760 Torr; for 4h;92%
4-methyl-benzoic acid 4-nitro-benzyloxymethyl ester

4-methyl-benzoic acid 4-nitro-benzyloxymethyl ester

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran Product distribution;100%
p-methylbenzyltri-n-butyl-stannane
74260-32-5

p-methylbenzyltri-n-butyl-stannane

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With C2H2Cl2F3O2V; oxygen In tert-butyl alcohol at 50℃; for 36h;100%
Conditions
ConditionsYield
With poly(diselanediyl-1,2-phenylene); dihydrogen peroxide In tetrahydrofuran for 42h; Heating;100%
With [hydroxy(tosyloxy)iodo]benzene; water In dimethyl sulfoxide at 20℃; for 24h;82%
4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In 1,4-dioxane for 2h; Heating;100%
N,4-dimethyl-N-tosylbenzamide

N,4-dimethyl-N-tosylbenzamide

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With sodium hydroxide In water at 85℃; for 12h;100%
para-xylene
106-42-3

para-xylene

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; water at 20℃; for 10h; Inert atmosphere;99%
With N-hydroxy-tetrahydrophthalimide; oxygen; nitric acid at 50℃; under 750.075 - 1500.15 Torr; for 25h; Autoclave; Green chemistry;91.16%
With MoO(O2)(8-quinolinolate)2; dihydrogen peroxide In acetonitrile for 6h; Oxidation; Heating;88%
para-methylacetophenone
122-00-9

para-methylacetophenone

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With oxygen; copper(II) nitrate In acetonitrile at 120℃; under 4500.45 Torr; for 10h;99%
With copper(II) nitrate trihydrate; oxygen In acetonitrile at 120℃; under 4500.45 Torr; for 10h; Autoclave;97%
With sodium hydroxide; sodium bromite; sodium bromide In water for 6h; Ambient temperature;96%
4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With hydrogen In ethanol at 100℃; under 2250.23 Torr; for 3h; Catalytic behavior; Inert atmosphere;99%
With W-7 Raney-Nickel In ethanol for 5h; Heating;89%
4,4'-dimethylbenzaldazine
4702-76-5, 139030-29-8

4,4'-dimethylbenzaldazine

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With poly(diselanediyl-1,2-phenylene); dihydrogen peroxide In tetrahydrofuran for 60h; Heating;99%
With [bis(acetoxy)iodo]benzene In tetrahydrofuran at 20℃; for 4h; Green chemistry;72%
carbon dioxide
124-38-9

carbon dioxide

5,5-dimethyl-2-(4-methylphenyl)-1,3,2-dioxaborinane
380481-66-3

5,5-dimethyl-2-(4-methylphenyl)-1,3,2-dioxaborinane

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
Stage #1: carbon dioxide; 5,5-dimethyl-2-(4-methylphenyl)-1,3,2-dioxaborinane With [Ni(N,N'-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]imidazole-2-ylidene)(allyl)Cl]; potassium tert-butylate In toluene at 100℃; under 760.051 Torr; for 15h; Schlenk technique; Inert atmosphere;
Stage #2: With hydrogenchloride In water; ethyl acetate; toluene at 20℃;
99%
Stage #1: carbon dioxide; 5,5-dimethyl-2-(4-methylphenyl)-1,3,2-dioxaborinane With potassium tert-butylate; silver(I) acetate; triphenylphosphine In tetrahydrofuran at 70℃; under 15201 Torr; for 16h; Inert atmosphere; Autoclave;
Stage #2: With hydrogenchloride In tetrahydrofuran; water Inert atmosphere;
83%
p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With oxygen; sodium methylate; silver trifluoromethanesulfonate In tetrahydrofuran; methanol at 37℃; under 760.051 Torr; for 12h; Sealed tube;99%
Stage #1: 1,2-di-p-tolylethane-1,2-diol With 2,3,4,5,6-pentamethyliodobenzene; oxygen; isobutyraldehyde In 1,2-dichloro-ethane under 760.051 Torr; for 24h;
Stage #2: With sodium chlorite; 2-methyl-but-2-ene In aq. phosphate buffer; 1,2-dichloro-ethane; tert-butyl alcohol at 25℃; for 14h;
80%
With oxygen In dichloromethane at 20℃; under 760.051 Torr; for 12h; Irradiation;78%
Stage #1: 1,2-di-p-tolylethane-1,2-diol With oxygen; sodium t-butanolate In tetrahydrofuran at 20℃; under 760.051 Torr; for 5h;
Stage #2: With hydrogenchloride In tetrahydrofuran; water pH=1; chemoselective reaction;
60%
para-xylene
106-42-3

para-xylene

A

terephthalic acid
100-21-0

terephthalic acid

B

4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

C

4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

D

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With hydrogen bromide; oxygen; acetic acid; cobalt(II) acetate; manganese(II) acetate In water at 190℃; under 16501.7 Torr; for 1h; Product distribution / selectivity;A 98.1%
B 0.2%
C 0.4%
D 0.4%
With oxygen; acetic acid; palladium diacetate; antimony(III) acetate In water at 182 - 195℃; under 16501.7 - 20929.4 Torr; for 1 - 1.5h; Product distribution / selectivity;A 50.3%
B 7.2%
C 6.4%
D 6.2%
With hydrogen bromide; oxygen; acetic acid; zirconium oxyacetate; cobalt(II) acetate In water at 190℃; under 16501.7 Torr; for 1h; Product distribution / selectivity;A 4.9%
B 3%
C 1.9%
D 36.9%
formic acid
64-18-6

formic acid

4-tolyl iodide
624-31-7

4-tolyl iodide

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With palladium diacetate; triethylamine; dicyclohexyl-carbodiimide; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 80℃; for 10h; Inert atmosphere; Sealed tube;98%
With palladium diacetate; triethylamine; dicyclohexyl-carbodiimide; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 100℃; for 20h; Inert atmosphere; Sealed tube;82%
4-methyl-benzoic acid methyl ester
99-75-2

4-methyl-benzoic acid methyl ester

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With iron(III) sulfate; water In toluene at 110℃; for 1.5h; Ionic liquid;97%
With iodine; aluminium In acetonitrile at 80℃; for 18h;96%
With potassium hydroxide In methanol at 35℃; for 0.5h;90%
carbon monoxide
201230-82-2

carbon monoxide

para-bromotoluene
106-38-7

para-bromotoluene

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With tetrabutylammomium bromide; dicobalt octacarbonyl In sodium hydroxide; benzene at 65℃; for 1h; Irradiation;97%
With sodium hydroxide; tetrabutylammomium bromide; dicobalt octacarbonyl In water; benzene at 65℃; under 760 Torr; for 1.5h; Irradiation;97%
With palladium diacetate; caesium carbonate; 1,2-bis[di(t-butyl)phosphinomethyl]benzene In water; N,N-dimethyl-formamide at 80℃; under 2068.65 Torr; Inert atmosphere;77%
4-Methyl-benzoic acid (E)-3-phenyl-allyl ester

4-Methyl-benzoic acid (E)-3-phenyl-allyl ester

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With Montmorillonite K-10 clay; methoxybenzene for 0.333333h; Dealkylation; Microwave irradiation;97%
With methoxybenzene In toluene for 15h; Heating;10%
4,4'-dimethylbenzoin
1218-89-9

4,4'-dimethylbenzoin

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII); magnesium sulfate In acetonitrile for 3h; Heating;97%
With sodium hypochlorite In acetonitrile at 20℃; for 5h;85%
With diphenyl diselenide; dihydrogen peroxide In water; acetonitrile at 20℃; for 24h;85%
With graphitic carbon nitride; oxygen; acetic acid In water; acetonitrile at 100℃; under 2250.23 Torr; for 16h; Autoclave; Irradiation; Green chemistry;69 %Chromat.
1-(4-methoxyphenyl)-2-(4-methylphenyl)ethanone
57297-25-3

1-(4-methoxyphenyl)-2-(4-methylphenyl)ethanone

A

p-Toluic acid
99-94-5

p-Toluic acid

B

4-methoxybenzoic acid
100-09-4

4-methoxybenzoic acid

Conditions
ConditionsYield
With oxygen; potassium hydroxide at 20℃; Schlenk technique; chemoselective reaction;A 93%
B 97%
1-phenyl-2-p-tolylethanone
2430-99-1

1-phenyl-2-p-tolylethanone

A

p-Toluic acid
99-94-5

p-Toluic acid

B

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With 5% active carbon-supported ruthenium; water; oxygen; calcium oxide at 100℃; for 24h; Overall yield = 56.7 mg;A 80%
B 97%
C8H12O4

C8H12O4

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With hydrogenchloride In water at 95℃; for 7h; Reagent/catalyst;97%
para-xylene
106-42-3

para-xylene

A

terephthalic acid
100-21-0

terephthalic acid

B

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With N-hydroxyphthalimide; oxygen; nitric acid at 110℃; under 760.051 Torr; for 6h; Ionic liquid;A 96%
B 3%
Stage #1: para-xylene With N-hydroxyphthalimide; cobalt(II) phthalocyanine; μ-oxo[manganese(III) tetraphenylporphine]2; oxygen at 120℃; under 3750.38 Torr;
Stage #2: With N-hydroxyphthalimide; cobalt(II) phthalocyanine; μ-oxo[manganese(III) tetraphenylporphine]2; oxygen; acetic acid at 232℃; under 16501.7 Torr; for 1.5h; Temperature; Pressure; Reagent/catalyst;
A 90%
B 9.7%
With chromium(VI) oxide; periodic acid In acetonitrile at 20℃; for 1h;A 6%
B 86%
4-Methylbenzyl chloride
104-82-5

4-Methylbenzyl chloride

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With sodium hydroxide In water; tert-butyl alcohol at 70℃; Ni-anode, 16 mA/cm2;96%
With 4 Angstroem MS; methyl tri-n-octyl ammonium hydrogen sulfate; sodium tungstate at 90℃; for 18h;68%
p-tolualdehyde p-toluenesulfonylhydrazone
40739-81-9

p-tolualdehyde p-toluenesulfonylhydrazone

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With poly(diselanediyl-1,2-phenylene); dihydrogen peroxide In tetrahydrofuran for 18h; Heating;96%
tert-butyl 4-methylbenzoate
13756-42-8

tert-butyl 4-methylbenzoate

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With aluminium(III) iodide In acetonitrile at 80℃; for 18h;96%
With 1,1,3,3-Tetramethyldisiloxane; pyrographite; palladium dichloride In 1,2-dimethoxyethane at 25 - 40℃; for 6h;95%
With toluene-4-sulfonic acid for 0.0666667h; microwave irradiation;93%
With (μ3,η2,η3,η5-acenaphthylene)Ru3(CO)7; Dimethylphenylsilane In 1,2-dimethoxyethane at 40℃; for 7h; Inert atmosphere;93%
With high-silica Hβ-75 zeolite In water at 130℃; for 24h; Reagent/catalyst;88%
methyl 3-(4-methylphenyl)-3-oxopropanedithioate
83392-35-2

methyl 3-(4-methylphenyl)-3-oxopropanedithioate

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With sodium hydroxide In water at 100℃; for 10h; Reflux; chemoselective reaction;96%
N-methoxy-4-methylbenzamide
25563-06-8

N-methoxy-4-methylbenzamide

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With tert.-butylnitrite; water at 29℃; for 0.583333h;96%
methanol
67-56-1

methanol

p-Toluic acid
99-94-5

p-Toluic acid

4-methyl-benzoic acid methyl ester
99-75-2

4-methyl-benzoic acid methyl ester

Conditions
ConditionsYield
With boron trifluoride at 65℃; for 0.333333h;100%
With sulfuric acid for 4h; Reflux;100%
With sulfuric acid Fischer-Speier esterification method; Reflux;100%
p-Toluic acid
99-94-5

p-Toluic acid

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane for 6h; Reflux;100%
With sodium bromate; sodium hydrogensulfite In water; ethyl acetate90%
With dihydrogen peroxide; bromine In dichloromethane; water for 4h; Reflux;87%
p-Toluic acid
99-94-5

p-Toluic acid

4-methyl-3-sulfobenzoic acid
62454-72-2

4-methyl-3-sulfobenzoic acid

Conditions
ConditionsYield
With chlorosulfonic acid at 90℃; for 4h;100%
With sulfuric acid at 160 - 170℃; for 4h;71%
With sulfuric acid at 150 - 160℃;
With sulfuric acid at 150℃;
With sulfur trioxide
p-Toluic acid
99-94-5

p-Toluic acid

4-methyl-benzoyl chloride
874-60-2

4-methyl-benzoyl chloride

Conditions
ConditionsYield
With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 2h; Reflux;100%
With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 35℃; for 1h;100%
Stage #1: p-Toluic acid With N,N-dimethyl-formamide In dichloromethane at 0℃; for 0.0833333h;
Stage #2: With oxalyl dichloride In dichloromethane at 20℃; for 12h;
100%
p-Toluic acid
99-94-5

p-Toluic acid

2,4,6-trimethylaniline
88-05-1

2,4,6-trimethylaniline

N-(2,4,6-trimethylphenyl)-4-methylbenzamide
86489-65-8

N-(2,4,6-trimethylphenyl)-4-methylbenzamide

Conditions
ConditionsYield
With diphosphorus tetraiodide In tetrachloromethane; dichloromethane Heating;100%
2,2'-dimethoxy-1,1'-binaphthyl
75685-01-7

2,2'-dimethoxy-1,1'-binaphthyl

p-Toluic acid
99-94-5

p-Toluic acid

6,6'-bis(4-methylbenzoyl)-2,2'-dimethoxy-1,1'-binaphthyl

6,6'-bis(4-methylbenzoyl)-2,2'-dimethoxy-1,1'-binaphthyl

Conditions
ConditionsYield
With methanesulfonic acid; phosphorus pentoxide at 60℃; for 24h; Friedel-Crafts acylation;100%
p-Toluic acid
99-94-5

p-Toluic acid

(2S)-2-[(1,1-dimethylethoxycarbonyl)amino]-3-[(4-methylbenzoyl)amino]propionic acid benzyl ester
847495-03-8

(2S)-2-[(1,1-dimethylethoxycarbonyl)amino]-3-[(4-methylbenzoyl)amino]propionic acid benzyl ester

Conditions
ConditionsYield
Stage #1: 3-amino-(2S)-[(1,1-dimethylethoxycarbonyl)amino]-propionic acid benzyl ester With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate In DMF (N,N-dimethyl-formamide) at 20℃; for 0.166667h;
Stage #2: p-Toluic acid With 4-methyl-morpholine In DMF (N,N-dimethyl-formamide) at 0 - 20℃; for 3h;
100%
Stage #1: 3-amino-(2S)-[(1,1-dimethylethoxycarbonyl)amino]-propionic acid benzyl ester With N,N,N',N'-tetramethyl-O-(benzotriazol-1-yl)uronium tetrafluoroborate In N,N-dimethyl-formamide at 20℃; for 0.166667h;
Stage #2: p-Toluic acid With 4-methyl-morpholine In N,N-dimethyl-formamide at 0 - 20℃; for 3h;
100%
p-Toluic acid
99-94-5

p-Toluic acid

methyl iodide
74-88-4

methyl iodide

4-methyl-benzoic acid methyl ester
99-75-2

4-methyl-benzoic acid methyl ester

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; Inert atmosphere;100%
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 5h;
With N'',N'''''-1,8-naphthalenediyl bis[N,N,N',N'-tetramethyl]guanidine In N,N-dimethyl-formamide at 20℃; Kinetics;
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 10h; Inert atmosphere; Sealed tube;
n-heptan1ol
111-70-6

n-heptan1ol

p-Toluic acid
99-94-5

p-Toluic acid

1-heptyl 4-methylbenzoate

1-heptyl 4-methylbenzoate

Conditions
ConditionsYield
With Candida antarctica lipase B immobilised in a macroporous DVB crosslinked polymer (Novozym 435) In cyclohexane at 80℃; for 24h; Enzymatic reaction;100%
With 25 wtpercent H3PO4/ZrO2-TiO2 at 130℃; for 1.75h; Neat (no solvent); chemoselective reaction;80%
4-benzylpyperidine
31252-42-3

4-benzylpyperidine

p-Toluic acid
99-94-5

p-Toluic acid

(4-benzylpiperidin-1-yl)(p-tolyl)methanone

(4-benzylpiperidin-1-yl)(p-tolyl)methanone

Conditions
ConditionsYield
Stage #1: p-Toluic acid With N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate at 20℃; for 0.166667h;
Stage #2: 4-benzylpyperidine at 20℃; for 1h;
100%
tetramethyl ammoniumhydroxide
75-59-2

tetramethyl ammoniumhydroxide

p-Toluic acid
99-94-5

p-Toluic acid

tetramethyl-ammonium; 4-methyl-benzoate

tetramethyl-ammonium; 4-methyl-benzoate

Conditions
ConditionsYield
With water In ethanol at 0 - 20℃; for 0.0833333h;100%
p-Toluic acid
99-94-5

p-Toluic acid

terephthalic acid
100-21-0

terephthalic acid

Conditions
ConditionsYield
With ammonium acetate; water; hydrogen bromide; oxygen; manganese(II) acetate; cobalt(II) diacetate tetrahydrate; 1-n-butyl-3-methylimidazolim bromide; acetic acid; 3-butyl-1-methylimidazolium acetate at 215℃; under 30753.1 Torr; for 3h; Inert atmosphere;99.1%
With ammonium acetate; water; hydrogen bromide; oxygen; manganese(II) acetate; cobalt(II) diacetate tetrahydrate; 1-n-butyl-3-methylimidazolim bromide; acetic acid; 3-butyl-1-methylimidazolium acetate at 215℃; under 30753.1 Torr; for 3h; Inert atmosphere;99.1%
With oxovanadium(IV) sulfate; hydrogen bromide; oxygen; acetic acid In water at 100℃; under 750.075 Torr; for 20h;97%
p-Toluic acid
99-94-5

p-Toluic acid

benzylamine
100-46-9

benzylamine

N-benzyl-4-methylbenzamide
5436-83-9

N-benzyl-4-methylbenzamide

Conditions
ConditionsYield
With borane-ammonia complex In 5,5-dimethyl-1,3-cyclohexadiene for 6h; Reflux;99%
With Bromotrichloromethane; 4-(diphenylphosphino)-benzyltrimethylammonium bromide; triethylamine In tetrahydrofuran at 60℃; for 6h; Inert atmosphere;98%
Stage #1: p-Toluic acid With N-chlorobenzotriazole; triphenylphosphine In dichloromethane for 0.25h;
Stage #2: benzylamine With triethylamine In dichloromethane at 20℃; for 0.75h;
95%
p-cresol
106-44-5

p-cresol

p-Toluic acid
99-94-5

p-Toluic acid

4-methylphenyl 4-methylbenzoate
15024-08-5

4-methylphenyl 4-methylbenzoate

Conditions
ConditionsYield
With triphenylphosphine In tetrahydrofuran at 65℃; for 16h; Product distribution; Further Variations:; Solvents; Mitsunobu reaction;99%
With trifluoromethylsulfonic anhydride; triethylamine; Triphenylphosphine oxide In 1,2-dichloro-ethane at 25℃; for 0.25h;88%
p-Toluic acid
99-94-5

p-Toluic acid

aniline
62-53-3

aniline

4-methyl-N-phenylbenzamide
6833-18-7

4-methyl-N-phenylbenzamide

Conditions
ConditionsYield
With fluorosulfonyl fluoride; N-ethyl-N,N-diisopropylamine In acetonitrile at 20℃; for 5h;99%
Stage #1: p-Toluic acid With N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate at 20℃; for 0.166667h;
Stage #2: aniline at 20℃; for 1h;
97%
With (3-{[(cyclohexylimino)methylidene]amino}propyl)oxy linked polystyrene resin In dichloromethane; N,N-dimethyl-formamide for 0.0833333h; Flow reactor;96%
p-Toluic acid
99-94-5

p-Toluic acid

<α,α-2H2>-4-methylbenzyl alcohol
40662-66-6

<α,α-2H2>-4-methylbenzyl alcohol

Conditions
ConditionsYield
With lithium aluminium deuteride In tetrahydrofuran for 24h; Heating;99%
With lithium aluminium deuteride In diethyl ether at 20℃; for 3h;90%
p-Toluic acid
99-94-5

p-Toluic acid

p-toluic hydrazide
3619-22-5

p-toluic hydrazide

Conditions
ConditionsYield
Stage #1: p-Toluic acid With sulfuric acid In ethanol for 6h; Reflux;
Stage #2: With hydrazine hydrate; sodium hydrogencarbonate; acetic acid Reflux;
99%
With acetic acid; acetic acid hydrazide for 0.1h; Microwave irradiation;85%
With hydrazine hydrate for 0.0472222h; Microwave irradiation;85%
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