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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 3-Methyl-4-nitrobenzoic acid(3113-71-1)

Cas:3113-71-1

Min.Order:100 Gram

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Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

3-Methyl-4-nitrobenzoic acid

Cas:3113-71-1

Min.Order:1 Kilogram

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

3-Methyl-4-nitrobenzoic acid

Cas:3113-71-1

Min.Order:1 Kilogram

FOB Price: $3.0

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Jinan Finer Chemical Co., Ltd

3-Methyl-4-nitrobenzoic acid Product Description Product Name 3-Methyl-4-nitrobenzoic acid CAS No. 3113-71-1 Appearance yellowish to yellow crystalline powder

4-Nitro-m-toluic acid

Cas:3113-71-1

Min.Order:1 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:White to light yellow powder Storage:cool dry place Package:25kg/drum Application:pharmaceutical intermediate Tran

Manufacturer high quality 3-Methyl-4-nitrobenzoic acid Cas 3113-71-1 with good price

Cas:3113-71-1

Min.Order:1 Kilogram

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

3-Methyl-4-nitrobenzoic acid

Cas:3113-71-1

Min.Order:1 Kilogram

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Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 3113-71-1 3-Methyl-4-nitrobenzoic acid Manufacturer

Cas:3113-71-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

3-Methyl-4-nitrobenzoic acid

Cas:3113-71-1

Min.Order:1 Kilogram

FOB Price: $5.0

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ANQING CHICO PHARMACEUTICAL CO.,LTD.

High quality. Factory supply. In stock. Best price.1.Quick response within 24 hours;2.Best quality in your requirement;?3.We pay more attention on delivery time, and usually ship on time;4.Under the premise of safety and effectiveness, we can produce

3-Methyl-4-nitrobenzoic acid

Cas:3113-71-1

Min.Order:0

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Type:Trading Company

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

3-Methyl-4-Nitrobenzoic Acid

Cas:3113-71-1

Min.Order:1 Metric Ton

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Type:Manufacturers

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Chemwill Asia Co., Ltd.

Chemwill Asia co.,Ltd is one of the leading manufacturer in CHINA. Product quality, process, price and service 3-Methyl-4-nitrobenzoic acid CAS 3113-71-1 3-methyl-4-nitrobenzoate IN STOCK 4-Nitro-m-toluic acid CAS 3113-71-1 3113-71-1 CAS 3

Hebei yanxi chemical co.,LTD.

1. Best quality in your requirement 2. Competitive price in China market 3. mature Technical support 4. Professional logistic support 5 . Full experience of large numbers containers loading in Chinese sea port 6 Fast shipment by reputed shipping

High quality 3-Methyl-4-nitrobenzoic acid CAS 3113-71-1

Cas:3113-71-1

Min.Order:1 Kilogram

FOB Price: $25.0 / 45.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

3113-71-1 3-Methyl-4-nitrobenzoic acid

Cas:3113-71-1

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturing

3-Methyl-4-nitrobenzoic acid cas 3113-71-1

Cas:3113-71-1

Min.Order:1 Kilogram

FOB Price: $20.0 / 80.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 4-Nitro-3-Methyl benzoic acid CAS:3113-71-1 MF: C8H6NO4 Appearance:Colorless liquid Storage:Preserve in well-closed, light-resistant and airtight containers. Package:25KG Application:Pesticide intermediate Transportation:By sea Port:Qingdao P

4-Nitro-3-Methyl benzoic acid

Cas:3113-71-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 3113-71-1 with best quality

Cas:3113-71-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by email in time prod

3-Methyl-4-nitrobenzoic acid

Cas:3113-71-1

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:Off-white or yellowish powder Storage:R.T Package:25kg/drum Application:Intermediates Transportation:Express/Sea/Air Port:Any port in China

High Quality 3-Methyl-4-nitrobenzoic acid cas 3113-71-1

Cas:3113-71-1

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

3-Methyl-4-nitrobenzoic acid 3113-71-1

Cas:3113-71-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

3-Methyl-4-nitrobenzoic acid Basic information Product Name: 3-Methyl-4-nitrobenzoic acid Synonyms: RARECHEM AL BO 0346;3-methyl-4-nitro-benzoicaci;Benzoic acid, 3-methyl-4-nitro-;m-Toluic acid, 4-nitro-;4-NITRO-3-METHYLBENZOIC ACID;4-NITRO-M-TOLUIC

3-Methyl-4-nitrobenzoic acid

Cas:3113-71-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

3-Methyl-4-nitrobenzoic acid

Cas:3113-71-1

Min.Order:1 Kilogram

FOB Price: $85.0 / 100.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

3-Methyl-4-nitrobenzoic acid CAS:3113-71-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality orga

3-Methyl-4-nitrobenzoic acid CAS:3113-71-1

Cas:3113-71-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:3113-71-1

Cas:3113-71-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several

3-Methyl-4-nitrobenzoic acid cas:3113-71-1

Cas:3113-71-1

Min.Order:25 Gram

FOB Price: $90.0 / 100.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

3-Methyl-4-nitrobenzoic acid

Cas:3113-71-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Lonwin Chemical Group Limited

4-Nitro-m-toluic acid CAS: 3113-71-1 Specification Product Name 3-Methyl-4-nitrobenzoic acid CAS No. 3113-71-1 Appearance yellowish to yellow crystalline powder

Factory supply 4-Nitro-m-toluic acid

Cas:3113-71-1

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

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Shanxi Ankesi Biotechnology Co., Ltd

Our Advantage 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good qual

Factory supply about 99% purity CAS 3113-71-1 3-Methyl-4-nitrobenzoic acid in stock

Cas:3113-71-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3-Methyl-4-Nitrobenzoic Acid

Cas:3113-71-1

Min.Order:0

Negotiable

Type:Manufacturers

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

3-Methyl-4-nitrobenzoic acid CAS 3113-71-1

Cas:3113-71-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Methyl-4-Nitrobenzoic Acid

Cas:3113-71-1

Min.Order:0 Metric Ton

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Type:Lab/Research institutions

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Synthetic route

methyl 3-methyl-4-nitrobenzoate
24078-21-5

methyl 3-methyl-4-nitrobenzoate

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran Heating;100%
methyl 3-methyl-4-nitrobenzoate
24078-21-5

methyl 3-methyl-4-nitrobenzoate

2-methoxy-3-quinolinecarboxyaldehyde
139549-06-7

2-methoxy-3-quinolinecarboxyaldehyde

A

2-(2-methoxy-quinolin-3-yl)-2,3-dihydro-benzofuran-5-carboxylic acid methyl ester

2-(2-methoxy-quinolin-3-yl)-2,3-dihydro-benzofuran-5-carboxylic acid methyl ester

B

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride; N-ethyl-N,N-diisopropylamine In tetrahydrofuran Heating;A 69%
B n/a
m-Toluic acid
99-04-7

m-Toluic acid

A

5-methyl-2-nitrobenzoic acid
3113-72-2

5-methyl-2-nitrobenzoic acid

B

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

C

3-methyl-2-nitrobenzoic acid
5437-38-7

3-methyl-2-nitrobenzoic acid

Conditions
ConditionsYield
With guanidine nitrate Reagent/catalyst;A 54%
B 13%
C 33%
With sulfuric acid; uronium nitrate at 25℃; for 24h;
With guanidine nitrate In sulfuric acid at 0 - 20℃;
With dinitrogen pentoxide In tetrachloromethane at 50℃; for 2h; regioselective reaction;
1-methyl-4-nitrosobenzene
623-11-0

1-methyl-4-nitrosobenzene

4-methyl-5-nitro-tropolone
98554-86-0

4-methyl-5-nitro-tropolone

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

3-methyl-4-nitro-benzaldehyde
18515-67-8

3-methyl-4-nitro-benzaldehyde

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
With chromium(III) oxide; sulfuric acid
4-isopropyl-2-methyl-1-nitro-benzene
859816-25-4

4-isopropyl-2-methyl-1-nitro-benzene

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
With nitric acid
3-methyl-4-nitrobenzonitrile
96784-54-2

3-methyl-4-nitrobenzonitrile

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
With hydrogenchloride at 160℃;
m-xylene
108-38-3

m-xylene

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
With nitric acid Siedetemperatur;
m-Toluic acid
99-04-7

m-Toluic acid

A

5-methyl-2-nitrobenzoic acid
3113-72-2

5-methyl-2-nitrobenzoic acid

B

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
With nitric acid
m-Toluic acid
99-04-7

m-Toluic acid

A

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

B

3-methyl-2-nitrobenzoic acid
5437-38-7

3-methyl-2-nitrobenzoic acid

Conditions
ConditionsYield
With nitric acid
2,4-dimethylnitrobenzene
89-87-2

2,4-dimethylnitrobenzene

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
With chromium(VI) oxide; sulfuric acid In acetic anhydride; acetic acid
With nitric acid
Multi-step reaction with 2 steps
1: CrO3; concentrated sulfuric acid; glacial acetic acid / 5 - 10 °C / weiteres Reagens: Acetanhydrid; durch Verseifung des entstandenen Diacetats mit Salzsaeure
2: Cr2O3-H2SO4
View Scheme
With potassium permanganate; tetrabutylammomium bromide; water at 90℃; under 2250.23 - 3750.38 Torr; for 1h; Temperature;
nitric acid
7697-37-2

nitric acid

m-xylene
108-38-3

m-xylene

mercury

mercury

A

2,4-dimethylnitrobenzene
89-87-2

2,4-dimethylnitrobenzene

B

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
Produktverhaeltnis abhaengig von der Reaktionstemperatur (75 grad / Siedetemperatur);
nitric acid
7697-37-2

nitric acid

m-Toluic acid
99-04-7

m-Toluic acid

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

2,4-dimethylnitrobenzene
89-87-2

2,4-dimethylnitrobenzene

water
7732-18-5

water

calcium permanganate

calcium permanganate

A

5-methyl-2-nitrobenzoic acid
3113-72-2

5-methyl-2-nitrobenzoic acid

B

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

C

4-nitroisophthalic acid
4315-09-7

4-nitroisophthalic acid

2,4-dimethylnitrobenzene
89-87-2

2,4-dimethylnitrobenzene

sulfuric acid
7664-93-9

sulfuric acid

acetic anhydride
108-24-7

acetic anhydride

acetic acid
64-19-7

acetic acid

CrO3

CrO3

A

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

B

diacetate of 4-nitro-3-methyl-benzaldehyde

diacetate of 4-nitro-3-methyl-benzaldehyde

Conditions
ConditionsYield
at 5 - 10℃;
3-ethyl-6-nitrotoluene
102878-76-2

3-ethyl-6-nitrotoluene

nitric acid
7697-37-2

nitric acid

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

6-nitro-1-methyl-3-ethylbenzene

6-nitro-1-methyl-3-ethylbenzene

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
With nitric acid
3-methyl-4-nitro-benzaldehyde
18515-67-8

3-methyl-4-nitro-benzaldehyde

chromic acid

chromic acid

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

3-methyl-4-nitrobiphenyl
69314-47-2

3-methyl-4-nitrobiphenyl

acetic acid
64-19-7

acetic acid

CrO3

CrO3

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

nitroxylol

nitroxylol

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
With potassium dichromate; sulfuric acid; water
m-Toluic acid
99-04-7

m-Toluic acid

A

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

B

2-nitro-3-methyl-benzoic acid , 6-nitro-3-methyl-benzoic acid

2-nitro-3-methyl-benzoic acid , 6-nitro-3-methyl-benzoic acid

Conditions
ConditionsYield
With nitric acid
2,4-dimethylnitrobenzene
89-87-2

2,4-dimethylnitrobenzene

A

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

B

4-nitro-isophthalic acid ; 6-nitro-3-methyl-benzoic acid

4-nitro-isophthalic acid ; 6-nitro-3-methyl-benzoic acid

Conditions
ConditionsYield
With calcium permanganate; water
3'-methyl-4-pentyl-[1,1'-biphenyl]-2,6-diol

3'-methyl-4-pentyl-[1,1'-biphenyl]-2,6-diol

nitric acid
7697-37-2

nitric acid

acetic acid
64-19-7

acetic acid

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

(3-methyl-4-nitrophenyl)acetonitrile
119713-11-0

(3-methyl-4-nitrophenyl)acetonitrile

alkaline potassium permanganate

alkaline potassium permanganate

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

4-amino 3-methylbenzoic acid
2486-70-6

4-amino 3-methylbenzoic acid

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
With Streptomyces thioluteus para-aminobenzoate N-oxygenase
m-cymene
535-77-3

m-cymene

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: fuming nitric acid
2: diluted nitric acid
View Scheme
3-Methylbenzonitrile
620-22-4

3-Methylbenzonitrile

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: concentrated hydrochloric acid / im Druckrohr
2: fuming nitric acid
View Scheme
m-Toluic acid
99-04-7

m-Toluic acid

A

5-methyl-2-nitrobenzoic acid
3113-72-2

5-methyl-2-nitrobenzoic acid

B

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

C

3-methyl-2-nitrobenzoic acid
5437-38-7

3-methyl-2-nitrobenzoic acid

D

3-methyl-2,6-dinitrobenzoic acid
3478-09-9

3-methyl-2,6-dinitrobenzoic acid

Conditions
ConditionsYield
With uronium nitrate In sulfuric acid at 0 - 20℃;
2,4-dimethylnitrobenzene
89-87-2

2,4-dimethylnitrobenzene

A

3-methyl-4-nitro-benzaldehyde
18515-67-8

3-methyl-4-nitro-benzaldehyde

B

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

C

3-methyl-4-nitrobenzyl alcohol
80866-75-7

3-methyl-4-nitrobenzyl alcohol

Conditions
ConditionsYield
Stage #1: 2,4-dimethylnitrobenzene With cerium(IV) oxide; C40H32MnN8; oxygen; acetic acid at 125℃; under 4500.45 Torr;
Stage #2: With water at 78℃; under 3000.3 Torr;
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

3-methyl-4-nitro-benzoyl chloride
35675-46-8

3-methyl-4-nitro-benzoyl chloride

Conditions
ConditionsYield
With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide at 0 - 20℃; for 3h;100%
With pyridine; thionyl chloride In toluene at 35 - 40℃; Large scale;97%
With thionyl chloride
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

dimethyl amine
124-40-3

dimethyl amine

N,N-dimethyl-3-methyl-4-nitrobenzamide
333350-50-8

N,N-dimethyl-3-methyl-4-nitrobenzamide

Conditions
ConditionsYield
Stage #1: 3-methyl-4-nitrobenzoic acid With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 4h;
Stage #2: dimethyl amine In dichloromethane; water at 20℃; for 0.5h;
100%
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide at 20℃; for 12h;73.17%
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide at 20℃; for 12h;73.17%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

4-amino 3-methylbenzoic acid
2486-70-6

4-amino 3-methylbenzoic acid

Conditions
ConditionsYield
With hydrogenchloride; sulfuric acid In water; acetonitrile at 40℃; for 4h; Solvent; Reagent/catalyst; Temperature; Electrolysis;99%
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; under 1875.19 Torr; for 2h;98%
With palladium on activated charcoal; hydrogen In methanol at 20℃; for 24h;96%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

3-methyl-4-nitrobenzyl alcohol
80866-75-7

3-methyl-4-nitrobenzyl alcohol

Conditions
ConditionsYield
With dimethylsulfide borane complex In tetrahydrofuran at 0℃; for 18h;99%
With dimethylsulfide borane complex In tetrahydrofuran Reflux;95%
With Trimethyl borate; dimethylsulfide borane complex In tetrahydrofuran for 6h; Reduction; Heating;90%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

methyl 4-amino-3-methylbenzoate
18595-14-7

methyl 4-amino-3-methylbenzoate

Conditions
ConditionsYield
With H2; palladium-carbon In methanol99%
Multi-step reaction with 2 steps
1: 74.3 percent / sulfuric acid / 2 h / Heating
2: 92.1 percent / aq. hydrazine / Raney Ni / methanol / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: HCl
2: alcoholic ammonium sulfide
View Scheme
4-n-pentylphenol
14938-35-3

4-n-pentylphenol

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

4-pentylphenyl-3-methyl-4-nitrobenzoate
765303-74-0

4-pentylphenyl-3-methyl-4-nitrobenzoate

Conditions
ConditionsYield
Stage #1: 3-methyl-4-nitrobenzoic acid With methanesulfonyl chloride; triethylamine In tetrahydrofuran at -30℃; for 1h;
Stage #2: 4-n-pentylphenol With dmap In tetrahydrofuran at -30℃; for 1h;
Stage #3: In tetrahydrofuran at 20℃; for 12h;
99%
1-methyl-4-aminopiperidine
41838-46-4

1-methyl-4-aminopiperidine

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

3-methyl-N-(1-methyl-4-piperidyI)-4-nitro-benzamide
1001345-96-5

3-methyl-N-(1-methyl-4-piperidyI)-4-nitro-benzamide

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide at 18 - 25℃; for 18h;98%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

tert-butyl 3-methyl-4-nitrobenzoate
147290-67-3

tert-butyl 3-methyl-4-nitrobenzoate

Conditions
ConditionsYield
With pyridine; benzenesulfonyl chloride In hexane; ethyl acetate; tert-butyl alcohol97%
85%
With benzenesulfonyl chloride In pyridine; water; toluene; tert-butyl alcohol
With benzenesulfonyl chloride In pyridine; water; toluene; tert-butyl alcohol
methanol
67-56-1

methanol

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

methyl 3-methyl-4-nitrobenzoate
24078-21-5

methyl 3-methyl-4-nitrobenzoate

Conditions
ConditionsYield
With thionyl chloride at 0 - 80℃; for 1h;96%
With sodium hydrogen sulfate for 12h; Reflux;96.4%
With sulfuric acid for 16h; Reflux;93%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

3-methyl-4-nitro-benzoic acid ethyl ester
30650-90-9

3-methyl-4-nitro-benzoic acid ethyl ester

Conditions
ConditionsYield
With thionyl chloride In ethanol at 0 - 80℃; for 2h;96.1%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl 3-methyl-4-nitrobenzoate
147290-67-3

tert-butyl 3-methyl-4-nitrobenzoate

Conditions
ConditionsYield
With pyridine; benzenesulfonyl chloride for 1h;95%
Stage #1: 3-methyl-4-nitrobenzoic acid With benzenesulfonyl chloride In pyridine at 20℃; for 0.166667h;
Stage #2: tert-butyl alcohol In pyridine for 1h;
95%
With pyridine; benzenesulfonyl chloride82%
With benzenesulfonyl chloride In pyridine; water for 1.75h;28%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

potassium 3-methyl-4-nitrobenzoate
1086406-21-4

potassium 3-methyl-4-nitrobenzoate

Conditions
ConditionsYield
With potassium tert-butylate In ethanol at 20℃; for 3h;95%
With potassium tert-butylate In ethanol at 20℃; Inert atmosphere;95%
oxalyl dichloride
79-37-8

oxalyl dichloride

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

3-Methylpiperidine
626-56-2, 53152-98-0

3-Methylpiperidine

3-methyl-1-(3-methyl-4-nitrobenzoyl)piperidine
321532-90-5

3-methyl-1-(3-methyl-4-nitrobenzoyl)piperidine

Conditions
ConditionsYield
With triethylamine In dichloromethane; water94%
ethanol
64-17-5

ethanol

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

3-methyl-4-nitro-benzoic acid ethyl ester
30650-90-9

3-methyl-4-nitro-benzoic acid ethyl ester

Conditions
ConditionsYield
With sulfuric acid for 24h; Heating;92%
With sulfuric acid at 20℃; for 168h;88%
With hydrogenchloride
With sulfuric acid for 24h; Inert atmosphere; Reflux;
With sulfuric acid Reflux;
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

dimethyl sulfate
77-78-1

dimethyl sulfate

methyl 3-methyl-4-nitrobenzoate
24078-21-5

methyl 3-methyl-4-nitrobenzoate

Conditions
ConditionsYield
Stage #1: 3-methyl-4-nitrobenzoic acid With potassium carbonate In acetone at 20℃; for 0.166667h;
Stage #2: dimethyl sulfate In acetone for 4h; Reflux;
92%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

ethyl iodide
75-03-6

ethyl iodide

3-methyl-4-nitro-benzoic acid ethyl ester
30650-90-9

3-methyl-4-nitro-benzoic acid ethyl ester

Conditions
ConditionsYield
With sodium hydrogencarbonate In N,N-dimethyl-formamide91%
With sodium hydrogencarbonate In N,N-dimethyl-formamide91%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

5-chloro-4-(1-(phenylsulfonyl)-1-indol-3-yl)-N-(piperidin-4-yl)pyrimidin-2-amine

5-chloro-4-(1-(phenylsulfonyl)-1-indol-3-yl)-N-(piperidin-4-yl)pyrimidin-2-amine

(4-(5-chloro-4-(1-(phenylsulfonyl)-1H-indol-3-yl)pyrimidin-2-ylamino)piperidin-1-yl)(3-methyl-4-nitrophenyl)methanone

(4-(5-chloro-4-(1-(phenylsulfonyl)-1H-indol-3-yl)pyrimidin-2-ylamino)piperidin-1-yl)(3-methyl-4-nitrophenyl)methanone

Conditions
ConditionsYield
With O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In dichloromethane at 23℃;91%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

C16H12Cl2N2O2
1350994-83-0

C16H12Cl2N2O2

Conditions
ConditionsYield
Stage #1: 3-methyl-4-nitrobenzoic acid With D-glucose; sodium hydroxide In water at 50℃; for 16.6667h;
Stage #2: With acetic acid In water pH=6;
Stage #3: With thionyl chloride; N,N-dimethyl-formamide at 90℃; for 10h;
88%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

toluene
108-88-3

toluene

benzyl 3-methyl-4-nitrobenzoate
808784-30-7

benzyl 3-methyl-4-nitrobenzoate

Conditions
ConditionsYield
With N,N-dimethyl acetamide; trifluorormethanesulfonic acid; oxygen; palladium diacetate at 115℃; under 760.051 Torr; for 24h; Schlenk technique;86%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

N,N-dimethyl-formamide dimethyl acetal
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

Methyl-3--4-nitrobenzoat
99474-17-6

Methyl-3--4-nitrobenzoat

Conditions
ConditionsYield
With pyrrolidine In N,N-dimethyl-formamide for 4h; Heating;85%
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

isopropyl alcohol
67-63-0

isopropyl alcohol

3-methyl-4-nitro-benzoic acid isopropyl ester
22913-13-9

3-methyl-4-nitro-benzoic acid isopropyl ester

Conditions
ConditionsYield
With thionyl chloride; sodium carbonate for 3.5h; Reflux;83%
n-pentyl formate
638-49-3

n-pentyl formate

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

pentyl 3-methyl-4-nitrobenzoate
1596172-38-1

pentyl 3-methyl-4-nitrobenzoate

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper(II) bis(trifluoromethanesulfonate) In 1,2-dichloro-ethane at 130℃; for 12h; Sealed tube;82%
4-ethylpiperazine
5308-25-8

4-ethylpiperazine

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

(4-ethylpiperazin-1-yl)(3-methyl-4-nitrophenyl)methanone
432503-80-5

(4-ethylpiperazin-1-yl)(3-methyl-4-nitrophenyl)methanone

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 2h;79%
With thionyl chloride In tetrahydrofuran; N,N-dimethyl-formamide at 0 - 20℃; for 4h;
3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

4-amino-3-mercapto-1,2,4-triazin-5(4H)-one
23702-90-1

4-amino-3-mercapto-1,2,4-triazin-5(4H)-one

C11H7N5O3S
1403748-01-5

C11H7N5O3S

Conditions
ConditionsYield
With trichlorophosphate Reflux;79%
[bis(acetoxy)iodo]benzene
3240-34-4

[bis(acetoxy)iodo]benzene

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

methyl 3-methyl-4-nitrobenzoate
24078-21-5

methyl 3-methyl-4-nitrobenzoate

Conditions
ConditionsYield
With copper diacetate; acetic anhydride In N,N-dimethyl-formamide; acetonitrile at 130℃; for 1h; Sealed tube;75%
8-amino-10-ethyl-10H-dibenzo[b,f][1,4]thiazepin-11-one
950858-27-2

8-amino-10-ethyl-10H-dibenzo[b,f][1,4]thiazepin-11-one

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

N-(10-ethyl-11-oxo-10,11-dihydro-dibenzo[b,f][1,4]thiazepin-8-yl)-3-methyl-4-nitro-benzamide

N-(10-ethyl-11-oxo-10,11-dihydro-dibenzo[b,f][1,4]thiazepin-8-yl)-3-methyl-4-nitro-benzamide

Conditions
ConditionsYield
With 1,1'-carbonyldiimidazole In 1,4-dioxane at 50 - 100℃; for 6h;72%
Stage #1: 3-methyl-4-nitrobenzoic acid With 1,1'-carbonyldiimidazole In 1,4-dioxane at 0.5℃; for 1h;
Stage #2: 8-amino-10-ethyl-10H-dibenzo[b,f][1,4]thiazepin-11-one In 1,4-dioxane for 5h; Heating; Further stages.;
72%
4-(2-Hydroxyethyl)piperidine
622-26-4

4-(2-Hydroxyethyl)piperidine

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

C15H20N2O4

C15H20N2O4

Conditions
ConditionsYield
With 1-hydroxy-7-aza-benzotriazole; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 24h;72%
methanol
67-56-1

methanol

3-methyl-4-nitrobenzoic acid
3113-71-1

3-methyl-4-nitrobenzoic acid

triphenyltin(IV) hydroxide
76-87-9

triphenyltin(IV) hydroxide

3-CH3-4-NO2-C6H3COO(C6H5)3Sn*CH3OH
1417341-61-7

3-CH3-4-NO2-C6H3COO(C6H5)3Sn*CH3OH

Conditions
ConditionsYield
In ethanol for 2h; Reflux;68.8%

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