Taixing Hehao Chemical Materials Co.,Ltd
Product description: Product name o-Toluic acid CAS number 118-90-1 Assay ≥99% Appearance White crystal Capacity 200mt/year Application Pesticides and pharmaceutical
Dayang Chem (Hangzhou) Co.,Ltd.
Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti
Cas:118-90-1
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquirySimagchem Corporation
Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:118-90-1
Min.Order:0 Metric Ton
Negotiable
Type:Manufacturers
inquiryJinan Finer Chemical Co., Ltd
Product description: Product name o-Toluic acid CAS number 118-90-1 Assay ≥99% Appearance White crystal Capacity 200mt/year Application Pesticides and pharmaceutical
Cas:118-90-1
Min.Order:100 Gram
FOB Price: $12.0
Type:Lab/Research institutions
inquiryHefei TNJ chemical industry co.,ltd
O-Toluic acid Molecular Formula C8H8O2 Molecular Weight 136.15 CAS Registry Number 118-90-1 EINECS 204-284-9 Appearance:white powder Storage:Warehouse ventilation, away from open flame, high temperature, and antioxidant Package:25kg/bag
Henan Allgreen Chemical Co.,Ltd
high quality Appearance:white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
EAST CHEMSOURCES LIMITED
o-Toluic acid Molecular Formula: C8H8O2 Molecular Weight: 136.15 Density: 1.062 Boiling Point: 258-259℃ Melting Point: 103-105℃
Ality Chemical Corporation
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Xi'an Xszo Chem Co., Ltd.
1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:118-90-1
Min.Order:1 Gram
FOB Price: $0.1
Type:Manufacturers
inquiryCOLORCOM LTD.
Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on
Enke Pharma-tech Co.,Ltd. （Cangzhou, China ）
Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi
Chemwill Asia Co., Ltd.
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Hebei yanxi chemical co.,LTD.
Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car
Cas:118-90-1
Min.Order:1 Metric Ton
FOB Price: $1.0 / 2.0
Type:Trading Company
inquiryHenan Tianfu Chemical Co., Ltd.
Product Name: o-Toluic acid Synonyms: 2-methylbenzoate;2-TOLUIC ACID;2-METHYLBENZOIC ACID;AKOS BBS-00003722;METHYLBENZOIC(O-) ACID;ORTHO-TOLUIC ACID;o-Methylbenzoate;O-METHYLBENZOIC ACID CAS: 118-90-1 MF: C8H8O2 MW: 136.15 EINECS: 204-284-9 P
Cas:118-90-1
Min.Order:1 Kilogram
FOB Price: $500.0
Type:Lab/Research institutions
inquiryHebei Nengqian Chemical Import and Export Co., LTD
Our advantages: 1) Standard:BP/USP/EP/Enterprise standard1, High quality with competitive price: 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can b
Cas:118-90-1
Min.Order:1 Kilogram
FOB Price: $1.0 / 10.0
Type:Trading Company
inquiryZhuozhou Wenxi import and Export Co., Ltd
WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:118-90-1
Min.Order:10 Gram
FOB Price: $146.0 / 176.0
Type:Trading Company
inquiryWuhan Han Sheng New Material Technology Co.，Ltd
Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:118-90-1
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiryHebei Sankai Chemical Technology Co., Ltd
1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W
Cas:118-90-1
Min.Order:1 Kilogram
FOB Price: $289.0 / 499.0
Type:Trading Company
inquiryHenan Sinotech Import&Export Corporation
Product Name o-Toluic acid CAS No. 118-90-1 Appearance White prismatic or needle crystal Assay
Cas:118-90-1
Min.Order:5 Metric Ton
FOB Price: $1.0 / 2.0
Type:Other
inquiryHenan Wentao Chemical Product Co., Ltd.
We are leading fine chemicals supplier in China and Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediat
Cas:118-90-1
Min.Order:1 Kilogram
FOB Price: $4.0 / 5.0
Type:Lab/Research institutions
inquiryHangzhou Sartort Biopharma Co., Ltd
Appearance:White to Light yellow powder Storage:room temperature Package:25kg/drum Application:o-Toluic acid is part of a group of Benzoic acid (B203900) derivatives that possess inhibitory activity against mushroom tyrosinases. o-Toluic acid is al
Cas:118-90-1
Min.Order:1 Kilogram
FOB Price: $1.0
Type:Lab/Research institutions
inquiryShanghai Upbio Tech Co.,Ltd
1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:118-90-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryShanghai Minstar Chemical Co., Ltd
Product Name: o-Toluic acid CAS: 118-90-1 MF: C8H8O2 MW: 136.15 EINECS: 204-284-9 Mol File: 118-90-1.mol o-Toluic acid Structure o-Toluic acid Chemical Properties Melting point 102-104 °C (lit.) Boiling point 258-259 &
Changchun Artel lmport and Export trade company
Price, service, company and transport advantage : 1. best service, high quality and reasonable price 2. it's customers' right to choose the package (ems, dhl, fedex, ups); 3. it's customers' right
Qingdao Beluga Import and Export Co., LTD
o-Toluic acid CAS:118-90-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates
Cas:118-90-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryShandong Hanjiang Chemical Co., Ltd.
Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Hubei Jiutian Bio-medical Technology Co., Ltd
1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists
Cas:118-90-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHebei Mojin Biotechnology Co.,Ltd
Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe,
Cas:118-90-1
Min.Order:1 Kilogram
FOB Price: $80.0 / 100.0
Type:Trading Company
inquiryXiamen Hisunny Chemical Co.,Ltd
Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Triumph International Development Limilted
Appearance:white powder/crystal Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common products:Sea/Ai
Cas:118-90-1
Min.Order:100 Metric Ton
Negotiable
Type:Lab/Research institutions
inquirySynthetic route
-
-
174473-23-5
2-methylbenzyltri-n-butylstannane
-
-
118-90-1
ortho-methylbenzoic acid
| Conditions | Yield |
|---|---|
| With C2H2Cl2F3O2V; oxygen In tert-butyl alcohol at 50℃; for 72h; | 100% |
| With VO(CH2CF3)Cl2; oxygen In tert-butyl alcohol at 50℃; for 72h; | 100% |
| Conditions | Yield |
|---|---|
| With phosphate buffer at 30℃; for 120h; rhodococcus rhodocrous AJ270, pH 7.0; | 99% |
| With potassium phosphate buffer at 30℃; for 120h; Rhodococcus sp. AJ270 cells; | 98.9% |
| With benzene-1,2-dicarboxylic acid for 0.833333h; microwave-irradiation; | 91% |
| Conditions | Yield |
|---|---|
| With 2-mesityl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In acetonitrile at 20℃; | 99% |
| With sodium chlorite; dimethyl sulfoxide In water; acetonitrile at 10℃; for 1.2h; | 98.6% |
| With oxygen; copper(II) acetate monohydrate; cobalt(II) diacetate tetrahydrate In water at 70℃; under 760.051 Torr; for 12h; | 96% |
| Conditions | Yield |
|---|---|
| With iodine; aluminium In acetonitrile at 80℃; for 18h; | 99% |
| With methanesulfonic acid; 1-methylimidazolium hydrobromide at 120℃; for 2h; | 92% |
| With AlBrCl3(1-)*C5H5N*H(1+) at 140℃; for 3h; | 91% |
| Conditions | Yield |
|---|---|
| With oxygen; sodium carbonate In water at 100℃; under 52505.3 Torr; for 0.533333h; Flow reactor; Green chemistry; | 98% |
| With picoline; tert.-butylhydroperoxide; chlorophyllin coppered trisodium salt In water at 80℃; for 15h; chemoselective reaction; | 97% |
| With dichloro(1,5-cyclooctadiene)ruthenium(II); C30H30N3P2(1+)*Cl(1-); potassium hydroxide In toluene at 120℃; for 24h; Inert atmosphere; Schlenk technique; | 96% |
| Conditions | Yield |
|---|---|
| With oxygen; tetra-N-butylammonium tribromide In ethyl acetate at 20℃; for 48h; Catalytic behavior; Irradiation; | 97% |
| With tert.-butylhydroperoxide; water at 20℃; for 12h; Inert atmosphere; | 90% |
| With tert.-butylhydroperoxide; chromium-pillared montmorillonite In 2,2,4-trimethylpentane; dichloromethane for 48h; Ambient temperature; | 87% |
-
-
16537-18-1
o-toluic acid t-butyl ester
-
-
118-90-1
ortho-methylbenzoic acid
| Conditions | Yield |
|---|---|
| With potassium hydroxide In tetrahydrofuran at 20℃; for 30h; | 97% |
| With sodium hydride In N,N-dimethyl-formamide at 20℃; for 6h; | 74% |
-
-
67157-60-2
2-methyl-benzoic acid benzyl ester
-
-
108-88-3
toluene
-
A
-
118-90-1
ortho-methylbenzoic acid
-
B
-
620-83-7
1-methyl-4-(phenylmethyl)benzene
-
C
-
713-36-0
2-benzyltoluene
| Conditions | Yield |
|---|---|
| With boron trifluoride diethyl etherate; water at 80℃; for 2h; regioselective reaction; | A 97% B n/a C n/a |
| Conditions | Yield |
|---|---|
| With tetrabutylammomium bromide; dicobalt octacarbonyl In sodium hydroxide; benzene at 65℃; for 1.5h; Irradiation; | 96% |
| With sodium hydroxide; tetrabutylammomium bromide; dicobalt octacarbonyl In water; benzene at 65℃; under 760 Torr; for 2.25h; Irradiation; | 96% |
| With sodium hydroxide; tetra-(n-butyl)ammonium iodide; bis(benzonitrile)palladium(II) dichloride; triphenylphosphine In xylene at 90℃; for 4h; Carbonylation; | 18% |
| Conditions | Yield |
|---|---|
| With potassium hydroxide; amphiphilic resin-supported phosphine-palladium; water at 25℃; under 760 Torr; for 12h; Product distribution; Further Variations:; Reagents; hydroxycarbonylation; | 96% |
| With water; palladium diacetate; potassium carbonate at 20℃; under 760.051 Torr; for 12h; | 89% |
| With water; potassium carbonate In acetonitrile at 100℃; under 3750.38 Torr; for 0.0161111h; | 86% |
| Conditions | Yield |
|---|---|
| With palladium diacetate; triethylamine; dicyclohexyl-carbodiimide; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 80℃; for 10h; Inert atmosphere; Sealed tube; | 95% |
| With palladium diacetate; triethylamine; dicyclohexyl-carbodiimide; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 100℃; for 20h; Inert atmosphere; Sealed tube; | 83% |
| Conditions | Yield |
|---|---|
| With palladium diacetate; sodium hydride In N,N-dimethyl acetamide at 25℃; for 3.5h; Inert atmosphere; | 95% |
| With palladium diacetate; sodium hydride In N,N-dimethyl acetamide; mineral oil at 25℃; for 4h; Inert atmosphere; | 95% |
-
-
118-90-1
ortho-methylbenzoic acid
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water at 100℃; for 9.5h; Reflux; chemoselective reaction; | 94% |
-
-
57139-25-0
N-methoxy-2-methylbenzamide
-
-
118-90-1
ortho-methylbenzoic acid
| Conditions | Yield |
|---|---|
| With tert.-butylnitrite; water at 29℃; for 0.583333h; | 94% |
-
-
577-16-2, 122382-54-1
2-Methylacetophenone
-
-
118-90-1
ortho-methylbenzoic acid
| Conditions | Yield |
|---|---|
| With 1,10-Phenanthroline; oxygen; copper diacetate; potassium hydroxide In dimethyl sulfoxide at 130℃; under 3000.3 Torr; for 12h; Autoclave; | 93% |
| With sodium hypochlorite; lithium hypochlorite In ethanol at 77℃; for 2h; | 89% |
| With copper(l) iodide; hydroxylamine hydrochloride; oxygen In dimethyl sulfoxide at 100℃; for 8h; | 87% |
-
-
64158-25-4
2,2'-dimethylhydrobenzoin
-
-
118-90-1
ortho-methylbenzoic acid
| Conditions | Yield |
|---|---|
| With sodium hypochlorite In acetonitrile at 20℃; for 3h; | 93% |
| Conditions | Yield |
|---|---|
| With phosphate buffer at 30℃; for 5.5h; rhodococcus rhodocrous AJ270, pH 7.0; | A 7% B 92% |
| With potassium phosphate buffer at 30℃; for 5.5h; Rhodococcus sp. AJ270 cells; | A 6.6% B 92.4% |
| Conditions | Yield |
|---|---|
| With manganese; bis(triphenylphosphine)nickel(II) chloride; 2.9-dimethyl-1,10-phenanthroline In N,N-dimethyl-formamide at 20℃; under 760.051 Torr; for 20h; Schlenk technique; Inert atmosphere; Glovebox; | 92% |
| Conditions | Yield |
|---|---|
| Stage #1: 2-Fluorotoluene With C78H70Al2Cl4N6P4Rh2; magnesium; ethylene dibromide In tetrahydrofuran at 20℃; for 22h; Inert atmosphere; Glovebox; Stage #2: carbon dioxide In tetrahydrofuran at 20℃; under 760.051 Torr; for 0.5h; | 92% |
-
-
124-38-9
carbon dioxide
-
-
2093-46-1
2-methylphenyl diazonium tetrafluoroborate
-
-
118-90-1
ortho-methylbenzoic acid
| Conditions | Yield |
|---|---|
| With tetra(n-butyl)ammonium hydrogensulfate In N,N-dimethyl-formamide for 2h; Electrochemical reaction; | 91% |
-
-
55886-48-1
2-methylcyclohexa-2,5-diene-1-carboxylic acid
-
-
118-90-1
ortho-methylbenzoic acid
| Conditions | Yield |
|---|---|
| In acetone at 0℃; for 2h; | 90% |
| Conditions | Yield |
|---|---|
| With manganese(IV) oxide; acetic acid In water at 25℃; Oxidation; | 90% |
| With copper dichloride In 1,4-dioxane; water Oxidation; | 83% |
| Conditions | Yield |
|---|---|
| Stage #1: 1-methyl-2-vinyl-benzene With tert.-butylhydroperoxide; iron(III) chloride hexahydrate; sodium hydroxide In water at 80℃; for 10h; Stage #2: With hydrogenchloride In water at 20℃; | 90% |
| With methyl 3,5-bis((1H-1,2,4-triazol-1-yl)methyl)benzoate; oxygen; sodium acetate; nickel dibromide at 120℃; under 760.051 - 912.061 Torr; for 48h; chemoselective reaction; | 72% |
| Stage #1: 1-methyl-2-vinyl-benzene With tert.-butylhydroperoxide; iodine; sodium hydroxide In water at 105℃; for 16h; Sealed tube; Stage #2: With hydrogenchloride In water | 51% |
| With Oxone In water; acetonitrile for 24h; Reflux; | 8% |
| Conditions | Yield |
|---|---|
| With copper(l) iodide; potassium carbonate In dimethyl sulfoxide at 100℃; for 24h; Inert atmosphere; | 90% |
-
-
38362-89-9
1-methyl-2-(2-nitroethyl)benzene
-
-
118-90-1
ortho-methylbenzoic acid
| Conditions | Yield |
|---|---|
| With zinc diacetate; water; tetra-(n-butyl)ammonium iodide at 80℃; for 24h; | 90% |
| With water; tetra-(n-butyl)ammonium iodide at 80℃; for 15h; Reagent/catalyst; | 90% |
| With tetra-(n-butyl)ammonium iodide; acetic acid In water at 80℃; for 15h; Reagent/catalyst; | 89% |
| Conditions | Yield |
|---|---|
| Stage #1: o-xylene With manganese(IV) oxide; C32H16N8O4Ru; C46H39CrN12O2; oxygen at 195℃; under 14251.4 Torr; for 0.2h; Stage #2: With manganese(IV) oxide; C32H16N8O4Ru; C46H39CrN12O2; oxygen; acetic acid at 150℃; under 4500.45 Torr; for 4h; Temperature; Pressure; Reagent/catalyst; | A 89.3% B 10.6% |
| Stage #1: o-xylene With N-acetylphthalimide; Cr(4+)*4NO3(1-); C36H24N8NiO4; C52H44FeN4O8; oxygen at 120℃; under 2250.23 Torr; for 1.5h; Stage #2: With N-acetylphthalimide; Cr(4+)*4NO3(1-); C36H24N8NiO4; C52H44FeN4O8; oxygen; acetic acid at 170℃; under 12001.2 Torr; for 0.6h; Temperature; Pressure; Reagent/catalyst; | A 14.4% B 85.3% |
| With zinc(II) oxide In N,N-dimethyl-formamide for 0.133333h; microwave irradiation; | A 80% B 5 % Spectr. |
-
-
67-56-1
methanol
-
-
7658-80-2
2-methylbenzohydrazide
-
A
-
118-90-1
ortho-methylbenzoic acid
-
B
-
89-71-4
2-Methyl-benzoic acid methyl ester
| Conditions | Yield |
|---|---|
| With copper diacetate; oxygen | A 89% B 7% |
| Conditions | Yield |
|---|---|
| With selenium(IV) oxide; dihydrogen peroxide In tetrahydrofuran for 10h; Heating; | A 88% B 9 % Chromat. |
| With dihydrogen peroxide; methyltrioctylammonium tetrakis(oxodiperoxotungsto)phosphate at 90℃; for 1.5h; | A 23% B 10% |
| Conditions | Yield |
|---|---|
| Stage #1: 1-ethynyl-2-methylbenzene With tert.-butylhydroperoxide; iron(III) chloride hexahydrate; sodium hydroxide In water at 80℃; for 10h; Stage #2: With hydrogenchloride In water at 20℃; | 88% |
-
-
1623774-99-1
N-(2-(1-benzyl-1H-1, 2, 3-triazol-4-yl)propan-2-yl)-2-methylbenzamide
-
-
118-90-1
ortho-methylbenzoic acid
| Conditions | Yield |
|---|---|
| With nitrosonium tetrafluoroborate In acetonitrile at 50℃; for 0.166667h; | 87% |
| Conditions | Yield |
|---|---|
| With sulfuric acid at 100℃; for 12h; | 100% |
| With thionyl chloride at 0 - 80℃; Inert atmosphere; | 99.5% |
| With thionyl chloride at 0 - 80℃; Inert atmosphere; | 99.5% |
| Conditions | Yield |
|---|---|
| With oxalyl dichloride In benzene at 20℃; for 14h; | 100% |
| With thionyl chloride Reflux; | 100% |
| With thionyl chloride; N,N-dimethyl-formamide at 90℃; for 3h; Concentration; Reagent/catalyst; Temperature; | 99.7% |
| Conditions | Yield |
|---|---|
| Stage #1: ortho-methylbenzoic acid With sec.-butyllithium In tetrahydrofuran; 1-hexene; cyclohexane at -78 - 20℃; Stage #2: ethyl iodide In tetrahydrofuran; 1-hexene; cyclohexane at -78 - 20℃; Stage #3: With hydrogenchloride; water In tetrahydrofuran; cyclohexane | 100% |
| With sec.-butyllithium In cyclohexane for 8h; Ambient temperature; | 82% |
| With sec.-butyllithium 1.) THF, cyclohexane, -78 deg C, 1 h, 2.) THF, cyclohexane, RT, 4 h; Yield given. Multistep reaction; |
-
-
118-90-1
ortho-methylbenzoic acid
| Conditions | Yield |
|---|---|
| In water at 130℃; for 16h; Microwave irradiation; | 100% |
| Conditions | Yield |
|---|---|
| With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere; | 100% |
| With dicyclohexyl-carbodiimide In N,N-dimethyl-formamide at 25℃; for 3h; | 32.9% |
| Conditions | Yield |
|---|---|
| With N,N-bis[2-oxo-3-oxazolidinyl]phosphorodiamidic chloride; triethylamine In dichloromethane at 20℃; for 0.5h; | 99% |
| With 2,6-dimethylpyridine; tris(2,2'-bipyridyl)ruthenium dichloride; carbon tetrabromide; N,N-dimethyl-formamide at 25 - 30℃; for 12h; Inert atmosphere; Photolysis; | 97% |
| With Selectfluor; triphenylphosphine In acetonitrile at 20℃; for 4h; Schlenk technique; Inert atmosphere; | 92% |
| Conditions | Yield |
|---|---|
| Stage #1: ortho-methylbenzoic acid With O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃; for 0.166667h; Inert atmosphere; Stage #2: aniline With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 60℃; Inert atmosphere; | 99% |
| With TEA; 1,2-benzisoxazol-3-yl diphenyl phosphate In various solvent(s) for 2h; Ambient temperature; | 90% |
| Stage #1: ortho-methylbenzoic acid With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide at 20℃; for 3h; Stage #2: aniline In dichloromethane at 20℃; | 31.7% |
-
-
118-90-1
ortho-methylbenzoic acid
-
-
74-88-4
methyl iodide
-
-
55262-10-7
1,2-dimethyl-2,5-cyclohexadiene-1-carboxylic acid
| Conditions | Yield |
|---|---|
| Stage #1: ortho-methylbenzoic acid With ammonia; lithium In tetrahydrofuran at -78℃; Birch reduction; Inert atmosphere; Stage #2: methyl iodide In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere; Stage #3: With hydrogenchloride In tetrahydrofuran; water | 99% |
| Stage #1: ortho-methylbenzoic acid With ammonia; lithium In water at -60℃; for 0.5h; Birch reduction; Stage #2: methyl iodide In water regioselective reaction; | 98% |
| Stage #1: ortho-methylbenzoic acid With lithium In tetrahydrofuran; ammonia at -78℃; Stage #2: methyl iodide | 91% |
| (i) Li, liq. NH3, (ii) /BRN= 969135/; Multistep reaction; |
| Conditions | Yield |
|---|---|
| With dichloro[1,3-di(ethoxycarbonyl)-2,4,5-trimethylcyclopentadienyl]rhodium(III) dimer; copper(II) acetate monohydrate; silver(I) triflimide In dichloromethane at 20℃; for 24h; Sealed tube; | 99% |
| With carbonyl(pentamethylcyclopentadienyl)cobalt diiodide; sodium acetate; copper(II) oxide In 2,2,2-trifluoroethanol at 80℃; for 24h; Schlenk technique; Molecular sieve; Inert atmosphere; | 92% |
| With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; C15H23NO4 In 2,2,2-trifluoroethanol at 30℃; for 35h; Reagent/catalyst; Temperature; | 90% |
| Conditions | Yield |
|---|---|
| In light petroleum byproducts: CH3C6H4COCl, HCl; exclusion of air and moisture, addn. of TiCl4 (by syringe) to the org. compound stirred in light petroleum (b.p. 100-120°C) at 0°C, slowly warming to room temp., then heating to reflux, 4 h, pptn.; cooling, filtration, washing (hexane), drying in vac. for 2 h, elem. anal.; | 99% |
| In light petroleum compds. are heated under reflux at 100-120°C;; elem. anal.;; | >99 |
| Conditions | Yield |
|---|---|
| With sulfuric acid at 110 - 120℃; for 13h; Neat (no solvent); | 99% |
-
-
118-90-1
ortho-methylbenzoic acid
-
-
75-09-2
dichloromethane
-
-
144168-19-4
bis(2-methylbenzoyloxy)methane
| Conditions | Yield |
|---|---|
| With potassium carbonate In dimethyl sulfoxide at 60℃; for 3h; Reagent/catalyst; Solvent; | 99% |
| With potassium carbonate In dimethyl sulfoxide at 130℃; for 5h; | 98% |
| Conditions | Yield |
|---|---|
| With C30H54N6Ru(2+)*2BF4(1-); potassium perfluoro-tert-butoxide; potassium carbonate at 140℃; for 16h; Reagent/catalyst; Temperature; Glovebox; Inert atmosphere; | 99% |
| With palladium diacetate; caesium carbonate; N-acetyl-L-isoleucine; silver carbonate at 30℃; for 36h; Schlenk technique; Inert atmosphere; | 59% |
| With dipotassium hydrogenphosphate; sodium acetate; palladium diacetate; silver carbonate In tert-butyl alcohol at 140℃; for 48h; | |
| With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; potassium carbonate; tricyclohexylphosphine In 1-methyl-pyrrolidin-2-one at 100℃; for 24h; Inert atmosphere; Glovebox; Sealed tube; |
| Conditions | Yield |
|---|---|
| Stage #1: ortho-methylbenzoic acid With O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃; for 0.166667h; Inert atmosphere; Stage #2: 2-Amino-6-methylpyridine With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 60℃; Inert atmosphere; | 99% |
-
-
118-90-1
ortho-methylbenzoic acid
-
-
15796-89-1
N-methyl-N-phenylmethacrylamide
| Conditions | Yield |
|---|---|
| With 2,6-dimethylpyridine; di-tert-butyl dicarbonate; tris[2-phenylpyridinato-C2,N]iridium(III); magnesium chloride In N,N-dimethyl-formamide at 20℃; for 48h; Sealed tube; Inert atmosphere; UV-irradiation; | 99% |
-
-
118-90-1
ortho-methylbenzoic acid
-
-
292638-85-8
acrylic acid methyl ester
| Conditions | Yield |
|---|---|
| With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; potassium acetate In water at 100℃; for 24h; Green chemistry; | 99% |
| With C45H51Cl2CuN4P4Ru(1+)*BF4(1-); sodium acetate In water at 100℃; for 12h; Inert atmosphere; Schlenk technique; | 90% |
| With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; oxygen; potassium acetate In butan-1-ol at 80℃; under 760.051 Torr; for 18h; Schlenk technique; chemoselective reaction; | 72% |
| Conditions | Yield |
|---|---|
| With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; potassium acetate In water at 100℃; for 24h; Catalytic behavior; Reagent/catalyst; Temperature; Green chemistry; | 99% |
| Conditions | Yield |
|---|---|
| With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere; | 99% |
-
-
118-90-1
ortho-methylbenzoic acid
-
-
616-38-6
carbonic acid dimethyl ester
-
-
89-71-4
2-Methyl-benzoic acid methyl ester
| Conditions | Yield |
|---|---|
| With sulfuric acid; acetic acid at 85 - 90℃; for 12h; Neat (no solvent); Large scale reaction; | 98.34% |
-
-
118-90-1
ortho-methylbenzoic acid
-
-
108-98-5
thiophenol
-
-
35092-37-6
2-Methyl-thiobenzoesaeure-S-phenylester
| Conditions | Yield |
|---|---|
| With pyridine; O-phenyl phosphorodichloridate In 1,2-dimethoxyethane for 16h; Ambient temperature; | 98% |
| Stage #1: ortho-methylbenzoic acid With aluminum (III) chloride In ethyl acetate at 0℃; for 2h; Stage #2: thiophenol With zinc(II) chloride In ethyl acetate for 4h; Reflux; | 85% |
| (i) SOCl2, (ii) /BRN= 506523/; Multistep reaction; | |
| Stage #1: ortho-methylbenzoic acid With dmap; 3-((1H-benzo[d][1,2,3]triazol-5-yl)methyl)-1,2-dimethyl-1H-imidazole-3-ium hexafluorophosphate; dicyclohexyl-carbodiimide In acetonitrile at 20℃; Green chemistry; Stage #2: thiophenol With dmap In water at 100℃; for 0.166667h; Microwave irradiation; Green chemistry; |
-
-
118-90-1
ortho-methylbenzoic acid
-
-
54811-50-6
2-iodo-6-methylbenzoic acid
| Conditions | Yield |
|---|---|
| With N-iodo-succinimide; palladium diacetate In N,N-dimethyl-formamide at 100℃; for 16h; Inert atmosphere; | 98% |
| With N-iodo-succinimide; [Ir(III)(η5-pentamethylcyclopentadienyl)(H2O)3](SO4) at 40℃; for 16h; Reagent/catalyst; Temperature; | 98% |
| With N-iodo-succinimide; palladium diacetate In 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran; N,N-dimethyl-formamide | 95% |
-
-
118-90-1
ortho-methylbenzoic acid
-
-
74-83-9
methyl bromide
-
-
55262-10-7
1,2-dimethyl-2,5-cyclohexadiene-1-carboxylic acid
| Conditions | Yield |
|---|---|
| Stage #1: ortho-methylbenzoic acid With ammonia; lithium at -60℃; Birch reduction; Stage #2: methyl bromide at -60 - 20℃; | 98% |
| With ammonia; lithium 1.) -60 deg C, 20 min, 2.) from -60 deg C to 25 deg C, 16 h; Yield given. Multistep reaction; |
-
-
118-90-1
ortho-methylbenzoic acid
-
-
75-26-3
isopropyl bromide
-
-
31689-42-6
2-methyl-1-(1-methylethyl)cyclohexa-2,5-diene-1-carboxylic acid
| Conditions | Yield |
|---|---|
| Stage #1: ortho-methylbenzoic acid With ammonia; lithium at -60℃; Birch reduction; Stage #2: isopropyl bromide at -60 - 20℃; | 98% |
| Stage #1: ortho-methylbenzoic acid With ammonia; lithium In water at -60℃; for 0.5h; Birch reduction; Stage #2: isopropyl bromide In water regioselective reaction; | 98% |
| With ammonia; lithium 1.) -60 deg C, 20 min, 2.) from -60 deg C to 25 deg C, 16 h; Yield given. Multistep reaction; | |
| Stage #1: ortho-methylbenzoic acid With ammonia; lithium at -78℃; for 1h; Stage #2: isopropyl bromide at -78℃; for 0.25h; |
-
-
118-90-1
ortho-methylbenzoic acid
-
-
19227-13-5
(Z)-N'-hydroxy-4-methylbenzimidamide
| Conditions | Yield |
|---|---|
| Stage #1: ortho-methylbenzoic acid With PS-PPh3; trichloroacetonitrile In tetrahydrofuran at 100℃; for 0.0833333h; microwave irradiation; Stage #2: (Z)-N'-hydroxy-4-methylbenzimidamide With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 150℃; for 0.25h; microwave irradiation; | 98% |
-
-
118-90-1
ortho-methylbenzoic acid
-
-
98-85-1, 13323-81-4
1-Phenylethanol
-
-
51801-00-4
1-phenylethyl 2-methylbenzoate
| Conditions | Yield |
|---|---|
| With potassium hydroxide | 98% |
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