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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

m-Toluic acid Manufacturer/High quality/Best price/In stock

Cas:99-04-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality M-Methylbenzoate supplier in China

Cas:99-04-7

Min.Order:1 Metric Ton

Negotiable

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Jinan Finer Chemical Co., Ltd

Product description: Product name m-Toluic acid CAS number 99-04-7 Assay ≥99% Appearance White crystalline powder Capacity 500mt/year Application Pesticides/pharmaceutical in

m-Toluic acid

Cas:99-04-7

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Hefei TNJ chemical industry co.,ltd

m-Toluic acid 99-04-7 CAS Registry Number 99-04-7 EINECS 202-723-9 m-Toluic acid Appearance:white powder Storage:Warehouse ventilation, away from open flame, high temperature, and antioxidant Package:25kg/bag or 25kg/drum Application:Mainly

m-Toluic acid

Cas:99-04-7

Min.Order:3 Metric Ton

Negotiable

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

vhe company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:White o

m-Toluic acid

Cas:99-04-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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EAST CHEMSOURCES LIMITED

m-Toluic acid Molecular Formula: C8H8O2 Molecular Weight: 136.15 Density: 1.054g/ml at 25º(lit.) refractive index: 1.509 Appearance:

m-Toluic acid

Cas:99-04-7

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply m-toluic acid

Cas:99-04-7

Min.Order:1

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Type:Other

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

m-Toluic acid

Cas:99-04-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

3-Methylbenzoic acid

Cas:99-04-7

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

m-Toluic acid

Cas:99-04-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Leader Biochemical Group

About Product Technical Details m-Toluic acid Chemical Properties Melting point 107-113 °C (lit.) Boiling point 263 °C (lit.) density 1.054 g/mL at 25 °C (lit.)

China Largest factory Manufacturer Supply M-TOLUIC ACID CAS 99-04-7

Cas:99-04-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Product Name: m-Toluic acid Synonyms: METHYLBENZOIC(M-) ACID;beta-methylbenzoic acid;3-TOLUIC ACID;3-METHYLBENZOIC ACID;RARECHEM AL BO 0048;M-TOLUIC ACID;M-TOLUYLIC ACID;M-METHYLBENZOIC ACID CAS: 99-04-7 MF: C8H8O2 MW: 136.15 EINECS: 202-723-9

99-04-7 m-Toluic acid

Cas:99-04-7

Min.Order:1 Kilogram

FOB Price: $300.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

m-Toluic acid

Cas:99-04-7

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Best Purity CAS 99-04-7 with best price

Cas:99-04-7

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product m-Toluic acid CAS 99-04-7 Molecular formula C8H8O2 Molecular weight 136.15 EINECS No. 202-723-9

m-Toluic acid CAS:99-04-7

Cas:99-04-7

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

m-Toluic acid 99-04-7

Cas:99-04-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

m-Toluic acid CAS:99-04-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediat

m-Toluic acid CAS:99-04-7

Cas:99-04-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

m-Toluic acid

Cas:99-04-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:99-04-7

Cas:99-04-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in lead acetate, diphenyl ethylamine and other chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countrie

factory direct sale M-methyl-benzoic acid

Cas:99-04-7

Min.Order:1 Kilogram

FOB Price: $25.0

Type:Trading Company

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

m-Toluic acid

Cas:99-04-7

Min.Order:1 Kilogram

FOB Price: $6.0 / 10.0

Type:Lab/Research institutions

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Guangdong Juda Chemical Industrial Co.,Limited

1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France etc. 3) OEM/ODM Available;

3-methylbenzoate METHYLBENZOIC m-Toluic acid with low price CAS 99-04-7

Cas:99-04-7

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

M-Toluic acid CAS NO.99-04-7

Cas:99-04-7

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

M-Toluic Acid

Cas:99-04-7

Min.Order:0

Negotiable

Type:Manufacturers

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

m-Toluic acid Pesticide CAS. NO.99-04-7

Cas:99-04-7

Min.Order:10 Kilogram

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Type:Trading Company

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Triumph International Development Limilted

Appearance:white powder/crystal Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common products:Sea/Ai

m-Toluic acid 99-04-7

Cas:99-04-7

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

Lonwin Industry group limited as a professional manufactor & exporter of chemical materials ,we totally haver more than 270 stuffs, we have been on this line for more than 9 years. Our chemical materials are exported to lot of countries and regio

m-Toluic acid CAS 99-04-7 METHYLBENZOIC C8H8O2

Cas:99-04-7

Min.Order:3 Kilogram

FOB Price: $1800.0 / 5000.0

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

m-Toluic acid

Cas:99-04-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

m-Toluic acid

Cas:99-04-7

Min.Order:1 Gram

Negotiable

Type:Other

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Wuhan Xinhao Biotechnology Co., Ltd.

Specification: Name M-toluic acid EINECS 202-723-9 CAS No. 99-04-7 Density 1.151 g/cm3 PSA 37.30000 LogP 1.69320 Solubility water: 1.054 g/mL at 25 °C(lit.) Melting

High Quality m-Toluic acid C8H8O2 CAS 99-04-7

Cas:99-04-7

Min.Order:10 Gram

FOB Price: $10.0

Type:Trading Company

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Synthetic route

m-tolyl aldehyde
620-23-5

m-tolyl aldehyde

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With 2-mesityl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In acetonitrile at 20℃;99%
With tert.-butylhydroperoxide; water; iodine; sodium hydroxide at 70℃; pH=10; Green chemistry;95%
With 2-mesityl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate; 1,4-diaza-bicyclo[2.2.2]octane; oxygen In tetrahydrofuran at 20℃; for 16h;95%
carbon monoxide
201230-82-2

carbon monoxide

3-Iodotoluene
625-95-6

3-Iodotoluene

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With amphiphilic resin-supported phosphine-palladium; water; potassium carbonate at 25℃; under 760 Torr; hydroxycarbonylation;99%
With water; potassium carbonate In acetonitrile at 100℃; under 3750.38 Torr; for 0.0161111h;98%
With 4,4’‐bis(trimethylammoniummethyl)‐2,2’‐bipyridine; bis-triphenylphosphine-palladium(II) chloride; water; sodium carbonate In water at 100℃; under 7600.51 Torr; for 24h; Catalytic behavior; Autoclave;86%
With water; palladium diacetate; triethylamine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; under 11251.1 Torr; Flow reactor;58%
3-Methylbenzonitrile
620-22-4

3-Methylbenzonitrile

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With water; sodium hydroxide at 100℃; for 4h; Temperature;98.5%
With hydrogenchloride im Druckrohr;
With steam; thorium dioxide at 420℃;
With sulfuric acid
With nitrilase from Gordonia terrae In aq. phosphate buffer at 35℃; for 1h; pH=8; Enzymatic reaction;
3-methylphenyloxoacetic acid
61560-94-9

3-methylphenyloxoacetic acid

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With oxone In N,N-dimethyl-formamide for 4h;98%
2-oxo-2-(m-tolyl)acetaldehyde
73318-83-9

2-oxo-2-(m-tolyl)acetaldehyde

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With oxone In N,N-dimethyl-formamide for 4h;98%
With tert.-butylhydroperoxide for 7h;82%
3-methylbenzyl alcohol
587-03-1

3-methylbenzyl alcohol

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With diethylene glycol dimethyl ether at 70℃; for 0.5h; Sonication;97%
With oxygen; sodium hydroxide In water at 80℃; for 10h; Catalytic behavior;97%
With tert.-butylhydroperoxide; water; iodine; sodium hydroxide at 70℃; pH=10; Green chemistry;90%
3-Iodobenzoic acid
618-51-9

3-Iodobenzoic acid

MeSnBr3

MeSnBr3

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With potassium hydroxide; palladium dichloride In water at 100℃; for 5h; Condensation;97%
methyl 3-methylphenylglyoxylate
136125-68-3

methyl 3-methylphenylglyoxylate

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With oxone In N,N-dimethyl-formamide for 4h;97%
m-xylene
108-38-3

m-xylene

A

isophthalic acid
121-91-5

isophthalic acid

B

m-formylphenyl benzoic acid
619-21-6

m-formylphenyl benzoic acid

C

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With dihydrogen peroxide In dimethyl sulfoxide at 70℃; for 10h; Catalytic behavior; Reagent/catalyst; Overall yield = > 99 %;A 96%
B n/a
C n/a
With cobalt(II) acetate; manganese(II) acetate; acetic acid; 3-benzyl-1-methylimidazolium bromide at 215℃; for 3h;
3-methyl-2-bromobenzoic acid
53663-39-1

3-methyl-2-bromobenzoic acid

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With isopropyl alcohol for 5h; Schlenk technique; Inert atmosphere; Irradiation; Heating;96%
With [RhCl2(p-cymene)]2; cesium acetate In isopropyl alcohol at 20 - 100℃; for 24h; Inert atmosphere;94%
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; cesium acetate; isopropyl alcohol at 100℃; Schlenk technique; Inert atmosphere;93%
2-chloro-3-methylbenzoic acid
15068-35-6

2-chloro-3-methylbenzoic acid

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With isopropyl alcohol for 20h; Schlenk technique; Inert atmosphere; Irradiation; Heating;96%
1-methoxycarbonyl-3-methylbenzene
99-36-5

1-methoxycarbonyl-3-methylbenzene

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With iodine; aluminium In acetonitrile at 80℃; for 18h;95%
With iron(III) chloride hexahydrate In glycerol at 70℃; for 14h;93%
With magnesium iodide In toluene for 72h; Heating;48%
m-tolylboronic acid
17933-03-8

m-tolylboronic acid

ethyl acetoacetate
141-97-9

ethyl acetoacetate

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With copper(l) iodide; potassium carbonate In dimethyl sulfoxide at 100℃; for 24h; Inert atmosphere;95%
formic acid
64-18-6

formic acid

3-Iodotoluene
625-95-6

3-Iodotoluene

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With palladium diacetate; triethylamine; dicyclohexyl-carbodiimide; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 80℃; for 10h; Inert atmosphere; Sealed tube;94%
With palladium diacetate; triethylamine; dicyclohexyl-carbodiimide; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 100℃; for 20h; Inert atmosphere; Sealed tube;82%
3-methyl-benzoic acid 3-methyl-but-2-enyl ester

3-methyl-benzoic acid 3-methyl-but-2-enyl ester

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With H-β zeolite; methoxybenzene In toluene for 2.5h; Heating;93%
2-(3-methylphenyl)ethanol
1875-89-4

2-(3-methylphenyl)ethanol

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With oxygen; sodium t-butanolate In tetrahydrofuran at 20℃; under 750.075 Torr; for 22h; chemoselective reaction;93%
3-tolyl triflate
32578-31-7

3-tolyl triflate

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane; water at 20℃; for 16h; Schlenk technique; Inert atmosphere; chemoselective reaction;93%
methyl 3-oxo-3-(m-tolyl)propanedithioate

methyl 3-oxo-3-(m-tolyl)propanedithioate

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With sodium hydroxide In water at 100℃; for 9h; Reflux; chemoselective reaction;93%
m-tolyl aldehyde
620-23-5

m-tolyl aldehyde

A

isophthalic acid
121-91-5

isophthalic acid

B

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With potassium ferrate(VI) In neat (no solvent) for 5h; Milling;A n/a
B 92.8%
benzyl 3-methylbenzoate
137932-33-3

benzyl 3-methylbenzoate

toluene
108-88-3

toluene

A

1-methyl-3-(phenylmethyl)-benzene
620-47-3

1-methyl-3-(phenylmethyl)-benzene

B

1-methyl-4-(phenylmethyl)benzene
620-83-7

1-methyl-4-(phenylmethyl)benzene

C

2-benzyltoluene
713-36-0

2-benzyltoluene

D

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; water at 80℃; for 2h; regioselective reaction;A n/a
B n/a
C n/a
D 92%
3-nitroxylene
38362-90-2

3-nitroxylene

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With water; tetra-(n-butyl)ammonium iodide at 80℃; for 15h; Reagent/catalyst;92%
With tetra-(n-butyl)ammonium iodide; acetic acid In water at 80℃; for 15h; Reagent/catalyst;87%
With zinc diacetate; water; tetra-(n-butyl)ammonium iodide at 80℃; for 24h;84%
1-ethynyl-3-methyl-benzene
766-82-5

1-ethynyl-3-methyl-benzene

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With oxone; sodium hydrogencarbonate In water; acetonitrile at 20℃; for 7h;91%
m-tolyl 2,3,4,5,6-pentafluorobenzenesulfonate

m-tolyl 2,3,4,5,6-pentafluorobenzenesulfonate

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane; water at 20℃; for 16h; Schlenk technique; Inert atmosphere; chemoselective reaction;91%
3-Iodotoluene
625-95-6

3-Iodotoluene

lithium formate
556-63-8

lithium formate

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
Stage #1: lithium formate With acetic anhydride; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃;
Stage #2: 3-Iodotoluene With tris(dibenzylideneacetone)dipalladium (0); lithium chloride In N,N-dimethyl-formamide at 80℃; for 5.5h;
90%
ethanol
64-17-5

ethanol

m-tolyl aldehyde
620-23-5

m-tolyl aldehyde

A

ethyl 3-methylbenzoate
120-33-2

ethyl 3-methylbenzoate

B

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With sodium cyanide In N,N-dimethyl-formamide at 80℃; for 24h; Molecular sieve;A 90%
B 6%
carbon dioxide
124-38-9

carbon dioxide

m-Fluorotoluene
352-70-5

m-Fluorotoluene

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
Stage #1: m-Fluorotoluene With C78H70Al2Cl4N6P4Rh2; magnesium; ethylene dibromide In tetrahydrofuran at -30℃; for 22h; Inert atmosphere; Glovebox;
Stage #2: carbon dioxide In tetrahydrofuran at 20℃; under 760.051 Torr; for 0.5h;
90%
carbon dioxide
124-38-9

carbon dioxide

3-methylbenzenediazonium tetrafluoroborate
1422-76-0

3-methylbenzenediazonium tetrafluoroborate

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydrogensulfate In N,N-dimethyl-formamide for 2h; Electrochemical reaction;88%
carbon dioxide
124-38-9

carbon dioxide

meta-bromotoluene
591-17-3

meta-bromotoluene

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With manganese; 2.9-dimethyl-1,10-phenanthroline; lithium acetate; cobalt(II) bromide In N,N-dimethyl acetamide at 20℃; under 760.051 Torr; for 12h; Inert atmosphere; Schlenk technique;88%
With tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide at 20℃; under 760.051 Torr; for 4h; Electrolysis;78%
With [2,2]bipyridinyl; lithium chloride; cobalt(II) iodide; zinc In N,N-dimethyl-formamide; acetonitrile at 40℃; under 760.051 Torr; for 14h; Sealed tube;45%
m-xylene
108-38-3

m-xylene

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; water at 20℃; for 12h; Inert atmosphere;87%
With cobalt(II) 5,10,15,20-tetraphenylporphyrin; oxygen at 200℃; under 19502 Torr; Pressure; Temperature; Reagent/catalyst;78.9%
With iron(III) sulfate In water; acetonitrile for 16h; Irradiation; Sealed tube;75%
m-xylene
108-38-3

m-xylene

A

isophthalic acid
121-91-5

isophthalic acid

B

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With N-hydroxyphthalimide; air; cobalt(II) acetate; manganese(II) acetate In acetic acid at 150℃; under 22801.5 Torr; for 3h;A 87%
B 7%
Stage #1: m-xylene With hafnium(IV) oxide; N-hydroxy-o-sulphonyl benzamide; C32H12F4FeN8; C44H28N4O8Ru; oxygen at 145℃; under 6000.6 Torr; for 1.6h;
Stage #2: With hafnium(IV) oxide; N-hydroxy-o-sulphonyl benzamide; C32H12F4FeN8; C44H28N4O8Ru; oxygen; acetic acid at 176℃; under 13501.4 Torr; for 2.2h; Temperature; Pressure; Reagent/catalyst;
A 84.4%
B 15.6%
With N-hydroxyphthalimide; oxygen; nitric acid at 110℃; under 760.051 Torr; for 6h; Ionic liquid;A 71%
B n/a
methanol
67-56-1

methanol

m-Toluic acid
99-04-7

m-Toluic acid

1-methoxycarbonyl-3-methylbenzene
99-36-5

1-methoxycarbonyl-3-methylbenzene

Conditions
ConditionsYield
With sulfuric acid at 20℃; for 15h; Heating / reflux;100%
With sulfuric acid for 4h; Reflux;100%
With thionyl chloride at 0 - 20℃; for 5h;99%
m-Toluic acid
99-04-7

m-Toluic acid

3-Methylbenzoyl chloride
1711-06-4

3-Methylbenzoyl chloride

Conditions
ConditionsYield
Stage #1: m-Toluic acid With N,N-dimethyl-formamide In dichloromethane at 0℃; for 0.0833333h;
Stage #2: With oxalyl dichloride In dichloromethane at 20℃; for 12h;
100%
With thionyl chloride; N,N-dimethyl-formamide at 90℃; for 3h;99.3%
With thionyl chloride; tetra(n-butyl)ammonium hydrogensulfate In 5,5-dimethyl-1,3-cyclohexadiene at 45℃; for 4.5h; Temperature; Reagent/catalyst; Solvent; Large scale;98.2%
n-heptan1ol
111-70-6

n-heptan1ol

m-Toluic acid
99-04-7

m-Toluic acid

heptyl 3-methylbenzoate
5462-02-2

heptyl 3-methylbenzoate

Conditions
ConditionsYield
With Candida antarctica lipase B immobilised in a macroporous DVB crosslinked polymer (Novozym 435) In cyclohexane at 80℃; for 24h; Enzymatic reaction;100%
With diphenylphosphinopolystyrene; diethylazodicarboxylate In tetrahydrofuran at 25℃; for 4h;90%
m-Toluic acid
99-04-7

m-Toluic acid

3-methylcyclohexa-2,5-dienecarboxylic acid
31673-44-6

3-methylcyclohexa-2,5-dienecarboxylic acid

Conditions
ConditionsYield
With sodium In ammonia100%
With ammonia; sodium In tetrahydrofuran for 0.5h;80%
With ammonia; sodium
2,2'-dimethoxy-1,1'-binaphthyl
75685-01-7

2,2'-dimethoxy-1,1'-binaphthyl

m-Toluic acid
99-04-7

m-Toluic acid

6,6'-bis(3-methylbenzoyl)-2,2'-dimethoxy-1,1'-binaphthyl

6,6'-bis(3-methylbenzoyl)-2,2'-dimethoxy-1,1'-binaphthyl

Conditions
ConditionsYield
With methanesulfonic acid; phosphorus pentoxide at 60℃; for 24h; Friedel-Crafts acylation;100%
N-(2-aminoethyl)-4-methyl-N-(prop-2-yn-1-yl)benzenesulfonamide
1438397-77-3

N-(2-aminoethyl)-4-methyl-N-(prop-2-yn-1-yl)benzenesulfonamide

m-Toluic acid
99-04-7

m-Toluic acid

3-methyl-N-[2-(N-propargyl-N-tosylamino)ethyl]benzamide

3-methyl-N-[2-(N-propargyl-N-tosylamino)ethyl]benzamide

Conditions
ConditionsYield
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 0.5h;100%
m-Toluic acid
99-04-7

m-Toluic acid

2,5-bis(3-methylphenyl)-1,3,4-oxadiazole
59646-37-6

2,5-bis(3-methylphenyl)-1,3,4-oxadiazole

Conditions
ConditionsYield
With hydrazine dihydrochloride; phosphoric acid; trichlorophosphate In water at 140℃; for 2h; Condensation;99.8%
With hydrazine dihydrochloride; phosphoric acid; phosphorus pentoxide at 130℃; for 0.0833333h; microwave irradiation;97%
With sodium tetrahydroborate; hydrazine dihydrochloride; phosphoric acid at 170 - 180℃; Inert atmosphere; Neat (no solvent);89%
methyl iodide
74-88-4

methyl iodide

m-Toluic acid
99-04-7

m-Toluic acid

1-methyl-3-methylcyclohexa-2,5-dienecarboxylic acid
31689-43-7

1-methyl-3-methylcyclohexa-2,5-dienecarboxylic acid

Conditions
ConditionsYield
Stage #1: m-Toluic acid With ammonia; lithium In water at -60℃; for 0.5h; Birch reduction;
Stage #2: methyl iodide In water regioselective reaction;
99%
(i) Li, liq. NH3, (ii) /BRN= 969135/; Multistep reaction;
Stage #1: m-Toluic acid With lithium In ammonia at -78 - -60℃; Birch reduction; liquid NH3;
Stage #2: methyl iodide Cooling with ice;
methyl bromide
74-83-9

methyl bromide

m-Toluic acid
99-04-7

m-Toluic acid

1-methyl-3-methylcyclohexa-2,5-dienecarboxylic acid
31689-43-7

1-methyl-3-methylcyclohexa-2,5-dienecarboxylic acid

Conditions
ConditionsYield
Stage #1: m-Toluic acid With ammonia; lithium at -60℃; Birch reduction;
Stage #2: methyl bromide at -60 - 20℃;
99%
4-Nitrophenylene-1,2-diamine
99-56-9

4-Nitrophenylene-1,2-diamine

m-Toluic acid
99-04-7

m-Toluic acid

5-nitro-2-(m-tolyl)-1H-benzo[d]imidazole
1571-91-1

5-nitro-2-(m-tolyl)-1H-benzo[d]imidazole

Conditions
ConditionsYield
With polyphosphoric acid (PPA) at 120 - 150℃; for 5h;99%
With polyphosphoric acid at 120 - 150℃; for 5h;99%
4,4'-dimethoxyphenyl disulfide
5335-87-5

4,4'-dimethoxyphenyl disulfide

m-Toluic acid
99-04-7

m-Toluic acid

1-[(4-methoxyphenyl)thio]-3-methylbenzene

1-[(4-methoxyphenyl)thio]-3-methylbenzene

Conditions
ConditionsYield
With manganese; 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); 1,3-bis-(diphenylphosphino)propane; 2,2-dimethylpropanoic anhydride; zinc In toluene at 160℃; for 24h; Sealed tube; Inert atmosphere;99%
[2-(2-thyenyl)ethyl]amine
30433-91-1

[2-(2-thyenyl)ethyl]amine

m-Toluic acid
99-04-7

m-Toluic acid

[2-(2-thienyl)ethylamino](m-tolyl)formaldehyde

[2-(2-thienyl)ethylamino](m-tolyl)formaldehyde

Conditions
ConditionsYield
With benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃;98%
N-(phenylethynyl)-S-methyl-S-phenylsulfoximine
1429402-56-1

N-(phenylethynyl)-S-methyl-S-phenylsulfoximine

m-Toluic acid
99-04-7

m-Toluic acid

C23H21NO3S

C23H21NO3S

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; regioselective reaction;98%
4-toluenesulfonyl azide
941-55-9

4-toluenesulfonyl azide

m-Toluic acid
99-04-7

m-Toluic acid

N-<(4-Methylphenyl)sulfonyl>-3-methylbenzenecarboxamide
152126-61-9

N-<(4-Methylphenyl)sulfonyl>-3-methylbenzenecarboxamide

Conditions
ConditionsYield
With dicobalt octacarbonyl; tert-butylisonitrile In acetonitrile at 80℃; for 4h;98%
With copper(l) iodide; methyl ethynyl ketone In acetonitrile at 80℃; for 4h;72%
3-aminobenzenemethanol
1877-77-6

3-aminobenzenemethanol

m-Toluic acid
99-04-7

m-Toluic acid

C15H15NO2

C15H15NO2

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃;98%
1-(3-aminophenyl)ethanone
99-03-6

1-(3-aminophenyl)ethanone

m-Toluic acid
99-04-7

m-Toluic acid

C16H15NO2
315669-99-9

C16H15NO2

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; Cooling;98%
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

m-Toluic acid
99-04-7

m-Toluic acid

1-methoxycarbonyl-3-methylbenzene
99-36-5

1-methoxycarbonyl-3-methylbenzene

Conditions
ConditionsYield
With sulfuric acid; acetic acid at 85 - 90℃; for 12h; Neat (no solvent); Large scale reaction;97.65%
N,N-diethylcarbamyl chloride
88-10-8

N,N-diethylcarbamyl chloride

m-Toluic acid
99-04-7

m-Toluic acid

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With triethylamine at 20℃; for 0.333333h;97.5%
With triethylamine at 20℃; for 0.333333h;97.5%
1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

m-Toluic acid
99-04-7

m-Toluic acid

2-(m-tolyl)-1H-benzo[d]imidazole
6528-83-2

2-(m-tolyl)-1H-benzo[d]imidazole

Conditions
ConditionsYield
Stage #1: m-Toluic acid In dichloromethane at 0℃; for 0.25h;
Stage #2: 1,2-diamino-benzene With pyridine In dichloromethane at 20℃; for 6h; Further stages.;
97%
With polyphosphoric acid In toluene at 165℃; for 6h;89%
With propylene glycol at 170℃; for 18h;78.5%
diphenyl acetylene
501-65-5

diphenyl acetylene

m-Toluic acid
99-04-7

m-Toluic acid

7-methyl-3,4-diphenyl-1H-2-benzopyran-1-one
93743-65-8

7-methyl-3,4-diphenyl-1H-2-benzopyran-1-one

Conditions
ConditionsYield
With dichloro[1,3-di(ethoxycarbonyl)-2,4,5-trimethylcyclopentadienyl]rhodium(III) dimer; copper(II) acetate monohydrate; silver(I) triflimide In dichloromethane at 20℃; for 24h; Sealed tube;97%
With carbonyl(pentamethylcyclopentadienyl)cobalt diiodide; sodium acetate; copper(II) oxide In 2,2,2-trifluoroethanol at 80℃; for 24h; Schlenk technique; Molecular sieve; Inert atmosphere;87%
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; copper(II) acetate monohydrate at 80℃; for 18h; Green chemistry; regioselective reaction;80%
N-methoxylamine hydrochloride
593-56-6

N-methoxylamine hydrochloride

m-Toluic acid
99-04-7

m-Toluic acid

N-methoxy-3-methylbenzamide
72755-11-4

N-methoxy-3-methylbenzamide

Conditions
ConditionsYield
With 1,1'-carbonyldiimidazole In tetrahydrofuran at 20℃;97%
Stage #1: m-Toluic acid With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 0 - 20℃; for 4h; Under an atmosphere of argon;
Stage #2: N-methoxylamine hydrochloride With potassium carbonate In water; ethyl acetate at 0 - 20℃; for 4h;
96%
1,2,3-Benzotriazole
95-14-7

1,2,3-Benzotriazole

m-Toluic acid
99-04-7

m-Toluic acid

(1H-benzo-[d][1,2,3]triazol-1-yl)(m-tolyl)methanone
313549-89-2

(1H-benzo-[d][1,2,3]triazol-1-yl)(m-tolyl)methanone

Conditions
ConditionsYield
Stage #1: m-Toluic acid With iodine; triphenylphosphine In dichloromethane at 0℃; for 0.5h;
Stage #2: 1,2,3-Benzotriazole In dichloromethane at 0℃; for 0.166667h;
Stage #3: With triethylamine In dichloromethane at 20℃; for 0.5h;
97%
With thionyl chloride In dichloromethane for 2h; Inert atmosphere;95%
With thionyl chloride In dichloromethane at 20℃;84%
cyclohexyl-N-tosyl aziridine
68820-12-2

cyclohexyl-N-tosyl aziridine

m-Toluic acid
99-04-7

m-Toluic acid

2-(4-methylphenylsulfonamido)cyclohexyl 3-methylbenzoate

2-(4-methylphenylsulfonamido)cyclohexyl 3-methylbenzoate

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 45℃; for 2h;97%
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