As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t
Cas:102-04-5
Min.Order:1 Gram
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inquiryProduct description: Product name 1,3-Diphenylacetone CAS number 102-04-5 Assay ≥99% Appearance Yellowish solid or liquid Capacity 500mt/year Application Organic synthesis
Cas:102-04-5
Min.Order:100 Gram
FOB Price: $12.0
Type:Lab/Research institutions
inquiry1,3-Diphenylacetone CAS 102-04-5 Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed additives, Fine chemicals in distrib
Cas:102-04-5
Min.Order:1 Kilogram
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Type:Trading Company
inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:102-04-5
Min.Order:5 Kiloliter
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Type:Manufacturers
inquiryOur Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con
Cas:102-04-5
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:102-04-5
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:102-04-5
Min.Order:10 Kilogram
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Type:Trading Company
inquiryAppearance:Light yellow crystal Storage:R.T Package:25kg/drum Application:Organic Synthesis Intermediate Transportation:Express/Sea/Air Port:Any port in China
Cas:102-04-5
Min.Order:25 Kilogram
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Type:Lab/Research institutions
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:102-04-5
Min.Order:1 Kilogram
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inquiryProduct Name: 1,3-Diphenylacetone CAS: 102-04-5 MF: C15H14O MW: 210.27 EINECS: 203-000-0 Mol File: 102-04-5.mol 1,3-Diphenylacetone Structure 1,3-Diphenylacetone Chemical Properties Melting point 32-34 °C(lit.) Boiling poi
Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese
Cas:102-04-5
Min.Order:1 Kilogram
FOB Price: $72.0 / 84.0
Type:Trading Company
inquiry1,3-Diphenylacetone CAS:3102-87-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm
Cas:102-04-5
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:102-04-5
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Hangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting 1,3-Diphenylacetone 99%;Dibenzyl Ketone,cas no.:102-04-5, Please contact us by email freely. We are leading exporter in China. If yo
Cas:102-04-5
Min.Order:1 Metric Ton
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Type:Other
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:102-04-5
Min.Order:0 Metric Ton
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Cas:102-04-5
Min.Order:4 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryMassive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Cas:102-04-5
Min.Order:1 Gram
FOB Price: $1.0
Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:102-04-5
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryWe are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov
Cas:102-04-5
Min.Order:100 Gram
FOB Price: $100.0 / 2000.0
Type:Lab/Research institutions
inquiryEstablished in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site
Cas:102-04-5
Min.Order:10 Gram
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Type:Lab/Research institutions
inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:102-04-5
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:102-04-5
Min.Order:1 Kilogram
FOB Price: $18.0 / 20.0
Type:Trading Company
inquiryHangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu
Top quality lower price 1,3-Diphenylacetone 102-04-5 manufacturer Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to vari
Cas:102-04-5
Min.Order:1 Gram
Negotiable
Type:Other
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:102-04-5
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:102-04-5
Min.Order:1 Metric Ton
FOB Price: $1.5
Type:Trading Company
inquiry2,2-bis(benzyl)-1,3-dithiolane
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
With trichloroisocyanuric acid; silver nitrate In water; acetonitrile Ambient temperature; | 99% |
With (CH3)3CI; dimethyl sulfoxide for 12h; | 95% |
With trimethylsilyl iodide; dimethyl sulfoxide In tetrachloromethane at 75 - 80℃; for 6h; | 85% |
With hydrogenchloride; dihydrogen peroxide In methanol Ambient temperature; | 81% |
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile at 20 - 25℃; for 2h; Irradiation; | 98% |
Conditions | Yield |
---|---|
With chloral hydrate In hexane at 25℃; for 5h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With copper(II) sulfate In tetrahydrofuran; methanol; water for 4h; Heating; | 95% |
1,3-Diphenylpropanone oxime O-acetate
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
Stage #1: 1,3-Diphenylpropanone oxime O-acetate With dicobalt octacarbonyl; triethylamine In diethyl ether at 20℃; for 0.25h; deoximation; Stage #2: With water In methanol at 20℃; for 0.5h; Hydrolysis; | 93% |
With diiron nonacarbonyl In methanol at 60℃; for 1h; Product distribution; Fe(CO)5, UV irradiation; | 82% |
1,3-diphenylacetone N,N-dimethylhydrazone
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
With dihydrogen peroxide; methyltrioxorhenium(VII) In acetic acid; acetonitrile at 0 - 20℃; Product distribution; oxidative cleavage; | 93% |
With porcin pancreatic lipase In water; acetone at 20℃; for 96h; Hydrolysis; | 94 % Chromat. |
1,3-diphenyl-1-phenylsulfanylpropan-2-one
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
With zinc In acetic acid | 92% |
Conditions | Yield |
---|---|
With n-butyllithium at -78℃; for 8h; | 92% |
Conditions | Yield |
---|---|
With copper(II) sulfate In tetrahydrofuran; methanol; water for 19h; Heating; | 90% |
With iron pentacarbonyl In methanol for 48h; Product distribution; Irradiation; Fe2(CO)9, 60 deg C; | 81% |
With water; oxygen In acetonitrile at 60℃; under 760.051 Torr; for 6h; Autoclave; Green chemistry; | 32% |
With bismuth(lll) trifluoromethanesulfonate; bismuth(III) bromide In water; acetone; acetonitrile for 4h; Heating; | |
Multi-step reaction with 2 steps 1: acetic acid; chlorine 2: NaN3; aqueous acetic acid; CO2 View Scheme |
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)nickel(0); 4,4'-di-tert-butyl-2,2'-bipyridine; magnesium chloride; zinc In acetonitrile at 25℃; for 12h; Inert atmosphere; | 90% |
With bis(1,5-cyclooctadiene)nickel(0); 4,4'-di-tert-butyl-2,2'-bipyridine; magnesium chloride; zinc In acetonitrile at 25℃; for 12h; Schlenk technique; Inert atmosphere; | 90% |
With tetrabutylammonium tetrafluoroborate; (2,2'-bipyridine)nickel(II) dibromide In acetonitrile Ambient temperature; zinc rod as the anode, vitreous carbon gauze as the cathode, 0.1 A; | 80% |
With [2,2]bipyridinyl; tetrabutylammonium tetrafluoroborate; tris(2,2'-bipyridine)nickel(II) tetrafluoroborate In acetonitrile at 25℃; Product distribution; Kinetics; Electrochemical reaction; | |
With bis(1,5-cyclooctadiene)nickel(0); magnesium chloride; zinc In acetonitrile at 20℃; for 12h; Inert atmosphere; | 41 mmol |
Conditions | Yield |
---|---|
With (2,2'-bipyridine)nickel(II) dibromide; tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide Ambient temperature; electrolysis; | 90% |
benzyl bromide
A
phenylacetonitrile
B
1,1'-(1,2-ethanediyl)bisbenzene
C
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
add of carbon monoxide; | A 1% B 6% C 89% |
Conditions | Yield |
---|---|
With [2,2]bipyridinyl; chloro-trimethyl-silane; nickel(II) bromide 2-methoxyethyl ether complex; zinc In tetrahydrofuran; N,N-dimethyl acetamide at 40℃; for 2h; Sealed tube; Inert atmosphere; | 86% |
Conditions | Yield |
---|---|
With silica gel; cobalt(II) nitrate for 0.283333h; microwave irradiation; | 85% |
With pyridiniumchlorochromate on aluminumoxide at 20℃; for 20h; | 84% |
With boron trifluoride diethyl etherate; tetrabutylammonium periodite In acetonitrile for 4h; Heating; | 60% |
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In dimethylsulfoxide-d6 at 23℃; primary kinetic isotope effect by its α-deuterio analog; |
Conditions | Yield |
---|---|
With lithium tert-butoxide In tetrahydrofuran at 23℃; for 3h; Glovebox; | 81% |
Conditions | Yield |
---|---|
In acetonitrile Ambient temperature; Bu4NBF4, nickel rod anode, nickel foam catode, 1.5 A/dm2; | 80% |
With diethyl ether; triethylamine | |
Multi-step reaction with 4 steps 1: 98 percent / diethyl ether 2: 93 percent / diethyl ether 3: 89 percent / SnCl4 / Ambient temperature 4: 92 percent / Zn / acetic acid View Scheme | |
Multi-step reaction with 2 steps 1: dmap / dichloromethane / 96 h / Cooling with ice 2: 3,6-dimethyl-1,2,4,5-tetrazine / chloroform / 1 h / 20 °C View Scheme |
2,3-epoxy-1,3-diphenyl-2-phenylsulfinylpropane
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
With sodium phenylselenide In ethanol for 3h; Ambient temperature; | 80% |
With sodium phenylselenide In ethanol for 3h; Ambient temperature; | 80% |
carbon monoxide
benzyl chloride
A
1,1'-(1,2-ethanediyl)bisbenzene
B
toluene
C
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
With [2,2]bipyridinyl; tetrabutylammonium tetrafluoroborate; iron(II) chloride; Fe64/Ni36 anode In N,N-dimethyl-formamide Ambient temperature; electrolysis; | A 10 % Chromat. B n/a C 80% |
With [2,2]bipyridinyl; tetrabutylammonium tetrafluoroborate; iron(II) chloride; Fe64/Ni36 anode In N,N-dimethyl-formamide Product distribution; Mechanism; Ambient temperature; electrolysis, var. of electrode material, ligand, halogen, other aryl and alkyl halogenides; | A 10 % Chromat. B n/a C 90 % Chromat. |
2.2-Dibenzyl-1.3-dithian
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
With antimonypentachloride In dichloromethane at 0℃; for 0.166667h; | 78% |
With 2,4,6-triphenylpyrilium perchlorate; oxygen In acetonitrile for 5h; Irradiation; | 31% |
3,3,6,6-tetrabenzyl-1,2,4,5-tetraoxan
A
phenylacetic acid
B
benzyl 2-phenylacetate
C
1,1'-(1,2-ethanediyl)bisbenzene
D
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
In benzene at 150℃; for 72h; Product distribution; Mechanism; thermolysis; var. temp., time and solvent; | A n/a B 12% C 77% D 2% |
carbon monoxide
B
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
In toluene at 20℃; under 760.051 Torr; Inert atmosphere; Schlenk technique; | A 72% B 76% |
carbon monoxide
benzyl bromide
A
phenylacetic acid
B
benzyl 2-phenylacetate
C
1,1'-(1,2-ethanediyl)bisbenzene
D
toluene
E
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
iron pentacarbonyl; tetrabutylammonium sulfate In sodium hydroxide; benzene at 20℃; under 760 Torr; for 15h; Product distribution; variation of solvent, temperature, catalyst, pressure, reaction time and ratio of catalyst and substrate, examinations with further benzyl halides; | A 75% B 3% C 6% D 2% E 14% |
Conditions | Yield |
---|---|
add of carbon monoxide; | A 9% B 75% |
morpholine
3,3-bis(phenylmethyl)-1,2-dioxetane
A
N-<(2-benzyl-2-hydroxy-3-phenylpropyl)oxy>morpholine
B
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
In dichloromethane for 15h; | A 74% B 12% |
Conditions | Yield |
---|---|
With lithium; 4,4'-di-tert-butylbiphenyl In tetrahydrofuran for 60h; Ambient temperature; Irradiation; ultrasonic irradiation; | 73% |
Conditions | Yield |
---|---|
With (2,2'-bipyridine)nickel(II) dibromide; tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide Ambient temperature; electrolysis; | 70% |
Conditions | Yield |
---|---|
With dipotassium hydrogenphosphate; nickel(II) chloride hexahydrate; 4-acetoxybenzophenone; 4,4'-di-tert-butyl-2,2'-bipyridine at 35℃; for 48h; Inert atmosphere; Sealed tube; Irradiation; Schlenk technique; | 70% |
carbon monoxide
benzyl bromide
A
phenylacetic acid
B
benzyl 2-phenylacetate
C
1,1'-(1,2-ethanediyl)bisbenzene
D
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
iron pentacarbonyl; tetrabutylammonium sulfate In sodium hydroxide; dichloromethane at 20℃; under 760 Torr; for 20h; | A 69% B 7% C 3% D 20% |
iron pentacarbonyl; tetrabutylammonium sulfate In sodium hydroxide; dichloromethane at 25℃; under 45600 Torr; for 27h; | A 66% B 8% C 4% D 11% |
Conditions | Yield |
---|---|
With C41H50ClN3Pd; sodium t-butanolate In 1,4-dioxane at 100℃; for 4h; Reagent/catalyst; | 69% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate In methanol; water | 100% |
With sodium tetrahydroborate In methanol at 0℃; for 0.25h; Inert atmosphere; | 100% |
With C26H33ClN5Ru(1+)*BF4(1-); potassium tert-butylate In isopropyl alcohol for 4h; Inert atmosphere; High pressure; Reflux; | 100% |
Conditions | Yield |
---|---|
With acetic acid; acetone oxime at 135℃; for 1.5h; | 100% |
With hydroxylamine hydrochloride; glycine In N,N-dimethyl-formamide at 25℃; for 6h; | 98% |
With hydroxylamine hydrochloride; sodium acetate In ethanol; water Reflux; | 96% |
ethane-1,2-dithiol
1,3-Diphenylpropanone
2,2-bis(benzyl)-1,3-dithiolane
Conditions | Yield |
---|---|
Nafion-H In benzene Heating; | 100% |
With silica gel; zirconium(IV) chloride In dichloromethane for 0.5h; Ambient temperature; | 99% |
With silica gel; iron(III) chloride In dichloromethane Ambient temperature; | 98% |
Conditions | Yield |
---|---|
With trichloroacetic acid at 100℃; for 0.0833333h; Fischer indole synthesis; | 100% |
With phosphorus trichloride In benzene | 80% |
With Amberlite IR 120 In ethanol at 80℃; for 12h; Fischer Indole Synthesis; | 80% |
With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide In ethyl acetate at 110℃; for 0.25h; Fischer indole synthesis; Microwave irradiation; Sealed vessel; | 77% |
trimethyl phosphonoacetate
1,3-Diphenylpropanone
4-Phenyl-3-(phenylmethyl)-2-butenoic acid methyl ester
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium In diethyl ether; hexane 1.) -20 deg C, 20 min, 2.) r.t., 50 h; | 100% |
Conditions | Yield |
---|---|
With acetic acid In methanol Heating; | 100% |
Conditions | Yield |
---|---|
at 250℃; for 0.0166667h; Fischer indole synthesis; | 100% |
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
With La(Cp)3 In tetrahydrofuran at 20℃; for 2h; Reagent/catalyst; Inert atmosphere; | 100% |
With [RhCl2(p-cymene)]2 In neat liquid at 60℃; for 15h; Inert atmosphere; Glovebox; chemoselective reaction; | |
With C23H33MnN3Si2 In diethyl ether at 25℃; for 16h; Glovebox; Inert atmosphere; chemoselective reaction; |
malononitrile
1,3-Diphenylpropanone
2-(1,3-diphenylpropan-2-ylidene)malononitrile
Conditions | Yield |
---|---|
With ammonium acetate; acetic acid In benzene at 120℃; Knoevenagel Condensation; Dean-Stark; | 99% |
With ammonium acetate In acetic acid; benzene for 48h; Heating; | 65% |
Conditions | Yield |
---|---|
With lithium perchlorate In diethyl ether at 20℃; for 0.25h; | 99% |
Conditions | Yield |
---|---|
With C29H46LaN3Si2 at 15℃; for 4h; Inert atmosphere; Glovebox; Schlenk technique; | 99% |
With tris(2,4,6-trimethoxyphenyl)phosphine In N,N-dimethyl-formamide at 20℃; for 0.5h; Inert atmosphere; | 98% |
With L-proline potassium salt at 20℃; for 24h; | 92% |
With iodine In dichloromethane at 0℃; for 0.5h; | |
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 0.5h; |
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol | 98.8% |
1,2-di(4-methylphenyl)-1,2-ethanedione
1,3-Diphenylpropanone
2,5-diphenyl-3,4-di(p-tolyl)cyclopenta-2,4-dien-1-one
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol at -78℃; for 0.5h; | 98% |
With potassium hydroxide In ethanol for 0.25h; Heating; | 90% |
With sodium hydroxide In methanol for 2h; Aldol condensation; Reflux; | 86% |
1,3-Diphenylpropanone
benzyl α-chlorobenzyl ketone
Conditions | Yield |
---|---|
With chloro-trimethyl-silane; tetrabutylammomium bromide; dimethyl sulfoxide In acetonitrile for 1h; | 98% |
With [bis(acetoxy)iodo]benzene; iron(III) chloride hexahydrate In acetic acid at 20℃; for 12h; Inert atmosphere; | 82% |
With tetrachloromethane; sulfuryl dichloride at 40℃; anschliessend Erhitzen auf Siedetemperatur; | |
With sulfuryl dichloride In tetrachloromethane |
n-butyl magnesium bromide
1,3-Diphenylpropanone
1-phenyl-2-(phenylmethyl)-2-hexanol
Conditions | Yield |
---|---|
With cerium(III) chloride In tetrahydrofuran at 0℃; for 0.5h; | 98% |
With cerium(III) chloride In tetrahydrofuran at 0℃; for 1h; | 93% |
With cerium(III) chloride In tetrahydrofuran 1.) 0 deg C, 2 h, 2.) 0 deg C, 0.5 h; | 82% |
In tetrahydrofuran 1.) -78 deg C, 3 h 2.) 0 deg C, 1 h; | 20% |
n-butyllithium
1,3-Diphenylpropanone
1-phenyl-2-(phenylmethyl)-2-hexanol
Conditions | Yield |
---|---|
With cerium(III) triiodide In tetrahydrofuran at -65℃; for 3h; Product distribution; various lanthanoid chlorides; | 98% |
With cerium(III) triiodide In tetrahydrofuran at -65℃; | 98% |
With cerium(III) triiodide In tetrahydrofuran; hexane at -65℃; for 3h; | 98% |
With cerium(III) chloride at -78℃; for 3h; Product distribution; other organometallics; | 96% |
With cerium(III) chloride In tetrahydrofuran at -78℃; for 1.5h; | 96% |
Methyllanthanum triflate
1,3-Diphenylpropanone
2-methyl-1,3-diphenylpropan-2-ol
Conditions | Yield |
---|---|
In tetrahydrofuran at -78℃; for 0.166667h; Product distribution; Mechanism; other carbonyl compounds, other times; | 98% |
1,3-Diphenylpropanone
Conditions | Yield |
---|---|
With tetra(n-butyl)ammonium hydroxide In methanol; isopropyl alcohol; toluene at 80℃; Inert atmosphere; | 97.7% |
ethylene glycol
1,3-Diphenylpropanone
1,3-diphenyl-2-propanone ethylene acetal
Conditions | Yield |
---|---|
With diphenylamine-terephthalaldehyde resin p-toluenesulfonate with high sulfo group content In toluene for 6h; Dean-Stark; Reflux; | 97% |
With zeolite HSZ-360 In toluene for 5h; Heating; | 95% |
With Ti(4+)-exchanged montmorillonite In toluene for 3h; Heating; | 94% |
dimethyl methane phosphonate
1,3-Diphenylpropanone
dimethyl (2-benzyl-2-hydroxy-3-phenyl)propylphosphonate
Conditions | Yield |
---|---|
Stage #1: dimethyl methane phosphonate With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.0833333h; Metallation; Stage #2: 1,3-Diphenylpropanone In tetrahydrofuran; hexane at -78℃; for 0.0833333h; Addition; | 97% |
isopropylmagnesium chloride
1,3-Diphenylpropanone
2-Benzyl-3-methyl-1-phenyl-2-butanol
Conditions | Yield |
---|---|
With neodymium(III) chloride; lithium chloride In tetrahydrofuran at 0℃; | 97% |
Stage #1: 1,3-Diphenylpropanone With lanthanium (III) chloride bis(lithium chloride) complex In tetrahydrofuran Inert atmosphere; Stage #2: isopropylmagnesium chloride In tetrahydrofuran at 0 - 25℃; Inert atmosphere; | 86% |
Conditions | Yield |
---|---|
With trimethyl orthoformate at 20℃; for 2h; | 97% |
phenylmagnesium chloride
1,3-Diphenylpropanone
1,2,3-triphenyl-propan-2-ol
Conditions | Yield |
---|---|
Stage #1: 1,3-Diphenylpropanone With lanthanium (III) chloride bis(lithium chloride) complex In tetrahydrofuran Inert atmosphere; Stage #2: phenylmagnesium chloride In tetrahydrofuran at 0 - 25℃; Inert atmosphere; | 97% |
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol; toluene at 78℃; for 1.25h; | 96% |
With potassium hydroxide In ethanol Reflux; | 95% |
With potassium hydroxide In ethanol; toluene for 0.0833333h; Heating; | 94% |
Conditions | Yield |
---|---|
With Vanadium (III) chloride-(tris-tetrahydrofuran); zinc In dichloromethane for 12h; | 96% |
n-butylcerium dichloride
1,3-Diphenylpropanone
1-phenyl-2-(phenylmethyl)-2-hexanol
Conditions | Yield |
---|---|
In tetrahydrofuran at -78℃; for 3h; | 96% |
benzyltriphenylphosphonium bromide
1,3-Diphenylpropanone
2-benzyl-1,3-diphenyl-1-propene
Conditions | Yield |
---|---|
With sodium hydride In benzene 1.) reflux, 2 h, 2.) reflux, 120 h; | 96% |
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