HANGZHOU THINK CHEMICAL CO., LTD. (THINKCHEM) is an integrative corporation of trade, research and contract manufacture. With about ten years of business experiences on the marketing & distribution, thinkchem specializes in exp
Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:64-18-6
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inquiryhebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm
Cas:64-18-6
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Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so
Product Description Product name Formic acid CAS 64-18-6 Assay 99% Appearance Colorless liquid
Chemical Name formic acid CAS No. 64-18-6 Molecular Formula CH2O2 Molecular Weight 46.02540 PSA 37.30000 LogP 0.33670
Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present
Cas:64-18-6
Min.Order:1 Kilogram
FOB Price: $2.0 / 5.0
Type:Trading Company
inquiryProduct Detail Minimum Order Qty. 10 Gram
Cas:64-18-6
Min.Order:10 Gram
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Type:Trading Company
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Product quality: Our company have high quality product , and also the product we have good manufacture . First of all, this product is of fine quality. Every finish should be checked by quality inspection system.And every one should be also tr
Cas:64-18-6
Min.Order:1 Kilogram
FOB Price: $30.0 / 50.0
Type:Trading Company
inquiryProduct Name: Formic acid Synonyms: FORMOL;FORMALDE-FRESH;FORMALDE-FRESH SOLUTION;FORMALDE-FRESH SOLUTION, BUFFERED;FORMALDEHYDE, BUFFERED;FORMALDEHYDE, CARSON-MILLON;METHANONE;METHYL ALDEHYDE CAS: 64-18-6 MF: CH2O2 MW: 46.03 EINECS: 200-
Cas:64-18-6
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryAppearance:white or yellowish white flaky crystal Storage:Keep the sun from direct sunlight ;prevention against high temperature Package:As customer request Application:Used for research and industrial manufacture. Transportatio
Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Lonwin Industry group limited as a professional manufactor & exporter of chemical materials ,we totally haver more than 270 stuffs, we have been on this line for more than 9 years. Our chemical materials are exported to lot of countries and reg
Cas:64-18-6
Min.Order:100 Kilogram
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Performic acidAppearance:Powder and crystal Storage:keep dry Package:according to customers' requirements Application:medical Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB or CIF or CNF ect...)or according to your demand. Por
Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Product name: Formic Acid CAS No,: 64-18-6 Molecule Formula:CH2O2 Molecule Weight:46.02 Purity: 99.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard TESTING I
Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h
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with strong MFG,with best service,with best price term Methods of production 1. Sodium formate method Carbon monoxide and sodium hydroxide solution react at 160-200℃ and 2MPa pressure to produce sodium formate, and then the finished product is obta
Cas:64-18-6
Min.Order:1 Metric Ton
Negotiable
Type:Trading Company
inquiryAppearance: Colourless combutibles liquid. Colour, Platinum Cobalt:20 max Purity: 85 % min Sulphate as SO4:0.002 % max Chl…Appearance:Colorless, transparent liquid Storage:Rom tep. Package:35kg net/drum, or 1200kg/BC Port:
Superior quality, moderate price & quick delivery. Appearance:colorless transparent liquid Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used for active pha
high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier
high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Conditions | Yield |
---|---|
With chlorotris(sodium 3-sulfonatophenyldiphenylphosphine)rhodium(I); hydrogen; sodium formate In water at 50℃; under 75007.5 Torr; for 20h; Inert atmosphere; | 100% |
With sodium hydrogencarbonate In water for 18h; Reagent/catalyst; Electrochemical reaction; | 93.6% |
Stage #1: carbon dioxide With phenylsilane In N,N-dimethyl acetamide at 50℃; under 22502.3 Torr; for 4h; pH=Ca. 1.2; Autoclave; Green chemistry; Stage #2: With water In N,N-dimethyl acetamide at 100℃; for 0.25h; Pressure; Temperature; Reagent/catalyst; Time; Green chemistry; | 91% |
Conditions | Yield |
---|---|
Stage #1: methanol With oxygen; nickel dichloride In water at 20℃; for 0.166667h; Flow reactor; Stage #2: With copper(II) sulfate In water at 55℃; for 0.166667h; Flow reactor; | 98% |
With sodium hydroxide; potassium hexacyanoferrate(III); iridium(III) chloride at 35℃; Rate constant; Thermodynamic data; ΔE, ΔS(excit.), ΔF(excit.); | |
With dipotassium peroxodisulfate In water at 45℃; Kinetics; Rate constant; Thermodynamic data; mechanism, concentration, temperature, overall energy of activation; |
Conditions | Yield |
---|---|
With iron(III) trifluoromethanesulfonate; 2-((4R,5R)-1-((4-(tert-butyl)phenyl)sulfonyl)-4,5-diphenylimidazolidin-2-yl)-6-((4R,5R)-1-((4-(tert-butyl)phenyl)sulfonyl)-4,5-diphenylimidazolidin-2-yl)pyridine; oxygen at 70℃; under 760.051 Torr; for 6h; Solvent; Green chemistry; | A n/a B 96% |
A
formic acid
B
3-(tert-butyldiphenylsilanyloxy)-2-methylpropionic acid
Conditions | Yield |
---|---|
With camphor-10-sulfonic acid; dihydrogen peroxide In chloroform-d1 | A 50% B 96% |
formic acid 2-formyloxy-1-methylpropyl ester
A
formic acid
B
trans-2-Butene
C
buta-1,3-diene
D
butanone
Conditions | Yield |
---|---|
at 500℃; for 5h; Mechanism; Inert atmosphere; Flow reactor; Pyrolysis; chemoselective reaction; | A 20% B n/a C 94% D n/a |
styrene
A
formaldehyd
B
formic acid
C
benzaldehyde
D
benzoic acid
Conditions | Yield |
---|---|
With pyridine; ozone at 20℃; for 1.16667h; Oxidation; ozonolysis; | A 2% B 2.4% C 2.6% D 93% |
Conditions | Yield |
---|---|
at 160℃; under 99.76 Torr; | A 92% B n/a |
Conditions | Yield |
---|---|
In perchloric acid; water Kinetics; react. at 30 +/- 0.2°C; detection by spectrophotometry; | A 90% B n/a C >99 D n/a |
Conditions | Yield |
---|---|
In perchloric acid; water Kinetics; react. at 30 +/- 0.2°C; detection by spectrophotometry; | A 90% B n/a C >99 D n/a |
formic acid
Conditions | Yield |
---|---|
With water at 20℃; for 0.5h; | 90% |
Conditions | Yield |
---|---|
Stage #1: syringic aldehyde With sodium percarbonate In tetrahydrofuran; water at 25℃; Dakin Phenol Oxidation; Inert atmosphere; Stage #2: With hydrogenchloride In tetrahydrofuran; water pH=1; Inert atmosphere; | A n/a B 90% |
6-methyl-6-phenyl-3-(1-phenylethyl)-5-(m-toluidino)-1,2,4-trioxan
A
formic acid
B
2-Phenylpropanal
C
acetophenone
D
1-amino-3-methylbenzene
Conditions | Yield |
---|---|
With hydrogenchloride In ethanol for 0.0833333h; Ambient temperature; Further byproducts given; | A 58% B 69% C 89% D 75% |
Conditions | Yield |
---|---|
In water at 20℃; for 0.333333h; Schlenk technique; Inert atmosphere; Glovebox; | A 88% B n/a |
Conditions | Yield |
---|---|
Stage #1: sodium hydrogencarbonate With hydrogen In water at 200℃; under 45004.5 Torr; for 4h; Autoclave; Stage #2: Pressure; Reagent/catalyst; | 86.1% |
With nickel; hydrazine hydrate In water at 300℃; for 2h; Reagent/catalyst; Green chemistry; | 50% |
With sodium chloride at 40℃; for 2h; Irradiation; Halobacterium halobium MMT22; Yield given; |
Conditions | Yield |
---|---|
With potassium bromate; ruthenium trichloride; perchloric acid at 39.85℃; Kinetics; Further Variations:; Reagents; Temperatures; Oxidation; | 86% |
With phosphovanadomolybdic acid; oxygen In water at 150℃; under 15001.5 Torr; for 3h; | 73.9% |
With aluminium(III) triflate; dihydrogen peroxide In acetonitrile at 70℃; for 12h; | 63.1% |
Conditions | Yield |
---|---|
With dihydrogen peroxide In neat (no solvent) at 25℃; for 24h; Catalytic behavior; Reagent/catalyst; | A n/a B 86% |
With oxygen; vanadia In water at 79.84℃; under 2250.23 Torr; for 1h; Autoclave; | A 14 %Chromat. B 13 %Chromat. |
Conditions | Yield |
---|---|
With 2,6-dimethylpyridine; water at 120℃; under 9000.9 Torr; | 85% |
With sulfuric acid Hydrolysis; | |
With water; N-cyclohexyl-cyclohexanamine at 130℃; Equilibrium constant; Reagent/catalyst; |
Glyoxal
formic acid
Conditions | Yield |
---|---|
With phosphovanadomolybdic acid; oxygen In water at 150℃; under 15001.5 Torr; for 3h; | 84.3% |
With dihydrogen peroxide; sodium molybdate; mercury(II) diacetate In 1,4-dioxane; water at 25℃; for 0.5h; Yield given; | |
With TiClO4 at 39.9℃; Rate constant; Kinetics; Thermodynamic data; E(excit.), ΔH(excit.), ΔS(excit.); var. temp.; | |
With sodium vanadate; sulfuric acid; oxygen In water at 160℃; under 22502.3 Torr; for 0.0166667h; Autoclave; | |
With H(1+)*Mo11O40PV(4-)*3C7H13N2O3S(1+); oxygen In water at 180℃; under 7500.75 Torr; for 1h; Autoclave; | 74.2 %Chromat. |
Conditions | Yield |
---|---|
With hydrogen In water at 200℃; under 45004.5 Torr; for 4h; Autoclave; | 83.7% |
With [{Ir(pentamethylcyclopentadienyl)(Cl)}2(4,4',6,6'-tetrahydroxybipyrimidine)](Cl2); hydrogen In water at 50℃; under 30003 Torr; for 8h; Catalytic behavior; Reagent/catalyst; Pressure; Time; Temperature; | |
With hydrogen carbonate reductase; hydrogen under 750.075 Torr; Kinetics; Reagent/catalyst; Enzymatic reaction; |
Conditions | Yield |
---|---|
With dihydrogen peroxide In neat (no solvent) at 25℃; for 24h; Catalytic behavior; Reagent/catalyst; | A n/a B 86% |
With oxygen; vanadia In water at 79.84℃; under 2250.23 Torr; for 1h; Autoclave; | A 14 %Chromat. B 13 %Chromat. |
With iron hydroxide oxide; manganese(IV) oxide; dihydrogen peroxide In water at 25℃; for 24h; Reagent/catalyst; Autoclave; |
Conditions | Yield |
---|---|
With hydrogenchloride; water at 199.84℃; for 0.166667h; Concentration; Temperature; Time; | A 83% B 43% |
With water at 185 - 205℃; for 0.420833h; Product distribution / selectivity; Acidic conditions; | A 82% B n/a |
With 5-methyl-dihydro-furan-2-one at 159.84℃; for 16h; | A 20% B 69% |
Conditions | Yield |
---|---|
With perchloric acid; bromamine T In water at 35 - 40℃; Kinetics; Mechanism; Thermodynamic data; ΔH and ΔS; var. solv.: D2O; | A 82% B 82% |
With perchloric acid; mercury(II) diacetate; N-bromoacetamide In water at 30℃; Kinetics; Mechanism; effect of the concentrations of NBA, MIK, acid and Hg(OAc)2; effect of the ionic strength; D2O isotopic effect; further temperatures; |
Conditions | Yield |
---|---|
With phosphoric acid immobilized anatase TiO2 In tetrahydrofuran; water at 119.84℃; for 2h; Sealed tube; Green chemistry; | A 81.2% B 10.5% |
With dihydrogen peroxide In water at 200℃; for 1h; pH=5.4; | A 11.55% B 5.68% |
alpha-D-glucopyranose
A
5-hydroxymethyl-2-furfuraldehyde
B
formic acid
C
levulinic acid
D
levoglucosan
Conditions | Yield |
---|---|
With 15 wtpercent phosphate impregnated titania In water; butan-1-ol at 175℃; under 22502.3 Torr; for 3h; Catalytic behavior; Temperature; Inert atmosphere; Autoclave; | A 81% B n/a C n/a D n/a |
Glycolaldehyde
A
formic acid
B
glycolic Acid
C
Glyoxal
D
carbon dioxide
E
acetic acid
Conditions | Yield |
---|---|
With water; oxygen at 90℃; under 7500.75 Torr; for 8h; Catalytic behavior; Mechanism; Temperature; Pressure; Time; Reagent/catalyst; | A 80.5% B 4.2% C 6.2% D 2.6% E 0.3% |
D-Arabinose
formic acid
Conditions | Yield |
---|---|
With dihydrogen peroxide In ethanol; water at 69.84℃; for 5h; Inert atmosphere; Schlenk technique; chemoselective reaction; | 79.7% |
Conditions | Yield |
---|---|
With dihydrogen peroxide In ethanol; water at 69.84℃; for 5h; Inert atmosphere; Schlenk technique; chemoselective reaction; | 79.6% |
With phosphovanadomolybdic acid; oxygen In water at 180℃; under 15001.5 Torr; for 3h; | 33.1% |
With sodium chloride In water at 189.84℃; under 15001.5 Torr; for 2h; Reagent/catalyst; Temperature; Sealed tube; Inert atmosphere; | 9.6% |
With sodium vanadate; sulfuric acid; oxygen In water at 160℃; under 22502.3 Torr; for 0.0166667h; Autoclave; | |
With C13H16ClN3O2Pd; dihydrogen peroxide; sodium hydroxide In water at 25℃; for 16h; Catalytic behavior; |
Conditions | Yield |
---|---|
With sulfuric acid | 79% |
With water Electrolysis.Mehrkammersystem mit Kammerwaenden aus semipermeablen Ionenaustauschern; | |
With sulfuric acid; sulfur trioxide |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; bis(acetylacetonato)dioxidomolybdenum(VI) In benzene at 70℃; for 48h; Product distribution; other reaction times, other catalysts, other allylic alcohols and olefins as substrates; | A n/a B 79% C 6% |
3β-formyloxy-5αH-cholestane
A
formic acid
B
cholestane
C
Cholestanol
Conditions | Yield |
---|---|
In N,N,N,N,N,N-hexamethylphosphoric triamide; water for 5h; Irradiation; | A n/a B 79% C 19% |
Conditions | Yield |
---|---|
With iodopentafluorobenzene bis(trifluoroacetate); water In benzene Product distribution; Heating; other alkynes or α-hydroxy-p-nitroacetophenone; | A n/a B 79% |
Conditions | Yield |
---|---|
With cyano-hydroxyimino-acetic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester; sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In water at 20℃; for 3h; Reagent/catalyst; Solvent; | 100% |
With aminoproplylated mesoporous SBA-15 silica at 40℃; for 0.25h; Neat (no solvent); chemoselective reaction; | 95% |
With NH2-MIL-53 at 50℃; for 0.333333h; | 95% |
Conditions | Yield |
---|---|
With cyano-hydroxyimino-acetic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester; sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In water at 20℃; for 3h; Reagent/catalyst; Solvent; | 100% |
In butan-1-ol at 120℃; Solvent; Temperature; | 99.35% |
In ethanol at 140℃; for 24h; Solvent; Autoclave; | 98% |
Conditions | Yield |
---|---|
With sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; ethyl cyanoglyoxylate-2-oxime In water; N,N-dimethyl-formamide at 20℃; for 3h; Reagent/catalyst; Solvent; | 100% |
Conditions | Yield |
---|---|
toluene-4-sulfonic acid at 85℃; for 4h; Esterification; | 100% |
With 2-methyl-1-butylimidazolium trifluoroacetate In neat (no solvent) at 70℃; for 1h; | 96% |
Stage #1: formic acid With acetic anhydride at 40℃; for 2h; Stage #2: 1-dodecyl alcohol at 0 - 20℃; for 15.25h; | 94% |
With hydrogenchloride |
Conditions | Yield |
---|---|
In water for 19h; | 100% |
at 20 - 25℃; for 4h; | 100% |
for 5h; Reflux; | 89.3% |
for 5h; Reflux; |
Conditions | Yield |
---|---|
In water at 100℃; for 3h; Phillips cyclization; | 100% |
In water at 100℃; for 3h; | 84.1% |
Conditions | Yield |
---|---|
With acetic anhydride at 20℃; for 1h; | 100% |
With acetic anhydride at 20℃; for 19h; | 87% |
In N,N-dimethyl-formamide for 0.166667h; Heating; | 81% |
Conditions | Yield |
---|---|
With water In aq. phosphate buffer at 20℃; for 1h; pH=7.4; Catalytic behavior; Reagent/catalyst; Electrolysis; Inert atmosphere; Enzymatic reaction; | 100% |
With cobalt(III) acetylacetonate; hydrogen; bis(trifluoromethanesulfonyl)amide; [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In tetrahydrofuran; ethanol at 100℃; under 52505.3 Torr; for 24h; Autoclave; Inert atmosphere; | 59% |
With C36H54IrN2P2(1+)*C24H20B(1-); hydrogen; sodium hydride In ethanol; toluene at 180℃; under 7500.75 - 45004.5 Torr; for 18h; Autoclave; | 31% |
Conditions | Yield |
---|---|
at 60℃; for 1h; Inert atmosphere; | 100% |
at 0 - 60℃; for 3.5h; | 78% |
at 50℃; Fraktionierung im Vakuum; |
Conditions | Yield |
---|---|
In toluene Reflux; | 100% |
With sodium formate at 20℃; for 2h; Neat (no solvent); | 98% |
With TiO2-SO4(2-) In acetonitrile at 20℃; for 6h; | 98.3% |
Conditions | Yield |
---|---|
In toluene Reflux; | 100% |
With sodium formate at 20℃; for 3h; Neat (no solvent); | 99% |
With TiO2-SO4(2-) In acetonitrile at 20℃; for 4h; | 99% |
formic acid
2-(3,4-dimethoxyphenyl)-ethylamine
N-[2-(3,4-dimethoxyphenyl)ethyl]formamide
Conditions | Yield |
---|---|
With acetic anhydride 1.) 60 deg C, 30 min, 2.) 20 deg C, overnight; | 100% |
With 4-methyl-morpholine; dmap; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine In dichloromethane at 35℃; for 0.05h; microwave irradiation; | 98% |
In dichloromethane at 80℃; for 8h; | 95% |
Conditions | Yield |
---|---|
Stage #1: formic acid With acetic acid at 25℃; for 1h; Stage #2: phenethylamine at 0 - 25℃; | 100% |
With sulfated tungstate at 70℃; for 0.166667h; Neat (no solvent); | 98% |
With pyridine; diisopropyl-carbodiimide at 20℃; for 72h; | 15% |
Conditions | Yield |
---|---|
With hydrogenchloride In water for 3h; Reflux; | 100% |
at 110℃; for 4h; | 95% |
With tetrabutyl-ammonium chloride In water; toluene at 160℃; for 0.25h; Microwave irradiation; | 89% |
Conditions | Yield |
---|---|
With sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; ethyl cyanoglyoxylate-2-oxime In water; N,N-dimethyl-formamide at 20℃; for 3h; Reagent/catalyst; Solvent; | 100% |
With zinc(II) oxide at 70℃; for 0.166667h; | 99% |
Stage #1: formic acid With silica gel at 20℃; for 0.0166667h; Stage #2: aniline With silica gel at 110℃; for 0.05h; | 99% |
Conditions | Yield |
---|---|
With hydrogenchloride In water for 8h; Reflux; | 100% |
With tetrabutyl-ammonium chloride In water; toluene at 160℃; for 0.2h; Microwave irradiation; | 90% |
With chloro-trimethyl-silane In water; N,N-dimethyl-formamide at 120℃; for 0.2h; Microwave irradiation; | 90% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 110℃; for 0.666667h; | 100% |
In N,N-dimethyl-formamide at 153℃; for 0.333333h; futher solvents, further temperatures, further reaction times; | 97% |
Stage #1: formic acid With acetic anhydride at 45℃; for 1h; Inert atmosphere; Stage #2: glycine at 20℃; for 72h; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
In toluene Reflux; | 100% |
In toluene Reflux; | 100% |
In toluene Reflux; | 100% |
Conditions | Yield |
---|---|
Stage #1: formic acid With silica gel at 20℃; for 0.0166667h; Stage #2: 4-Methoxybenzyl alcohol With silica gel at 110℃; for 0.0166667h; | 100% |
With aminopropylated mesoporous SBA-15 silica at 40℃; for 0.0833333h; Neat (no solvent); chemoselective reaction; | 95% |
With iodine at 20℃; for 0.116667h; neat (no solvent); | 94% |
Conditions | Yield |
---|---|
With sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; ethyl cyanoglyoxylate-2-oxime In water; N,N-dimethyl-formamide at 20℃; for 3h; Reagent/catalyst; Solvent; | 100% |
With 4-methyl-morpholine; dmap; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine In dichloromethane at 35℃; for 0.1h; microwave irradiation; | 99% |
With sulfated tungstate at 70℃; for 0.166667h; Neat (no solvent); | 99% |
Conditions | Yield |
---|---|
In toluene Reflux; | 100% |
With sodium formate at 20℃; for 2.75h; Neat (no solvent); | 99% |
With zinc(II) oxide at 70℃; for 0.333333h; | 98% |
Conditions | Yield |
---|---|
at 100℃; | 100% |
With hydrogenchloride In water for 3h; Reflux; | 97.5% |
for 2h; Reflux; | 85% |
With hydrogenchloride | |
Stage #1: formic acid; 4-Bromo-benzene-1,2-diamine for 2h; Reflux; Stage #2: With sodium hydroxide In water at 20℃; |
formic acid
methyl α-chloro-α-phenylbenzeneacetate
methyl (formyloxy)diphenylacetate
Conditions | Yield |
---|---|
With sodium formate for 4h; Ambient temperature; | 100% |
With sodium formate In N,N-dimethyl-formamide for 3h; Ambient temperature; | 96% |
Conditions | Yield |
---|---|
Stage #1: formic acid With acetic anhydride In dichloromethane at 20℃; for 0.166667h; Stage #2: 2-iodophenylamine In dichloromethane at 20℃; | 100% |
In water; toluene at 110℃; for 4h; | 99% |
Stage #1: formic acid With acetic anhydride at 20℃; for 0.166667h; Inert atmosphere; Stage #2: 2-iodophenylamine In dichloromethane at 20℃; for 2h; Inert atmosphere; | 98% |
formic acid
tetra(n-butyl)ammonium hydroxide
tetra(n-butyl)ammonium formate
Conditions | Yield |
---|---|
In water pH=Ca. 8.45; Glovebox; | 100% |
In methanol; water at 20 - 60℃; | 99% |
In methanol at 20℃; for 2h; Inert atmosphere; | 85% |
formic acid
4-(2-aminoethyl)-1-(phenylmethyl)piperidine
1-benzyl-4-<2-(N-formylamino)ethyl>piperidine
Conditions | Yield |
---|---|
With acetic anhydride | 100% |
at 100℃; for 6h; | 38% |
formic acid
1-(4-hydroxy-phenyl)-piperazine dihydrobromide
1-Formyl-4-(4-hydroxyphenyl)piperazine
Conditions | Yield |
---|---|
With sodium carbonate In water; toluene for 18h; Heating; | 100% |
formic acid
1-(2,2-dimethyl-3-but-enyl)-5-hydroxy-2-pyrrolid-one
rel-(6R,7aS)-6-<2-(formyloxy)prop-2-yl>hexahydro-3H-pyrrolizin-3-one
Conditions | Yield |
---|---|
for 0.0833333h; Ambient temperature; | 100% |
at 40℃; for 0.0833333h; | 0.462 g |
Conditions | Yield |
---|---|
for 2h; Ambient temperature; | 100% |
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