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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Chlorobenzyl Bromide WITH HIGH P[URITY

Cas:611-17-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:Whit

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU-CHEM 2-Chlorobenzyl bromide 611-17-6

Cas:611-17-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 611-17-6 with best quality

Cas:611-17-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

2-Chlorobenzyl bromide CAS611-17-6

Cas:611-17-6

Min.Order:1 Kilogram

FOB Price: $289.0 / 499.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-(bromomethyl)-2-chloro- 611-17-6

Cas:611-17-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:611-17-6

Cas:611-17-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Chlorobenzyl Bromide

Cas:611-17-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzene,1-(bromomethyl)-2-chloro-

Cas:611-17-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 2-Chlorobenzyl bromide Synonyms: Toluene, alpha-bromo-o-chloro-;Toluene,α-bromo-o-chloro-;alpha-bromo-o-chloro-toluen;alpha-bromo-o-chlorotoluene;benzylbromide,2-chloro;-Bromo-2-chlorotoluene;α-Bromo-o-chlorotoluene;2-

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Chlorobenzyl bromide cas no. 611-17-6 98%

Cas:611-17-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

1-(BroMoMethyl)-2-chlorobenzene

Cas:611-17-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

2-Chlorobenzyl Bromide

Cas:611-17-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-Chlorobenzyl broMide

Cas:611-17-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

2-Chlorobenzyl bromide CAS No.611-17-6

Cas:611-17-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

2-Chlorobenzyl bromide cas 611-17-6Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-Chlorobenzyl bromide cas 611-17-6

Cas:611-17-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:Clear yellow liquid Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

2-Chlorobenzyl bromide manufacture

Cas:611-17-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

611-17-6 Application:intermediate

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Chlorobenzyl bromide

Cas:611-17-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

2-Chlorobenzyl bromide 611-17-6

Cas:611-17-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-Chlorobenzyl alcohol
17849-38-6

2-Chlorobenzyl alcohol

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

Conditions
ConditionsYield
With 1,1,1,2,2,2-hexamethyldisilane In chloroform for 1.5h; Reflux;96%
With phosphorus pentoxide; potassium bromide In acetonitrile at 20℃; for 0.5h;89%
With hydrogen bromide; benzene
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

A

2-chloro-benzaldehyde
89-98-5

2-chloro-benzaldehyde

B

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

C

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With oxygen; cobalt(II) acetate; sodium bromide In acetic acid at 95℃; for 0.666667h; Kinetics; Mechanism; Rate constant; other time; other temperature; various concentrations of Co(OAc)2 and NaBr;A n/a
B n/a
C 96%
With oxygen; cobalt(II) acetate; sodium bromide In acetic acid at 95℃; for 0.666667h;A n/a
B n/a
C 95%
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

Conditions
ConditionsYield
With dihydrogen peroxide; bromine In dichloromethane; water for 4h; Reflux;94%
With N-Bromosuccinimide In acetonitrile at 40℃; for 0.216667h; Flow reactor; Irradiation;88%
With sodium bromate; 2,2'-azobis(isobutyronitrile); sulfuric acid; sodium bromide; dibenzoyl peroxide In water; 1,2-dichloro-ethane Reflux;80%
2-chloro-benzaldehyde
89-98-5

2-chloro-benzaldehyde

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

Conditions
ConditionsYield
With Dichloromethylsilane; phosphorus tribromide; iron(III) chloride In acetonitrile for 4h; Heating;93%
With chloro-trimethyl-silane; 1,1,3,3-Tetramethyldisiloxane; lithium bromide In acetonitrile at 80℃; for 0.25h;64%
With chloro-trimethyl-silane; 1,1,3,3-Tetramethyldisiloxane; lithium bromide 1.) acetonitrile, room temperature, 10 min, 2.) 15 min, 80 deg C; Yield given. Multistep reaction;
1-chloro-2-(chloromethyl)benzene
611-19-8

1-chloro-2-(chloromethyl)benzene

A

2-bromo-2’-chlorodiethyl ether
51070-66-7

2-bromo-2’-chlorodiethyl ether

B

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

Conditions
ConditionsYield
With sodium bromide; 1,2-dibromomethane In N,N-dimethyl-formamide at 100℃; for 6h;A n/a
B 93%
1-chloro-2-(chloromethyl)benzene
611-19-8

1-chloro-2-(chloromethyl)benzene

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

Conditions
ConditionsYield
With 1,1'-[1,2-phenylenebis(nitrilomethylylidene)dinaphthalen-2-olato]uranyl(VI); bromine In dichloromethane at 20℃; for 0.583333h;82%
2-chloro-1-(methoxymethoxy)methyl benzene
1058649-12-9

2-chloro-1-(methoxymethoxy)methyl benzene

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

Conditions
ConditionsYield
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.0833333h; Microwave irradiation; Neat (no solvent); chemoselective reaction;81%
2-chloro-1-[(ethoxymethoxy)methyl]benzene
1058649-16-3

2-chloro-1-[(ethoxymethoxy)methyl]benzene

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

Conditions
ConditionsYield
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.0833333h; Microwave irradiation; Neat (no solvent); chemoselective reaction;79%
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

A

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

B

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper(ll) bromide In acetic anhydrideA 72%
B 12%
bromocyane
506-68-3

bromocyane

1-(2-chlorophenyl)-N,N-dimethylmethanamine
10175-31-2

1-(2-chlorophenyl)-N,N-dimethylmethanamine

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

bromocyane
506-68-3

bromocyane

(2-chloro-benzyl)-methyl-(4-nitro-benzyl)-amine
65763-39-5

(2-chloro-benzyl)-methyl-(4-nitro-benzyl)-amine

A

methyl-(4-nitro-benzyl)-carbamonitrile
52245-37-1

methyl-(4-nitro-benzyl)-carbamonitrile

B

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

bromocyane
506-68-3

bromocyane

(2-chloro-benzyl)-(3-iodo-benzyl)-methyl-amine

(2-chloro-benzyl)-(3-iodo-benzyl)-methyl-amine

A

(2-chloro-benzyl)-methyl-carbamonitrile

(2-chloro-benzyl)-methyl-carbamonitrile

B

(3-iodo-benzyl)-methyl-carbamonitrile

(3-iodo-benzyl)-methyl-carbamonitrile

C

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

D

3-iodobenzyl bromide
49617-83-6

3-iodobenzyl bromide

bromocyane
506-68-3

bromocyane

(2-bromo-benzyl)-(2-chloro-benzyl)-methyl-amine
876476-07-2

(2-bromo-benzyl)-(2-chloro-benzyl)-methyl-amine

A

(2-bromo-benzyl)-methyl-carbamonitrile

(2-bromo-benzyl)-methyl-carbamonitrile

B

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

bromocyane
506-68-3

bromocyane

(2-chloro-benzyl)-methyl-(2-nitro-benzyl)-amine
854392-01-1

(2-chloro-benzyl)-methyl-(2-nitro-benzyl)-amine

A

methyl-(2-nitro-benzyl)-carbamonitrile

methyl-(2-nitro-benzyl)-carbamonitrile

B

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

bromocyane
506-68-3

bromocyane

1-(2-chlorophenyl)-N,N-dimethylmethanamine
10175-31-2

1-(2-chlorophenyl)-N,N-dimethylmethanamine

A

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

B

NCNMe2
1467-79-4

NCNMe2

C

dimethyl-bis-<2-chloro-benzyl>-ammonium bromide

dimethyl-bis-<2-chloro-benzyl>-ammonium bromide

chlorobenzene
108-90-7

chlorobenzene

1,1-dibromomethane
74-95-3

1,1-dibromomethane

A

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

B

4-chlorobenzyl bromide
622-95-7

4-chlorobenzyl bromide

Conditions
ConditionsYield
Stage #1: chlorobenzene With sodium hydride In N,N-dimethyl-formamide at 20℃;
Stage #2: 1,2-dibromomethane In N,N-dimethyl-formamide at 60℃; for 2h;
ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium tetrahydroborate / methanol / 2 h / 0 - 20 °C
2: phosphorus tribromide / dichloromethane / 0.5 h / 0 - 5 °C
View Scheme
Multi-step reaction with 2 steps
1: sodium tetrahydroborate; iodine / tetrahydrofuran / 12 h / 0 °C / Heating
2: acetic acid; hydrogen bromide / water / 2 h / 100 °C
View Scheme
methyl 2-hydroxy-5-(tetrahydropyranyloxy)benzoate
94420-55-0

methyl 2-hydroxy-5-(tetrahydropyranyloxy)benzoate

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

C20H21ClO5
945989-82-2

C20H21ClO5

Conditions
ConditionsYield
With caesium carbonate In acetone at 40℃; for 4h;100%
ethyl 4-bromo-2-nitro-6-(trifluoromethyl)phenylcarbamate
444901-29-5

ethyl 4-bromo-2-nitro-6-(trifluoromethyl)phenylcarbamate

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

ethyl 4-bromo-2-nitro-6-(trifluoromethyl)phenyl(2-chlorobenzyl)carbamate
444901-30-8

ethyl 4-bromo-2-nitro-6-(trifluoromethyl)phenyl(2-chlorobenzyl)carbamate

Conditions
ConditionsYield
With potassium carbonate In DMF (N,N-dimethyl-formamide) at 50℃; for 1h;100%
1,3-Dihydro-3,3-dimethyl-5-nitro-2H-indol-2-one
100511-00-0

1,3-Dihydro-3,3-dimethyl-5-nitro-2H-indol-2-one

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

C17H15ClN2O3
925220-74-2

C17H15ClN2O3

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 80℃; for 12h;100%
1-hydroxy-3,6,7-tris(methoxymethoxy)-9H-xanthen-9-one
1314917-55-9

1-hydroxy-3,6,7-tris(methoxymethoxy)-9H-xanthen-9-one

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

C26H25ClO9
1314917-82-2

C26H25ClO9

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 6h;100%
methyl 3-chloro-1H-indole-4-carboxylate

methyl 3-chloro-1H-indole-4-carboxylate

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

C17H13Cl2NO2

C17H13Cl2NO2

Conditions
ConditionsYield
With sodium hydride at 0℃; for 5h;100%
3,5-dibromo-4-hydroxybenzaldehyde
2973-77-5

3,5-dibromo-4-hydroxybenzaldehyde

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

(E)-2,6-dibromo-4-(2-chlorostyryl)phenol
1207104-21-9

(E)-2,6-dibromo-4-(2-chlorostyryl)phenol

Conditions
ConditionsYield
Stage #1: 1-bromomethyl-2-chlorobenzene With triethyl phosphite at 150℃; for 3h; Horner-Wittig reaction; Inert atmosphere;
Stage #2: With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; Horner-Wittig reaction; Inert atmosphere;
Stage #3: 3,5-dibromo-4-hydroxybenzaldehyde In N,N-dimethyl-formamide; mineral oil at 0℃; Horner-Wittig reaction; Inert atmosphere;
99%
2-(N,N-dimethylamino)ethanol
108-01-0

2-(N,N-dimethylamino)ethanol

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

2-((2-chlorobenzyl)oxy)-N,N-dimethylethanamine hydrochloride

2-((2-chlorobenzyl)oxy)-N,N-dimethylethanamine hydrochloride

Conditions
ConditionsYield
Stage #1: 2-(N,N-dimethylamino)ethanol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 20℃; for 0.5h;
Stage #2: 1-bromomethyl-2-chlorobenzene In N,N-dimethyl-formamide; mineral oil at 20℃; for 16h;
Stage #3: With hydrogenchloride In 1,4-dioxane; methanol for 0.5h;
99%
de(3'-N-methyl)-9-dihydro-pseudoerythromycin A 6,9-epoxide

de(3'-N-methyl)-9-dihydro-pseudoerythromycin A 6,9-epoxide

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

de(3'-N-methyl)-3'-N-(o-chlorobenzyl)-9-dihydro-pseudoerythromycin A 6,9-epoxide

de(3'-N-methyl)-3'-N-(o-chlorobenzyl)-9-dihydro-pseudoerythromycin A 6,9-epoxide

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In chloroform at 20℃; for 2.5h;98%
t-butyl 3-(2-fluorospiro[4,5-dihydrothieno[2,3-c]pyran-7,4'-piperidine]-1'-yl)propanoate
1283095-51-1

t-butyl 3-(2-fluorospiro[4,5-dihydrothieno[2,3-c]pyran-7,4'-piperidine]-1'-yl)propanoate

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

tert-butyl 2-[(2-chlorophenyl)methyl]-3-(2-fluorospiro[4,5-dihydrothieno[2,3-c]pyran-7,4'-piperidine]-1'-yl)propanoate
1283095-53-3

tert-butyl 2-[(2-chlorophenyl)methyl]-3-(2-fluorospiro[4,5-dihydrothieno[2,3-c]pyran-7,4'-piperidine]-1'-yl)propanoate

Conditions
ConditionsYield
Stage #1: t-butyl 3-(2-fluorospiro[4,5-dihydrothieno[2,3-c]pyran-7,4'-piperidine]-1'-yl)propanoate With lithium hexamethyldisilazane In tetrahydrofuran at -78℃; for 1.5h;
Stage #2: With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone In tetrahydrofuran at -78℃; for 0.5h;
Stage #3: 1-bromomethyl-2-chlorobenzene In tetrahydrofuran at -78 - 0℃; for 1h;
98%
1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

diethyl 2-(2-chlorobenzyl)malonate
77738-21-7

diethyl 2-(2-chlorobenzyl)malonate

Conditions
ConditionsYield
Stage #1: malonic acid dimethyl ester With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.25h;
Stage #2: 1-bromomethyl-2-chlorobenzene In tetrahydrofuran; mineral oil at 60℃;
98%
1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

potassium selenocyanate
3425-46-5

potassium selenocyanate

(2-chlorophenyl)methaneselenenyl cyanide
57239-47-1

(2-chlorophenyl)methaneselenenyl cyanide

Conditions
ConditionsYield
In ethanol for 0.166667h;97%
In ethanol for 5h; Ambient temperature;85%
2-(2-chloro-5-hydroxyphenyl)-2-isopropyl-3-methylbutanenitrile
1274905-18-8

2-(2-chloro-5-hydroxyphenyl)-2-isopropyl-3-methylbutanenitrile

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

2-(2-chloro-((2-chlorobenzyl)oxy)phenyl)-2-isopropyl-3-methylbutanenitrile
1274905-20-2

2-(2-chloro-((2-chlorobenzyl)oxy)phenyl)-2-isopropyl-3-methylbutanenitrile

Conditions
ConditionsYield
With potassium carbonate In acetone at 50℃;97%
1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

(piperidin-4-yl)carbamic acid tert-butyl ester
73874-95-0

(piperidin-4-yl)carbamic acid tert-butyl ester

C17H25ClN2O2
1286273-10-6

C17H25ClN2O2

Conditions
ConditionsYield
With potassium carbonate In dichloromethane at 20℃;97%
With triethylamine In ethanol
With sodium hydride In tetrahydrofuran at -20℃; for 12h;
methyl 2-(7-hydroxy-4,8-dimethyl-2-oxo-2H-chromen-3-yl)acetate
433703-81-2

methyl 2-(7-hydroxy-4,8-dimethyl-2-oxo-2H-chromen-3-yl)acetate

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

methyl 2-(7-((2-chlorobenzyl)oxy)-4,8-dimethyl-2-oxo-2H-chromen-3-yl)acetate

methyl 2-(7-((2-chlorobenzyl)oxy)-4,8-dimethyl-2-oxo-2H-chromen-3-yl)acetate

Conditions
ConditionsYield
With potassium carbonate In acetone Reflux;97%
4-(3-methyl-5-oxo-4H-pyrazol-1-yl)-N-(pyridine-4-ylmethyl)benzamide

4-(3-methyl-5-oxo-4H-pyrazol-1-yl)-N-(pyridine-4-ylmethyl)benzamide

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

1-[(2-chlorophenyl)methyl]-4-({[4-(3-methyl-5-oxo-4H-pyrazol-1-yl)phenyl]formamido}methyl)pyridin-1-ium bromide

1-[(2-chlorophenyl)methyl]-4-({[4-(3-methyl-5-oxo-4H-pyrazol-1-yl)phenyl]formamido}methyl)pyridin-1-ium bromide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 40 - 50℃;96.53%
1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

triethyl phosphite
122-52-1

triethyl phosphite

2-chlorobenzyl diethylphosphonate
29074-98-4

2-chlorobenzyl diethylphosphonate

Conditions
ConditionsYield
at 150℃; Inert atmosphere; neat (no solvent);96%
In xylene for 20h; Reflux;91%
4,5-dichloro-2H-pyridazin-3-one
932-22-9

4,5-dichloro-2H-pyridazin-3-one

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

4,5-dichloro-2-[2-chlorophenyl]methylpyridazin-3-one

4,5-dichloro-2-[2-chlorophenyl]methylpyridazin-3-one

Conditions
ConditionsYield
With potassium carbonate; potassium iodide In N,N-dimethyl-formamide at 90℃; for 2h;96%
4-(4-chlorophenyl)-1-(2-methoxyethyl)-6-methyl-2-oxo-3,4-dihydropyridine-5-carboxylic acid

4-(4-chlorophenyl)-1-(2-methoxyethyl)-6-methyl-2-oxo-3,4-dihydropyridine-5-carboxylic acid

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

(2-chlorophenyl)methyl 4-(4-chlorophenyl)-1-(2-methoxyethyl)-6-methyl-2-oxo-3,4-dihydropyridine-5-carboxylate

(2-chlorophenyl)methyl 4-(4-chlorophenyl)-1-(2-methoxyethyl)-6-methyl-2-oxo-3,4-dihydropyridine-5-carboxylate

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 20℃; for 1h;96%
(Z)-β-bromostyrene
588-73-8

(Z)-β-bromostyrene

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

1-(2-chlorobenzyl)-4-phenyl-1H-1,2,3-triazole
63778-13-2

1-(2-chlorobenzyl)-4-phenyl-1H-1,2,3-triazole

Conditions
ConditionsYield
With copper(l) iodide; sodium azide; 1,8-diazabicyclo[5.4.0]undec-7-ene at 100℃; for 0.5h;96%
phenoxyacetylene
4279-76-9

phenoxyacetylene

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

C15H12ClN3O

C15H12ClN3O

Conditions
ConditionsYield
Stage #1: 1-bromomethyl-2-chlorobenzene With sodium azide In methanol at 20℃; Green chemistry;
Stage #2: phenoxyacetylene In methanol at 20℃; Green chemistry;
96%
1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

phenylpropyolic acid
637-44-5

phenylpropyolic acid

1-(2-chlorobenzyl)-4-phenyl-1H-1,2,3-triazole
63778-13-2

1-(2-chlorobenzyl)-4-phenyl-1H-1,2,3-triazole

Conditions
ConditionsYield
With copper(l) iodide; sodium azide; potassium carbonate at 60℃; for 0.5h;96%
1,2,3,4-tetrahydroisoquinoline
91-21-4

1,2,3,4-tetrahydroisoquinoline

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

2-(2-chlorobenzyl)-1,2,3,4-tetrahydroisoquinoline
72809-43-9

2-(2-chlorobenzyl)-1,2,3,4-tetrahydroisoquinoline

Conditions
ConditionsYield
With sodium hydride; N,N-dimethyl-formamide In mineral oil at 50℃;96%
8-tert-butyl-3,3,5-trimethyl-3H,11H-pyrano[3,2-a]carbazole

8-tert-butyl-3,3,5-trimethyl-3H,11H-pyrano[3,2-a]carbazole

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

8-(tert-butyl)-11-(2-chlorobenzyl)-3,3,5-trimethyl-3,11-dihydropyrano[3,2-a]carbazole

8-(tert-butyl)-11-(2-chlorobenzyl)-3,3,5-trimethyl-3,11-dihydropyrano[3,2-a]carbazole

Conditions
ConditionsYield
Stage #1: 8-tert-butyl-3,3,5-trimethyl-3H,11H-pyrano[3,2-a]carbazole With sodium hydride In tetrahydrofuran at 0℃; for 0.5h;
Stage #2: 1-bromomethyl-2-chlorobenzene In tetrahydrofuran at 0 - 20℃; for 3h;
96%
(2-chlorophenyl)methaneselenenyl cyanide
57239-47-1

(2-chlorophenyl)methaneselenenyl cyanide

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

bis-(2-chloro-benzyl)-selenide
56344-09-3

bis-(2-chloro-benzyl)-selenide

Conditions
ConditionsYield
With sodium tetrahydroborate In benzene for 1h; Ambient temperature;95%
1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

α-deuterio-o-chlorotoluene
138433-41-7

α-deuterio-o-chlorotoluene

Conditions
ConditionsYield
With lithium aluminium deuteride In tetrahydrofuran95%
With sodium borodeuteride In dimethylsulfoxide-d6 at 0 - 20℃; for 4h; Inert atmosphere;72%
1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

2-chlorobenzylazide
63777-70-8

2-chlorobenzylazide

Conditions
ConditionsYield
With sodium azide In N,N-dimethyl-formamide at 20 - 80℃; for 4h;95%
With sodium azide In dimethyl sulfoxide at 20℃; for 24h;92%
With sodium azide In water; acetone at 20 - 60℃;
2-aminopyrimidine
109-12-6

2-aminopyrimidine

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

N-(2-chlorobenzyl)-(2-pyrimidyl)amine
23676-58-6

N-(2-chlorobenzyl)-(2-pyrimidyl)amine

Conditions
ConditionsYield
Stage #1: 2-aminopyrimidine With sodium hydride In tetrahydrofuran for 0.25h; Cooling with ice;
Stage #2: 1-bromomethyl-2-chlorobenzene In tetrahydrofuran at 20℃; for 24h; Cooling with ice;
95%
benzyl 2-(benzyloxy)-4-(N-(4-cyclohexylbenzyl)-2-(perfluorophenylsulfonamido)acetamido)benzoate
1455006-14-0

benzyl 2-(benzyloxy)-4-(N-(4-cyclohexylbenzyl)-2-(perfluorophenylsulfonamido)acetamido)benzoate

1-bromomethyl-2-chlorobenzene
611-17-6

1-bromomethyl-2-chlorobenzene

benzyl 2-(benzyloxy)-4-(2-(N-(2-chlorobenzyl)-2,3,4,5,6-pentafluorophenylsulfonamido)-N-(4-cyclohexylbenzyl)acetamido)benzoate
1455006-27-5

benzyl 2-(benzyloxy)-4-(2-(N-(2-chlorobenzyl)-2,3,4,5,6-pentafluorophenylsulfonamido)-N-(4-cyclohexylbenzyl)acetamido)benzoate

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 20℃; Inert atmosphere;95%

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