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Xinyang Longye Chemical CO.,LTD

Our Strength 1) Quick Response Within 12 hours; 2) Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, Accept any third party agency inspection and analysis before shipment fr

2-Chlorobenzoic acid CAS: 118-91-2

Cas:118-91-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2-Chlorobenzoic acid Manufacturer/High quality/Best price/In stock

Cas:118-91-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Chlorobenzoic Acid supplier in China

Cas:118-91-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------

High purity 118-91-2 ortho chloro benzoic acid

Cas:118-91-2

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

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Jinan Finer Chemical Co., Ltd

Product description: Product name 2-Chlorobenzoic acid CAS number 118-91-2 Assay ≥99% Appearance White crystalline powder Capacity 500mt/year Application Pharmaceutical/pesti

2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:100 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality 2-Chlorobenzoic acid Basic information Product Name: 2-Chlorobenzoic acid Synonyms: O-CHLOROBENZOIC ACID;RARECHEM AL BO 0021;2-CBA;2-Chlorbenzoes&alp

2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-chlorobenzoic acid

Cas:118-91-2

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 2-Chlorobenzoic acid 118-91-2 ISO Producer

Cas:118-91-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Chlorobenzoic Acid

Cas:118-91-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

2-chlorobenzoic Acid

Cas:118-91-2

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

118-91-2 2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

2-Chlorobenzoic acid 118-91-2 OCBA

Cas:118-91-2

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 118-91-2 with fast shipping

Cas:118-91-2

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

o-chlorobenzoic acid Molecular formula: C7H5ClO2 Molecular weight: 156.57 Appearance: white or almost white crystal powder solub

2-Chlorobenzoic acid CAS: 118-91-2

Cas:118-91-2

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:White crystals or powder Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Any port in china

2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Chlorobenzoic acid 118-91-2

Cas:118-91-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

HANWAYS CHEMPHARM CO.,LIMITED

Wuhan hanweishi Pharmchem Co., Ltd(Hanways chempharm) is a specialized company concentrating on the R&D, production, marketing and technical service of APIs and pharmaceutical intermediates. The leading products range are APIs, Hormones, Peptides

O-Chlorobenzoic Acid CAS 118-91-2

Cas:118-91-2

Min.Order:100 Kilogram

FOB Price: $1.0 / 5.0

Type:Trading Company

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Dye intermediate, 2-Chlorobenzoic acid CAS:118-91-2

Cas:118-91-2

Min.Order:1 Kilogram

FOB Price: $42.0 / 48.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

2-Chlorobenzoic acid CAS:118-91-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm

2-Chlorobenzoic acid CAS:118-91-2

Cas:118-91-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

2-Chlorobenzoic acid CAS NO.118-91-2

Cas:118-91-2

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 118-91-2 2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Company information: Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big custo

2-chlorobenzoic Acid CAS 118-91-2

Cas:118-91-2

Min.Order:1 Kilogram

FOB Price: $8.0 / 10.0

Type:Trading Company

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Chlorobenzoic Acid

Cas:118-91-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Chlorobenzoic acid

Cas:118-91-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2-chloro-benzaldehyde
89-98-5

2-chloro-benzaldehyde

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With sodium perborate In acetic acid for 1.5h; steam bath;100%
With sodium chlorite; dimethyl sulfoxide In water; acetonitrile at 10℃; for 1h;98%
With selenium(IV) oxide; dihydrogen peroxide In tetrahydrofuran for 9h; Heating;97%
methyl chlorobenzoate
610-96-8

methyl chlorobenzoate

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With sodium; diphenyldisulfane In 1-methyl-pyrrolidin-2-one at 90℃; for 0.25h;100%
With iodine; aluminium In acetonitrile at 80℃; for 18h;98%
With potassium hydroxide In toluene at 150℃; for 0.166667h; microwave irradiation;97%
2-Chlorobenzyl alcohol
17849-38-6

2-Chlorobenzyl alcohol

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With NH-pyrazole; sodium hydride In tetrahydrofuran for 20h; Ambient temperature;100%
With Oxone; potassium bromide In water; acetonitrile at 20℃; for 24h; Reagent/catalyst; Solvent;99%
With sodium hydroxide; sodium periodate; trans-Na6 In water for 1.5h;96%
2-chlorobenzaldehyde N-[(2-chlorophenyl)methylidene]hydrazone
5328-80-3

2-chlorobenzaldehyde N-[(2-chlorophenyl)methylidene]hydrazone

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With poly(diselanediyl-1,2-phenylene); dihydrogen peroxide In tetrahydrofuran for 140h; Heating;98%
With [bis(acetoxy)iodo]benzene In tetrahydrofuran at 20℃; for 4h; Green chemistry;76%
N’-(2-chlorobenzylidene)-4-methylbenzenesulfonohydrazide
107135-19-3

N’-(2-chlorobenzylidene)-4-methylbenzenesulfonohydrazide

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With poly(diselanediyl-1,2-phenylene); dihydrogen peroxide In tetrahydrofuran for 85h; Heating;98%
1-(2-chlorophenyl)-4,4,4-trifluorobutane-1,3-dione
23975-60-2

1-(2-chlorophenyl)-4,4,4-trifluorobutane-1,3-dione

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With oxygen; sodium hydrogencarbonate In acetonitrile for 4h; Molecular sieve; Irradiation;98%
2-Chlorobenzonitrile
873-32-5

2-Chlorobenzonitrile

A

2-chlorobenzamide
609-66-5

2-chlorobenzamide

B

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With potassium hydroxide In toluene at 150℃; for 0.166667h; microwave irradiation;A 2%
B 97%
With phosphate buffer at 30℃; for 6.5h; rhodococcus rhodocrous AJ270, pH 7.0;A 94%
B 4%
With potassium phosphate buffer at 30℃; for 6.5h; Rhodococcus sp. AJ270 cells;A 94.1%
B 4.4%
With potassium hydroxide; cetyltrimethylammonim bromide In toluene at 100℃; for 0.166667h; microwave irradiation;A 45%
B 5%
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

A

2-chloro-benzaldehyde
89-98-5

2-chloro-benzaldehyde

B

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

C

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With oxygen; cobalt(II) acetate; sodium bromide In acetic acid at 95℃; for 0.666667h; Kinetics; Mechanism; Rate constant; other time; other temperature; various concentrations of Co(OAc)2 and NaBr;A n/a
B n/a
C 96%
With oxygen; cobalt(II) acetate; sodium bromide In acetic acid at 95℃; for 0.666667h;A n/a
B n/a
C 95%
methyl 3-(2-chlorophenyl)-3-oxopropanedithioate
1429790-14-6

methyl 3-(2-chlorophenyl)-3-oxopropanedithioate

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With sodium hydroxide In water at 100℃; for 8.5h; Reflux; chemoselective reaction;96%
2-Chlorobenzonitrile
873-32-5

2-Chlorobenzonitrile

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With benzene-1,2-dicarboxylic acid for 0.833333h; microwave-irradiation;94%
With phosphate buffer at 30℃; for 168h; rhodococcus rhodocrous AJ270, pH 7.0;80%
With potassium phosphate buffer at 30℃; for 168h; Rhodococcus sp. AJ270 cells;79.9%
With sulfuric acid
2-chlorostyrene
2039-87-4

2-chlorostyrene

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
Stage #1: 2-chlorostyrene With tert.-butylhydroperoxide; iron(III) chloride hexahydrate; sodium hydroxide In water at 80℃; for 10h;
Stage #2: With hydrogenchloride In water at 20℃;
94%
With Oxone; 2-iodo-3,4,5,6-tetramethylbenzoic acid In water; acetonitrile for 24h;79%
Stage #1: 2-chlorostyrene With tert.-butylhydroperoxide; iodine; sodium hydroxide In water at 105℃; for 16h; Sealed tube;
Stage #2: With hydrogenchloride In water
58%
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With ruthenium trichloride; sodium hypochlorite; tetrabutylammomium bromide In 1,2-dichloro-ethane at 25℃; for 2h;93%
With carbon tetrabromide; oxygen In acetonitrile at 20℃; for 60h; UV-irradiation;91.5%
With oxygen; Langlois reagent In acetonitrile at 25℃; for 12h; Irradiation; Green chemistry;91%
L-tyrosine ethyl ester
949-67-7

L-tyrosine ethyl ester

o-chlorobenzoyl chloride
609-65-4

o-chlorobenzoyl chloride

A

N-(2-chlorobenzoyl)-(L)-tyrosine ethyl ester
797760-44-2

N-(2-chlorobenzoyl)-(L)-tyrosine ethyl ester

B

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
Stage #1: L-tyrosine ethyl ester With sodium hydrogencarbonate In tetrahydrofuran; water at 20℃;
Stage #2: o-chlorobenzoyl chloride In tetrahydrofuran; water at 0 - 20℃; for 0.5h;
A 92%
B 5%
benzyl 2-chlorobenzoate
7579-40-0

benzyl 2-chlorobenzoate

toluene
108-88-3

toluene

A

1-methyl-3-(phenylmethyl)-benzene
620-47-3

1-methyl-3-(phenylmethyl)-benzene

B

1-methyl-4-(phenylmethyl)benzene
620-83-7

1-methyl-4-(phenylmethyl)benzene

C

2-benzyltoluene
713-36-0

2-benzyltoluene

D

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; water at 80℃; for 2h; regioselective reaction;A n/a
B n/a
C n/a
D 92%
2-chloro-benzaldehyde
89-98-5

2-chloro-benzaldehyde

A

2-Chlorobenzyl alcohol
17849-38-6

2-Chlorobenzyl alcohol

B

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
Stage #1: 2-chloro-benzaldehyde With potassium hydroxide In water at 20℃; Cannizzaro reaction;
Stage #2: With hydrogenchloride In water
A 85%
B 91%
With sodium hydroxide In water at 20℃; for 2.5h; Cannizzaro Reaction;A n/a
B 90%
Stage #1: 2-chloro-benzaldehyde In neat (no solvent) for 0.0333333h; Green chemistry;
Stage #2: With 1,4-diaza-bicyclo[2.2.2]octane In neat (no solvent) at 40℃; for 0.00833333h; Reagent/catalyst; Cannizzaro Reaction; Microwave irradiation; Green chemistry;
2-chloro benzaldehyde oxime
3717-28-0

2-chloro benzaldehyde oxime

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With poly(diselanediyl-1,2-phenylene); dihydrogen peroxide In tetrahydrofuran for 63h; Heating;90%
(DL)-o-chlorophenyl-1,2-ethanediol
32345-65-6, 133082-13-0, 59365-60-5

(DL)-o-chlorophenyl-1,2-ethanediol

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; potassium tert-butylate In water at 80℃; for 8h;90%
carbon monoxide
201230-82-2

carbon monoxide

2-iodochlorobenzene
615-41-8

2-iodochlorobenzene

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With water; palladium diacetate; triethylamine; triphenylphosphine In 1,4-dioxane at 110℃; under 11251.1 Torr; for 2h; Reagent/catalyst; Temperature; Pressure; Flow reactor;90%
Stage #1: carbon monoxide; 2-iodochlorobenzene With potassium carbonate In water at 100℃; under 3750.38 Torr; for 12h; Autoclave;
Stage #2: With hydrogenchloride In water
85%
With water; potassium carbonate In acetonitrile at 100℃; under 3750.38 Torr; for 0.0161111h;74%
2-chloro-N,N-diisopropylbenzamide
70657-63-5

2-chloro-N,N-diisopropylbenzamide

A

3-chlorobenzoic acid isopropylamide
6291-28-7

3-chlorobenzoic acid isopropylamide

B

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With hydrogenchloride; zinc(II) chloride at 160℃; for 72h;A 9%
B 89%
carbon dioxide
124-38-9

carbon dioxide

2-(2-chlorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane
346656-42-6

2-(2-chlorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
Stage #1: carbon dioxide; 2-(2-chlorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane With potassium tert-butylate; silver(I) acetate; triphenylphosphine In tetrahydrofuran at 70℃; under 15201 Torr; for 16h; Inert atmosphere; Autoclave;
Stage #2: With hydrogenchloride In tetrahydrofuran; water Inert atmosphere;
89%
furan
110-00-9

furan

benzenedizolium-2-carboxylate
1608-42-0

benzenedizolium-2-carboxylate

A

1,4-dihydronaphthalene-1,4-epoxide
573-57-9

1,4-dihydronaphthalene-1,4-epoxide

B

2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

C

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With 1,2-dichloro-ethane at 80℃; for 2h; Product distribution; Mechanism; acids were detected as methyl esters (methylated by CH2N2);A 88%
B n/a
C n/a
2-CHLOROBENZYLAMINE
89-97-4

2-CHLOROBENZYLAMINE

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; laccasefrom Trametes versicolor; oxygen In water at 30℃; for 240h; pH=4.5; Enzymatic reaction;88%
2'-chloro-sec-phenethyl alcohol
13524-04-4

2'-chloro-sec-phenethyl alcohol

A

2-chloro-benzaldehyde
89-98-5

2-chloro-benzaldehyde

B

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With sodium nitrate; water; oxygen In dimethyl sulfoxide at 130℃; for 36h;A 9%
B 87%
furan
110-00-9

furan

benzenedizolium-2-carboxylate
1608-42-0

benzenedizolium-2-carboxylate

A

1,4-dihydronaphthalene-1,4-epoxide
573-57-9

1,4-dihydronaphthalene-1,4-epoxide

B

chlorobenzene
108-90-7

chlorobenzene

C

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With triethylamine hydrochloride In chloroform at 60℃; for 48h; Product distribution; Mechanism; var. temp.: RT; acid was identified as methyl ester (methylated by CH2N2);A 85%
B 6%
C 15%
2-chloro-benzoic acid tert-butyl ester
16537-16-9

2-chloro-benzoic acid tert-butyl ester

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With water; iodine In acetonitrile for 4h; Heating;85%
anthranilic acid
118-92-3

anthranilic acid

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
Stage #1: anthranilic acid With hydrogenchloride; sodium nitrite In water at 6 - 8℃; for 0.416667h;
Stage #2: With aluminum sulfate; potassium chloride; copper(II) sulfate In water for 1 - 1.5h;
84%
With hydrogenchloride; water; sodium nitrite man giesst dann in eine Loesung von CuCl;
With tert.-butylnitrite; copper dichloride In acetonitrile
2-Chloro-benzoic acid 3-methyl-but-2-enyl ester

2-Chloro-benzoic acid 3-methyl-but-2-enyl ester

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With iodine In cyclohexane for 6h; Ambient temperature;84%
benzyl 2-chlorobenzoate
7579-40-0

benzyl 2-chlorobenzoate

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With methanol; sodium tetrahydroborate; nickel(II) chloride hexahydrate at 20℃; for 0.0833333h; chemoselective reaction;83%
2'-chloro-benzeneacetic acid
2444-36-2

2'-chloro-benzeneacetic acid

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With iodine; dimethyl sulfoxide at 120℃; for 25h; Sealed tube; Green chemistry;83%
methanol
67-56-1

methanol

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

methyl chlorobenzoate
610-96-8

methyl chlorobenzoate

Conditions
ConditionsYield
With sulfuric acid for 4h; Reflux;100%
With sulfuric acid Heating;99%
With 1,3,5-trichloro-2,4,6-triazine; sodium carbonate at 50℃; for 0.333333h; Sonication;94%
ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

o-chlorobenzoyl chloride
609-65-4

o-chlorobenzoyl chloride

Conditions
ConditionsYield
With thionyl chloride In toluene at 75℃;100%
With thionyl chloride Reflux;100%
With thionyl chloride at 100℃;100%
ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With hydrogen; triethylamine; palladium on activated charcoal In methanol at 20℃; for 3h;100%
With borane-ammonia complex In water; isopropyl alcohol at 40℃; for 3h; Sealed tube;97%
With 1H-imidazole; copper ammonium sulphate hexahydrate; lithium tert-butoxide In N,N-dimethyl-formamide; isopropyl alcohol for 72h; Irradiation;87%
1-ethylpiperidin-4-ol
3518-83-0

1-ethylpiperidin-4-ol

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

2-chloro-benzoic acid 1-ethyl-piperidin-4-yl ester

2-chloro-benzoic acid 1-ethyl-piperidin-4-yl ester

Conditions
ConditionsYield
With pyridine; p-toluenesulfonyl chloride at 0 - 20℃; Esterification;100%
ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

2,5-bis-(2-chlorophenyl)-1,3,4-oxadiazole
2492-02-6

2,5-bis-(2-chlorophenyl)-1,3,4-oxadiazole

Conditions
ConditionsYield
With hydrazine dihydrochloride; phosphoric acid; trichlorophosphate In water at 140℃; for 2h; Condensation;99.2%
With hydrazine dihydrochloride; phosphoric acid; phosphorus pentoxide at 130℃; for 0.0833333h; microwave irradiation;96%
With sodium tetrahydroborate; hydrazine dihydrochloride; phosphoric acid at 170 - 180℃; for 6h; Inert atmosphere; Neat (no solvent);87%
With Montmorillonite K10 clay; hydrazine hydrate In ethanol for 0.05h; microwave irradiation;86%
Multi-step reaction with 3 steps
1: sulfuric acid / 70 - 80 °C
2: hydrazine hydrate / ethanol / 60 - 70 °C
3: trichlorophosphate / 8 h
View Scheme
ethanol
64-17-5

ethanol

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

ethyl 2-chlorobenzoate
7335-25-3

ethyl 2-chlorobenzoate

Conditions
ConditionsYield
With fluorosulfonyl fluoride; N-ethyl-N,N-diisopropylamine In 1,2-dichloro-ethane at 20℃; for 5h;99%
With sulfuric acid at 100℃; for 12h; Sealed tube;95%
With thionyl chloride for 2h; Heating;86%
3-chloro-aniline
108-42-9

3-chloro-aniline

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

N-(3-chlorophenyl)anthranilic acid
13278-36-9

N-(3-chlorophenyl)anthranilic acid

Conditions
ConditionsYield
With copper(I) oxide; copper; potassium carbonate In 2-ethoxy-ethanol at 130℃; for 24h;99%
With pyridine; copper; potassium carbonate In water for 1h; Heating;60%
With copper; potassium carbonate for 5h; Heating;44%
benzyl bromide
100-39-0

benzyl bromide

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

benzyl 2-chlorobenzoate
7579-40-0

benzyl 2-chlorobenzoate

Conditions
ConditionsYield
With N(Et)4(1+)*(2-pyrrolidone-anion) In N,N-dimethyl-formamide for 1h; Ambient temperature;99%
benzylamine
100-46-9

benzylamine

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

N-benzylanthranilic acid
6622-55-5

N-benzylanthranilic acid

Conditions
ConditionsYield
With copper(I) oxide; copper; potassium carbonate In various solvent(s) at 130℃; for 24h;99%
With potassium hydroxide; copper(II) oxide; tetrabutylammomium bromide In water at 130℃; for 0.0833333h; Ullmann-type C-N coupling; microwave irradiation;55%
With potassium phosphate; ethylene glycol; copper(l) iodide In butan-1-ol at 100℃; for 72h;48%
With copper; potassium carbonate In pentan-1-ol at 140℃; for 4h;44%
ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

3-amino-3',5'-dimethylbiphenyl
783325-73-5

3-amino-3',5'-dimethylbiphenyl

N-[3-(3,5-dimethylphenyl)phenyl]anthranilic acid
783325-75-7

N-[3-(3,5-dimethylphenyl)phenyl]anthranilic acid

Conditions
ConditionsYield
With copper(I) oxide; copper; potassium carbonate In 2-ethoxy-ethanol at 130℃; for 24h;99%
With copper(I) oxide; potassium carbonate; copper(II) oxide In 2-methoxy-ethanol for 2h; Heating;95%
With copper(I) oxide; copper; potassium carbonate In ethyl methyl ether for 2h; Heating / reflux;95%
ethylbenzene
100-41-4

ethylbenzene

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

1-phenylethyl 2-chlorobenzoate
111021-09-1

1-phenylethyl 2-chlorobenzoate

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide In water at 80℃; for 8h;99%
cyclohexyl-N-tosyl aziridine
68820-12-2

cyclohexyl-N-tosyl aziridine

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

2-((4-methylphenyl)sulfonamido)cyclohexyl 2-chlorobenzoate

2-((4-methylphenyl)sulfonamido)cyclohexyl 2-chlorobenzoate

Conditions
ConditionsYield
With tetrabutylammomium bromide In N,N-dimethyl-formamide at 65℃; for 33h; stereoselective reaction;99%
In N,N-dimethyl-formamide at 65℃; for 43h;97%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 50℃; Green chemistry;93%
(1S,2S,4S,5R,6S)-di-tert-butyl 4-amino-2-[(tert-butoxycarbonyl)amino]bicyclo[3.1.0]hexane-2,6-dicarboxylate
1440525-63-2

(1S,2S,4S,5R,6S)-di-tert-butyl 4-amino-2-[(tert-butoxycarbonyl)amino]bicyclo[3.1.0]hexane-2,6-dicarboxylate

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

di-tert-butyl (1S,2S,4S,5R,6S) 2-((tert-butoxycarbonyl)amino)-4-[(2-chlorobenzoyl)amino]bicyclo[3.1.0]hexane-2,6-dicarboxylate

di-tert-butyl (1S,2S,4S,5R,6S) 2-((tert-butoxycarbonyl)amino)-4-[(2-chlorobenzoyl)amino]bicyclo[3.1.0]hexane-2,6-dicarboxylate

Conditions
ConditionsYield
Stage #1: ortho-chlorobenzoic acid With benzotriazol-1-ol; dicyclohexyl-carbodiimide In N,N-dimethyl-formamide
Stage #2: (1S,2S,4S,5R,6S)-di-tert-butyl 4-amino-2-[(tert-butoxycarbonyl)amino]bicyclo[3.1.0]hexane-2,6-dicarboxylate In N,N-dimethyl-formamide
99%
aniline
62-53-3

aniline

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

N-(2-chlorophenyl)-N'-phenylurea
2989-99-3

N-(2-chlorophenyl)-N'-phenylurea

Conditions
ConditionsYield
With diphenyl phosphoryl azide; triethylamine In toluene at 100℃; for 0.0166667h; Curtius Rearrangement; Microwave irradiation;99%
2-iodobiphenyl
2113-51-1

2-iodobiphenyl

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

triphenylene
217-59-4

triphenylene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate; p-benzoquinone In dimethyl sulfoxide at 140℃; for 4h; Schlenk technique; Inert atmosphere;99%
1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

2-(m-tolylamino)benzoic acid
16524-22-4

2-(m-tolylamino)benzoic acid

Conditions
ConditionsYield
With copper; caesium carbonate; copper(II) oxide In water at 105℃; Reagent/catalyst; Temperature; Large scale;98.3%
With copper(I) oxide; copper; potassium carbonate In 2-ethoxy-ethanol at 130℃; for 24h;80%
With potassium carbonate; copper In N,N-dimethyl-formamide for 2h; Heating;63%
p-toluidine
106-49-0

p-toluidine

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

N-p-tolyl-anthranilic acid
16524-23-5

N-p-tolyl-anthranilic acid

Conditions
ConditionsYield
With copper; potassium carbonate for 5h; Heating;98%
With copper; sodium carbonate; copper(II) oxide In water at 105℃; Large scale;97.9%
With pyridine; copper; potassium carbonate In pentan-1-ol for 1h; Heating;84%
aniline
62-53-3

aniline

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

2-(phenylamino)benzoic acid
91-40-7

2-(phenylamino)benzoic acid

Conditions
ConditionsYield
With copper(I) sulfate; potassium carbonate; copper(II) sulfate In water for 0.0833333h; Ullmann condensation; microwave irradiation;98%
With potassium carbonate; copper(II) sulfate for 0.025h; Ullmann condensation; microwave irradiation;98%
With sodium acetate; copper (I) acetate In water for 4h; Heating;91%
ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

butan-1-ol
71-36-3

butan-1-ol

butyl 2-chlorobenzoate
52468-48-1

butyl 2-chlorobenzoate

Conditions
ConditionsYield
With sulfuric acid; acetonitrile at 80 - 85℃; for 16 - 18h;98%
With thionyl chloride for 2h; Heating;81%
With sulfuric acid
4-amino-benzoic acid
150-13-0

4-amino-benzoic acid

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

N-(4-carboxyphenyl)anthranilic acid
17332-57-9

N-(4-carboxyphenyl)anthranilic acid

Conditions
ConditionsYield
With copper(I) oxide; copper; potassium carbonate In 2-ethoxy-ethanol at 130℃; for 24h;98%
With copper; potassium carbonate In i-Amyl alcohol at 160℃; Ullmann Condensation;91%
With copper; potassium carbonate In N,N-dimethyl-formamide at 140 - 145℃; for 3.5h;79%
3-methylantranilic acid
4389-45-1

3-methylantranilic acid

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

2-<(2-carboxyphenyl)amino>-3-methylbenzoic acid
80841-45-8

2-<(2-carboxyphenyl)amino>-3-methylbenzoic acid

Conditions
ConditionsYield
With copper; potassium carbonate; copper(I) bromide In various solvent(s) at 160℃; for 0.5h;98%
ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

2-deuteriobenzoic acid
4551-39-7

2-deuteriobenzoic acid

Conditions
ConditionsYield
With hydrogen; water-d2; triethylamine; palladium on activated charcoal at 20℃;98%
With 10% Pd/C; hydrogen; water-d2; triethylamine In methanol at 20℃; for 24h; chemoselective reaction;97%
With deuteriated sodium hydroxide; aluminum nickel In water-d2 at 40℃; for 1h; Yield given;
ethyl iodide
75-03-6

ethyl iodide

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

ethyl 2-chlorobenzoate
7335-25-3

ethyl 2-chlorobenzoate

Conditions
ConditionsYield
With caesium carbonate In acetonitrile for 1.5h; Heating;98%
ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

2-chloro-6-iodobenzoic acid
13420-63-8

2-chloro-6-iodobenzoic acid

Conditions
ConditionsYield
With N-iodo-succinimide; [Ir(III)(η5-pentamethylcyclopentadienyl)(H2O)3](SO4) at 60℃; for 16h;98%
With [bis(acetoxy)iodo]benzene; iodine; palladium diacetate In N,N-dimethyl-formamide at 100℃; for 24h; Sealed tube;91%
With [bis(acetoxy)iodo]benzene; iodine; palladium diacetate In N,N-dimethyl-formamide at 100℃; for 24h;87%
Stage #1: ortho-chlorobenzoic acid With (E)-N,N,N′,N′-tetramethylethene-1,2-diamine; sec.-butyllithium In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: With iodine In tetrahydrofuran at -78 - 0℃;
53%
9-hydroxymethylanthracene
1468-95-7

9-hydroxymethylanthracene

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

2-chloro-benzoic acid anthracen-9-ylmethyl ester

2-chloro-benzoic acid anthracen-9-ylmethyl ester

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃;98%

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