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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Benzyl phenylacetate

Cas:102-16-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Benzyl phenylacetate

Cas:102-16-9

Min.Order:1

Negotiable

Type:Other

inquiry

Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality BENZYL PHENYLACETATE

Cas:102-16-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Benzyl phenylacetate

Cas:102-16-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 102-16-9 with best quality

Cas:102-16-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

BENZYL PHENYLACETATE CAS102-16-9

Cas:102-16-9

Min.Order:1 Kilogram

FOB Price: $289.0 / 489.0

Type:Trading Company

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

102-16-9 BENZYL PHENYLACETATE

Cas:102-16-9

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:Colorless to Almost colorless?neat Storage:room temperature Package:25kg/drum Application:Perfumery and flavors. Transportation:Express/Sea/Air Port:any port in china

benzylphenylacetate factory price

Cas:102-16-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzeneacetic acid,phenylmethyl ester 102-16-9

Cas:102-16-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzeneacetic acid,phenylmethyl ester

Cas:102-16-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Benzyl Phenylacetate 102-16-9 Pharma Grade For Human Health

Cas:102-16-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

BENZYL PHENYLACETATE

Cas:102-16-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzeneacetic acid,phenylmethyl ester

Cas:102-16-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung, LG, Merck, Thermo Fisher Scientific and so o

102-16-9 BENZYL PHENYLACETATE

Cas:102-16-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Benzyl Phenylacetate 102-16-9 Pharma Grade For Human Health

Cas:102-16-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Benzyl Phenylacetate 102-16-9 Pharma Grade For Human Health

Cas:102-16-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Benzyl Phenylacetate 102-16-9 Pharma Grade For Human Health

Cas:102-16-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Benzyl phenylacetate

Cas:102-16-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Benzyl Phenylacetate 102-16-9 Pharma Grade For Human Health

Cas:102-16-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Benzeneacetic acid,phenylmethyl ester

Cas:102-16-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Benzyl Phenylacetate

Cas:102-16-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

benzyl phenylacetate

Cas:102-16-9

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Benzeneacetic acid,phenylmethyl ester

Cas:102-16-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Benzyl Phenylacetate

Cas:102-16-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

benzyl phenylacetate

Cas:102-16-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

BENZYL PHENYLACETATE

Cas:102-16-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

BENZYL PHENYLACETATE

Cas:102-16-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzyl phenylacetate

Cas:102-16-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

Benzyl Phenylacetate 102-16-9 Pharma Grade For Human Health Application:Benzyl Phenylacetate 102-16-9 Pharma Grade For Human Health

Benzyl Phenylacetate 102-16-9 Pharma Grade For Human Health

Cas:102-16-9

Min.Order:0

Negotiable

Type:Other

inquiry

DB BIOTECH CO., LTD

best seller Application:API

BENZYL PHENYLACETATE

Cas:102-16-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

phenylacetyl chloride
103-80-0

phenylacetyl chloride

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere;100%
With samarium In acetonitrile at 70℃; for 0.0333333h;92%
With triethylamine In dichloromethane at 20℃; for 12h;70.1%
phenylacetic acid
103-82-2

phenylacetic acid

benzyl bromide
100-39-0

benzyl bromide

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With potassium carbonate In acetone at 60℃;100%
With potassium carbonate In acetone Heating;99%
With hydrogen fluoride; mercury(II) oxide In 1,2-dichloro-ethane at 80℃; for 1h;79%
phenylacetic acid
103-82-2

phenylacetic acid

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With glucose-diphenylaminium tosylate-derived carbon solid acid (GDTCSA) In n-heptane at 80℃; for 1h;99%
With monoammonium 12-tungstophosphate for 12h; Heating;98%
With [bis(acetoxy)iodo]benzene; triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran at 25℃; for 16h; Mitsunobu reaction;97%
benzyl alcohol
100-51-6

benzyl alcohol

benzeneacetic acid methyl ester
101-41-7

benzeneacetic acid methyl ester

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With C16H25N3O2S In n-heptane for 48h; Reflux; Molecular sieve; Inert atmosphere;99%
With 1,3-bis(3,5-bis(trifluoro-ethyl)phenyl)thiourea; 4-pyrrolidin-1-ylpyridine In octane for 6h; Reflux;98%
With SO3H and NH2+ functional carbon-based solid acid at 80℃; for 6h;92%
benzyl 2-hydroxy-2-phenylacetate
62173-99-3, 80409-16-1, 97415-09-3, 890-98-2

benzyl 2-hydroxy-2-phenylacetate

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
Stage #1: benzyl 2-hydroxy-2-phenylacetate With dmap; triethylamine; chlorophosphoric acid diphenyl ester In tetrahydrofuran at 20℃;
Stage #2: With dichloro bis(acetonitrile) palladium(II); sodium tetrahydroborate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In tetrahydrofuran; 1,2-dimethoxyethane at 75℃;
99%
2,6-dimethylpyridine
108-48-5

2,6-dimethylpyridine

phenylacetic acid
103-82-2

phenylacetic acid

2-chloro-1-methyl-pyridinium iodide
14338-32-0

2-chloro-1-methyl-pyridinium iodide

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With benzyl alcohol In dichloromethane98%
phenylacetic acid
103-82-2

phenylacetic acid

2-chloro-1-methyl-pyridinium iodide
14338-32-0

2-chloro-1-methyl-pyridinium iodide

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With tributyl-amine; benzyl alcohol In diethyl ether97%
phenylacetic acid
103-82-2

phenylacetic acid

2-bromo-1-methyl-pyridinium iodide
52693-56-8

2-bromo-1-methyl-pyridinium iodide

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With tributyl-amine; benzyl alcohol In dichloromethane97%
3-(2-phenylacetyl)-1,3-oxazolidin-2-one
109853-53-4

3-(2-phenylacetyl)-1,3-oxazolidin-2-one

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
lanthanum(III) iodide In tetrahydrofuran Ambient temperature;95%
phenylacetic acid
103-82-2

phenylacetic acid

1-ethyl-2-iodoquinolinium iodide
4800-58-2

1-ethyl-2-iodoquinolinium iodide

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With tributyl-amine; benzyl alcohol In dichloromethane95%
phenylacetic acid
103-82-2

phenylacetic acid

2-chloro-1-ethyl-4-methoxypryridinium tetrafluoroborate

2-chloro-1-ethyl-4-methoxypryridinium tetrafluoroborate

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With triethylamine; benzyl alcohol In dichloromethane95%
phenylacetic acid
103-82-2

phenylacetic acid

benzyl chloroformate
501-53-1

benzyl chloroformate

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With triethylamine; dmap In dichloromethane at 0℃; for 1h;94%
With dmap; triethylamine 1.) CH2Cl2, 0 deg C, 5 min, 2.) 0 deg C, 1 h; Yield given. Multistep reaction;
(S)-4-iso-propyl-3-(2'-phenylacetyl)oxazolidin-2-one
103422-95-3, 138690-03-6

(S)-4-iso-propyl-3-(2'-phenylacetyl)oxazolidin-2-one

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
lanthanum(III) iodide In tetrahydrofuran Ambient temperature;93%
carbon monoxide
201230-82-2

carbon monoxide

benzyl alcohol
100-51-6

benzyl alcohol

A

phenylacetic acid
103-82-2

phenylacetic acid

B

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

C

toluene
108-88-3

toluene

Conditions
ConditionsYield
With hydrogen iodide; tetrakis(triphenylphosphine) palladium(0) In acetone at 90℃; under 68400 Torr; for 44h; Carbonylation; reduction;A 90%
B 3%
C 6%
With tetrakis(triphenylphosphine) palladium(0); hydrogen iodide In acetone at 90℃; under 68400 Torr; for 44h;A 90 % Spectr.
B 3 % Spectr.
C 6 % Spectr.
With tetrakis(triphenylphosphine) palladium(0); hydrogen iodide In acetone at 90℃; under 68400 Torr; for 44h;A 24 % Spectr.
B 58 % Spectr.
C 7 % Spectr.
phenylacetic acid
103-82-2

phenylacetic acid

benzylamine
100-46-9

benzylamine

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With sodium nitrite In acetonitrile at 0 - 20℃; for 0.416667h;90%
2-iodobenzyl 2-chloro-2-phenylacetate
1166870-60-5

2-iodobenzyl 2-chloro-2-phenylacetate

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With [Ir(2-phenylpyridine)-2-(4,4’-di-tert-butyl-2,2’-bipyridine)]PF6; N-ethyl-N,N-diisopropylamine In acetonitrile at 25℃; for 1h; Irradiation;90%
With [Ir(2-phenylpyridine)-2-(4,4’-di-tert-butyl-2,2’-bipyridine)]PF6; N-ethyl-N,N-diisopropylamine In acetonitrile at 25℃; for 3h; Irradiation;
Benzeneacetamide
103-81-1

Benzeneacetamide

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) In n-heptane at 100℃; for 24h;90%
With cerium(IV) oxide In 1,3,5-trimethyl-benzene at 165℃; for 22h; Inert atmosphere;86%
phenylacetyl fluoride
370-84-3

phenylacetyl fluoride

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃;88%
p-toluidine
106-49-0

p-toluidine

(2RS)-2-benzyloxy-3-phenylpropanal
256229-10-4

(2RS)-2-benzyloxy-3-phenylpropanal

A

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

B

N-(4-methylphenyl)formamide
3085-54-9

N-(4-methylphenyl)formamide

Conditions
ConditionsYield
With trifluoroacetic acid In toluene at 50℃; for 1h;A 86%
B n/a
Ethyl 2-phenylethanoate
101-97-3

Ethyl 2-phenylethanoate

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With titanium(IV) tetraethanolate at 110℃; for 15h;85%
bromobenzene
108-86-1

bromobenzene

benzyl glycolate
30379-58-9

benzyl glycolate

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; triphenylphosphine; 4,4'-di-tert-butyl-2,2'-bipyridine; lithium bromide; nickel dibromide In 1-methyl-pyrrolidin-2-one at 20℃; for 14h; Glovebox; Electrolysis;85%
Phenyl-acetic acid [2,2']bipyridinyl-6-yl ester
75178-11-9

Phenyl-acetic acid [2,2']bipyridinyl-6-yl ester

benzyl alcohol
100-51-6

benzyl alcohol

A

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

B

<2,2'-bipyridin>-6(1H)-one
101001-90-5

<2,2'-bipyridin>-6(1H)-one

Conditions
ConditionsYield
With cesium fluoride In dichloromethane for 72h; Ambient temperature;A 83%
B n/a
phenylacetic acid
103-82-2

phenylacetic acid

A

7β-[α-carboxy-α-phenylacetamido]-3-methyl-Δ3 -0-2-isocephem-4-carboxylic acid

7β-[α-carboxy-α-phenylacetamido]-3-methyl-Δ3 -0-2-isocephem-4-carboxylic acid

B

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With toluene-4-sulfonic acid; benzyl alcohol In tolueneA n/a
B 83%
N,N,N-­trimethyl-­1-­phenylmethanaminium trifluoromethanesulfonate
260783-80-0

N,N,N-­trimethyl-­1-­phenylmethanaminium trifluoromethanesulfonate

carbon monoxide
201230-82-2

carbon monoxide

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate; triphenylphosphine In toluene at 100℃; under 760.051 Torr; for 12h; Catalytic behavior; Solvent; Reagent/catalyst; Temperature; Schlenk technique;82%
phenylacetic acid
103-82-2

phenylacetic acid

benzyl chloride
100-44-7

benzyl chloride

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With tetrabutylammomium bromide; potassium carbonate; potassium iodide In diethoxymethane at 80 - 85℃; for 6h;81%
With triethylamine at 90℃; for 2h;70%
With potassium fluoride; 1,3-dimethylimidazolinium methanesulfonate at 90℃; for 2h;
(S)-4-benzyl-3-phenylacetyl-2-oxazolidinone
104266-89-9

(S)-4-benzyl-3-phenylacetyl-2-oxazolidinone

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
lanthanum(III) iodide In tetrahydrofuran Ambient temperature;78%
3,3,6,6-tetrabenzyl-1,2,4,5-tetraoxan
71916-06-8

3,3,6,6-tetrabenzyl-1,2,4,5-tetraoxan

A

phenylacetic acid
103-82-2

phenylacetic acid

B

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

C

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

D

1,3-Diphenylpropanone
102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
In benzene at 150℃; for 72h; Product distribution; Mechanism; thermolysis; var. temp., time and solvent;A n/a
B 12%
C 77%
D 2%
carbon monoxide
201230-82-2

carbon monoxide

benzyl bromide
100-39-0

benzyl bromide

A

phenylacetic acid
103-82-2

phenylacetic acid

B

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

C

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

D

toluene
108-88-3

toluene

E

1,3-Diphenylpropanone
102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
iron pentacarbonyl; tetrabutylammonium sulfate In sodium hydroxide; benzene at 20℃; under 760 Torr; for 15h; Product distribution; variation of solvent, temperature, catalyst, pressure, reaction time and ratio of catalyst and substrate, examinations with further benzyl halides;A 75%
B 3%
C 6%
D 2%
E 14%
carbon monoxide
201230-82-2

carbon monoxide

benzyl trifluoroacetate
351-70-2

benzyl trifluoroacetate

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

Conditions
ConditionsYield
With 1,3-bis-(diphenylphosphino)propane; triethylamine; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl-formamide at 100℃; for 24h;74%
methanol
67-56-1

methanol

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

benzeneacetic acid methyl ester
101-41-7

benzeneacetic acid methyl ester

Conditions
ConditionsYield
With tert-butylamine; lithium bromide for 0.25h; Heating;100%
With indium; iodine for 12h; transesterification; Heating;88%
In acetonitrile Ambient temperature; Et4NClO4 electrolyte, glassy carbon cathode, Pt anode, -1,7 V potential;43%
With PCS-DBU In water at 60℃; Rate constant; Mechanism; other quaternary ammonium resins, other temperatures, other reaction time;
benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

phenylacetic acid
103-82-2

phenylacetic acid

Conditions
ConditionsYield
With scandium(III) tris(trifluoromethylsulfonyl)methide; methoxybenzene at 100℃; for 0.5h; debenzylation;100%
Stage #1: benzyl 2-phenylacetate With sodium methylate; dimethylsulfoxonium methylide In tetrahydrofuran at 20℃; for 0.666667h;
Stage #2: With hydrogenchloride; water In ethyl acetate
90%
With methanol; sodium tetrahydroborate; nickel(II) chloride hexahydrate at 20℃; for 0.166667h; chemoselective reaction;83%
benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

2-phenylethanol
60-12-8

2-phenylethanol

Conditions
ConditionsYield
With tri-n-butyl-tin hydride; hafnium tetrachloride In tetrahydrofuran at -20℃; for 3h; Inert atmosphere;99%
With (Ppyz)Zr(BH4)2Cl2 In diethyl ether for 8h; Heating;92%
With phenylsilane; potassium tert-butylate; water; sodium triethylborohydride; cobalt(II) chloride In 1,4-dioxane; toluene at 60℃; for 15h; Inert atmosphere; Glovebox; Schlenk technique;84%
carbon monoxide
201230-82-2

carbon monoxide

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

A

phenylacetic acid
103-82-2

phenylacetic acid

B

toluene
108-88-3

toluene

Conditions
ConditionsYield
With hydrogen iodide; tetrakis(triphenylphosphine) palladium(0) In acetone at 100℃; under 76000 Torr; for 42h; Carbonylation; reduction;A 98%
B 17%
trimethylsilyl trifluoromethanesulfonate
27607-77-8

trimethylsilyl trifluoromethanesulfonate

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

(1-(benzyloxy)-2-phenylethoxy)trimethylsilane

(1-(benzyloxy)-2-phenylethoxy)trimethylsilane

Conditions
ConditionsYield
Stage #1: benzyl 2-phenylacetate With diisobutylaluminium hydride In dichloromethane at -78℃; for 2h; Inert atmosphere;
Stage #2: trimethylsilyl trifluoromethanesulfonate With pyridine In dichloromethane at -78℃; for 3h; Inert atmosphere;
Stage #3: With sodium tartrate; potassium tartrate In dichloromethane; water at -78℃; for 0.25h; Inert atmosphere;
91%
benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

diphenyl diselenide
1666-13-3

diphenyl diselenide

A

phenylacetic acid
103-82-2

phenylacetic acid

B

benzyl phenyl selenide
18255-05-5

benzyl phenyl selenide

Conditions
ConditionsYield
Stage #1: diphenyl diselenide With aluminum (III) chloride; zinc In acetonitrile at 70℃; under 760.051 Torr; for 1.25h; Neutral;
Stage #2: benzyl 2-phenylacetate In acetonitrile at 70℃; under 760.051 Torr; for 12h; Neutral;
A 88%
B n/a
benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

benzoyl chloride
98-88-4

benzoyl chloride

3-oxo-2,3-diphenylpropionic acid benzyl ester
512176-69-1

3-oxo-2,3-diphenylpropionic acid benzyl ester

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 1h;87%
benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

α-diazo-α-phenylacetic acid benzyl ester
218792-82-6

α-diazo-α-phenylacetic acid benzyl ester

Conditions
ConditionsYield
With 4-toluenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃;86%
With 4-acetamidobenzenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃;86%
Stage #1: benzyl 2-phenylacetate With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃; for 0.416667h;
Stage #2: With 4-acetamidobenzenesulfonyl azide In acetonitrile
80%
benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

benzyl 2-azido-2-phenylacetate
1263368-81-5

benzyl 2-azido-2-phenylacetate

Conditions
ConditionsYield
With sodium azide; 4,4'-bis-(dichloroiodo)-biphenyl; triethylamine In 1,4-dioxane for 4h; Reflux;85%
Multi-step reaction with 2 steps
1: 4-toluenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene / acetonitrile / 20 °C / Inert atmosphere; Schlenk technique
2: tris(pentafluorophenyl)borate; trimethylsilylazide / dichloromethane / 4 h / 0 - 20 °C / Inert atmosphere; Schlenk technique; Molecular sieve
View Scheme

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