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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Borane-tetrahydrofuran complex Manufacturer/High quality/Best price/In stock

Cas:14044-65-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Sinoway Industrial Co., Ltd.

1. High quality: viscosity range from 400mPAS to 75000mPAS 2. Big capacity: 500mt per month 3. A lower price with high quality 4. Certificate: ISO, COA 5. Package: Packed with multi-layer paper bags, with polyethylene inner bag, net weight 25kg

Borane tetrahydrofuran complex solution

Cas:14044-65-6

Min.Order:25 Kilogram

FOB Price: $20.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

The company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance:Colorless liquid Storage:Sealed, dry, microther

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Borane-tetrahydrofuran complex

Cas:14044-65-6

Min.Order:1

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Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Borane-tetrahydrofuran complex

Cas:14044-65-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Borane-tetrahydrofuran complex/ LIDE PHARMA- Factory supply / Best price

Cas:14044-65-6

Min.Order:1 Gram

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Henan Tianfu Chemical Co., Ltd.

Borane-tetrahydrofuran complex Basic information Product Name: Borane-tetrahydrofuran complex Synonyms: borane-tetrahydrofurancomplex,bthf-1m;borane-tetrahydrofurancomplex,bthf-2m;TETRAH

TIANFU-CHEM CAS:14044-65-6 Borane-tetrahydrofuran complex

Cas:14044-65-6

Min.Order:1 Gram

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

Borane-tetrahydrofuran complex CAS 14044-65-6

Cas:14044-65-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 14044-65-6 with best quality

Cas:14044-65-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Boron,trihydro(tetrahydrofuran)-, (T-4)- 14044-65-6

Cas:14044-65-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: Borane-tetrahydrofuran complex Synonyms: borane-tetrahydrofurancomplex,bthf-1m;BORAN-TETRAHYDROFURANCOMPLEX;BORANE-TETRAHYDROFURANCOMPLEX,1MSOLUTIONINTETRAHYDROFURAN;Borane tetrahydrofuran complex 1.0 molar in THF;Borane-tetrahydr

Borane-tetrahydrofuran complex

Cas:14044-65-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Organic Synthesis, Borane-tetrahydrofuran complex CAS:14044-65-6

Cas:14044-65-6

Min.Order:1 Kilogram

FOB Price: $21.0 / 24.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Borane-tetrahydrofuran complex CAS:14044-65-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality or

Borane-tetrahydrofuran complex CAS:14044-65-6

Cas:14044-65-6

Min.Order:1 Gram

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Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Boron,trihydro(tetrahydrofuran)-, (T-4)-

Cas:14044-65-6

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Product quality: Our company have high quality product , and also the product we have good manufacture . First of all, this product is of fine quality. Every finish should be checked by quality inspection system.And every one should be also tried

High Quality Borane-Tetrahydrofu Ran Complex CAS 14044-65-6 Tetrahydrofuran-Borane

Cas:14044-65-6

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Trading Company

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Borane-tetrahydrofuran complex

Cas:14044-65-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Lab/Research institutions

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Zhengzhou Yuanli Biological Technology Co., Ltd.

ProName: 14044-65-6 1.0om/L,YL CasNo: 14044-65-6 Molecular Formula: C4H11BO Appearance: colorless liquid. Application: Intermediates. DeliveryTime:Have stock. Processing period:1 kg/5 weeks. PackAge: 4L/bottle. Port: Beijing, Shanghai,

14044-65-6 1.0om/L,YL

Cas:14044-65-6

Min.Order:1 Liter

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

BORANE-TETRAHYDROFURAN COMPLEX

Cas:14044-65-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Borane-tetrahydrofuran complex

Cas:14044-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Borane-tetrahydrofuran complex

Cas:14044-65-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Borane-tetrahydrofuran complex

Cas:14044-65-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

Borane-tetrahydrofuran complex

Cas:14044-65-6

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)

Borane-tetrahydrofuran complex CAS NO.: 14044-65-6

Cas:14044-65-6

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Borane-tetrahydrofurancomplex

Cas:14044-65-6

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Borane-tetrahydrofuran complex

Cas:14044-65-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Borane-tetrahydrofuran complex

Cas:14044-65-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

Boron,trihydro(tetrahydrofuran)-, (T-4)-

Cas:14044-65-6

Min.Order:0

Negotiable

Type:Other

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Wuhu Nuowei Chemistry Technologies Co., Ltd.

Wuhu Nuovo Chemical Technology Co., Ltd. was established in August 2014, mainly engaged in the development, production and sales of ionic liquids, ribose, nucleosides, nucleotides and related chemicals; Products are mainly used in new energy, new ma

Borane tetrahydrofuran complex solution

Cas:14044-65-6

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

BORANE-TETRAHYDROFURAN COMPLEX

Cas:14044-65-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in

SAGECHEM/ Borane tetrahydrofuran /Manufacturer in China

Cas:14044-65-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Synthetic route

tetrahydrofuran
109-99-9

tetrahydrofuran

borane-THF
14044-65-6

borane-THF

Conditions
ConditionsYield
With dimethylsulfide borane complex for 0.5h; Heating / reflux;
lithium borohydride

lithium borohydride

methanesulfonic acid
75-75-2

methanesulfonic acid

borane-THF
14044-65-6

borane-THF

Conditions
ConditionsYield
With tetrahydrofuran In tetrahydrofuran byproducts: LiO3SMe, H2; N2-atmosphere, 25°C, 0.25 h, stirring; not isolated, reaction followed by (11)B-NMR spectroscopy and H2-volumetry;
lithium borohydride

lithium borohydride

aluminium trichloride
7446-70-0

aluminium trichloride

A

borane-THF
14044-65-6

borane-THF

B

hydridoaluminium bis(tetrahydroborate)

hydridoaluminium bis(tetrahydroborate)

Conditions
ConditionsYield
With tetrahydrofuran In tetrahydrofuran molar ratio B:Al=1:1 to 7.2:1; not isolated, detd. by (11)B-NMR spectroscopy;
lithium borohydride

lithium borohydride

aluminium bromide
7727-15-3

aluminium bromide

A

borane-THF
14044-65-6

borane-THF

B

hydridoaluminium bis(tetrahydroborate)

hydridoaluminium bis(tetrahydroborate)

Conditions
ConditionsYield
With tetrahydrofuran In tetrahydrofuran molar ratio B:Al=2.8:1 to 1:2; not isolated, detd. by (11)B-NMR spectroscopy;
lithium borohydride

lithium borohydride

borane-THF
14044-65-6

borane-THF

Conditions
ConditionsYield
With tetrahydrofuran; aluminium trichloride In tetrahydrofuran addn. of AlCl3 to LiBH4 (molar ratio B:Al=1.2:1 to 1.7:1); not isolated, detd. by (11)B-NMR spectroscopy;
With tetrahydrofuran; aluminum tri-bromide; aluminium trichloride In tetrahydrofuran addn. of LiBH4 to AlBr3 (molar ratio B:Al=4:1), 1 h; not isolated, detd. by (11)B-NMR spectroscopy;
With tetrahydrofuran; aluminum tri-bromide In tetrahydrofuran molar ratio B:Al=1:1 to 7.4:1; not isolated, detd. by (11)B-NMR spectroscopy;
lithium borohydride

lithium borohydride

bis(trimethylsilyl)sulphate
18306-29-1

bis(trimethylsilyl)sulphate

borane-THF
14044-65-6

borane-THF

Conditions
ConditionsYield
With tetrahydrofuran In tetrahydrofuran byproducts: Li2SO4; N2-atmosphere, 25°C, 0.25 h, stirring; not isolated, reaction followed by (11)B-NMR spectroscopy;
lithium borohydride

lithium borohydride

trimethylsilyl methanesulfonate
10090-05-8

trimethylsilyl methanesulfonate

borane-THF
14044-65-6

borane-THF

Conditions
ConditionsYield
With tetrahydrofuran In tetrahydrofuran byproducts: LiO3SMe, HSiMe3; N2-atmosphere, 25°C, 0.25 h, stirring; not isolated, reaction followed by (11)B-NMR spectroscopy;
triborane(7)*tetrahydrofuran

triborane(7)*tetrahydrofuran

trimethylphosphine-borane
1898-77-7

trimethylphosphine-borane

A

borane-THF
14044-65-6

borane-THF

B

pentaborane(9)
19624-22-7

pentaborane(9)

C

trimethylphosphine-triborane adduct
97012-38-9

trimethylphosphine-triborane adduct

D

diborane
19287-45-7

diborane

Conditions
ConditionsYield
In tetrahydrofuran soln. of educts in THF allowed to stand at room temp. for 8 months; NMR anal.;
tetraborane
18283-93-7

tetraborane

trimethylphosphane
594-09-2

trimethylphosphane

A

borane-THF
14044-65-6

borane-THF

B

octahydrotriborate(1-)

octahydrotriborate(1-)

C

trimethylphosphine-triborane adduct
97012-38-9

trimethylphosphine-triborane adduct

D

triborane(7)*tetrahydrofuran

triborane(7)*tetrahydrofuran

E

trimethylphosphine-borane
1898-77-7

trimethylphosphine-borane

Conditions
ConditionsYield
With tetrahydrofuran In tetrahydrofuran; dichloromethane B4H10 dissolved in THF at -80°C, kept at 0°C for 4 h, treated with PMe3 in CH2Cl2 at 25°C; NMR anal.;
tetraborane
18283-93-7

tetraborane

trimethylphosphane
594-09-2

trimethylphosphane

A

borane-THF
14044-65-6

borane-THF

B

triborane(7)*tetrahydrofuran

triborane(7)*tetrahydrofuran

C

H2B[P(CH3)3]2(1+)*B3H8(1-)=H2B[P(CH3)3]2B3H8

H2B[P(CH3)3]2(1+)*B3H8(1-)=H2B[P(CH3)3]2B3H8

D

trimethylphosphine-borane
1898-77-7

trimethylphosphine-borane

Conditions
ConditionsYield
With tetrahydrofuran In tetrahydrofuran B4H10 dissolved in THF at -80°C, kept at -63°C for 3 h, treated with PMe3, kept at -10 to 25°C; NMR anal.;
aluminium trichloride
7446-70-0

aluminium trichloride

tetrabutylammonium borohydride

tetrabutylammonium borohydride

A

borane-THF
14044-65-6

borane-THF

B

(CH3CH2CH2CH2)4N(1+)*Al(3+)*2BH4(1-)*2Cl(1-)=(CH3CH2CH2CH2)4N[Al(BH4)2Cl2]

(CH3CH2CH2CH2)4N(1+)*Al(3+)*2BH4(1-)*2Cl(1-)=(CH3CH2CH2CH2)4N[Al(BH4)2Cl2]

Conditions
ConditionsYield
In tetrahydrofuran addn. of AlCl3 to Bu4NBH4 (molar ratio B:Al=1:2 or 1:3); or addn. of Bu4NBH4 to AlCl3 (molar ratio B:Al=5:1 to 2:1); not isolated, detd. by (11)B-NMR spectrocopy;
tetraborane
18283-93-7

tetraborane

phosphan
7803-51-2

phosphan

A

borane-THF
14044-65-6

borane-THF

B

triborane(7)*tetrahydrofuran

triborane(7)*tetrahydrofuran

C

phosphine-triborane(7)

phosphine-triborane(7)

D

phosphine-borane
19121-56-3

phosphine-borane

Conditions
ConditionsYield
With tetrahydrofuran In tetrahydrofuran B4H10 dissolved in THF at -80°C, kept at 0°C for 4 h, treated with PH3 at -60°C, allowed to warm to 0°C, stored for67 h; NMR anal.;
With tetrahydrofuran In tetrahydrofuran B4H10 dissolved in THF at -80°C, kept at -63°C for 3 h, treated with PH3 at -80 to -50°C, warmed slowly to 0°C; NMR anal.;
aluminium trichloride
7446-70-0

aluminium trichloride

tetrabutylammonium borohydride

tetrabutylammonium borohydride

A

borane-THF
14044-65-6

borane-THF

B

(CH3CH2CH2CH2)4N(1+)*Al(3+)*2BH4(1-)*2Cl(1-)=(CH3CH2CH2CH2)4N[Al(BH4)2Cl2]

(CH3CH2CH2CH2)4N(1+)*Al(3+)*2BH4(1-)*2Cl(1-)=(CH3CH2CH2CH2)4N[Al(BH4)2Cl2]

C

tetrabutylammonium diborohydride
40001-25-0

tetrabutylammonium diborohydride

Conditions
ConditionsYield
In tetrahydrofuran addn. of AlCl3 to Bu4NBH4 (molar ratio B:Al=1:1); not isolated, detd. by (11)B-NMR spectrocopy;
tetrahydrofuran
109-99-9

tetrahydrofuran

triphenylmethane hydrodisulfide
3492-71-5

triphenylmethane hydrodisulfide

A

borane-THF
14044-65-6

borane-THF

B

triphenylmethanethiol
3695-77-0

triphenylmethanethiol

C

hydrosulfide anion
15035-72-0

hydrosulfide anion

Conditions
ConditionsYield
With tetrabutylammonium borohydride In dichloromethane-d2 Inert atmosphere; Glovebox;
tetrahydrofuran
109-99-9

tetrahydrofuran

sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

borane-THF
14044-65-6

borane-THF

Conditions
ConditionsYield
With dimethyl sulfate at -10℃;
With chloro-trimethyl-silane at 20℃; for 24h; Reagent/catalyst; Temperature;
With iodine In tetrahydrofuran at 0 - 20℃; for 1h; Inert atmosphere; Schlenk technique;
With iodine at 0℃; for 1h; Inert atmosphere;
tetrahydrofuran
109-99-9

tetrahydrofuran

diborane
19287-45-7

diborane

borane-THF
14044-65-6

borane-THF

Conditions
ConditionsYield
at 0 - 5℃; for 0.75h; Inert atmosphere;
tetrahydrofuran
109-99-9

tetrahydrofuran

BH4(1-)*BH6N2(1-)*2H(1+)

BH4(1-)*BH6N2(1-)*2H(1+)

borane-THF
14044-65-6

borane-THF

Conditions
ConditionsYield
With dimethyl amine at -40 - 20℃; for 0.166667h; Inert atmosphere;
ammonia borane complex
10043-11-5

ammonia borane complex

H2BCl * tetrahydrofuran
55606-72-9

H2BCl * tetrahydrofuran

A

borane-THF
14044-65-6

borane-THF

B

ammonia chloroborane
71648-05-0

ammonia chloroborane

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; Equilibrium constant; Schlenk technique;
benzophenone
119-61-9

benzophenone

borane-THF
14044-65-6

borane-THF

tris(diphenylmethoxy)borane
29002-71-9

tris(diphenylmethoxy)borane

Conditions
ConditionsYield
In tetrahydrofuran (N2); 0°C, 5 min; removal of volatiles, recrystn. (hot toluene); elem. anal.;100%
borane-THF
14044-65-6

borane-THF

[disodium(2+)][1,2-diselena-diboranate(2-)]

[disodium(2+)][1,2-diselena-diboranate(2-)]

Na(1+)*H3BSe(B2H5)(1-)=Na[H3BSeB2H5]
131636-29-8

Na(1+)*H3BSe(B2H5)(1-)=Na[H3BSeB2H5]

Conditions
ConditionsYield
In further solvent(s) byproducts: H2; Ar atm.; triglyme or diglyme, room temp., heating (50°C); evapn. (vac.), followed by NMR;100%
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

borane-THF
14044-65-6

borane-THF

diphosphane-borane
186336-54-9

diphosphane-borane

sodium 1,1,2-tris(borane)-1,2,2-trihydrogendiphosphide
186336-57-2

sodium 1,1,2-tris(borane)-1,2,2-trihydrogendiphosphide

Conditions
ConditionsYield
In tetrahydrofuran byproducts: H2, Na2[P2H2(BH3)4]; N2 atm.; molar ratio P2H4BH3:NaBH4 1:1, cooling (-78 to -196°C), stirring (4 h), heating (-78°C, 3 h), stirring (room temp., 6 h); crystn. (-78°C, several d);100%
borane-THF
14044-65-6

borane-THF

((CH3)3Si)2NHBH3
186796-04-3

((CH3)3Si)2NHBH3

N,N-bis(trimethylsilyl)-μ-aminodiborane
186796-05-4

N,N-bis(trimethylsilyl)-μ-aminodiborane

Conditions
ConditionsYield
In tetrahydrofuran byproducts: H2; N2 atm.; equimolar ratio, stirring (room temp., 12 h); solvent removal (vac.);100%
borane-THF
14044-65-6

borane-THF

tris(3,5-dibromo-2-hydoxyphenyl)methane
1289219-86-8

tris(3,5-dibromo-2-hydoxyphenyl)methane

C23H15BBr6O4
1289219-91-5

C23H15BBr6O4

Conditions
ConditionsYield
In tetrahydrofuran; dichloromethane at 20℃; for 2h; Inert atmosphere;100%
borane-THF
14044-65-6

borane-THF

tris(5-bromo-2-hydroxyphenyl)methane
1289219-87-9

tris(5-bromo-2-hydroxyphenyl)methane

C23H18BBr3O4
1289219-92-6

C23H18BBr3O4

Conditions
ConditionsYield
In tetrahydrofuran; dichloromethane at 20℃; for 2h; Inert atmosphere;100%
borane-THF
14044-65-6

borane-THF

tris(5-fluoro-2-hydroxyphenyl)methane
1289219-88-0

tris(5-fluoro-2-hydroxyphenyl)methane

C23H18BF3O4
1289219-94-8

C23H18BF3O4

Conditions
ConditionsYield
In tetrahydrofuran; dichloromethane at 20℃; for 2h; Inert atmosphere;100%
borane-THF
14044-65-6

borane-THF

tris(2-hydroxy-3-phenylphenyl)methane
1289219-89-1

tris(2-hydroxy-3-phenylphenyl)methane

C41H33BO4
1289219-95-9

C41H33BO4

Conditions
ConditionsYield
In tetrahydrofuran; dichloromethane at 20℃; for 2h; Inert atmosphere;100%
borane-THF
14044-65-6

borane-THF

tris(2-hydroxy-3-(1-naphthyl)phenyl)methane
1289219-90-4

tris(2-hydroxy-3-(1-naphthyl)phenyl)methane

C53H39BO4
1289219-96-0

C53H39BO4

Conditions
ConditionsYield
In tetrahydrofuran; dichloromethane at 20℃; for 3h; Inert atmosphere;100%
borane-THF
14044-65-6

borane-THF

N2,N6-bis(diisopropylphosphino)pyridine-2,6-diamine
885665-51-0

N2,N6-bis(diisopropylphosphino)pyridine-2,6-diamine

N,N′-bis(diisopropylphosphino-borane)-2,6-diaminopyridine
1433219-02-3

N,N′-bis(diisopropylphosphino-borane)-2,6-diaminopyridine

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere; Schlenk technique;100%
borane-THF
14044-65-6

borane-THF

o-anisyl(hydroxymethyl)phenylphosphine oxide

o-anisyl(hydroxymethyl)phenylphosphine oxide

o-anisyl(hydroxymethyl)phenylphosphine borane

o-anisyl(hydroxymethyl)phenylphosphine borane

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 4.03h; Inert atmosphere; Schlenk technique; regioselective reaction;100%
borane-THF
14044-65-6

borane-THF

C34H30N2

C34H30N2

C34H36B2N2

C34H36B2N2

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 2.5h; Inert atmosphere;100%
borane-THF
14044-65-6

borane-THF

(η5-C5H4PCy2)Re(CO)2CO

(η5-C5H4PCy2)Re(CO)2CO

C20H29BO3PRe

C20H29BO3PRe

Conditions
ConditionsYield
In tetrahydrofuran100%
borane-THF
14044-65-6

borane-THF

(η5-C5H4PPh2)Re(CO)2PMe3
1241904-55-1

(η5-C5H4PPh2)Re(CO)2PMe3

C22H26BO2P2Re

C22H26BO2P2Re

Conditions
ConditionsYield
In tetrahydrofuran100%
borane-THF
14044-65-6

borane-THF

(η5-C5H4PPh2)Re(CO)2P(OMe)3
1241904-56-2

(η5-C5H4PPh2)Re(CO)2P(OMe)3

C22H26BO5P2Re

C22H26BO5P2Re

Conditions
ConditionsYield
In tetrahydrofuran100%
borane-THF
14044-65-6

borane-THF

tricarbonyl(η5-diphenylphosphinocyclopentadienyl)rhenium

tricarbonyl(η5-diphenylphosphinocyclopentadienyl)rhenium

C20H17BO3PRe

C20H17BO3PRe

Conditions
ConditionsYield
In tetrahydrofuran100%
3,5-dibromopyridine
625-92-3

3,5-dibromopyridine

borane-THF
14044-65-6

borane-THF

tris[{S}-1-{2-hydroxy-3-(1-naphthyl)naphthyl}]methane

tris[{S}-1-{2-hydroxy-3-(1-naphthyl)naphthyl}]methane

C66H40BBr2NO3

C66H40BBr2NO3

Conditions
ConditionsYield
Stage #1: borane-THF; tris[{S}-1-{2-hydroxy-3-(1-naphthyl)naphthyl}]methane In dichloromethane at 60℃; for 8h; Glovebox; Inert atmosphere; Sealed tube;
Stage #2: 3,5-dibromopyridine In dichloromethane for 0.0833333h; Glovebox; Inert atmosphere; Sealed tube;
100%
borane-THF
14044-65-6

borane-THF

tris[{S}-1-{2-hydroxy-3-(1-naphthyl)naphthyl}]methane

tris[{S}-1-{2-hydroxy-3-(1-naphthyl)naphthyl}]methane

C65H45BO4

C65H45BO4

Conditions
ConditionsYield
In dichloromethane at 60℃; for 8h; Glovebox; Inert atmosphere; Sealed tube;100%
borane-THF
14044-65-6

borane-THF

[2-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)phenyl]diphenylphosphine
1250258-94-6

[2-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)phenyl]diphenylphosphine

diphenyl-[2-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]phosphine borane
1417911-71-7

diphenyl-[2-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]phosphine borane

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 3h; Inert atmosphere;100%
borane-THF
14044-65-6

borane-THF

tris(3-bromo-2-hydroxyphenyl)(methyl)silane

tris(3-bromo-2-hydroxyphenyl)(methyl)silane

C23H20BBr3O4Si

C23H20BBr3O4Si

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; Glovebox;100%
borane-THF
14044-65-6

borane-THF

tris(2-hydroxy- [1,1'-biphenyl]-3-yl)(methyl)silane

tris(2-hydroxy- [1,1'-biphenyl]-3-yl)(methyl)silane

C41H35BO4Si

C41H35BO4Si

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; Glovebox;100%
borane-THF
14044-65-6

borane-THF

(4-hydroxyphenyl)(methyl)(phenyl)phosphine

(4-hydroxyphenyl)(methyl)(phenyl)phosphine

(4-hydroxyphenyl)(methyl)(phenyl)phosphine borane

(4-hydroxyphenyl)(methyl)(phenyl)phosphine borane

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 3h; Inert atmosphere;100%
borane-THF
14044-65-6

borane-THF

bis(di-tert-butylphosphanyl)amine
97049-90-6

bis(di-tert-butylphosphanyl)amine

C16H43B2NP2

C16H43B2NP2

Conditions
ConditionsYield
In tetrahydrofuran; toluene for 0.166667h;100%
borane-THF
14044-65-6

borane-THF

Tri-(tert-butyl)-phosphinmethylen
64286-40-4

Tri-(tert-butyl)-phosphinmethylen

trihydro(tri-tert-butylphosphoniomethyl)borate
73946-50-6

trihydro(tri-tert-butylphosphoniomethyl)borate

Conditions
ConditionsYield
In tetrahydrofuran byproducts: THF; under N2, mixt. decompd. at -20°C, then stirring at 20°C for 2 h; solvent removed, recrystd. from toluene/pentane, elem. anal.;99%
borane-THF
14044-65-6

borane-THF

4,5-dihydro-3H-dinaphtho[2.1-c:1',2'-e]phosphepine
218767-47-6

4,5-dihydro-3H-dinaphtho[2.1-c:1',2'-e]phosphepine

Fe(CO)4(4,5-dihydro-3H-dinaphtho[2.1-c:1',2'-e]phosphepine), borane adduct
524941-61-5, 218767-81-8, 1092063-99-4

Fe(CO)4(4,5-dihydro-3H-dinaphtho[2.1-c:1',2'-e]phosphepine), borane adduct

Conditions
ConditionsYield
In tetrahydrofuran inert atmosphere; equimolar amts., stirring for 12 h; solvent removal (20°C, 0.05 mbar); elem. anal.;99%
borane-THF
14044-65-6

borane-THF

arachno-9-1,1'-bis(diphenylphosphino)ferrocene-6-SB9H11

arachno-9-1,1'-bis(diphenylphosphino)ferrocene-6-SB9H11

arachno-9-1,1'-bis(diphenylphosphino)ferrocene(BH3)-6-SB9H11

arachno-9-1,1'-bis(diphenylphosphino)ferrocene(BH3)-6-SB9H11

Conditions
ConditionsYield
In tetrahydrofuran; toluene byproducts: THF; N2-atmosphere; addn. of borane (in THF) to Fe-complex (in PhMe), standing for 2 h; in air; filtration (SiO2), evapn. (vac.), chromy. (SiO2, CH2Cl2/hexane=1:1); elem. anal.;99%
borane-THF
14044-65-6

borane-THF

[(η6-p-cymeme)RuCl2(η1-PPh2CCPPh2)]
913821-47-3

[(η6-p-cymeme)RuCl2(η1-PPh2CCPPh2)]

[(η6-p-cymeme)RuCl2(η1-PPh2CCPPh2BH3)]
913821-48-4

[(η6-p-cymeme)RuCl2(η1-PPh2CCPPh2BH3)]

Conditions
ConditionsYield
In tetrahydrofuran under N2; 1.2 M soln. of BH3*THF (0.01 ml) added dropwise to soln. of Rucomplex (0.01 ml) in THF (2 ml, -78°C); stirred (1 h); solvent removed (vac., room temp.);99%
1,1'-oxybis(2-bromo-ethane)
5414-19-7

1,1'-oxybis(2-bromo-ethane)

borane-THF
14044-65-6

borane-THF

methylphenylphosphine
6372-48-1

methylphenylphosphine

2,2'-oxybis(ethane-2,1-diyl)bis(methylphenylphosphine-borane)
1147564-62-2, 1147564-78-0

2,2'-oxybis(ethane-2,1-diyl)bis(methylphenylphosphine-borane)

Conditions
ConditionsYield
With NaOCH(CH3)2CH2CH2; [RuH(1,2-bis(dimethylphosphino)ethane)((R)-DIFLUORPHOS)][tetraphenylborate] In tetrahydrofuran (N2); addn. of phosphine deriv. and benzyl chloride to THF soln. of sodium alcoholate deriv. and ruthenium compd., stirring at room temp. for 90min, addn. of THF soln. of borane deriv., stirring at room temp. for 30 min; addn. of water, extn. (ethyl acetate), washing with brine, drying over Na2SO4, filtration, concg., chromy. (silica gel, 75:25 hexanes/ethyl acetate), NMR and MS;99%
borane-THF
14044-65-6

borane-THF

4,6-bis(chloromethyl)dibenzofuran
1147564-68-8

4,6-bis(chloromethyl)dibenzofuran

methylphenylphosphine
6372-48-1

methylphenylphosphine

C12H6O(CH2P(Me)(Ph)(BH3))2
1147564-48-4, 1147564-70-2

C12H6O(CH2P(Me)(Ph)(BH3))2

Conditions
ConditionsYield
With NaOCH(CH3)2CH2CH2; [RuH(1,2-bis(dimethylphosphino)ethane)((R)-MeO-BiPHEP)][tetraphenylborate] In tetrahydrofuran (N2); addn. of phosphine deriv. and benzyl chloride to THF soln. of sodium alcoholate deriv. and ruthenium compd., stirring at room temp. for 90min, addn. of THF soln. of borane deriv., stirring at room temp. for 30 min; addn. of water, extn. (ethyl acetate), washing with brine, drying over Na2SO4, filtration, concg., chromy. (silica gel, 75:25 hexanes/ethyl acetate);99%
borane-THF
14044-65-6

borane-THF

(CH3)2C13H6O(CH2Cl)2
1147564-67-7

(CH3)2C13H6O(CH2Cl)2

methylphenylphosphine
6372-48-1

methylphenylphosphine

(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(methylene)bis(methylphenylphosphine-borane)
1147564-34-8, 1147564-69-9

(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(methylene)bis(methylphenylphosphine-borane)

Conditions
ConditionsYield
With NaOCH(CH3)2CH2CH2; [RuH(1,2-bis(dimethylphosphino)ethane)((R)-MeO-BiPHEP)][tetraphenylborate] In tetrahydrofuran (N2); addn. of phosphine deriv. and benzyl chloride to THF soln. of sodium alcoholate deriv. and ruthenium compd., stirring at room temp. for 90min, addn. of THF soln. of borane deriv., stirring at room temp. for 30 min; addn. of water, extn. (ethyl acetate), washing with brine, drying over Na2SO4, filtration, concg., chromy. (silica gel, 75:25 hexanes/ethyl acetate);99%
With NaOCH(CH3)2CH2CH2; [RuH(1,2-bis(dimethylphosphino)ethane)((R)-MeO-BiPHEP)][tetraphenylborate] In tetrahydrofuran (N2); addn. of phosphine deriv. and benzyl chloride to THF soln. of sodium alcoholate deriv. and ruthenium compd., stirring at room temp. for 90min, addn. of THF soln. of borane deriv., stirring at -30°C; addn. of water, extn. (ethyl acetate), washing with brine, drying over Na2SO4, filtration, concg., chromy. (silica gel, 75:25 hexanes/ethyl acetate);

Raw Materials

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