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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Methylbenzyl bromide Manufacturer/High quality/Best price/In stock

Cas:104-81-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Methylbenzyl Bromide supplier in China

Cas:104-81-4

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

4-Methylbenzyl Bromide

Cas:104-81-4

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

p-Xylyl bromide

Cas:104-81-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

4-Methylbenzyl bromide 104-81-4 4-Methylbenzyl bromide Basic information Product Name: 4-Methylbenzyl bromide Synonyms: 1-(bromomethyl)-4-methyl-benzen;alpha-bromo-p-xylen;alpha-Bromo-

4-Methylbenzyl bromide 104-81-4

Cas:104-81-4

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

4-Methylbenzyl bromide 104-81-4

Cas:104-81-4

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 104-81-4 with best quality

Cas:104-81-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:White to light yellow powder Storage:2-8°C Package:25kg/drum Application:4-Methylbenzyl bromide is used as a pharmaceutical intermediate. Transportation:Express/Sea/Air Port:any port in china

4-Methylbenzyl bromide factory price

Cas:104-81-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White to off white powder Storage:Store in sealed containers

4-Methylbenzyl bromide 104-81-4

Cas:104-81-4

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-(bromomethyl)-4-methyl- 104-81-4

Cas:104-81-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

4-Methylbenzyl bromide CAS: 104-81-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

4-Methylbenzyl bromide CAS: 104-81-4

Cas:104-81-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-(bromomethyl)-4-methyl-

Cas:104-81-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,1-(bromomethyl)-4-methyl-

Cas:104-81-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

P-Methylbenzyl Bromide

Cas:104-81-4

Min.Order:0

Negotiable

Type:Manufacturers

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HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Specification : 4-Methylbenzyl bromide CAS No:10

4-Methylbenzyl bromide

Cas:104-81-4

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Methylbenzyl bromide

Cas:104-81-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

4-Methylbenzyl bromide

Cas:104-81-4

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzene,1-(bromomethyl)-4-methyl-

Cas:104-81-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

4-Methylbenzyl bromide

Cas:104-81-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply p-Methylbenzyl bromide;p-Xylyl bromide

Cas:104-81-4

Min.Order:0

Negotiable

Type:Other

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

4-Methylbenzyl bromide

Cas:104-81-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

4-Methylbenzyl bromide Basic information Product Name: 4-Methylbenzyl bromide Synonyms: 1-(bromomethyl)-4-methyl-benzen;alpha-bromo-p-xylen;alpha-Bromo-p-xylol;Benzene, 1-(bromomethyl)-4-methyl-;Benzene,1-(bromomethyl)-4-methyl-;-Bromo-p-xylene;omeg

4-Methylbenzyl bromide

Cas:104-81-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-Methylbenzyl bromide

Cas:104-81-4

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1-(bromomethyl)-4-methylbenzene

Cas:104-81-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

p-Methylbenzyl bromide

Cas:104-81-4

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

1-(BroMoMethyl)-4-Methylbenzene

Cas:104-81-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

p-Methylbenzyl bromide

Cas:104-81-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 4-Methylbenzyl bromide 100g

Cas:104-81-4

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

alpha-BroMo-p-xylene

Cas:104-81-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

4-Methylbenzyl Bromide

Cas:104-81-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

4-Methylbenzyl alcohol
589-18-4

4-Methylbenzyl alcohol

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With phosphorus tribromide In benzene at 20℃;100%
With phosphorus tribromide In dichloromethane at 0℃; for 1h;99%
With phosphorus tribromide In dichloromethane at 0℃; for 1h;99%
4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With polymethylhydrosiloxane; dimethylbromosulphonium bromide In chloroform at 20℃; for 4h;96%
With triethylsilane; trimethylsilyl bromide In acetic acid methyl ester at 20℃; for 1h;95%
With Dichloromethylsilane; phosphorus tribromide; iron(III) chloride In acetonitrile for 5h; Heating;90%
para-xylene
106-42-3

para-xylene

A

1,4-bis(bromomethyl)benzene
623-24-5

1,4-bis(bromomethyl)benzene

B

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With sodium bromate; sodium hydrogensulfite In water; ethyl acetate at 20℃; for 4h; Bromination;A 70%
B 6%
With N-Bromosuccinimide In water at 25℃; for 22h; Wohl-Ziegler bromination;A 3%
B 66%
With hydrogen bromide; dihydrogen peroxide In water at 20℃; Irradiation;A 10%
B 62%
para-xylene
106-42-3

para-xylene

A

4-bromo-m-xylene
553-94-6

4-bromo-m-xylene

B

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With sodium bromate; sodium hydrogensulfite In water; acetonitrile at 20℃; for 4h; Bromination;A 62%
B n/a
With bromine; bentonite In carbon disulfide for 4h; Heating;A 50%
B 30%
With N-Bromosuccinimide In methanol at 150℃; under 2625.26 Torr; for 0.0666667h; microwave irradiation;A 27 % Chromat.
B 32 % Chromat.
With hydrogen bromide; dihydrogen peroxide In water at 20℃; for 24h; Darkness;A 66 %Spectr.
B 14 %Spectr.
With N-Bromosuccinimide; silver hexafluoroantimonate; adamantan-1-yl(methyl)sulfane In 1,2-dichloro-ethane at 20℃; for 1h; Inert atmosphere; Schlenk technique;A 50 %Chromat.
B 20 %Chromat.
para-xylene
106-42-3

para-xylene

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With bromine In tetrachloromethane Solvent;100%
With 2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one; silica gel for 4.5h; UV-irradiation;84%
With bromine In tetrachloromethane for 1.5h; Ambient temperature;83%
4-tolylacetic acid
622-47-9

4-tolylacetic acid

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With Ag(Phen)2OTf; dibromoisocyanuric acid In 1,2-dichloro-ethane at 20℃; for 1h; Inert atmosphere; Schlenk technique;80%
diethyl 2,6-dimethyl-4-(4-methylbenzyl)-1,4-dihydropyridine-3,5-dicarboxylate

diethyl 2,6-dimethyl-4-(4-methylbenzyl)-1,4-dihydropyridine-3,5-dicarboxylate

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With dipotassium peroxodisulfate; tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate; sodium bromide In water; acetonitrile at 20℃; for 24h; Sealed tube; Inert atmosphere; Irradiation; regioselective reaction;82%
4-methylbenzaldehyde dimethylacetal
3395-83-3

4-methylbenzaldehyde dimethylacetal

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With triethylsilane; Acetyl bromide; tin(II) bromide In dichloromethane for 3h; Ambient temperature;86%
toluene
108-88-3

toluene

1,2-dibromomethane
74-95-3

1,2-dibromomethane

A

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

B

2-methylbenzyl bromide
89-92-9

2-methylbenzyl bromide

Conditions
ConditionsYield
Stage #1: toluene With sodium hydride In N,N-dimethyl-formamide at 20℃;
Stage #2: 1,2-dibromomethane In N,N-dimethyl-formamide at 60℃; for 2h;
4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

A

m-hydroxybenzyl bromide
74597-04-9

m-hydroxybenzyl bromide

B

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With chloro-trimethyl-silane; 1,1,3,3-Tetramethyldisiloxane; lithium bromide In acetonitrile at 80℃; for 0.333333h;A 77 % Spectr.
B 97%
1-(4-Methyl-benzyl)-2,4,6-triphenyl-pyridinium; bromide
71017-67-9

1-(4-Methyl-benzyl)-2,4,6-triphenyl-pyridinium; bromide

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With 2,4,6-triphenylpyridine at 180 - 220℃; under 0.5 - 2 Torr;80%
1-(4-Methyl-benzyl)-2,3,4,5,6-pentaphenyl-pyridinium; bromide
76192-19-3

1-(4-Methyl-benzyl)-2,3,4,5,6-pentaphenyl-pyridinium; bromide

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With 2,4,6-triphenylpyridine at 180 - 220℃; under 0.5 - 2 Torr;74%
4-(4-Chloro-phenyl)-1-(4-methyl-benzyl)-2,3,5,6-tetraphenyl-pyridinium; bromide
76192-16-0

4-(4-Chloro-phenyl)-1-(4-methyl-benzyl)-2,3,5,6-tetraphenyl-pyridinium; bromide

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With 2,4,6-triphenylpyridine at 180 - 220℃; under 0.5 - 1.5 Torr;72%
formaldehyd
50-00-0

formaldehyd

toluene
108-88-3

toluene

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With hydrogen bromide In acetic acid for 7h; bromomethylation; Irradiation;87%
With sulfuric acid; acetic acid; sodium bromide
4-methyl-1-(methoxymethoxy)methyl benzene
92565-77-0

4-methyl-1-(methoxymethoxy)methyl benzene

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.075h; Microwave irradiation; Neat (no solvent); chemoselective reaction;83%
4-methyl-1-(ethoxymethoxy)methyl benzene
93306-62-8

4-methyl-1-(ethoxymethoxy)methyl benzene

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.075h; Microwave irradiation; Neat (no solvent); chemoselective reaction;84%
p-Toluic acid
99-94-5

p-Toluic acid

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: dimethyl sulfate; acetone; potassium carbonate / 4 h / Reflux
1.2: 0 - 20 °C
2.1: phosphorus tribromide / dichloromethane / 0 - 20 °C
View Scheme
Multi-step reaction with 3 steps
1: potassium carbonate / acetone / Reflux
2: lithium aluminium tetrahydride / tetrahydrofuran / 4 h / 20 °C / Inert atmosphere; Cooling with ice
3: phosphorus tribromide / dichloromethane / 4 h / Cooling with ice; Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1: potassium carbonate / acetone / Reflux
2: lithium aluminium tetrahydride / tetrahydrofuran / 0 - 20 °C
3: phosphorus tribromide / dichloromethane / 0 - 20 °C
View Scheme
Multi-step reaction with 3 steps
1: potassium carbonate / acetone / 4 h / Reflux
2: lithium aluminium tetrahydride / tetrahydrofuran / 4 h / 20 °C / Inert atmosphere
3: phosphorus tribromide / dichloromethane / 4 h / Inert atmosphere; Cooling with ice
View Scheme
Multi-step reaction with 2 steps
1: lithium aluminium tetrahydride / tetrahydrofuran / 26 h / 0 °C / Reflux
2: phosphorus tribromide / diethyl ether / 24 h / 0 - 20 °C
View Scheme
4-methyl-benzoic acid methyl ester
99-75-2

4-methyl-benzoic acid methyl ester

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: lithium aluminium tetrahydride / tetrahydrofuran / 4 h / 20 °C / Inert atmosphere; Cooling with ice
2: phosphorus tribromide / dichloromethane / 4 h / Cooling with ice; Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: lithium aluminium tetrahydride / tetrahydrofuran / 0 - 20 °C
2: phosphorus tribromide / dichloromethane / 0 - 20 °C
View Scheme
Multi-step reaction with 2 steps
1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / 0 °C
2: phosphorus tribromide / dichloromethane / 1 h / 0 °C
View Scheme
Multi-step reaction with 2 steps
1: lithium aluminium tetrahydride / tetrahydrofuran / 4 h / 20 °C / Inert atmosphere
2: phosphorus tribromide / dichloromethane / 4 h / Inert atmosphere; Cooling with ice
View Scheme
para-xylene
106-42-3

para-xylene

A

4-bromo-m-xylene
553-94-6

4-bromo-m-xylene

B

2,5-dibromo-p-xylene
1074-24-4

2,5-dibromo-p-xylene

C

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With bromine; acetic acidA 77%
B 10%
C 13%
With bromineA 48%
B n/a
C n/a
Bromotrichloromethane
75-62-7

Bromotrichloromethane

<4-MeC6H4CH2Co(dmgH)2Py>

<4-MeC6H4CH2Co(dmgH)2Py>

A

1-(2,2,2-trichloroethyl)-4-methylbenzene
2201-10-7

1-(2,2,2-trichloroethyl)-4-methylbenzene

B

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With 1H-imidazole In chloroform at 70℃; for 1h; Title compound not separated from byproducts;
methanol
67-56-1

methanol

para-xylene
106-42-3

para-xylene

A

4-methylbenzyl methyl ether
3395-88-8

4-methylbenzyl methyl ether

B

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With sodium periodate; sulfuric acid; lithium bromide at 65℃; for 24h;A 30%
B 45%
2-(1-ethynyl-cyclohexyloxy)-tetrahydro-pyran
42969-66-4

2-(1-ethynyl-cyclohexyloxy)-tetrahydro-pyran

4-Methylbenzyl alcohol
589-18-4

4-Methylbenzyl alcohol

A

2-((4-methylbenzyl)oxy)tetrahydro-2H-pyran
18484-04-3

2-((4-methylbenzyl)oxy)tetrahydro-2H-pyran

B

1-Ethynyl-1-cyclohexanol
78-27-3

1-Ethynyl-1-cyclohexanol

C

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With gold(III) tribromide In acetonitrile at 25℃; for 12h;
4-methylbenzyl iodide
4484-74-6

4-methylbenzyl iodide

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With pyridine; tributyltin bromide at 50℃; Thermodynamic data; Δ G;
1-(4-Methyl-benzyl)-2-(2-oxo-2-phenyl-ethylsulfanyl)-4,6-diphenyl-pyridinium; bromide
96928-04-0

1-(4-Methyl-benzyl)-2-(2-oxo-2-phenyl-ethylsulfanyl)-4,6-diphenyl-pyridinium; bromide

A

4,6-diphenyl-2-phenacylthiopyridine
96938-17-9

4,6-diphenyl-2-phenacylthiopyridine

B

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
at 160℃; under 1 Torr;
2-[2-(4-Bromo-phenyl)-2-oxo-ethylsulfanyl]-1-(4-methyl-benzyl)-4,6-diphenyl-pyridinium; bromide
96928-05-1

2-[2-(4-Bromo-phenyl)-2-oxo-ethylsulfanyl]-1-(4-methyl-benzyl)-4,6-diphenyl-pyridinium; bromide

A

1-(4-Bromo-phenyl)-2-(4,6-diphenyl-pyridin-2-ylsulfanyl)-ethanone

1-(4-Bromo-phenyl)-2-(4,6-diphenyl-pyridin-2-ylsulfanyl)-ethanone

B

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
at 160℃; under 1 Torr;
4-Methylbenzyl chloride
104-82-5

4-Methylbenzyl chloride

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
With pyridine; tributyltin bromide at 50℃; Thermodynamic data; Equilibrium constant; Δ G;
para-xylene
106-42-3

para-xylene

A

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

B

p-xylylidene dibromide

p-xylylidene dibromide

Conditions
ConditionsYield
With bromine at 130℃; man trennt durch Destillation;
para-methylbenzylamine
104-84-7

para-methylbenzylamine

higher-melting α.α'-dibromo-pimelic acid diethyl ester

higher-melting α.α'-dibromo-pimelic acid diethyl ester

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 74 percent / CH2Cl2 / 6 h / 25 °C
2: 80 percent / 2,4,6-triphenylpyridine / 180 - 220 °C / 0.5 - 2 Torr
View Scheme
2-Benzylselanyl-cyclopent-2-enone
116279-45-9

2-Benzylselanyl-cyclopent-2-enone

A

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

(2R,3S)-2-Benzylselanyl-3-methyl-2-(4-methyl-benzyl)-cyclopentanone
116279-47-1

(2R,3S)-2-Benzylselanyl-3-methyl-2-(4-methyl-benzyl)-cyclopentanone

Conditions
ConditionsYield
With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium dimethylcuprate 1.) THF, -78 deg C, 40 min, 2.) RT, 17 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
1-(4-Methyl-benzyl)-4,6-diphenyl-1H-pyridine-2-thione
76950-85-1

1-(4-Methyl-benzyl)-4,6-diphenyl-1H-pyridine-2-thione

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 92 percent / benzene / 5 h / Ambient temperature
2: 160 °C / 1 Torr
View Scheme
Multi-step reaction with 4 steps
1: 94 percent / benzene / 5 h / Ambient temperature
2: methanol / 2 h / Heating
3: 92 percent / benzene / 5 h / Ambient temperature
4: 160 °C / 1 Torr
View Scheme
Multi-step reaction with 2 steps
1: 94 percent / benzene / 5 h / Ambient temperature
2: 160 °C / 1 Torr
View Scheme
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

trimethylamine
75-50-3

trimethylamine

(4-methylbenzyl)trimethylammonium bromide
16814-21-4

(4-methylbenzyl)trimethylammonium bromide

Conditions
ConditionsYield
In diethyl ether at 0 - 20℃;100%
In tetrahydrofuran; ethanol at 25℃; for 24h; Inert atmosphere;99%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

1,2-di-p-tolylethane
538-39-6

1,2-di-p-tolylethane

Conditions
ConditionsYield
With tetrabutylammomium bromide; urea; potassium hydroxide Electrolysis; Inert atmosphere;100%
With Wilkinson's catalyst; dimethyl zinc(II) In tetrahydrofuran; hexane at 20℃; for 1h;97%
With N,N,N,N,N,N-hexamethylphosphoric triamide; samarium; nickel dichloride In tetrahydrofuran for 8h; Inert atmosphere; Reflux;96%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

4-methylphenylmethylazide
17271-89-5

4-methylphenylmethylazide

Conditions
ConditionsYield
With sodium azide In dimethyl sulfoxide at 80℃;100%
With sodium azide In dimethyl sulfoxide at 80℃;100%
With sodium azide In N,N-dimethyl-formamide at 65℃; for 4h;99%
tri-n-propyl borate
688-71-1

tri-n-propyl borate

carbon monoxide
201230-82-2

carbon monoxide

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

p-Tolyl-acetic acid propyl ester
93578-98-4

p-Tolyl-acetic acid propyl ester

Conditions
ConditionsYield
1,5-hexadienerhodium(I)-chloride dimer at 75℃; under 760 Torr; Heating; overnight; other solvent;100%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

triethyl phosphite
122-52-1

triethyl phosphite

diethyl 4-methylbenzylphosphonate
3762-25-2

diethyl 4-methylbenzylphosphonate

Conditions
ConditionsYield
at 140℃;100%
for 20h; Reflux; Inert atmosphere;94%
at 200℃; for 1h;82%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

2-(4-fluoro-benzenesulfonylamino)-3-methyl-butyric acid tert-butyl ester
245364-65-2

2-(4-fluoro-benzenesulfonylamino)-3-methyl-butyric acid tert-butyl ester

2-[(4-fluoro-benzenesulfonyl)-(4-methyl-benzyl)-amino]-3-methyl-butyric acid tert-butyl ester
245364-85-6

2-[(4-fluoro-benzenesulfonyl)-(4-methyl-benzyl)-amino]-3-methyl-butyric acid tert-butyl ester

Conditions
ConditionsYield
With polystyrene-bound 2-tert-butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine In dichloromethane100%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

(3-trifluoromethyl-benzenesulfonylamino)-acetic acid tert-butyl ester
245364-63-0

(3-trifluoromethyl-benzenesulfonylamino)-acetic acid tert-butyl ester

[(4-methyl-benzyl)-(3-trifluoromethyl-benzenesulfonyl)-amino]-acetic acid tert-butyl ester
245364-75-4

[(4-methyl-benzyl)-(3-trifluoromethyl-benzenesulfonyl)-amino]-acetic acid tert-butyl ester

Conditions
ConditionsYield
With polystyrene-bound 2-tert-butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine In dichloromethane100%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

3-methyl-2-(3-trifluoromethyl-benzenesulfonylamino)-butyric acid tert-butyl ester
245364-64-1

3-methyl-2-(3-trifluoromethyl-benzenesulfonylamino)-butyric acid tert-butyl ester

3-methyl-2-[(4-methyl-benzyl)-(3-trifluoromethyl-benzenesulfonyl)-amino]-butyric acid tert-butyl ester
245364-84-5

3-methyl-2-[(4-methyl-benzyl)-(3-trifluoromethyl-benzenesulfonyl)-amino]-butyric acid tert-butyl ester

Conditions
ConditionsYield
With polystyrene-bound 2-tert-butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine In dichloromethane100%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

2-(4-fluoro-benzenesulfonylamino)-3-phenyl-propionic acid tert-butyl ester
245364-67-4

2-(4-fluoro-benzenesulfonylamino)-3-phenyl-propionic acid tert-butyl ester

2-[(4-fluoro-benzenesulfonyl)-(4-methyl-benzyl)-amino]-3-phenyl-propionic acid tert-butyl ester
245364-96-9

2-[(4-fluoro-benzenesulfonyl)-(4-methyl-benzyl)-amino]-3-phenyl-propionic acid tert-butyl ester

Conditions
ConditionsYield
With polystyrene-bound 2-tert-butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine In dichloromethane100%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

3-phenyl-2-(3-trifluoromethyl-benzenesulfonylamino)-propionic acid tert-butyl ester
245364-66-3

3-phenyl-2-(3-trifluoromethyl-benzenesulfonylamino)-propionic acid tert-butyl ester

2-[(4-methyl-benzyl)-(3-trifluoromethyl-benzenesulfonyl)-amino]-3-phenyl-propionic acid tert-butyl ester
245364-95-8

2-[(4-methyl-benzyl)-(3-trifluoromethyl-benzenesulfonyl)-amino]-3-phenyl-propionic acid tert-butyl ester

Conditions
ConditionsYield
With polystyrene-bound 2-tert-butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine In dichloromethane100%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

C20H17NO3S2
433211-61-1

C20H17NO3S2

1-[5-benzoyl-4-ethoxycarbonylmethyl-2-(4-methyl-benzylsulfanyl)-thiophen-3-yl]-pyridinium; bromide

1-[5-benzoyl-4-ethoxycarbonylmethyl-2-(4-methyl-benzylsulfanyl)-thiophen-3-yl]-pyridinium; bromide

Conditions
ConditionsYield
100%
In chloroform at 20℃;
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

C21H19NO3S2
433211-65-5

C21H19NO3S2

1-[5-benzoyl-4-ethoxycarbonylmethyl-2-(4-methyl-benzylsulfanyl)-thiophen-3-yl]-4-methyl-pyridinium; bromide

1-[5-benzoyl-4-ethoxycarbonylmethyl-2-(4-methyl-benzylsulfanyl)-thiophen-3-yl]-4-methyl-pyridinium; bromide

Conditions
ConditionsYield
100%
In chloroform at 20℃;
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

(1S)-2-benzyl-1-methyl-1,3,4,6-tetrahydro-2H-pyrazino[2,1-b]quinazoline-3,6-dione
427888-22-0

(1S)-2-benzyl-1-methyl-1,3,4,6-tetrahydro-2H-pyrazino[2,1-b]quinazoline-3,6-dione

(1S)-2-benzyl-1-methyl-4,4-bis(4-methylbenzyl)-1,3,4,6-tetrahydro-2H-pyrazino[2,1-b]quinazoline-3,6-dione

(1S)-2-benzyl-1-methyl-4,4-bis(4-methylbenzyl)-1,3,4,6-tetrahydro-2H-pyrazino[2,1-b]quinazoline-3,6-dione

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran at -78 - 0℃; for 0.383333h;100%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

(1R)-7,7-dimethyl-1-[(3S)-2-thiabicyclo[2.2.1]hept-3-yl]bicyclo[2.2.1]heptan-2-one
352207-48-8

(1R)-7,7-dimethyl-1-[(3S)-2-thiabicyclo[2.2.1]hept-3-yl]bicyclo[2.2.1]heptan-2-one

(1S,3S,4R)-2-(4-methylphenylmethyl)-3-[(1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-2-thioniabicyclo[2.2.1]heptane tetrafluoroborate

(1S,3S,4R)-2-(4-methylphenylmethyl)-3-[(1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-2-thioniabicyclo[2.2.1]heptane tetrafluoroborate

Conditions
ConditionsYield
With silver tetrafluoroborate In dichloromethane at 20℃; for 48h;100%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

methyl p-tolylacetate
23786-13-2

methyl p-tolylacetate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; C44H39IOP2Pd; triphenylphosphine at 60℃; for 2h; Conversion of starting material;100%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

4-nitro-aniline
100-01-6

4-nitro-aniline

bis(4-methylbenzyl)(4-nitrophenyl)amine
1032373-70-8

bis(4-methylbenzyl)(4-nitrophenyl)amine

Conditions
ConditionsYield
With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 100℃; for 24h; Inert atmosphere;100%
thiophenol
108-98-5

thiophenol

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

4-methylbenzyl phenyl sulfide
5023-65-4

4-methylbenzyl phenyl sulfide

Conditions
ConditionsYield
With potassium carbonate In acetone for 24h; Reflux; Inert atmosphere;100%
With silica gel In water at 20℃; for 1h;92%
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 5h;92%
With potassium carbonate
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

methyl 2-cyanoacetate
105-34-0

methyl 2-cyanoacetate

cyano-di(4-methyl-benzyl)acetic acid methyl ester
1202778-97-9

cyano-di(4-methyl-benzyl)acetic acid methyl ester

Conditions
ConditionsYield
Stage #1: methyl 2-cyanoacetate With sodium methylate In methanol at 20℃;
Stage #2: 4-Methylbenzyl bromide In methanol Reflux;
100%
tert-butyl (3-perfluorooctyl)propoxycarbamate
1228692-98-5

tert-butyl (3-perfluorooctyl)propoxycarbamate

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

C24H24F17NO3
1228693-02-4

C24H24F17NO3

Conditions
ConditionsYield
With caesium carbonate In acetonitrile at 45℃; for 2h;100%
N-methyl-N-[4-(diphenylphosphino)benzyl]pyrrolidinium bromide
1229444-44-3

N-methyl-N-[4-(diphenylphosphino)benzyl]pyrrolidinium bromide

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

2Br(1-)*C32H36NP(2+)

2Br(1-)*C32H36NP(2+)

Conditions
ConditionsYield
In dichloromethane at 0 - 40℃; for 24h; Inert atmosphere;100%
1-hydroxy-3,6,7-tris(methoxymethoxy)-9H-xanthen-9-one
1314917-55-9

1-hydroxy-3,6,7-tris(methoxymethoxy)-9H-xanthen-9-one

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

C27H28O9
1314917-78-6

C27H28O9

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 6h;100%
tert-butyl 4-(2-perfluoroctylethyl)benzyloxycarbamate
1313585-45-3

tert-butyl 4-(2-perfluoroctylethyl)benzyloxycarbamate

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

tert-butyl (4-methylbenzyl)(4-(2-perfluoroctylethyl)benzyloxy)carbamate
1313585-50-0

tert-butyl (4-methylbenzyl)(4-(2-perfluoroctylethyl)benzyloxy)carbamate

Conditions
ConditionsYield
With caesium carbonate In acetonitrile at 45℃; for 3h;100%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

phenylacetylene
536-74-3

phenylacetylene

1-(4-methylbenzyl)-4-phenyl-1H-1,2,3-triazole
126800-02-0

1-(4-methylbenzyl)-4-phenyl-1H-1,2,3-triazole

Conditions
ConditionsYield
With sodium azide; C31H38ClCuN2 In water at 20℃; for 2h; Reagent/catalyst; Huisgen Cycloaddition;100%
With sodium azide; sodium ascorbate In water; tert-butyl alcohol at 50℃; for 2.5h;98%
With sodium azide; C46H64CuN2O8Si2 In water at 25℃; for 1h; Reagent/catalyst;98%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

malononitrile
109-77-3

malononitrile

2,2-Bis-(4-methyl-benzyl)-malononitrile

2,2-Bis-(4-methyl-benzyl)-malononitrile

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 80℃; for 2h; Inert atmosphere;100%
6-hydroxy-7-methoxy-2-methylisoquinolin-1(2H)-one
1043429-41-9

6-hydroxy-7-methoxy-2-methylisoquinolin-1(2H)-one

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

7-methoxy-2-methyl-6-(4-methylbenzyloxy)-isoquinolin-1(2H)-one

7-methoxy-2-methyl-6-(4-methylbenzyloxy)-isoquinolin-1(2H)-one

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃;100%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol
269409-70-3

4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol

C20H25BO3

C20H25BO3

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 20℃; for 18h;100%
2-fluoro-4-hydroxybenzonitrile
82380-18-5

2-fluoro-4-hydroxybenzonitrile

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

2-fluoro-4-[(4-methylphenyl)methoxy]benzonitrile

2-fluoro-4-[(4-methylphenyl)methoxy]benzonitrile

Conditions
ConditionsYield
With caesium carbonate In acetonitrile at 100℃; for 1.5h; Sealed tube; Inert atmosphere;100%
methyl 3-chloro-1H-indole-4-carboxylate

methyl 3-chloro-1H-indole-4-carboxylate

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

C18H16ClNO2

C18H16ClNO2

Conditions
ConditionsYield
With sodium hydride at 0℃; for 5h;100%

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