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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

N-Formylmorpholine Manufacturer/High quality/Best price/In stock

Cas:4394-85-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality N-Formylmorpholine supplier in China

Cas:4394-85-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hefei TNJ chemical industry co.,ltd

Good products, good service. We have professional sales team working on sales service for 15 years. Good products can win good market but can not stand long without good service. We have strict sales regulation and service procedure to make sure yo

N-Formayl Morpholine From China Supplier At Factory Price

Cas:4394-85-8

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high purity Appearance:Colorless transparent liquid Storage:cold storage Package:meet the demand of customer Application:Biomedical reagents Transportation:by sea or by air Port:Shanghai, Qingdao

N-FORMYLMORPHOLINE

Cas:4394-85-8

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-morpholinecarbaldehyde

Cas:4394-85-8

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Large Stock 99.0% N-Formylmorpholine 4394-85-8 Producer

Cas:4394-85-8

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

N-Formylmorpholine -- CHemwill

Cas:4394-85-8

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production . enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carbon environmental protection

N-Formylmorpholine CAS NO.4394-85-8

Cas:4394-85-8

Min.Order:1 Kilogram

FOB Price: $11.0 / 16.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

N-Formylmorpholine Basic information Product Name: N-Formylmorpholine Synonyms: 4-Morpholinecarbaldehyde;Formmorpholime;Morpholine, 4-formyl-;N-Formylmorfolin;4-MOR

TIANFU-CHEM N-Formylmorpholine 4394-85-8

Cas:4394-85-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Valued High QualityCAS 4394-85-8 with fast shipping

Cas:4394-85-8

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-Morpholinecarboxaldehyde 4394-85-8

Cas:4394-85-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

N-Formylmorpholine

Cas:4394-85-8

Min.Order:1 Kilogram

FOB Price: $50.0 / 54.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

N-Formylmorpholine CAS: 4394-85-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm

N-Formylmorpholine CAS: 4394-85-8

Cas:4394-85-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-Morpholinecarboxaldehyde

Cas:4394-85-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 4394-85-8 N-Formylmorpholine

Cas:4394-85-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

4-Morpholinecarboxaldehyde

Cas:4394-85-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

N-Formylmorpholine

Cas:4394-85-8

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

N-Formylmorpholine

Cas:4394-85-8

Min.Order:0

Negotiable

Type:Manufacturers

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

low price N-Formylmorpholine 4394-85-8 supplier in China

Cas:4394-85-8

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

N-Formylmorpholine

Cas:4394-85-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

N-Formylmorpholine

Cas:4394-85-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Miheng Trading Co., Ltd.

N-Formylmorpholine CAS 4394-85-8 Our advantage 1.Top quality: Using high quality material and establishing a strict quality control system,assigning specific persons in charge of each part of production,from raw material purchase to assembly.

N-Formylmorpholine CAS 4394-85-8

Cas:4394-85-8

Min.Order:1 Kilogram

FOB Price: $50.0 / 100.0

Type:Trading Company

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Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

4-Formylmorpholine

Cas:4394-85-8

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Lingrui Chemical Co.,Ltd.

Best price 4394-85-8 high quality N-Formylmorpholine manufacturer Molecular Formula C5H9NO2 Molar Mass 115.13 Density 1.145 g/mL at 25 °C (lit.) Melting Point 20-23 °C (lit.) Boling Po

Best price 4394-85-8 high quality N-Formylmorpholine manufacturer

Cas:4394-85-8

Min.Order:1 Gram

Negotiable

Type:Other

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Hefei Zhaobo Technology Co., Ltd.

N-Formylmorpholine CAS 4394-85-8 Purity: 99% Min Application: Intermediates Appearance: Powder Package: Bag Delivery: 3-5days Our Advantage & Service 1.Top quality: Using high quality material and establishing a strict quality contro

N-Formylmorpholine CAS 4394-85-8

Cas:4394-85-8

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High purity N-Formylmorpholine

Cas:4394-85-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

low price N-Formylmorpholine 4394-85-8 supplier in China

Cas:4394-85-8

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: N-Formylmorpholine CAS No.: 4394-85-8 Molecule Formula:C5H9NO2 Molecule Weight:115.13 Purity: 99.0% Package: 180kg/drum Description:Colorless to light yellow liquid Manufacture Standards:Enterprise Standard

Lower Price N-Formylmorpholine

Cas:4394-85-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Wuhan Fortuna Chemical Co.,Ltd

CAS:4394-85-8 EINECS:224-518-3 MW:115.13 MF:C5H9NO2 Melting point:20-23 °C(lit.) Boiling point:236-237 °C(lit.) Appearance:colorless liquid Package:200kg/Steel drum Transportation:by sea Port:Shanghai

N-Formylmorpholine

Cas:4394-85-8

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

N-Formylmorpholine Chemical Properties Melting point 20-23 °C (lit.) Boiling point 236-237 °C (lit.) density 1.145 g/mL at 25 °C (lit.) vapor pressure 0.03 hPa (20 °C) refractive index n20/D 1.485(lit.) Fp >

N-Formylmorpholine

Cas:4394-85-8

Min.Order:1 Gram

FOB Price: $65.0

Type:Lab/Research institutions

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Synthetic route

morpholine
110-91-8

morpholine

formic acid
64-18-6

formic acid

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With cyano-hydroxyimino-acetic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester; sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In water at 20℃; for 3h; Reagent/catalyst; Solvent;100%
In butan-1-ol at 120℃; Solvent; Temperature;99.35%
In ethanol at 140℃; for 24h; Solvent; Autoclave;98%
morpholine
110-91-8

morpholine

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With Iron(III) nitrate nonahydrate In toluene for 7h; Reflux;100%
With water; boric acid at 100℃; for 24h;87%
With [bis(acetoxy)iodo]benzene In neat (no solvent) at 100℃; for 0.333333h; Microwave irradiation; Green chemistry;86%
lithium morpholide
37828-58-3

lithium morpholide

carbon monoxide
201230-82-2

carbon monoxide

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With water In tetrahydrofuran at 0℃; under 759.8 Torr;100%
In tetrahydrofuran at 0℃; Product distribution; with/without n-BuLi reag.; various inhibitors;
morpholine
110-91-8

morpholine

carbon dioxide
124-38-9

carbon dioxide

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With phenylsilane; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In tetrahydrofuran-d8 at 100℃; under 750.075 Torr; for 6h; Inert atmosphere;100%
With C21H24N2; phenylsilane In tetrahydrofuran at 20℃; under 750.075 - 2250.23 Torr; for 0.25h; Reagent/catalyst; Solvent; Temperature; Time; Concentration; Inert atmosphere; Glovebox;100%
With phenylsilane at 25℃; under 3750.38 Torr; for 12h; Pressure; Temperature; Autoclave;100%
morpholine
110-91-8

morpholine

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With 1,2,4-Triazole; 8-quinolinol; copper(II) choride dihydrate at 150℃; Reagent/catalyst; Temperature;98%
With zinc(II) phthalocyanine; carbon dioxide; phenylsilane at 25℃; under 3750.38 Torr; for 6h; Autoclave; chemoselective reaction;92%
Stage #1: N,N-dimethyl-formamide With bis(2-chlorophenyl)borinic acid; acetic acid at 65℃; for 0.25h; Inert atmosphere;
Stage #2: morpholine at 65℃; for 24h; Inert atmosphere;
89%
morpholine
110-91-8

morpholine

formaldehyd
50-00-0

formaldehyd

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With sodium hydroxide In water at 25℃; for 6h;97%
With potassium iodide In water Ambient temperature; electrolysis;83%
With oxygen; sodium hydroxide In tetrahydrofuran; water at 10℃; for 23h;75%
morpholine
110-91-8

morpholine

Isopropenyl formate
32978-00-0

Isopropenyl formate

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
In ethyl acetate for 1h; Ambient temperature;97%
4-((Z)-2-Methyl-undec-1-enyl)-morpholine

4-((Z)-2-Methyl-undec-1-enyl)-morpholine

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

methyl nonyl ketone
112-12-9

methyl nonyl ketone

Conditions
ConditionsYield
With oxygen; Cu-X zeolite In 1,2-dichloro-ethane; acetonitrile at 50℃; for 5h; Oxidation; Oxidative cleavage;A 96%
B 97%
morpholine
110-91-8

morpholine

Methyl formate
107-31-3

Methyl formate

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With calcium(II) bis(trifluoromethanesulfonyl)imide In neat (no solvent) at 115℃; for 1h; Microwave irradiation; Sealed tube;96%
With methanol at 140℃; for 16h; Reagent/catalyst;92.7%
With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In toluene at 20℃; for 0.5h;90%
With [bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amide](carbonyl)(hydride)iron(II) In tetrahydrofuran at 80℃; for 8h; Catalytic behavior; Mechanism; Reagent/catalyst; Schlenk technique; Sealed tube; Inert atmosphere;
morpholine
110-91-8

morpholine

carbon monoxide
201230-82-2

carbon monoxide

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
dodecacarbonyl-triangulo-triruthenium In tetrahydrofuran at 185℃; for 24h;95.5%
With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In toluene at 100℃; under 22502.3 Torr; for 20h; Autoclave;83%
With potassium hydroxide In methanol at 110℃; under 7500.75 Torr; for 15h; Autoclave;76%
morpholine
110-91-8

morpholine

chloroform
67-66-3

chloroform

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With sodium ethanolate at 50℃; Riemer-Tiemann reaction; Inert atmosphere;95%
With potassium fluoride on basic alumina In acetonitrile at 20℃; for 18h;80%
With sodium hydroxide; tetrabutyl ammonium fluoride at 50℃; for 2.08333h;35%
1-(4-morpholino)-2,2-diphenylethene
61253-71-2

1-(4-morpholino)-2,2-diphenylethene

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

benzophenone
119-61-9

benzophenone

Conditions
ConditionsYield
With oxygen; copper dichloride In 1,2-dichloro-ethane; acetonitrile at 50℃; for 1h; Oxidation; Oxidative cleavage;A 95%
B 87%
With aluminum oxide; potassium permanganate; neutral In acetone for 4h; Ambient temperature;A n/a
B 75%
morpholine
110-91-8

morpholine

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
In acetonitrile for 10h; Formylation;95%
morpholine
110-91-8

morpholine

carbon dioxide
124-38-9

carbon dioxide

A

4-methyl-morpholine
109-02-4

4-methyl-morpholine

B

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With tris(2-diphenylphosphinoethyl)phosphine; hydrogen; potassium carbonate; cobalt(II) perchlorate hexahydrate In ethanol at 140℃; under 45004.5 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Temperature; Autoclave; Green chemistry;A 1%
B 95%
With tris(2-diphenylphosphinoethyl)phosphine; hydrogen; potassium carbonate; cobalt(II) perchlorate hexahydrate In ethanol at 120℃; under 45004.5 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Temperature; Autoclave; Green chemistry;A 10%
B 79%
With potassium phosphate; tris(2-diphenylphosphinoethyl)phosphine; hydrogen; cobalt(II) perchlorate hexahydrate In tetrahydrofuran at 140℃; under 45004.5 Torr; for 24h; Catalytic behavior; Mechanism; Time; Reagent/catalyst; Temperature; Pressure; Autoclave; Green chemistry;A 69%
B 28%
With C27H36Cl2N2Zn; phenylsilane at 100℃; for 20h;
With diphenylsilane; [(2,6-(2,4,6-Me3C6H2)2C6H3)Ge(O)(1,3,4,5-tetramethylimidazol-2-ylidene)2]Cl In [D3]acetonitrile at 50℃; under 750.075 Torr; for 3h; Time; Inert atmosphere;A 75 %Spectr.
B 21 %Spectr.
N-cyanomorpholine
1530-89-8

N-cyanomorpholine

acetic acid
64-19-7

acetic acid

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

4-acetylmorpholine
1696-20-4

4-acetylmorpholine

Conditions
ConditionsYield
With zinc for 2h; Heating;A 6%
B 94%
N-cyanomorpholine
1530-89-8

N-cyanomorpholine

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

4-acetylmorpholine
1696-20-4

4-acetylmorpholine

Conditions
ConditionsYield
With acetic acid; zinc for 2h; Heating;A 6%
B 94%
4-(2-methyl-1-propenyl)morpholine
2403-55-6

4-(2-methyl-1-propenyl)morpholine

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With oxygen; Cu-X zeolite In 1,2-dichloro-ethane; acetonitrile at 50℃; for 5h; Oxidation; Oxidative cleavage;A 93%
B n/a
1,2-dimorpholylethane
1723-94-0

1,2-dimorpholylethane

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; water; oxygen; silica gel; caesium carbonate In acetonitrile at 20℃; for 60h; Inert atmosphere; Irradiation;93%
4-((E)-2,6-Dimethyl-hepta-1,5-dienyl)-morpholine

4-((E)-2,6-Dimethyl-hepta-1,5-dienyl)-morpholine

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
With aluminum oxide; potassium permanganate; neutral In acetone for 4h; Ambient temperature;A n/a
B 92%
3-(4-isopropyl)-phenyl-2-methyl-1-(4-morpholino)-1-propene

3-(4-isopropyl)-phenyl-2-methyl-1-(4-morpholino)-1-propene

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

1-(4-isopropylphenyl)propan-2-one
7306-39-0

1-(4-isopropylphenyl)propan-2-one

Conditions
ConditionsYield
With aluminum oxide; potassium permanganate; neutral In acetone for 4h; Ambient temperature;A n/a
B 91%
morpholine
110-91-8

morpholine

formic acid ethyl ester
109-94-4

formic acid ethyl ester

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With Novozyme 435 CALB In tetrahydrofuran at 20℃; Green chemistry; Enzymatic reaction;91%
With o-toluenesulfonic acid at 55℃; for 4h;88%
With toluene-4-sulfonic acid at 60℃; for 24h;56%
at 65℃; for 12h; Inert atmosphere;
at 60℃; for 24h;
morpholine
110-91-8

morpholine

[((η5-C5H3)2(SiMe2)2)Ru2(μ-D)(CO)4]OSO2CF3

[((η5-C5H3)2(SiMe2)2)Ru2(μ-D)(CO)4]OSO2CF3

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

[(η5-C5H3)2(Si(CH3)2)2]Ru2(CO)4
287097-09-0

[(η5-C5H3)2(Si(CH3)2)2]Ru2(CO)4

C

[(η5-C5H3)2(SiMe2)2]Ru2(CO)3(morpholine)
287097-16-9

[(η5-C5H3)2(SiMe2)2]Ru2(CO)3(morpholine)

Conditions
ConditionsYield
With triphenylmethane In benzene-d6 Kinetics; amine was added to a soln. in C6D6 in NMR tube for 5 min (Ar); not sepd., detected by NMR spectra;A 91%
B 5%
C n/a
morpholine
110-91-8

morpholine

Hex-1-en-2-yl formate
134965-38-1

Hex-1-en-2-yl formate

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
In ethyl acetate for 1h; Ambient temperature;90%
4-(2-phenyl-propenyl)-morpholine
28478-27-5

4-(2-phenyl-propenyl)-morpholine

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

acetophenone
98-86-2

acetophenone

Conditions
ConditionsYield
With aluminum oxide; potassium permanganate; neutral In acetone for 4h; Ambient temperature;A n/a
B 90%
With aluminum oxide; potassium permanganate In acetone for 4h; Product distribution; Ambient temperature; reactions of derivatives, under var. conditions;A n/a
B 90%
4-[(1H-imidazol-1-yl)carbonyl]morpholine
93605-74-4

4-[(1H-imidazol-1-yl)carbonyl]morpholine

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With sodium tetrahydroborate In tetrahydrofuran; water at 20℃;90%
4-methyl-morpholine
109-02-4

4-methyl-morpholine

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With [2,2]bipyridinyl; C10H16NO; copper(II) bis(trifluoromethanesulfonate); copper(l) chloride In acetonitrile at 20℃; for 6h;90%
4-((trimethylsilyl)methyl)morpholine
54600-30-5

4-((trimethylsilyl)methyl)morpholine

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With copper(I) bromide In acetonitrile at 25℃; for 4h; chemoselective reaction;86%
4-(2-methyl-undec-1-enyl)-morpholine
28478-28-6

4-(2-methyl-undec-1-enyl)-morpholine

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

methyl nonyl ketone
112-12-9

methyl nonyl ketone

Conditions
ConditionsYield
With aluminum oxide; potassium permanganate; neutral In acetone for 4h; Ambient temperature;A n/a
B 84%
1-(4-morpholino)-2-phenylpropene
39166-22-8

1-(4-morpholino)-2-phenylpropene

A

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

B

acetophenone
98-86-2

acetophenone

Conditions
ConditionsYield
With oxygen; Cu-X zeolite In 1,2-dichloro-ethane; acetonitrile at 50℃; for 5h; Oxidation; Oxidative cleavage;A 70%
B 84%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

dimethyl sulfate
77-78-1

dimethyl sulfate

4-(Methoxymethylene)-morpholinium methyl sulfate
5780-15-4

4-(Methoxymethylene)-morpholinium methyl sulfate

Conditions
ConditionsYield
at 60 - 70℃; for 3h;100%
at 70℃; for 2h;
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

3-bromo-4,5-bis(trimethylsilylethynyl)toluene
350600-10-1

3-bromo-4,5-bis(trimethylsilylethynyl)toluene

2,3-bis(trimethylsilylethynyl)-5-methylbenzaldehyde
350600-11-2

2,3-bis(trimethylsilylethynyl)-5-methylbenzaldehyde

Conditions
ConditionsYield
With sec.-butyllithium In tetrahydrofuran; diethyl ether at -78℃;100%
2-(4-isopropoxyphenoxy)thiazole
929118-32-1

2-(4-isopropoxyphenoxy)thiazole

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

2-(4-isopropoxyphenoxy)thiazole-5-carbaldehyde
929118-34-3

2-(4-isopropoxyphenoxy)thiazole-5-carbaldehyde

Conditions
ConditionsYield
Stage #1: 2-(4-isopropoxyphenoxy)thiazole With n-butyllithium In tetrahydrofuran at -78℃; for 1.25h;
Stage #2: 4-morpholinecarboxaldehyde In tetrahydrofuran at -78℃; for 4h; Further stages.;
100%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

4-thioformylmorpholine
5780-30-3

4-thioformylmorpholine

Conditions
ConditionsYield
With Lawessons reagent In dichloromethane at 20℃; for 3h;99%
With tetraphosphorus decasulfide In diethyl ether at 0 - 20℃; for 3h;80%
With tetraphosphorus decasulfide78.9%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

toluene-4-sulfonamide
70-55-3

toluene-4-sulfonamide

(E)-4-methyl-N-(morpholinomethylene)benzenesulfonamide
15294-84-5

(E)-4-methyl-N-(morpholinomethylene)benzenesulfonamide

Conditions
ConditionsYield
With diazoacetic acid ethyl ester; zinc trifluoromethanesulfonate In cyclohexane for 12h; Reflux; stereoselective reaction;99%
With thionyl chloride In chloroform at 60℃; for 3h;87%
With tert.-butylhydroperoxide; sodium iodide In water at 90℃; for 3h;52%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

para-chlorotoluene
106-43-4

para-chlorotoluene

4-(4-methylphenyl)morpholine
3077-16-5

4-(4-methylphenyl)morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; potassium tert-butylate In tetrahydrofuran at 20℃; for 6h; Inert atmosphere;99%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

chlorobenzene
108-90-7

chlorobenzene

4-Phenylmorpholine
92-53-5

4-Phenylmorpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; potassium tert-butylate In tetrahydrofuran at 20℃; for 6h; Inert atmosphere;99%
With bis(1,5-cyclooctadiene)nickel (0); 7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium chloride; potassium tert-butylate In water; toluene at 35℃; for 10h; Glovebox; Sealed tube; Inert atmosphere;90%
3-Chloropyridine
626-60-8

3-Chloropyridine

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

N-(3-pyridyl)morpholine
92670-29-6

N-(3-pyridyl)morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; potassium tert-butylate In tetrahydrofuran at 20℃; for 6h; Inert atmosphere;99%
2-chloropyridine
109-09-1

2-chloropyridine

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

4-(pyridin-2-yl)morpholine
24255-25-2

4-(pyridin-2-yl)morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; potassium tert-butylate In tetrahydrofuran at 20℃; for 6h; Inert atmosphere;99%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

4-(3-methylbenzyl)morpholine
90754-64-6

4-(3-methylbenzyl)morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;99%
With potassium hydroxide In water at 50℃; for 3h; Green chemistry;80%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

4-(2-methylbenzyl)morpholine
51180-64-4

4-(2-methylbenzyl)morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;99%
With potassium hydroxide In water at 50℃; for 3h; Green chemistry;81%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

p-methoxybenzyl chloride
824-94-2

p-methoxybenzyl chloride

4-(4-methoxy-benzyl)-morpholine
17494-29-0

4-(4-methoxy-benzyl)-morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;99%
With potassium hydroxide In water at 80℃; for 3h; Temperature; Green chemistry;90%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

m-methoxybenzyl chloride
824-98-6

m-methoxybenzyl chloride

4-[(3-methoxyphenyl)methyl]morpholine
122439-14-9

4-[(3-methoxyphenyl)methyl]morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;99%
With potassium hydroxide In water at 50℃; for 3h; Green chemistry;90%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

2-cyanobenzyl chloride
612-13-5

2-cyanobenzyl chloride

2-(morpholin-4-ylmethyl)benzonitrile
37812-33-2

2-(morpholin-4-ylmethyl)benzonitrile

Conditions
ConditionsYield
With potassium hydroxide In water at 50℃; for 3h; Green chemistry;99%
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;98%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

m-tolyl aldehyde
620-23-5

m-tolyl aldehyde

(3-methylphenyl)-4-morpholinylmethanethione

(3-methylphenyl)-4-morpholinylmethanethione

Conditions
ConditionsYield
With sulfur; sodium carbonate; triethylamine In water at 120℃; for 12h; Inert atmosphere; Sealed tube;99%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

N-(4-methoxy-thiobenzoyl)-morpholine
6392-01-4

N-(4-methoxy-thiobenzoyl)-morpholine

Conditions
ConditionsYield
With sulfur; sodium carbonate; triethylamine In water at 120℃; for 12h; Schlenk technique; Inert atmosphere;99%
With sulfur; sodium carbonate; triethylamine In water at 120℃; for 12h; Inert atmosphere; Sealed tube;96%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

2-(2-chloro-4-methoxyphenoxy)-1,3-thiazole-5-carbaldehyde
946884-30-6

2-(2-chloro-4-methoxyphenoxy)-1,3-thiazole-5-carbaldehyde

Conditions
ConditionsYield
Stage #1: 2-(2-chloro-4-methoxyphenoxy)-1,3-thiazole With n-butyllithium In tetrahydrofuran; hexanes at -78℃; for 1.16667h;
Stage #2: 4-morpholinecarboxaldehyde In tetrahydrofuran; hexanes at -78 - 25℃; for 1.08333h; Product distribution / selectivity;
98%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

1-chloro-3-methoxy-benzene
2845-89-8

1-chloro-3-methoxy-benzene

4-(3-methoxyphenyl)morpholine
32040-09-8

4-(3-methoxyphenyl)morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; potassium tert-butylate In tetrahydrofuran at 20℃; for 6h; Inert atmosphere;98%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

1-chloro-3-methylbenzene
108-41-8

1-chloro-3-methylbenzene

4-m-tolylmorpholine
7025-91-4

4-m-tolylmorpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; potassium tert-butylate In tetrahydrofuran at 20℃; for 6h; Inert atmosphere;98%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

4-tert-butylbenzyl chloride
19692-45-6

4-tert-butylbenzyl chloride

4-(4-(tert-butyl)benzyl)morpholine

4-(4-(tert-butyl)benzyl)morpholine

Conditions
ConditionsYield
With potassium hydroxide In water at 100℃; for 3h; Temperature; Green chemistry;98%
With NHC-Pd(II)-Im; sodium hydroxide In water at 80℃; for 3h; Temperature; Inert atmosphere; Schlenk technique;94%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

4-cyanobenzyl chloride
874-86-2

4-cyanobenzyl chloride

4-(morpholin-4-ylmethyl)benzonitrile
37812-51-4

4-(morpholin-4-ylmethyl)benzonitrile

Conditions
ConditionsYield
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;98%
With potassium hydroxide In water at 50℃; for 3h; Green chemistry;92%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

4-nitrobenzyl chloride
100-14-1

4-nitrobenzyl chloride

4-(4-nitrobenzyl)morpholine
6425-46-3

4-(4-nitrobenzyl)morpholine

Conditions
ConditionsYield
With potassium hydroxide In water at 50℃; for 3h; Green chemistry;98%
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;97%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

1-Chloro-4-(chloromethyl)benzene
104-83-6

1-Chloro-4-(chloromethyl)benzene

4-(4'-chloro-benzyl)morpholine
6425-43-0

4-(4'-chloro-benzyl)morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;98%
With potassium hydroxide In water at 80℃; for 3h; Temperature; Green chemistry;93%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

1-chloro-2-(chloromethyl)benzene
611-19-8

1-chloro-2-(chloromethyl)benzene

2-(morpholinomethyl)chlorobenzene
415932-72-8

2-(morpholinomethyl)chlorobenzene

Conditions
ConditionsYield
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;98%
With potassium hydroxide In water at 50℃; for 3h; Green chemistry;96%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

1-Chloromethylnaphthalene
86-52-2

1-Chloromethylnaphthalene

4-(naphthalene-1-ylmethyl)morpholine
2862-82-0

4-(naphthalene-1-ylmethyl)morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;98%
With potassium hydroxide In water at 80℃; for 3h; Temperature; Green chemistry;87%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

4-Methylbenzyl chloride
104-82-5

4-Methylbenzyl chloride

4-(4-methylbenzyl)morpholine
46340-40-3

4-(4-methylbenzyl)morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;98%
With potassium hydroxide In water at 80℃; for 3h; Temperature; Green chemistry;96%
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