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Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualified

Factory Supply 3-Methylbenzyl chloride Supplier Manufacturer

Cas:620-19-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:1 Kilogram

FOB Price: $3.0

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3-Methylbenzyl Chloride supplier in China

Cas:620-19-9

Min.Order:1 Metric Ton

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Jinan Finer Chemical Co., Ltd

Product description: Product name 3-Methylbenzyl chloride CAS number 620-19-9 Assay ≥99% Appearance Colorless transparent to yellowish liquid Capacity 200mt/year Application

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Factory supply 3-Methylbenzyl chloride CAS 620-19-9 with fast delivery Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Fee

Factory supply 3-Methylbenzyl chloride CAS 620-19-9 with fast delivery

Cas:620-19-9

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-Methylbenzyl Chloride

Cas:620-19-9

Min.Order:1

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Type:Other

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EAST CHEMSOURCES LIMITED

Founded in 2008, East Chemsources Limited is a professional manufacturer and supplier in food and chemical field in China. Through more than ten years development, our company has developed from single product at first to provide solution to final

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:1 Metric Ton

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:1 Metric Ton

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Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 620-19-9 3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

3-Methylbenzyl chloride -- CHemwill

Cas:620-19-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

CHENGDU YANXI is a comprehensive manufacturer and an international distribution of products throughout the world. Specialized in Scrap metal, Chemical raw materials, Paper products and color industry. We aim to become leading position in global dis

medical intermediate 3-Methylbenzyl chloride CAS 620-19-9

Cas:620-19-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Product Name: 3-Methylbenzyl chloride Synonyms: M-XYLYL CHLORIDE;M-METHYL BENZYL CHLORIDE;1-Chloromethyl-3-methylbenzene;1-chloromethyl-3-methyl-benzene;3-(Chloromethyl)toluene;alpha-Chloro-meta-xylene;-Chloro-m-xylene;m-(Chloromethyl)

620-19-9 3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:1 Gram

FOB Price: $8900.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

3-Methylbenzyl Chloride CAS 620-19-9

Cas:620-19-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 620-19-9 with best quality

Cas:620-19-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name: 3-Methylbenzyl chloride Synonyms: 3-METHYLBENZYL CHLORIDE;ALPHA-CHLORO-M-XYLENE;AKOS BBS-00004023;A-CHLORO-M-XYLENE;MBC;Benzene, 1-(chloromethyl)-3-methyl-;à-chloro-m-xylene;3-Methylben

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

3-Methylbenzyl chloride 620-19-9

Cas:620-19-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

3-Methylbenzyl chloride CAS:620-19-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

3-Methylbenzyl chloride CAS:620-19-9

Cas:620-19-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:620-19-9

Cas:620-19-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3-Methylbenzyl Chloride

Cas:620-19-9

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:clear colorless to slightly yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request.

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 3-Methylbenzyl Chloride

Cas:620-19-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

3-Methylbenzyl chloride

Cas:620-19-9

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Synthetic route

m-tolyl aldehyde
620-23-5

m-tolyl aldehyde

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

Conditions
ConditionsYield
With chloro-trimethyl-silane; trimethylsilan In acetic acid methyl ester at 0℃; for 4h;80%
3-methylbenzyl Co(III)(dmgH)2py
36583-13-8

3-methylbenzyl Co(III)(dmgH)2py

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

Conditions
ConditionsYield
With chlorine In chloroform a solution of two equivalents of halogen added dropwise to a solution of organocobaloxime at room temperature under nitrogen in the dark; NMR, UV;75%
With chlorine In acetic acid a solution of two equivalents of halogen added dropwise to a solution of organocobaloxime at room temperature under nitrogen in the dark; NMR, UV;75%
m-xylene
108-38-3

m-xylene

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

Conditions
ConditionsYield
With N-chloro-succinimide In 1,2-dichloro-ethane at 80℃; regiospecific reaction;70%
With N-hydroxyphthalimide; carbon tetrabromide; trichloroisocyanuric acid; copper(II) acetate monohydrate In dichloromethane at 25℃; for 42h;33%
With N-chloro-succinimide; N-hydroxyphthalimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile at 80℃; for 16h; Time; Sealed tube; Inert atmosphere;26%
N-chloro-succinimide
128-09-6

N-chloro-succinimide

m-xylene
108-38-3

m-xylene

A

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

B

3-(chloromethyl)benzyl chloride
626-16-4

3-(chloromethyl)benzyl chloride

Conditions
ConditionsYield
Irradiation.UV-Licht;
3-methylbenzyl alcohol
587-03-1

3-methylbenzyl alcohol

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

Conditions
ConditionsYield
With hydrogenchloride at 60 - 70℃;
tetrachloromethane
56-23-5

tetrachloromethane

acetic acid-(2,4,6,N-tetrachloro-anilide)
27876-29-5

acetic acid-(2,4,6,N-tetrachloro-anilide)

m-xylene
108-38-3

m-xylene

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

3-Methylbenzoyl chloride
1711-06-4

3-Methylbenzoyl chloride

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

Conditions
ConditionsYield
With triethylsilane; zinc(II) chloride
3-methyl-benzylium
60154-94-1

3-methyl-benzylium

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

Conditions
ConditionsYield
With tertiary butyl chloride In gaseous matrix at 600℃; chloride affinity;
dichloro-phenyl-methylium
24154-22-1

dichloro-phenyl-methylium

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

Conditions
ConditionsYield
With tertiary butyl chloride In gaseous matrix at 600℃; chloride affinity;
3-methylbicyclo<4.1.0>hepta-1,3,5-triene
75366-05-1

3-methylbicyclo<4.1.0>hepta-1,3,5-triene

A

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

B

4-Methylbenzyl chloride
104-82-5

4-Methylbenzyl chloride

Conditions
ConditionsYield
With hydrogenchloride In tetrachloromethane for 1h; Yield given. Yields of byproduct given;
2-methyl-1H-cyclopropabenzene
75366-04-0

2-methyl-1H-cyclopropabenzene

A

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

B

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

Conditions
ConditionsYield
With hydrogenchloride In tetrachloromethane for 1h; Product distribution; Mechanism; reaction regioselectivity; a series of reagents;
m-xylene
108-38-3

m-xylene

A

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

B

3-(chloromethyl)benzyl chloride
626-16-4

3-(chloromethyl)benzyl chloride

C

m-chloromethylbenzylidene chloride
30220-25-8

m-chloromethylbenzylidene chloride

D

α,α-dichloro-m-xylene
2719-42-8

α,α-dichloro-m-xylene

E

α,α,α',α'-Tetrachloro-m-xylene
30430-40-1

α,α,α',α'-Tetrachloro-m-xylene

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); chlorine at 70℃; for 1.2h; Product distribution; various educt-reagent ratio, various time;
<(3-methylphenyl)methyl>trimethylsilane
38226-17-4

<(3-methylphenyl)methyl>trimethylsilane

oxovanadium(V) ethoxydichloride
1801-77-0

oxovanadium(V) ethoxydichloride

A

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

B

α-ethoxy-m-xylene
64988-09-6

α-ethoxy-m-xylene

Conditions
ConditionsYield
In acetonitrile Product distribution; -30 deg C, 2 h; RT, 4 h;
m-xylene
108-38-3

m-xylene

A

2,4-dimethylchlorobenzene
95-66-9

2,4-dimethylchlorobenzene

B

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

Conditions
ConditionsYield
With perchloric acid; trichloroisocyanuric acid In acetic acid at 35℃; Rate constant; Mechanism;
With perchloric acid; trichloroisocyanuric acid In acetic acid at 35℃;
3-(chloromethyl)benzyl chloride
626-16-4

3-(chloromethyl)benzyl chloride

A

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

B

1,2-di-m-tolylethane
4662-96-8

1,2-di-m-tolylethane

C

C16H17Cl

C16H17Cl

Conditions
ConditionsYield
With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In tetrahydrofuran; N,N-dimethyl-formamide Ambient temperature; n-Bu4NBF4, Hg pool cathode, SCE reference electrode;A 1 % Spectr.
B 43 % Spectr.
C 12 % Spectr.
chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

toluene
108-88-3

toluene

A

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

B

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

C

4-Methylbenzyl chloride
104-82-5

4-Methylbenzyl chloride

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane at 25℃; Rate constant; Mechanism;A 0.5 % Chromat.
B 31 % Chromat.
C 69 % Chromat.
chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

toluene
108-88-3

toluene

A

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

B

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

C

4-Methylbenzyl chloride
104-82-5

4-Methylbenzyl chloride

D

Methanol; compound with GENERIC INORGANIC NEUTRAL COMPONENT

Methanol; compound with GENERIC INORGANIC NEUTRAL COMPONENT

Conditions
ConditionsYield
With aluminium trichloride In nitromethane at 0℃; Product distribution; Mechanism;A 0.37 % Chromat.
B 31 % Chromat.
C 68 % Chromat.
D n/a
Methoxyacetyl chloride
38870-89-2

Methoxyacetyl chloride

toluene
108-88-3

toluene

A

carbon monoxide
201230-82-2

carbon monoxide

B

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

C

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

D

4-Methylbenzyl chloride
104-82-5

4-Methylbenzyl chloride

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane at 25℃; Rate constant;
Methoxyacetyl chloride
38870-89-2

Methoxyacetyl chloride

toluene
108-88-3

toluene

A

carbon monoxide
201230-82-2

carbon monoxide

B

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

C

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

D

4-Methylbenzyl chloride
104-82-5

4-Methylbenzyl chloride

E

Methanol; compound with GENERIC INORGANIC NEUTRAL COMPONENT

Methanol; compound with GENERIC INORGANIC NEUTRAL COMPONENT

Conditions
ConditionsYield
With aluminium trichloride In nitromethane at 0℃; for 0.555h; Product distribution; Rate constant; Mechanism; effects of various periods of time (up to 1072.5 min) and conc. of AlCl3;A n/a
B 0.52 % Chromat.
C 26.54 % Chromat.
D 73.22 % Chromat.
E n/a
4-(1-Chloro-2,2,2-trifluoro-ethyl)-1,2-dimethyl-benzene
191402-56-9

4-(1-Chloro-2,2,2-trifluoro-ethyl)-1,2-dimethyl-benzene

3-methyl-benzylium
60154-94-1

3-methyl-benzylium

A

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

B

C10H10F3(1+)
128408-29-7

C10H10F3(1+)

Conditions
ConditionsYield
at 69.85℃; Thermodynamic data; chloride-transfer;
chlorine
7782-50-5

chlorine

m-xylene
108-38-3

m-xylene

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

Conditions
ConditionsYield
Dampfphase.Irradiation;
Irradiation;
tetrachloromethane
56-23-5

tetrachloromethane

sulfuryl dichloride
7791-25-5

sulfuryl dichloride

m-xylene
108-38-3

m-xylene

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

hydrogenchloride
7647-01-0

hydrogenchloride

formaldehyd
50-00-0

formaldehyd

water
7732-18-5

water

toluene
108-88-3

toluene

A

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

B

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

C

4-Methylbenzyl chloride
104-82-5

4-Methylbenzyl chloride

m-Toluic acid
99-04-7

m-Toluic acid

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous-alcoholic sulfuric acid / bei der elektrolytischen Reduktion
2: hydrogen chloride / 60 - 70 °C
View Scheme
m-xylene
108-38-3

m-xylene

A

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

B

3-(chloromethyl)benzyl chloride
626-16-4

3-(chloromethyl)benzyl chloride

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); 1,3,4,6-tetrachloro-3α,6α-diphenyl glycoluril In tetrachloromethane at 81℃; for 2h; Inert atmosphere;A 52 %Chromat.
B 16 %Chromat.
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

triphenylphosphine
603-35-0

triphenylphosphine

(3-methylbenzyl)triphenylphosphonium chloride
63368-37-6

(3-methylbenzyl)triphenylphosphonium chloride

Conditions
ConditionsYield
In acetonitrile for 4.5h; Reflux;100%
In benzene
Yield given;
In 5,5-dimethyl-1,3-cyclohexadiene at 20℃; Reflux;28 g
In toluene at 20℃; Reflux;
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

(Z)-6-methoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one
1178094-73-9

(Z)-6-methoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one

(Z)-1-(3-methylbenzyl)-4-((6-methoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride
1250364-34-1

(Z)-1-(3-methylbenzyl)-4-((6-methoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride

Conditions
ConditionsYield
In acetonitrile Reflux;100%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

(Z)-6-ethoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one
1250364-18-1

(Z)-6-ethoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one

(Z)-1-(3-methylbenzyl)-4-((6-ethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride
1250364-49-8

(Z)-1-(3-methylbenzyl)-4-((6-ethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride

Conditions
ConditionsYield
In acetonitrile Reflux;100%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

(Z)-6-propoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one
1250364-19-2

(Z)-6-propoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one

(Z)-1-(3-methylbenzyl)-4-((6-propoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride
1250364-60-3

(Z)-1-(3-methylbenzyl)-4-((6-propoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride

Conditions
ConditionsYield
In acetonitrile Reflux;100%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

m-xylene
108-38-3

m-xylene

Conditions
ConditionsYield
With palladium dichloride In methanol at 40℃; for 1h; Green chemistry; chemoselective reaction;99%
With Perbenzoic acid; tri-n-butyl-tin hydride In benzene at 90℃; for 12h; Mechanism; in the presence of α-chlorotoluene (competitor), relative reactivity;
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

phenylboronic acid
98-80-6

phenylboronic acid

1-methyl-3-(phenylmethyl)-benzene
620-47-3

1-methyl-3-(phenylmethyl)-benzene

Conditions
ConditionsYield
With C58H82Cl4N6Pd2; potassium tert-butylate In water; isopropyl alcohol at 80℃; for 4h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;99%
With potassium phosphate; triphenylphosphine; palladium diacetate In toluene for 19h; Suzuki cross-coupling reaction;96%
With potassium phosphate; C114H132Cl6N10Pd3 In water; isopropyl alcohol at 80℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;96%
With potassium carbonate; N,N-dimethyl-formamide; palladium dichloride In water at 90℃; for 1h; Suzuki Coupling;90%
With potassium carbonate; sodium chloride; palladium dichloride; cucurbituril In ethanol; water at 90℃; for 1h; Suzuki Coupling; Inert atmosphere;76%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

tributyl(p-tolyl)stannane
31614-66-1

tributyl(p-tolyl)stannane

1-methyl-3-(4-methylbenzyl)benzene
21895-16-9

1-methyl-3-(4-methylbenzyl)benzene

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; potassium fluoride; palladium diacetate In 1,4-dioxane at 80℃; for 3h; Stille cross-coupling;99%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

4-(3-methylbenzyl)morpholine
90754-64-6

4-(3-methylbenzyl)morpholine

Conditions
ConditionsYield
With NHC-Pd(II)-Im; sodium hydroxide In water at 50℃; for 3h; Inert atmosphere; Schlenk technique;99%
With potassium hydroxide In water at 50℃; for 3h; Green chemistry;80%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

para-thiocresol
106-45-6

para-thiocresol

1-methyl-3-((p-tolylsulfinyl)methyl)benzene
1312161-87-7

1-methyl-3-((p-tolylsulfinyl)methyl)benzene

Conditions
ConditionsYield
With iodine pentoxide; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 90℃; for 6h;99%
With iodine pentoxide; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 100℃; for 6h;98%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

m-tolyl aldehyde
620-23-5

m-tolyl aldehyde

Conditions
ConditionsYield
With water; sodium hydroxide at 20℃; for 0.05h; Microwave irradiation;98%
With 4-methylmorpholine N-oxide; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride; potassium iodide at 100℃; for 0.0333333h; Microwave irradiation; Ionic liquid;90%
With 4-methylmorpholine N-oxide In tetrahydrofuran at 20℃; for 12h; Reflux;80%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

2-iodophenylamine
615-43-0

2-iodophenylamine

2-(m-tolyl)benzo[d]thiazole
1211-32-1

2-(m-tolyl)benzo[d]thiazole

Conditions
ConditionsYield
With copper(II) acetate monohydrate; sodium carbonate; sulfur In dimethyl sulfoxide at 130℃; for 24h; Schlenk technique; Inert atmosphere;98%
4-nitro-phenol
100-02-7

4-nitro-phenol

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

1-methyl-3-((4-nitrophenoxy)methyl)benzene

1-methyl-3-((4-nitrophenoxy)methyl)benzene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 24h;98%
1-Methylbenzimidazole
1632-83-3

1-Methylbenzimidazole

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

C16H17N2(1+)*Cl(1-)

C16H17N2(1+)*Cl(1-)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 95℃; for 4h; Inert atmosphere; Schlenk technique;97%
1-methyl-1H-imidazole
616-47-7

1-methyl-1H-imidazole

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

1-methyl-3-(3’-methylbenzyl)imidazolium chloride
958445-59-5

1-methyl-3-(3’-methylbenzyl)imidazolium chloride

Conditions
ConditionsYield
In acetonitrile for 48h; Inert atmosphere; Reflux;96%
In tetrahydrofuran at 69.84℃; for 48h;94%
In acetonitrile at 59.84℃; Kinetics; Mechanism; Solvent; Menshutkin reaction;
In toluene at 45 - 105℃; for 24.5h;
1H-imidazole
288-32-4

1H-imidazole

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

1-(3-methylbenzyl)-1H-imidazole

1-(3-methylbenzyl)-1H-imidazole

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 2h;96%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

2-Chloronitrobenzene
88-73-3

2-Chloronitrobenzene

2-(m-tolyl)benzo[d]thiazole
1211-32-1

2-(m-tolyl)benzo[d]thiazole

Conditions
ConditionsYield
With N-methylcyclohexylamine; sulfur at 110℃; for 24h; Sealed tube; Inert atmosphere;96%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

potassium thioacyanate
333-20-0

potassium thioacyanate

3-methylbenzyl thiocyanate
37141-50-7

3-methylbenzyl thiocyanate

Conditions
ConditionsYield
With silica gel at 30℃; for 48h;95%
With Fe3O4*SiO2/DABCO In water at 90℃; for 1.5h;85%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

2-chloroindole-3-carboxaldehyde
5059-30-3

2-chloroindole-3-carboxaldehyde

2-Chloro-1-(3-methyl-benzyl)-1H-indole-3-carbaldehyde
75621-55-5

2-Chloro-1-(3-methyl-benzyl)-1H-indole-3-carbaldehyde

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 60℃; for 6h;95%
With potassium carbonate In acetone at 20℃; for 2h;
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

phenyltriisopropoxytitanium(IV)
16635-23-7

phenyltriisopropoxytitanium(IV)

1-methyl-3-(phenylmethyl)-benzene
620-47-3

1-methyl-3-(phenylmethyl)-benzene

Conditions
ConditionsYield
With palladium diacetate; Tri(p-tolyl)phosphine In toluene at 25℃; for 2h; Inert atmosphere;95%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

(3-methyl-benzyl)-(4-methyl-benzyl)-sulfide

(3-methyl-benzyl)-(4-methyl-benzyl)-sulfide

Conditions
ConditionsYield
Stage #1: 4-Methylbenzyl bromide With thiourea In methanol Inert atmosphere; Reflux;
Stage #2: With sodium hydroxide In methanol Inert atmosphere; Reflux;
Stage #3: 1-chloromethyl-3-methyl-benzene In methanol at 20℃; Inert atmosphere; Reflux;
95%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

1-(azidomethyl)-3-methylbenzene
126799-82-4

1-(azidomethyl)-3-methylbenzene

Conditions
ConditionsYield
With sodium azide; potassium iodide In water; acetone at 20℃; for 60h; Inert atmosphere;95%
With sodium azide In water at 90℃; for 0.25h;88%
With sodium azide In water at 80℃; for 0.333333h; Green chemistry;82%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

potassium 2-cyano-2-methyl-propanoate
851233-80-2

potassium 2-cyano-2-methyl-propanoate

2,2-dimethyl-3-(m-tolyl)propanenitrile
1228309-98-5

2,2-dimethyl-3-(m-tolyl)propanenitrile

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; bis(η3-allyl-μ-chloropalladium(II)) In toluene at 110℃; for 12h; Inert atmosphere;95%
benzoxazole
273-53-0

benzoxazole

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

2-(3-methylbenzyl)benzo[d]oxazole

2-(3-methylbenzyl)benzo[d]oxazole

Conditions
ConditionsYield
With NHC-Pd(II)-Im; lithium tert-butoxide In toluene at 130℃; for 3h; Inert atmosphere; Sealed tube;95%
1-H-perimidine
204-02-4

1-H-perimidine

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

1-(3-methylbenzyl)perimidine

1-(3-methylbenzyl)perimidine

Conditions
ConditionsYield
Stage #1: 1-H-perimidine With potassium tert-butylate In dimethyl sulfoxide at 20℃; for 0.5h;
Stage #2: 1-chloromethyl-3-methyl-benzene In dimethyl sulfoxide at 110℃; for 0.5h; Microwave irradiation;
95%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

2-hydroxy-5-methylbenzaldehyde
613-84-3

2-hydroxy-5-methylbenzaldehyde

5-methyl-2-(3-methylbenzyloxy)benzaldehyde

5-methyl-2-(3-methylbenzyloxy)benzaldehyde

Conditions
ConditionsYield
With potassium carbonate In acetone for 6h; Reflux; Inert atmosphere;95%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

5,7-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidine-2-thiol
51646-17-4

5,7-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidine-2-thiol

5,7-dimethyl-2-(3-methyl-benzylsulfanyl)-[1,2,4]triazolo[1,5-a]pyrimidine
51646-24-3

5,7-dimethyl-2-(3-methyl-benzylsulfanyl)-[1,2,4]triazolo[1,5-a]pyrimidine

Conditions
ConditionsYield
With sodium hydroxide In methanol at 25℃;94%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

phenylacetylene
536-74-3

phenylacetylene

1‐(3‐methylbenzyl)‐4‐phenyl‐1H‐1,2,3‐triazole
126800-03-1

1‐(3‐methylbenzyl)‐4‐phenyl‐1H‐1,2,3‐triazole

Conditions
ConditionsYield
With sodium azide; sodium L-ascorbate In water; tert-butyl alcohol at 70℃; for 0.75h; Huisgen Cycloaddition; Green chemistry; regioselective reaction;94%
With sodium azide In water at 70℃; for 7h; Huisgen Cycloaddition; Green chemistry; regioselective reaction;91%
With sodium azide; sodium L-ascorbate In water at 70℃; for 3h;90%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

(E)-3,3'-dimethylstilbene
35286-92-1

(E)-3,3'-dimethylstilbene

Conditions
ConditionsYield
With Benzyl phenyl selenoxide; potassium hexamethylsilazane In toluene at 25℃; for 4h; Inert atmosphere;94%
With potassium phenyl selenide In 1,2-dimethoxyethane for 5h; Inert atmosphere; Sealed tube;84%
With sodium 4-methylbenzenesulfinate; potassium hydroxide In dimethyl sulfoxide at 100℃; for 16h;66%
1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

1-chloromethyl-2-methylbenzene
552-45-4

1-chloromethyl-2-methylbenzene

(2-methyl-benzyl)-(3-methyl-benzyl)-sulfide

(2-methyl-benzyl)-(3-methyl-benzyl)-sulfide

Conditions
ConditionsYield
Stage #1: 1-chloromethyl-3-methyl-benzene With thiourea In methanol Inert atmosphere; Reflux;
Stage #2: With sodium hydroxide In methanol Inert atmosphere; Reflux;
Stage #3: 1-chloromethyl-2-methylbenzene In methanol at 20℃; Inert atmosphere; Reflux;
94%
Diisopropylsilyl dichloride
7751-38-4

Diisopropylsilyl dichloride

1-chloromethyl-3-methyl-benzene
620-19-9

1-chloromethyl-3-methyl-benzene

diisopropyl(3-methylbenzyl)silanol
1361982-34-4

diisopropyl(3-methylbenzyl)silanol

Conditions
ConditionsYield
Stage #1: Diisopropylsilyl dichloride; 1-chloromethyl-3-methyl-benzene With iodine; magnesium In tetrahydrofuran at 20℃; for 1.5h; Inert atmosphere;
Stage #2: With water; sodium hydrogencarbonate In tetrahydrofuran; N,N-dimethyl-formamide at 0 - 20℃; for 0.5h; Inert atmosphere;
94%
Stage #1: 1-chloromethyl-3-methyl-benzene With magnesium In diethyl ether at 0℃; Reflux;
Stage #2: Diisopropylsilyl dichloride In tetrahydrofuran; diethyl ether at 0℃; for 12h; Reflux;
Stage #3: With triethylamine; sodium chloride In tetrahydrofuran; diethyl ether at 0 - 20℃; for 1h;
76%
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