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Dayang Chem (Hangzhou) Co.,Ltd.

Index Name Specifications Appearance Most yellow transparent liquid Assay 95.0 to 103.0% Acidity Tes

N,N-Diethyl-3-methylbenzamide

Cas:134-62-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hefei TNJ chemical industry co.,ltd

Certificate for pesticide temporary registration If you want to buy DEET, please contact our company TNJ Chemical Appearance:Colorless to Amberlike Liquid Storage:Keep in cool place Package:200kg/Drum Application:It is for a variety of solid and

N,N-Diethyl-3-methylbenzamide/DEET

Cas:134-62-3

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

inquiry

Hunan Xuetian Fine Chemical Industry Co,.Ltd

Deet Deet, chemical name N, N-diethyl m-toluamide, a kind of excellent broad-spectrum mosquito repellent recognized in the world and recommended by WHO. It is used to be called DEET or DETA abroad. Deet can be used to make repellent floral w

Top quality 99.5%Deet

Cas:134-62-3

Min.Order:500 Kilogram

Negotiable

Type:Manufacturers

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality N,N-Diethyl-m-toluamide supplier in China

Cas:134-62-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance Clear,Colorless or light yellow liquid,free of foreign matter and suspended solids Colorless liquid

High purity 134-62-3 N,N-Diethyl-3-methylbenzamide

Cas:134-62-3

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

N,N-Diethyl-3-methylbenzamide CAS NO.134-62-3

Cas:134-62-3

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Unique advantages for N,N-Diethyl-m-toluamide Cas134-62-3 Guaranteed the purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Colorless liquid Storage:Refrigerator Package:200kg/plastic drum Applic

Favorable price N,N-Diethyl-m-toluamide Cas134-62-3 with good quality

Cas:134-62-3

Min.Order:200 Kilogram

FOB Price: $7.0 / 9.0

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply N,N-diethyl-m-toluamide (DEET)

Cas:134-62-3

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

huge stock TC Insecticide N,N-Diethyl-m-toluamide 134-62-3 GLP Manufacturer

Cas:134-62-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

N,N-Diethyl m-methylbenzamide (DEET)

Cas:134-62-3

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Sinoway Industrial Co., Ltd.

Why is SINOWAY: 1) Specialized in pharmaceutical and healthcare industrial for 34 years. 2) ISO 9001:2015 & SGS audited supplier . 3) Accept various payment terms : T.T 30-60 days. 4) We have warehouse in USA with quickly shipment . 5) We c

Factory supply Deet/N,N-Diethyl-m-toluamide CAS 134-62-3

Cas:134-62-3

Min.Order:100 Kilogram

FOB Price: $5.0

Type:Trading Company

inquiry

Hubei DiBo chemical co., LTD

Name: N,N-Diethyl-3-methylbenzamide CAS no. : 134-62-3 Molecular formula: C12H17NO Molecular weight:191.2695 Product Quality 12 years of chemical raw materials Mature operation of the industry System stability Data storage Security withou

N,N-Diethyl-3-methylbenzamide /CAS :134-62-3 /raw material/high-quality

Cas:134-62-3

Min.Order:25 Kilogram

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: N,N-Diethyl-m-toluamide Synonyms: bepperdet;Delphene;det(insectrepellant);DETA-20;detamid;Detamide;Dieltamid;ENT 22542 CAS: 134-62-3 MF: C12H17NO MW: 191.27 EINECS: 205-149-7 398- Appear

134-62-3 N,N-Diethyl-m-toluamide

Cas:134-62-3

Min.Order:1 Gram

FOB Price: $8900.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

N,N-Diethyl-m-toluamide

Cas:134-62-3

Min.Order:1 Gram

FOB Price: $1.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 134-62-3 with best quality

Cas:134-62-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Name: N,N-Diethyl-3-methylbenzamide Synonyms: DEET; N,N-Diethyl-m-toluamide CAS:134-62-3 MF: C12H17NO Appearance:Colorless to yellowish liquid Storage: Preserve in well-closed, light-resistant and airtight containers. Package: 25kgs/drum Applic

N,N-Diethyl-3-methylbenzamide CAS:134-62-3

Cas:134-62-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:Powder Storage:Store in sealed containers at cool & dry plac

CAS 134-62-3 N,N-Diethyl-3-methylbenzamide

Cas:134-62-3

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

N,N-Diethyl-3-methylbenzamide 134-62-3

Cas:134-62-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: N,N-Diethyl-m-toluamide CAS: 134-62-3 MF: C12H17NO MW: 191.27 EINECS: 205-149-7 Mol File: 134-62-3.mol N,N-Diethyl-m-toluamide Structure N,N-Diethyl-m-toluamide Chemical Properties Melting point -45 °C Boilin

N,N-Diethyl-m-toluamide

Cas:134-62-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Insect repellent N,N-Diethyl-m-toluamide with CAS:134-62-3

Cas:134-62-3

Min.Order:1 Kilogram

FOB Price: $8.0 / 10.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

N,N-Diethyl-m-toluamide CAS: 134-62-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic in

N,N-Diethyl-m-toluamide CAS: 134-62-3

Cas:134-62-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

N,N-Diethyl-3-methylbenzamide

Cas:134-62-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Wonda Pharm Limited

1.high quality: quality is life. quality is the most important element for all goods. we have a lab doing research in wuhan china. hplc and nmr is available if needed. 2.reasonable price: we provide high quality products wi

bepperdet ; Delphene; det(insectrepellant) ; DETA-20; detamid ; Detamide; Dieltamid

Cas:134-62-3

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 134-62-3 N,N-Diethyl-m-toluamide

Cas:134-62-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several

N,N-Diethyl-3-methylbenzamide cas:134-62-3

Cas:134-62-3

Min.Order:25 Gram

FOB Price: $90.0 / 100.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

N,N-Diethyl-3-methylbenzamide

Cas:134-62-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Terui OP New Material Technology Co., Ltd.

We have overseas warehouses in California, New Laredo Mexico, Vancouver Canada, Amsterdam Netherlands, and Melbourne Australia. Overseas warehouses can provide some of the best-selling products. We look forward to the cooperation of local powerful

Safe and fast delivery, great priceN,N-Diethyl-m-toluamide CAS 134-62-3

Cas:134-62-3

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

N,N-Diethyl-3-methylbenzamide CAS NO.134-62-3

Cas:134-62-3

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Triumph International Development Limilted

Appearance:white powder/crystal Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common products:Sea/A

N,N-Diethyl-3-methylbenzamide

Cas:134-62-3

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

diethylamine
109-89-7

diethylamine

3-Methylbenzoyl chloride
1711-06-4

3-Methylbenzoyl chloride

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With sodium hydroxide In water at 45℃; for 0.05h; Temperature; Reagent/catalyst;97.5%
With benzene
With triethylamine Heating; Microwave irradiation;
With triethylamine In dichloromethane at 0 - 20℃;
at 0 - 20℃; for 20h; Alkaline conditions;
N,N-diethylcarbamyl chloride
88-10-8

N,N-diethylcarbamyl chloride

m-Toluic acid
99-04-7

m-Toluic acid

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With triethylamine at 20℃; for 0.333333h;97.5%
With triethylamine at 20℃; for 0.333333h;97.5%
diethylamine
109-89-7

diethylamine

m-Toluic acid
99-04-7

m-Toluic acid

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With Zn-MCM-22 catalyst at 100 - 280℃; under 15001.5 Torr; for 6h; Inert atmosphere; Large scale;96%
Stage #1: m-Toluic acid With niobium pentachloride In dichloromethane
Stage #2: diethylamine In dichloromethane at 45 - 50℃; for 2.5h;
85%
hydroxy-apatite at 280 - 320℃; Product distribution; other catalysts; var. reaction time and temp.; influence of mineral acids with different pKa values;
N-formyldiethylamine
617-84-5

N-formyldiethylamine

m-Toluic acid
99-04-7

m-Toluic acid

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With hydrogenchloride; 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide In 1,4-dioxane at 120℃; for 22h;91%
3-Methylbenzonitrile
620-22-4

3-Methylbenzonitrile

diethylamine
109-89-7

diethylamine

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
Stage #1: diethylamine With ethylmagnesium bromide In tetrahydrofuran; diethyl ether at 30℃; for 1h;
Stage #2: 3-Methylbenzonitrile With ethylmagnesium bromide In diethyl ether; dichloromethane at 30℃; for 1h;
Stage #3: With hydrogenchloride In tetrahydrofuran; diethyl ether; dichloromethane at 22℃;
90%
3-Methylbenzotrichloride
3335-34-0

3-Methylbenzotrichloride

triethylamine
121-44-8

triethylamine

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With heptamethyl Coβ-perchlorato-cob(II)yrinate; tetrabutylammonium perchlorate In acetonitrile at 20℃; for 3h; Electrolysis;90%
carbon monoxide
201230-82-2

carbon monoxide

3-Iodotoluene
625-95-6

3-Iodotoluene

diethylamine
109-89-7

diethylamine

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With palladium diacetate; triethylamine; triphenylphosphine In toluene at 80℃; for 18h; Sealed tube;89%
With potassium carbonate In N,N-dimethyl-formamide at 120℃; under 750.075 Torr; for 2h; Autoclave; chemoselective reaction;85%
With triethylamine In N,N-dimethyl acetamide at 130℃; under 15001.5 Torr; for 1.5h; Autoclave; Green chemistry;84%
triethylamine
121-44-8

triethylamine

m-Toluic acid
99-04-7

m-Toluic acid

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With trifuran-2-yl-phosphane; palladium diacetate; 2,2-dimethylpropanoic anhydride In toluene at 120℃; for 15h; Inert atmosphere;89%
m-toluic acid diethylammonium salt

m-toluic acid diethylammonium salt

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
at 200℃; for 0.0277778h; Product distribution / selectivity; microwave irradiation;88%
potassium trifluoro(3-methylphenyl)borate

potassium trifluoro(3-methylphenyl)borate

2-(diethylamino)-2-oxoacetic acid
55441-26-4

2-(diethylamino)-2-oxoacetic acid

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With dipotassium peroxodisulfate; palladium diacetate In water; dimethyl sulfoxide; acetonitrile at 20℃;86%
m-toluic acid diethylammonium salt

m-toluic acid diethylammonium salt

A

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

B

N-ethyl-m-Toluamide
26819-07-8

N-ethyl-m-Toluamide

Conditions
ConditionsYield
With tetrabutoxytitanium at 200℃; under 15001.5 Torr; for 0.0333333h; Product distribution / selectivity; microwave irradiation;A 81%
B 9%
furfural
98-01-1

furfural

3-Iodotoluene
625-95-6

3-Iodotoluene

triethylamine
121-44-8

triethylamine

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With Wilkinson’s catalyst; 1,3-bis-(diphenylphosphino)propane; water In tetrahydrofuran at 140℃; for 12h; Inert atmosphere; Sealed tube;80%
diethyl amine hydrochloride
660-68-4

diethyl amine hydrochloride

m-Toluic acid
99-04-7

m-Toluic acid

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With silica gel; triethylamine; p-toluenesulfonyl chloride at 20℃; for 0.0166667h;76%
With triethylamine at 20℃; for 0.0166667h;60%
1,2:3,4-di-O-isopropylidene-α-D-galactopyranose
4064-06-6

1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

N,N-diethyl-α,α-difluoro-(meta-methylbenzyl)amine
500131-50-0

N,N-diethyl-α,α-difluoro-(meta-methylbenzyl)amine

A

6-deoxy-6-fluoro-1,2:3,4-di-O-isopropylidene-α-D-galctopyranose
2021-97-8, 6185-32-6, 70981-54-3

6-deoxy-6-fluoro-1,2:3,4-di-O-isopropylidene-α-D-galctopyranose

B

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
In n-heptane for 0.333333h; microwave irradiation;A 70%
B n/a
isopropyl 2-(diethylcarbamoyl)-4-methylbenzoate

isopropyl 2-(diethylcarbamoyl)-4-methylbenzoate

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); sodium t-butanolate In toluene at 20 - 180℃; for 14h; Inert atmosphere; Glovebox; Sealed tube;64%
N,N-Diethyl-3-methyl-2-(2-methyl-propane-2-sulfonyl)-benzamide
118354-88-4

N,N-Diethyl-3-methyl-2-(2-methyl-propane-2-sulfonyl)-benzamide

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
With hydrogen; nickel In ethanol for 15h; Heating;55%
tert-butyl phenyl sulfide
3019-19-0

tert-butyl phenyl sulfide

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: H2O2 / acetic acid / 3 h / 100 °C
2: 1.) n-BuLi / 1.) THF, -78 deg C, 0.5 h, 2.) -78 deg C
3: 1.) n-BuLi / 1.) THF, -78 deg C, 30 min, 2.) -78 deg C
4: 55 percent / H2 / Raney Ni / ethanol / 15 h / Heating
View Scheme
tert-butyl-phenyl sulfone
4170-72-3

tert-butyl-phenyl sulfone

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 1.) n-BuLi / 1.) THF, -78 deg C, 0.5 h, 2.) -78 deg C
2: 1.) n-BuLi / 1.) THF, -78 deg C, 30 min, 2.) -78 deg C
3: 55 percent / H2 / Raney Ni / ethanol / 15 h / Heating
View Scheme
2-<(1,1-dimethylethyl)sulphonyl>-N,N'-diethylbenzamide
118335-04-9

2-<(1,1-dimethylethyl)sulphonyl>-N,N'-diethylbenzamide

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1.) n-BuLi / 1.) THF, -78 deg C, 30 min, 2.) -78 deg C
2: 55 percent / H2 / Raney Ni / ethanol / 15 h / Heating
View Scheme
phenyllithium
591-51-5

phenyllithium

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: tetrahydrofuran / -78 °C
2: H2O2 / acetic acid / 3 h / 100 °C
3: 1.) n-BuLi / 1.) THF, -78 deg C, 0.5 h, 2.) -78 deg C
4: 1.) n-BuLi / 1.) THF, -78 deg C, 30 min, 2.) -78 deg C
5: 55 percent / H2 / Raney Ni / ethanol / 15 h / Heating
View Scheme
diethylamine
109-89-7

diethylamine

m-toluic acid n-butyl ester

m-toluic acid n-butyl ester

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
sodium ethanolate at 305℃; under 26252.6 Torr; for 0.00944444h; autoclave; Industry scale; Microwave irradiation;
ortho-methylbenzoic acid
118-90-1

ortho-methylbenzoic acid

thionyl chloride
7719-09-7

thionyl chloride

dichloromethane
75-09-2

dichloromethane

dibenzylamine
103-49-1

dibenzylamine

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
Stage #1: ortho-methylbenzoic acid; thionyl chloride; dichloromethane With N,N-dimethyl-formamide for 2h; Reflux;
Stage #2: dibenzylamine at 20℃;
diethylamine
109-89-7

diethylamine

3-(3-methylbenzoyl)-5,5-dimethylhydantoin

3-(3-methylbenzoyl)-5,5-dimethylhydantoin

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
In ethyl acetate at 50℃; Sealed tube;
3-methylbenzyl alcohol
587-03-1

3-methylbenzyl alcohol

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium hydrogencarbonate; iron(III) chloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / acetonitrile; water / 35 °C
2: ethyl acetate / 50 °C / Sealed tube
View Scheme
m-Toluic acid
99-04-7

m-Toluic acid

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1,3,5-trichloro-2,4,6-triazine; 1-pyrrolidinecarboxaldehyde / acetonitrile / Heating
2: 20 h / 0 - 20 °C / Alkaline conditions
View Scheme
2-bromo-5-methylbenzoic acid
6967-82-4

2-bromo-5-methylbenzoic acid

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: oxalyl dichloride / N,N-dimethyl-formamide; dichloromethane / 2 h / 0 - 20 °C
1.2: 0 - 20 °C
2.1: zinc(II) chloride; diisobutylaluminium hydride; magnesium; lithium chloride / tetrahydrofuran / 6 h / 20 °C / Inert atmosphere
2.2: 50 °C / Inert atmosphere
3.1: bis(1,5-cyclooctadiene)nickel (0); sodium t-butanolate / toluene / 14 h / 20 - 180 °C / Inert atmosphere; Glovebox; Sealed tube
View Scheme
2-bromo-N,N-diethyl-5-methylbenzamide

2-bromo-N,N-diethyl-5-methylbenzamide

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: zinc(II) chloride; diisobutylaluminium hydride; magnesium; lithium chloride / tetrahydrofuran / 6 h / 20 °C / Inert atmosphere
1.2: 50 °C / Inert atmosphere
2.1: bis(1,5-cyclooctadiene)nickel (0); sodium t-butanolate / toluene / 14 h / 20 - 180 °C / Inert atmosphere; Glovebox; Sealed tube
View Scheme
N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

N-ethyl-N-(3-methylbenzyl)ethanamine
22704-60-5

N-ethyl-N-(3-methylbenzyl)ethanamine

Conditions
ConditionsYield
With n-butyllithium; borane-THF; diisopropylamine at 25℃;99%
With lithium (diisopropylamino)borohydride In tetrahydrofuran at 25℃; for 2h;99%
With diisobutylaluminum borohydride In tetrahydrofuran at 0 - 25℃; Inert atmosphere;99%
styrene
292638-84-7

styrene

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

N,N-diethyl-5-methyl-2-(1-phenylethyl)benzamide
1620210-49-2

N,N-diethyl-5-methyl-2-(1-phenylethyl)benzamide

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; 1,4-bis[bis(pentafluorophenyl)phosphino]butane In 1,4-dioxane at 100℃; for 48h; Sealed tube; Inert atmosphere;99%
N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

N,N-diethyl-αlpha;-chloro-meta-toluylamidinum chloride
500131-49-7

N,N-diethyl-αlpha;-chloro-meta-toluylamidinum chloride

Conditions
ConditionsYield
With oxalyl dichloride In tetrachloromethane at 0 - 50℃; for 1.5h;98%
With oxalyl dichloride In tetrachloromethane at 0 - 50℃; for 1.5h;98%
With oxalyl dichloride In tetrachloromethane at 0 - 50℃; for 1.5h;
With oxalyl dichloride In tetrachloromethane at 0 - 50℃; for 1.5h;
1,1,1,3,5,5,5-heptamethyltrisiloxan
1873-88-7

1,1,1,3,5,5,5-heptamethyltrisiloxan

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

C19H37NO3Si3
1583285-82-8

C19H37NO3Si3

Conditions
ConditionsYield
With [Rh(coe)2OH]2; 3,4,5-MeO-MeO-BIPHEP; cyclohexene In tetrahydrofuran at 45℃; regioselective reaction;96%
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 2.9-dimethyl-1,10-phenanthroline In 1,4-dioxane at 100℃; for 20h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Sealed tube; regioselective reaction;63%
N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

3-methylbenzyl alcohol
587-03-1

3-methylbenzyl alcohol

Conditions
ConditionsYield
With pyrrolidine; n-butyllithium; borane-THF at 25℃;95%
With LiPyrrBH3 In tetrahydrofuran at 25℃; for 2h;95%
N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

N,N-diethyl 3-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide

N,N-diethyl 3-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide

Conditions
ConditionsYield
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine In hexane at 80℃; for 18h; Inert atmosphere; Sealed tube; regioselective reaction;95%
Stage #1: bis(pinacol)diborane With C24H28ClIrN2O In n-heptane; isopropyl alcohol at 75℃; for 1h; Sealed tube; Inert atmosphere;
Stage #2: N,N-Diethyl-3-methylbenzamide In n-heptane; isopropyl alcohol Sealed tube; Inert atmosphere;
87%
Stage #1: bis(pinacol)diborane With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,2’-bipyridine In hexane at 60℃; for 0.5h; Inert atmosphere; Glovebox; Sealed tube;
Stage #2: N,N-Diethyl-3-methylbenzamide With bis(2,6-di-tert-butyl-4-methylphenoxide)methylaluminum In hexane at 20℃; for 18h; Sealed tube;
55%
N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

N,N-diethyl-3-methylthiobenzamide
1017241-61-0

N,N-diethyl-3-methylthiobenzamide

Conditions
ConditionsYield
With triethylamine; trichlorophosphate In water at 60 - 70℃; for 0.0833333h; microwave irradiation;89%
With trichlorothiophosphine; water; triethylamine Microwave irradiation;89%
With trichlorothiophosphine; water; triethylamine Heating; Microwave irradiation;
N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

C24H30LaN3

C24H30LaN3

(4-(dimethylamino)phenyl)(m-tolyl)methanone
26704-95-0

(4-(dimethylamino)phenyl)(m-tolyl)methanone

Conditions
ConditionsYield
at 0℃; for 1h; Inert atmosphere; Schlenk technique;86%
N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

N,N-diethyl-α,α-difluoro-(meta-methylbenzyl)amine
500131-50-0

N,N-diethyl-α,α-difluoro-(meta-methylbenzyl)amine

Conditions
ConditionsYield
Stage #1: N,N-Diethyl-3-methylbenzamide With oxalyl dichloride In dichloromethane at 40℃; for 2h;
Stage #2: With triethylamine tris(hydrogen fluoride); triethylamine In dichloromethane at 20℃; for 2h;
82%
Stage #1: N,N-Diethyl-3-methylbenzamide With oxalyl dichloride In dichloromethane at 40℃; for 2h;
Stage #2: With triethylamine tris(hydrogen fluoride); triethylamine In dichloromethane at 20℃; for 2h; Further stages.;
82%
With Carbonyl fluoride In 1,2-dichloro-ethane at 158℃; for 10h; Product distribution / selectivity;60%
With Carbonyl fluoride at 72 - 170℃; for 10h; Product distribution / selectivity;7%
N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

1-((5-phenylpent-1-en-2-yl)oxy)pyridin-1-ium bis((trifluoromethyl)sulfonyl)amide

1-((5-phenylpent-1-en-2-yl)oxy)pyridin-1-ium bis((trifluoromethyl)sulfonyl)amide

2-oxo-5-phenylpentyl 3-methylbenzoate

2-oxo-5-phenylpentyl 3-methylbenzoate

Conditions
ConditionsYield
With water In dichloromethane at 45℃; for 6h;82%
With water at 60℃; for 18h;82%
ethanol
64-17-5

ethanol

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

ethyl 3-methylbenzoate
120-33-2

ethyl 3-methylbenzoate

Conditions
ConditionsYield
With hydrogenchloride; iron(III) chloride hexahydrate In hexane; water at 80℃; for 14h;81%
N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
With niobium(V) oxide; water In neat (no solvent) for 24h; Reflux; Inert atmosphere;76%
2,3-dimethyl-2,3-butane diol
76-09-5

2,3-dimethyl-2,3-butane diol

Trimethyl borate
121-43-7

Trimethyl borate

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

pinacolo[2-(N,N-diethylcarboxamido)-4-methylphenyl]boronate
698376-34-0

pinacolo[2-(N,N-diethylcarboxamido)-4-methylphenyl]boronate

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium In tetrahydrofuran (Ar); soln. of benzamide in THF was added dropwise to stirred soln. of s-BuLi/tetramethylethylenediamine (1/1) in THF at -78°C; mixt. wasstirred at -78°C for 1 h; treated with B(OMe)3; mixt. was warmed to room temp. over 8-12 h; quenched with satd. aq. NH4Cl; aq. phase extd. (Et2O); extract dried (Na2SO4); concd. (vac.); chromd. (silica gel, EtOAc/hexane); stirred with pinacol and MgSO4 in CH2Cl2 for 12 h; filtered; concd.; chromd. (silica gel, EtOAc/hexane, 1/3);70%
N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

A

3-methylbenzyl alcohol
587-03-1

3-methylbenzyl alcohol

B

m-tolyl aldehyde
620-23-5

m-tolyl aldehyde

Conditions
ConditionsYield
With titanium(IV) isopropylate; 1,1,3,3-Tetramethyldisiloxane In methyl cyclohexane at 20℃; for 15h; Inert atmosphere;A Ca. 10 %Spectr.
B 70%
Triethoxyvinylsilane
78-08-0

Triethoxyvinylsilane

N,N-Diethyl-3-methylbenzamide
134-62-3

N,N-Diethyl-3-methylbenzamide

C14H19NO

C14H19NO

Conditions
ConditionsYield
With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper diacetate; lithium fluoride In 1,2-dichloro-ethane at 120℃; for 36h; Schlenk technique;68%
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