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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Alpha-Bromo-P-Toluic Acid , 4-Bromomethylbenzoic Acid

Cas:6232-88-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

ANQING CHICO PHARMACEUTICAL CO.,LTD.

High quality. Factory supply. In stock. Best price.1.Quick response within 24 hours;2.Best quality in your requirement;?3.We pay more attention on delivery time, and usually ship on time;4.Under the premise of safety and effectiveness, we can produce

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:1 Kilogram

FOB Price: $15.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-(Bromomethyl)-benzoic acid

Cas:6232-88-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

4-Bromomethylbenzoic acid Basic information Product Name: 4-Bromomethylbenzoic acid Synonyms: ALPHA-BROMO-P-TOLUYLIC ACID;ALPHA-BROMO-P-TOLUIC ACID;AKOS BBS-0000671

4-Bromomethylbenzoic acid_

Cas:6232-88-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:1 Kilogram

FOB Price: $2.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 6232-88-8 with high quality products

Cas:6232-88-8

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoic acid,4-(bromomethyl)- 6232-88-8

Cas:6232-88-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

4-Bromomethylbenzoic acid 99%

Cas:6232-88-8

Min.Order:1 Kilogram

FOB Price: $52.0 / 65.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supply High quality4-Bromomethylbenzoic acid CAS 6232-88-8 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made

High quality4-Bromomethylbenzoic acid CAS 6232-88-8

Cas:6232-88-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzoic acid,4-(bromomethyl)-

Cas:6232-88-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:6232-88-8

Cas:6232-88-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Alpha-Bromo-P-Toluic Acid , 4-Bromomethylbenzoic Acid

Cas:6232-88-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

4-Bromomethylbenzoic acid_

Cas:6232-88-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

4-Bromomethylbenzoic acid Chemical Properties Melting point 224-229 °C(lit.) Boiling point 252.95°C (rough estimate) density 1.5313 (rough estimate) refractive index 1.5500 (estimate) storage temp. Store below +30°C. p

4-(Bromomethyl)benzoic Acid

Cas:6232-88-8

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

4-(Bromomethyl)benzoic acid

Cas:6232-88-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

4-Bromomethylbenzoic acid

Cas:6232-88-8

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Changzhou Anchor Biological Technology Co., Ltd.

Our company is engaged in customizing the benzene ring and pyridine derivative organic intermediates, and the quantity is flexible according to customer's needs. It mainly provides high-quality intermediates for domestic and foreign pharmaceutical an

4-(Bromomethyl)benzoic acid Manufacturer/High quality/Best price/In stock CAS NO.6232-88-8

Cas:6232-88-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratoryAppearance:White to off-white powder Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

4-(Bromomethyl)benzoic acid cas no. 6232-88-8 98%

Cas:6232-88-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Alpha-Bromo-p-toluic acid

Cas:6232-88-8

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

p-Toluic acid
99-94-5

p-Toluic acid

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane for 6h; Reflux;100%
With sodium bromate; sodium hydrogensulfite In water; ethyl acetate90%
With dihydrogen peroxide; bromine In dichloromethane; water for 4h; Reflux;87%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
With carbon tetrabromide; oxygen In acetonitrile at 20℃; for 60h; UV-irradiation;91.3%
With carbon tetrabromide; oxygen In acetonitrile at 20℃; for 60h; Irradiation;75%
4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

A

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

B

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With N-Bromosuccinimide In water at 27℃; for 25h; Irradiation;A 2 %Spectr.
B 80%
4-cyanobenzyl bromide
17201-43-3

4-cyanobenzyl bromide

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
With hydrogen bromide for 5h; Heating;77.5%
With hydrogen bromide
With hydrogenchloride
4-Methylbenzyl alcohol
589-18-4

4-Methylbenzyl alcohol

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane for 0.5h; Heating;72%
N-Bromosuccinimide
128-08-5

N-Bromosuccinimide

p-Toluic acid
99-94-5

p-Toluic acid

A

4-(Bromomethyl)benxoic acid

4-(Bromomethyl)benxoic acid

B

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
With dibenzoyl peroxide In tetrachloromethaneA n/a
B 67.7%
p-Toluic acid
99-94-5

p-Toluic acid

A

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

B

terephthalic acid
100-21-0

terephthalic acid

C

3-bromo-4-methylbenzoic acid
7697-26-9

3-bromo-4-methylbenzoic acid

D

p-acetoxymethyl benzoic acid
15561-46-3

p-acetoxymethyl benzoic acid

E

4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

F

benzyl alcohol
100-51-6

benzyl alcohol

Conditions
ConditionsYield
With cobalt(III) acetate; sodium bromide In water; trifluoroacetic acid at 72℃; for 2.5h; Product distribution; other oxidizing agents (Mn(III) triacetate, lead tetraacetate, cerium ammonium nitrate), other time and temperature.;A 16.6%
B 1.4%
C 17.7%
D 15.3%
E 43.1%
F 5.4%
4-bromomethylbenzoyl chloride
52780-16-2

4-bromomethylbenzoyl chloride

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
With formic acid
4-(bromomethyl)benzoyl bromide
876-07-3

4-(bromomethyl)benzoyl bromide

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
With formic acid at 30 - 35℃;
p-Toluic acid
99-94-5

p-Toluic acid

trifluoroacetic acid
76-05-1

trifluoroacetic acid

A

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

B

terephthalic acid
100-21-0

terephthalic acid

C

3-bromo-4-methylbenzoic acid
7697-26-9

3-bromo-4-methylbenzoic acid

D

p-acetoxymethyl benzoic acid
15561-46-3

p-acetoxymethyl benzoic acid

E

4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

F

4-(2,2,2-Trifluoro-acetoxymethyl)-benzoic acid
78504-88-8

4-(2,2,2-Trifluoro-acetoxymethyl)-benzoic acid

Conditions
ConditionsYield
With cobalt(III) acetate; sodium bromide In water at 25℃; Product distribution; Concentration and the amount of Co(III) acetate, sodium bromide and water was tested;A 53.6 % Chromat.
B 4.9 % Chromat.
C 1.0 % Chromat.
D 0.8 % Chromat.
E 7.6 % Chromat.
F 0.8 % Chromat.
p-Toluic acid
99-94-5

p-Toluic acid

A

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

B

3-bromo-4-methylbenzoic acid
7697-26-9

3-bromo-4-methylbenzoic acid

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate; sodium bromide In water; trifluoroacetic acid for 48h; Ambient temperature; Yield given. Yields of byproduct given;
p-Toluic acid
99-94-5

p-Toluic acid

A

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

B

terephthalic acid
100-21-0

terephthalic acid

C

3-bromo-4-methylbenzoic acid
7697-26-9

3-bromo-4-methylbenzoic acid

D

4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

Conditions
ConditionsYield
With cobalt(III) acetate; sodium bromide In water; trifluoroacetic acid at 25℃; Title compound not separated from byproducts;A 94.2 % Chromat.
B 2.2 % Chromat.
C 2.5 % Chromat.
D 1.1 % Chromat.
hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

4-cyanobenzyl bromide
17201-43-3

4-cyanobenzyl bromide

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

p-Me-C6H4-CO2H or p-Me-C6H4-CO2Et

p-Me-C6H4-CO2H or p-Me-C6H4-CO2Et

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
With N-Bromosuccinimide; Perbenzoic acid In tetrachloromethane for 3h; Heating; Irradiation;
p-xylylene glycol
589-29-7

p-xylylene glycol

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 96 percent / H2 / Raney Ni / aq. NaOH / 20 °C
2: 72 percent / NBS / benzoyl peroxide / CCl4 / 0.5 h / Heating
View Scheme
para-bromotoluene
106-38-7

para-bromotoluene

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: pyridine / 195 °C / Erhitzen des Reaktionsgemisches mit wss. H2SO4 auf 150grad
2: nitrobenzene; bromine
View Scheme
4-methyl-benzoyl chloride
874-60-2

4-methyl-benzoyl chloride

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: bromine / 160 °C / Irradiation.mit Gluehlampenlicht
2: aqueous formic acid
View Scheme
p-Toluic acid
99-94-5

p-Toluic acid

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

A

2-(p-Aminomethylphenyl)penem-3-carboxylic Acid

2-(p-Aminomethylphenyl)penem-3-carboxylic Acid

B

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
With N-Bromosuccinimide In water; benzeneA 15.0 g (69.7 mmol, 71.1%)
B n/a
4-methylbenzoic acid ethyl ester
94-08-6

4-methylbenzoic acid ethyl ester

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: N-Bromosuccinimide; dibenzoyl peroxide / tetrachloromethane / Reflux
2: potassium hydroxide / water / 0.5 h
View Scheme
Ethyl 4-(bromomethyl)benzoate
26496-94-6

Ethyl 4-(bromomethyl)benzoate

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
With potassium hydroxide In water for 0.5h;
phthalic anhydride
85-44-9

phthalic anhydride

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: water; sodium hydroxide / 3 h / 80 - 150 °C
2: ammonium hydroxide / 1 h / 180 °C
3: aluminum (III) chloride / diethyl ether / 1 h / 40 °C
4: N-Bromosuccinimide; dibenzoyl peroxide / tetrachloromethane / 2 h / 80 °C
View Scheme
benzoic acid
65-85-0

benzoic acid

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aluminum (III) chloride / diethyl ether / 1 h / 40 °C
2: N-Bromosuccinimide; dibenzoyl peroxide / tetrachloromethane / 2 h / 80 °C
View Scheme
benzene-1,2-dicarboxylic acid
88-99-3

benzene-1,2-dicarboxylic acid

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: ammonium hydroxide / 1 h / 180 °C
2: aluminum (III) chloride / diethyl ether / 1 h / 40 °C
3: N-Bromosuccinimide; dibenzoyl peroxide / tetrachloromethane / 2 h / 80 °C
View Scheme
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

4-bromomethylbenzoyl chloride
52780-16-2

4-bromomethylbenzoyl chloride

Conditions
ConditionsYield
With thionyl chloride In toluene for 5 - 6h; Heating / reflux;100%
With thionyl chloride at 20℃; for 4.5h; Heating / reflux;100%
With thionyl chloride for 3h; Chlorination; Heating;93%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Methyl 4-(bromomethyl)benzoate
2417-72-3

Methyl 4-(bromomethyl)benzoate

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at 0℃;100%
With potassium hydroxide In diethyl ether; ethanol for 12h;98%
In diethyl ether
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

4-(bromomethyl)benzyl alcohol
71831-21-5

4-(bromomethyl)benzyl alcohol

Conditions
ConditionsYield
Stage #1: 4-bromomethylbenzoic Acid With borane-THF In tetrahydrofuran at 0 - 20℃;
Stage #2: With methanol; water In tetrahydrofuran
99%
Stage #1: 4-bromomethylbenzoic Acid With borane-THF In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;
Stage #2: With methanol In tetrahydrofuran at 20℃; Inert atmosphere;
96%
With borane-THF In tetrahydrofuran at 0 - 20℃;94%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

triethyl phosphite
122-52-1

triethyl phosphite

4-[(diethoxyphosphinyl)methyl]benzoic acid
28149-48-6

4-[(diethoxyphosphinyl)methyl]benzoic acid

Conditions
ConditionsYield
for 20h; Heating / reflux;98%
In toluene for 18h; Arbuzov reaction; Heating;77%
In toluene for 18h; Heating / reflux;77%
for 3h; Heating;
ammonium hexafluorophosphate

ammonium hexafluorophosphate

Ru(C5H3N(C7H9N2)2)2(2+)*2PF6(1-)=[Ru(C5H3N(C7H9N2)2)2](PF6)2

Ru(C5H3N(C7H9N2)2)2(2+)*2PF6(1-)=[Ru(C5H3N(C7H9N2)2)2](PF6)2

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Ru(C5H3N(C7H8(CH2C6H4CO2CH3)N2)2)2(2+)*2PF6(1-)=[Ru(C5H3N(C7H8(CH2C6H4CO2CH3)N2)2)2](PF6)2

Ru(C5H3N(C7H8(CH2C6H4CO2CH3)N2)2)2(2+)*2PF6(1-)=[Ru(C5H3N(C7H8(CH2C6H4CO2CH3)N2)2)2](PF6)2

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran byproducts: H2; refluxing Ru-complex with NaH under Ar for 2 h, addn. of excess alkylating agent, refluxing for 24 h, solvent removal, dissoln. in CHCl3, washing (water), chromy. (Al2O3, 10% MeOH in CH2Cl2), pptn. from MeOH soln. with excess aq. NH4PF6; cooling in refrigerator for 1 h, collection (filtration), drying (vac.);elem. anal.;98%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

4-[(nitrooxy)methyl]benzoic acid
258278-55-6

4-[(nitrooxy)methyl]benzoic acid

Conditions
ConditionsYield
With silver nitrate In acetonitrile at 20℃; Darkness;97%
With silver nitrate In acetonitrile Substitution;84%
With silver nitrate In acetonitrile at 20℃; for 24h;83%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

triphenylphosphine
603-35-0

triphenylphosphine

((4-carboxyphenyl)methyl)triphenylphosphonium bromide

((4-carboxyphenyl)methyl)triphenylphosphonium bromide

Conditions
ConditionsYield
In acetone for 3h; Reflux;97%
In acetone for 6h; Heating;82%
In toluene Heating;80%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

3-hydroxymethyl-benzoic acid
3006-96-0

3-hydroxymethyl-benzoic acid

Conditions
ConditionsYield
With water for 2h; Heating;96%
With water for 4h; Heating;91%
With water for 1h; Heating;88%
methanol
67-56-1

methanol

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Methyl 4-(bromomethyl)benzoate
2417-72-3

Methyl 4-(bromomethyl)benzoate

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 16h;96%
With sulfuric acid for 5h; Heating;93%
With thionyl chloride at 25℃; for 12h;93.2%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

thioacetic acid
507-09-5

thioacetic acid

thioacetic acid S-(4-carboxybenzyl) ester
132035-64-4

thioacetic acid S-(4-carboxybenzyl) ester

Conditions
ConditionsYield
With sodium hydrogencarbonate In acetone for 24h; Ambient temperature;96%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

pent-4-enyl 3,4,6-tri-O-benzoyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside
174356-27-5

pent-4-enyl 3,4,6-tri-O-benzoyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside

acetonitrile
75-05-8

acetonitrile

1-N-(acetyl)-[N-(4-bromomethyl)-benzoyl]-2-deoxy-2-tetrachlorophthalimido-3,4,6-tri-O-benzoyl-β-D-glucopyranosyl amine

1-N-(acetyl)-[N-(4-bromomethyl)-benzoyl]-2-deoxy-2-tetrachlorophthalimido-3,4,6-tri-O-benzoyl-β-D-glucopyranosyl amine

Conditions
ConditionsYield
With N-Bromosuccinimide at 20℃; for 7h;96%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

N-isocyaniminotriphenylphosphorane
73789-56-7

N-isocyaniminotriphenylphosphorane

acenaphthene quinone
82-86-0

acenaphthene quinone

2-[5-[4-(bromomethyl)phenyl]-1,3,4-oxadiazol-2-yl]-2-hydroxy-1(2H)-acenaphthylenone
1309930-27-5

2-[5-[4-(bromomethyl)phenyl]-1,3,4-oxadiazol-2-yl]-2-hydroxy-1(2H)-acenaphthylenone

Conditions
ConditionsYield
In acetonitrile at 20℃; for 0.25h; Time; Sonication;96%
In water at 20 - 26℃; for 15h; Green chemistry;85%
In acetonitrile at 20℃; for 24h;82%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

p-aminomethylbenzoic acid
56-91-7

p-aminomethylbenzoic acid

Conditions
ConditionsYield
With potassium carbonate; triethylamine In tetrachloromethane at 25℃; for 4h; Temperature;95.32%
With ammonium hydroxide
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

acetic acid
64-19-7

acetic acid

p-acetoxymethyl benzoic acid
15561-46-3

p-acetoxymethyl benzoic acid

Conditions
ConditionsYield
With potassium acetate for 8h; Heating;95%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

thiophenol
108-98-5

thiophenol

4-<(Phenylthio)methyl>benzoic acid
88382-49-4

4-<(Phenylthio)methyl>benzoic acid

Conditions
ConditionsYield
With sodium carbonate for 3h;95%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

2-aminopyridine-3-carboxamide
13438-65-8

2-aminopyridine-3-carboxamide

4-(3-Carbamoyl-2-imino-2H-pyridin-1-ylmethyl)-benzoic acid; hydrobromide

4-(3-Carbamoyl-2-imino-2H-pyridin-1-ylmethyl)-benzoic acid; hydrobromide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 15℃; for 480h;95%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

Benzimidazol-2-thiol
134469-07-1

Benzimidazol-2-thiol

4-<(2'-thiobenzimidazol)methyl>benzoic acid
194479-08-8

4-<(2'-thiobenzimidazol)methyl>benzoic acid

Conditions
ConditionsYield
With potassium hydroxide In water for 10h; Heating;95%
With sodium hydroxide In various solvent(s) at 120℃;
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

(4-azidomethyl)benzoic acid
79584-03-5

(4-azidomethyl)benzoic acid

Conditions
ConditionsYield
With sodium azide In dimethyl sulfoxide at 80℃; for 48h;95%
With sodium azide In N,N-dimethyl-formamide at 50℃; for 48h; Inert atmosphere;95%
With sodium azide In N,N-dimethyl-formamide at 50℃; for 15h;94%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

(4-carboxyphenyl)methylphosphonic acid
101258-15-5

(4-carboxyphenyl)methylphosphonic acid

Conditions
ConditionsYield
Stage #1: 4-bromomethylbenzoic Acid With triethyl phosphite In toluene for 12h; Reflux;
Stage #2: With hydrogenchloride In water; toluene for 12h; Reflux;
94%
Multi-step reaction with 2 steps
1: 3 h / Heating
2: 6N HCl / H2O / 72 h / Heating
View Scheme
carbon disulfide
75-15-0

carbon disulfide

1-butanethiol
109-79-5

1-butanethiol

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

4-((((butylthio)carbon-thioyl)thio)methyl)benzoic acid

4-((((butylthio)carbon-thioyl)thio)methyl)benzoic acid

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20℃; for 6.5h; Inert atmosphere;93.9%
pyridine-4-carboxylic acid
55-22-1

pyridine-4-carboxylic acid

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

4-carboxy-1-(4-carboxybenzyl)pyridinium bromide

4-carboxy-1-(4-carboxybenzyl)pyridinium bromide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 70℃; for 6h;93%
5-[(4-benzyloxy-3-methoxyphenyl)methylidene]-2,4-thiazolidinedione
911714-25-5

5-[(4-benzyloxy-3-methoxyphenyl)methylidene]-2,4-thiazolidinedione

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

4-({5-[(4-benzyloxy-3-methoxyphenyl)methylidene]-2,4-dioxothiazolidin-3-yl}methyl)benzoic acid

4-({5-[(4-benzyloxy-3-methoxyphenyl)methylidene]-2,4-dioxothiazolidin-3-yl}methyl)benzoic acid

Conditions
ConditionsYield
With potassium carbonate In acetone for 48h; Reflux;93%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

sodium acetate
127-09-3

sodium acetate

p-acetoxymethyl benzoic acid
15561-46-3

p-acetoxymethyl benzoic acid

Conditions
ConditionsYield
In acetic acid for 24h; Reflux; Inert atmosphere;93%
6-bromo-1,2,3,4-tetrahydroisoquinoline
226942-29-6

6-bromo-1,2,3,4-tetrahydroisoquinoline

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

4-((6-bromo-3,4-dihydroisoquinolin-2(1H)-yl)methyl)benzoic acid

4-((6-bromo-3,4-dihydroisoquinolin-2(1H)-yl)methyl)benzoic acid

Conditions
ConditionsYield
In tetrahydrofuran for 8h; Reflux;92.3%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

4-(3-cyano-4,6-diphenyl-pyridin-2-ylsulfanylmethyl)-benzoic acid

4-(3-cyano-4,6-diphenyl-pyridin-2-ylsulfanylmethyl)-benzoic acid

Conditions
ConditionsYield
Stage #1: 4,6-diphenyl-2-thioxo-1,2-dihydropyridine-3-carbonitrile With potassium hydroxide In water; N,N-dimethyl-formamide for 0.166667h;
Stage #2: 4-bromomethylbenzoic Acid In water; N,N-dimethyl-formamide
Stage #3: With hydrogenchloride; water In N,N-dimethyl-formamide
92%
thionyl chloride
7719-09-7

thionyl chloride

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

4-(bromomethyl)benzamide
58914-40-2

4-(bromomethyl)benzamide

Conditions
ConditionsYield
Stage #1: thionyl chloride; 4-bromomethylbenzoic Acid In tetrachloromethane for 95h; Heating / reflux;
Stage #2: With ammonia In tetrachloromethane for 0.166667h;
92%
1-thiopropane
107-03-9

1-thiopropane

4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

4-(propylthiomethyl)benzoic acid
1019561-88-6

4-(propylthiomethyl)benzoic acid

Conditions
ConditionsYield
Stage #1: 1-thiopropane With sodium hydride In tetrahydrofuran; mineral oil
Stage #2: 4-bromomethylbenzoic Acid In tetrahydrofuran; mineral oil for 1h; Reflux;
Stage #3: In tetrahydrofuran; methanol; mineral oil for 16h; Reflux;
92%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

phenylacetylene
536-74-3

phenylacetylene

4-((4-phenyl-1H-1,2,3-triazol-4-yl)methyl)benzoic acid
1235527-54-4

4-((4-phenyl-1H-1,2,3-triazol-4-yl)methyl)benzoic acid

Conditions
ConditionsYield
With sodium azide In ethanol at 80℃; for 8h;92%
4-bromomethylbenzoic Acid
6232-88-8

4-bromomethylbenzoic Acid

C34H22CoN10O4(1-)

C34H22CoN10O4(1-)

C66H46CoN10O12(1-)*Br(1-)*4H2O*2H(1+)

C66H46CoN10O12(1-)*Br(1-)*4H2O*2H(1+)

Conditions
ConditionsYield
In dimethyl sulfoxide at 20℃; for 2h;92%

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